DE1547711C3 - Verfahren zur Herstellung von hchtentwickelbarem Silberhalogenid - Google Patents

Verfahren zur Herstellung von hchtentwickelbarem Silberhalogenid

Info

Publication number: DE1547711C3
Authority: DE; Germany
Prior art keywords: silver halide; silver; preparation; photographic; halogen
Prior art date: 1965-07-13
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

DE1547711A

Other languages

German (de)

English (en)

Other versions

DE1547711B2 (de

DE1547711A1 (de

Inventor

Robert Elwin Rochester N.Y. Bacon (V.St.A.)

Jean-France Leon Paul Paris Barbier

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Eastman Kodak Co

Original Assignee

Eastman Kodak Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1965-07-13

Filing date

1966-07-12

Publication date

1973-09-20

1966-07-12 Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co

1970-02-19 Publication of DE1547711A1 publication Critical patent/DE1547711A1/de

1973-03-01 Publication of DE1547711B2 publication Critical patent/DE1547711B2/de

1973-09-20 Application granted granted Critical

1973-09-20 Publication of DE1547711C3 publication Critical patent/DE1547711C3/de

Status Expired legal-status Critical Current

Links

-1 silver halide Chemical class 0.000 title claims description 75
229910052709 silver Inorganic materials 0.000 title claims description 52
239000004332 silver Substances 0.000 title claims description 52
238000000034 method Methods 0.000 title claims description 13
238000002360 preparation method Methods 0.000 title claims description 9
239000000839 emulsion Substances 0.000 claims description 28
229910052736 halogen Inorganic materials 0.000 claims description 26
239000000463 material Substances 0.000 claims description 25
150000002367 halogens Chemical class 0.000 claims description 22
230000002378 acidificating effect Effects 0.000 claims description 6
SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical group [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 claims description 3
229910052785 arsenic Inorganic materials 0.000 claims description 3
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 3
229910052797 bismuth Inorganic materials 0.000 claims description 3
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 3
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 3
229910052737 gold Inorganic materials 0.000 claims description 3
239000010931 gold Substances 0.000 claims description 3
238000012986 modification Methods 0.000 claims description 3
230000004048 modification Effects 0.000 claims description 3
ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 claims description 3
229910052787 antimony Inorganic materials 0.000 claims description 2
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 2
230000015572 biosynthetic process Effects 0.000 claims description 2
150000002500 ions Chemical class 0.000 claims description 2
239000000370 acceptor Substances 0.000 description 23
239000013078 crystal Substances 0.000 description 11
238000004519 manufacturing process Methods 0.000 description 10
239000000243 solution Substances 0.000 description 10
229910021645 metal ion Inorganic materials 0.000 description 8
108010010803 Gelatin Proteins 0.000 description 5
150000005840 aryl radicals Chemical class 0.000 description 5
229920000159 gelatin Polymers 0.000 description 5
