DE2718697C3 - Komposition mit geregelter Änderung von Farbe und pH-Wert beim Gefrieren sowie Verfahren zu ihrer Herstellung - Google Patents
Komposition mit geregelter Änderung von Farbe und pH-Wert beim Gefrieren sowie Verfahren zu ihrer HerstellungInfo
- Publication number
- DE2718697C3 DE2718697C3 DE2718697A DE2718697A DE2718697C3 DE 2718697 C3 DE2718697 C3 DE 2718697C3 DE 2718697 A DE2718697 A DE 2718697A DE 2718697 A DE2718697 A DE 2718697A DE 2718697 C3 DE2718697 C3 DE 2718697C3
- Authority
- DE
- Germany
- Prior art keywords
- composition
- freezing
- solution
- color
- red
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
- G01N31/22—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using chemical indicators
- G01N31/221—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using chemical indicators for investigating pH value
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- Biophysics (AREA)
- Molecular Biology (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
- Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
Description
Farbe bei +20 C
9,40 | dunkelviolett | grünbraun | blau | gelb |
9,00 | dunkelviolett | gelbrot | blau | gelb |
8,50 | dunkelviolett | gelbrot | blau | gelb |
8,00 | dunkelviolett | gelbrot | blau | gelb |
7,50 | dunkelviolett | gelbrot | blaugrün | gelb |
7,00 | violett | gelbrot | grün | gelb |
6,50 | braun | gelbrot | grün | gelb |
6,00 | braunrot | gelbrot | gelbgrün | gelb |
5,50 | rotgelb | gelbrot | gelb | gelb |
5,00 | gelbrot | gelbrot | gelb | gelb |
4,60 | gelbrot | gelb | gelb | |
pH | Nitrazingelb | -20 C | Bromthymnlblau | -20 Γ |
( + 20 C) | Farbe bei +20 C | dunkelviolett | Farbe bei +20 t | blau |
9.40 | dunkelviolett | dunkelviolett | blau | blau |
9,00 | dunkelviolett | dunkelviolett | blau | blaugrün |
8,50 | dunkelviolett | dunkelviolett | blau | grün |
8,00 | dunkeiviolett | dunkelviolett | blau | grüngelb |
7,50 | dunkelviolett | violett | blaugrün | gelb |
7,00 | violett | hellviolett | grün | gelb |
6,50 | braun | gelbbraun | grün | gelb |
6,00 | braunrot | gclbrot | gclbgrün | gelb |
5,50 | rotgelb | gelbrot | gelb | gelb |
5,00 | gelbrot | gelbrot | gelb | gelb |
4,60 | gelbrot | gelb | ||
0,02 M | Tris-PulTer + 0.1 M NaCI | |||
pH | Nitrazingelb | 18 C | Bromthymolhlau | -20 C |
( + 20 C) | Farbe bei +20 C | violett | Farbe bei + 20 C | hellblau |
9,4 | violett | violett | blau | hellblau |
9,0 | violett | violett | blau | hellblau |
8,5 | violett | violett | blau | hellblau |
8,0 | violett | violett | blau | blaugrau |
7,5 | violett | violett | grünblau | graugrün |
7,0 | hellviolett | violett | grün | gelbgrau |
6,5 | lilabraun | hellbraun | grün | gelb |
6,0 | braun | - | gelbgrün | gelb |
5,5 | - | gelbrot | gelb | gelb |
5,0 | gelb | gelb | ||
pH-Indikator
Thymolblau
r | VT | V | hlv | V | y | r | h | r | y | ν | V | _ V | J | _ h | v | y | y | V | [ | y _ | uh | I,. | r | y | b | b | — vr | ! | |
ry — | V | ,_ V | _ V | ν ν | y | V | b | ||||||||||||||||||||||
rv | hl | r | Γ | hlv | |||||||||||||||||||||||||
r | ο | y | |||||||||||||||||||||||||||
- — | |||||||||||||||||||||||||||||
