RU2017123807A - Пиколинамиды с фунгицидной активностью - Google Patents
Пиколинамиды с фунгицидной активностью Download PDFInfo
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- RU2017123807A RU2017123807A RU2017123807A RU2017123807A RU2017123807A RU 2017123807 A RU2017123807 A RU 2017123807A RU 2017123807 A RU2017123807 A RU 2017123807A RU 2017123807 A RU2017123807 A RU 2017123807A RU 2017123807 A RU2017123807 A RU 2017123807A
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- alkyl
- optionally substituted
- independently selected
- aryl
- hydrogen
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C271/06—Esters of carbamic acids
- C07C271/08—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
- C07C271/10—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms
- C07C271/22—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of hydrocarbon radicals substituted by carboxyl groups
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/10—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with sulfur as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/33—Heterocyclic compounds
- A61K31/395—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins
- A61K31/435—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins having six-membered rings with one nitrogen as the only ring hetero atom
- A61K31/44—Non condensed pyridines; Hydrogenated derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C229/00—Compounds containing amino and carboxyl groups bound to the same carbon skeleton
- C07C229/02—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton
- C07C229/04—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
- C07C229/06—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one amino and one carboxyl group bound to the carbon skeleton
- C07C229/08—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one amino and one carboxyl group bound to the carbon skeleton the nitrogen atom of the amino group being further bound to hydrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C229/00—Compounds containing amino and carboxyl groups bound to the same carbon skeleton
- C07C229/02—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton
- C07C229/04—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
- C07C229/22—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated the carbon skeleton being further substituted by oxygen atoms
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C229/00—Compounds containing amino and carboxyl groups bound to the same carbon skeleton
- C07C229/02—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton
- C07C229/34—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton containing six-membered aromatic rings
- C07C229/36—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton containing six-membered aromatic rings with at least one amino group and one carboxyl group bound to the same carbon atom of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/81—Amides; Imides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/07—Optical isomers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/02—Systems containing only non-condensed rings with a three-membered ring
Claims (39)
1. Соединение формулы I
X представляет собой водород или C(O)R5;
Y представляет собой водород, C(O)R5 или Q;
Q представляет собой
R1 представляет собой CH2OCH3 или водород или алкил, где алкил необязательно замещен 0, 1 или несколькими R8;
R2 представляет собой метил;
R3 выбран из C(O)OCH3 или алкила, алкенила или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8;
R4 выбран из алкила или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8;
R5 представляет собой алкокси, необязательно замещенный 0, 1 или несколькими R8;
R6 выбран из водорода или алкокси, каждый из которых необязательно замещен 0, 1 или несколькими R8;
R7 выбран из водорода, -C(O)R9 или -CH2OC(O)R9;
R8 выбран из водорода, алкила, арила, галогена, алкенила или фенокси, каждый из которых необязательно замещен 0, 1 или несколькими R10;
R9 выбран из алкила, алкокси или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8;
R10 выбран из алкила, арила, галогена, галогеналкила, галогенарила, алкенила или алкокси;
R11 выбран из водорода или метила.
2. Соединение по п.1, где X и Y представляют собой водород.
3. Соединение по п.2, где R1 и R11 независимо выбраны из водорода или метила.
4. Соединение по п.2, где R3 независимо выбран из алкила или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8.
5. Соединение по п.2, где R4 независимо выбран из алкила или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8.
6. Соединение по п.2, где R1 и R11 независимо выбраны из водорода или метила, R3 независимо выбран из алкила или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8, и R4 независимо выбран из алкила или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8.
7. Соединение по п.1, где X представляет собой C(O)R5, и Y представляет собой водород.
8. Соединение по п.7, где R1 и R11 независимо выбраны из водорода или метила.
9. Соединение по п.7, где R3 независимо выбран из алкила или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8.
10. Соединение по п.7, где R4 независимо выбран из алкила или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8.
