JP2010150315A - 界面活性剤組成物 - Google Patents
界面活性剤組成物 Download PDFInfo
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- JP2010150315A JP2010150315A JP2008327293A JP2008327293A JP2010150315A JP 2010150315 A JP2010150315 A JP 2010150315A JP 2008327293 A JP2008327293 A JP 2008327293A JP 2008327293 A JP2008327293 A JP 2008327293A JP 2010150315 A JP2010150315 A JP 2010150315A
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- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000004491 isohexyl group Chemical group C(CCC(C)C)* 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229940050906 magnesium chloride hexahydrate Drugs 0.000 description 1
- DHRRIBDTHFBPNG-UHFFFAOYSA-L magnesium dichloride hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[Cl-].[Cl-] DHRRIBDTHFBPNG-UHFFFAOYSA-L 0.000 description 1
- 229940091250 magnesium supplement Drugs 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229950001046 piroctone Drugs 0.000 description 1
- BTSZTGGZJQFALU-UHFFFAOYSA-N piroctone olamine Chemical compound NCCO.CC(C)(C)CC(C)CC1=CC(C)=CC(=O)N1O BTSZTGGZJQFALU-UHFFFAOYSA-N 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229960003504 silicones Drugs 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
- 229940082004 sodium laurate Drugs 0.000 description 1
- 229940045845 sodium myristate Drugs 0.000 description 1
- 229940045870 sodium palmitate Drugs 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 description 1
- GGXKEBACDBNFAF-UHFFFAOYSA-M sodium;hexadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCC([O-])=O GGXKEBACDBNFAF-UHFFFAOYSA-M 0.000 description 1
- JUQGWKYSEXPRGL-UHFFFAOYSA-M sodium;tetradecanoate Chemical compound [Na+].CCCCCCCCCCCCCC([O-])=O JUQGWKYSEXPRGL-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- TYLSDQJYPYQCRK-UHFFFAOYSA-N sulfo 4-amino-4-oxobutanoate Chemical compound NC(=O)CCC(=O)OS(O)(=O)=O TYLSDQJYPYQCRK-UHFFFAOYSA-N 0.000 description 1
- HIFJUMGIHIZEPX-UHFFFAOYSA-N sulfuric acid;sulfur trioxide Chemical compound O=S(=O)=O.OS(O)(=O)=O HIFJUMGIHIZEPX-UHFFFAOYSA-N 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229960003500 triclosan Drugs 0.000 description 1
