TWI258182B - High-voltage transistor device having an interlayer dielectric etch stop layer for preventing leakage and improve breakdown voltage - Google Patents

High-voltage transistor device having an interlayer dielectric etch stop layer for preventing leakage and improve breakdown voltage Download PDF

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TWI258182B
TWI258182B TW094140955A TW94140955A TWI258182B TW I258182 B TWI258182 B TW I258182B TW 094140955 A TW094140955 A TW 094140955A TW 94140955 A TW94140955 A TW 94140955A TW I258182 B TWI258182 B TW I258182B
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layer
stop layer
region
semiconductor device
gate
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TW200618064A (en
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Chung-I Chen
Hsin Kuan
Zhi-Cheng Chen
Rann-Shyan Yeh
Chi-Hsuen Chang
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Taiwan Semiconductor Mfg
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    • H01L29/7835Field effect transistors with field effect produced by an insulated gate with lightly doped drain or source extension, e.g. LDD MOSFET's; DDD MOSFET's with asymmetrical source and drain regions, e.g. lateral high-voltage MISFETs with drain offset region, extended drain MISFETs
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    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76801Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
    • H01L21/76829Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing characterised by the formation of thin functional dielectric layers, e.g. dielectric etch-stop, barrier, capping or liner layers
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    • H01L21/76801Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
