WO2013141118A1 - Composition détergente liquide - Google Patents

Composition détergente liquide Download PDF

Info

Publication number
WO2013141118A1
WO2013141118A1 PCT/JP2013/057059 JP2013057059W WO2013141118A1 WO 2013141118 A1 WO2013141118 A1 WO 2013141118A1 JP 2013057059 W JP2013057059 W JP 2013057059W WO 2013141118 A1 WO2013141118 A1 WO 2013141118A1
Authority
WO
WIPO (PCT)
Prior art keywords
component
mass
acid
general formula
detergent composition
Prior art date
Application number
PCT/JP2013/057059
Other languages
English (en)
Japanese (ja)
Inventor
光俊 森部
葉月 筒井
Original Assignee
ライオン株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ライオン株式会社 filed Critical ライオン株式会社
Priority to JP2014506169A priority Critical patent/JP6013454B2/ja
Priority to KR1020147020562A priority patent/KR101876272B1/ko
Publication of WO2013141118A1 publication Critical patent/WO2013141118A1/fr
Priority to PH12014502080A priority patent/PH12014502080A1/en

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/55—Phosphorus compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2079—Monocarboxylic acids-salts thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/596—Mixtures of surface active compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds

Definitions

  • the present invention relates to a liquid detergent composition for use in hair detergents such as shampoos and rinse-in shampoos, body soaps, hand soaps, foam hand soaps, cleansing foams and other skin detergents, kitchen detergents and clothing detergents. About.
  • the liquid detergent composition is less irritating to the skin, has excellent foam performance such as foaming, foam creaminess, and rinsing properties, as well as having a high bactericidal effect against pathogenic bacteria such as Escherichia coli. It is desired.
  • fatty acid salts have been used as cleaning components that have excellent foam performance and a high bactericidal effect against pathogenic bacteria such as Escherichia coli.
  • the fatty acid salt is used in a liquid detergent composition, there is a problem that fatty acid is precipitated due to a decrease in pH, the mesh of the former container is clogged, the rinsing property is decreased, and skin irritation is increased.
  • a detergent composition containing an anionic surfactant and an alkyl amino acid type surfactant see Patent Document 2 and Patent Document 4
  • a detergent composition containing an anionic surfactant and an alkylaminodicarboxylic acid type surfactant is proposed. According to these proposals, a formulation excellent in hypoallergenicity, foaming property, and rinsing property can be realized, but sufficiently satisfactory performance is obtained in terms of bactericidal effect against pathogenic bacteria such as E. coli and pH stability. Did not have.
  • liquid detergent composition that is excellent in bactericidal effect against E. coli, pH stability, foam performance, and rinsing properties, and has little skin irritation.
  • an object of the present invention is to provide a liquid detergent composition that is excellent in bactericidal effect against E. coli, pH stability, foam performance, and rinsing properties, and has little skin irritation.
  • the bactericidal effect is improved by capturing divalent ions on the membrane surface and changing the physical properties of the bacterial membrane, and by capturing divalent ions (Ca 2+ , Mg 2+, etc.) in tap water, the component (A) And it succeeded in suppressing inactivation of the said (B) component and improving foaming.
  • (D) By adding polyhydric alcohol to lower the polarity of the solvent, the components (A) and (B) can be stably arranged at the gas-liquid interface, thereby realizing a creamy foam quality. Each was found to be capable of giving a moist and good feel.
  • the component (A) to the component (C), preferably the component (D), acts synergistically to provide excellent bactericidal effect against Escherichia coli, excellent foaming, foam creaminess, and rinsing properties.
  • the skin irritation is low, it has been found that a liquid detergent composition that can be used with peace of mind from a woman with sensitive skin to a child with weak skin can be obtained.
  • the liquid cleaning composition of this invention as a means for solving the said subject is represented by (A) following General formula (1). 1% to 7% by weight of fatty acid salt, R 1 COOM General formula (1) (In the general formula (1), R 1 represents a monovalent hydrocarbon group having 5 to 25 carbon atoms, and M represents any one of an alkali metal, ammonium, an alkanolamine, and a basic amino acid.) ) (B) an alkylaminocarboxylic acid type amphoteric surfactant, and (C) a chelating agent, Wherein component (A), the general formula (1) R 1 in the fatty acid salt is a monovalent hydrocarbon group having 5 to 12 carbon atoms (A 1), R 1 carbon atoms in the general formula (1) And a fatty acid salt (A 2 ) that is a monovalent hydrocarbon group of 13 to 25, and the mass ratio mass ratio (A 1 / A 2 ) of the (A 1 ) component and the (A)
  • the above-described problems can be solved and the above-mentioned object can be achieved, and a liquid detergent composition having excellent bactericidal effect against E. coli, pH stability, foam performance, and rinsing properties and less skin irritation Things can be provided.
  • the liquid detergent composition of the present invention contains (A) a fatty acid salt, (B) an alkylaminocarboxylic acid type amphoteric surfactant, and (C) a chelating agent, and (D) a polyhydric alcohol. Preferably, it contains other components as required.
  • R 1 represents a monovalent hydrocarbon group having 5 to 25 carbon atoms
  • M represents any one of an alkali metal, ammonium, alkanolamine, and a basic amino acid.
  • R 1 represents a straight or branched monovalent hydrocarbon group having 5 to 25 carbon atoms, preferably 7 to 17 carbon atoms, and may be saturated or unsaturated.