239000008273 gelatin Substances 0.000 description 5
235000019322 gelatine Nutrition 0.000 description 5
235000011852 gelatine desserts Nutrition 0.000 description 5
150000002429 hydrazines Chemical class 0.000 description 5
125000004435 hydrogen atom Chemical group [H]* 0.000 description 5
150000003254 radicals Chemical class 0.000 description 5
230000035945 sensitivity Effects 0.000 description 5
UDATXMIGEVPXTR-UHFFFAOYSA-N 1,2,4-triazolidine-3,5-dione Chemical group O=C1NNC(=O)N1 UDATXMIGEVPXTR-UHFFFAOYSA-N 0.000 description 4
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
125000004433 nitrogen atom Chemical group N* 0.000 description 4
SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 4
125000001424 substituent group Chemical group 0.000 description 4
UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 4
WYENVTYBQKCILL-UHFFFAOYSA-N 1,2,4-triazolidine-3,5-dithione Chemical compound S=C1NNC(=S)N1 WYENVTYBQKCILL-UHFFFAOYSA-N 0.000 description 3
229910021607 Silver chloride Inorganic materials 0.000 description 3
238000007792 addition Methods 0.000 description 3
MDFFNEOEWAXZRQ-UHFFFAOYSA-N aminyl Chemical compound [NH2] MDFFNEOEWAXZRQ-UHFFFAOYSA-N 0.000 description 3
239000007864 aqueous solution Substances 0.000 description 3
125000004429 atom Chemical group 0.000 description 3
238000012822 chemical development Methods 0.000 description 3
150000004820 halides Chemical class 0.000 description 3
229910052751 metal Inorganic materials 0.000 description 3
239000002184 metal Substances 0.000 description 3
NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 3
238000001556 precipitation Methods 0.000 description 3
229910052703 rhodium Inorganic materials 0.000 description 3
239000010948 rhodium Substances 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 3
GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 3
OXFSTTJBVAAALW-UHFFFAOYSA-N 1,3-dihydroimidazole-2-thione Chemical group SC1=NC=CN1 OXFSTTJBVAAALW-UHFFFAOYSA-N 0.000 description 2
WXTMDXOMEHJXQO-UHFFFAOYSA-N 2,5-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC(O)=CC=C1O WXTMDXOMEHJXQO-UHFFFAOYSA-N 0.000 description 2
ZPDYXWCBXQWHAI-UHFFFAOYSA-N 5-sulfanylidene-1,2,4-triazolidin-3-one Chemical group O=C1NNC(=S)N1 ZPDYXWCBXQWHAI-UHFFFAOYSA-N 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical group O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
PDQAZBWRQCGBEV-UHFFFAOYSA-N Ethylenethiourea Chemical group S=C1NCCN1 PDQAZBWRQCGBEV-UHFFFAOYSA-N 0.000 description 2
DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
PCLIMKBDDGJMGD-UHFFFAOYSA-N N-bromosuccinimide Chemical compound BrN1C(=O)CCC1=O PCLIMKBDDGJMGD-UHFFFAOYSA-N 0.000 description 2
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical group [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 2
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 2
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
150000001768 cations Chemical class 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
125000005843 halogen group Chemical group 0.000 description 2
125000000623 heterocyclic group Chemical group 0.000 description 2
RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 description 2
229910017604 nitric acid Inorganic materials 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
239000001301 oxygen Chemical group 0.000 description 2