    • H01L21/76829Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing characterised by the formation of thin functional dielectric layers, e.g. dielectric etch-stop, barrier, capping or liner layers
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    • H01L29/7836Field effect transistors with field effect produced by an insulated gate with lightly doped drain or source extension, e.g. LDD MOSFET's; DDD MOSFET's with a significant overlap between the lightly doped extension and the gate electrode
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    • H01L29/02Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/06Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions
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    • H01L29/0642Isolation within the component, i.e. internal isolation
    • H01L29/0649Dielectric regions, e.g. SiO2 regions, air gaps
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    • H01L29/66409Unipolar field-effect transistors
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Description

1258182 九、發明說明: 【發明所屬之技術領域】 本發明有關於一 有蝕刻停止層之高電 崩潰電壓。 種應用在高電壓之電晶體元件, i電日日體元件,其中韻刻停止層 而特別有關於一種具 可預防漏電流及改善 【先别技術】
管理件可在錄領域中,包括··液晶顯轉之鶴η、電源 二 電源供應斋,非揮發性記憶體、通訊電路以及控制雷跋。盆由 ’ Γ顯:r_c需要在蝴或中等電:下以驅動相關 4電路’而以南糕來驅動液晶顯示器。由於單_ 瓜而5,大部分金氧半導體電晶體中會在閘極與源極△及極區域之間 口入絶緣層’來降低通道中的垂直電場。也可將絕緣層下的漂移區域(_ 哪⑽)與·及跡區域,輯輕微雜,提供_必要的電麵度。上 籲述兩種方法可增加源極及汲極區域中的接面崩潰電屢,因此可使金氧半導 體電晶體在高電麈下(例如電壓大於5V)也可正常運作。DM〇s(d〇ubie cUd drain MOS)為一種高電壓電晶體,依其電流路徑方向可歸類為 VDMOSherticalDMOS)電晶體及 LDMOSdateralDMOS)電晶體。參照美國 專利U. S. Pat Ν0· 6468870,揭露一種具有層間介電層之ldm〇s電晶體的 製造方法。 傳統上,源極及汲極區域電性連接至層間介電層中的導電接觸窗,且 在電路結構上通常會形成—侧停止層,使後續接職細製程中不會傷 害到電路結構。U.s· Pat NO· 6630398揭露一種具有氮氧化矽蝕刻停止層之 無邊界接觸窗。U.S· Pat. NO· 6235653 及 U.S. Pat· NO. 6316348 揭露一種矽 0503-A30922TWF 5 1258182 -莫耳百分比介於約58%至62%之富矽氮氧化石夕薄膜,這種富矽之氮氧化石夕 薄膜不足以在高電壓元件應用中當作緩衝絕緣,因為富矽之氮氧化矽薄膜 會在漏電流處引發額外的漏電流。