WO2003075341A1 - Embase et dispositif semi-conducteur - Google Patents
Embase et dispositif semi-conducteur Download PDFInfo
- Publication number
- WO2003075341A1 WO2003075341A1 PCT/JP2003/002451 JP0302451W WO03075341A1 WO 2003075341 A1 WO2003075341 A1 WO 2003075341A1 JP 0302451 W JP0302451 W JP 0302451W WO 03075341 A1 WO03075341 A1 WO 03075341A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- solder
- layer
- submount
- substrate
- film
- Prior art date
Links
- 239000004065 semiconductor Substances 0.000 title claims abstract description 55
- 229910000679 solder Inorganic materials 0.000 claims abstract description 153
- 239000000758 substrate Substances 0.000 claims abstract description 75
- 230000003746 surface roughness Effects 0.000 claims abstract description 25
- 230000008018 melting Effects 0.000 claims abstract description 18
- 238000002844 melting Methods 0.000 claims abstract description 18
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 54
- 239000010931 gold Substances 0.000 claims description 41
- 238000000034 method Methods 0.000 claims description 40
- 230000004888 barrier function Effects 0.000 claims description 27
- 239000010936 titanium Substances 0.000 claims description 27
- 229910052697 platinum Inorganic materials 0.000 claims description 14
- 238000009792 diffusion process Methods 0.000 claims description 12
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 11
- 229910052737 gold Inorganic materials 0.000 claims description 11
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 claims description 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 8
- 230000002265 prevention Effects 0.000 claims description 8
- 229910052719 titanium Inorganic materials 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 5
- JVPLOXQKFGYFMN-UHFFFAOYSA-N gold tin Chemical compound [Sn].[Au] JVPLOXQKFGYFMN-UHFFFAOYSA-N 0.000 claims description 4
- 239000010410 layer Substances 0.000 claims 19
- 239000012790 adhesive layer Substances 0.000 claims 2
- 239000010408 film Substances 0.000 description 80
- 229910052751 metal Inorganic materials 0.000 description 16
- 239000002184 metal Substances 0.000 description 16
- 239000000463 material Substances 0.000 description 14
- 238000004519 manufacturing process Methods 0.000 description 13
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 9
- 238000001514 detection method Methods 0.000 description 7
- 239000000919 ceramic Substances 0.000 description 6
- 238000007796 conventional method Methods 0.000 description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 5
- 239000000956 alloy Substances 0.000 description 5
- 239000013078 crystal Substances 0.000 description 5
- 229910052750 molybdenum Inorganic materials 0.000 description 5
- 239000011733 molybdenum Substances 0.000 description 5
- 238000000059 patterning Methods 0.000 description 5
- 239000004020 conductor Substances 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 238000005520 cutting process Methods 0.000 description 4
- 238000000206 photolithography Methods 0.000 description 4
- 238000005498 polishing Methods 0.000 description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 4
- 229910052721 tungsten Inorganic materials 0.000 description 4
- 239000010937 tungsten Substances 0.000 description 4
- JBRZTFJDHDCESZ-UHFFFAOYSA-N AsGa Chemical compound [As]#[Ga] JBRZTFJDHDCESZ-UHFFFAOYSA-N 0.000 description 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000001788 irregular Effects 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 150000004767 nitrides Chemical class 0.000 description 3
- 238000007747 plating Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910001218 Gallium arsenide Inorganic materials 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 229910000623 nickel–chromium alloy Inorganic materials 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- 238000001771 vacuum deposition Methods 0.000 description 2
- 238000007738 vacuum evaporation Methods 0.000 description 2
- 238000007740 vapor deposition Methods 0.000 description 2
- 229910017750 AgSn Inorganic materials 0.000 description 1
- 229910020658 PbSn Inorganic materials 0.000 description 1
- 101150071746 Pbsn gene Proteins 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- QCEUXSAXTBNJGO-UHFFFAOYSA-N [Ag].[Sn] Chemical compound [Ag].[Sn] QCEUXSAXTBNJGO-UHFFFAOYSA-N 0.000 description 1