- XWNXEWLCHSLQOI-UHFFFAOYSA-K trisodium;triacetate Chemical compound [Na+].[Na+].[Na+].CC([O-])=O.CC([O-])=O.CC([O-])=O XWNXEWLCHSLQOI-UHFFFAOYSA-K 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 229940043810 zinc pyrithione Drugs 0.000 description 1
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0094—High foaming compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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Abstract
【解決手段】次の成分(A)、(B)及び(C)を含有し、成分(A)の含有量が40重量%以上である界面活性剤組成物。
(A):下記一般式(1)で表される硫酸塩型界面活性剤
R1O−(PO)m(EO)nSO3M (1)
(式中、R1は炭化水素基を示し、POはプロピレンオキシ基を、EOはエチレンオキシ基を示し、m、nは0<m<1、0<n<5の範囲の数を示し、Mは陽イオンを示す。)
(B):下記(B−1)及び(B−2)からなる群から選ばれる1種以上の化合物
(B−1)下記一般式(2)
R2O−(AO)t−R3 (2)
(式中、R2はアルキル基又はアルケニル基を示し、AOはアルキレンオキシ基を示し、平均付加モル数tは0.5〜4.0の数を示し、R3は水素原子又はメチル基を示す。)で表されるアルコールのアルキレンオキシド付加物
(B−2)モノアルキル(炭素数6〜18)又はモノアルケニル(炭素数6〜18)グリセリルエーテル
(C):水溶性塩類
【選択図】なし
Description
この問題を解決するために、特許文献1では、(a)ポリオキシエチレンアルキルエーテル硫酸塩又はアルキルエーテル硫酸塩に(b)炭素数4〜24のアルキル基またはアルケニル基を有する1種以上のグリセリルエーテル又はジグリセリルエーテル及び(c)水溶性塩類を組み合わせ、成分(a)の含有量が40重量%以上である、界面活性剤組成物が提案されている。
また、特許文献2では、(a)ポリオキシエチレンアルキルエーテル硫酸塩又はアルキル硫酸塩に(b‘)R2O−(AO)m−R3で表されるアルコールのアルキレンオキシド付加物と(c)水溶性塩類を組み合わせ、成分(a)の含有量が40重量%以上である界面活性剤組成物が提案されている。
従って、本発明は、低温(5℃)で長期保存後の流動性や希釈時の起泡性に優れる界面活性剤組成物を提供することを課題とする。
(A):下記一般式(1)で表される硫酸塩型界面活性剤
R1O−(PO)m(EO)nSO3M (1)
(式中、R1は炭素数8〜18の飽和又は不飽和の炭化水素基を示し、POはプロピレンオキシ基を、EOはエチレンオキシ基を示し、m、nは平均付加モル数を示し、同一又は異なって、0<m<1、0<n<5の範囲の数を示し、Mは陽イオンを示す。)
(B):下記(B−1)及び(B−2)からなる群から選ばれる1種以上の化合物
(B−1)下記一般式(2)で表されるアルコールのアルキレンオキシド付加物
R2O−(AO)t−R3 (2)
(式中、R2は炭素数8〜10の直鎖又は分岐鎖のアルキル基又はアルケニル基を示し、AOは炭素数2〜4のアルキレンオキシ基を示し、tはAOの平均付加モル数で、0.5〜4.0の数を示し、R3は水素原子又はメチル基を示す。)
(B−2)モノアルキル(炭素数6〜18)又はモノアルケニル(炭素数6〜18)グリセリルエーテル
(C):水溶性塩類
(A):下記一般式(1)で表される硫酸塩型界面活性剤
R1O−(PO)m(EO)nSO3M (1)
(式中、R1は炭素数8〜18の飽和又は不飽和の炭化水素基を示し、POはプロピレンオキシ基を、EOはエチレンオキシ基を示し、m、nは平均付加モル数を示し、同一又は異なって、0<m<1、0<n<5の範囲の数を示し、Mは陽イオンを示す。)
(B):下記(B−1)及び(B−2)からなる群から選ばれる1種以上の化合物
(B−1)下記一般式(2)で表されるアルコールのアルキレンオキシド付加物
R2O−(AO)t−R3 (2)
(式中、R2は炭素数8〜10の直鎖又は分岐鎖のアルキル基又はアルケニル基を示し、AOは炭素数2〜4のアルキレンオキシ基を示し、tはAOの平均付加モル数で、0.5〜4.0の数を示し、R3は水素原子又はメチル基を示す。)