額外的漏電流路徑會在閘極至源極間引 發大量漏電流,而降低閘極氧化物的崩潰電壓。晶片可靠度測試顯示,具 有富石夕氮氧化石夕薄膜之高電壓金氧半導體電晶體無法通過G〇l(gate oxide integrating)測試,且會引發時依性汲極電流。 【發明内容】 有鑑於此,本發明的目的就在於提供一高電壓電晶體元件,具有電阻 率超過10ohm-cm之蝕刻停止層,可預防漏電流及改善崩潰電壓。 為達成上述目的,本發明提供一種高電壓電晶體元件,其製造方法包 括·提供-半導體基底;在—高電壓元件區域上形成_閘極結構;在高電 件區域及半導體基底上形成至少—擴散區域,且側面地排列於閑極結 構的側壁;在閘極結構及擴散區域上形成一侧停止層,其中侧停止層 之電阻率大於10〇hm-cm;在該鍅刻停止層上形成一層間介電層,其中至少 -接,窗穿過層間介電層及_停止層域出擴散區域。侧停止層選擇 ^ 自除富石夕但氧化石夕外的所有介電材料。 本發明之高電壓電晶體元件包括: 於一午等體基底之 r甲]極結構立々、丁守菔巷 问電塵讀區域上;至少一擴散區域,形成在該高電壓元件區域中,且 側面地鄰祕該閘極結構的側壁;—爛停止層,置麟 散區域之上,其愤侧停止層的電阻率大於胸以及_^間= 層’置於該侧壯狀上,且具枝少—接贿,料 該侧停止層。 "丨电層汉 為了讓本發明之上述和其他目的 特舉一較佳實施例,並配合所附圖示 特徵、和優點能更明顯易懂 作詳細說明如下: ,下文
0503-A30922TWF 6 1258182 f實施方式j 高賴電晶體元件,具有層間介電層及餘 介電薄縣當賴刻停止層,配置在層 /大於1销的南電阻 製程中形成接觸窗,高電阻率之__可=二=電屢元件 ?體元件中之閘極在_下運作時所產生的: γU酿”極至祕_相電翁㈣魅,並改, 知步驟大抵相同,因此本發明之高電塵 交又1 及中等籠元賴軸容。 轉“也與目祕糕元件製程 =書巾「侧停讀」是指軸麵卩錢之上並與其上之材料不 从具有減上之材料慢的被侧速率,作驗刻製程停止之指示。 在本發明部分實補巾,侧停止層為氮切⑽y)之單層結構,直中X =為原子組成_,在此皆是指SiN。不f命名法,依形成_薄膜的沈 魏程及參數薄膜實質上的成分可能為為氫。本發明其他實施例中,钱刻 停止層為-複合材料層,包括氧切及氮鱗(删)。本發㈣—實施例中, 餘刻停止層為-非富狀氮氧切層,在此是指非f ♦秘具,其中X、丫、 z為原子組成比例,在此是指非富石夕Si〇N。此外,氯也可為薄膜之組成。 如本發明說明書中所述’非富石夕是指Si〇N是指石夕原子莫耳百分比小於約 柳。例如,在本發明-實施例中非富石夕別⑽薄膜之石夕、氧及氮原子組成 比例約12 : 21 : 42 ’相較之下,傳統之高電壓元件中,非富石夕沿⑽薄膜 之矽、氧及氮原子組成比例約158 : 72 : 144。 本發明中,「南電廢電晶體元件」是指一操作電壓大於5V之M〇S電 晶體,一般在10V至80V之間。本發明可應用至多種工業,包括但不限於 南電壓應用之積體電路製造、微電子製造,光電製造,例如··液晶顯示器 0503-A30922TWF 7 1258182 之驅動IC、電源官理7〇件,電源供應器、非揮發性記憶體、通訊電路以及 控:電路。制岐,本發明提供_電壓在,至之液晶顯示器最佳 化南電壓MQS電晶體。本發明可制淺溝槽絕緣(STIM局部石夕氧化 (LOCOS)絕緣技術來製造非對稱型高刪電晶體或對稱型高電壓 MOS電曰曰體’其中问電壓购8電晶體依電流路徑方向包括譲⑺電晶體、 LDMOS電晶體以及VDMOS電晶體。 在本發明實施例中,侧停止層為一單層氮化石夕層,在另一實施例中, 蝕刻停止層為-複合層,包括一氧化石夕層及一氮化石夕層。在另一實施例 中蝕^Ητ止層為-非备含石夕之氮氧化石夕層,在此非富含石夕之氮氧化石夕是 指矽莫耳百分比低於55%。 第1圖顯示本發明一較佳實施例之非對稱型舰⑶元件,包括一半導 體基底10,較佳為- P型半導體,包括一 p型井12及一 n型井Μ,形成 在高龍元件區域中的主動區HV。半導體基底1G包括但不限树 '絕緣 層上石夕層(SOI)、絕緣層切鍺或上述之組合。形成p輕適合的推雜物包 括卿)及BF2,摻雜量約在6·0χ,至9 〇χ奶⑽細2之間。形成㈣ 井適合之摻雜物包括石申(As)、銻(Sb)以及磷(p),其摻雜量約在6 〇χ ι〇12至 9版10 i〇ns/cm之間。