WO2000066650A2 - Carboxylfunktionelles additiv zur aufkondensierung von polyamiden - Google Patents
Carboxylfunktionelles additiv zur aufkondensierung von polyamiden Download PDFInfo
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- WO2000066650A2 WO2000066650A2 PCT/EP2000/003757 EP0003757W WO0066650A2 WO 2000066650 A2 WO2000066650 A2 WO 2000066650A2 EP 0003757 W EP0003757 W EP 0003757W WO 0066650 A2 WO0066650 A2 WO 0066650A2
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- block
- oligo
- additive
- polyamide
- polyamides
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- GDOPTJXRTPNYNR-UHFFFAOYSA-N CC1CCCC1 Chemical compound CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/44—Polyester-amides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/04—Preparatory processes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
- C08G69/16—Preparatory processes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/38—Polyamides prepared from aldehydes and polynitriles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
Definitions
- the present invention relates to an additive for the condensation of oligo- and / or (co-) polyamides, its use for the condensation of oligo- and / or (co-) polyamides and a method for the condensation of oligo- and / or (co-) Polyamides
- Polyamides are macromolecules that contain the grouping -CO-NH- in the main chain. They are obtained either from two different bifunctional monomer units, each of which contains two identical reactive groups, eg -NH 2 or -COOH, or from uniform bifunctional units
- the main representatives are polyamide 6,6 and polyamide 6.
- the polyamide building blocks can be varied widely (A genuine, manual of technical polymer chemistry).
- Polyamides are, for example, by polycondensation reactions or by ineffective polymerization of lactams
- the molar mass of the polyamides depends heavily on the process conditions, since the technical properties of the polyamides depend on the one hand on the preparation, ie on the molar mass and on the content of monomers, oligomers and amino end groups, and on the other hand on the processing, ie on the degree of installation and the water content , become high demands are placed on the procedure in order to produce certain polyamides with constant quality, especially in the spin process, the exclusion of solid impurities and gel particles as well as the proper storage of the granules with exclusion of air and moisture
- polyamides which are processed in injection molding processes should have a higher melt index (MFI) than polyamides which are used as thermoplastic extrusion compositions
- MFI melt index
- Extrusion compounds usually have a higher relative molecular weight and thus a higher melt viscosity or a lower melt index, compared to injection molding compounds made from the same materials.
- melt viscosities or lower melt indices enable, among other things, better stamina after exiting the die when extruding.
- Higher relative molecular weight, higher melt viscosity or reduced melt index is also associated with improved mechanical values.
- processing in injection molding is more difficult
- DE-A-4 136 082, DE-A-4 136 083, DE-A-4 136 081, DE-A-4 136 078 and DE-A-4 136 079 disclose processes for the preparation of Rapidly condensed polyamides Dnsocyanates, blocked or blocked Dusocyanates or Ohgo- and / or polyurethanes are used as additives for rapid condensation
- EP-A-408957 discloses a further example for adjusting the viscosity of polyamide melts.
- certain (co) polyamides which dissolve in the lactam melt are used there, M Xanthos describes, in addition, in reactive extrusion, pnciples and practice, Hanser, Kunststoff (1992) the use of epoxy compounds for the condensation of polyamides
- Ciba-Geigy offers an additive to stabilize polyamides during recycling (EB 35-50). This is to compensate for the degradation during recycling by hydrolysis.However, the product information itself shows that the melt index of the stabilized polyamide increases again after multiple processing, ie it multiple extrusion is not possible
- the modified polyamides of the prior art show no stable further processing properties, ie multiple extrusion is only possible with a deterioration in mechanical properties. This is unacceptable for many applications, since the waste obtained, for example, in a spinning process, as a pure polymer, can often only be reused with renewed modification
- the additives used in the processes described above often react with other additives, such as stabilizers or processing agents. auxiliaries, which leads to side reactions and undesirable discoloration and necessitates an increased and therefore more expensive use of the additives
- This object is achieved by a process for the condensation of oligo- and / or (co-) polyamides, which is characterized in that at least one compound having at least two carbon atoms is used as an additive for the condensation
- the process according to the invention enables the condensation of oligo- and / or (co-) polyamides without causing gel formation and thus inhomogeneities. Furthermore, the additive used according to the invention is not or significantly less toxic than the previously used dnsocyanates and epoxy compounds and several times Processing of the condensation product obtained is possible both in dry and in moist form without the important mechanical parameters dropping
- the present invention provides the use of at least one compound having at least two carbonate units for the condensation of oligo- and / or (co-) polyamides
- the present invention provides an additive for the condensation of oligo- and / or (co-) polyamides
- condensation or Aufko ⁇ densiere ⁇ being used synonymously with the terms modification or modification. All ratios, unless stated otherwise, relate to the weight, and all molecular weights are weight means
- All possible polyamides can be used in the process according to the invention for the condensation of oligo- and / or (co-) polyamides. Illustrative examples of these are PA 6, PA 11, PA 12, PA 6.6, PA 6.10, PA 6.11, PA 6.12, PA 6.6 / 6, PA 4.6, PA 6-T, PA 6,6-T, Trogamide (Creanova), partially aromatic polyamides as well as the corresponding copolyamides, mixtures of polyamides and thermoplastically processable aramids.
- block copolymers of polyamides and polyethers can also be used according to the invention, which are used in numerous areas as thermoplastic elastomers because of their interesting mechanical properties.
- the starting compounds preferably have molecular weights of greater than 5000, particularly preferably greater than 10,000.
- the oligo- and / or (co-) polyamides to be encoded are preferably those which partially still have amino groups. These can exist as end groups or as page groups.
- At least one compound with at least two carbonate units is used in a quantitative ratio of 0.005 to 10% by weight, calculated on the basis of the carbonate units in relation to the oligo- and / or (co-) polyamide used.
- the ratio described above is preferably in the range from 0.01 to 5.0% by weight, particularly preferably in the range from 0.5 to 3% by weight.
- the additive used in the process according to the invention for the condensation of the oligo- and / or (co-) polyamides is at least one compound with at least two carbonate units.
- This compound can be low molecular weight, oligomeric or polymeric. It can consist entirely of carbonate units or it can have further units. These are preferably oligo or poly amide, ester, ether, ether ester amide or ester amide units.
- Such compounds can be produced by known oligo- or polymerization processes or by polymer-analogous reactions. The knowledge required for this is known to the person skilled in the art from the prior art. If the connection with at least two carbonate units consists only of carbonate units, these are preferably selected from units based on compounds of the formula
- n 0 or 1
- R 1 to R 8 each independently, denote H, alkyl or halogen
- R 9 represents H, alkyl or acyl; wherein R 10 and Rn together to form a
- R 2 is alkyl or acyl.
- the alkyl group is preferably a group with 1 to 6 carbon atoms, particularly preferably with 1 to 3 carbon atoms. These groups can be optionally substituted. Preferred examples of substituents are halogens (Cl, Br, F, I) and alkoxy groups with 1 to 3 carbon atoms.
- the acyl group (-COR) is preferably an acyl group in which R H, alkyl with 1 to
- the aryl group is preferably an aryl group with
- the aryl group is preferably a phenyte group.
- R is particularly preferably alkyl having 1 to 3 carbon atoms.
- the ring formed by R 10 and Rn can be a saturated or unsaturated ring with or without heteroatoms. This ring is preferably a 3- to 12-membered ring, particularly preferably a 5- to 8-membered ring. This ring is more preferably a saturated ring without a hetero atom. A Ce ring is particularly preferred.