(B−2)モノアルキル(炭素数6〜18)又はモノアルケニル(炭素数6〜18)グリセリルエーテル
(C):水溶性塩類
成分(A):
一般式(1)で表される硫酸塩型界面活性剤において、一般式(1)中のR1の飽和又は不飽和の炭化水素基の平均炭素数は8〜18であるが、8〜16が好ましく、より好ましくは10〜14であり、更に好ましくは12〜14である。更に、起泡力、泡のキメ細かさといった性能面から、R1は、油脂原料由来の直鎖アルキル基であることが好ましい。具体的には、オクチル基、デシル基、ラウリル基、ミリスチル基、セチル基、ステアリル基等が挙げられる。
工程(II):工程(I)で得られたプロピレンオキサイド付加物1モルに対し、エチレンオキサイドを平均で0モル超5モル未満の範囲で付加させる工程
工程(III):工程(II)で得られたアルコキシレートを硫酸化し、次いで中和する工程
R2O−(AO)t−R3 (2)
(式中、R2は炭素数8〜10の直鎖又は分岐鎖のアルキル基又はアルケニル基を示し、AOは炭素数2〜4のアルキレンオキシ基を示し、tはAOの平均付加モル数で、0.5〜4.0の数を示し、R3は水素原子又はメチル基を示す。)
一般式(2)の化合物において、起泡性の観点から、平均付加モル数tは0.5〜4.0の数を示すが、好ましくは1.0〜4.0、より好ましくは1.5〜3.0である。
一般式(2)中のR3は、水素原子又はメチル基を示すが、水素原子が好ましい。
)
ここで、アルキル基としては、例えばn−ブチル基、イソブチル基、tert−ブチル基、n−ペンチル基、イソペンチル基、n−ヘキシル基、イソヘキシル基、n−ヘプチル基、n−オクチル基、2−エチルヘキシル基、n−ノニル基、n−デシル基、イソデシル基、n−ラウリル基、n-イソステアリル等が挙げられる。泡質の改善の点から、分岐鎖が好ましく、モノ2−エチルヘキシルグリセリルエーテルが好ましい。
このような粘度を持つ組成物とするには、成分(A)に対して成分(B)及び成分(A)に対して成分(C)を、前記の範囲内にすればよい。
カチオン性界面活性剤としては、下記一般式
で表わされる第4級アンモニウム塩が挙げられる。
任意成分としては、コンディショニング成分として、ラウリルアルコール、ミリスチルアルコール、セチルアルコール、ステアリルアルコール等の高級アルコール、シリコーン及びシリコーン誘導体、ラノリン、スクワレン、炭化水素、蛋白誘導体、ポリエチレングリコールの脂肪酸エステル等の油剤、カチオン化セルロース、カチオン化グアガムやマーコート550(Nalco社製)等のカチオンポリマー、ソフケアKG-301W[花王(株)製]等のカチオン性基含有共重合体等が挙げられる。
本発明の洗浄剤組成物のpH(20℃)は4〜7が好ましく、5〜7が更に好ましい。
炭素数12のアルコール(花王(株)、製品名:カルコール2098)3447g、炭素数14のアルコール(花王(株)、製品名:カルコール4098)1341g、およびKOH6.8gを攪拌装置、温度制御装置、自動導入装置を備えたオートクレーブに仕込み、110℃、1.3kPaにて30分間脱水を行った。脱水後窒素置換を行い、120℃まで昇温した後、プロピレンオキサイドを575g仕込んだ。120℃にて付加反応・熟成を行った後、145℃に昇温し、エチレンオキサイドを1625g仕込んだ。145℃にて付加反応・熟成を行った後、80℃まで冷却し、4.0kPaで未反応のEOを除去した。未反応EO除去後、7.3gの酢酸をオートクレーブ内に加え、80℃で30分間攪拌した後、抜き出しを行い、POの平均付加モル数が0.4モル、EOの平均付加モル数が1.5モルであるアルコキシレートを得た。
同様にして硫酸塩型界面活性剤2〜6を得た。
表1、表2に示した硫酸塩型界面活性剤1〜6(純分70重量%)を用いて、表4〜6に示す界面活性剤組成物を下記の方法に従って調製し、下記評価方法により評価した。結果を表4〜6に示す。
調製方法:成分(A)、成分(B)とを、適量の水に溶解させた成分(C)とを混合し、合計が100重量部になるように、水で調整した。尚、pHは6.0(20℃)に水酸化ナトリウム又はクエン酸で調製した。
なお、表4〜6に示すアルキレングリコールエーテル1〜3は、表3に示すものである。
粘度の測定条件は次の通りである。
使用粘度計 B形粘度計((株)東京計器製)
ローターNo./回転数 No.4/6rpm 測定時間 1分間
温度30℃:30℃±1の恒温槽にサンプルの入ったガラス瓶を1時間つけた後測定した。
温度5℃:5℃±1の恒温器に1週間いれた後、取り出しすぐに測定した。
温度30℃:30℃±1の恒温槽にサンプルの入ったガラス瓶を1時間つけた後評価した。
温度5℃:5℃±1の恒温器に1週間いれた後、取り出しすぐに評価した。
(評価方法)
