TW533604B - Light emitting device - Google Patents
Light emitting device Download PDFInfo
- Publication number
- TW533604B TW533604B TW090132753A TW90132753A TW533604B TW 533604 B TW533604 B TW 533604B TW 090132753 A TW090132753 A TW 090132753A TW 90132753 A TW90132753 A TW 90132753A TW 533604 B TW533604 B TW 533604B
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- Prior art keywords
- light
- emitting device
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Classifications
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- C—CHEMISTRY; METALLURGY
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- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
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- C09K11/7783—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing two or more rare earth metals one of which being europium
- C09K11/7795—Phosphates
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y20/00—Nanooptics, e.g. quantum optics or photonic crystals
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
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- C09K11/7734—Aluminates
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
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- C09K11/77344—Aluminosilicates
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
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- C09K11/7728—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing europium
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- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/0001—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
- G02B6/0011—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
- G02B6/0033—Means for improving the coupling-out of light from the light guide
- G02B6/0035—Means for improving the coupling-out of light from the light guide provided on the surface of the light guide or in the bulk of it
- G02B6/0036—2-D arrangement of prisms, protrusions, indentations or roughened surfaces
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
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- G02B6/0001—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
- G02B6/0011—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
- G02B6/0066—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form characterised by the light source being coupled to the light guide
- G02B6/0073—Light emitting diode [LED]
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
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Description