- Carbonate units based on dioxydiphenylalkanes such as bisphenol A, bisphenol B, bisphenol F, halogenated bisphenols, such as 3,3 ', 5,5'-tetrachloro- or 3,3', 5,5'-tetrabromobesphenol A, or are further preferred alkylated bisphenols, such as 3,3 ', 5,5'-tetramethylb ⁇ sphenol A, carbonate units based on bisphenol A and bisphenol F are particularly preferred
- Such compounds preferably have a molecular weight of less than 50,000, particularly preferably from 1,000 to 30,000 and particularly preferably from 5,000 to 20,000
- the compound with at least two carbonate units also comprises other units as defined above, these are preferably selected from the following
- Amide units derived from PA 6 and PA 6,6 are preferred
- Ester units Ester units derived from aliphatic, aromatic or mixed aromatic / ahphatic polyesters, such as PET, PBT, PDCT, PCL, PHB, polylactic acid, polytetramethylene adipate, poly (4-hydroxybenzoic acid) and polycondensates from bisphenol A and phthalic acids.
- Ester units derived from mixed aromatic are preferred / ahphatic polyesters ether units ether units, derived from polyethers such as polyalkylene glycols (PEG, PPG, polyepichlohyd ⁇ ne), epoxy resins, polytetrahydrofurans, polyoxetanes, polyphenyl ethers, polyaryl ethers (poly (oxy-2,6-dimethyl-p-phenylene), poly (oxy-2 , 6-d ⁇ phenyl-p-phenylene)) or polyether ether ketones.
- Ether units derived from polyalkylene glycols are preferred
- the compound comprises at least two such carbonate units, these are preferably in the form of blocks. These blocks preferably have one Molecular weight of less than 50,000, particularly preferably from 30,000 to 1,000 and particularly preferably from 5,000 to 20,000
- the additive used according to the invention is preferably a block copolymer of the AB or A [BA] n >, type.
- A is a carbonate block and B is a non-carbonate block.
- Block B is preferably an oligo- or polyamide block and / or an oligo- or polyester block and / or an oligo or polyether block and / or an oligo or polyether ester amide block and / or an oligo or polyester amide block or mixtures or (block) copolymers thereof are used. Examples and preferred embodiments thereof are described above.
- n in this formula is 1 to 3rd
- the ratio of A to B is preferably 99 1 to 5 95, particularly preferably 95 5 to 20 80, based on the weight.
- Block B which does not consist of carbonate units, preferably has a molecular weight in the range of less than 50,000, particularly preferably in the range from 30,000 to 1,000, particularly preferably in the range from 20,000 to 5,000
- Block B is particularly preferably an oligo- or polyamide block, in particular made of polyamide 6, preferably with a molecular weight of 20,000 to 10,000
- the carbonate block A comprises at least two carbonate units which can be aphatic, aromatic or ahphatic-aromatic.
- This block preferably has a molecular weight of less than 50,000, particularly preferably from 1,000 to 30,000 and particularly preferably from 5,000 to 20,000 according to the invention both blocks of only one type of carbonate units and blocks of more than one type of carbonate units are suitable, such as units based on compounds of the formula
- n 0 or 1
- R 1 to R 8 each independently, represent H, alkyl or halogen
- R 9 represents H, alkyl or acyl; wherein R10 and Rn together form a
- R 12 is alkyl or acyl.
- the alkyl group is preferably a group with 1 to 6 carbon atoms, particularly preferably with 1 to 3 carbon atoms. These groups can be optionally substituted. Preferred examples of substituents are halogens (Cl, Br, F, I) and alkoxy groups with 1 to 3 carbon atoms.
- the acyl group is preferably an acyl group in which RH is alkyl of 1 to 5 carbon atoms or aryl.
- the aryl group is preferably an aryl group having 6 to 24 carbon atoms, which may optionally be substituted.
- the aryl group is preferably a phenyl group.
- R is particularly preferably alkyl having 1 to 3 carbon atoms.
- the ring formed by R 10 and Rn can be a saturated or unsaturated ring with or without heteroatoms. This ring is preferably a 3- to 12-membered ring, particularly preferably a 5- to 8-membered ring. This ring is more preferably a saturated ring without a hetero atom.