在半導體基底1〇中佈植臨界電屢調整離子,形成 f界電壓調整區15。淺溝槽絕緣結構10a及議形成在半導體基底ι〇中來 定義高電壓元件主動區HV。-額外的淺溝槽絕緣結構18形成在部分主動 己中乂溝槽絶緣結構18較佳形成在]型井中並靠近沒極。 接著以習知技術形成-閘極結構’包括一閘極介電層2〇及一閑極層 22,其中有部分閘極結構形成在主動區上,部分形成在淺溝槽絕緣結構^ 之上。閘極介電層20例如是氧化石夕、氮氧化石夕、氮化石夕、高介電常數^材 料(例如k大於4)、過渡金躲化物及稀土金魏絲,可㈣知沈積技術 =成’例如.熱氧化製程及化學氣相沈積。閘極介電層2〇之厚度可視高電 壓轉技術之所需作調整。閘極層22之材料可為多晶@、非晶㈣、推雜 8
0503-A30922TWF C8 1258182 -之多晶⑪、多晶補、金屬或上述之組合,_層22之製造方法可為 氣相沈積、濺鍍或熱成長製程。 之後以輕摻雜製程在半導縣底1G巾形成—輕摻雜祕區⑽吻, 較佳為-形成在P型井中的㈣。輕摻_極區24之邊緣大抵順著閑極处 構之侧壁排列。輕摻雜製程可在能量約i至100Kev下進行,推雜量^ X妒至W 。接著赠叙嶋,附式,沿賴極的 側壁形成介電間隙壁26。介電間隙壁26的材料例如是氮化石夕、氧化石夕、氮 氧化石夕、氮化石夕及氧化石夕之間隔層或上述之組合。接著以介電間隙壁%為 遮罩’以-重摻雜製程分別在P型井及N型井中形成矿區,用來當作源極 區28及錄區3〇。源·及汲極區的邊界分別大抵順著介賴隙壁側壁的 外部排列。汲極區30形成在淺溝槽絕緣18及收之間的n型井中,並與 閘極結構間分隔出-段距離。重摻雜製程可在能量約丨至1眶^ > 摻雜量約⑽炉至L0x 10Wcm2。接著利用耐火金屬,例如:二’ 鶴、鈦、錄在閘極層22、源極區28及没極區3〇上選擇性形成—金屬石夕化 物,以降低電阻。 在半導體基底H)上沈積-侧停止層34,該侧停止層%材料選擇 自除富含石夕之氮氧化石夕之外任何介電材料。其中較特別的是,蝴亭止層 34為-電醇超㈣。化顿之高電_膜,可達職之絕緣效果以阻止 ^高電壓刊壯超過W)_魅麟關電親道。在本發明實施例 ,侧停止層34為氮化销,可_不_沈積技術進攸積,例如: «化學餘沈積、《加強辦氣相沈積。更具體絲,氮切層可藉 由S1H4、顺3、沉1此或N2之混合,例如在壓力約2〇〇mT〇iT至4_丁⑽ 之間’溫度約300至800t:下沈積約1〇〇埃至麵埃。 本發明另-實施例中,射彳停止層34包括—氧鮮層及—氮化石夕層。 =石夕層可_各種沈積技術,例如··熱氧化法、健化學氣相沈積、電 衆加強化學氣相沈積。更具體來說,氧化石夕層藉由_及N2〇兩種反應物
0503-A30922TWF 1258182 “…以《加強化學氣相沈積法沈積,另外也可糊低壓化學氣相沈 在脈度約7GG至95G°C之間沈積厚度1G至丨_埃。在本發明另—實施例中, 利用一複合侧停止層,例如··氧化魏鮮或氮切/氧切之雙層結 構’而其中氧切層及氮切層厚度之選制視實際介電需,細作適當調 整0 ° *在本us @關中,蝴停止層34為非富秒之氮氧切層,盆石夕 之莫耳百分比低於55%,可利用各種沈積技術形成,例如:低壓化學氣相
沈積、電漿加強化學氣相沈積。在一實際應用上,利用叫〇、細4、版或 nh3、n2之混合以賴加強化學氣相沈積在温度約至6崎之間,次藉 厚度約100至1000埃。 〜積 將-層間介電層36沈積在钱刻停止層34上,再以一化學機械研 程_>)進龍光。層間介電層包括但不限於:二氧化石夕、未接雜石夕酸鹽玻 璃(USG)、氟石夕玻璃(FSG)、氟化四乙基正石夕酸鹽_沉)、含石夕倍半氧烧 (HSQ)以及低介電常數材料(介電常數低於4)。層間介電層% 3000至8000埃之間。 序厌,习隹 形成層間介電層之後,接著在層間介電層中形成複數個接觸窗弘,並 ,滿導電材料4〇以電性連接至源涵域28及汲極區域3G。接觸窗可利用 2統之微雜顺術完成’例如:在層間介電層上形成_細層,將接觸 窗圖案轉換至光阻層形成-接觸窗圖案之遮罩,進行一非等向曰性侧製 ,,將未遮蔽部分之層間介電層移除。例如,#層間介電層為未推雜石夕玻 璃或鼠魏鱗,_製料糊侧氣體包括·· 咖約10至施cm、C〇㈣至5()咖及&。隱 接著再以另-侧製程將侧停止層未遮蔽的部分移除且不傷宝到層 間介電層36及金屬魏物層32。此侧製程為—非等向性蝴,_侧