533604 五、發明說明(1) 技術領Μ 本發明為關於具有發光元件之發光裝置,特別為該發光 元件為於弟一光譜區域中發光,且,至少含有來自驗土金 屬原石夕酸鹽群或其螢光體群並且再具有吸收該發光元件之 刀發光、且於另外之光譜區域發光之榮光體的發光裝 置。 " 背景拮衛 該發光裝置例如為無機LED、有機LED、激光二極管、無 機厚膜電激發光薄片或無機薄膜電激發光零件。 LED尤其以哥命長、不佔地方、衝擊強、並且於狹窄的 光譜帶中發光之特徵而引人注目。 多數的發光色,特別為廣泛光譜帶的多數發光色,於 LED情況之活性半導體材料之固有發光下並不能實現發 光、或僅以非效率地實現發光。此情況尤其適用於取得白 色發光之情況。 若根據公知技術水準,則半導體中本來無法實現的發光 色,可經由色轉換技術而取得。 本質上此色轉換技術為根據下列原理,即,於LEd塑膜 上配置至少一個螢光體。該螢光體為吸收此塑膜之發光, 且其後將光激發光的光線以另外之發光色放出。 螢光體基本上可使用有機系,且亦可使用無機系。無機 顏料之本質上的優點為比有機系之耐環境性更高。關聯於 無機LED的壽命長度,因此若考慮色安定,則以無機系為 有利的。
90132753.ptd 第6頁 533604
有利使用無機螢光顏料,代替 成長期間(Wachstumzeiten)之 進入矩陣中,且再被置於LED 關於加工之容易度,可知 於取得必要膜厚上具有過長 有機螢光喷塗系。該顏料為 塑膜上。 由滿足上述要求之無機材料數且少之理, 許多情況使用來自YAG類之材料做為辛 口 ^ 曰 a m、,θ w 竹竹做為色轉換用之顏料。但 疋’此材料具有僅於該材料為夫 ^ i ^ ^ 付局禾滿56Onm之發光最大值之 巧中顯不兩效率之缺點。由於此類理由,使用與藍色二 極管(450至490nm)組合之YAG海料 目丨丨叮〜 ” ^ Λ ^ τ ^ <ΪΛΐ1顏科,則可實現僅為冷感之 ^ :光色。特別於照明領域中之㈣,關於色溫度及色 對於光源之要求更高。此要求為目前所使用之白 色LED所無法滿足的。 更且,由W0 00/33389得知,於使用藍色LED取得接近白 色之光上,尤其使用BaJiO* : Eu2+做為螢光體。Ba2Si04 : Eu2+之發光為5〇5nm,即為較短之波長,其結果,此光 著冷感。 於s· Η. M· Poort 等人之論文,,0ptical pr〇perties 〇f Eu2+-akt 1 vated. 2 97頁中,研究經^;#活化之Ba2Si〇4及磷 酸鹽,例如KBaP〇4及KSrP〇4之性質。又,於該文獻中,確 認B^SiO4之發光為50 5nm。所研究之二個磷酸鹽之發光為 相對地於本質上為更短之波長(42〇nm至43〇1111])。 本發明之課題為令上述之發光裝置,經由螢光體將第一 光源之紫外線或藍色放射顯著良好吸收,則可變更成於高 的光發光效果下,實現不同光顏色及高顏色再現之程度,
90132753.ptd 第7頁 533604
$ 2,一般照明用之光源中常用的cie 内置特別有利於約,和7_之間之極近= 之揭主 上述課題為經由上述之發光裝置 ’則於且無备儿此+ a ^...... 右·根據本發 明 光 則於具備氮化物半導體所構成之發光 、、 ,件所發出之一部分光,並且:出和吸收發 丹百與此吸收氺夕油 同波長光之螢光體的發光裝置中,罄本 ' 化爻认丄人府a a , T資先體為由經銪活 <驗土金屬石夕酸鹽所構成。
螢光體為式: ^2-x~y)sr〇 . x(Ba,Ca)0 · (1-a-b-c-d) i〇2 aP2 05 bAl2〇3 cB2 03 dGe02 : y Eu2+ 式中,0 <x <1. 6、 〇· 0〇5 <y <〇· 5、 0 ^ \a、b、c、d<0.5) (2示之經二價銪所活化之鹼土金屬原矽酸鹽和/或 、x〜y)BaO · x(Sr,Ca)0 · (l-a-b-c-d)
Sl〇2 · aP2 05 bAl2〇3 cB2 03 dGe02 :y Eu2+
式中,0· 01 <x <1. 6、 〇· 0〇5 <y <〇· 5、 0 、b、c、d<0.5) 戶斤一 不之鹼土金屬原矽酸鹽亦可。此時,有利令a、b、c及d 之值中之至少一者為大於〇〇1。 印’使用矽酸鳃或矽酸鋇與矽酸锶原矽酸鹽之混合裂式
533604
五、發明說明(4) 代替矽酸鋇之情形中,意外地發現所放射之光波長變長。 石夕部分以錯予以取代及加成存在之P2〇3、Al2〇3和/或 對發光光譜具有影響,其結果,該發光光譜可於分別使用 之情況中調整至最適。 自經二價銪和/或錳活化 體和/或來自Y(V、p、si) 前述之發光裝置為有利具有來 之鹼土金屬鋁酸鹽群之其他螢光 〇4 : Eu或下式:
Me(3-x-y)MgSi2 03 : xEu,yMn (式中, 〇·〇〇5<χ<〇·5、 〇·〇05<Υ<〇·5、
Me為表示3&和/或^和/或ca) 所示鹼土金屬一鎂—二矽酸鹽·· Eu2+、Mn2+群之再其他之紅色 發光的螢光體。 更且’少量之一價離子、特別為!i化物併入螢光體袼子 中’則察見有利於結晶化度及放射率。 、第一光譜區域為3 0 0至5 0 0 nm時,為有利的。於此波長區 ά或下’本發明之螢光體可被良好激發。 更且’第二光譜區域為430nm至650nm時,為有利的。配 合此情況,可取得較純的白色。 乂有利之發光裝置為放射出具有Ra值>72之白色光。 佳實施形熊 若根據本發明之第一實施態樣,則發光裝置為具有二個 同的螢光體,此時,至少一者為驗土金屬原石夕酸鹽營光
9013如.则
533604 五、發明說明(5) 體。如此則可令白色色調特別正確地調整。 根= :光f:置之機械性實施存在許多可能性。若 ^之某板上了且罄,將1個以上之LED晶片配置於反射鏡 散。土 且,螢光體為於反射鏡上所配置之透鏡中分 但是’亦可將1個以上之I FD曰H 上,且,將蒂先雜泠欲 曰曰片0己置於反射鏡内之基板 上且將螢光肢塗佈於該反射鏡。 有利令該LED晶片以且右詁样彤业+、泰口口 早C2右植巧糾壯八有豉樣形狀之透明封裝用化合物 真^封袭用化合物一方面為形成機械性保護, 且,另一方面該封裝用化合物為再改善 模之光予以改善的發光)。 干化貝(將LED塑 該螢光體可於封裝用化合物中分散,且經由此封裝用化 5物,儘可能不會封入氣體地,令基板上配置之led晶片 與聚合物透鏡結合’此時,該聚合物透鏡與該 曰曰 物最大僅具有O.i差異之折射率。亦可經由該封裂用化合口 物將LED塑模直接封閉,但是,亦可令該UD以透明的封裝 用化合物予以充填(即,於此情形中存在含有透明的'^ 用化合物與螢光體之封裝用化合物)。經由類似的折射、 率,則幾乎無邊界面反射所造成之損失。 有利令聚合物透鏡為具有球形成橢圓形之凹坑,該凹坑 為經由前述的封裝用化合物而被充填,其結果,UD陣列 為因聚合物透鏡而被稍有距離固定。如此處理,則可減少 機械構造之大小。 / 為了達成螢光體的均勻分布,較佳令螢光體於無機之基