y | |||||||||||||||||||||||||||||
ry — | Iy | ||||||||||||||||||||||||||||
_ | ν | Γ | |||||||||||||||||||||||||||
r | -y | V | |||||||||||||||||||||||||||
y | -y | ||||||||||||||||||||||||||||
— | — - | ||||||||||||||||||||||||||||
ν | |||||||||||||||||||||||||||||
r | |||||||||||||||||||||||||||||
— | |||||||||||||||||||||||||||||
ry | |||||||||||||||||||||||||||||
b | = blau | grbr = | graubraun |
b! | - schwarz | Iy = | hellgelb |
blv | = schwarzviolett | Ibr = | hellbraun |
br | = braun | 0 = | orange |
C | = farblos | r = | rot |
ry | = rotgelb |
y | = gelb |
yr | = gelbrot |
V | = violett |
vr | = violettrot |
Tafel 3 | 13 | 2% | 27 18 | 697 | 20% | 14 | Farbe bei Ziminertemp. (alle) |
pll-lndi! atnr | Glyceri ngchalt 1% |
rot blaugrün dunkelrot |
5 Vn | 10% | rot blau rot |
0-Kontrollc | violett blau rot |
Chlorphenole Bromkresolgrün Kongorot |
gelb mit etwas rot blaugrün braunrot |
rot blau rot |
rot blau rot |
gelb grün schwarz |
|||
<
-!4 | hUiiiorii Ii —c" *-■ ■ |
hj. IMOi-Mr; | begrün |
-16 | gelb | grüngelb | gclbgrün |
-18 | gelb | gelbgrün | gelbgrün |
-20 | gelb | gelbgrün | gelb |
22 | gelb | gelb | gelb |
-16
-18
-20
-22
(Gew.Λ öl,-■■..)
Sorbitol (5"..|
Saccharose (y n)
Polyathylenglykol (5.)
Cellosolve (5%)
Methanol (5"·.■.)
Äthanol (5"«)
Natriumglutamat (5%)
Natriumsuccinat (5%)
Natriumacetat (5%)
Natriumeitrat (5°/·)
Ammoniumformiat (5%)
blau
blau
blau
grün
pH (+20 C | -20X | -15 C | -6 C | +5 C | + 10 C | +20C |
9,9 | rot | rot | rot | rot | rot | rot |
9,15 | rot | rot | rot | rot | rot | rot |
8,5 | rot | rot | rotbraun | rot | rot | rot |
8,0 | schwarz | schwarz | schwarz | rot | rot | rot |
7,5 | schwarz | schwarz | schwarz | rot | rot | rot |
7,0 | schwarz | schwarz | schwarz | rot | rot | rot |
6,5 | schwarz | schwarz | schwarz | rot | rot | rot |
6,0 | schwarz | schwarz | schwarz | rot | rot | rot |
fest | flüssig | |||||
Beispiel 8 |
Temperatur | Farbe |
(C) | |
+20 | rot |
- 6 | rot |
-10 | gelbrot |
-18 | gelbrot |
Enzym | Substrat | Beispiel | Regelmittel | Übrige Produkte |
Phosphatase | Olucose-6-Phosphat | Glucose | Phosphat | |
Phosphatase | jS-Glycerophosphal | Glycerin | Phosphat | |
Esterase | Äthylbutyrat | Äthanol | Butyral | |
Lipase | Trigiycerid | Glycerin | Fettsäuresalz | |
10 |
Claims (29)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE7605338A SE410229B (sv) | 1976-05-11 | 1976-05-11 | Vattenhaltig komposition med reglerad ph-forskjutning vid frysning, samt sett for dess framstellning |
Publications (3)
Publication Number | Publication Date |
---|---|
DE2718697A1 DE2718697A1 (de) | 1977-11-24 |
DE2718697B2 DE2718697B2 (de) | 1979-04-12 |
DE2718697C3 true DE2718697C3 (de) | 1979-12-20 |
Family
ID=20327813
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE2718697A Expired DE2718697C3 (de) | 1976-05-11 | 1977-04-27 | Komposition mit geregelter Änderung von Farbe und pH-Wert beim Gefrieren sowie Verfahren zu ihrer Herstellung |
Country Status (21)
Country | Link |
---|---|
US (1) | US4149852A (de) |
JP (1) | JPS5857710B2 (de) |
AT (1) | AT359043B (de) |
AU (1) | AU506640B2 (de) |
BE (1) | BE854352A (de) |
CA (1) | CA1080096A (de) |