界面活性剤組成物の入ったガラスビンを90℃に傾け目視で評価した。
A:直ちに界面活性剤組成物が流れ出す。
B:ゆっくりと界面活性剤組成物が流れ出す。
C:界面活性剤組成物が流れ出さない。
成分(A)と成分(B)との合計量が15重量%になるように、イオン交換水で希釈して調製した界面活性剤組成物(20℃)を、手のひらに1ml取り、10mlの水道水(35〜40℃)で希釈し、手、腕を洗浄したときの起泡性を専門パネラー10名により下記の評価基準に従い、硫酸塩型界面活性剤1のみの15重量%に調整した界面活性剤組成物(20℃)を標準品として、比較評価した。
A:標準品と比べて、泡量が非常に多い。
B:標準品と比べて、泡量が多い。
C:標準品と同等の泡量。
D:標準品と比べて、泡量が少ない。
尚、表4、5の界面活性剤組成物は15重量%への希釈時に、ゲルはほとんど生じず、容易に希釈ができた。
比較例11のEOのみを付加された硫酸塩型界面活性剤は、低温(5℃)の粘度が高く、流動性に劣り、起泡性にもやや劣ることが判る。
比較例12のPOの平均付加モル数が大きい硫酸塩型界面活性剤は、起泡性に劣ることが判る。
下記組成のボディシャンプーを製造した。
(成分) (重量%)
実施例5の界面活性剤組成物 5.0
ラウリン酸ナトリウム 6.0
ミリスチン酸ナトリウム 3.0
パルミチン酸ナトリウム 1.0
2−エチルヘキシルグリセリルエーテル 1.0
グリセリン 3.0
メチルパラベン 適量
香料 適量
精製水 バランス
計 100.0
このボディシャンプーは、実施例5の界面活性剤組成物の希釈時に粘度上昇がなく容易に配合でき、起泡性が良好で、使用感に優れていた。
下記組成のシャンプーを製造した。
(成分) (重量%)
実施例2の界面活性剤組成物 15.0
アミドプロピルベタイン* 2.0
ミリスチルアルコール 1.0
カチオン化グアガム** 0.5
エタノール 3.0
香料 適量
精製水 バランス
計 100.0
*:アンヒトール20AB(花王(株)製)
**:JAGUAR C-13S(ローディア社製)
このシャンプーは、実施例2の界面活性剤組成物の希釈時に粘度上昇がなく容易に配合でき、起泡性が良好で、使用感に優れていた。
下記組成のシャンプーを製造した。
(成分) (重量%)
実施例17の界面活性剤組成物 16.0
ヤシ油脂肪酸N-メチルエタノールアミド* 1.0
ミリスチルアルコール 1.0
カチオン化グアガム** 0.5
エタノール 3.0
香料 適量
精製水 バランス
計 100.0
*:アミノーンC-11S(花王(株)製)
**:JAGUAR C-13S(ローディア社製)
このシャンプーは、実施例17の界面活性剤組成物の希釈時に粘度上昇がなく容易に配合でき、起泡性が良好で、使用感に優れていた。
下記組成のシャンプーを製造した。
(成分) (重量%)
実施例22の界面活性剤組成物 17.0
シリコーンエマルルション* 2.0
カチオン化セルロース** 0.5
ラウリルヒドロキシスルホベタイン*** 5.0
グリセリン 3.0
香料,メチルパラベン 適量
精製水 バランス
計 100.0
*:BY22−050A〔東レ・ダウコーニング(株)製〕
**:ポイズ C-150L〔花王(株)製
***:アンヒトール20HD〔花王(株)製〕
このシャンプーは、実施例22の界面活性剤組成物の希釈時に粘度上昇がなく容易に配合でき、起泡性が良好で、使用感に優れていた。
下記組成の食器用洗剤を製造した。
(成分) (重量%)
実施例17の界面活性剤組成物 27.0
アミンオキシド* 9.0
ラウリルヒドロキシスルホベタイン** 10.0
塩化マグネシウム・6水塩 3.0
p−トルエンスルホン酸ナトリウム 10.0
エタノール 2.5
プロピレングリコール 5.0
pH調整剤*** 適量
香料,メチルパラベン 適量
精製水 バランス
計 100.0
*:アンヒトール20N 〔花王(株)製〕
**:アンヒトール20HD〔花王(株)製〕
***:クエン酸又は水酸化ナトリウム
この食器用洗剤は、実施例17の界面活性剤組成物の希釈時に粘度上昇がなく容易に配合でき、起泡性が良好で、使用感に優れていた。
下記組成のコンディショニングシャンプーを製造した。
(成分) (重量%)
実施例13界面活性剤組成物 24.0
ココイルモノエタノールアミド 0.8
ミリスチルアルコール 1.0
カチオン性基含有共重合体* 5.0
カチオン化セルロース** 0.4
シリコーンエマルルション*** 2.5
香料 適量
精製水 バランス
計 100.0
*:ソフケアKG301W(花王製)
**:ポイズC−150L(花王製)
***:BY22−060〔東レ・ダウコーニング(株)製〕
このシャンプーは、実施例13の界面活性剤組成物の希釈時に粘度上昇がなく容易に配合でき、起泡性が良好で、使用感に優れていた。