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533604 五、發明說明(6) 質中懸浮。 所於使用二個螢光體之情形中,二個螢光體為於各別之基 2中懸浮,此時,較佳令此些基質於光傳送方向上互相以 前後配置。經此則令基質之濃度為比不同螢光體一起分散 之情況更為減少。 其次,說明本發明第一實施態樣中之製造螢光體的重要 工程。 所為了製造矽酸鹽螢光體,乃將根據所選擇組成之起始物 1鹼土金屬被酸鹽、二氧化矽及氧化銪之化學計量性份量 緊密混合,且,以製造螢光體所常用之固體反應,於 =氛圍氣下:以溫度110(TC&14〇(rc轉換成所欲之螢光,、 :。此時,對於結晶度而言,以反應混合物中之比例少、 n j :〇. 2莫耳之比例下添加氯化銨或其他鹵化物為 視而要,亦可將一部分矽以鍺、硼、鋁、磷予以取 代,且亦可將一部分銪以錳予以取代, 熱而分解成氧化物之上述元素之化合物的;應 仃。於此情形中,維持反應條件之範圍。 所侍之矽酸鹽為以波長510nms 6 0 0nm放射,且且 11 Onm為止之半值寬度。 /、有 自上述群之一個螢光體或來自上述群組 爱无體、或者、缔士 -押》亡X /丄、h , 又 1^# A ^ ^ Y(V . p s':.; ^ ^ ^ ^ ^ ^ 光體、來自Y2 02 s ·· Eu3+螢么體二:::替、::色發光之螢 可取得I有;2定羞EUA邊先體群之常用螢光體的組合,則 有所疋義之色溫度的發光色及高的色再現性,此
533604 五、發明說明(7) 為如下列實施例所示。 T = 2 778K(464nm + Sr1 4Ba〇 6Si04 :Eu2+) ;x =0.4619 ^y = (K 4247、Ra =72、 T = 2 9 50K(464nm + Sr1 4Ba〇 6Si04 · Eu2+) ; x = 0. 4380 " y = 0. 4 0 0 4、Ra=73、 T = 3497K(464nm + Sr1 6Ba〇 4Si04 : Eu2+) ; x = 0. 4086 - y = (K 3 996、Ra =74、 T=4183K(464nm + Srh9Ba0.08Ca0.02SiO4 :Eu2+); x =0· 3762、y =0· 3873、Ra =75、
T = 6624K(464nm + Sr1.9Ba002Ca008SiO4 :Eu2+); x =0. 3101、y = 0. 330 6、Ra =76、 T^^SSSKUGhm + SruBauSiC^ zEi^ + SruBauSiOi :
Eu2+) ;χ=0·3135、y=0.3397、Ra=82、 T =4216K(464nm + Sr1.9Ba〇.〇8Ca〇.02Si04 :Eu2+)); x =0. 3710、y =(K 3696、Ra =82、 3954K(464nm + Sr16BaQ.4Si04 zEi^ + SruBauSiC^ :
Eu2+ + YV04 :Eu3+) ;x=0.3756、y=0.3816、Ra=84、
T = 6489K(464nm + Sr1.6Ba0>4SiO4 : Eu2HSr0>4Ba1>6SiO4 : Eu2H 鋁酸鋇鎂:Eu2+); x =0. 3115、 y = 0. 33 9 0、Ra =66、 T = 5 0 97K ( 4 64ηο + 8Γ! 6Ba〇 4 (S i〇 08B0 〇2 ) 〇4 :
Eu2HSiY6Ba14Si04 :Eu2+) ;x = 0.3423、y=0· 3485、Ra 二 82 ^
90132753.ptd 第12頁 533604 五、發明說明(8) T = 5084K(464nm + Sr1 6Ba〇>4 (Si〇 08B0 02 )〇4 : Eu2+ + 、y
Sr0.6Ba14SiO4 :Eu2++鋁酸勰鎂:E2+) ;χ=〇· 343〇 0.3 53 1、Ra =83、 T = 3369K(464nm + Sr1 4Ba〇>6Si〇 95Ge〇 O5 04 : Eu2+); x =0. 4134、y = 0. 39 5 9、Ra =74、 T = 2787K( 466nm + SrL4Ba0>6Si0>98P0 02 〇4 〇1 :Eu2+); x = 0. 4 6 3 0、y= 0.4280、Ra=72、 T =2913K(464nm + SrL4Ba〇.6Si 0 98 A 1 0 02 〇4 :Eu2+); x = 0. 4425、y= 0.4050、Ra=73。 於本發明之一個實施態樣之情形中,色轉換為如下實 施。 將1個以上之LED晶片於基板上組裝。於該LED上直接(一 方面為保護LED晶片,另一方面為令LED晶片内笋生之光 良好釋出)將封裝用材料以半球或半橢圓之型式配置。此 封裝用材料亦可分別包含各塑模,且該封裝用材料亦可全 部之LED以共通之-個型式。將如此處理裝備之基板設置 於反射鏡内,或將該反射鏡覆蓋該LED晶片上。 於該,射鏡中設置透鏡。—方面該透鏡為使用於保護裝
Li;:方面為於該透鏡中混入營光體顏料。如此處理 .ψ =二不透明且造成黃色顏色之映像。通過該透鏡所 二M = (包含紫外光)為經由光學零件中通過時,進 >ί丁轉換成長波光朵彳 ^ Sz ^ A A λ 、 。”、,、口果’將藍色光和黃色光合 併取付白色顏色之咏後。Α 吐你田、止#认f 例如於平面平行板間所產生之導 波作用造成的損失,矸細& n 、天 了、、二由邊透鏡之不透明性及擴散性而
