HU213909B - Polypropilenes made by new chemical degradation and process for producing them - Google Patents
Polypropilenes made by new chemical degradation and process for producing them Download PDFInfo
- Publication number
- HU213909B HU213909B HU9401696A HU9401696A HU213909B HU 213909 B HU213909 B HU 213909B HU 9401696 A HU9401696 A HU 9401696A HU 9401696 A HU9401696 A HU 9401696A HU 213909 B HU213909 B HU 213909B
- Authority
- HU
- Hungary
- Prior art keywords
- polypropylenes
- elastic
- tert
- priority
- polypropylene
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/50—Partial depolymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/10—Chemical modification of a polymer including a reactive processing step which leads, inter alia, to morphological and/or rheological modifications, e.g. visbreaking
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
Abstract
A találmány tárgyát őlyan pőliprőpilének képezik, amelyekelasztikűs pőliprőpilének szerves perőxidőkkal végzett kémiailebőntásával nyerhetők. A találmány tővábbi tárgya eljárás az újpőliprőpilének előállítására. ŕ
Claims (8)
1. Javított tulajdonságokkal rendelkező polipropilének, azzaljellemezve, hogy elasztikus polipropiléneknek vagy polipropilének és elasztikus polipropilének keverékeinek szerves peroxidokkal, adott esetben szokásos adalék- és/vagy töltőanyagok jelenlétében végzett kémiai lebontásával nyerhetők.
(Elsőbbsége: 1994. július 1.)
2. Az 1. igénypont szerinti polipropilének, azzal jellemezve, hogy a lebontáshoz felhasznált elasztikus polipropilén folyási száma 230 °C-on és 2,16 kg terhelés mellett kisebb, mint 0,1 g/10 perc.
(Elsőbbsége: 1994. július 1.)
3. Az 1. vagy 2. igénypont szerinti polipropilének, azzal jellemezve, hogy peroxidként bisz[2-(l,l-dimetil— etil)-peroxi-izopropil]-benzolt vagy di(terc-butil)-peroxidot használunk előállításokat.
(Elsőbbsége: 1994. július 1.)
4. Az 1-3. igénypontok bármelyike szerinti polipropilének, azzaljellemezve, hogy adalékanyagként 2,6-di(terc-butil)-4-metil-fenolt, pentaeritritil-tetrakisz[3-(3,5-di-terc-butil)-4-hidroxi-fenil]-propionátot, trisz(2,4-di(terc-buti)-fenil)-foszfitot vagy tetrakisz (2,4-di/terc-butil/-fenil)-4,4-bifenilén-difoszfonitot, illetve ezek keverékét használjuk előállításuk során.
(Elsőbbsége: 1994. július 1.)
5. Eljárás javított tulajdonságokkal rendelkező polipropilének előállítására, azzal jellemezve, hogy elasztikus polipropiléneket vagy polipropilének és elasztikus polipropilének keverékét, adott esetben szokásos adalékanyagok és/vagy töltőanyagok hozzáadása mellett, szerves peroxidokkal degradáljuk.
(Elsőbbsége: 1993. június 7.)
6. Az 5. igénypont szerinti eljárás, azzal jellemezve, hogy a polipropilének tömegére számított 0,05-0,5 tömeg% peroxidot használunk.
(Elsőbbsége: 1993. június 7.)
7. Az 5. vagy 6. igénypont szerinti eljárás, azzal jellemezve, hogy a degradálást (lebontást) 190-240 °Con végezzük.
(Elsőbbsége: 1993. június 7.)