- a C 6 ring is particularly preferred.
- the aryl group is preferably an aryl group having 6 to 24 carbon atoms, which may optionally be substituted.
- the aryl group is preferably a phenyl group.
- Preferred examples of carbonate units are oligo- and polycarbonate blocks of dioxydiphenylalkanes, such as bisphenol A, bisphenol B, bisphenol F, halogenated bisphenols, such as 3,3 ', 5,5'-tetrachloro- or 3,3', 5,5 '-tetrabromobisphenol A, or alkylated bisphenols such as 3,3 ', 5,5'-tetramethylbisphenol A. Preference is given to blocks of bisphenol A and / or bisphenol F.
- the compound with at least two carbonate units preferably has a melt index which is comparable or higher than the melt index of the oligo- and / or (co-) polyamides to be condensed. This enables a good and even distribution of the compound with at least two carbonate units in the melt.
- the compound having at least two carbonate units preferably has a melt index in the range from 10 to 350, particularly preferably from 20 to 300, in each case under comparable measurement conditions of, for example, 240 ° C. 2.16 kg for polyamide-6.
- the usual additives that are used in the production of polyamide products can also be used.
- Illustrative examples of these are coloring agents, flame retardants and protective agents, stabilizers, fillers, lubricity improvers, mold release agents, impact modifiers, crystallization accelerators, antistatic agents, lubricants, processing aids and other polymers which are usually compounded with polyamides.
- Colorants titanium dioxide, lead white, zinc white, liptone, antimony white, carbon black, iron oxide black, manganese black, cobalt black, antimony black, lead chromate, red lead, zinc yellow, zinc green, cadmium red, cobalt blue, Berlin blue, ultramarine, manganese violet, cadmium yellow and reddish orange, pig fur orange green , Chrome orange and red, iron oxide red, chrome oxide green, strontium yellow, molybdenum blue, chalk, ocher, umber, green earth, terra di Siena burned and graphite.
- Flame retardants and flame retardants Antimont ⁇ oxid, Hexabromcyclododeca ⁇ , Tetrachlor- or Tetrabrombisphenol and halogenated phosphates, borates, chlorinated paraffins, red phosphorus
- Stabilizers metal salts especially copper salts and molybdenum salts, copper complexes
- Lubricants and lubricants MoS 2 paraffins, fatty alcohols, stearates, fatty acid amides
- Mold release agents and processing aids waxes (montanates), montan acid waxes, montan ester waxes, polysiloxanes, stearates, polyvinyl alcohol, SiO 2 , calcium silicate
- the condensed product obtained in the process according to the invention can either be stored in the form of granules until final use or can be converted directly into the corresponding end products. Since the granules obtained can be extruded again without problems and without a drop in the mechanical characteristics, intermediate storage is without disadvantage
- Direct processing to the end products and later processing to the corresponding end products is carried out using the customary devices and methods which are well known to the person skilled in the art, such as those in A Echte, Handbuch der Technischen Polymerchemie, VCH-Verlagsgesellschaft mbH, Weinheim, 1993, in Polymeric Materials , published by H Batzer, Georg Thieme Vertag, Stuttgart, 1984 and in Ulimann's Encyklopadie der technical chemistry, Volume 15, Vertag Chemie, Weinheim, 1978 are described
- the condensed polyamides according to the invention are characterized, particularly in the case of polyamide-6, by surprisingly good impact strength.
- renewed extrusion for example of fiber waste, is possible without the addition of additive, and there is no decrease in important mechanical parameters. Elongation at break still affects the modulus of elasticity
- the properties of the condensed polyamide can be varied over a wide range by adding the compound with at least two carbonate units and the process parameters, the polyamides obtained can be used in many areas
- the polyamides can be used for fiber spinning with the advantage that the fiber waste obtained can be recycled without further workup.
- Film blowing and film pressing are also possible with the polyamides condensed according to the invention.
