KR20020084087A - 단일 벽을 이룬 탄소 나노튜브를 대규모로 제조하기 위한고수율의 기상 증착 방법 - Google Patents

단일 벽을 이룬 탄소 나노튜브를 대규모로 제조하기 위한고수율의 기상 증착 방법 Download PDF

Info

Publication number
KR20020084087A
KR20020084087A KR1020027008727A KR20027008727A KR20020084087A KR 20020084087 A KR20020084087 A KR 20020084087A KR 1020027008727 A KR1020027008727 A KR 1020027008727A KR 20027008727 A KR20027008727 A KR 20027008727A KR 20020084087 A KR20020084087 A KR 20020084087A
Authority
KR
South Korea
Prior art keywords
carbon
drying process
catalyst
group
combinations
Prior art date
Application number
KR1020027008727A
Other languages
English (en)
Korean (ko)
Inventor
리우지
Original Assignee
듀크 유니버시티
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 듀크 유니버시티 filed Critical 듀크 유니버시티
Publication of KR20020084087A publication Critical patent/KR20020084087A/ko

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/32Carbides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/88Molybdenum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/88Molybdenum
    • B01J23/881Molybdenum and iron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8906Iron and noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/32Freeze drying, i.e. lyophilisation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00Manufacture or treatment of nanostructures
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/15Nano-sized carbon materials
    • C01B32/158Carbon nanotubes
    • C01B32/16Preparation
    • C01B32/162Preparation characterised by catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00Structure or properties of carbon nanotubes
    • C01B2202/02Single-walled nanotubes
KR1020027008727A 2000-01-07 2001-01-05 단일 벽을 이룬 탄소 나노튜브를 대규모로 제조하기 위한고수율의 기상 증착 방법 KR20020084087A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US17487400P 2000-01-07 2000-01-07
US60/174,874 2000-01-07
PCT/US2001/000335 WO2001049599A2 (fr) 2000-01-07 2001-01-05 Procede de depot en phase vapeur a haut rendement pour la preparation a grande echelle de nanotubes de carbone a paroi simple

Publications (1)

Publication Number Publication Date
KR20020084087A true KR20020084087A (ko) 2002-11-04

Family

ID=22637890

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020027008727A KR20020084087A (ko) 2000-01-07 2001-01-05 단일 벽을 이룬 탄소 나노튜브를 대규모로 제조하기 위한고수율의 기상 증착 방법

Country Status (7)

Country Link
EP (1) EP1252360A4 (fr)
JP (1) JP2003520176A (fr)
KR (1) KR20020084087A (fr)
CN (1) CN1418260A (fr)
AU (1) AU5287601A (fr)
CA (1) CA2395807A1 (fr)
WO (1) WO2001049599A2 (fr)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020172767A1 (en) * 2001-04-05 2002-11-21 Leonid Grigorian Chemical vapor deposition growth of single-wall carbon nanotubes
ES2238582T5 (es) 2001-07-03 2010-05-26 Facultes Universitaires Notre-Dame De La Paix Soportes de catalizador y nanotubos de carbono producidos sobre dichos soportes.
GB0216654D0 (en) * 2002-07-17 2002-08-28 Univ Cambridge Tech CVD Synthesis of carbon nanoutubes
US6974493B2 (en) 2002-11-26 2005-12-13 Honda Motor Co., Ltd. Method for synthesis of metal nanoparticles
US6974492B2 (en) 2002-11-26 2005-12-13 Honda Motor Co., Ltd. Method for synthesis of metal nanoparticles
US7214361B2 (en) * 2002-11-26 2007-05-08 Honda Giken Kogyo Kabushiki Kaisha Method for synthesis of carbon nanotubes
GB2399092B (en) * 2003-03-03 2005-02-16 Morgan Crucible Co Nanotube and/or nanofibre synthesis
WO2006041170A1 (fr) * 2004-10-15 2006-04-20 Ngk Insulators, Ltd. Méthode de fabrication d’un matériau poreux
US7485600B2 (en) * 2004-11-17 2009-02-03 Honda Motor Co., Ltd. Catalyst for synthesis of carbon single-walled nanotubes
US7871591B2 (en) * 2005-01-11 2011-01-18 Honda Motor Co., Ltd. Methods for growing long carbon single-walled nanotubes
CA2500766A1 (fr) 2005-03-14 2006-09-14 National Research Council Of Canada Methode et appareil de production et de fonctionnalisation en continu de nanotubes de carbone a simple paroi au moyen d'une torche a plasma inductif haute frequence
EP1797950A1 (fr) * 2005-12-14 2007-06-20 Nanocyl S.A. Catalyseur pour la fabrication de nanotubes de carbone à parois multiples
WO2008016390A2 (fr) 2006-01-30 2008-02-07 Honda Motor Co., Ltd. Catalyseur de la croissance de nanotubes de carbone monoparoi
JP5055520B2 (ja) * 2006-02-24 2012-10-24 独立行政法人産業技術総合研究所 多孔質構造体及びその製造方法
US9005755B2 (en) 2007-01-03 2015-04-14 Applied Nanostructured Solutions, Llc CNS-infused carbon nanomaterials and process therefor
US8951631B2 (en) 2007-01-03 2015-02-10 Applied Nanostructured Solutions, Llc CNT-infused metal fiber materials and process therefor
US8951632B2 (en) 2007-01-03 2015-02-10 Applied Nanostructured Solutions, Llc CNT-infused carbon fiber materials and process therefor
JP5753102B2 (ja) * 2009-02-27 2015-07-22 アプライド ナノストラクチャード ソリューションズ リミテッド ライアビリティー カンパニーApplied Nanostructuredsolutions, Llc ガス予熱方法を用いた低温cnt成長
US20100224129A1 (en) 2009-03-03 2010-09-09 Lockheed Martin Corporation System and method for surface treatment and barrier coating of fibers for in situ cnt growth
US8969225B2 (en) 2009-08-03 2015-03-03 Applied Nano Structured Soultions, LLC Incorporation of nanoparticles in composite fibers
EP2616189B1 (fr) 2010-09-14 2020-04-01 Applied NanoStructured Solutions, LLC Substrats en verre présentant des nanotubes de carbone qui ont grandi sur ceux-ci et procédés pour la production de ceux-ci
KR101877475B1 (ko) 2010-09-22 2018-07-11 어플라이드 나노스트럭처드 솔루션스, 엘엘씨. 탄소 나노튜브가 성장된 탄소 섬유 기판 및 그의 제조 방법
JP6042314B2 (ja) * 2012-12-04 2016-12-14 本田技研工業株式会社 カーボンナノチューブ成長用基板及びその製造方法
JP6041775B2 (ja) * 2013-09-13 2016-12-14 本田技研工業株式会社 カーボンナノチューブ成長用基板及びその製造方法
JP7254809B2 (ja) * 2017-09-18 2023-04-10 ウェスト バージニア ユニバーシティ 調整可能な根元成長多層カーボンナノチューブ用の触媒とプロセス
JP7360133B2 (ja) * 2018-07-31 2023-10-12 株式会社大阪ソーダ カーボンナノチューブの製造方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4713233A (en) * 1985-03-29 1987-12-15 Allied Corporation Spray-dried inorganic oxides from non-aqueous gels or solutions
US4916108A (en) * 1988-08-25 1990-04-10 Westinghouse Electric Corp. Catalyst preparation using supercritical solvent
JP3285614B2 (ja) * 1992-07-30 2002-05-27 日本碍子株式会社 排ガス浄化用触媒及びその製造方法
US6004436A (en) * 1996-08-16 1999-12-21 The Regents Of The University Of California Processes for the chemical modification of inorganic aerogels
KR100376197B1 (ko) * 1999-06-15 2003-03-15 일진나노텍 주식회사 탄소 소오스 가스 분해용 촉매금속막을 이용한탄소나노튜브의 저온 합성 방법