CH (1) | CH634148A5 (de) |
DE (1) | DE2718697C3 (de) |
DK (1) | DK205277A (de) |
ES (1) | ES458645A1 (de) |
FR (1) | FR2351406A1 (de) |
GB (1) | GB1557742A (de) |
GR (1) | GR63135B (de) |
IE (1) | IE45416B1 (de) |
IT (1) | IT1113587B (de) |
LU (1) | LU77223A1 (de) |
MC (1) | MC1150A1 (de) |
NL (1) | NL171198C (de) |
NO (1) | NO144307C (de) |
PT (1) | PT66522B (de) |
SE (1) | SE410229B (de) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3704068A1 (de) * | 1986-02-11 | 1987-08-13 | Gouws & Scheepers Pty Ltd | Landwirtschaftliche zusammensetzungen |
Families Citing this family (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1601922A (en) * | 1977-03-11 | 1981-11-04 | Minnesota Mining & Mfg | Steam formaldehyde sterilization indicator |
US4232552A (en) * | 1978-09-28 | 1980-11-11 | Akzona Incorporated | Temperature indicating compositions of matter |
US4362645A (en) * | 1978-09-28 | 1982-12-07 | Akzona, Inc. | Temperature indicating compositions of matter |
US4339207A (en) * | 1978-09-28 | 1982-07-13 | Akzona Incorporated | Temperature indicating compositions of matter |
SE431258B (sv) * | 1982-07-02 | 1984-01-23 | Tiru Maj Britt Ingegerd | Komposition med reglerad forendring av opalescens eller uppklarning vid valda temperaturer och sett for dess framstellning samt anvendning av kompositionen |
IT1198706B (it) * | 1983-10-18 | 1988-12-21 | Consiglio Nazionale Ricerche | Sensore di temperatura a fibra ottica ad effetto termocormico |
JPS62243675A (ja) * | 1986-04-15 | 1987-10-24 | Kao Corp | pH緩衝法 |
US4846095A (en) * | 1987-10-02 | 1989-07-11 | Minnesota Mining And Manufacturing Company | Critical temperature indicating device |
JPH01168814U (de) * | 1988-05-19 | 1989-11-28 | ||
US5077222A (en) * | 1988-09-30 | 1991-12-31 | Miles Inc. | Method for assaying for proteins using a dual indicator reagent composition |
US5049358A (en) * | 1988-09-30 | 1991-09-17 | Miles Inc. | Composition and test device for assaying for proteins |
SE9403859L (sv) * | 1994-04-29 | 1995-10-30 | Visual Indicator Tag Systems V | Sätt och anordning för kontroll av hanteringsbetingelser |
US5817454A (en) * | 1995-06-07 | 1998-10-06 | Coffee Chek, Inc. | Portable apparatus and method for detection of methylxanthine chemical species |
US5964181A (en) * | 1995-11-16 | 1999-10-12 | 3M Innovative Properties Company | Temperature indicating device |
US7253003B2 (en) * | 2001-10-19 | 2007-08-07 | Wisconsin Alumni Research Foundation | Method for monitoring the environment within a microfluidic device |
DE10226716A1 (de) * | 2002-06-14 | 2004-01-08 | Henkel Kgaa | Indikationssystem |
JP3852395B2 (ja) * | 2002-11-06 | 2006-11-29 | 東亞合成株式会社 | 2−シアノアクリレート用硬化判定剤及び硬化判定方法 |
ES2237315B2 (es) * | 2003-11-10 | 2006-03-01 | Universidad De Alicante | Sistema de verificacion visual de la integridad de la cadena de frio. |
US7258073B2 (en) * | 2004-01-20 | 2007-08-21 | Mcguire Katherine M | Pictorial thermometer |
US8491471B2 (en) * | 2006-08-31 | 2013-07-23 | Dignity Health | Inflatable surgical retractor |
US9138137B2 (en) | 2006-08-31 | 2015-09-22 | Dignity Health | Inflatable surgical retractor |
