MX2014012548A - Methods and structures for reducing carbon oxides with non-ferrous catalysts. - Google Patents

Methods and structures for reducing carbon oxides with non-ferrous catalysts.

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Publication number
MX2014012548A
MX2014012548A MX2014012548A MX2014012548A MX2014012548A MX 2014012548 A MX2014012548 A MX 2014012548A MX 2014012548 A MX2014012548 A MX 2014012548A MX 2014012548 A MX2014012548 A MX 2014012548A MX 2014012548 A MX2014012548 A MX 2014012548A
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MX
Mexico
Prior art keywords
carbon
catalyst
carbon oxide
reactor
ferrous
Prior art date
Application number
MX2014012548A
Other languages
Spanish (es)
Inventor
Dallas B Noyes
Original Assignee
Seerstone Llc
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Publication date
Application filed by Seerstone Llc filed Critical Seerstone Llc
Publication of MX2014012548A publication Critical patent/MX2014012548A/en

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    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/05Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24Chromium, molybdenum or tungsten
    • B01J23/28Molybdenum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24Chromium, molybdenum or tungsten
    • B01J23/30Tungsten
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/75Cobalt
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    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
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    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
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    • B01J23/85Chromium, molybdenum or tungsten
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    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16Reducing
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01J37/16Reducing
    • B01J37/18Reducing with gases containing free hydrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
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Abstract

A method of reducing a gaseous carbon oxide includes reacting a carbon oxide with a gaseous reducing agent in the presence of a non-ferrous catalyst. The reaction proceeds under conditions adapted to produce solid carbon of various allotropes and morphologies, the selective formation of which can be controlled by means of controlling reaction gas composition and reaction conditions including temperature and pressure. A method for utilizing a non-ferrous catalyst in a reactor includes placing the catalyst in a suitable reactor and flowing reaction gases comprising a carbon oxide with at least one gaseous reducing agent through the reactor where, in the presence of the catalyst, at least a portion of the carbon in the carbon oxide is converted to solid carbon and a tail gas mixture containing water vapor.
MX2014012548A 2012-04-16 2013-03-15 Methods and structures for reducing carbon oxides with non-ferrous catalysts. MX2014012548A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261624702P 2012-04-16 2012-04-16
PCT/US2013/000072 WO2013158156A1 (en) 2012-04-16 2013-03-15 Methods and structures for reducing carbon oxides with non-ferrous catalysts

Publications (1)

Publication Number Publication Date
MX2014012548A true MX2014012548A (en) 2015-04-10

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MX2014012548A MX2014012548A (en) 2012-04-16 2013-03-15 Methods and structures for reducing carbon oxides with non-ferrous catalysts.

Country Status (6)

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US (1) US9796591B2 (en)
EP (1) EP2838837A4 (en)
JP (1) JP6328611B2 (en)
CN (1) CN104271498B (en)
MX (1) MX2014012548A (en)
WO (1) WO2013158156A1 (en)

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US9221685B2 (en) 2012-04-16 2015-12-29 Seerstone Llc Methods of capturing and sequestering carbon
EP2838837A4 (en) 2012-04-16 2015-12-23 Seerstone Llc Methods and structures for reducing carbon oxides with non-ferrous catalysts
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EP2838839B1 (en) 2012-04-16 2020-08-12 Seerstone LLC Method for producing solid carbon by reducing carbon dioxide
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US9604848B2 (en) 2012-07-12 2017-03-28 Seerstone Llc Solid carbon products comprising carbon nanotubes and methods of forming same
US10815124B2 (en) 2012-07-12 2020-10-27 Seerstone Llc Solid carbon products comprising carbon nanotubes and methods of forming same
WO2014011206A1 (en) 2012-07-13 2014-01-16 Seerstone Llc Methods and systems for forming ammonia and solid carbon products
US9779845B2 (en) 2012-07-18 2017-10-03 Seerstone Llc Primary voltaic sources including nanofiber Schottky barrier arrays and methods of forming same
JP6389824B2 (en) 2012-11-29 2018-09-12 シーアストーン リミテッド ライアビリティ カンパニー Reactor and method for producing solid carbon material
WO2014151138A1 (en) 2013-03-15 2014-09-25 Seerstone Llc Reactors, systems, and methods for forming solid products
EP3114077A4 (en) 2013-03-15 2017-12-27 Seerstone LLC Methods of producing hydrogen and solid carbon
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US10115844B2 (en) 2013-03-15 2018-10-30 Seerstone Llc Electrodes comprising nanostructured carbon
US9783421B2 (en) 2013-03-15 2017-10-10 Seerstone Llc Carbon oxide reduction with intermetallic and carbide catalysts
WO2018022999A1 (en) 2016-07-28 2018-02-01 Seerstone Llc. Solid carbon products comprising compressed carbon nanotubes in a container and methods of forming same
WO2018075123A1 (en) 2016-10-19 2018-04-26 Vanderbilt University Nanostructured carbon materials and methods of making and use thereof
CN106485993A (en) * 2016-11-12 2017-03-08 罗相平 Linesless charcoal reductive copper oxide teaching and experiment method and its equipment
US11383196B2 (en) * 2017-06-02 2022-07-12 Monalaser, Llc Method and apparatus for decomposing carbon dioxide gas
KR102384914B1 (en) * 2017-06-08 2022-04-08 에스케이이노베이션 주식회사 Method for the production of carbon nanotubes in a fluidized bed reactor
JP7539623B2 (en) * 2019-01-28 2024-08-26 カーボノバ コーポレイション Apparatus and method for producing carbon nanofibers from light hydrocarbons
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