- BYDQGSVXQDOSJJ-UHFFFAOYSA-N [Ge].[Au] Chemical compound [Ge].[Au] BYDQGSVXQDOSJJ-UHFFFAOYSA-N 0.000 description 1
- 239000006061 abrasive grain Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000003486 chemical etching Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000001312 dry etching Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- RHZWSUVWRRXEJF-UHFFFAOYSA-N indium tin Chemical compound [In].[Sn] RHZWSUVWRRXEJF-UHFFFAOYSA-N 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- LQBJWKCYZGMFEV-UHFFFAOYSA-N lead tin Chemical compound [Sn].[Pb] LQBJWKCYZGMFEV-UHFFFAOYSA-N 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- MAKDTFFYCIMFQP-UHFFFAOYSA-N titanium tungsten Chemical compound [Ti].[W] MAKDTFFYCIMFQP-UHFFFAOYSA-N 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S5/00—Semiconductor lasers
- H01S5/02—Structural details or components not essential to laser action
- H01S5/022—Mountings; Housings
- H01S5/0235—Method for mounting laser chips
- H01S5/02355—Fixing laser chips on mounts
- H01S5/0237—Fixing laser chips on mounts by soldering
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S5/00—Semiconductor lasers
- H01S5/02—Structural details or components not essential to laser action
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S3/00—Lasers, i.e. devices using stimulated emission of electromagnetic radiation in the infrared, visible or ultraviolet wave range
- H01S3/09—Processes or apparatus for excitation, e.g. pumping
- H01S3/091—Processes or apparatus for excitation, e.g. pumping using optical pumping
- H01S3/094—Processes or apparatus for excitation, e.g. pumping using optical pumping by coherent light
- H01S3/0941—Processes or apparatus for excitation, e.g. pumping using optical pumping by coherent light of a laser diode
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/0001—Technical content checked by a classifier
- H01L2924/0002—Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/62—Arrangements for conducting electric current to or from the semiconductor body, e.g. lead-frames, wire-bonds or solder balls
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01S—DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
- H01S5/00—Semiconductor lasers
- H01S5/02—Structural details or components not essential to laser action
- H01S5/024—Arrangements for thermal management
- H01S5/02476—Heat spreaders, i.e. improving heat flow between laser chip and heat dissipating elements
Definitions
- the present invention relates to a submount and a semiconductor device using the same, and more particularly, to a submount on which a semiconductor light emitting element is mounted and a semiconductor device using the submount.
- the “semiconductor light emitting device” of the present invention refers to, for example, a laser-diode / light-emitting diode. Background art
- FIG. 5 and 6 are schematic cross-sectional views illustrating a conventional method for manufacturing a semiconductor device. A conventional method for manufacturing a semiconductor device will be described with reference to FIG.
- a submount 103 for mounting a semiconductor light emitting element is prepared.
- the submount 103 includes a ceramic substrate 104, a laminated film 105 (Ti / Pt laminated film 105) of a film containing titanium (T i) and a film containing platinum (Pt) formed on the substrate 104. ), A gold (Au) film 106 as an electrode layer formed on the Ti / Pt laminated film 105, and a solder barrier layer 107 containing platinum (Pt) formed on the Au film 106. And a solder 108 containing gold (Au) tin (Sn) -based solder formed on the solder barrier layer 107.
- the method for forming the 1 ⁇ / ? 1; laminated film 105, Au film 106, solder barrier layer 107 and solder 108 is based on conventional film forming methods such as vapor deposition, sputtering or plating, and photolithography. Or a patterning method such as a metal mask method.
- the solder 108 of the submount 103 is heated and melted.
- Detecting means 200 force Solder 108 melted Image recognition as to whether or not. Specifically, before the solder 108 is melted, the reflected light from the solder is large, so the color of the solder 108 is recognized as “white” by the binarization method of image recognition. When the solder 108 melts, the reflected light from the solder 108 decreases, and the color of the solder 108 is similarly recognized as “black”.