Also Published As

Publication number Publication date
EP1252360A2 (fr) 2002-10-30
EP1252360A4 (fr) 2006-07-26
AU5287601A (en) 2001-07-16
WO2001049599A2 (fr) 2001-07-12
CA2395807A1 (fr) 2001-07-12
JP2003520176A (ja) 2003-07-02
CN1418260A (zh) 2003-05-14
WO2001049599A3 (fr) 2002-03-07

Similar Documents

Publication Publication Date Title
US20030012722A1 (en) High yiel vapor phase deposition method for large scale sing walled carbon nanotube preparation
KR20020084087A (ko) 단일 벽을 이룬 탄소 나노튜브를 대규모로 제조하기 위한고수율의 기상 증착 방법
Su et al. A scalable CVD method for the synthesis of single-walled carbon nanotubes with high catalyst productivity
Qingwen et al. A scalable CVD synthesis of high-purity single-walled carbon nanotubes with porous MgO as support material
Venegoni et al. Parametric study for the growth of carbon nanotubes by catalytic chemical vapor deposition in a fluidized bed reactor
Stamatin et al. The synthesis of multi-walled carbon nanotubes (MWNTs) by catalytic pyrolysis of the phenol-formaldehyde resins
JP5102633B2 (ja) 長いカーボン単層ナノチューブを成長させるための方法
JP5065898B2 (ja) 狭小な直径分布のカーボン単層ナノチューブの合成
US9126828B2 (en) Mixed structures of single walled and multi walled carbon nanotubes
US20040022719A1 (en) Process for the mass production of multiwalled carbon nanotubes
Jeong et al. Narrow diameter distribution of singlewalled carbon nanotubes grown on Ni–MgO by thermal chemical vapor deposition
Méhn et al. A comparison of different preparation methods of Fe/Mo/Al2O3 sol–gel catalyst for synthesis of single wall carbon nanotubes
Liu et al. Co/carbon-nanotube monometallic system: the effects of oxidation by nitric acid
Yardimci et al. The effects of catalyst pretreatment, growth atmosphere and temperature on carbon nanotube synthesis using Co–Mo/MgO catalyst
KR20090019777A (ko) 금속층으로부터의 단일 벽 탄소 나노튜브의 제조 방법
JP2003206117A (ja) 多層カーボンナノチューブの大量生産方法
US8562935B2 (en) Amplification of carbon nanotubes via seeded-growth methods
Dong et al. Effects of hydrogen on the formation of aligned carbon nanotubes by chemical vapor deposition
CN112978715A (zh) 一种以醇类溶剂为碳源的碳纳米管及其制备方法
Ruan et al. Oxygen as the growth enhancer of carbon nanotubes in solid-state pyrolysis of organometallic precursors
Somanathan et al. Catalytic activity of Fe, Co and Fe-Co-MCM-41 for the growth of carbon nanotubes by chemical vapour deposition method
Zhang et al. Few walled carbon nanotube production in large-scale by nano-agglomerate fluidized-bed process
Seelan et al. Synthesis of multiwalled carbon nanotubes by high-temperature vacuum annealing of amorphous carbon
Rao et al. Nanostructured forms of carbon: an overview
US20220298017A1 (en) Long and Narrow Diameter Carbon Nanotubes and Catalysts for Producing Same

Legal Events

Date Code Title Description
WITN Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid