CN102934026A - 用于加成法制造的可led固化的液体树脂组合物 - Google Patents
用于加成法制造的可led固化的液体树脂组合物 Download PDFInfo
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- CN102934026A CN102934026A CN2010800579442A CN201080057944A CN102934026A CN 102934026 A CN102934026 A CN 102934026A CN 2010800579442 A CN2010800579442 A CN 2010800579442A CN 201080057944 A CN201080057944 A CN 201080057944A CN 102934026 A CN102934026 A CN 102934026A
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- Prior art keywords
- phenyl
- sulfonium
- resin composition
- photocurable resin
- group
- Prior art date
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- 239000011342 resin composition Substances 0.000 title claims abstract description 107
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 88
- 239000007788 liquid Substances 0.000 title claims abstract description 24
- 239000000654 additive Substances 0.000 title abstract 4
- 230000000996 additive effect Effects 0.000 title abstract 4
- 238000010538 cationic polymerization reaction Methods 0.000 claims abstract description 32
- 238000010526 radical polymerization reaction Methods 0.000 claims abstract description 31
- 230000000977 initiatory effect Effects 0.000 claims abstract description 23
- 239000007787 solid Substances 0.000 claims abstract description 12
- -1 aryl ketones Chemical class 0.000 claims description 240
- 238000000034 method Methods 0.000 claims description 119
- 230000008569 process Effects 0.000 claims description 96
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 72
- 239000000203 mixture Substances 0.000 claims description 52
- 239000003999 initiator Substances 0.000 claims description 49
- 150000001768 cations Chemical class 0.000 claims description 48
- 239000005864 Sulphur Substances 0.000 claims description 42
- 239000011347 resin Substances 0.000 claims description 42
- 229920005989 resin Polymers 0.000 claims description 42
- 230000005855 radiation Effects 0.000 claims description 35
- 238000006116 polymerization reaction Methods 0.000 claims description 33
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 29
- 125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 claims description 29
- 150000003254 radicals Chemical class 0.000 claims description 28
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 27
- 150000003839 salts Chemical class 0.000 claims description 27
- 150000001875 compounds Chemical class 0.000 claims description 26
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 24
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 21
- 239000003504 photosensitizing agent Substances 0.000 claims description 21
- 239000003795 chemical substances by application Substances 0.000 claims description 20
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 19
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 claims description 19
- 229910052760 oxygen Inorganic materials 0.000 claims description 18
- 239000001301 oxygen Substances 0.000 claims description 18
- 239000012965 benzophenone Substances 0.000 claims description 17
- 229920000642 polymer Polymers 0.000 claims description 16
- 150000002500 ions Chemical class 0.000 claims description 15
- 150000003568 thioethers Chemical class 0.000 claims description 15
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 14
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 13
- 229910052740 iodine Inorganic materials 0.000 claims description 13
- 239000011630 iodine Substances 0.000 claims description 13
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 12
- 239000002585 base Substances 0.000 claims description 12
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 11