11. Соединение по п.7, где R1 и R11 независимо выбраны из водорода или метила, R3 независимо выбран из алкила или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8, и R4 независимо выбран из алкила или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8.
12. Соединение по п.1, где X представляет собой водород, и Y представляет собой Q.
13. Соединение по п.12, где R7 представляет собой водород.
14. Соединение по п.13, где R6 представляет собой OCH3.
15. Соединение по п.14, где R1 и R11 независимо выбраны из водорода или метила.
16. Соединение по п.14, где R3 независимо выбран из алкила или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8.
17. Соединение по п.14, где R4 независимо выбран из алкила или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8.
18. Соединение по п.14, где R1 и R11 независимо выбраны из водорода или метила, R3 независимо выбран из алкила или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8, и R4 независимо выбран из алкила или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8.
19. Соединение по п.13, где R7 представляет собой C(O)R9 или CH2OC(O)R9.
20. Соединение по п.19, где R1 и R11 независимо выбраны из водорода или метила.
21. Соединение по п.19, где R3 независимо выбран из алкила или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8.
22. Соединение по п.19, где R4 независимо выбран из алкила или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8.
23. Соединение по п.19, где R1 и R11 независимо выбраны из водорода или метила, R3 независимо выбран из алкила или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8, и R4 независимо выбран из алкила или арила, каждый из которых необязательно замещен 0, 1 или несколькими R8.
Applications Claiming Priority (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201462098089P | 2014-12-30 | 2014-12-30 | |
US201462098097P | 2014-12-30 | 2014-12-30 | |
US62/098,089 | 2014-12-30 | ||
US62/098,097 | 2014-12-30 | ||
US201562255144P | 2015-11-13 | 2015-11-13 | |
US201562255152P | 2015-11-13 | 2015-11-13 | |
US62/255,152 | 2015-11-13 | ||
US62/255,144 | 2015-11-13 | ||
PCT/US2015/067199 WO2016109300A1 (en) | 2014-12-30 | 2015-12-21 | Picolinamides with fungicidal activity |
Publications (2)
Publication Number | Publication Date |
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RU2017123807A true RU2017123807A (ru) | 2019-01-31 |
RU2017123807A3 RU2017123807A3 (ru) | 2019-06-18 |
Family
ID=56284928
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU2017123618A RU2703402C2 (ru) | 2014-12-30 | 2015-12-21 | Пиколинамиды с фунгицидной активностью |
RU2017123807A RU2017123807A (ru) | 2014-12-30 | 2015-12-21 | Пиколинамиды с фунгицидной активностью |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU2017123618A RU2703402C2 (ru) | 2014-12-30 | 2015-12-21 | Пиколинамиды с фунгицидной активностью |
Country Status (17)
Country | Link |
---|---|
US (3) | US10173971B2 (ru) |
EP (2) | EP3240408B1 (ru) |
JP (2) | JP2018504389A (ru) |
KR (2) | KR20170100547A (ru) |
CN (2) | CN107205386B (ru) |
AU (3) | AU2015374376B2 (ru) |
BR (2) | BR112017013589A2 (ru) |