8. Az 5-7. igénypontok bármelyike szerinti eljárás, azzal jellemezve, hogy a degradálást (lebontást) folytonos üzemben egy extrúderben végezzük.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT0109993A AT403581B (de) | 1993-06-07 | 1993-06-07 | Verfahren zur herstellung von neuen polypropylenen durch chemische degradierung |
Publications (3)
Publication Number | Publication Date |
---|---|
HU9401696D0 HU9401696D0 (en) | 1994-09-28 |
HUT69321A HUT69321A (en) | 1995-09-28 |
HU213909B true HU213909B (en) | 1997-11-28 |
Family
ID=3506574
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
HU9401696A HU213909B (en) | 1993-06-07 | 1994-06-06 | Polypropilenes made by new chemical degradation and process for producing them |
Country Status (14)
Country | Link |
---|---|
US (1) | US5705568A (hu) |
EP (1) | EP0632062B1 (hu) |
JP (1) | JPH07138315A (hu) |
KR (1) | KR100331584B1 (hu) |
CN (1) | CN1061053C (hu) |
AT (2) | AT403581B (hu) |
CZ (1) | CZ137794A3 (hu) |
DE (1) | DE59404251D1 (hu) |
ES (1) | ES2110143T3 (hu) |
FI (1) | FI942653A (hu) |
HU (1) | HU213909B (hu) |
NO (1) | NO306469B1 (hu) |
RU (1) | RU2141487C1 (hu) |
SK (1) | SK279635B6 (hu) |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5738745A (en) * | 1995-11-27 | 1998-04-14 | Kimberly-Clark Worldwide, Inc. | Method of improving the photostability of polypropylene compositions |
AT406684B (de) * | 1996-04-09 | 2000-07-25 | Danubia Petrochem Polymere | Verwendung von polypropylenen zur verbesserung der stabilität gegenüber ionisierender strahlung |
CN1072738C (zh) * | 1997-09-04 | 2001-10-10 | 中国石化扬子石油化工公司 | 一种制备聚丙烯纤维纺丝料的方法 |
AT407044B (de) | 1998-04-24 | 2000-11-27 | Borealis Ag | Verwendung von modifikatoren auf basis von ethylenpolymeren oder amorphen olefinelastomeren zur reduktion der oberflächenklebrigkeit von amorphen polypropylenen |
ITMI981213A1 (it) | 1998-06-01 | 1999-12-01 | Montell North America Inc | Polimeri propilenici adatti per film cast trasparenti |
FR2792321B1 (fr) | 1999-04-19 | 2003-12-12 | Atochem Elf Sa | Procede de fabrication d'une resine de polypropylene a rheologie controlee |
KR100718424B1 (ko) | 1999-12-22 | 2007-05-14 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 폴리프로필렌계 접착제 조성물 |
EP1186618A1 (en) * | 2000-09-08 | 2002-03-13 | ATOFINA Research | Controlled rheology polypropylene heterophasic copolymers |
EP1312617A1 (en) * | 2001-11-14 | 2003-05-21 | ATOFINA Research | Impact strength polypropylene |
WO2004046214A2 (en) | 2002-10-15 | 2004-06-03 | Exxonmobil Chemical Patents Inc. | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
US6855771B2 (en) * | 2002-10-31 | 2005-02-15 | Grant Doney | Process for making block polymers or copolymers from isotactic polypropylene |
US6869982B2 (en) * | 2002-11-27 | 2005-03-22 | Basell Poliolefine Italia S.P.A. | Irradiated, oxidized olefin polymer coupling agents |
JP2005099712A (ja) * | 2003-08-28 | 2005-04-14 | Sharp Corp | 表示装置の駆動回路および表示装置 |
CN101429308B (zh) * | 2007-11-08 | 2011-04-20 | 中国石油天然气股份有限公司 | 一种聚丙烯降解母粒的制造方法 |
JP5560450B2 (ja) * | 2010-09-01 | 2014-07-30 | 株式会社神戸製鋼所 | 混練押出機での粘度調整方法、および、混練押出機 |
US9388256B2 (en) * | 2012-09-21 | 2016-07-12 | Northwestern University | Peroxy-derivative functionalization of polypropylene via solid-state shear pulverization |
JP6538355B2 (ja) * | 2015-01-06 | 2019-07-03 | 中村留精密工業株式会社 | 旋削工具及び真球加工方法 |
WO2020056119A1 (en) * | 2018-09-14 | 2020-03-19 | Fina Technology, Inc. | Polyethylene and controlled rheology polypropylene polymer blends and methods of use |