EP2069446B1 (de) * | 2006-09-08 | 2010-03-17 | 3M Innovative Properties Company | Farbwechselnde cyanoacrylatkleber |
US8133403B2 (en) * | 2007-07-31 | 2012-03-13 | Behr Process Corporation | System and method for controlling the application of acid etchers or cleaners by means of color-changing dye |
EP2904361A1 (de) | 2012-10-01 | 2015-08-12 | Innorese AG | Anzeigevorrichtung |
US10851414B2 (en) | 2013-10-18 | 2020-12-01 | Good Start Genetics, Inc. | Methods for determining carrier status |
JP6519777B2 (ja) * | 2014-03-20 | 2019-05-29 | トッパン・フォームズ株式会社 | 保冷具 |
AU2015239668B2 (en) | 2014-03-31 | 2019-12-19 | Innorese Ag | Indicating device |
EP3224595A4 (de) * | 2014-09-24 | 2018-06-13 | Good Start Genetics, Inc. | Prozesssteuerung für erhöhte robustheit von genetischen assays |
JP6446754B2 (ja) * | 2015-01-20 | 2019-01-09 | トッパン・フォームズ株式会社 | 保冷具 |
US20170130432A1 (en) * | 2015-11-10 | 2017-05-11 | Aqua View Inc. | Water conserving shower system and thermochromic fixtures used therein |
US11524515B2 (en) * | 2019-04-05 | 2022-12-13 | Xerox Corporation | Thermochromic dye compositions and method for preparing same |
CN114137773B (zh) * | 2021-11-05 | 2024-03-08 | 哈尔滨工业大学(深圳) | 一种热电双响应智能变色器件及其制备方法 |
CN114958092B (zh) * | 2022-06-01 | 2023-06-20 | 东莞职业技术学院 | 一种温变防伪油墨及其制备方法和应用 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2261473A (en) * | 1938-04-16 | 1941-11-04 | George W Jennings | Temperature indicator |
US2195395A (en) * | 1938-10-21 | 1940-04-02 | Chapman Arthur William | Means for indicating the extent of a thermal treatment |
US2614430A (en) * | 1950-02-01 | 1952-10-21 | Eastman Kodak Co | Temperature indicating device |
US2809116A (en) * | 1955-10-07 | 1957-10-08 | Armour Res Found | 2, 4, 6-trinitrobenzoate ester-addition compound indicator |
GB1183160A (en) * | 1968-11-08 | 1970-03-04 | Westinghouse Electric Corp | Thermometer |
SE380098B (de) * | 1974-02-21 | 1975-10-27 | Food Control | |
US3935834A (en) * | 1975-02-04 | 1976-02-03 | The United States Of America As Represented By The Secretary Of The Army | Frost line indicator |
-
1976
- 1976-05-11 SE SE7605338A patent/SE410229B/xx not_active IP Right Cessation
-
1977
- 1977-04-26 AT AT290577A patent/AT359043B/de not_active IP Right Cessation
- 1977-04-27 DE DE2718697A patent/DE2718697C3/de not_active Expired
- 1977-04-28 CA CA277,260A patent/CA1080096A/en not_active Expired
- 1977-04-28 LU LU77223A patent/LU77223A1/xx unknown
- 1977-05-03 GR GR53352A patent/GR63135B/el unknown
- 1977-05-04 AU AU25020/77A patent/AU506640B2/en not_active Expired
- 1977-05-06 PT PT66522A patent/PT66522B/pt unknown
- 1977-05-06 US US05/794,681 patent/US4149852A/en not_active Expired - Lifetime
- 1977-05-06 BE BE177348A patent/BE854352A/xx not_active IP Right Cessation
- 1977-05-09 CH CH575177A patent/CH634148A5/de not_active IP Right Cessation
- 1977-05-10 IE IE949/77A patent/IE45416B1/en unknown
- 1977-05-10 NL NLAANVRAGE7705176,A patent/NL171198C/xx not_active IP Right Cessation
- 1977-05-10 JP JP52053620A patent/JPS5857710B2/ja not_active Expired
- 1977-05-10 DK DK205277A patent/DK205277A/da not_active Application Discontinuation