CA (2) | CA2972034A1 (ru) |
CO (2) | CO2017006827A2 (ru) |
IL (2) | IL252964A0 (ru) |
MX (2) | MX2017008060A (ru) |
NZ (2) | NZ732799A (ru) |
RU (2) | RU2703402C2 (ru) |
TW (2) | TW201627276A (ru) |
UY (2) | UY36490A (ru) |
WO (2) | WO2016109301A1 (ru) |
ZA (2) | ZA201704562B (ru) |
Families Citing this family (29)
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BR112017013653A2 (pt) | 2014-12-30 | 2018-03-13 | Dow Agrosciences Llc | uso de compostos de picolinamida com atividade fungicida |
RU2702088C2 (ru) | 2014-12-30 | 2019-10-03 | ДАУ АГРОСАЙЕНСИЗ ЭлЭлСи | Применение соединений пиколинамида в качестве фунгицидов |
CN107205397A (zh) | 2014-12-30 | 2017-09-26 | 美国陶氏益农公司 | 具有杀真菌活性的吡啶酰胺化合物的用途 |
CN107205385A (zh) | 2014-12-30 | 2017-09-26 | 美国陶氏益农公司 | 吡啶酰胺作为杀真菌剂的用途 |
KR20170100547A (ko) | 2014-12-30 | 2017-09-04 | 다우 아그로사이언시즈 엘엘씨 | 살진균 활성을 갖는 피콜린아미드 |
US10173982B2 (en) | 2016-08-30 | 2019-01-08 | Dow Agrosciences Llc | Picolinamides as fungicides |
TW201808905A (zh) * | 2016-08-30 | 2018-03-16 | 美商陶氏農業科學公司 | 具有殺真菌活性的硫代吡啶醯胺化合物 |
US10172358B2 (en) | 2016-08-30 | 2019-01-08 | Dow Agrosciences Llc | Thiopicolinamide compounds with fungicidal activity |
WO2018045012A1 (en) | 2016-08-30 | 2018-03-08 | Dow Agrosciences Llc | Pyrido-1,3-oxazine-2,4-dione compounds with fungicidal activity |
WO2018045006A1 (en) | 2016-08-30 | 2018-03-08 | Dow Agrosciences Llc | Picolinamide n-oxide compounds with fungicidal activity |
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TW201842851A (zh) | 2017-05-02 | 2018-12-16 | 美商陶氏農業科學公司 | 用於穀類中的真菌防治之協同性混合物 |
TWI774761B (zh) | 2017-05-02 | 2022-08-21 | 美商科迪華農業科技有限責任公司 | 用於穀物中的真菌防治之協同性混合物 |
CN110996665B (zh) | 2017-05-02 | 2021-10-26 | 陶氏益农公司 | 无环吡啶酰胺化合物作为针对草坪草上的真菌病害的杀真菌剂的用途 |
UY37913A (es) | 2017-10-05 | 2019-05-31 | Syngenta Participations Ag | Derivados de picolinamida fungicidas que portan un grupo terminal cuaternario |
UY37912A (es) | 2017-10-05 | 2019-05-31 | Syngenta Participations Ag | Derivados de picolinamida fungicidas que portan grupos terminales heteroarilo o heteroariloxi |
US11459318B2 (en) | 2017-10-06 | 2022-10-04 | Syngenta Participations Ag | Pesticidally active pyrrole derivatives |
CN111344279B (zh) | 2017-11-15 | 2023-07-07 | 先正达参股股份有限公司 | 杀微生物的吡啶酰胺衍生物 |
WO2019121149A1 (en) | 2017-12-19 | 2019-06-27 | Syngenta Participations Ag | Microbiocidal picolinamide derivatives |
BR102019004480B1 (pt) * | 2018-03-08 | 2023-03-28 | Dow Agrosciences Llc | Picolinamidas como fungicidas |
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US11629129B2 (en) | 2018-05-25 | 2023-04-18 | Syngenta Participations Ag | Microbiocidal picolinamide derivatives |
CN110963963A (zh) * | 2018-09-29 | 2020-04-07 | 沈阳中化农药化工研发有限公司 | 一种吡啶酰胺类化合物及其杀菌用途 |
BR112021006669A2 (pt) | 2018-10-15 | 2021-07-06 | Dow Agrosciences Llc | métodos para síntese de oxipicolinamidas |
WO2020208095A1 (en) | 2019-04-10 | 2020-10-15 | Syngenta Crop Protection Ag | Microbiocidal picolinamide derivatives |
WO2020208096A1 (en) | 2019-04-10 | 2020-10-15 | Syngenta Crop Protection Ag | Fungicidal compositions |
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