533604 五、發明說明(9) 減少。再經由反射鏡,僅令已調整之光線入射 其結果,全反射作用由開始以後減少。 W $ % 、另外,亦可於各LED晶片上覆蓋反射鏡,且,該反射鏡 為被充填成圓蓋形,且透鏡為被配置於各個反射鏡上或此 裝置之全體上。 製造照明之發光裝置較佳使用LED陣列代替單一 iLED。 其他實施態樣之情形中,色轉換為以⑽晶片 於基板上直接組裝之led陣列如下實施。 =ED陣列使用封裝用化合物(例如環氧樹脂),接黏至 =他材料(例如PMMA)所構成之透明聚合物透鏡。該聚合物 ,鏡及該封裝用化合物之材料為儘可能折^ LI透= t地選擇。該封裝用化合於 ♦ 口物透鏡之取大且球形或橢圓形之凹坑 對於色轉換物質於該封裝用化合物 =式 二,^此類型式,保證可取得無關於=二=的另 聚合物透鏡。 輯名用化合物接黏至前述之 對於使用至少二個不同螢光體^ ^ ^ ^ ^ ^ ^ ^ 較佳令此些螢光體分別分散且重疊。其特土貝中’其 之發光色為經由複數的色轉換 ς θ」:〗用於最: 長波之發光色為經由一個發光= 之組合。即,最 過程之經過如下^,生成,此時,該發光 下即以弟一螢光體將LED發光吸收、第 90132753.ptd 第14頁 533604
一螢光體之發光、 收、及第二螢光體 佳將各個螢光體於 亦可比各種螢光體 度。 以第二螢光體將第 之發光。特別,對 光傳送方向上,互 單一分散之情況更 一螢光體之發光吸 於此種過程而言,較 相為前後配置,藉此 加減少螢光體的濃 土發明不限定於上述實施例。帛光體亦可被編入聚合物 (或其他之光學零件)中。亦可將該螢光體於led塑模 直接配置,且亦可於透明的封裝用化合物之表面上配 置。又,該螢光體與分散粒子亦可共同編入一個基質中。 藉此,可防 >止於基質中的沈降,且,保證均句的發光。 以下,更詳細說明將具有前述光激發光效果之螢光體使 用於發光二極管(L E D )燈之例。 圖為本發明發光裝置之第二實施形態LED燈的模式截面 圖,不出所謂的透鏡型LED燈。GaN系半導體所構成之藍色 LED4,為於形成擔任令藍色LED發光於LED燈上方反射之反 ,鏡職務之杯10的金屬電子管心柱3上,透過支柱5而安 展將1色L E D 4之一者電極與導線框2經由金製之接合電 線7予以接續,且另一者電極與導線框丨經由金屬之接合電 線6予以接續。為了固定藍gLED4,以塗覆材料之内部樹 月曰8覆盖杯1 〇。更且’將形成導線框2及金屬電子管心柱3 之導線框1 ’以塑模材料之外部樹脂9予以封裝。因此,藍 色LED4為由内部樹脂8及外部樹脂9予以雙重封裝。尚,金 屬電子管心柱3與導線框丨亦稱為支柱導線。又,關於藍色 LED4之詳細說明為於後述。
90132753.ptd
533604 五、發明說明(η) 一 面ί: Hi!之内部樹脂8為被充填至比杯1 °上緣水平 氐之杯1 0内部。藉此,於複數LED接近配置之情 得解I ί ί生LED間的混色,且以LED實現平面顯示並乂可取 付%像度良好的晝像。 上j取 二部樹脂8為使用於固化後呈透明的聚矽氧樹脂 =:又,内部樹脂8為混入前述經二價銪活化之驗 11 體(广為驗Λ金屬原石夕酸鹽做為主成分的營光體 Ϊ 达邊先體11為如别述般,具有光激發光效果,且誃备 光。為吸收發出的光,並發出與吸收光之波長不同波=之 為二呷:::吏用二熔點玻璃代替聚矽氧樹脂或環氧樹脂做 树知8。低熔點玻璃為耐濕性優良並且可阻止 ®此侵入藍色LED4。更且,因為來自藍&LED4之發光不\ J收且就其原樣穿·’故不需要預估吸收部分而‘::被 又,亦可於混入前述螢光體丨丨之内部樹脂8之聚矽 以氧樹?或低溶點玻璃中’再混入擴散材料 '經二 藍色tED4之光線易接觸螢光體11,且可令榮光體 $ 4 *色之光直增加。此擴散材料並無特別限定,可使用 热知之物質。 〜 』便用 外部樹脂9可使用固化後呈透明的環氧樹脂。 脂支$由易操作方面而言’則可使用環氧樹脂等各種樹 支柱5中所用之樹脂為具有接黏性,且即使於極小駐 533604 五、發明說明(12) 色LED4之側面乘載支柱5,亦具有不會令側面各声 之絕緣性的樹脂為佳。 s ]短路 支柱5為了將來自藍色LED4之各向同性發出之 表面之反射鏡反射並於LED燈之上方放出, 透明之樹脂。特別,將LED燈使用白色夺之亦% + 用 亦可為不妨礙白色光之白色。 系之先源時,支柱5 又’於支柱5中亦可含有螢光體n。使 燈,比未使用螢光體UiLED燈之光密度更^極浐㈣=LED 即,由藍色LED4所放出之光因為不透才而炎回。 Ϊ = :ί光二經由藍色_附近設= 出且向同性重新放 i部八夕批玄、, 鏡被反射,且亦經由led燈 ^ =刀之=射率差而被反射。因此,藍色LED4附近之光為 口P分被緊密關閉’且藍色LED4附折夕止Α ώ:上 、
燈為高亮度發光。 附近之“度極高,令LED 祐ϊ n4同性發光’且此光即使於杯10之表面亦 Ϊ 故=為透過支柱5中,故支柱5中之光密度極 :之=二' 5中含有螢光體11,則藍色㈣4所發 螢光體11所反射,又,以支柱5中之 生式各向同性地重新放出。如此,若 ”柱5中亦:含有螢光體u,則_燈為更高亮度。 声夕Ϊ FT) I 1用含有Ag等無機材料之樹脂。1述高亮 :用产;W楚日守間使用’則因於支柱5和内部樹脂8中’ 衣乳3月曰之树脂’故藍色LED4極附近之合成樹脂支 90132753.ptd 第17頁 五 發明說明(13) ----—____ 和内部樹脂8為被著色成茶色 效率降低。特別,誌色LED …、色且惡化,並且發光 ㈣大為降低。的著色乃令發光 候性,且亦被要求接好糾 求對於藍色LED4之光為耐 惡化可於支柱5中使用'含有AgY無^等材而光所造成之樹月旨 =念柱5可將Ag糊料與螢光體;;於= 於金屬電子管心柱3卜 、又柱糊科中化合,且 簡單形成。 機器塗佈並且接黏LED4則可 料之Γ機:了脂含二之上氧:^ 樹脂之密合性良好,X ^支柱5中之無機材料必須與 因此,令樹脂中含有—種二:藍色LED4之光而惡化。 鋁、石夕石、氧化鈦、氮化_彡自銀、金、鋁、銅、氧化 機材料。特別,以銀、 虱化錫、氧化鋅、ITO之無 且具有導電性,故可適用於#呂、銅等因為令放熱性提高, 又,氧化!s m ^期待導電性的半導體裝置。 持高反射率。益 =、氮化删等為耐候性強且可維 ^作成球狀= 性和電性導電等而令其 了機材料含量可對放埶赍^種形狀。支柱5樹脂中之 ^ ’樹脂中之無機材^含:”導性等進行各種調節。但 费合性降低,故以5重量::夕’則樹脂之惡化少,但因 重量%以上至80重量%以°,上,80重量%以下,且若為60 如此於支柱5中,,則最適於防止樹脂之惡化。