- 1977-05-10 ES ES458645A patent/ES458645A1/es not_active Expired
- 1977-05-10 GB GB19468/77A patent/GB1557742A/en not_active Expired
- 1977-05-10 NO NO771641A patent/NO144307C/no unknown
- 1977-05-10 MC MC771239A patent/MC1150A1/xx unknown
- 1977-05-11 FR FR7714410A patent/FR2351406A1/fr active Granted
- 1977-05-11 IT IT23416/77A patent/IT1113587B/it active
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3704068A1 (de) * | 1986-02-11 | 1987-08-13 | Gouws & Scheepers Pty Ltd | Landwirtschaftliche zusammensetzungen |
DE3704068C2 (de) * | 1986-02-11 | 1999-03-18 | Gouws & Scheepers Pty Ltd | Wasserverdünnbares Konzentrat und dessen Verwendung |
Also Published As
Publication number | Publication date |
---|---|
NL171198C (nl) | 1983-02-16 |
ES458645A1 (es) | 1978-10-16 |
US4149852A (en) | 1979-04-17 |
PT66522A (en) | 1977-06-01 |
AU2502077A (en) | 1978-11-16 |
ATA290577A (de) | 1980-03-15 |
SE7605338L (sv) | 1977-11-12 |
DK205277A (da) | 1977-11-12 |
NO144307B (no) | 1981-04-27 |
FR2351406A1 (fr) | 1977-12-09 |
IT1113587B (it) | 1986-01-20 |
DE2718697A1 (de) | 1977-11-24 |
LU77223A1 (de) | 1977-08-18 |
IE45416B1 (en) | 1982-08-25 |
JPS5857710B2 (ja) | 1983-12-21 |
BE854352A (fr) | 1977-09-01 |
FR2351406B1 (de) | 1981-09-11 |
IE45416L (en) | 1977-11-11 |
CA1080096A (en) | 1980-06-24 |
DE2718697B2 (de) | 1979-04-12 |
PT66522B (en) | 1978-10-16 |
GR63135B (en) | 1979-09-18 |
NL7705176A (nl) | 1977-11-15 |
NO144307C (no) | 1981-08-05 |
SE410229B (sv) | 1979-10-01 |
AT359043B (de) | 1980-10-10 |
NO771641L (no) | 1977-11-14 |
MC1150A1 (fr) | 1978-01-30 |
JPS5325489A (en) | 1978-03-09 |
NL171198B (nl) | 1982-09-16 |
GB1557742A (en) | 1979-12-12 |
AU506640B2 (en) | 1980-01-17 |
CH634148A5 (de) | 1983-01-14 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
OD | Request for examination | ||
C3 | Grant after two publication steps (3rd publication) | ||
EGA | New person/name/address of the applicant | ||
8327 | Change in the person/name/address of the patent owner |
Owner name: I-POINT AB, 21375 MALMOE, SE |
|
8328 | Change in the person/name/address of the agent |
Free format text: CZOWALLA, E., DIPL.-ING. DIPL.-LANDW. MATSCHKUR, P., DIPL.-PHYS., PAT.-ANW., 8500 NUERNBERG |
|
8327 | Change in the person/name/address of the patent owner |
Owner name: I-POINT BIOTECHNOLOGIES AB, MALMOE, SE |
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8327 | Change in the person/name/address of the patent owner |
Owner name: ENZYMETECH INTERNATIONAL N.V., PHILIPSBURG, ST. MA |
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8327 | Change in the person/name/address of the patent owner |
Owner name: I-POINT BIOTECHNOLOGIES AB, MALMOE, SE |
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8328 | Change in the person/name/address of the agent |
Free format text: CZOWALLA, E., DIPL.-ING. DIPL.-LANDW. MATSCHKUR, P., DIPL.-PHYS., 8500 NUERNBERG GOETZ, G., DIPL.-ING., PAT.-ANWAELTE, 8700 WUERZBURG |
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Free format text: DERZEIT KEIN VERTRETER BESTELLT |
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8339 | Ceased/non-payment of the annual fee |