- YCWSUKQGVSGXJO-NTUHNPAUSA-N nifuroxazide Chemical group C1=CC(O)=CC=C1C(=O)N\N=C\C1=CC=C([N+]([O-])=O)O1 YCWSUKQGVSGXJO-NTUHNPAUSA-N 0.000 claims description 11
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 10
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 claims description 10
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 9
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 9
- REUQOSNMSWLNPD-UHFFFAOYSA-N [2-(diethylamino)phenyl]-phenylmethanone Chemical compound CCN(CC)C1=CC=CC=C1C(=O)C1=CC=CC=C1 REUQOSNMSWLNPD-UHFFFAOYSA-N 0.000 claims description 9
- 125000002091 cationic group Chemical group 0.000 claims description 9
- 230000003287 optical effect Effects 0.000 claims description 9
- 125000005409 triarylsulfonium group Chemical group 0.000 claims description 9
- 229920002554 vinyl polymer Polymers 0.000 claims description 9
- NJWGQARXZDRHCD-UHFFFAOYSA-N 2-methylanthraquinone Chemical compound C1=CC=C2C(=O)C3=CC(C)=CC=C3C(=O)C2=C1 NJWGQARXZDRHCD-UHFFFAOYSA-N 0.000 claims description 8
- OKIHXNKYYGUVTE-UHFFFAOYSA-N 4-Fluorothiophenol Chemical compound FC1=CC=C(S)C=C1 OKIHXNKYYGUVTE-UHFFFAOYSA-N 0.000 claims description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 8
- 150000004056 anthraquinones Chemical class 0.000 claims description 8
- 239000000470 constituent Substances 0.000 claims description 8
- 238000007046 ethoxylation reaction Methods 0.000 claims description 8
- RMVRSNDYEFQCLF-UHFFFAOYSA-O phenylsulfanium Chemical compound [SH2+]C1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-O 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 7
- 125000001931 aliphatic group Chemical group 0.000 claims description 7
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 7
- 230000035515 penetration Effects 0.000 claims description 7
- 229920000570 polyether Polymers 0.000 claims description 7
- 229910052717 sulfur Inorganic materials 0.000 claims description 7
- 239000011593 sulfur Substances 0.000 claims description 7
- YIKSHDNOAYSSPX-UHFFFAOYSA-N 1-propan-2-ylthioxanthen-9-one Chemical compound S1C2=CC=CC=C2C(=O)C2=C1C=CC=C2C(C)C YIKSHDNOAYSSPX-UHFFFAOYSA-N 0.000 claims description 6
- 229910018286 SbF 6 Inorganic materials 0.000 claims description 6
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 claims description 6
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims description 6
- QDLAGTHXVHQKRE-UHFFFAOYSA-N lichenxanthone Natural products COC1=CC(O)=C2C(=O)C3=C(C)C=C(OC)C=C3OC2=C1 QDLAGTHXVHQKRE-UHFFFAOYSA-N 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 claims description 6
- 238000003860 storage Methods 0.000 claims description 6
- 239000012953 triphenylsulfonium Substances 0.000 claims description 6
- JNELGWHKGNBSMD-UHFFFAOYSA-N xanthone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3OC2=C1 JNELGWHKGNBSMD-UHFFFAOYSA-N 0.000 claims description 6
- 229910019142 PO4 Inorganic materials 0.000 claims description 5
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 claims description 5
- 239000000975 dye Substances 0.000 claims description 5
- 230000003647 oxidation Effects 0.000 claims description 5
- 238000007254 oxidation reaction Methods 0.000 claims description 5
- 239000003208 petroleum Substances 0.000 claims description 5
- 239000010452 phosphate Substances 0.000 claims description 5
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 5
- WWMFRKPUQJRNBY-UHFFFAOYSA-N (2,3-dimethoxyphenyl)-phenylmethanone Chemical compound COC1=CC=CC(C(=O)C=2C=CC=CC=2)=C1OC WWMFRKPUQJRNBY-UHFFFAOYSA-N 0.000 claims description 4