  • the carbon number of R 1 is less than 5, there is no surface activity and foaming and bactericidal power against E. coli may be deteriorated, and when it exceeds 25, bubbling, rinsing performance and bactericidal power against E. coli are poor. May be.
  • M represents any one of an alkali metal, ammonium, alkanolamine, and a basic amino acid.
  • an alkali metal is preferable and potassium is especially preferable from the point of the bactericidal effect with respect to colon_bacillus
  • R 1 in is a monovalent hydrocarbon group having 5 to 12 carbon atoms fatty acid salt (A 1), R 1 in the general formula (1) And a fatty acid salt (A 2 ) which is a monovalent hydrocarbon group having 13 to 25 carbon atoms, and the mass ratio (A 1 / A 2 ) between the (A 1 ) component and the (A 2 ) component is 0.8 to 20, and preferably 1 to 9 from the viewpoint of rinsing properties, skin irritation, foaming and foam creaminess.
  • the mass ratio (A 1 / A 2 ) is less than 0.8, foaming and rinsing properties may deteriorate, and when it exceeds 20, the skin irritation becomes strong and the creamy property of the bubbles deteriorates. May be.
  • the component (A 1 ) is not particularly limited as long as R 1 in the general formula (1) is a monovalent hydrocarbon group having 5 to 12 carbon atoms, and may be appropriately selected depending on the purpose.
  • capronate carbon number of R 1 : 5
  • caprylate carbon number of R 1 : 7
  • caprate carbon number of R 1 : 9
  • laurate of R 1 Carbon number: 11
  • caprate and laurate are preferable from the viewpoints of foaming, foam creaminess, and bactericidal activity against E. coli, and are excellent in skin irritation and foam creaminess.
  • laurate specifically, potassium laurate is more preferable.
  • the component (A 2 ) is not particularly limited as long as R 1 in the general formula (1) is a monovalent hydrocarbon group having 13 to 25 carbon atoms, and may be appropriately selected depending on the purpose.
  • myristic acid salt (R 1 carbon number: 13), palmitate (R 1 carbon number: 15), stearic acid salt (R 1 carbon number: 17), oleate (R 1 carbon number: Examples thereof include carbon number: 17), linoleate (carbon number of R 1 : 17), isostearate (carbon number of R 1 : 17), behenate (carbon number of R 1 : 21), and the like. These may be used alone or in combination of two or more.
  • the component (A 2 ) from the viewpoint of foaming, rinsing properties, and bactericidal power against E. coli, myristate and palmitate are preferable, and from the viewpoint of foaming, rinsing properties and stability at low temperatures, Myristate, specifically potassium myristate, is particularly preferred.
  • the fatty acid salt of the component (A) a mixture of natural fatty acid salts can be used.
  • Examples of the fatty acid salt mixture include coconut oil fatty acid salt, hardened coconut oil fatty acid salt, palm oil fatty acid salt, Examples include hardened palm oil fatty acid salt, palm kernel oil fatty acid salt, hardened palm kernel oil fatty acid salt, beef tallow fatty acid salt, and hardened beef tallow fatty acid salt.
  • the content of the fatty acid salt of the component (A) is 1% by mass to 7% by mass with respect to the total amount of the liquid detergent composition, and is foaming, bactericidal against E. coli, rinsing properties, and skin irritation. Therefore, 4% by mass to 6% by mass is preferable. When the content is less than 1% by mass, foaming may be deteriorated or the bactericidal power against E. coli may be reduced. When the content exceeds 7% by mass, rinsing properties and skin irritation may be deteriorated. .
  • the content of the component (A 1 ) is not particularly limited and may be appropriately selected depending on the intended purpose, but is preferably 0.3% by mass to 6% by mass with respect to the total amount of the liquid detergent composition.
  • the content of the component (A 2 ) is not particularly limited and may be appropriately selected depending on the intended purpose, but is preferably 0.1% by mass to 5% by mass with respect to the total amount of the liquid detergent composition. 0.5 mass% to 3 mass% is more preferable. When the content is less than 0.1% by mass, foaming and bactericidal activity against E. coli may be deteriorated. When the content is more than 5% by mass, rinsing properties may be deteriorated.
  • the fatty acid salt of the component (A) is not particularly limited and can be blended as a fatty acid salt, but the fatty acid and potassium hydroxide, triethanolamine, or monoethanolamine are blended separately. It is good also as a fatty-acid salt by adding in a tank and making it neutralize.
  • alkylaminocarboxylic acid type amphoteric surfactant As the amino acid type amphoteric surfactant of the component (B), an alkylaminomonocarboxylic acid type amphoteric surfactant represented by the following general formula (I) and an alkylamino dicarboxylic acid represented by the following general formula (II) At least one selected from acid type surfactants is preferred.
  • R 2 —NH (CH 2 ) k COOM 2
  • R 2 is any of a linear or branched alkyl group, alkenyl group, and hydroxyalkyl group having 6 to 22 carbon atoms.
  • k represents an integer of 1 to 4.
  • M 2 represents at least one selected from a hydrogen atom, an alkali metal, ammonium, and a mono-, di-, or trialkanolamine having an alkanol group having 2 to 3 carbon atoms.
  • R 3 is any one of a linear or branched alkyl group, alkenyl group, and hydroxyalkyl group having 6 to 22 carbon atoms.
  • m and n represent an integer of 1 to 4, and may be the same or different from each other.
  • M 3 and M 4 represent one selected from a hydrogen atom, an alkali metal, ammonium, and a mono-, di- or trialkanolamine having an alkanol group having 2 to 3 carbon atoms, and the M 3 and the M 4 are They may be the same or different from each other.
  • R 2 and R 3 are any of a linear or branched alkyl group, alkenyl group, and hydroxyalkyl group having 6 to 22 carbon atoms. .
  • the carbon number is preferably 10-16.