- the method according to the invention further allows the generation of pseudoplastic behavior in polyamide melts
- Structural viscosity is a designation from rheology, which is understood to mean a phenomenon that is opposite to the dilatancy.
- the viscosity of flowing substances decreases under the influence of increasing shear stress or shear rate under the influence of increasing shear stress (Rompp Chemie Lexikon, 9th edition, Georg Thieme Vertag, Stuttgart, New York, 1992)
- the broadening of the molar mass distribution during the condensation of the polyamides achieves a structurally viscous flow in the melt in processing processes, such as, for example, in semi-finished product and profile extrusion and in injection molding.
- the improvement in the mechanical properties of the polyamides condensed according to the invention goes hand in hand with a further improvement in the process control for shaping.
- the variability of the process also allows the production of polyamides that are suitable for deep drawing, profile extrusion, film extrusion and blow molding.
- additives in the form of the block copolymers are suitable for the compatibility of polymer blends.
- Additives of the block copolymer type for example of the AB type or of the A [BA] n> r type, according to the invention can be used for the compatibility of polymer blends from polymers of type A and polymers of type B.
- polymers of type A or of type B are here as described above for the additives. All preferred embodiments of the additive compounds described in connection with the condensation of polyamides are also preferred here.
- the additive according to the invention containing at least one structural element of the formula (I), as described here in the application, including all preferred variants, is also suitable for use to compatibilize polymer blends.
- an additive of the formula (I), (la) or (II) in which a polyamide block is linked to a polycarbonate block is suitable for the compatibility of polyamide-polycarbonate blends.
- the additive according to the invention here does not condense the polyamide component, but serves to modify the boundary phase of the blend polymers, which are in principle incompatible, so that improved material properties, such as increasing the tensile strength while improving the flowability of the melt (increasing the melt index, advantageously for shorter cycle times in injection molding or for higher throughputs in extrusion processes).
- the process according to the invention is carried out in the customary plastics processing devices which are well known to the person skilled in the art. These devices are melt mixers and include single-screw and twin-screw extruders, the two screws being able to rotate in the same or opposite directions, melt-kneading tools such as Banbury mixers, Buss kneaders and platinum roll extruders. However, the process is preferably carried out in well-mixing extruders. The necessary process parameters and the specific configurations of the devices depend on the type of starting materials and the desired results and end products, but are well known to the person skilled in the art.
- the process according to the invention can be designed in such a way that the at least one compound having at least two carbonate units is either premixed directly with the oligo- and / or (co-) polyamides to be condensed, melted and reacted or only after the oligo- and / or or (co) polyamides are added at a later time. It is also possible to use the at least one compound with at least two carbonate units either as a pure substance or in the form of a master batch.
- the particular embodiments of the method are familiar to the person skilled in the art and offer the following advantages.
- the at least one compound with at least two carbonate units simultaneously with the glass fibers into the already melted mixture.
- this ensures that the glass fibers are not excessively mechanically stressed and destroyed, at the same time it can be ensured by the rapid but not too rapid condensation reaction that the glass fibers are distributed evenly in the melted mass.
- the metering of the additive in the form of a master batch enables more precise metering of the additive, since larger amounts are used.
- the master batch preferably comprises the polyamide as the matrix material, which is also condensed in the process, but is not limited to this.
- the concentration of the additive in the master batch is preferably 1 to 50% by weight, more preferably 5 to 25% by weight and particularly preferably 10 to 15% by weight, based on the total weight of the master batch.
- the master batch can also contain other additives, such as those described above.
- Such a master batch is produced in the usual manner which is familiar to the person skilled in the art.
- This compound is preferably used before the compound is metered in with at least two carbonate units.
- the type of this connection is not limited; the amino groups or the NH 2 end groups are essential.
- this compound is preferably an oligoamide which corresponds in structure to the polyamide to be produced.
- the amount added of the additional di- and / or polyamide and / or NH 2 -terminated oligoamide is 0.1 to 10% by weight, preferably 1 to 3% by weight, based on the amount of oligo- and / or ( Co-) polyamide.