- VNQXSTWCDUXYEZ-UHFFFAOYSA-N 1,7,7-trimethylbicyclo[2.2.1]heptane-2,3-dione Chemical compound C1CC2(C)C(=O)C(=O)C1C2(C)C VNQXSTWCDUXYEZ-UHFFFAOYSA-N 0.000 claims description 4
- BOCJQSFSGAZAPQ-UHFFFAOYSA-N 1-chloroanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2Cl BOCJQSFSGAZAPQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 claims description 4
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 claims description 4
- QPXVRLXJHPTCPW-UHFFFAOYSA-N 2-hydroxy-2-methyl-1-(4-propan-2-ylphenyl)propan-1-one Chemical compound CC(C)C1=CC=C(C(=O)C(C)(C)O)C=C1 QPXVRLXJHPTCPW-UHFFFAOYSA-N 0.000 claims description 4
- XMLYCEVDHLAQEL-UHFFFAOYSA-N 2-hydroxy-2-methyl-1-phenylpropan-1-one Chemical compound CC(C)(O)C(=O)C1=CC=CC=C1 XMLYCEVDHLAQEL-UHFFFAOYSA-N 0.000 claims description 4
- UMWZLYTVXQBTTE-UHFFFAOYSA-N 2-pentylanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC(CCCCC)=CC=C3C(=O)C2=C1 UMWZLYTVXQBTTE-UHFFFAOYSA-N 0.000 claims description 4
- QGHDLJAZIIFENW-UHFFFAOYSA-N 4-[1,1,1,3,3,3-hexafluoro-2-(4-hydroxy-3-prop-2-enylphenyl)propan-2-yl]-2-prop-2-enylphenol Chemical group C1=C(CC=C)C(O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(O)C(CC=C)=C1 QGHDLJAZIIFENW-UHFFFAOYSA-N 0.000 claims description 4
- NIYOXHRKDAIDSK-UHFFFAOYSA-N C(=O)SC.C1=CC=CC=C1 Chemical compound C(=O)SC.C1=CC=CC=C1 NIYOXHRKDAIDSK-UHFFFAOYSA-N 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- DIZVCHSWMYKZHY-UHFFFAOYSA-N [I].C(CCCCCCCCCCC)C1=CC=CC=C1 Chemical compound [I].C(CCCCCCCCCCC)C1=CC=CC=C1 DIZVCHSWMYKZHY-UHFFFAOYSA-N 0.000 claims description 4
- 150000001450 anions Chemical class 0.000 claims description 4
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims description 4
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 claims description 4
- 229930006711 bornane-2,3-dione Natural products 0.000 claims description 4
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 4
- VYVRIXWNTVOIRD-LRHBOZQDSA-N ciguatoxin CTX1B Chemical compound C([C@@]12[C@@H](C)[C@@H]([C@@H]3[C@H]([C@H]([C@H](C)[C@H]4O[C@H]5C[C@@H](C)C[C@H]6O[C@@]7(C)[C@H](O)C[C@H]8O[C@H]9C=C[C@H]%10O[C@H]%11C[C@@H]%12[C@H]([C@@H]([C@H]%13O[C@H](C=CC[C@@H]%13O%12)\C=C\[C@H](O)CO)O)O[C@@H]%11C=C[C@@H]%10O[C@@H]9C\C=C/C[C@@H]8O[C@@H]7C[C@@H]6O[C@@H]5C[C@@H]4O3)O)O2)C)[C@H](O)CO1 VYVRIXWNTVOIRD-LRHBOZQDSA-N 0.000 claims description 4
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 150000002576 ketones Chemical class 0.000 claims description 4
- 229960004194 lidocaine Drugs 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
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- WLOQLWBIJZDHET-UHFFFAOYSA-N triphenylsulfonium Chemical compound C1=CC=CC=C1[S+](C=1C=CC=CC=1)C1=CC=CC=C1 WLOQLWBIJZDHET-UHFFFAOYSA-N 0.000 claims description 4
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- HLJYBXJFKDDIBI-UHFFFAOYSA-N O=[PH2]C(=O)C1=CC=CC=C1 Chemical compound O=[PH2]C(=O)C1=CC=CC=C1 HLJYBXJFKDDIBI-UHFFFAOYSA-N 0.000 claims description 3
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- UNUJZVUJPIOMGH-UHFFFAOYSA-N ethoxyphosphonoylbenzene Chemical compound CCOP(=O)C1=CC=CC=C1 UNUJZVUJPIOMGH-UHFFFAOYSA-N 0.000 claims description 3
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
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- ROMWNDGABOQKIW-UHFFFAOYSA-N phenyliodanuidylbenzene Chemical compound C=1C=CC=CC=1[I-]C1=CC=CC=C1 ROMWNDGABOQKIW-UHFFFAOYSA-N 0.000 claims description 3
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- VZXOZSQDJJNBRC-UHFFFAOYSA-N 4-chlorobenzenethiol Chemical compound SC1=CC=C(Cl)C=C1 VZXOZSQDJJNBRC-UHFFFAOYSA-N 0.000 claims description 2
