CA2395807A1 - Procede de depot en phase vapeur a haut rendement pour la preparation a grande echelle de nanotubes de carbone a paroi simple - Google Patents

Procede de depot en phase vapeur a haut rendement pour la preparation a grande echelle de nanotubes de carbone a paroi simple Download PDF

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Publication number
CA2395807A1
CA2395807A1 CA002395807A CA2395807A CA2395807A1 CA 2395807 A1 CA2395807 A1 CA 2395807A1 CA 002395807 A CA002395807 A CA 002395807A CA 2395807 A CA2395807 A CA 2395807A CA 2395807 A1 CA2395807 A1 CA 2395807A1
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CA
Canada
Prior art keywords
aerogel
carbon
catalyst
combinations
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002395807A
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English (en)
Inventor
Jie Liu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Duke University
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2395807A1 publication Critical patent/CA2395807A1/fr
Abandoned legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/32—Carbides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/881—Molybdenum and iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8906—Iron and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/32—Freeze drying, i.e. lyophilisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C01B32/16—Preparation
    • C01B32/162—Preparation characterised by catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00—Structure or properties of carbon nanotubes
    • C01B2202/02—Single-walled nanotubes

Abstract

La présente invention concerne un procédé amélioré de dépôt en phase vapeur destiné à la préparation de nanotubes de carbone à paroi simple sur un catalyseur métallique supporté sur aérogel. Le rendement total de nanotubes de carbone à paroi simple est souvent égal à au moins 100 % environ, sur la base du poids du catalyseur, pour un temps de réaction d'au moins 30 minutes environ.
CA002395807A 2000-01-07 2001-01-05 Procede de depot en phase vapeur a haut rendement pour la preparation a grande echelle de nanotubes de carbone a paroi simple Abandoned CA2395807A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US17487400P 2000-01-07 2000-01-07
US60/174,874 2000-01-07
PCT/US2001/000335 WO2001049599A2 (fr) 2000-01-07 2001-01-05 Procede de depot en phase vapeur a haut rendement pour la preparation a grande echelle de nanotubes de carbone a paroi simple

Publications (1)

Publication Number Publication Date
CA2395807A1 true CA2395807A1 (fr) 2001-07-12

Family

ID=22637890

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002395807A Abandoned CA2395807A1 (fr) 2000-01-07 2001-01-05 Procede de depot en phase vapeur a haut rendement pour la preparation a grande echelle de nanotubes de carbone a paroi simple

Country Status (7)

