JP2007525600A - 鉄−リン電気めっき浴および方法 - Google Patents
鉄−リン電気めっき浴および方法 Download PDFInfo
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- JP2007525600A JP2007525600A JP2007501772A JP2007501772A JP2007525600A JP 2007525600 A JP2007525600 A JP 2007525600A JP 2007501772 A JP2007501772 A JP 2007501772A JP 2007501772 A JP2007501772 A JP 2007501772A JP 2007525600 A JP2007525600 A JP 2007525600A
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- iron
- bath
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- 238000009713 electroplating Methods 0.000 title claims abstract description 44
- DPTATFGPDCLUTF-UHFFFAOYSA-N phosphanylidyneiron Chemical compound [Fe]#P DPTATFGPDCLUTF-UHFFFAOYSA-N 0.000 title claims abstract description 33
- 238000000034 method Methods 0.000 title claims abstract description 10
- -1 phosphinic acid ions Chemical class 0.000 claims abstract description 42
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 32
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 31
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 31
- 239000011593 sulfur Substances 0.000 claims abstract description 31
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 29
- 239000000956 alloy Substances 0.000 claims abstract description 29
- 150000001875 compounds Chemical class 0.000 claims abstract description 27
- 239000000758 substrate Substances 0.000 claims abstract description 20
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 18
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 17
- 229910052742 iron Inorganic materials 0.000 claims abstract description 17
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 17
- 239000011574 phosphorus Substances 0.000 claims abstract description 17
- 230000002378 acidificating effect Effects 0.000 claims abstract description 11
- 229920002873 Polyethylenimine Polymers 0.000 claims abstract description 7
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 6
- OARRHUQTFTUEOS-UHFFFAOYSA-N safranin Chemical compound [Cl-].C=12C=C(N)C(C)=CC2=NC2=CC(C)=C(N)C=C2[N+]=1C1=CC=CC=C1 OARRHUQTFTUEOS-UHFFFAOYSA-N 0.000 claims abstract description 6
- 150000003460 sulfonic acids Chemical class 0.000 claims abstract description 6
- 238000007747 plating Methods 0.000 claims description 41
- 229910001096 P alloy Inorganic materials 0.000 claims description 13
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical group O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 11
- 239000001257 hydrogen Substances 0.000 claims description 11
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 239000008139 complexing agent Substances 0.000 claims description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 229910021577 Iron(II) chloride Inorganic materials 0.000 claims description 5
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 claims description 5
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 5
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 5
- 239000001011 safranin dye Substances 0.000 claims description 5
- 150000001340 alkali metals Chemical group 0.000 claims description 4
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 125000000623 heterocyclic group Chemical group 0.000 claims description 3
- 150000002431 hydrogen Chemical group 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- SQZYOZWYVFYNFV-UHFFFAOYSA-L iron(2+);disulfamate Chemical compound [Fe+2].NS([O-])(=O)=O.NS([O-])(=O)=O SQZYOZWYVFYNFV-UHFFFAOYSA-L 0.000 claims description 3
- NULNPXHQQOCYIL-UHFFFAOYSA-L iron(2+);methanesulfonate Chemical compound [Fe+2].CS([O-])(=O)=O.CS([O-])(=O)=O NULNPXHQQOCYIL-UHFFFAOYSA-L 0.000 claims description 3
- PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical class [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims 2
- 238000002485 combustion reaction Methods 0.000 claims 1
- 238000004070 electrodeposition Methods 0.000 claims 1
- 150000002506 iron compounds Chemical class 0.000 claims 1
- 239000002244 precipitate Substances 0.000 abstract description 25
- 238000005336 cracking Methods 0.000 abstract description 3
- 230000000052 comparative effect Effects 0.000 description 11
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 10
- 229910000831 Steel Inorganic materials 0.000 description 9
- 238000000137 annealing Methods 0.000 description 9
- 239000010959 steel Substances 0.000 description 9
- 238000012360 testing method Methods 0.000 description 8
- 239000000835 fiber Substances 0.000 description 7
- 239000010936 titanium Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
- 229910052719 titanium Inorganic materials 0.000 description 5
- 150000003755 zirconium compounds Chemical class 0.000 description 5
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 4
- 239000010419 fine particle Substances 0.000 description 4
- 229910000838 Al alloy Inorganic materials 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000000399 optical microscopy Methods 0.000 description 3
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 3
- 238000000634 powder X-ray diffraction Methods 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- QNAYBMKLOCPYGJ-UHFFFAOYSA-N Alanine Chemical compound CC([NH3+])C([O-])=O QNAYBMKLOCPYGJ-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- 229910001111 Fine metal Inorganic materials 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- JZQOJFLIJNRDHK-CMDGGOBGSA-N alpha-irone Chemical compound CC1CC=C(C)C(\C=C\C(C)=O)C1(C)C JZQOJFLIJNRDHK-CMDGGOBGSA-N 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000002198 insoluble material Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- CEHCOJSZSZWUIG-UHFFFAOYSA-M sodium;propyl sulfate Chemical compound [Na+].CCCOS([O-])(=O)=O CEHCOJSZSZWUIG-UHFFFAOYSA-M 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- 229910000859 α-Fe Inorganic materials 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910018125 Al-Si Inorganic materials 0.000 description 1
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- 229910018520 Al—Si Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical class [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229910017060 Fe Cr Inorganic materials 0.000 description 1
- 229910002544 Fe-Cr Inorganic materials 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- 229910001060 Gray iron Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 239000002211 L-ascorbic acid Substances 0.000 description 1
- 235000000069 L-ascorbic acid Nutrition 0.000 description 1
- 229910000861 Mg alloy Inorganic materials 0.000 description 1
- 229910017318 Mo—Ni Inorganic materials 0.000 description 1
- 240000007930 Oxalis acetosella Species 0.000 description 1
- 235000008098 Oxalis acetosella Nutrition 0.000 description 1
- 229910020220 Pb—Sn Inorganic materials 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- XPLRYTOINDRIQD-UHFFFAOYSA-M S(=O)(=O)(OCCCS)[O-].[Na+] Chemical compound S(=O)(=O)(OCCCS)[O-].[Na+] XPLRYTOINDRIQD-UHFFFAOYSA-M 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910020888 Sn-Cu Inorganic materials 0.000 description 1
- 229910020935 Sn-Sb Inorganic materials 0.000 description 1
- 229910019204 Sn—Cu Inorganic materials 0.000 description 1
- 229910008757 Sn—Sb Inorganic materials 0.000 description 1
- 229910000639 Spring steel Inorganic materials 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 238000000441 X-ray spectroscopy Methods 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- GEIAQOFPUVMAGM-UHFFFAOYSA-N ZrO Inorganic materials [Zr]=O GEIAQOFPUVMAGM-UHFFFAOYSA-N 0.000 description 1
- 229960003767 alanine Drugs 0.000 description 1
- 229910000905 alloy phase Inorganic materials 0.000 description 1
- CSDREXVUYHZDNP-UHFFFAOYSA-N alumanylidynesilicon Chemical compound [Al].[Si] CSDREXVUYHZDNP-UHFFFAOYSA-N 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 229910021387 carbon allotrope Inorganic materials 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- UPHIPHFJVNKLMR-UHFFFAOYSA-N chromium iron Chemical compound [Cr].[Fe] UPHIPHFJVNKLMR-UHFFFAOYSA-N 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- WIYCQLLGDNXIBA-UHFFFAOYSA-L disodium;3-(3-sulfonatopropyldisulfanyl)propane-1-sulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)CCCSSCCCS([O-])(=O)=O WIYCQLLGDNXIBA-UHFFFAOYSA-L 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 229950010030 dl-alanine Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 229950006191 gluconic acid Drugs 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000005367 kimax Substances 0.000 description 1
- 239000002648 laminated material Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000002113 nanodiamond Substances 0.000 description 1
- 239000002071 nanotube Substances 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 229940116315 oxalic acid Drugs 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- TYRGSDXYMNTMML-UHFFFAOYSA-N propyl hydrogen sulfate Chemical compound CCCOS(O)(=O)=O TYRGSDXYMNTMML-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 238000004846 x-ray emission Methods 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/562—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of iron or nickel or cobalt
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/20—Electroplating: Baths therefor from solutions of iron
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Electroplating Methods And Accessories (AREA)
- Cylinder Crankcases Of Internal Combustion Engines (AREA)
Abstract
【解決手段】1つの実施形態においては、本発明は、(A)鉄が電解で析出し得る少なくとも1つの化合物と、(B)ホスフィン酸イオンと、(C)スルホアルキル化ポリエチレンイミン、スルホン化サフラニン染料、およびメルカプト脂肪族スルホン酸もしくはそのアルカリ金属塩から選択される硫黄含有化合物とを含む、水性で酸性の鉄リン浴に関する。任意で、本発明の水性で酸性の鉄リン浴は、アルミニウムイオンをさらに含む。本発明の方法によって基板上に析出される合金は、鉄、リンおよび硫黄の存在を特徴とする。
Description
(A)鉄が電解で析出し得る少なくとも1つの化合物と、
(B)ホスフィン酸イオンと、
(C)スルホアルキル化ポリエチレンイミン、スルホン化サフラニン染料、およびメルカプト脂肪族スルホン酸もしくはそのアルカリ金属塩から選択される硫黄含有化合物とを含む、水性で酸性の鉄リン浴に関する。
任意で、本発明の水性で酸性の鉄リン電気めっき浴は、さらに、アルミニウムイオンを含み得る。
(A)上記の酸性で水性の電気めっき浴を準備する工程と、
(B)前記浴を用いて基板上に合金を電着させる工程とを含む、
導電基板上に鉄−リン合金を電着する方法に関する。
本発明の方法によって基板上に析出される合金は、鉄、リンおよび硫黄の存在を特徴とする。
(A)鉄が電解で析出し得る少なくとも1つの化合物と、
(B)ホスフィン酸イオンと、
(C)スルホアルキル化ポリエチレンイミン、スルホン化サフラニン染料、およびメルカプト脂肪族スルホン酸もしくはそのアルカリ金属塩から選択される硫黄含有化合物とを含む、水性で酸性の鉄リン浴に関する。
Y−S−R1−SO3X (1)
ここで、Xは水素またはアルカリ金属であり、R1は1〜約5個の炭素原子を含むアルキレン基であり、Yは水素、S−R1−SO3X、C(S)NR2”、C(S)OR” 、C(NH2)NR2” 、または複素環基であり、R”はそれぞれ独立して水素または1〜約5個の炭素原子を含むアルキル基である。
別の実施形態においては、R1は水素または1〜3個の炭素原子を含むアルキレン基であり、R”は水素またはメチル基である。
(1)320、400および600グリットのサンドペーパーで、心棒を順次磨く
(2)心棒の重さを量る
(3)めっきされない領域にテープを貼り、めっきされる領域を注意して測る
(4)高温アルカリ電気洗浄剤中の標準液浸に続き、冷水洗浄(CWR)、希塩酸中の短時間の液浸、および、2回目の冷水洗浄により、めっき用の鋼鉄の心棒を準備する
(5)標準二重亜鉛酸塩処理により、めっき用のアルミニウム心棒およびパネルを準備する
である。
Claims (24)
- (A)鉄が電解で析出し得る少なくとも1つの化合物と、
(B)ホスフィン酸イオンと、
(C)スルホアルキル化ポリエチレンイミン、スルホン化サフラニン染料、およびメルカプト脂肪族スルホン酸もしくはそのアルカリ金属塩から選択される硫黄含有化合物とを含む、
水性で酸性の鉄リン浴。 - 前記鉄化合物が、塩化鉄(II)、硫酸鉄(II)、フッ化ホウ素酸鉄(II)、メタンスルホン酸鉄(II)、スルファミン酸鉄(II)、およびこれらの混合物から選択される、請求項1に記載の浴。
- 前記ホスフィン酸イオン源が、ホスフィン酸、アルカリ金属ホスフィン酸塩、またはこれらの混合物である、請求項1に記載の浴。
- 前記硫黄含有化合物が、メルカプト脂肪族スルホン酸もしくはそのアルカリ金属塩、またはこれらの混合物である、請求項1に記載の浴。
- 前記硫黄含有化合物が、下記式(1)で表される、請求項1に記載の浴:
Y−S−R1−SO3X (1)
ここで、Xは水素またはアルカリ金属であり、R1は1〜約5個の炭素原子を含むアルキレン基であり、Yは水素、S−R1−SO3X、C(S)NR2”、C(S)OR” 、C(NH2)NR2” 、または複素環基であり、R”はそれぞれ独立して水素または1〜約5個の炭素原子を含むアルキル基である。 - アルミニウムイオンをさらに含む、請求項1に記載の電気めっき浴。
- pHが約0.5〜約5である、請求項1に記載の浴。
- 錯化剤を含まない、請求項1に記載の浴。
- 前記鉄(II)イオン源が、硫酸鉄(II)および塩化鉄(II)を含む、請求項1に記載の浴。
- (A)約20〜約120g/lの鉄(II)イオンと、
(B)ホスフィン酸イオンとして供給される、約0.2〜約8g/lのリンと、
(C)スルホアルキル化ポリエチレンイミン、スルホン化サフラニン染料、およびメルカプト脂肪族スルホン酸もしくはそのアルカリ金属塩から選択される硫黄含有化合物として存在する約0.001〜約0.5g/lの硫黄とを含む、
水性で酸性の鉄リン電気めっき浴。 - 前記鉄(II)イオンが、塩化鉄(II)、硫酸鉄(II)、フッ化ホウ素酸鉄(II)、メタンスルホン酸鉄(II)、スルファミン酸鉄(II)、およびこれらの混合物から選択される少なくとも1つの塩として存在する、請求項10に記載の電気めっき浴。
- 前記リンが、ホスフィン酸、アルカリ金属ホスフィン酸塩、またはこれらの混合物として存在する、請求項10に記載の電気めっき浴。
- 前記硫黄含有化合物が、メルカプト脂肪族スルホン酸化合物もしくはその塩である、請求項10に記載の電気めっき浴。
- 前記硫黄含有化合物が、下記式(1)で表される、請求項10に記載のめっき浴:
Y−S−R1−SO3X (1)
ここで、Xは水素またはアルカリ金属であり、R1は1〜約5個の炭素原子を含むアルキレン基であり、Yは水素、S−R1−SO3X、C(S)NR2”、C(S)OR” 、C(NH2)NR2” 、または複素環基であり、R”はそれぞれ独立して水素または1〜約5個の炭素原子を含むアルキル基である。 - 約0.1〜約10g/lのアルミニウムイオンをさらに含む、請求項10に記載の電気めっき浴。
- pHが約0.8〜約2.5である、請求項10に記載のめっき浴。
- 錯化剤を含まない、請求項10に記載のめっき浴。
- (A)請求項1に記載の酸性で水性の電気めっき浴を準備する工程と、
(B)前記浴を用いて基板上に合金を電着させる工程とを含む、
導電基板上に鉄−リン合金を電着する方法。 - 前記基板が、内燃機関のシリンダーである、請求項18に記載の方法。
- (A)請求項10に記載の酸性で水性の電気めっき浴を準備する工程と、
(B)前記浴を用いて基板上に合金を電着させる工程とを含む、
導電基板上に鉄−リン合金を電着する方法。 - その上に電着された鉄−リン合金を有する導電基板であって、
該電着合金は、請求項1に記載の浴から電着させることによって形成されている、導電基板。 - 前記合金が、原子百分率で約1〜約30%のリンを含む、請求項21に記載の導電基板。
- 前記合金が、原子百分率で約70〜約99%の鉄を含む、請求項21に記載の導電基板。
- 前記合金が、原子百分率で約0.1〜約0.5%の硫黄を含む、請求項21に記載の導電基板。
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US10/790,365 US7494578B2 (en) | 2004-03-01 | 2004-03-01 | Iron-phosphorus electroplating bath and method |
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JP (1) | JP4532539B2 (ja) |
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Cited By (4)
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JP2010100927A (ja) * | 2008-09-26 | 2010-05-06 | Nissei Plastics Ind Co | めっき被覆アルミニウム製品 |
WO2012053283A1 (ja) * | 2010-10-20 | 2012-04-26 | ユケン工業株式会社 | 電気めっき浴および電気めっき皮膜の形成方法並びに電気めっき製品 |
WO2013015608A2 (en) * | 2011-07-27 | 2013-01-31 | Yoon Jong-Oh | Zirconium alloy electroplating solution composition and plated product using the same |
JP2013144852A (ja) * | 2013-03-18 | 2013-07-25 | Yuken Industry Co Ltd | 電気めっき浴および電気めっき皮膜の形成方法並びに電気めっき製品 |
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US7494578B2 (en) * | 2004-03-01 | 2009-02-24 | Atotech Deutschland Gmbh | Iron-phosphorus electroplating bath and method |
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KR101657465B1 (ko) * | 2014-12-18 | 2016-09-19 | 주식회사 포스코 | 무방향성 전기강판 및 그 제조방법 |
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DE102021125366A1 (de) * | 2021-09-30 | 2023-03-30 | Federal-Mogul Burscheid Gmbh | Verschleißschutzschicht für Kolbenringe |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5396933A (en) * | 1977-02-07 | 1978-08-24 | Mine Tomohiro | Hard iron plating method |
JPS60131993A (ja) * | 1983-12-21 | 1985-07-13 | C Uyemura & Co Ltd | 鉄・リン電気めつき浴 |
JPS60131999A (ja) * | 1983-12-21 | 1985-07-13 | Toyota Motor Corp | 摺動部材及びその製造方法 |
JPS60165384A (ja) * | 1984-02-09 | 1985-08-28 | C Uyemura & Co Ltd | 鉄・リン電気めつき浴 |
JPS62109991A (ja) * | 1985-07-29 | 1987-05-21 | C Uyemura & Co Ltd | 電気めつき液 |
JPH05140719A (ja) * | 1991-11-18 | 1993-06-08 | Nippon Steel Corp | 溶融亜鉛系合金化めつき鋼板の製造方法 |
JPH10140388A (ja) * | 1996-11-13 | 1998-05-26 | Toyota Motor Corp | 鉄・リン電気めっき浴 |
JP2003526015A (ja) * | 2000-03-09 | 2003-09-02 | アトーテヒ ドイッチュラント ゲゼルシャフト ミット ベシュレンクテル ハフツング | 軽金属表面に金属層を施与するための方法 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3086927A (en) | 1960-08-29 | 1963-04-23 | Horst Corp Of America V D | Iron-phosphorus electroplating |
CA1072910A (en) | 1976-05-20 | 1980-03-04 | Satoru Uedaira | Method of manufacturing amorphous alloy |
CA1255246A (en) | 1983-05-14 | 1989-06-06 | Toshio Irie | Corrosion resistant surface-treated steel strip and process for making |
US4533441A (en) | 1984-03-30 | 1985-08-06 | Burlington Industries, Inc. | Practical amorphous iron electroform and method for achieving same |
US4746412A (en) * | 1986-07-03 | 1988-05-24 | C. Uyemura & Co., Ltd. | Iron-phosphorus electroplating bath and electroplating method using same |
US4968391A (en) | 1988-01-29 | 1990-11-06 | Nippon Steel Corporation | Process for the preparation of a black surface-treated steel sheet |
CN1051060A (zh) * | 1990-11-10 | 1991-05-01 | 机械电子工业部武汉材料保护研究所 | 耐磨非晶态铁镍磷合金电沉积溶液及其工艺 |
JP3373329B2 (ja) | 1995-05-18 | 2003-02-04 | シャープ株式会社 | 画像伝送装置 |
DE19601265A1 (de) | 1996-01-16 | 1997-07-17 | Bayer Ag | 2-Oxo- und 2-Thio-1,2-dihydrochinolinyl-oxazolidinone |
US6284123B1 (en) | 1998-03-02 | 2001-09-04 | Briggs & Stratton Corporation | Electroplating formulation and process for plating iron onto aluminum/aluminum alloys |
US7494578B2 (en) * | 2004-03-01 | 2009-02-24 | Atotech Deutschland Gmbh | Iron-phosphorus electroplating bath and method |
-
2004
- 2004-03-01 US US10/790,365 patent/US7494578B2/en not_active Expired - Fee Related
- 2004-12-27 TW TW093140721A patent/TWI276706B/zh not_active IP Right Cessation
-
2005
- 2005-01-11 WO PCT/US2005/000791 patent/WO2005093134A2/en active Application Filing
- 2005-01-11 CA CA2558466A patent/CA2558466C/en not_active Expired - Fee Related
- 2005-01-11 CN CN2005800064110A patent/CN1926265B/zh not_active Expired - Fee Related
- 2005-01-11 BR BRPI0508287-0A patent/BRPI0508287A/pt not_active Application Discontinuation
- 2005-01-11 JP JP2007501772A patent/JP4532539B2/ja not_active Expired - Fee Related
- 2005-01-11 EP EP05705444A patent/EP1721029A2/en not_active Withdrawn
- 2005-02-28 MY MYPI20050817A patent/MY145292A/en unknown
-
2006
- 2006-09-28 KR KR1020067020126A patent/KR101153048B1/ko not_active IP Right Cessation
-
2007
- 2007-04-27 HK HK07104567.8A patent/HK1097008A1/xx not_active IP Right Cessation
-
2008
- 2008-12-23 US US12/342,468 patent/US7588675B2/en not_active Expired - Fee Related
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5396933A (en) * | 1977-02-07 | 1978-08-24 | Mine Tomohiro | Hard iron plating method |
JPS60131993A (ja) * | 1983-12-21 | 1985-07-13 | C Uyemura & Co Ltd | 鉄・リン電気めつき浴 |
JPS60131999A (ja) * | 1983-12-21 | 1985-07-13 | Toyota Motor Corp | 摺動部材及びその製造方法 |
JPS60165384A (ja) * | 1984-02-09 | 1985-08-28 | C Uyemura & Co Ltd | 鉄・リン電気めつき浴 |
JPS62109991A (ja) * | 1985-07-29 | 1987-05-21 | C Uyemura & Co Ltd | 電気めつき液 |
JPH05140719A (ja) * | 1991-11-18 | 1993-06-08 | Nippon Steel Corp | 溶融亜鉛系合金化めつき鋼板の製造方法 |
JPH10140388A (ja) * | 1996-11-13 | 1998-05-26 | Toyota Motor Corp | 鉄・リン電気めっき浴 |
JP2003526015A (ja) * | 2000-03-09 | 2003-09-02 | アトーテヒ ドイッチュラント ゲゼルシャフト ミット ベシュレンクテル ハフツング | 軽金属表面に金属層を施与するための方法 |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010100927A (ja) * | 2008-09-26 | 2010-05-06 | Nissei Plastics Ind Co | めっき被覆アルミニウム製品 |
WO2012053283A1 (ja) * | 2010-10-20 | 2012-04-26 | ユケン工業株式会社 | 電気めっき浴および電気めっき皮膜の形成方法並びに電気めっき製品 |
JP2012087380A (ja) * | 2010-10-20 | 2012-05-10 | Yuken Industry Co Ltd | 電気めっき浴および電気めっき皮膜の形成方法並びに電気めっき製品 |
WO2013015608A2 (en) * | 2011-07-27 | 2013-01-31 | Yoon Jong-Oh | Zirconium alloy electroplating solution composition and plated product using the same |
WO2013015608A3 (en) * | 2011-07-27 | 2013-04-04 | Yoon Jong-Oh | Zirconium alloy electroplating solution composition and plated product using the same |
JP2013144852A (ja) * | 2013-03-18 | 2013-07-25 | Yuken Industry Co Ltd | 電気めっき浴および電気めっき皮膜の形成方法並びに電気めっき製品 |
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CA2558466C (en) | 2012-01-03 |
EP1721029A2 (en) | 2006-11-15 |
TW200530432A (en) | 2005-09-16 |
HK1097008A1 (en) | 2007-06-15 |
TWI276706B (en) | 2007-03-21 |
KR20060134136A (ko) | 2006-12-27 |
US20090101515A1 (en) | 2009-04-23 |
CN1926265A (zh) | 2007-03-07 |
WO2005093134A3 (en) | 2006-05-04 |
CA2558466A1 (en) | 2005-10-06 |
US20050189232A1 (en) | 2005-09-01 |
CN1926265B (zh) | 2010-09-22 |
KR101153048B1 (ko) | 2012-06-04 |
JP4532539B2 (ja) | 2010-08-25 |
MY145292A (en) | 2012-01-13 |
BRPI0508287A (pt) | 2007-08-07 |
WO2005093134A2 (en) | 2005-10-06 |
US7588675B2 (en) | 2009-09-15 |
US7494578B2 (en) | 2009-02-24 |
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