- NYWSOZIZKAROHJ-UHFFFAOYSA-N 5-phenylthianthren-5-ium Chemical compound C12=CC=CC=C2SC2=CC=CC=C2[S+]1C1=CC=CC=C1 NYWSOZIZKAROHJ-UHFFFAOYSA-N 0.000 claims description 2
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- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 claims description 2
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- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 11
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- Chemical & Material Sciences (AREA)
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Abstract
Description
实施例编号 | CPI/RPI | CPC/RPC |
1 | 1.33 | 1.13 |
2 | 0.18 | 3.19 |
3 | 0.25 | 3.19 |
4 | 0.43 | 3.19 |
5 | 0.67 | 3.19 |
6 | 0.67 | 1.37 |
7 | 0.67 | 1.30 |
8 | 0.67 | 1.23 |
9 | 0.67 | 1.33 |
10 | 0.67 | 1.33 |
11 | 0.67 | 1.47 |
12 | 0.67 | 1.55 |
13 | 0.67 | 1.47 |
14 | 0.67 | 1.47 |
15 | 0.25 | 1.48 |
16 | 0.25 | 1.48 |
17 | 0.25 | 1.48 |
18 | 0.25 | 1.48 |
19 | 0.25 | 2.23 |
20 | 0.25 | 2.27 |
21 | 0.25 | 2.23 |
22 | 0.25 | 0.94 |
23 | 0.25 | N/A |
24 | 0.25 | N/A |
25 | 0.25 | N/A |
26 | 0.25 | N/A |
27 | 0.25 | N/A |
28 | 0.25 | 0.54 |
29 | 0.25 | 0.54 |
30 | 0.25 | 0.54 |
实施例编号 | CPI/RPI | CPC/RPC |
31 | 0.82 | 3.56 |
32 | 0.76 | 1.10 |
33 | 0.76 | 1.10 |
34 | 0.82 | 3.56 |
35 | 1.22 | 3.56 |
36 | 1.26 | 1.10 |
37 | 0.50 | 1.87 |
38 | 0.50 | 1.87 |
39 | 0.50 | 1.87 |
40 | 0.50 | 1.87 |
41 | 0.50 | 1.87 |
42 | 0.50 | 1.87 |
43 | 0.50 | 1.87 |
44 | 0.50 | 1.87 |
45 | 0.71 | 6.50 |
46 | 0.71 | 6.50 |
47 | 0.88 | 6.53 |
48 | 4.09 | 6.53 |
49 | 1.02 | 6.53 |
50 | 0.70 | 6.53 |
51 | 0.35 | 6.53 |
52 | 1.29 | 6.53 |
53 | 1.29 | 6.53 |
54 | 1.29 | 6.53 |
55 | 1.29 | 6.53 |
56 | 0.40 | 6.56 |
Claims (24)
Priority Applications (1)
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CN201610479298.8A CN106125509B (zh) | 2009-12-17 | 2010-12-16 | 用于加成法制造的可led固化的液体树脂组合物 |
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US28762009P | 2009-12-17 | 2009-12-17 | |
US61/287,620 | 2009-12-17 | ||
PCT/US2010/060677 WO2011075555A1 (en) | 2009-12-17 | 2010-12-16 | Led curable liquid resin compositions for additive fabrication |
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CN102934026A true CN102934026A (zh) | 2013-02-13 |
CN102934026B CN102934026B (zh) | 2016-08-03 |
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CN201080057939.1A Active CN102666073B (zh) | 2009-12-17 | 2010-12-16 | 基于基材的加成法制造工艺 |
CN201610479298.8A Active CN106125509B (zh) | 2009-12-17 | 2010-12-16 | 用于加成法制造的可led固化的液体树脂组合物 |
CN201080057944.2A Active CN102934026B (zh) | 2009-12-17 | 2010-12-16 | 用于加成法制造的可led固化的液体树脂组合物 |
CN201080057942.3A Active CN102858738B (zh) | 2009-12-17 | 2010-12-16 | 用于加成法制造的包含三芳基锍硼酸盐阳离子光引发剂的液体可辐射固化树脂 |
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CN201080057939.1A Active CN102666073B (zh) | 2009-12-17 | 2010-12-16 | 基于基材的加成法制造工艺 |
CN201610479298.8A Active CN106125509B (zh) | 2009-12-17 | 2010-12-16 | 用于加成法制造的可led固化的液体树脂组合物 |
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Country Status (7)
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US (3) | US9034236B2 (zh) |
EP (3) | EP2512779B1 (zh) |
JP (2) | JP5849350B2 (zh) |
KR (4) | KR101821426B1 (zh) |
CN (4) | CN102666073B (zh) |
BR (2) | BR112012014900B1 (zh) |
WO (3) | WO2011084578A1 (zh) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106125509A (zh) * | 2009-12-17 | 2016-11-16 | 帝斯曼知识产权资产管理有限公司 | 用于加成法制造的可led固化的液体树脂组合物 |
CN107236096A (zh) * | 2017-07-19 | 2017-10-10 | 中山大简科技有限公司 | 一种透明sla光敏树脂组合物 |
CN107428092A (zh) * | 2015-03-19 | 2017-12-01 | 陶氏环球技术有限责任公司 | 使用光调节自由基聚合的增材制造方法 |
CN107636025A (zh) * | 2015-06-08 | 2018-01-26 | 帝斯曼知识产权资产管理有限公司 | 用于加成法制造的液体、混杂的紫外/可见光可辐射固化树脂组合物 |
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