229940067157 phenylhydrazine Drugs 0.000 description 2
NDGRWYRVNANFNB-UHFFFAOYSA-N pyrazolidin-3-one Chemical compound O=C1CCNN1 NDGRWYRVNANFNB-UHFFFAOYSA-N 0.000 description 2
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 2
229910052711 selenium Chemical group 0.000 description 2
229910001961 silver nitrate Inorganic materials 0.000 description 2
FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Inorganic materials [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 description 2
GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
ZEMGGZBWXRYJHK-UHFFFAOYSA-N thiouracil Chemical group O=C1C=CNC(=S)N1 ZEMGGZBWXRYJHK-UHFFFAOYSA-N 0.000 description 2
TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 1
LZKWWERBNXLGLI-UHFFFAOYSA-N (2,5-dichlorophenyl)hydrazine Chemical compound NNC1=CC(Cl)=CC=C1Cl LZKWWERBNXLGLI-UHFFFAOYSA-N 0.000 description 1
XAMBIJWZVIZZOG-UHFFFAOYSA-N (4-methylphenyl)hydrazine Chemical compound CC1=CC=C(NN)C=C1 XAMBIJWZVIZZOG-UHFFFAOYSA-N 0.000 description 1
FPZXQVCYHDMIIA-UHFFFAOYSA-N 1,1-diphenylthiourea Chemical compound C=1C=CC=CC=1N(C(=S)N)C1=CC=CC=C1 FPZXQVCYHDMIIA-UHFFFAOYSA-N 0.000 description 1
FUIQANIDAMJELP-UHFFFAOYSA-N 1,2,3,4-tetrahydro-1,3,5-triazine Chemical compound C1NCN=CN1 FUIQANIDAMJELP-UHFFFAOYSA-N 0.000 description 1
150000005206 1,2-dihydroxybenzenes Chemical class 0.000 description 1
ZWLWGULMKSZGRW-UHFFFAOYSA-N 1,4-dibutyl-1,2,4-triazolidine-3,5-dione Chemical compound C(CCC)N1NC(=O)N(C1=O)CCCC ZWLWGULMKSZGRW-UHFFFAOYSA-N 0.000 description 1
LYRRSGFYGKLVFF-UHFFFAOYSA-N 1,4-dibutyl-1,2,4-triazolidine-3,5-dithione Chemical compound C(CCC)N1NC(=S)N(C1=S)CCCC LYRRSGFYGKLVFF-UHFFFAOYSA-N 0.000 description 1
150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 1
FKMZWZGFVKCYKR-UHFFFAOYSA-N 1,4-diphenyl-1,2,4-triazolidine-3,5-dione Chemical compound O=C1N(C=2C=CC=CC=2)C(=O)NN1C1=CC=CC=C1 FKMZWZGFVKCYKR-UHFFFAOYSA-N 0.000 description 1
JHDMPABDCKUGMR-UHFFFAOYSA-N 1-octyl-1,2,4-triazolidine-3,5-dione Chemical compound C(CCCCCCC)N1NC(=O)NC1=O JHDMPABDCKUGMR-UHFFFAOYSA-N 0.000 description 1
WFYLHMAYBQLBEM-UHFFFAOYSA-N 1-phenyl-1,2,4-triazolidine-3,5-dione Chemical compound O=C1NC(=O)NN1C1=CC=CC=C1 WFYLHMAYBQLBEM-UHFFFAOYSA-N 0.000 description 1
JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 1
RVBUGGBMJDPOST-UHFFFAOYSA-N 2-thiobarbituric acid Chemical group O=C1CC(=O)NC(=S)N1 RVBUGGBMJDPOST-UHFFFAOYSA-N 0.000 description 1
BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 description 1
JIGUICYYOYEXFS-UHFFFAOYSA-N 3-tert-butylbenzene-1,2-diol Chemical compound CC(C)(C)C1=CC=CC(O)=C1O JIGUICYYOYEXFS-UHFFFAOYSA-N 0.000 description 1
SJSJAWHHGDPBOC-UHFFFAOYSA-N 4,4-dimethyl-1-phenylpyrazolidin-3-one Chemical compound N1C(=O)C(C)(C)CN1C1=CC=CC=C1 SJSJAWHHGDPBOC-UHFFFAOYSA-N 0.000 description 1
BWFMTHGMFVQPSE-UHFFFAOYSA-N 4-amino-1,2,4-triazolidine-3,5-dione Chemical compound NN1C(=O)NNC1=O BWFMTHGMFVQPSE-UHFFFAOYSA-N 0.000 description 1
PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical class NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 1
DONGNZDECHITKF-UHFFFAOYSA-N 4-butyl-1,2,4-triazolidine-3,5-dithione Chemical compound CCCCN1C(=S)NNC1=S DONGNZDECHITKF-UHFFFAOYSA-N 0.000 description 1
FTLPCUOUNXWZMN-UHFFFAOYSA-N 4-ethyl-1,2,4-triazolidine-3,5-dione Chemical compound CCN1C(=O)NNC1=O FTLPCUOUNXWZMN-UHFFFAOYSA-N 0.000 description 1
ZZEYCGJAYIHIAZ-UHFFFAOYSA-N 4-methyl-1-phenylpyrazolidin-3-one Chemical compound N1C(=O)C(C)CN1C1=CC=CC=C1 ZZEYCGJAYIHIAZ-UHFFFAOYSA-N 0.000 description 1
ZVNPWFOVUDMGRP-UHFFFAOYSA-N 4-methylaminophenol sulfate Chemical compound OS(O)(=O)=O.CNC1=CC=C(O)C=C1.CNC1=CC=C(O)C=C1 ZVNPWFOVUDMGRP-UHFFFAOYSA-N 0.000 description 1
ICGLPKIVTVWCFT-UHFFFAOYSA-N 4-methylbenzenesulfonohydrazide Chemical compound CC1=CC=C(S(=O)(=O)NN)C=C1 ICGLPKIVTVWCFT-UHFFFAOYSA-N 0.000 description 1
USUCKGULNGXXRO-UHFFFAOYSA-N 4-naphthalen-1-yl-1,2,4-triazolidine-3,5-dione Chemical compound O=C1NNC(=O)N1C1=CC=CC2=CC=CC=C12 USUCKGULNGXXRO-UHFFFAOYSA-N 0.000 description 1
GOSUFRDROXZXLN-UHFFFAOYSA-N 4-phenyl-1,2,4-triazolidine-3,5-dione Chemical compound O=C1NNC(=O)N1C1=CC=CC=C1 GOSUFRDROXZXLN-UHFFFAOYSA-N 0.000 description 1
WSCQSKLSWOQFNU-UHFFFAOYSA-N 5-butyl-1,3,5-triazinane-2-thione Chemical compound CCCCN1CNC(=S)NC1 WSCQSKLSWOQFNU-UHFFFAOYSA-N 0.000 description 1
CWQRZHJVEYUBDY-UHFFFAOYSA-N 6-sulfanylidene-1,3-diazinane-2,4-dione Chemical compound O=C1CC(=S)NC(=O)N1 CWQRZHJVEYUBDY-UHFFFAOYSA-N 0.000 description 1
229940090898 Desensitizer Drugs 0.000 description 1
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
239000004471 Glycine Substances 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
ODBPVOUIVTXBLI-UHFFFAOYSA-N OC1=NC(=NN1)[SeH] Chemical compound OC1=NC(=NN1)[SeH] ODBPVOUIVTXBLI-UHFFFAOYSA-N 0.000 description 1
229910021612 Silver iodide Inorganic materials 0.000 description 1
239000005708 Sodium hypochlorite Substances 0.000 description 1
BGNXCDMCOKJUMV-UHFFFAOYSA-N Tert-Butylhydroquinone Chemical compound CC(C)(C)C1=CC(O)=CC=C1O BGNXCDMCOKJUMV-UHFFFAOYSA-N 0.000 description 1
MNOILHPDHOHILI-UHFFFAOYSA-N Tetramethylthiourea Chemical compound CN(C)C(=S)N(C)C MNOILHPDHOHILI-UHFFFAOYSA-N 0.000 description 1
229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
MUDHKEQEBJQRRG-GHXNOFRVSA-N [(z)-[4-(dimethylamino)phenyl]methylideneamino]thiourea Chemical compound CN(C)C1=CC=C(\C=N/NC(N)=S)C=C1 MUDHKEQEBJQRRG-GHXNOFRVSA-N 0.000 description 1
IEIREBQISNYNTN-UHFFFAOYSA-K [Ag](I)(Br)Cl Chemical compound [Ag](I)(Br)Cl IEIREBQISNYNTN-UHFFFAOYSA-K 0.000 description 1
CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 description 1
OMQATPITDSAIFV-KVTDHHQDSA-N [[(2R,3R,4R,5R)-2,3,4,5,6-pentahydroxyhexylidene]amino]thiourea Chemical compound C([C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO)=NNC(N)=S OMQATPITDSAIFV-KVTDHHQDSA-N 0.000 description 1
OMQATPITDSAIFV-KCDKBNATSA-N [[(2S,3R,4S,5R)-2,3,4,5,6-pentahydroxyhexylidene]amino]thiourea Chemical compound C([C@H](O)[C@@H](O)[C@@H](O)[C@H](O)CO)=NNC(N)=S OMQATPITDSAIFV-KCDKBNATSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
229910001508 alkali metal halide Inorganic materials 0.000 description 1
150000008045 alkali metal halides Chemical class 0.000 description 1
150000008044 alkali metal hydroxides Chemical class 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
150000001462 antimony Chemical class 0.000 description 1
230000005540 biological transmission Effects 0.000 description 1
150000001621 bismuth Chemical class 0.000 description 1
FBXVOTBTGXARNA-UHFFFAOYSA-N bismuth;trinitrate;pentahydrate Chemical compound O.O.O.O.O.[Bi+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O FBXVOTBTGXARNA-UHFFFAOYSA-N 0.000 description 1
229910021538 borax Inorganic materials 0.000 description 1
OIPQUBBCOVJSNS-UHFFFAOYSA-L bromo(iodo)silver Chemical compound Br[Ag]I OIPQUBBCOVJSNS-UHFFFAOYSA-L 0.000 description 1
PKCHODKZKBAVIJ-UHFFFAOYSA-L chloro(iodo)silver Chemical compound Cl[Ag]I PKCHODKZKBAVIJ-UHFFFAOYSA-L 0.000 description 1
AJPXTSMULZANCB-UHFFFAOYSA-N chlorohydroquinone Chemical compound OC1=CC=C(O)C(Cl)=C1 AJPXTSMULZANCB-UHFFFAOYSA-N 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
239000000084 colloidal system Substances 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
229960005219 gentisic acid Drugs 0.000 description 1
VKYBUEJAQKBUFU-UHFFFAOYSA-N hexylhydrazine Chemical compound CCCCCCNN VKYBUEJAQKBUFU-UHFFFAOYSA-N 0.000 description 1
BRWIZMBXBAOCCF-UHFFFAOYSA-N hydrazinecarbothioamide Chemical compound NNC(N)=S BRWIZMBXBAOCCF-UHFFFAOYSA-N 0.000 description 1
JGJLWPGRMCADHB-UHFFFAOYSA-N hypobromite Inorganic materials Br[O-] JGJLWPGRMCADHB-UHFFFAOYSA-N 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
229910052741 iridium Inorganic materials 0.000 description 1
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
PMRYVIKBURPHAH-UHFFFAOYSA-N methimazole Chemical compound CN1C=CNC1=S PMRYVIKBURPHAH-UHFFFAOYSA-N 0.000 description 1
125000001624 naphthyl group Chemical group 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
YCIMNLLNPGFGHC-UHFFFAOYSA-N o-dihydroxy-benzene Natural products OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
150000004686 pentahydrates Chemical class 0.000 description 1
CMCWWLVWPDLCRM-UHFFFAOYSA-N phenidone Chemical compound N1C(=O)CCN1C1=CC=CC=C1 CMCWWLVWPDLCRM-UHFFFAOYSA-N 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
HKOOXMFOFWEVGF-UHFFFAOYSA-N phenylhydrazine Chemical compound NNC1=CC=CC=C1 HKOOXMFOFWEVGF-UHFFFAOYSA-N 0.000 description 1
125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
230000005855 radiation Effects 0.000 description 1
150000003283 rhodium Chemical class 0.000 description 1
229940045105 silver iodide Drugs 0.000 description 1
SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
235000009518 sodium iodide Nutrition 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
235000010265 sodium sulphite Nutrition 0.000 description 1
239000004328 sodium tetraborate Substances 0.000 description 1
235000010339 sodium tetraborate Nutrition 0.000 description 1
239000001119 stannous chloride Substances 0.000 description 1
235000011150 stannous chloride Nutrition 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
125000003107 substituted aryl group Chemical group 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
NBOMNTLFRHMDEZ-UHFFFAOYSA-N thiosalicylic acid Chemical compound OC(=O)C1=CC=CC=C1S NBOMNTLFRHMDEZ-UHFFFAOYSA-N 0.000 description 1
229940103494 thiosalicylic acid Drugs 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/49—Print-out and photodevelopable emulsions
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/08—Sensitivity-increasing substances
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/494—Silver salt compositions other than silver halide emulsions; Photothermographic systems ; Thermographic systems using noble metal compounds
- G03C1/496—Binder-free compositions, e.g. evaporated
- G03C1/4965—Binder-free compositions, e.g. evaporated evaporated
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/06—Silver salts

Landscapes

Physics & Mathematics (AREA)
Chemical & Material Sciences (AREA)
General Physics & Mathematics (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Spectroscopy & Molecular Physics (AREA)
Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
Silver Salt Photography Or Processing Solution Therefor (AREA)
Photosensitive Polymer And Photoresist Processing (AREA)

DE1547711A 1965-07-13 1966-07-12 Verfahren zur Herstellung von hchtentwickelbarem Silberhalogenid Expired DE1547711C3 (de)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
FR24443A FR1456581A (fr)	1965-07-13	1965-07-13	Nouveau produit sensible aux rayonnements
US48192765A	1965-08-23	1965-08-23

Publications (3)

Publication Number	Publication Date
DE1547711A1 DE1547711A1 (de)	1970-02-19
DE1547711B2 DE1547711B2 (de)	1973-03-01
DE1547711C3 true DE1547711C3 (de)	1973-09-20

Family

ID=26164743

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DE1547711A Expired DE1547711C3 (de)	1965-07-13	1966-07-12	Verfahren zur Herstellung von hchtentwickelbarem Silberhalogenid

Country Status (6)

Country	Link
US (1)	US3447927A (xx)
JP (1)	JPS5025809B1 (xx)
BE (1)	BE683561A (xx)
DE (1)	DE1547711C3 (xx)
FR (1)	FR1456581A (xx)
GB (1)	GB1158014A (xx)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3725073A (en) *	1967-05-25	1973-04-03	Xerox Corp	Light developable,direct writing,silver halide emulsions containing gold,iodine,lead and copper
JPS4933781B1 (xx) *	1968-05-10	1974-09-10
BE756627A (fr) *	1969-09-26	1971-03-01	Du Pont	Emulsions positives directes contenant des amino-boranes et dessels de bismuth
BE756067A (fr) *	1969-09-29	1971-02-15	Eastman Kodak Co	Produit photographique a couche anti-halo amelioree
US3705148A (en) *	1970-04-03	1972-12-05	Eastman Kodak Co	Photographic films on heat resistant cellulose triacetate
US3690888A (en) *	1970-06-04	1972-09-12	Eastman Kodak Co	Process of making silver halide emulsions having polyvalent metal ions occluded therein
US3748137A (en) *	1970-12-10	1973-07-24	Eastman Kodak Co	Photosensitive and thermosensitive elements and process for development
US3854949A (en) *	1971-03-10	1974-12-17	Eastman Kodak Co	Silver halide photographic compositions and processes for obtaining positive images
JPS5517374B2 (xx) *	1971-11-09	1980-05-10
JPS51127720A (en) *	1975-04-30	1976-11-08	Konishiroku Photo Ind Co Ltd	Method for sensitizing silver halide photographic light sensitive mate rials
US4076532A (en) *	1976-01-16	1978-02-28	Eastman Kodak Company	Thermosensitive image-forming element and method of processing thereof
GB1560005A (en) *	1976-08-11	1980-01-30	Fuji Photo Film Co Ltd	Silver halide photographic emulsions
US4221863A (en) *	1978-03-31	1980-09-09	E. I. Du Pont De Nemours And Company	Formation of silver halide grains in the presence of thioureas
US4650746A (en) *	1978-09-22	1987-03-17	Eastman Kodak Company	High contrast photographic emulsions and elements and processes for their development
DE3482606D1 (de)	1983-11-25	1990-08-02	Fuji Photo Film Co Ltd	Waermeentwickelbares lichtempfindliches material.
US4710631A (en) *	1984-08-28	1987-12-01	Fuji Photo Film Co., Ltd.	Temperature compensation for a semiconductor light source used for exposure of light sensitive material
JPS61209433A (ja) *	1985-02-18	1986-09-17	Fuji Photo Film Co Ltd	熱現像感光材料
US4775613A (en)	1985-03-30	1988-10-04	Fuji Photo Film Co., Ltd.	Heat-developable light-sensitive material
US4661438A (en)	1985-04-04	1987-04-28	Eastman Kodak Company	Quaternized tellurium salt fog inhibiting agents for silver halide photography
DE3681347D1 (de)	1985-05-31	1991-10-17	Konishiroku Photo Ind	Verfahren zur herstellung eines direkt positiven farbbildes.
JPH0677131B2 (ja) *	1986-05-02	1994-09-28	富士写真フイルム株式会社	ハロゲン化銀写真感光材料
EP0447688B1 (en) *	1990-03-19	1993-06-02	Agfa-Gevaert N.V.	Photographic roomlight materials containing halogen acceptors
JP3041736B2 (ja) *	1991-11-01	2000-05-15	コニカ株式会社	ハロゲン化銀写真感光材料
JPH05165139A (ja) *	1991-12-17	1993-06-29	Konica Corp	色素画像形成方法
EP0650087B1 (en) *	1993-08-31	2000-01-26	Konica Corporation	Silver halide photographic light sensitive material
US5374497A (en) *	1993-08-31	1994-12-20	Eastman Kodak Company	Donor element for use in a dry color proofing process
JPH0887097A (ja) *	1994-09-16	1996-04-02	Konica Corp	画像形成方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2717833A (en) *	1952-05-12	1955-09-13	Sperry Rand Corp	Direct positive emulsions
BE620828A (xx) *	1961-08-01