CN111533994B (zh) * | 2020-05-09 | 2021-09-17 | 东华能源(张家港)新材料有限公司 | 一种高裂解率高熔指聚丙烯材料及其制备方法和应用 |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3144436A (en) * | 1961-01-04 | 1964-08-11 | Du Pont | Process for degrading stereoregular polymers |
NL298986A (hu) * | 1963-01-09 | 1900-01-01 | ||
US3480580A (en) * | 1965-10-22 | 1969-11-25 | Eastman Kodak Co | Modified polymers |
AT319589B (de) * | 1972-07-25 | 1974-12-27 | Chemie Linz Ag | Verfahren zur Herstellung von Polypropylen |
US4105837A (en) * | 1976-10-06 | 1978-08-08 | Hercules Incorporated | Conversion of stereoregular polypropylene to atactic polypropylene |
DE2830160A1 (de) * | 1977-07-12 | 1979-01-25 | Du Pont | Fraktionierbares elastisches polypropylen und verfahren zu seiner herstellung |
US4335225A (en) * | 1978-06-20 | 1982-06-15 | E. I. Du Pont De Nemours And Company | Elastomeric polypropylene |
DE3105830A1 (de) * | 1981-02-18 | 1982-09-09 | Harald 8871 Ellzee Hofmann | Abbau von polypropylen mittels azo-ester oder azo-aether |
DE63654T1 (de) * | 1981-04-23 | 1986-02-13 | Himont Inc., Wilmington, Del. | Verfahren zum kettenkracken von polypropylen. |
US4451589A (en) * | 1981-06-15 | 1984-05-29 | Kimberly-Clark Corporation | Method of improving processability of polymers and resulting polymer compositions |
CA1210176A (en) * | 1981-06-15 | 1986-08-19 | Michael T. Morman | Degradation of polypropylene for future improved processability |
SU1070138A1 (ru) * | 1982-01-07 | 1984-01-30 | Томское отделение Охтинского научно-производственного объединения "Пластполимер" | Способ получени модифицированного атактического полипропилена |
NO834504L (no) * | 1983-01-20 | 1984-07-23 | El Paso Polyolefins | Propylenkopolymerer med forbedret slagfasthet |
ES8403504A1 (es) * | 1983-01-27 | 1984-03-16 | Huerta Arevalo Gonzalo De | Procedimiento para la preparacion de un caucho sintetico poliolefinico. |
IN166935B (hu) * | 1985-01-31 | 1990-08-11 | Himont Inc | |
US4774293A (en) * | 1985-06-26 | 1988-09-27 | Akzo N.V. | Process for cross-linking or degrading polymers and shaped articles obtained by this process |
US4734448A (en) * | 1985-07-10 | 1988-03-29 | Idemitsu Petrochemical Co., Ltd. | Propylene polymer composition |
CA1296484C (en) * | 1986-01-28 | 1992-02-25 | Thomas William Smith | Process for the direct synthesis of highly amorphous propylene homopolymers and propylene-ethylene copolymers |
DE3742845C2 (de) * | 1987-12-17 | 1996-07-11 | Danubia Petrochem Deutschland | Verfahren zur Herstellung von faserverstärkten Polypropylenbahnen sowie faserverstärkte Polypropylenbahnen |
US5047485A (en) * | 1989-02-21 | 1991-09-10 | Himont Incorporated | Process for making a propylene polymer with free-end long chain branching and use thereof |
AU643315B2 (en) * | 1990-09-07 | 1993-11-11 | Huntsman Polymers Corporation | Amorphous elastomeric propylene homopolymers |
CA2049373A1 (en) * | 1990-09-07 | 1992-03-08 | Brian J. Pellon | Process for the production of amorphous elastomeric propylene homopolymers |
JP3016880B2 (ja) * | 1991-02-01 | 2000-03-06 | 三菱化学株式会社 | フィルム成形用高結晶性ポリプロピレン |
-
1993
- 1993-06-07 AT AT0109993A patent/AT403581B/de not_active IP Right Cessation
-
1994
- 1994-05-20 AT AT94107821T patent/ATE159034T1/de not_active IP Right Cessation
- 1994-05-20 DE DE59404251T patent/DE59404251D1/de not_active Expired - Fee Related
- 1994-05-20 ES ES94107821T patent/ES2110143T3/es not_active Expired - Lifetime
- 1994-05-20 EP EP94107821A patent/EP0632062B1/de not_active Revoked