  • Examples of the alkyl group include octyl group, nonyl group, decyl group, undecyl group, lauryl group, tridecyl group, myristyl group, pentadecyl group, palmityl group, stearyl group, isostearyl group, nonadecyl group, eicosyl group, and the like. Can be mentioned.
  • alkenyl group examples include a tetradecenyl group, a hexadecenyl group, an octadecenyl group, an isooctadecenyl group, an eicocenyl group, and the like.
  • a lauryl group, a myristyl group, a palmityl group, and a stearyl group are preferable, and a lauryl group is more preferable from the point of foaming and foam creamy property.
  • examples of the alkali metal include lithium, sodium, and potassium.
  • examples of the mono-, di- or trialkanol amine having an alkanol group having 2 to 3 carbon atoms include monoethanolamine, diethanolamine, and triethanolamine. Among these, sodium, potassium, and triethanolamine are particularly preferable.
  • the alkylaminomonocarboxylic acid type amphoteric surfactant represented by the general formula (I) is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include sodium laurylaminoacetate and laurylaminopropionic acid. Examples include sodium, potassium laurylaminopropionate, sodium myristylaminopropionate, potassium myristylaminopropionate, triethanolamine laurylaminopropionate, and the like. These may be used individually by 1 type and may use 2 or more types together.
  • the alkylaminodicarboxylic acid type surfactant represented by the general formula (II) is not particularly limited and may be appropriately selected depending on the intended purpose.
  • laurylaminodiacetate triethanolamine laurylaminodioxide Potassium acetate
  • sodium myristylaminodiacetate potassium myristylaminodiacetate
  • sodium palmitylaminodiacetate potassium palmitylaminodiacetate
  • sodium stearylaminodiacetate potassium stearylaminodiacetate
  • potassium laurylaminodipropionate myristylamino Sodium dipropionate
  • potassium myristylaminodipropionate sodium palmitylaminodipropionate
  • potassium palmitylaminodipropionate sodium stearylaminodipropionate
  • stearylamino Potassium dipropionate acid may be used individually by 1 type and may use 2 or more types together.
  • alkylaminocarboxylic acid type amphoteric surfactant of the component (B) sodium laurylaminodipropionate, sodium laurylaminodiacetate, potassium laurylaminodipropionate from the viewpoint of pH stability and bactericidal activity against E. coli , Potassium laurylaminodiacetate and sodium laurylaminopropionate are preferable, and sodium laurylaminodipropionate and sodium laurylaminodiacetate are particularly preferable.
  • alkylaminocarboxylic acid type amphoteric surfactant of the component (B) those appropriately synthesized may be used, or commercially available products may be used.
  • the content of the alkylaminocarboxylic acid type amphoteric surfactant as the component (B) is not particularly limited and may be appropriately selected depending on the intended purpose. It is preferably 4% by mass to 6% by mass, and more preferably 1% by mass to 4% by mass from the viewpoints of foaming, foam creaminess, bactericidal power against E. coli, rinsing properties, pH stability, and skin irritation. When the content is less than 0.4% by mass, foaming may be deteriorated, and the bactericidal activity against E. coli and pH stability may be lowered. When the content exceeds 6% by mass, rinsing properties and foam creamy properties are obtained. May be worse and skin irritation may increase.
  • the mass ratio (A / B) of the content of the fatty acid salt of the component (A) and the content of the alkylaminocarboxylic acid type amphoteric surfactant of the component (B) is 1 to 9, and From the viewpoint of bactericidal power, pH stability, foaming, foam creaminess, and rinsing properties, 1.3 to 5 is preferable. If the mass ratio (A / B) is less than 1, the sterilizing power against E. coli may be reduced, or the creamy property, rinsing property and foaming of the foam may be deteriorated. The force may decrease and the pH stability may deteriorate.
  • the chelating agent for component (C) is not particularly limited as long as it has the ability to chelate metal ions, and can be appropriately selected according to the purpose.
  • aminopolycarboxylic acid chelating agents aromatics Aliphatic or aliphatic carboxylic acid chelating agents, amino acid chelating agents, ether polycarboxylic acid chelating agents, phosphonic acid chelating agents, hydroxycarboxylic acid chelating agents, phosphoric acid chelating agents, polymer electrolytes (including oligomer electrolytes) )
  • Type chelating agent dimethylglyoxime (DG), other chelating agents and the like.
  • Each of these chelating agents may be a free acid form, a salt such as a sodium salt, a potassium salt, or an ammonium salt, or may be a hydrolyzable ester derivative. These may be used individually by 1 type and may use 2 or more types together.
  • aminopolycarboxylic acid chelating agent examples include ethylenediaminetetraacetic acid (EDTA), cyclohexanediaminetetraacetic acid (CDTA), nitrilotriacetic acid (NTA), iminodiacetic acid (IDA), and N- (2-hydroxyethyl) iminodiacetic acid.
  • EDTA ethylenediaminetetraacetic acid
  • CDTA cyclohexanediaminetetraacetic acid
  • NTA nitrilotriacetic acid
  • IDA iminodiacetic acid
  • GEDTA glycol etherdiaminetetraacetic acid
  • aromatic or aliphatic carboxylic acid chelating agent examples include oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, itaconic acid, aconitic acid, pyruvic acid, salicylic acid, fumaric acid, acetylsalicylic acid, hydroxybenzoic acid.
  • examples thereof include acids, aminobenzoic acid (including anthranilic acid), phthalic acid, trimellitic acid, gallic acid, or salts thereof, methyl esters or ethyl esters.
  • the amino acid chelating agent examples include glycine, serine, alanine, lysine, cystine, cysteine, ethionine, tyrosine, methionine, or salts or derivatives thereof.
