JP5524086B2 - サニタリー物品上に塗布するための接着剤 - Google Patents
サニタリー物品上に塗布するための接着剤 Download PDFInfo
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Description
R2、R3=(−CH2−CH2−O)n−R4または(−(CH2)3−O)n−R4であり、
R4=H、アルキル、アリールであり、n=1〜100である)
によるエトキシル化ポリイミン、すなわち、ポリイミンのエトキシル化により得られる系である。
R2、R3=C(O)−N−X
(式中、X=コポリマー、例えば、ポリウレタンであり、すなわち、側基が上記式(1)のポリマー鎖(ブロックポリマーのコポリマーとしてのイミン類似体)に再び結合する)である。
Claims (14)
- サニタリー物品上に直接塗布することができ、そこに接着し、比較的多数のフラッシュ操作回数の後にのみ洗い流すことができ、界面活性剤および接着促進剤を含むサニタリー分野用の接着剤であって、
前記接着促進剤は、官能基がランダムに分布したポリアルキレン鎖を含むポリアルキレン誘導体の群から、またはポリ/メチルビニルエーテル/カルボン酸無水物のモノアルキルエステルの群のコポリマー、部分的に酸化、もしくはグラフト分子を介してさらに官能化されているオレフィンホモポリマーおよび2種以上のオレフィンのコポリマーの群から、ならびにアルコキシル化形態も含めたポリアルキレンイミン、ポリエーテルアミンおよびポリグリセロールポリエーテルアルキルカルボン酸もしくはポリマーまたはこれらのポリマー群を含有する誘導体の群から選択され、
Haake粘度計、プレート/プレートシステム、プレート直径10mmを使用して2.62s-1の剪断勾配および20℃で測定すると、前記接着剤の粘度は少なくとも30Pasであり、この粘着性は便器中に棒状の組成物を付着させるのに十分な粘着性であり、ポリアルキレンイミンの群の接着促進剤の場合、前記界面活性剤の濃度は7と60重量%の間であることを特徴とする接着剤。 - 前記ポリアルキレン誘導体の群の接着促進剤のポリアルキレン鎖は、ポリブタジエン、ポリイソプロピレンおよびポリプロピレン鎖であり、前記官能基は、無水物、チオール、エポキシドまたは第一級アミンであることを特徴とする、請求項1に記載の接着剤。
- 前記ポリアルキレン誘導体は、無水マレイン酸基がポリブタジエン鎖にランダムに結合したポリマーであることを特徴とする、請求項1または2のいずれかに記載の接着剤。
- 部分的に酸化、もしくはグラフト分子を介してさらに官能化されているオレフィンホモポリマーおよび2種以上のオレフィンのコポリマーの群の前記接着促進剤は、ポリブタジエンゴム、スチレン−ブタジエンブロックポリマーおよびコポリマー、ポリイソプレン、
ブタジエンまたはイソプレンを、スチレンまたはα−メチルスチレン上に1,3−付加することにより調製されるランダム(ブロック)ポリマー、エチレンおよびプロピレンのホモポリマーまたはコポリマー、から選択されることにより調製されることを特徴とする、請求項1に記載の接着剤。 - ポリアルキレンイミンの群の前記接着促進剤は、ホモポリマーのポリアルキレンイミン、R=アルキルまたはアルキル誘導体であり、n=10〜105であり、窒素官能基上に2または3次元の架橋結合を有する、一般式−(R−NH)nのものであることを特徴とする請求項1に記載の接着剤。
- ポリエーテルアミンが、エトキシル化またはプロポキシル化された第一級および/または第二級および/または第三級アルキルまたはアリールアミンを含むことを特徴とする、請求項1に記載の接着剤。
- 前記ポリエーテルアミンは、三官能性、二官能性および/または一官能性第一級アミン、ならびにポリエーテル基として、ポリエチレンオキシド、混合ポリ(エチレンオキシド/プロピレンオキシド)またはポリプロピレンオキシド基を含有することを特徴とする、請求項1に記載の接着剤。
- ポリグリセロールポリエーテルアルキルカルボン酸が、トリステアリン酸ポリエチレングリコール−150ポリグリセリル−2またはトリステアリン酸PEG−150ジグリセリルまたはジステアリン酸PEG−150テトラグリセリルの群から選択されることを特徴とする請求項1に記載の接着剤。
- 前記接着促進剤の濃度は、15重量%と80重量%の間であることを特徴とする請求項1に記載の接着剤。
- 前記接着剤は、増量剤をさらに備え、前記増量剤は、増粘剤、芳香剤、染料、塩、泡安定剤、増泡剤、発泡剤およびポリマー天然物質の群から選択されることを特徴とする請求項1に記載の接着剤。
- 0.25重量%と20重量%の間の濃度で芳香剤または香油を含むことを特徴とする請求項1に記載の接着剤。
- 前記棒状の組成物は、1つまたは複数の相を有する通常のリムブロック、香り付きの相を有するリムブロック、漂白剤を含有するリムブロック、圧縮タブレット、有効成分を含む水溶性または水不溶性プラスチック、脱臭タブレット、固体脱臭ゲル、漂白タブレット、スケール除去タブレットまたは強力洗浄タブレットのいずれかであることを特徴とする、請求項1に記載の接着剤。
- 請求項1に記載の少なくとも一種の接着剤、および、1つまたは複数の相を有するリムブロック、香り付きの相を有するリムブロック、漂白剤を含有するリムブロック、圧縮タブレット、有効成分を含む水溶性または水不溶性プラスチック、脱臭タブレット、固体脱臭ゲル、漂白タブレット、スケール除去タブレットまたは強力洗浄タブレットの群の1つまたは複数の棒状の組成物が含まれることを特徴とする、トイレ洗浄セット。
- 目的物を小便器、手洗器もしくはタイル、またはキッチン、レストラン、屠殺場、洗浄設備に付着させたり、配水管もしくは下水管の上/中で使用するための低温接着剤として、あるいは害獣を駆除するための毒餌のセッティングや窓、ファサードに目的物を付着させるためのペーストとしての請求項1に記載される接着剤。
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DE102008012092.8 | 2008-02-29 | ||
DE102008012092A DE102008012092A1 (de) | 2008-02-29 | 2008-02-29 | Haftendes Mittel zur Applikation auf einem Sanitärgegenstand |
DE102008051173.0 | 2008-10-14 | ||
DE200810051173 DE102008051173A1 (de) | 2008-10-14 | 2008-10-14 | Haftendes Mittel zur Applikation auf einem Sanitärgegenstand |
PCT/EP2009/000873 WO2009106220A1 (de) | 2008-02-29 | 2009-02-09 | Haftendes mittel zur applikation auf einem sanitärgegenstand |
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JP2011039599A Division JP5524108B2 (ja) | 2008-02-29 | 2011-02-25 | サニタリー物品上に塗布するための接着剤 |
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