Ag等無機材料,則可抑制因藍色LED4發光之光而惡化之 P制支柱5之樹脂因光所造成之惡 533604 發明說明(14) 化,故惡化所造成之著色部位少並可防止發光效率之降 低’可取得良好的接黏性。又,亦可經由支柱5中含有螢 光體11 ’則可令LED燈之亮度更加提高。 藉此,可提供即使於高亮度、長時間之使用中亦可令發 光效率之降低極少之可高亮度發光的LED燈。更且,於使 用熱傳導性良好之材料下,可令藍色LED4之特性安定化, 且亦可減少色斑。
圖2為示出圖1所示LED燈之藍色LED4的層構造。藍色 LED4為例如具有藍寶石基板41做為透明基板,且於^此誌寶 石基板41上,以M0CVD法等將做為氮化物半導體層之例^如、 緩衝層42、η型導電層43、η型覆蓋層44、 MQW(multi-quantum well)活性層 45、ρ 型覆蓋層 46、及ρ 型V電層4 7依序形成,並以濺鍍法、真空澱積法等,於ρ 型導電層47上之全面形成透光性電極5〇,於透光性電極5〇 上之一部分形成ρ電極48、及η型導電層43上之一部分形 η電極4 9。 夕 緩衝層42為例如由Α1Ν所構成,且η型導電層43為例如 GaN所構成。
—η型覆盍層44為例如由AlyGapyNCO gy<l)所構成,p型覆 蓋層46為例如由AlxGaixN(0 <χ<1)所構成,p型導電層u 為例如由AlzGai—ζΝ(〇9<1、z<x)所構成。又,1)型^蓋 層46之帶間隙為大於η型覆蓋層44的帶間隙。^型覆蓋声 及Ρ型覆盍層46可為單一組成之構成,且亦可如超袼子構 造般,將彼此組成不同之厚度100Α以下的上述氮化物半
533604 五、發明說明(15) 導體膜疊層所構成亦可。由 可防止膜φ & a 將膜厗作成1 〇〇 A以下,則
J防止膜中發生裂痕和結晶缺陷。 J MQW活性層45為由InGaN所構 構成之複數阻擋層所構成…如—所 及阻擋層之厚ώ^1ΠΛ。 成赵礼子層般,井層 為钍日性所& ^為以下、較佳為60〜7〇 Α。lnGaN因 ::曰曰杜貝比其—1GaN等含有M之氮化物半導 ^文將InGaN使用於構成活性層45之層中,則可 = 氮化物半導體層全體難發生裂#。 且曰之各 丄τ广 雖知玍衣辰尚,MQW活性層4 5亦玎 由nGaN所構成之複數的井層、和AlGaN所槿& >. 1 Γ 由A1InGaN所構成之複數的井層、和 =旦aN戶斤構成之複數阻擋層所構成。但,阻撞層之帶間 ί永月b里為大於井層之帶間隙能量。 尚,由MQW活性層45開始的藍寶石基板41側,例如,於^ 型導電層43之緩衝層42側亦可形成反射層。又,反射鏡亦 可於MQW活性層45所疊層之藍寶石基板41的表面與反側表 面上形成。反射層以對於活性層45所釋出之光具有最大反 射率者為佳,例如,可由A1所形成,且亦可由GaN系薄膜 之多層膜所形成。經由設置反射層,則可將來自活性層45 之放出光以反射層予以反射,且令來自活性層4 5之放出光 的内部吸收減少,可增大對於上方的輸出光,減低對於支 柱5的光入射並且防止其光惡化。 如此所構成之藍色LED4之發光波長的半值寬度為5〇nm以 下、較佳為40nm以下。又,藍色LED4之波峰發光波長為 380nm至5 0 0nm之範圍,例如為450nm。
90132753.ptd 第20頁 533604 五、發明說明(16) " ~----- 對於如此構成之LED燈,若於導線框i、2間外加電壓, 則藍色LED4為發出450ηπι波長之藍色光。藍色光為激發内 部樹脂8中之螢光體n,且所激發之螢光體n為發出 560^ 570、nm之黃色光。内部樹脂8中之藍色光與黃色光混合 之光為通過外部樹脂9漏出至外部,此混合光以人類眼睛 察見白色,結果,察見LED燈為發光成白色。即,螢光體 11為經由藍色LED4所發出之藍色光而被激盘該 =係,發出比藍色波長更長之黃色。本發明;、= e複數的螢光體,而可取得更接近純的白色。 『為,出本發明發光裝置之第三實施形態之面狀光源 用2 =之構成,(a)為平面圖,(b)為(a)之A_A線截面圖。 柄i Λ所Λ之面狀光源用裝置為例如適用於做為液晶面 光,i北ί ί ’且由液晶面板之裏面側對液晶面板照射 】=先性液晶面板之文字和畫像給與明亮度和對比 度,k向其辨視性,具備下列要素所構成。 即,面狀光源用裝置為具備透明之大約為矩狀的 Λ 的藍色LED4、和除了導光板7〇之光 射出面7〇a包圍其他面並將導光板7〇所安裝之光 之光反射盒71、和於導光板7〇之射出面7〇 形成微細凹凸模樣的光擴散模樣 先板70上女叙覆蓋射出面7〇 、
之透明薄膜74所構成。 1且於Μ合有營光體U 又,各藍色LED4為透過接合電線及導線框等之電源供給 90132753.ptd 第21頁 533604 五、發明說明(17) Γί i?t段ΐ:: 5給指定電壓之驅動電壓般地安裝於光反 光板70之内立ϋ吴樣73為將來自藍色LED4所射出之光於導 无扳7 0之内部擴散。 $ 對於如此構成之面肤杏、、盾 # 驅動電遵,則射出來自置:右於各藍色LED4外加 亦故认道止4 自所驅動之各藍色LED4之光。此射出 成:氺妒坍^样中以指定方向前進,且接觸反射面72所形 過薄膜7:1 = 並且—邊反射擴散一邊由射出面7〇3通 於通過細時,;色LED4之射出光為 波長而射出。藉此令薄二所吸…同時轉換 ,± ^ 寻膜74之月,j面所硯測之發光色為合成 匕二先之顏色,例如由前述之原理而言為呈白色。 如此,若根據第三實施形態面狀光源用裝置,則 ^LED4之射出光為人射至導光板7(),且此人射光—邊以導 =70之反射面72所形成之光擴散模樣予以反射擴散,一 邊由射出面7〇3射出至薄膜74 ’且於此薄膜74中, 八 =為被螢光=11所吸收,㈤時轉換波長而被射出:刀 先河般,即使未使用紅、綠、藍各色之,僅以 =亦:將發光色作成白色。又,因為以營光⑴「色 腿不直接接觸之構造,故可長期抑制螢光體k亞:色 且可經過長期保持面狀光源之指定色調。 心 二匕:卜,經由改變薄膜74中所含有之;光體㈣ 僅可貫現白色’且亦可實現其他色之發光色。若將薄膜74 之女裝構造作成易脫除構造’並且準備數種含有不 登光體U之薄膜74 ’則僅將薄膜74更換即可輕易令面狀: 90132753.ptd 第22頁 533604 五、發明說明(18) 源之色調可變。 又、’螢光體1 1除了於薄膜74中含有以外,若於薄膜74之 表面塗佈含有,則可取得同樣之效果。 又]藍色LED4為藉由埋入導光板7〇中,而與導光板7〇予 以光學性接續,此外,亦可將藍色LED4接黏導光板7〇之端 面’將藍色LED4之發光以光纖等光傳導手段導至導光板7〇 之端面’將藍色LED4與導光板7〇予以光學性接續。又,藍 色LED4即使為1個亦可。 a 圖4為示出本發明發光裝置之第四實施形態之 SMD(Surface Mounted Device)型的LED 燈。 型之LED燈為具有下列構成。覆蓋具有絕緣性之玻璃 壞氧樹脂基板8 〇之兩面,且,以電性分離形成之二個金所 作成之圖型配線81、8 2形成金屬框,並於圖型配線8 1、8 2 亡設置具有塑膠製杯83a之框體83。杯83a以其表面成為將 監色LED4之放出光予以反射之反射鏡。圖型配線81、82為 非對稱’且於圖型配線82之上面為形成至框體83所形成空 間之底部中央為止,另一者之圖型配線81為僅於框體8 3所 形成空間之底部少許露出。 監色L E D 4為於圖型配線8 2之上面,以含有銀充填物之環 氧樹脂糊料84予以固黏。藍色LED4之p電極與圖型配線82 為經由金製之接地電線6予以接續,且藍色LED4之η電極與 圖型配線8 1為經由金製之接合電線7予以接續。 框體83之杯83a所形成之空間内充填於固化後呈透明的 封展』8 8。經由封裝劑§ 8將备色l E D 4固定。封裝劑8 8為混
五、發明說明(19) 入鈾述經二價銪活化之驗土 原矽酸鹽做為主成分之螢光 聚碎氧樹脂。 金屬原石夕酸鹽和/或鹼土金屬 體11 °封裝劑88為環氧樹脂或 汴匕入逢光體11之封裝劑8 8 空間内充填一虹,y女 於框體83之杯83a所形成之 填。 4體8 3之上緣至下方部位充 尚,W述混入螢光體^之封梦 料。經由擴|姑料 对衣刈Μ亦可再混入擴散材 :十、甶擴放材#,可將來自發光藍色LED4之光予以μ 射成為散亂光,故來自藍色Lj;d彳β | ^ & 5 可八罄# 八丄a aLED4之先易於接觸螢光體U, J 7堂无體1 1所發光之弁景掛ι ,, _ ^ 尤里J日加。此擴散材料並盔特別m 定,可使用習知物質。 1 W 1…、符別限 門ίΓΐί所構成之SMD型之L_,若於圖型西己線81、82 間外加電壓,則藍色LED4為發出45Qnm波長之q 82 色光為激發封裝劑88中之螢光體n,且所激發之螢光體 為發出560〜57〇11„1之黃色光。封裝劑88中之藍色光與黃色 光混合之光為漏出至外部,此混合光以人類眼睛察見白 色,結果,察見L E D燈為發光成白色。即,螢光體11為_ 由藍色LED4所發出之藍色光而被激發,與藍色具有補〃色關 係,發出比藍色波長更長之黃色。本發明為經由組合複數 的螢光體,而可取得更接近純的白色。 圖5為示出本發明發光裝置之第五實施形態之LED燈。本 實施形態為將藍色LED4保護免受到靜電等之過電壓,且對 圖1構成之光源追加過電壓保護元件9 1為其構成。 如圖5所示般,過電壓保護元件9丨為被晶片化成為與誌 533604 、發明說明(20) LED4同程度之大小,且被配設於藍色LED4與支柱5之 二°於本貫施形態中,與圖1之情況不同,因為後述之理 ’,將藍色LED4予以倒裝接合(f lip chip)組裝。過電 ^保4 το件91為具備與藍色LE])4及導線框1接續用之電極 92 93。電極92為被設置於圖2所示之P電極48之對向位 置又,電極93為被設置於n電極4 9之對向位置,更且為 了易與接合電線6接續,乃於過電壓保護元件91之側面延 伸形成。過電壓保護元件91上之電極92、93為分別透過Au 凸起物94a、94b而接續至藍色LED4之?電極48、n電極49。 此過電壓保濩元件9 1若外加規定電壓以上之電壓,則可使 用於吸收通電狀恶之齊納二極管(zener di〇de)、脈衝性 電壓之電容器等。
圖6為不出於過電壓保護元件9丨使用齊納二極管時之接 續電路。做為過電壓保護元件91之齊納二極管95為對藍色 LEDj以電性並列接續,且藍gLED4之陰極和齊納二極管 之陽極為接續。導線框丨與導線框2之間外加過大電壓時, 其電壓若超過齊納二極管95之齊納電壓,則藍&led4之端 子間電壓為保持於齊納電壓,無法變成齊納電壓以上。因 此,可防止對藍色LED4外加過大之電壓,保護藍色““免 受到過大電壓,並且防止元件破壞和性能惡化之發生。 圖7為示出於過電壓保護元件91使用電容器時之接續電 路。做為過電壓保護元件91之電容器96可使用表面組裝用 之晶片(chip type c⑽ponent)。此類構造之電容器“為 於兩側設置帶狀電極,此電極為並列接續至藍色led4之陽
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五、發明說明(21) 極及陰極。導線框1與導線框2之間外加過大電壓時,經由 此過大電壓令充電電流流至電容器96,使得電容器96 2 , 子間電壓瞬時下降,對於藍色LED4之外加電壓不會上而 故可保護藍色LED4免受到過電壓。又,外加含有高周成 分之雜訊時,亦因電容器96可作用為分流(bypass)電衮^ 之機能,故可排除外來的雜訊。 口口 如上述, 合組裝。其 電壓保護元 藍色LED4與 為接地數增 的接觸、斷 色LED4予以 41之下面做 電壓保護元 色LED4 。尚 電極5 0可代 極48之表面 體,並將其 如以上所 光源的基本 靜電等外加 化。又,因 將藍色LED4 藍色LED4為相對於圖!進行上下反轉之倒裝接 理由為因設置過電壓保護元件91,故必須將過 件91與藍色LED4兩者予以電性接續。假定,將 過電壓保護元件91分別以接合電線接續時,因 加^故生產性降低,又,因為接地電線彼此間 線等增加,故恐導致信賴性降低。於是,將藍 倒裝接合組裝。即,以圖2所示之寶藍色基板 為最上面’且Ρ極48透過Au凸起94b而接續至過 件91之電極93,且接合電線6、7不會接續至藍 μ將藍色LED4倒裝接合時,圖2所示之透光性 :非,光性之電極。又,將n電極變厚成與p電 同一南度’或者,對η電極42接續新的導電 做為電極亦可。 ^明般’若根據圖5之構成,於圖1所示構成之 ^果亡加上設置過電壓保護元件9 1,則即使以 2電壓’亦不會令藍色LED4損傷,導致性能惡 ;,電,保護元件91可作用為次支柱,故即使 乂倒裝接合’亦不會令接合電線67晶片側