Claims (6)
- 次の成分(A)、(B)及び(C)を含有し、成分(A)の含有量が40〜75重量%である界面活性剤組成物。
(A):下記一般式(1)で表される硫酸塩型界面活性剤
R1O−(PO)m(EO)nSO3M (1)
(式中、R1は炭素数8〜18の飽和又は不飽和の炭化水素基を示し、POはプロピレンオキシ基を、EOはエチレンオキシ基を示し、m、nは平均付加モル数を示し、同一又は異なって、0<m<1、0<n<5の範囲の数を示し、Mは陽イオンを示す。)
(B):下記(B−1)及び(B−2)からなる群から選ばれる1種以上の化合物
(B−1)下記一般式(2)で表されるアルコールのアルキレンオキシド付加物
R2O−(AO)t−R3 (2)
(式中、R2は炭素数8〜10の直鎖又は分岐鎖のアルキル基又はアルケニル基を示し、AOは炭素数2〜4のアルキレンオキシ基を示し、tはAOの平均付加モル数で、0.5〜4.0の数を示し、R3は水素原子又はメチル基を示す。)
(B−2)モノアルキル(炭素数6〜18)又はモノアルケニル(炭素数6〜18)グリセリルエーテル
(C):水溶性塩類 - 成分(A)と成分(B)との重量比が(A)/(B)=99/1〜75/25である請求項1記載の界面活性剤組成物。
- 成分(A)と成分(C)との重量比が(A)/(C)=99/1〜85/15である請求項1又は2記載の界面活性剤組成物。
- 5℃に1週間保存した後における5℃の粘度が9万mPa・s以下である請求項1〜3の何れか1項記載の界面活性剤組成物。
- (C)水溶性塩類の含有量が、0.3〜10重量%である、請求項1〜4の何れか1項記載の界面活性剤組成物。
- 請求項1〜5記載の界面活性剤組成物に、成分(A)及び成分(B)以外の界面活性剤及び/又は水を混合して得られる洗浄剤組成物。
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JP2017066401A (ja) * | 2015-09-30 | 2017-04-06 | 日本乳化剤株式会社 | 濡れ性向上剤およびこれを含む樹脂組成物、ならびに親水化コーティング剤 |
US11179301B2 (en) | 2016-10-21 | 2021-11-23 | The Procter And Gamble Company | Skin cleansing compositions and methods |
US11185486B2 (en) | 2016-10-21 | 2021-11-30 | The Procter And Gamble Company | Personal cleansing compositions and methods |
US10675231B2 (en) | 2017-02-17 | 2020-06-09 | The Procter & Gamble Company | Packaged personal cleansing product |
US10806686B2 (en) | 2017-02-17 | 2020-10-20 | The Procter And Gamble Company | Packaged personal cleansing product |
US11202744B2 (en) | 2017-02-17 | 2021-12-21 | The Procter And Gamble Company | Packaged personal cleansing product |
Also Published As
Publication number | Publication date |
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KR101646802B1 (ko) | 2016-08-08 |
CN102264884B (zh) | 2013-05-22 |
EP2368970B1 (en) | 2015-06-24 |
KR20110103932A (ko) | 2011-09-21 |
EP2368970A4 (en) | 2014-08-27 |
EP2368970A1 (en) | 2011-09-28 |
US8188024B2 (en) | 2012-05-29 |
ES2546289T3 (es) | 2015-09-22 |
WO2010073644A1 (ja) | 2010-07-01 |
US20110212880A1 (en) | 2011-09-01 |
JP5346574B2 (ja) | 2013-11-20 |
CN102264884A (zh) | 2011-11-30 |
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