- the laser diode 102 as a semiconductor light emitting element is mounted at a predetermined position on the solder 108. (The die bonding process is performed). Thereafter, the solder 108 is cooled and solidified. As a result, the laser diode 102 is bonded and fixed on the submount 103 by the solder 108. Thereafter, by connecting and fixing the back surface of the submount 103 to a heat sink (not shown) with solder or the like, a semiconductor device having a semiconductor light emitting element can be obtained.
- the conventional semiconductor device manufactured by the steps shown in FIGS. 5 and 6 has the following problems. That is, when the color of the solder 108 is recognized by the detecting means 200, if the surface roughness of the solder 108 is large, light is irregularly reflected on the surface of the solder 108, and the detecting means 200 A sufficient amount of light does not enter 0. Therefore, the detecting means 200 recognizes the color of the solder 108 before melting as black. As a result, the force that causes an error to occur in the die bonding device and stops it. ⁇ The laser diode 102 is pressed against the solder 108 before melting, and the laser diode 102 cannot be mounted on the submount 103. There was a problem. . DISCLOSURE OF THE INVENTION
- the present invention has been made to solve the above problems, and an object of the present invention is to provide a submount having a pre-melting solder layer capable of normally mounting a semiconductor light emitting device with a high yield, and a submount thereof.
- An object of the present invention is to provide a semiconductor device using a submount.
- a submount according to the present invention includes a submount substrate and a solder layer formed on a main surface of the submount substrate.
- the surface roughness Ra of the solder layer before melting is 0.18 / zm or less.
- the surface roughness Ra of the solder layer before melting is reduced. Since it is as small as 0.18 ⁇ or less, irregular reflection of light on the surface of the solder layer is small. Therefore, when the color of the surface of the solder layer is image-recognized by the detection means, it can react more faithfully to a change in the state of the layer surface. As a result, the probability that the semiconductor light emitting device is normally soldered can be increased.
- the surface roughness Ra of the solder layer is 0.15 / m or less, and more preferably, 1 & is 0.10 / im or less.
- the surface roughness Ra of the solder layer is measured by a method specified in JI SB 0601.
- the average particle size of the solder contained in the solder layer before melting is 3.5 ⁇ m or less, more preferably 2 ⁇ or less. In this case, since the average particle size of the solder is small, diffuse reflection of light on the surface of the solder layer can be further prevented.
- the surface roughness Ra of the main surface of the submount substrate is equal to or less than 0, more preferably equal to or less than 0.05 zm.
- the surface roughness Ra of the substrate is smaller, the unevenness of the substrate is transferred to the solder layer, and the increase in the surface roughness Ra of the solder layer can be suppressed. As a result, irregular reflection of light on the surface of the solder layer can be further reduced.
- solder barrier layer formed between the submount substrate and the solder layer may be further provided.
- the semiconductor device may further include an electrode layer formed between the submount substrate and the solder barrier layer.
- the electrode layer can be used as a base film for the solder layer.
- an adhesion layer formed so as to be in contact with the surface of the submount substrate, and a diffusion prevention layer formed on the adhesion layer may be provided between the submount substrate and the solder barrier layer.
- the electrode layer is disposed on the diffusion preventing layer.
- the adhesion layer may include titanium, the diffusion prevention layer may include platinum, the electrode layer may include gold, the solder barrier layer may include platinum, and the solder layer may include a gold-tin solder.
- the submount substrate includes an aluminum nitride sintered body.
- aluminum nitride has high thermal conductivity, a submount with excellent heat dissipation characteristics is obtained. be able to.
- a semiconductor device includes any one of the above-described submounts, and a semiconductor light emitting element mounted on a solder layer.
- the semiconductor light emitting element can be mounted on the timing mount submount in a state of a normal solder layer.
- FIG. 1 is a schematic sectional view showing Embodiment 1 of a semiconductor device according to the present invention.
- FIG. 2 is a schematic cross-sectional view for explaining a method for manufacturing the semiconductor device shown in FIG.
- FIG. 3 is a graph showing the gradation characteristics of the sample according to Sample 1.
- FIG. 4 is a graph showing the gradation characteristics of the sample according to Sample 21.