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之接合位置的高度降低 局度之位置下進行接合 故可在與圖1構成情 況大約相同 尚,於圖5及圖6中,於過電壓保護元件91使用 件时,亦可使用一般的矽二極管代替齊納二極管Μ。 /元 時,將複數個矽二極管作成同一極性並且直列 j ^ 部之順方向電壓下降(約〇. 7V x個數)值為令動;= 於過電壓地決定石夕二極管的使用根數。 目田 又’於過電壓保護元件91亦可使用可變電阻元件 (variable registor)。此可變電阻元件為具有隨著外加 電壓之增加而令電阻值減少之特性,且與齊納二4極 ° 樣可抑制過電壓。 问 圖8為示出本發明發光裝置之第六實施形態之半導體發 光裝置。 χ 此圖8所示之半導體發光裝置為將來自發光元件所發出 之光予以波長轉換並且放射至透鏡型之樹脂封裝體外部, 除了含有前述圖1所示之導線框1、2、和金屬電子管心柱 3、和藍色LED4、和支柱5、和接合電線6、7、和不含螢光 體1 1之内部樹脂8、和外部樹脂9、和杯1 0之構成以外,具 備將外部樹脂9之外面密合包圍且含有螢光體丨丨之透光性 螢光罩1 0 0為其構成。 螢光罩100為例如含有樹脂基材中以藍色LED4之發光所 讀文發發出螢光之螢光體11而形成。樹脂基材例如為透光性 之聚i旨樹脂、丙烯樹脂、胺基甲酸酯、尼龍、聚矽氧樹 月曰、氯乙稀、聚苯乙烯、鄰驗酸樹脂(Bekelite)、
533604 五、發明說明(23) 龍9(聚m—氧醇,.碳酸醋樹脂)等’胺基甲酸醋、尼 可_=1= 於榮光罩100賦與某程度之彈性,故 J幸二易裝黏至外部樹脂9。 筒ΐ狀ΐίΓ方〇〇人為以密合外部樹脂9外面之形⑻,即於圓 Λ半球形狀之罩以—體形成之形狀,於外 ρ树月日9上可自由脫除安裝。又,罄亦人k , Ι!#ί^ 罩ιοο為將含有螢弁㈣…Λ 狀為#。更且,螢光 狀德虚外部與先體11树雁以射出成型形成指定之形 樹"Λ Λ 密合則可較簡單完成,但為了令外部 之樹脂原料直接噴霧二層承乃將含有螢光體11 可。 、卜邛树月曰9後,硬化形成螢光罩10 0亦 於如此所構成之半導體發光裝置中,來 二光為透過内部樹脂以外部肖脂9彳射至螢光罩1〇。。之此射 至夕d Ϊ:ί螢光體11所吸收,同時轉換波長並射出 ^ 、13 螢光罩10 〇之外面所觀測的發光色為將此 i光合成之顏色,例如由前述之原理而呈白色。 =此,若根據第六實施形態之半導體發光裝置,則於藍 之:ϊΐΐϊ之内部樹脂8及外部樹脂9中不含有榮 先體11而々復盍外部樹脂9外面之螢光罩1〇〇含有體
11 ’故於内部樹脂8及夕卜立β姑4 η匕q 士 丁 X .^ J θ8及外邛樹知9中不會產生螢光體1 1所造 成的先政亂。X,因為螢光罩1〇〇為以 光體U所造成之光散亂較*。因此,經由將夕卜“脂^ 透鏡部形狀作成任意形狀(上述實施形態為半球狀)則可取 90132753.ptd 第28頁 533604
所伴 隨之亮度降低抑 且可將波長轉換 五、發明說明(24) 得所欲的光指向性 制至最小限度。 此外,經由改變螢光罩100之基鉍由π人‘ 若將螢光罩100之安裝構造作成易脫Λ除構、1 之發光色。 #人上 肌矛、構造,並且準備數 種含有不同種類螢光體11之螢光罩1〇〇, 千角双 ® ΐΑ „ 貝〗僅將邊光罩1 0 0 更換即可輕易令射出光之色調可變。 又’螢光體11除了於螢光罩100中含有以外,若於榮光 罩1 〇 〇之表面塗佈含有,則可取得同樣之效果。更且,因 為可於市售之半導體發光元件上裝附螢光罩1〇〇,故可 價製造半導體發光裝置。 可利用性 如上述,本發明之具有發光元件和螢光體的發光裝置可 適於led顯示器、背光裝置、信號機、照光式開關、各種 感應器、各種指示器。 思—件轉L^j兒明 1 導線框 2 導線框 金屬電子管心柱
4 藍色LED 5 支柱 5 接合電線 7 接合電線 8 内部樹脂
533604 五、發明說明 (25) 9 外部樹脂 10 杯 11 螢光體 41 藍寶石基板 42 緩衝層 43 η型導電層 44 η型覆蓋層 45 MQW活性層 46 Ρ型覆蓋層 47 Ρ型導電層 48 ρ電極 49 Π電極 50 透光性電極 70 導光板 70a 射出面 71 光反射盒 72 反射面 73 光擴散模樣 74 透明薄膜 80 基板 81 圖型配線 82 圖型配線 83 框體 83a 杯
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90132753.ptd 第31頁 533604 圖式簡單說明 圖1為本發明發光裝置之第二實施形態之LED燈的截面 圖。 圖2為示出圖1所示之藍色LED層構造之截面圖。 圖3為示出本發明發光裝置之第三實施形態之面狀光源 用裝置之構造,(a)為平面圖,(b)為(a)之A-A線截面圖。 圖4為本發明發光裝置之第四實施形態之SMD(Surface Mounted Device)型之LED燈的截面圖。 圖5為本發明發光裝置之第五實施形態之L E D燈的截面 圖。 圖6為對過電壓保護元件使用齊納二極管時的接續電路 圖。 圖7為對過電壓保護元件使用電容器時的接續電路圖。 圖8為本發明發光裝置之第六實施形態之半導體發光裝 置的截面圖。
90132753.ptd 第32頁
Claims (1)