  • ether polycarboxylic acid chelating agent examples include diglycolic acid, a compound represented by the following general formula (A), an analogous compound thereof or a salt thereof (for example, alkali metal salts such as sodium and potassium, ammonium salts).
  • alkali metal salts such as sodium and potassium, ammonium salts.
  • sodium is more preferable from the viewpoint of solubility.
  • Examples of the phosphonic acid-based chelating agent include iminodimethylphosphonic acid (IDP), alkyldiphosphonic acid (ADPA), 1-hydroxyethane-1,1-diphosphonic acid (eg, DEQUEST TM 2010, manufactured by Solutia Co.). Etc.
  • IDP iminodimethylphosphonic acid
  • ADPA alkyldiphosphonic acid
  • 1-hydroxyethane-1,1-diphosphonic acid eg, DEQUEST TM 2010, manufactured by Solutia Co.
  • Examples of the hydroxycarboxylic acid chelating agent include malic acid, glycolic acid, gluconic acid, heptonic acid, tartaric acid, lactic acid, or salts thereof.
  • Examples of the phosphoric acid chelating agent include orthophosphoric acid, pyrophosphoric acid, triphosphoric acid, and polyphosphoric acid.
  • polymer electrolyte (including oligomer electrolyte) chelating agent examples include acrylic acid polymer, maleic anhydride polymer, ⁇ -hydroxyacrylic acid polymer, itaconic acid polymer, or constituent monomers of these polymers. Or a copolymer composed of two or more of these, or an epoxy succinic acid polymer.
  • Examples of the other chelating agents include ascorbic acid, thioglycolic acid, phytic acid, glyoxylic acid, glyoxalic acid, and salts thereof.
  • EDTA ethylenediaminetetraacetic acid
  • CDTA cyclohexanediaminetetraacetic acid
  • 1-hydroxyethane-1,1-diphosphone from the viewpoint of bactericidal power against E. coli, foaming and rinsing properties.
  • Acid DEQUEST TM 2010, manufactured by Solutia Co.
  • oxalic acid or a salt thereof is preferable. From the viewpoint of bactericidal activity against E.
  • EDTA ethylenediaminetetraacetic acid
  • CDTA cyclohexanediaminetetraacetic acid
  • DEQUEST TM 2010, manufactured by Solutia Co. 1-hydroxyethane- 1,1-diphosphonic acid
  • a salt thereof is particularly preferable.
  • the chelating agent for the component (C) an appropriately synthesized product or a commercially available product may be used.
  • the content of the chelating agent of the component (C) is not particularly limited and may be appropriately selected depending on the intended purpose, but is 0.01% by mass to 1% by mass with respect to the total amount of the liquid cleaning composition. From the viewpoint of bactericidal power against E. coli, foaming, and rinsing properties, 0.05 mass% to 0.2 mass% is more preferable. When the content is less than 0.01% by mass, the bactericidal power against E. coli may be reduced or foaming may be deteriorated. When the content exceeds 1% by mass, the rinsing property may be deteriorated.
  • the mass ratio (A / C) between the content of the fatty acid salt represented by the general formula of the component (A) and the content of the chelating agent of the component (C) is not particularly limited and depends on the purpose. 5 to 150 is preferable, and 30 to 100 is more preferable from the viewpoint of bactericidal activity against E. coli and rinsing properties. When the mass ratio (A / C) is less than 5, the rinsing property may be deteriorated. When the mass ratio (A / C) is more than 150, the bactericidal power against Escherichia coli may be reduced or foaming may be deteriorated.
  • the polyhydric alcohol as the component (D) is not particularly limited as long as it is a dihydric to hexahydric alcohol, and can be appropriately selected according to the purpose.
  • ethylene glycol, diethylene glycol, polyethylene glycol 200 (average Molecular weight 190-210), polyethylene glycol 300 (average molecular weight 280-320), polyethylene glycol 400 (average molecular weight 380-420), polyethylene glycol 600 (average molecular weight 570-630), propylene glycol, dipropylene glycol, 1,3- Examples include butylene glycol, isopentyl diol, pentylene glycol, 1,2-hexanediol, hexylene glycol, glycerin, diglycerin, sorbit, xylitol, and mannitol.
  • 1,3-butylene glycol, dipropylene glycol, propylene glycol, glycerin, and sorbit are preferable, and propylene glycol, glycerin, and sorbit are particularly preferable in terms of foam creaminess and skin irritation.
  • the polyhydric alcohol of the component (D) an appropriately synthesized product or a commercially available product may be used.
  • the average molecular weight of the polyethylene glycol indicates the average molecular weight described in the quasi-drug raw material standard 2006, and depending on the product, for example, polyethylene glycol # 200, there is a # between the polyethylene glycol and the numerical value. There is a case.
  • the content of the polyhydric alcohol as the component (D) is not particularly limited and may be appropriately selected depending on the intended purpose, but is 1% by mass to 30% by mass with respect to the total amount of the liquid detergent composition. Preferably, 5% by mass to 20% by mass is more preferable from the viewpoint of creaminess, rinsing properties and skin irritation of the foam. If the content is less than 1% by mass, the creaminess and skin irritation of the foam may decrease, and if it exceeds 30% by mass, the rinsing property and foaming may be deteriorated.
  • the pH of the liquid detergent composition of the present invention is not particularly limited and may be appropriately selected depending on the intended purpose. From the viewpoint of skin irritation and low temperature stability, 9.5 to 11 at 25 ° C. Is preferred. When the pH is less than 9.5, the low-temperature stability and the discharging ability from the former pump may be deteriorated. When the pH is more than 11, the skin irritation may be increased.
  • the pH can be measured, for example, according to a cosmetic raw material standard general test method pH measurement method.
  • the said (A) component, the said (B) component, and the said (C) component Preferably Can be obtained by mixing the component (D) and, if necessary, the other components.