- FIG. 5 is a schematic cross-sectional view illustrating a first step of a conventional method for manufacturing a semiconductor device.
- FIG. 6 is a schematic cross-sectional view illustrating a second step of the conventional method for manufacturing a semiconductor device.
- FIG. 1 is a schematic sectional view showing Embodiment 1 of a semiconductor device according to the present invention.
- the semiconductor device 1 has a structure in which a laser diode 2 as a semiconductor light emitting element is mounted on a submount 3.
- the submount 3 includes, for example, a submount substrate 4 made of a sintered body containing aluminum nitride (A 1 N), a titanium (T i) film 5 b as an adhesion layer, and platinum ( The Pt) film 5 a of the laminated film 5 (TiZPt laminated film 5), the gold (Au) film 6 as an electrode layer formed on the TiZPt laminated film 5, and the Au It comprises a solder barrier layer 7 formed on the film 6 and containing platinum (Pt), and a solder layer 8 formed on the solder barrier layer 7 and containing gold (Au) tin (Sn) -based solder. As shown in FIG. 1, the laser diode 2 and the submount 3 are connected by a solder layer 8.
- the width of the laser diode 2, the width of the solder layer 8, and the width of the solder barrier layer 7 are substantially equal.
- the width and length of the solder layer 8 may be larger or smaller than the width and length of the laser diode 2.
- the width and length of the solder barrier layer 7 may be larger or smaller than the width and length of the solder layer 8.
- ceramic, semiconductor, or metal may be used as the material of the substrate 4 that forms the submount 3.
- the ceramic material constituting the substrate 4 for example above nitride Anoreminiumu (A 1 N), aluminum oxide (A 1 2 0 3), carbide Kei element (S i C), nitride Kei element (S i 3 N 4 ) Those containing, as main components, etc. can be mentioned.
- a semiconductor constituting the substrate 4 for example, silicon (Si) can be cited.
- the metal constituting the substrate 4 for example, copper (Cu), tungsten (W), molybdenum (Mo), iron (Fe), alloys containing these, and composite materials can be used. .
- the substrate 4 it is preferable to use a material having high thermal conductivity.
- the thermal conductivity of the substrate 4 is preferably 10 OWZmK or more, more preferably 17 OW / mK or more.
- the thermal expansion coefficient of the substrate 4 is close to the thermal expansion coefficient of the material forming the laser diode 2.
- the thermal expansion coefficient of the substrate 4 is preferably 10 ⁇ 10 16 / K or less. It is more preferably 5 ⁇ 10 ⁇ 6 / K or less.
- the through hole may be formed therein.
- a high melting point metal particularly tungsten (W) or molybdenum (Mo) can be used.
- the above-mentioned conductor includes a metal conductor such as tungsten or molybdenum and a transition metal such as titanium (T i) or a glass component or a material of a base material for forming the substrate 4 (for example, aluminum nitride).
- Minimum (A 1 N)) may be included.
- the flatness of the substrate 4 is preferably 5 ⁇ or less, more preferably 1 / im or less. If the flatness exceeds 5 ⁇ , a gap may occur between the submount 3 and the laser diode 2 when the laser diode 2 is joined, and the effect of cooling the laser diode 2 may decrease. Note that flatness refers to the magnitude of deviation of a planar shape from a geometrically correct plane, and is defined in the JIS standard (JISB0621).
- the Ti film (the film containing titanium (T i)) constituting the Ti / Pt laminated film 5 is formed to be in contact with the upper surface of the substrate 4 and has good adhesion to the substrate 4. It is a so-called adhesion layer made of various materials.
- a material for forming the adhesion layer for example, the above-mentioned titanium (T i), furthermore, chromium (Cr), nickel chrome alloy (NiCr), tantalum (Ta), and compounds thereof are used. Can be.
- the platinum (Pt) film constituting the TiZPt laminated film 5 is a so-called diffusion preventing layer formed on the upper surface of the Ti film.
- the material of the diffusion prevention layer examples include the above-mentioned platinum (Pt), palladium (Pd), nickel-chromium alloy (NiCr), tungsten titanium (TiW), nickel (Ni). And molybdenum (Mo) can be used.
- the Au film 6 is a so-called electrode layer, and a film containing Au as a main component is usually used.
- solder barrier layer 7 As a material of the solder barrier layer 7, for example, platinum (Pt), nickel-chromium alloy (NiCr), nickel (Ni), or the like can be used.
- solder layer 8 examples of the material of the solder layer 8 include gold tin (AuSn) -based solder and gold germanium.
- AlGe lead-tin
- PbSn lead-tin
- InSn indium tin.
- AgSn silver-tin
- Au gold-tin
- the composition ratio is 65 to 85% by mass of gold (Au) or 5% by mass of gold (Au). / It is preferably 0 or more and 20 mass ° / 0 or less.
- the above-described Ti / Pt laminated film 5, Au film 6, solder barrier layer 7, and solder layer 8 are hereinafter also referred to as metallized layers. And the method of forming these metallized layers For example, a conventional method can be used as appropriate. Specifically, as a method of forming the above-described metallized layer, a thin film forming method such as an evaporation method or a sputtering method, or a plating method can be used. In addition, as a patterning method for forming the Ti / Pt laminated film 5, the Au film 6, the solder barrier layer 7 and the solder layer 8 so as to have a predetermined pattern, a photolithographic method is used. A lift-off method, a chemical etching method, a dry etching method, a metal mask method, or the like can be used.
- the thickness of the titanium (T i) film 5 as the adhesion layer constituting the Ti / Pt laminated film 5 is preferably not less than 0.1 ⁇ and not more than 1. ⁇ ⁇ .
- the thickness of the platinum (Pt) film 5a as a diffusion preventing layer constituting the Ti / Pt laminated film 5 is preferably not less than 0.0 l iin and not more than 1.5 / m.
- the thickness of the Au film 6 as an electrode layer is preferably 0.1 zm or more and 10 in or less.
- the thickness of the solder barrier layer 7 is preferably not less than 0.1 ⁇ and not more than 1.5 ⁇ .
- the thickness of the solder layer 8 is preferably 0.1 ⁇ m or more and 10 im or less.
- the semiconductor light emitting device of the present invention refers to, for example, a laser diode or a light emitting diode.
- the semiconductor material may be, for example, a GaAs semiconductor or an InP semiconductor, that is, an III-V group compound semiconductor, and may be either a top emission type or a bottom emission type.
- a bottom emission type (a light emitting portion of the laser diode 2 is formed on a side surface of the laser diode 2 facing a junction between the laser diode 2 and the solder layer 8).
- the light emitting portion which is the heat generating portion, is arranged closer to the substrate 4, the heat radiation of the semiconductor device 1 can be further improved.
- an insulating layer such as a silicon oxide film (SiO 2 ) and a metallized layer such as an electrode layer such as gold (Au) are formed.
- the thickness of the gold (Au) layer as the electrode layer is preferably from 0.1 / zm to 10 ⁇ in order to ensure good wettability with the solder layer 8.
- the semiconductor device 1 shown in FIG. 1 may be connected to a heat sink using solder or the like.
- a Ti / Pt laminated film 5 is formed on the substrate 4.
- a heat sink is disposed on the back surface of the substrate 4 via a sheet-like solder.
- the heat sink and the board 4 are connected and fixed by the above-mentioned solder arranged on the back side of the board 4.
- the solder for joining the heat sink and the substrate 4 may be a sheet-like solder (solder foil) as described above, or may be arranged in advance on the surface of the heat sink. Good.
- a solder layer may be formed on the metallized layer on the back surface of the substrate 4 in advance. In that case, it is preferable to bond the laser diode 2 and the heat sink to the substrate 4 at the same time.
- the material of the heat sink for example, metal or ceramic can be used.
- the metal constituting the heat sink for example, copper (Cu), tungsten (W), molybdenum (Mo), iron (Fe), alloys and composite materials containing these metals can be used. Note that it is preferable to form a film containing Ueckel (Ni), gold (Au) and a metal containing these metals on the surface of the heat sink. These films can be formed by an evaporation method or a plating method.
- the heat conductivity of the heat sink is preferably high.
- the heat conductivity of the heat sink is preferably 100 W / mK or more.
- FIG. 2 is a schematic cross-sectional view for explaining the method for manufacturing the semiconductor device shown in FIG. 1 assuming a case where a sintered body of aluminum nitride is used as a substrate.
- a substrate is manufactured as a first step.
- the size of the substrate can be, for example, 5 Omm in width, 5 Omm in length, and 0.4 mm in thickness.
- a substrate larger in size than the substrate 4 of the submount 3 is prepared, a required structure is formed on the surface of the substrate, and the substrate is cut and divided in a cutting process described later, thereby forming a submount. You can get 3.
- the substrate to be the substrate 4 of the submount 3 is manufactured based on a normal substrate manufacturing method.
- As a material for the substrate 4 an aluminum nitride (A 1 N) sintered body is used.
- a 1 N aluminum nitride sintered body
- the nitride film manufactured in the first step, the substrate manufacturing step is manufactured.
- the surface of a substrate made of a luminium sintered body is polished.
- the surface roughness of the nitrided aluminum substrate to serve as the substrate 4 is less 0. ⁇ ⁇ ⁇ in R a, more preferably 0. 05; zm to carry out the polishing until become less desirable.
- a normal method such as polishing with a grinder, sand plast, or polishing with sandpaper / abrasive grains can be applied.
- a third step is performed to form a Ti film 5b as an adhesion layer, a Pt film 5a as a diffusion prevention layer, and an Au film 6 as an electrode layer in a predetermined pattern. And perform a patterning step.
- a resist film is formed on the substrate surface in a region other than the region where the TU 5b, the Pt film 5a, and the Au film 6 are to be formed by using a photolithography method.
- an adhesion layer is deposited. Specifically, a Ti film to be the Ti film 5b as the adhesion layer is deposited on the substrate surface.
- the thickness of the Ti film formed at this time can be, for example, 0.1 in.
- a Pt film to be a Pt film 5a as a diffusion preventing layer is formed on the Ti film to be a Ti film 5b as an adhesion layer.
- a thickness of the Pt film for example, a value of 0.2 ⁇ can be used.
- an Au film 6 as an electrode layer is formed by an evaporation method.
- the thickness of the Au film can be, for example, 0.6 zm.
- a lift-off step is performed as a seventh step.
- the resist film formed in the third patterning step is removed by a resist stripping solution, and a part of the Ti film, Pt film, and Au film located on the resist film is removed together with the resist film. I do.
- the Ti film 5b, the Pt film 5a, and the Au film 6 having a predetermined pattern can be formed on the substrate.
- solder barrier layer 7 is formed as an eighth step.
- a solder barrier layer 7 made of platinum (Pt) is formed on the Au film 6 by using a metal mask method.
- the thickness of the solder barrier layer 7 is 0.2 ⁇ .
- a solder layer 8 is formed on the solder barrier layer 7 by a vacuum evaporation method.
- OX 1 CT 4 Pa or less is preferable.
- ultimate vacuum exceeds 5.
- 0X 10- 4 P a impurity gases such as moisture and oxygen is liable to remain in the solder layer, in the solder layer 8, there is a possibility that the particle size of the larger foreign matter is mixed .
- the attained vacuum is 1.0 X 1 CT 4 Pa or less.
- the crystal grain size and the surface roughness Ra can be changed by changing the solder film forming rate (film forming rate).
- the deposition rate is preferably 0.1 nm / sec or more and 1.0 nm / sec or less. More preferably, the film formation rate is in the range of 3131 311 / sec to 0.7 nm / sec. If the deposition rate is less than 0.1 nmZ seconds, nucleus growth is promoted, the crystal grain size increases, and the surface roughness Ra increases. The film formation rate exceeds 1. O NMZ seconds, the substrate temperature is increased, the reason will be described later, easy grain size is increased, as a result, the surface roughness Ra also increases ease les, 0
- the crystal grain size and the surface roughness Ra can be changed.
- the temperature is preferably from 20 ° C to 150 ° C, more preferably from 20 ° C to 120 ° C. If the temperature exceeds 1'50 ° C, the substrate temperature rises and nucleus growth is promoted, so that the crystal grain size increases and the surface roughness Ra also increases.
- solder layer 8 having a predetermined pattern As a method for forming the solder layer 8 having a predetermined pattern, a metal mask method or a photolithography method as shown in the third to seventh steps of the method for manufacturing a semiconductor device according to the present invention may be used.
- a cutting step of cutting the substrate is performed. As a result, the submount 3 shown in FIG. 1 can be obtained.
- a bonding step of a laser diode 2 as a semiconductor light emitting element is performed. Specifically, the solder layer 8 is melted by heating.
- the detecting means 200 recognizes whether the solder layer 8 has melted or not. More specifically, for example, the gradation of the illuminance of light incident on the detection means is divided into 256 levels, the gradation of the darkest part of the substrate 4 is set to 0, and the gradation of the brightest part of the Au film 6 is set to 255. And Solder When the gradation of the incident light from the layer 8 exceeds 50, the color of the solder layer 8 is recognized as “white”, and it is determined that the solder layer 8 is not melted.
- the color of the solder layer 8 is recognized as “black”, and it is determined that the solder layer 8 has melted.
- the melting Y es and No of the solder layer 8 are determined by the binarization method of the image recognition.
- the laser diode 2 is arranged on the solder layer 8 determined to have melted.
- the laser diode 2 which is a chip using GaAs is joined to the submount 3 by the solder layer 8.
- the semiconductor device 1 of FIG. 1 is completed.
- the detection means 200 can suppress the probability that the solder layer 8 before melting is ⁇ black '', that is, the probability that the solder layer 8 is mistaken for a molten state is small. Y es, No can be determined by probability. As a result, the laser diode 2 can be soldered to the submount 3 in a timely manner with the solder layer in a molten state.
- Samples 1 to 30 shown in Tables 1 and 2 were produced by the following method. Samples 1 to 20 correspond to the examples, and samples 21 to 30 correspond to the comparative examples.
- a Ti film 5b with a thickness of 0.1 nm, a Pt film 5a with a thickness of 0.2 ⁇ m, and a Pt film 5a with a thickness of 0.6 ⁇ m were used.
- a metallized layer composed of the Au film 6 was formed.
- a solder barrier layer 7 made of platinum having a thickness of 0.2 Aim was formed on the metallized layer by a metal mask method and vacuum deposition on the samples other than the sample 10 and the samples 12 and 27.
- solder layer 8 having a thickness of 3 / im was formed on all the samples by a metal mask method and vacuum evaporation.
- the composition of the solder layer 8 and the conditions for vapor deposition are as shown in Table 1.
- “Solder composition” in Table 1 indicates the mass ratio of the elements constituting the solder layer 8. Further, by cutting the substrate 4, 20 submounts of 1.2 mm ⁇ 1.5 mm ⁇ 0.3 mm in length ⁇ width ⁇ thickness were manufactured for each of the samples 1 to 30. Then, for each sample, the ratio of successful image recognition using the detection means 200 when the laser diode 2 was soldered was examined. The results are also shown in Table 2.
- good image-recognition product means the ratio of the number of samples in which the solder layer 8 was actually melted when the detecting means 200 determined that the solder layer 8 was melted. The closer this ratio is to 1, the higher the probability that the detection means 200 could repeatedly detect the melting of the solder layer 8 in accordance with the actual situation. According to the results shown in Table 2, in the submount 3 constituting the semiconductor device 1 (see FIG. 1) according to the present invention, in order to increase this probability, the surface roughness R of the surface 8 f of the solder layer 8 was increased.