Country Link
EP (1) EP1252360A4 (fr)
JP (1) JP2003520176A (fr)
KR (1) KR20020084087A (fr)
CN (1) CN1418260A (fr)
AU (1) AU5287601A (fr)
CA (1) CA2395807A1 (fr)
WO (1) WO2001049599A2 (fr)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020172767A1 (en) * 2001-04-05 2002-11-21 Leonid Grigorian Chemical vapor deposition growth of single-wall carbon nanotubes
ES2238582T5 (es) 2001-07-03 2010-05-26 Facultes Universitaires Notre-Dame De La Paix Soportes de catalizador y nanotubos de carbono producidos sobre dichos soportes.
GB0216654D0 (en) * 2002-07-17 2002-08-28 Univ Cambridge Tech CVD Synthesis of carbon nanoutubes
US6974493B2 (en) 2002-11-26 2005-12-13 Honda Motor Co., Ltd. Method for synthesis of metal nanoparticles
US6974492B2 (en) 2002-11-26 2005-12-13 Honda Motor Co., Ltd. Method for synthesis of metal nanoparticles
US7214361B2 (en) * 2002-11-26 2007-05-08 Honda Giken Kogyo Kabushiki Kaisha Method for synthesis of carbon nanotubes
GB2399092B (en) * 2003-03-03 2005-02-16 Morgan Crucible Co Nanotube and/or nanofibre synthesis
WO2006041170A1 (fr) * 2004-10-15 2006-04-20 Ngk Insulators, Ltd. Méthode de fabrication d’un matériau poreux
US7485600B2 (en) * 2004-11-17 2009-02-03 Honda Motor Co., Ltd. Catalyst for synthesis of carbon single-walled nanotubes
US7871591B2 (en) * 2005-01-11 2011-01-18 Honda Motor Co., Ltd. Methods for growing long carbon single-walled nanotubes
CA2500766A1 (fr) 2005-03-14 2006-09-14 National Research Council Of Canada Methode et appareil de production et de fonctionnalisation en continu de nanotubes de carbone a simple paroi au moyen d'une torche a plasma inductif haute frequence
EP1797950A1 (fr) * 2005-12-14 2007-06-20 Nanocyl S.A. Catalyseur pour la fabrication de nanotubes de carbone à parois multiples
WO2008016390A2 (fr) 2006-01-30 2008-02-07 Honda Motor Co., Ltd. Catalyseur de la croissance de nanotubes de carbone monoparoi
JP5055520B2 (ja) * 2006-02-24 2012-10-24 独立行政法人産業技術総合研究所 多孔質構造体及びその製造方法
US9005755B2 (en) 2007-01-03 2015-04-14 Applied Nanostructured Solutions, Llc CNS-infused carbon nanomaterials and process therefor
US8951631B2 (en) 2007-01-03 2015-02-10 Applied Nanostructured Solutions, Llc CNT-infused metal fiber materials and process therefor
US8951632B2 (en) 2007-01-03 2015-02-10 Applied Nanostructured Solutions, Llc CNT-infused carbon fiber materials and process therefor
JP5753102B2 (ja) * 2009-02-27 2015-07-22 アプライド ナノストラクチャード ソリューションズ リミテッド ライアビリティー カンパニーＡｐｐｌｉｅｄ Ｎａｎｏｓｔｒｕｃｔｕｒｅｄｓｏｌｕｔｉｏｎｓ， Ｌｌｃ ガス予熱方法を用いた低温ｃｎｔ成長
US20100224129A1 (en) 2009-03-03 2010-09-09 Lockheed Martin Corporation System and method for surface treatment and barrier coating of fibers for in situ cnt growth
US8969225B2 (en) 2009-08-03 2015-03-03 Applied Nano Structured Soultions, LLC Incorporation of nanoparticles in composite fibers
EP2616189B1 (fr) 2010-09-14 2020-04-01 Applied NanoStructured Solutions, LLC Substrats en verre présentant des nanotubes de carbone qui ont grandi sur ceux-ci et procédés pour la production de ceux-ci
KR101877475B1 (ko) 2010-09-22 2018-07-11 어플라이드 나노스트럭처드 솔루션스, 엘엘씨. 탄소 나노튜브가 성장된 탄소 섬유 기판 및 그의 제조 방법
JP6042314B2 (ja) * 2012-12-04 2016-12-14 本田技研工業株式会社 カーボンナノチューブ成長用基板及びその製造方法
JP6041775B2 (ja) * 2013-09-13 2016-12-14 本田技研工業株式会社 カーボンナノチューブ成長用基板及びその製造方法
JP7254809B2 (ja) * 2017-09-18 2023-04-10 ウェスト バージニア ユニバーシティ 調整可能な根元成長多層カーボンナノチューブ用の触媒とプロセス
JP7360133B2 (ja) * 2018-07-31 2023-10-12 株式会社大阪ソーダ カーボンナノチューブの製造方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4713233A (en) * 1985-03-29 1987-12-15 Allied Corporation Spray-dried inorganic oxides from non-aqueous gels or solutions
US4916108A (en) * 1988-08-25 1990-04-10 Westinghouse Electric Corp. Catalyst preparation using supercritical solvent
JP3285614B2 (ja) * 1992-07-30 2002-05-27 日本碍子株式会社 排ガス浄化用触媒及びその製造方法
US6004436A (en) * 1996-08-16 1999-12-21 The Regents Of The University Of California Processes for the chemical modification of inorganic aerogels
KR100376197B1 (ko) * 1999-06-15 2003-03-15 일진나노텍 주식회사 탄소 소오스 가스 분해용 촉매금속막을 이용한탄소나노튜브의 저온 합성 방법

Also Published As

Publication number Publication date
KR20020084087A (ko) 2002-11-04
EP1252360A2 (fr) 2002-10-30
EP1252360A4 (fr) 2006-07-26
AU5287601A (en) 2001-07-16
WO2001049599A2 (fr) 2001-07-12
JP2003520176A (ja) 2003-07-02
CN1418260A (zh) 2003-05-14
WO2001049599A3 (fr) 2002-03-07

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