- 1994-06-01 SK SK655-94A patent/SK279635B6/sk unknown
- 1994-06-04 KR KR1019940012617A patent/KR100331584B1/ko not_active IP Right Cessation
- 1994-06-04 CN CN94106505A patent/CN1061053C/zh not_active Expired - Fee Related
- 1994-06-06 RU RU94019973/04A patent/RU2141487C1/ru not_active IP Right Cessation
- 1994-06-06 CZ CZ941377A patent/CZ137794A3/cs unknown
- 1994-06-06 JP JP6124015A patent/JPH07138315A/ja active Pending
- 1994-06-06 NO NO942087A patent/NO306469B1/no unknown
- 1994-06-06 HU HU9401696A patent/HU213909B/hu not_active IP Right Cessation
- 1994-06-06 FI FI942653A patent/FI942653A/fi unknown
-
1996
- 1996-07-24 US US08/685,758 patent/US5705568A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
RU2141487C1 (ru) | 1999-11-20 |
SK65594A3 (en) | 1994-12-07 |
EP0632062A1 (de) | 1995-01-04 |
DE59404251D1 (de) | 1997-11-13 |
US5705568A (en) | 1998-01-06 |
JPH07138315A (ja) | 1995-05-30 |
SK279635B6 (sk) | 1999-01-11 |
FI942653A0 (fi) | 1994-06-06 |
HU9401696D0 (en) | 1994-09-28 |
EP0632062B1 (de) | 1997-10-08 |
RU94019973A (ru) | 1996-12-27 |
NO942087L (no) | 1994-12-08 |
FI942653A (fi) | 1994-12-08 |
KR100331584B1 (ko) | 2002-08-08 |
HUT69321A (en) | 1995-09-28 |
CN1107480A (zh) | 1995-08-30 |
CZ137794A3 (en) | 1995-03-15 |
AT403581B (de) | 1998-03-25 |
NO942087D0 (no) | 1994-06-06 |
ATA109993A (de) | 1997-08-15 |
NO306469B1 (no) | 1999-11-08 |
KR950000738A (ko) | 1995-01-03 |
ATE159034T1 (de) | 1997-10-15 |
CN1061053C (zh) | 2001-01-24 |
ES2110143T3 (es) | 1998-02-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
HU213909B (en) | Polypropilenes made by new chemical degradation and process for producing them | |
RU2141492C1 (ru) | Композиции из эластомерных полипропиленов и неолефиновых термопластов, способ их получения | |
US5639822A (en) | Process for the production of high-flow propylene/ethylene copolymers | |
AU682284B2 (en) | Modification of (co)polymers with cyclic ketone peroxides | |
JP3423058B2 (ja) | ラジカル性崩壊開始剤を用いるグラフト化プロピレン共重合体 | |
US7999046B2 (en) | Neutralization of deactivated polymerization catalyst using phosphoric or phosphonic acid salts | |
EP0316692B1 (en) | Propylene polymer composition | |
US5461119A (en) | Olefin polymers partially crosslinked with bismaleimido compounds | |
RU2140933C1 (ru) | Модифицированные эластомерные полипропилены, способ модификации эластомерных полипропиленов, композиция на основе полиолефинов и неолефиновых термопластов | |
EP1828286A1 (en) | Process for preparing trioxepane composition and use thereof in crosslinking polymers | |
JP3215187B2 (ja) | 改質プロピレン系重合体の製造方法 | |
JP2607099B2 (ja) | 高剛性エチレン−プロピレンブロック共重合体組成物 | |
DE4321529A1 (de) | Neue, durch chemische Degradierung erhältliche Polypropylene | |
JPS60215047A (ja) | ポリプロピレン組成物 | |
EP0533089B1 (en) | Liquid peroxidic compositions | |
WO2002032973A1 (en) | Flexible polypropylene resin | |
JPH08225495A (ja) | フェノール化合物およびその用途 | |
EP0803495B1 (en) | Phenolic compounds and uses thereof | |
EP0625525B1 (de) | Hochaktive Katalysatoren für die Olefinpolymerisation und Polymerisationsverfahren unter Verwendung dieser Katalysatoren | |
EP0570812B1 (en) | Process for the preparation of cross-linked olefin polymers | |
JPS63146953A (ja) | プロピレン樹脂組成物 | |
JP2741274B2 (ja) | 結晶性ポリオレフイン組成物 | |
JPH05306358A (ja) | プロピレン系共重合体の製造方法 | |
JPH0796588B2 (ja) | 架橋プロピレン系重合体の製造法 | |
JPH07165819A (ja) | 金属化合物により部分的架橋された合成樹脂材料 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
HMM4 | Cancellation of final prot. due to non-payment of fee |