  • the water in the other components is preferably blended as the remainder so that the total amount of the liquid detergent composition is 100% by mass.
  • the liquid detergent composition may be prepared using an apparatus.
  • limiting in particular as said apparatus According to the objective, it can select suitably, For example, there exists a shearing force and the stirring apparatus provided with the stirring blade which can mix the whole etc. are mentioned.
  • limiting in particular as said stirring blade According to the objective, it can select suitably, For example, a propeller, a turbine, a disper, etc. are mentioned.
  • the liquid detergent composition of the present invention may be filled in a squeeze container, a pump container, or a former container.
  • the former container include a non-gas type foam discharge container.
  • the non-gas type foam discharge container is not particularly limited as long as the liquid cleaning material can be mixed with air and discharged in a foamed state, and can be appropriately selected according to the purpose.
  • Examples thereof include a squeeze foamer container capable of discharging bubbles by squeezing by hand, and a pump former container capable of discharging bubbles by depressing a nozzle part.
  • a former container for example, a commercial product manufactured by Yamato Seikan Co., Ltd. or Yoshino Kogyo Co., Ltd. can be used.
  • the non-gas type foam discharge container usually has a porous film body for forming bubbles (the material is preferably a plastic material such as nylon, polyester, polyolefin, etc.), and the liquid detergent composition is a porous film body. Passing through, bubbles are formed.
  • the mesh (mesh) of the porous membrane is not particularly limited and may be appropriately selected depending on the intended purpose, but is preferably 100 mesh or more, more preferably 100 mesh to 400 mesh, and more preferably 200 mesh to 350 mesh. A mesh is more preferred.
  • the number of the porous membranes is not particularly limited and may be appropriately selected according to the purpose. However, from the viewpoint of improving the bubble performance, 2 to 4 sheets are preferable. More specifically, as the former container, those described in JP-A-7-315463, JP-A-8-230961, and JP-A-2005-193972 can be suitably used.
  • the viscosity of the liquid detergent composition is: There is no particular limitation, and it can be appropriately selected according to the purpose, but it is preferably 15 mPa ⁇ s or less at 25 ° C., more preferably 1 mPa ⁇ s to 10 mPa ⁇ s.
  • the viscosity can be measured by, for example, a BL type viscometer (rotor No. 1, 60 rpm, 1 minute later, manufactured by Tokyo Keiki Co., Ltd.).
  • the shape and dosage form of the liquid detergent composition of the present invention are not particularly limited, and can be appropriately selected depending on the purpose.
  • various types such as liquid, cream, lotion and foam It can be prepared and used in properties and dosage forms, and can be prepared according to conventional methods for each dosage form.
  • the liquid detergent composition of the present invention includes, for example, hair detergents such as shampoos and rinse-in shampoos, body soaps, hand soaps, foam hand soaps, skin cleansers such as cleansing foams, kitchen detergents, clothing detergents, etc.
  • hair detergents such as shampoos and rinse-in shampoos
  • body soaps such as shampoos and rinse-in shampoos
  • hand soaps such as shampoos and rinse-in shampoos
  • foam hand soaps such as cleansing foams, kitchen detergents, clothing detergents, etc.
  • skin cleansing agents such as body soaps, hand soaps, foam hand soaps, and cleansing foams are particularly preferable from the viewpoint of bactericidal activity against E. coli. They can be used according to conventional methods at normal dosages of the product.
  • a liquid detergent composition (hand soap) was prepared as follows. First, purification of a mass corresponding to 95% of the predetermined amount of (A) component, (B) component, and (C) component shown in Table 1 to Table 10, and (D) component if necessary Water was weighed into a heat-resistant container. (A) component, (B) component, (C) component, and (D) component were dissolved uniformly as needed, the common component was added, and it stirred until it became uniform. Subsequently, potassium hydroxide (48% by mass solution) or citric acid was gradually added while measuring the pH using a pH meter to adjust the pH.
  • E. coli Escherichia coli NBRC 3972 (obtained from National Institute of Technology and Evaluation (NBRC))
  • Test liquid A solution obtained by diluting each liquid detergent composition (hand soap) obtained 6 times with hard water 3 times was used as a test liquid.
  • the bactericidal power was calculated from the initial bacterial count and the viable bacterial count, and the bactericidal effect was evaluated according to the following criteria.
  • sterilizing power represents that sterilizing power is so high that a numerical value is large.
  • Bactericidal power -log 10 (number of surviving bacteria / number of first bacteria) ⁇ Evaluation criteria ⁇
  • Bactericidal power Bactericidal power is 0.5 or more and less than 1
  • Bactericidal power is less than 0.5
  • ⁇ PH stability> A hard transparent glass bottle with a lid of 8 cm in height and 3 cm in diameter (capacity 55 mL) was filled with 50 mL of each of the liquid detergent compositions of Examples and Comparative Examples and stored in an environment of 50 ° C. for 4 weeks, and then a pH meter (Toa PH was measured at 25 ° C. using a DK Corporation model (HM-30R) and evaluated based on the following criteria.
  • Creamy property of foam >> The creaminess of the foam was evaluated by the following criteria by collecting the foam remaining in the hand after rubbing 20 reciprocations with both hands. ⁇ Evaluation criteria ⁇ 5 points: Large bubbles are not recognized with fine bubbles. 4 points: Large bubbles are slightly mixed in fine bubbles. 3 points: Large bubbles are slightly mixed in fine bubbles. 2 points: Large bubbles are mixed in fine bubbles. 1 point: There is no fine bubble and it is a large rough bubble [Criteria for rating average value] ⁇ : 4.5 points or more ⁇ ⁇ ⁇ : 4.0 points or more and less than 4.5 points ⁇ : 3.5 points or more and less than 4.0 points ⁇ : 3.0 points or more and less than 3.5 points ⁇ : 3.0 Less than
  • Example 43 Liquid detergent composition in foam container (foam body soap)-
  • the liquid cleaning composition shown below is manufactured according to a conventional method, and a pump former container capable of discharging bubbles by pushing down a non-gas type nozzle (using two 200 mesh (75 ⁇ m), manufactured by Yoshino Kogyo Co., Ltd.) And was evaluated in the same manner as in Example 1 using 10 mL of body soap. The results are shown below.
  • Potassium laurate (A 1 ) 5.0% by mass Potassium myristate (A 2 ) 1.0% by mass Sodium laurylaminodiacetate (B) 2.0% by mass Ethylenediaminetetraacetic acid (C) 0.1% by mass 1-hydroxyethane-1,1-diphosphonic acid (C) 0.1% by mass Glycerin (D) 7.0% by mass Sorbit (D) 3.0% by mass Isopropyl methylphenol 0.1% by mass Styrene polymer emulsion 0.4% by mass Perfume Small amount Dye Suitable amount Potassium hydroxide or citric acid Adjusted amount to pH 10 Purified water remaining Total 100% by mass The mass ratio (A 1 / A 2): 5 Mass ratio (A / B): 3 Mass ratio (A / C): 30 Bactericidal power against E. coli ⁇ pH stability: ⁇ Foaming: ⁇ Creamy properties of foam: ⁇ Skin irritation: ⁇ Rinsing property: ⁇
  • Example 44 Liquid detergent composition in foam container (foam hand soap)-
  • the liquid detergent composition shown below is manufactured according to a conventional method, and filled into a pump former container (using two 200 mesh, manufactured by Yoshino Kogyo Co., Ltd.) capable of discharging foam by pushing down the non-gas type nozzle. Evaluation was performed in the same manner as in Example 1 using 2 mL of hand soap. The results are shown below.
  • Example 45 Liquid detergent composition (hand soap)-
  • the liquid cleaning composition shown below is produced according to a conventional method, filled in a container with a pump dispenser (discharge amount 1 mL, nozzle diameter 3.5 mm, manufactured by Canyon), and using 2 mL, the same as in Example 1 And evaluated. The results are shown below.
  • the liquid detergent composition of the present invention includes, for example, hair detergents such as shampoos and rinse-in shampoos, body soaps, hand soaps, foam hand soaps, skin detergents such as cleansing foams, kitchen detergents, clothing detergents, etc. Can be used widely.
  • hair detergents such as shampoos and rinse-in shampoos
  • body soaps hand soaps
  • foam hand soaps foam hand soaps
  • skin detergents such as cleansing foams, kitchen detergents, clothing detergents, etc. Can be used widely.
  • a fatty acid salt represented by the following general formula (1), R 1 COOM General formula (1) (In the general formula (1), R 1 represents a monovalent hydrocarbon group having 5 to 25 carbon atoms, and M represents any one of an alkali metal, ammonium, an alkanolamine, and a basic amino acid.) ) (B) an alkylaminocarboxylic acid type amphoteric surfactant, and (C) a chelating agent, Wherein component (A), the general formula (1) R 1 in the fatty acid salt is a monovalent hydrocarbon group having 5 to 12 carbon atoms (A 1), R 1 carbon atoms in the general formula (1) A fatty acid salt (A 2 ) that is a monovalent hydrocarbon group of 13 to 25, and a mass ratio (A 1 / A 2 ) of the (A 1 ) component to the (A 2 ) component is 0.8.
  • a mass ratio (A / B) of the component (A) to the component (B) is 1 to 9.
  • the content of the component (C) is 0.01% by mass to 1% by mass, and the mass ratio (A / C) of the component (A) to the component (C) is 5 to 150
  • ⁇ 4> The liquid cleaning agent according to any one of ⁇ 1> to ⁇ 3>, wherein the content of the alkylaminocarboxylic acid type amphoteric surfactant as component (B) is 0.4% by mass to 6% by mass. It is a composition.
  • ⁇ 5> The liquid cleaning composition according to any one of ⁇ 1> to ⁇ 4>, further comprising (D) a polyhydric alcohol.
  • ⁇ 6> The liquid detergent composition according to any one of ⁇ 1> to ⁇ 5>, which is filled in a former container.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Epidemiology (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Birds (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Dermatology (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention se rapporte à une composition détergente liquide qui contient (A) de 1 à 7% en masse d'un sel d'acide gras qui est représenté par la formule générale R1COOM (dans laquelle R1 représente un groupe hydrocarbure monovalent ayant de 5 à 25 atomes de carbone et M représente un métal alcalin, de l'ammonium, de l'alcanol amine ou de l'acide aminé basique), (B) un tensioactif amphotère à base d'acide carboxylique alkylamino et (C) un agent de chélation. Le composant (A) contient (A1) un sel d'acide gras représenté par la formule générale mentionnée ci-dessus dans laquelle R1 est un groupe hydrocarbure monovalent ayant de 5 à 12 atomes de carbone et (A2) un sel d'acide gras représenté par la formule générale ci-dessus mentionnée dans laquelle R1 est un groupe hydrocarboné monovalent ayant 13 à 25 atomes de carbone. Le rapport en masse du composant (A1) au composant (A2), à savoir Al/A2 est de 0,8 à 20. Le rapport en masse du composant (A) au composant B), à savoir A/B est 1 à 9.
PCT/JP2013/057059 2012-03-19 2013-03-13 Composition détergente liquide WO2013141118A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2014506169A JP6013454B2 (ja) 2012-03-19 2013-03-13 液体洗浄剤組成物
KR1020147020562A KR101876272B1 (ko) 2012-03-19 2013-03-13 액체 세정제 조성물
PH12014502080A PH12014502080A1 (en) 2012-03-19 2014-09-22 Liquid detergent composition