二體’例如·’ 〇2、c2f6、QFs、舰及He,在勤約1〇至獅龜蝕 刻K)至卿i此即在層齡騎36中完成接_8,並露祕臟 0503-A30922TWF 10 1258182 -極區域28、30上的金屬矽化物層32。 ♦第2圖顯示本發明實施例之非對稱型pM〇s元件之截面圖,相較於 對雛NMOS元件,形成在高電壓區域之主動區域上的非龍^生⑽, 更包括-置於N型井14及P型井12之下的N型埋層⑽训,其參 雜祕區24為-形成在N型井14中的⑼、源極區28為一形成在^ 井中的P+區、汲極區30為一形成在P型井12中的p+區。 <第3圖顯示本發明實施例之隔離型應⑽元件之截面目,相較於非 無型NMOS το件,形成在高電壓區域之主動區取上的隔離型刪⑶元件 更匕括置於P型井12及N型井14之下的n型埋層(NBL)ll,盆中、为技 區28包括一矿區施及一 P+區29b。 极 ,第4圖顯示本發明實施例之對稱型龐〇s元件之截面目,相較於非對 私型NMOS το件,形成在高電壓區域之主動區取±的對翻舰〇s元件 .包括兩個破Ρ型井12分開之Ν型井14a及14b,以及兩淺溝槽絕緣結構收 及18b、,分別形成在分開的N型井⑷及_中。靠近源極的間極結構置 於部分淺溝槽絕緣結構l8a及N型井14a的鄰近部分上。靠近沒極的閑極 結構置於部分淺溝槽絕緣18b&N型井14b鄰近的部分上。 • /帛5 ®顯示本發明實施例之對稱型PMOS元件之截關,相較於非對 稱型PMOStg件,形成在高電壓區域之主動區取上的對翻pM〇s元件 f括兩淺溝槽絕緣結構1如及18b,分別形成在分開的p型井❿及中。 靠近源極的閘極結構,置於部分淺溝槽絕緣結構版及p型井❿的鄰近 部分上。靠近汲極的閘極結構,置於部分淺溝槽絕緣娜及p型井既鄰 近的部分上。 第6圖顯示本發明實施例之非對稱型DDDM〇s電晶體之截面圖,相較 於非對稱型LDM0S電晶體,非對稱型DDDM〇s電晶體包括兩場氧化區 17a及17b t成在半導體基底中,用來定義高電壓元件區之主動區服。 昜氧化區17a及17b可以習知LOCOS絕緣技術來形成σ擴散延伸區31鄰
0503-A30922TWF 11 1258182 ’ $於靠近沒極區的間極結構,並環繞汲極區3〇以建構出雙擴散汲極區。擴 散延伸區31具有相對較大的面積及較輕微之捧雜量,而沒極區具有相對較 小的區域及相對較重的摻雜量。作為之基底,擴散延伸區域Μ為摻 雜里約6·0χ 1〇至9·〇χ 1〇i2i〇ns/cm2的ν型區域,而汲極區3〇及源極區 28為摻雜i約5·〇χ 1〇13至1〇i6i〇ns/cm2的區域。作為刚電晶 體之基底,擴散延伸區31為一掺雜量約6 〇χ 1〇!2至9 〇χ的⑽/^的p 型區域’而没極30及源極區28為摻雜量約5·0χ 1013至l.〇x 10i6i〇ns/cm2 的P+區域。 籲帛7圖顯示本發明實施例之對稱型DDDMOS t晶體之截面圖,相較於 非對稱型DDDMOS電晶體,對翻DDDM〇S電晶體包括兩_之擴散延 伸I 31a及31b,η於兩場氧化區i7a及17b之間。擴散延伸區31a鄰近於 靠近源極端的閘極結構,並環繞源極區28形成一雙擴散源極區。另一對稱 •的擴散延伸區31b,鄰近於靠近汲極區之閘極結構並環繞汲極區3〇,形成 一雙擴散汲極區。 雖然本發明已以較佳實施例揭露如上,然其並非用以限定本發明,任 何熟習此技藝者,在不脫離本發明之精神和範圍内,當可作些許之更動與 φ 潤飾,因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。 【圖式簡單說明】 第1圖為本發明實施例中非對稱型_〇3元件之截面圖。 第2圖為本發明實施例中非對稱型PMOS元件之截面圖。 第3圖為本發明實施例中隔離型NMOS元件之截面圖。 第4圖為本發明實施例中隔離型PM〇s元件之截面圖。 第5圖為本發明實施例中對稱型PM〇S元件之截面圖。 第6圖為本發明實施例中非對稱型DDDMQS電晶體之截面圖。 第7圖為本發明實施例中對稱型DDDMOS電晶體之截面爵。