1965
- 1965-07-13 FR FR24443A patent/FR1456581A/fr not_active Expired
1966
- 1966-07-01 BE BE683561D patent/BE683561A/xx unknown
- 1966-07-12 DE DE1547711A patent/DE1547711C3/de not_active Expired
- 1966-07-13 GB GB31467/66A patent/GB1158014A/en not_active Expired
1967
- 1967-03-24 US US625590A patent/US3447927A/en not_active Expired - Lifetime
1969
- 1969-07-04 JP JP44052542A patent/JPS5025809B1/ja active Pending

Also Published As

Publication number	Publication date
FR1456581A (fr)	1966-10-28
DE1547711B2 (de)	1973-03-01
JPS5025809B1 (xx)	1975-08-27
GB1158014A (en)	1969-07-09
DE1547711A1 (de)	1970-02-19
US3447927A (en)	1969-06-03
BE683561A (xx)	1966-12-16

Legal Events

Date	Code	Title
1973-09-20	C3	Grant after two publication steps (3rd publication)
1977-12-31	E77	Valid patent as to the heymanns-index 1977
1978-05-11	EHJ	Ceased/non-payment of the annual fee

Publication	Publication Date	Title
DE1547711C3 (de)	1973-09-20	Verfahren zur Herstellung von hchtentwickelbarem Silberhalogenid
DE3315589C2 (xx)	1992-07-09
DE1255484B (de)	1967-11-30	Lichtempfindliches photographisches Material mit mindestens einer lichtempfindlichen Silbersalzemulsionsschicht
DE2811025A1 (de)	1978-10-05	Silbersalze von 3-amino-1,2,4-mercaptotriazolderivaten
DE1281845B (de)	1968-10-31	Photographische Silberhalogenidemulsion
DE1547780B2 (de)	1980-09-11	Verschleierte direktpositive photographische Silberhalogenidemulsion
DE1170778B (de)	1964-05-21	Silberhalogenid-Auskopieremulsion mit einem Gehalt an einem Schwermetallsalz
DE1177002B (de)	1964-08-27	Verfahren zur Verhinderung der Schleierbildung und lichtempfindliche photographische Halogen-silberemulsion bzw. Photomaterial
DE2034064B2 (de)	1978-07-20	Farbfotografisches Aufzeichenmaterial
DE1929223A1 (de)	1969-12-11	Entwickler-Vorlaeufer-Verbindungen und ihre Verwendung in der Photographie
DE1772026A1 (de)	1970-10-22	Photographisches Aufzeichnungsmaterial
DE2100622C2 (de)	1983-12-15	Lichtempfindliche Silberhalogenidemulsion
DE2850612A1 (de)	1979-05-31	Photomaterial und photographischer entwickler
DE1547726C3 (de)	1974-03-28	Verfahren zur Herstellung sichtbarer photographischer Silberbilder
DE1019171B (de)	1957-11-07	Verfahren zur Herstellung von direktpositivem lichtempfindlichem Material
DE2325039C2 (de)	1984-06-20	Farbphotographische Silberhalogenidemulsion
DE2112728C3 (de)	1984-05-30	Farbphotographisches Aufzeichnungsmaterial
DE2212550A1 (de)	1972-11-02	Verwendung von Azotriazolen und Azotetrazolen als Antischleier- und Antispotmittel und selektive Desensibilisatoren in photographischen Halogensilberemulsionen und in photographischen Baedern,sowie diese Verbindungen enthaltendes photographisches Aufzeichnungsmaterial
DE3020262C2 (de)	1982-10-14	Behandlungslösung für das Silbersalz-Diffusionsübertragungsverfahren
DE2063669B2 (de)	1974-06-12	Photographisches Aufzeichnungsmaterial mit einer spektral sensibilisierten Silberhalogenidemulsionsschicht
DE1547970A1 (de)	1969-12-11	Loesung fuer die Stabilisierung eines entwickelten Bildes in einem photographischen Halogensilbermaterial
DE2222832A1 (de)	1972-11-16	Verfahren zur Herstellung von fotografischen Bildern
DE2607895A1 (de)	1976-09-16	Verfahren zum entwickeln eines lichtempfindlichen photographischen silberhalogenidmaterials
DE1772088C3 (de)	1976-01-08	Fixierlösung für lichtempfindliche photographische Silberhalogenidaufzeichnungsmaterialien
DE2049502A1 (de)	1971-04-15	Photographisches Entwicklungsverfahren und hierfür geeignete Entwicklerlosung