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2012062170 2012-03-19
JP2012-062170 2012-03-19

Publications (1)

Publication Number Publication Date
WO2013141118A1 true WO2013141118A1 (fr) 2013-09-26

Family

ID=49222578

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2013/057059 WO2013141118A1 (fr) 2012-03-19 2013-03-13 Composition détergente liquide

Country Status (5)

Country Link
JP (1) JP6013454B2 (fr)
KR (1) KR101876272B1 (fr)
MY (1) MY167787A (fr)
PH (1) PH12014502080A1 (fr)
WO (1) WO2013141118A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014208633A (ja) * 2013-03-29 2014-11-06 ライオン株式会社 フォーマー容器入り皮膚洗浄剤組成物
WO2015068728A1 (fr) * 2013-11-07 2015-05-14 ホーユー株式会社 Composition cosmétique capillaire
JP2021066793A (ja) * 2019-10-23 2021-04-30 株式会社 資生堂 洗浄剤組成物及び洗浄剤製品
JP2021169413A (ja) * 2020-04-14 2021-10-28 東洋ビューティ株式会社 身体洗浄剤

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09227359A (ja) * 1996-02-26 1997-09-02 Tsumura & Co 皮膚用液体洗浄剤組成物
JP2001172686A (ja) * 1999-12-14 2001-06-26 Lion Corp 洗浄剤組成物
JP2001172668A (ja) * 1999-12-14 2001-06-26 Lion Corp 洗浄剤組成物
JP2005306843A (ja) * 2004-03-25 2005-11-04 Kose Corp 皮膚洗浄剤組成物
JP2006096699A (ja) * 2004-09-29 2006-04-13 Nof Corp 泡状洗浄剤組成物
JP2007223951A (ja) * 2006-02-23 2007-09-06 Nof Corp 身体用液状洗浄剤組成物
WO2007145054A1 (fr) * 2006-06-12 2007-12-21 Lion Corporation Composition détergente liquide à conditionner dans des récipients pour agent moussant
JP2011190376A (ja) * 2010-03-16 2011-09-29 Lion Corp 浴室用洗浄剤組成物
JP2012131951A (ja) * 2010-12-24 2012-07-12 Lion Corp 液体洗浄剤製品

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US542681A (en) * 1895-07-16 lytle
GB9323306D0 (en) * 1993-11-11 1994-01-05 Procter & Gamble Cleansing compositions
JP3441261B2 (ja) * 1994-09-20 2003-08-25 花王株式会社 水性液体洗浄剤
JP3620140B2 (ja) * 1996-02-26 2005-02-16 株式会社ツムラ 皮膚用液体洗浄剤組成物
JPH10147793A (ja) * 1996-11-15 1998-06-02 Kao Corp 洗浄剤組成物
JP3018158B2 (ja) * 1996-12-27 2000-03-13 花王株式会社 洗浄剤組成物
JP2002161028A (ja) * 2000-11-28 2002-06-04 Kose Corp 洗浄剤組成物
JP2002348217A (ja) * 2001-03-23 2002-12-04 Matsumoto Yushi Seiyaku Co Ltd 化粧品用滑り剤とそれを用いた清浄用化粧品
MXPA04003543A (es) * 2001-10-18 2004-07-22 Procter & Gamble Composiciones de champu con surfactantes anionicos, surfactantes anfoteros y polimeros cationicos.
JP2006036655A (ja) * 2004-07-23 2006-02-09 Fancl Corp Ｄｆａ含有刺激緩和剤
JP2006056837A (ja) * 2004-08-20 2006-03-02 Sanyu:Kk マイナスイオン発生セラミック物質を含有する化粧料
JP2006083140A (ja) * 2004-09-17 2006-03-30 Lion Corp 皮膚洗浄剤組成物
EP2380955A1 (fr) * 2008-12-22 2011-10-26 Lion Corporation Composition de nettoyant, son procédé de fabrication, composé amphiphile et composition

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09227359A (ja) * 1996-02-26 1997-09-02 Tsumura & Co 皮膚用液体洗浄剤組成物
JP2001172686A (ja) * 1999-12-14 2001-06-26 Lion Corp 洗浄剤組成物
JP2001172668A (ja) * 1999-12-14 2001-06-26 Lion Corp 洗浄剤組成物
JP2005306843A (ja) * 2004-03-25 2005-11-04 Kose Corp 皮膚洗浄剤組成物
JP2006096699A (ja) * 2004-09-29 2006-04-13 Nof Corp 泡状洗浄剤組成物
JP2007223951A (ja) * 2006-02-23 2007-09-06 Nof Corp 身体用液状洗浄剤組成物
WO2007145054A1 (fr) * 2006-06-12 2007-12-21 Lion Corporation Composition détergente liquide à conditionner dans des récipients pour agent moussant
JP2011190376A (ja) * 2010-03-16 2011-09-29 Lion Corp 浴室用洗浄剤組成物
JP2012131951A (ja) * 2010-12-24 2012-07-12 Lion Corp 液体洗浄剤製品

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014208633A (ja) * 2013-03-29 2014-11-06 ライオン株式会社 フォーマー容器入り皮膚洗浄剤組成物
WO2015068728A1 (fr) * 2013-11-07 2015-05-14 ホーユー株式会社 Composition cosmétique capillaire
JP2021066793A (ja) * 2019-10-23 2021-04-30 株式会社 資生堂 洗浄剤組成物及び洗浄剤製品
JP7359637B2 (ja) 2019-10-23 2023-10-11 株式会社 資生堂 洗浄剤組成物及び洗浄剤製品
JP2021169413A (ja) * 2020-04-14 2021-10-28 東洋ビューティ株式会社 身体洗浄剤

Also Published As

Publication number Publication date
PH12014502080A1 (en) 2014-12-10
JP6013454B2 (ja) 2016-10-25
KR101876272B1 (ko) 2018-07-09
KR20140138606A (ko) 2014-12-04
MY167787A (en) 2018-09-26
JPWO2013141118A1 (ja) 2015-08-03

Similar Documents

Publication Publication Date Title
KR102144496B1 (ko) 액체 피부 세정제 제품
TWI262213B (en) Cleaning agent composition
JP2010150315A (ja) 界面活性剤組成物
JP6203539B2 (ja) 皮膚洗浄剤組成物
JP2013095898A (ja) 液体洗浄剤組成物
JP5838816B2 (ja) 液体皮膚洗浄剤製品
TWI605831B (zh) Detergent composition
KR101876272B1 (ko) 액체 세정제 조성물
JP2012153627A (ja) 皮膚洗浄剤組成物
JP6653751B2 (ja) 洗浄剤組成物及びその製造方法
JP2015107927A (ja) 液体洗浄剤組成物
JP5969311B2 (ja) 液体洗浄剤組成物
JP2014208633A (ja) フォーマー容器入り皮膚洗浄剤組成物
JP2008137943A (ja) 液体身体洗浄剤組成物
JP7236314B2 (ja) 液体皮膚洗浄剤組成物
JP5536086B2 (ja) 液体皮膚洗浄剤組成物
WO2004029190A1 (fr) Nouveau tensioactif et utilisation de celui-ci
JP6237173B2 (ja) 液体洗浄剤組成物
US20190336406A1 (en) Article for skin cleansing agent
JP6534382B2 (ja) フォーマー容器入り液体洗浄剤組成物
JP2013067610A (ja) 皮膚洗浄剤組成物
JP2008179543A (ja) 皮膚洗浄剤組成物
JP6234705B2 (ja) 液体皮膚洗浄剤組成物
WO2023276272A1 (fr) Composition liquide de nettoyant pour la peau
JP2022047734A (ja) 皮膚洗浄剤組成物

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 13764874

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 20147020562

Country of ref document: KR

Kind code of ref document: A

ENP Entry into the national phase

Ref document number: 2014506169

Country of ref document: JP

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 13764874

Country of ref document: EP

Kind code of ref document: A1