0503-A30922TWF 12 (β 1258182 【主要元件符號說明】 半導體基底〜10 ; N 型井〜14、14a、14b、14c ; 淺溝槽絕緣結構〜16a、16b ; 淺溝槽絕緣結構〜18、18a、18b ; 閘極〜22 ; 介電間隙壁〜26 ; 矿區〜29a ; >及極區^30, 金屬碎化物層〜32 ; 層間介電層〜36 ; 金屬材料〜40。 P型井〜12 ; 臨界電壓調整區〜15 ; 場氧化區〜17a、17b ; 閘極介電層〜20 ; 輕掺雜没極區〜24 ; 源極區〜28, P+區〜29b ; 擴散延伸區〜31、31a、31b ; #刻停止層〜34 ; 接觸窗〜38 ;
0503-A30922TWF 13

Claims (1)

  1. 〇9mt
    郭摩3修正本 修正日期·· 95.5.10 十、申請專利範圍: 1·一種半導體元件,包括: 一閘極結構’置於—半導體基底之—高電壓元件區域上; 極結:::酬’形成在該高電壓元件區域申’且橫向地鄰近™ 一_停止層,置於該閘極結構及該擴散區域之上,其中該_停止 層的電阻率大於10ohm-cm ;以及 ▲ -層間介電層,置於該細停止層之上,且具有至少—接觸窗, 5亥層間介電層及該蝕刻停止層。 2_如申請專利範圍第丨項所述之半導體元件,其中該侧停止層選擇自 除矽莫耳百分比超過55%之氮氧化矽外的所有介電材料。 3·如申請專利細第丨項所述之轉體树,其中該侧停止層為一氮 化梦層。 尸4.如申請專利範圍第!項所述之半導體元件,其中紐刻停止層包括一 氧化矽層及一氮化矽層。 5·如申請專利範圍第i項所述之半導體元件,其中舰刻停止層為一石夕 莫耳百分比低於55%之氮氧化矽層。 6.如申請專利範圍第i項所述之半導體元件,其中更包括_金屬石夕化物 層’置於該擴散區域之上,其中接觸窗穿過該層間介電層及該爛停止層, 以露出該金屬矽化物層。 曰 、7.如申請專利細f !項所述之半導體元件,其中更包括兩絕緣區,形 成在該半導體基底中,來定義該高電壓元件區域。 8. 如申請專織E第1項所述之半導體元件,其巾該閘極結構包括.一 閘極介電層’置於該半導體基底之上;以及1極,置於·極介電層之 上。 9. 如申請專利範圍第8項所述之半導體元件,其中該閘極結構包括:一 14 0503-A30922TWF1 1258182 m 〜 介電間隙壁,形成在該閘極介電層及該閘極的侧壁上;以及其中該擴散區 域大抵對位於該介電間隙壁的侧壁外圍排列。 10·如申請專利範圍帛1項所述之半導體元件,其中該接觸窗填滿一導 電材料以電性連接至該擴散區域。 、 11.如申請專利範圍第!項所述之半導體元件,其中該半導體元件為一 操作電壓超過5V之高電壓電晶體。 …
    12·—種半導體元件之製造方法,包括下列步驟: &供一半導體基底,具有一高電壓元件區域; 形成一閘極結構於該高電壓元件區域上; 其中該擴散區域橫向地 在该南電壓元件區域中形成至少一擴散區域 鄰近於該閘極結構的側壁; 層,其中該钱刻停止層 在該閘極結構及該擴散區域上形成一钱刻停止 之電阻率大於10ohm-cm ; 在該钱刻停止層上形成一層間介電層;以及 在該層間介電層中形成至,接職,穿過該_介電層及該餘刻停 其中該蝕刻 電材料。 13. 如申請專利範圍第12項所述之半導體元件之製造方法, 停止層選擇自除石夕莫耳百分比超過%%之氮氧化石夕外的所有介 14. 如申請翻綱第12項所述之半導體元件之製造 停止層為-氮切層。 ,、中该蝕刻 ,其中該蝕刻 ’其中該餘刻 ^ 15.如申請專利範圍第12項所述之半導體元件之製造方法 停止層包括一氧化矽層及一氮化矽層。 16·如申請專利範圍第12項所述之半導體元件之製造方法 停止層為一矽莫耳百分比低於55%之氮氧化矽層。 0503-A30922TWF1 15 1258182 - 18.如申請專利範圍第17項所述之半導體元件之製造方法,其中該接觸 窗穿過該層間介電層及該钱刻停止層,以露出該擴散區域。 , 19.如申請專利範圍第12項所述之半導體元件之製造方法,其中更包 括:在該半導體基底上形成兩絕緣區域,來定義該高電壓元件區域。 20.如申請專利範圍第12項所述之半導體元件之製造方法,其中更包 括:將該接觸窗填滿一導電材料,以電性連接至該擴散區域。
    0503-A30922TWF1 16
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