- 533604 案號 90132753 修正 92. 2. ί 2 翁綠.太 六、申請專利範圍 1. 一種發光裝置,其特徵為於具備氮化物半導體所構成 之發光元件、和吸收該發光元件所發出之一部分光,並且 發出具有與此吸收光之波長不同波長光之螢光體的發光裝 置中, 該螢光體為由鹼土金屬矽酸鹽所構成。 2. 如申請專利範圍第1項之發光裝置,其中,該螢光體 為由經銪活化之鹼土金屬矽酸鹽所構成。 3. 如申請專利範圍第1項之發光裝置,其中,該螢光體 為由經二價銪活化之鹼土金屬矽酸鹽所構成。 4 ·如申請專利範圍第1項之發光裝置,其中,該螢光體 為式. (2-x-y)SrO -x(Ba,Ca)0 · (l-a-b-c-d)Si02 -aP205 bAl2 03 cB2 03 dGe02 -y Eu2+ (式中,0<χ<1·6、 0.005 <y<0.5、 0<a、b、c、d<0.5) 所示之經二價銪活化之鹼土金屬原矽酸鹽和/或 (2-x-y)Ba0 - x(Sr,Ca)0 -(l-a-b-c-cDSiOg -aP2 05 bAl203 cB2 03 dGe02 · y Eu2+ (式中,0· 01 <x <1· 6、 0.005 <y <0.5、 0<a、b、c、d<0.5) 所示之驗土金屬原石夕酸鹽,此時,有利令a、b、c及d之值 中之至少一個為大於0 . 0 1。C:\專利案件總檔案\90\90132753\90]32753(替換)-l.ptc 第 33 頁 533604 ΛΜ 901327.^__科年f>月」> 日其中,該螢光體 六、申請專利範圍 5 ·如申請專利範圍第1項之發光裝置 為被混入覆蓋該發光元件之覆被材料中 6 ·如申請專利範圍第5項之發光裝置, 料為由聚矽氧樹脂所構成。 7. 如申請專利範圍第5項之發光裝置, 料為由環氧樹脂所構成。 8. 如申請專利範圍第5項之發光裝置, 料為由低熔點玻璃所構成。 9 ·如申请專利範圍第5至8項中任一項之 中,該螢光體Λ祜、、曰入舜堂#八1 χ疋我置,其 ]η ^由」^ 覆盍光元件之覆被材料中。 10. 如申5月專利範圍第5至8項中任一項之中 中,該覆被材料為再以透明之第二覆被材料天予以衣,其 11. 如申睛專利範圍第1項之發光裝置,其中,=现。 件為於發光層中含有銦。 〃 5亥發光元 12·如申請專利範圍第丨或丨丨項之發光 光7L件為具有具備於ρ型覆蓋層與η型覆蓋声二,該發 光層的雙層異質構造。 斤夾住之發 13·如申請專利範圍第12項之發光裝置,盆中 盍層為由八^^⑼^夂^所構成, 型覆 該η型覆蓋層為由AlyGVyN(但,〇^y<i)所構成 /4·如申請專利範圍第13項之發光裝置,其中,該 蓋層之帶間隙為大於n型覆蓋層的帶間隙。 1復 1 5·如申請專利範圍第i 2項之發光裝置,其中,該 几件之發光層為由量子井構造所構成。 又 其中 其中 該覆被材 該覆被材 其中,該覆被材 ___ C:\ 專利案件總檔案\90\90132753\90132753(替換)·ΐ. Ptc第34頁 533604案號901320 六、申請專利範圍 也1 6’如申請專利範圍第1 5項之發光裝置,其中,該量子 井構造為由InGaN所槿点 .r q w ^ ^ 〆里子 組成。 焉成之井層、和GaN所構成之阻擋層所 1 7·、如申請專利範圍第i 5項之發光裝置,其中,該 井構造為由I n G a N所椹成+ # a $ a i r 〇 μ πw里子 所組成。 厅構成之井層、和AiGaN所構成之阻擋層 18.如申請專利範圍第15項之發光裝置’其 井構造為由AUnGaN所構成之和AHnGa 或置子 層所組成, W構成之阻擋 該阻擋層之帶間隙能量為大於該井層之帶間旦。 1 9.如申請專利範圍第i 5項之發光裝置,其、 之厚度為100A以下。 ' ’该井層 2 0 ·如申請專利範圍第1 2項之發光裝置,其中 别变# 】和/或η型覆蓋層為由彼此組成不同之氮化物口 ^ 層之超格子構造所構成。 牛 2 1.如申請專利範圍第1項之發光裝置,1 件為經由絕緣性之接黏劑而被固定於框。八,該勒光元 22.如申請專利範圍第21項之發光裝置,其 劑為透明。 、T 5亥接黏 請專利範圍第21似項之發光裝置,i中,9 l由含有該鹼土金屬矽酸鹽所構成之該螢光辦。以 24.如申請專利範圍第21項之發光 赏九月豆 劑為白色。 衣置,其中,該接黏 2 5·如申請專利範圍第1項之發光裝盆 /、宁,該發光元_|_1 c:\專利案件總檔案\9〇\9〇]32753、9〇1;32753(替換w.ptc第35頁 533604533604 曰 修正 案號 901327Μ 六、申請專利範圍 配置之GaN系半導體所構成之發光元 吸收該發光元件所發出之一部/ 吸收光之波長不同波長光之螢光體、亚且發出具有與此 令含有該螢光體之封裝劑充 、 覆蓋該塗層材料、該發光元件及該:柱j f層材料、和 模材料之發光裝置中, ^ ^往^線之前端之塑 該螢光體為由鹼土金屬矽酸鹽所構成。 3 7 · —種發光裝置,1特 裝之GaN系化合物半導具備框體内倒裝接合組 ^ 千^ 所構成之led晶片所構成之發光元 件、和 吸收該LED晶片所發出之一部分光,並且發出具有與此 吸收光之波長不同波長光之螢光體、和 以含有該螢光體之透明封裝劑充填配設該LED晶片之框 體内之塑模材料之發光裝置中, 該螢光體為由鹼土金屬矽酸鹽所構成,經由將該LED晶 片所發出之光和該螢光體所發出之光之混合,則玎放射出 白色光。 38·如申請專利範圍第36或37項之發光裝置,其中,該人 發光兀件為於一者之面側具有p側及n側電極,且被配置方、 金屬框上,且p電極及η電極為分別以金線予以電線接合’ 透過該金線所供給之電壓而發光成藍色。 > 3 9·如申請專利範圍第36或37項之發光裝置,其中’該人 發光元件為被配置於該杯内,並覆蓋該發光元件且以低方、 該杯上面邊緣部配置該螢光體。 wm m c:\專利案件總檔案\90\90]32753\90]32753(替換)-l.ptc 第 37 頁533604 _案號90132753_7年 > 月’> 曰 修正_ 六、申請專利範圍 4 〇.如申請專利範圍第1項之發光裝置,其中,該發光元 件為經由保護元件而被保護免受到靜電。 4 1.如申請專利範圍第4 0項之發光裝置,其中,該保護 元件為齊納二極管或電容器。 4 2.如申請專利範圍第40項之發光裝置,其中,該保護 元件為由齊納二極管所構成之次支柱, 該發光元件為被配置於該次支柱上,且,周圍為經該螢 光體所覆蓋。 4 3. —種發光裝置,其特徵為於具備支柱導線之杯内所 配置之GaN系化合物半導體所構成之發光元件、和 吸收該發光元件所發出之一部分光,並且發出具有與此 吸收光之波長不同波長光之螢光體、和 覆盖該發光元件及該支柱導線之前端之塑模材料之發光 裝置中, 該螢光體為由鹼土金屬矽酸鹽所構成,且被含有於構成 覆蓋該塑模材料之螢光蓋的樹脂基材中。c:\專利案件總檔案\9〇\9〇132753\9〇132753(替換M.ptc第38頁
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