- a is 0.18 ⁇ or less, preferably, the surface roughness Ra of the surface 8 f is 0.15 ⁇ or less, and more preferably, the surface roughness Ra of the surface 8 f is 0.1 ⁇ m. It turns out that it is 10 m or less. Further, for the same reason, the average particle diameter of the solder constituting the solder layer 8 is preferably not more than 3.5 m, more preferably not more than 2.O ⁇ um. It can also be seen that the surface roughness Ra is preferably not more than 0.10 ⁇ m, more preferably not more than 0.05 0m. (Specific data of gradation)
- the detection means 200 measured the intensity (illuminance) of light reflected by the substrate 4 as a submount substrate, the solder layer 8 before melting, and the Au film 6. .
- Figure 3 shows part of the results.
- the vertical axis in FIG. 3 indicates the illuminance of the reflected light in 256 gradations.
- the horizontal axis indicates the position on the submount.
- “4”, “8” and “6” indicate the reflected light from the substrate 4, the solder layer 8 and the Au film 6 in FIGS. 1 and 2, respectively. Indicates strength.
- the detecting means 200 can easily recognize the solder layer 8 as a state before melting.
- the vertical axis in FIG. 4 indicates the illuminance of the reflected light in 256 gradations.
- the horizontal axis indicates the position on the submount.
- “104”, “108J” and “106” are the substrate 104 and the solder layer 1 in FIGS. 5 and 6, respectively.
- the intensity of the reflected light from the 08 and Au films 106 is shown.
Landscapes
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Optics & Photonics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Plasma & Fusion (AREA)
- Semiconductor Lasers (AREA)
- Led Device Packages (AREA)
- Die Bonding (AREA)
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/506,510 US7298049B2 (en) | 2002-03-06 | 2003-03-03 | Submount for mounting semiconductor device |
EP03743567.4A EP1482544B1 (en) | 2002-03-06 | 2003-03-03 | Submount and semiconductor device |
KR1020047013738A KR100957669B1 (ko) | 2002-03-06 | 2003-03-03 | 서브 마운트 및 반도체 장치 |
AU2003211502A AU2003211502A1 (en) | 2002-03-06 | 2003-03-03 | Submount and semiconductor device |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2002060764A JP3982284B2 (ja) | 2002-03-06 | 2002-03-06 | サブマウントおよび半導体装置 |
JP2002-60764 | 2002-03-06 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2003075341A1 true WO2003075341A1 (fr) | 2003-09-12 |
Family
ID=27784815
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/JP2003/002451 WO2003075341A1 (fr) | 2002-03-06 | 2003-03-03 | Embase et dispositif semi-conducteur |
Country Status (7)
Country | Link |
---|---|
US (1) | US7298049B2 (ja) |
EP (1) | EP1482544B1 (ja) |
JP (1) | JP3982284B2 (ja) |
KR (1) | KR100957669B1 (ja) |
CN (1) | CN1298032C (ja) |
AU (1) | AU2003211502A1 (ja) |
WO (1) | WO2003075341A1 (ja) |
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---|---|---|---|---|
US8472208B2 (en) | 2005-03-18 | 2013-06-25 | Dowa Electronics Materials Co., Ltd. | Submount and method of manufacturing the same |
US8581106B2 (en) | 2005-03-18 | 2013-11-12 | Dowa Electronics Materials Co., Ltd. | Submount |
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TWI402947B (zh) * | 2005-04-07 | 2013-07-21 | Tanaka Precious Metal Ind | 不透氣密封蓋及其製造方法 |
Also Published As
Publication number | Publication date |
---|---|
CN1298032C (zh) | 2007-01-31 |
EP1482544B1 (en) | 2016-11-30 |
EP1482544A1 (en) | 2004-12-01 |
KR100957669B1 (ko) | 2010-05-12 |
US20050067636A1 (en) | 2005-03-31 |
EP1482544A4 (en) | 2006-09-27 |
KR20040093094A (ko) | 2004-11-04 |
JP2003258360A (ja) | 2003-09-12 |
US7298049B2 (en) | 2007-11-20 |
JP3982284B2 (ja) | 2007-09-26 |
CN1633706A (zh) | 2005-06-29 |
AU2003211502A1 (en) | 2003-09-16 |
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