- the addition of this special compound leads to a further improved condensation reaction.
- the present invention provides the use of at least one compound with at least two carbonate units for the condensation of oligo- and / or (co-) polyamides. Preferred embodiments of this use result from the above.
- the present invention provides an additive for the condensation of oligo- and / or (co-) polyamides, which contains a structural element of the formula (I):
- P means a block selected from an oligo- or polyamide block, an oligo- or polyester block, an oligo- or polyether block, an oligo- or polyetheresteramide block and an oligo- or polyesteramide block or mixtures thereof or (block) copolymer blocks thereof. Examples and preferred embodiments thereof have been set out above in connection with the method according to the invention.
- CE 1 and CE 2 each represent a carbonate unit, which can be the same or different.
- L represents a connecting group selected from divalent organic groups and a single bond.
- CE 1 and CE 2 are selected from carbonate units that can be made based on the following compounds:
- n 0 or 1
- R T to R 8 each independently, denote H, alkyl or halogen
- R 9 represents H, alkyl or acyl; wherein R 10 and Rn together to form a
- R ⁇ 2 is alkyl or acyl.
- the alkyl group is preferably a group having 1 to 6 carbon atoms, particularly preferably having 1 to 3 carbon atoms. These groups can be optionally substituted. Preferred examples of substituents are halogens (Cl, Br, F, I) and alkoxy groups with 1 to 3 carbon atoms.
- the acyl group is preferably an acyl group in which RH is alkyl of 1 to 5 carbon atoms or aryl.
- the aryl group is preferably an aryl group having 6 to 24 carbon atoms, which may optionally be substituted.
- the aryl group is preferably a phenyl group.
- R is particularly preferably alkyl having 1 to 3 carbon atoms.
- the ring formed by R 10 and Rn can be a saturated or unsaturated ring with or without heteroatoms. This ring is preferably a 3- to 12-membered ring, particularly preferably a 5- to 8-membered ring. This ring is more preferably a saturated ring without a hetero atom.
- a C 6 ring is particularly preferred.
- the aryl group is preferably an aryl group having 6 to 24 carbon atoms, which may optionally be substituted.
- the aryl group is preferably a phenyl group.
- Dioxydiphenylalkanes such as bisphenol A, bisphenol B, bisphenol F, halogenated bisphenols, such as 3,3 ', 5,5'-tetrachloro- or 3,3', 5,5'-tetrabromobisphenol A, are preferred. or alkylated bisphenols, such as 3,3 ', 5,5'-tetramethylbisphenol A. Carbonate units based on bisphenol A or bisphenol F are preferred.
- CE 1 and CE 2 are preferably the same.
- L examples of divalent organic groups for L are -COO-, -CO-, -O-, -NR-, -NHCOO-, -NHCONH-, -N (COR) -, where R represents an alkyl or aryl group, - CONH - and - (CH 2 ) n - with n equal to 1 to 5.
- L is preferably a -COO group.
- the additive according to the invention is preferably used for the condensation of oligo- and / or (co-) polyamides, in particular in the process described above.
- the additive of the invention preferably also comprises an oligo- or polycarbonate block (PCB), connected to the structural element of the formula (I) by CE 2
- the additive according to the invention also has an oligo or polycarbonate block
- the oligo or polycarbonate block and P are in a ratio of 99: 1 to 5:95, preferably from 70:30 to 30:70, more preferably from 60:40 to 40 : 60 and especially from 50:50, based on the weight.
- the additive according to the invention is preferably a compound in which P represents an oligo- or polyamide block and L represents -CO ⁇ -.
- This additive particularly preferably also has an oligo or polycarbonate block.
- the oligo or polyamide block is preferably an oligo or polyamide 6 block.
- this preferred additive can be obtained by reacting a polyamide with -COOH groups with a polycarbonate become.
- the production can take place, for example, in an extruder under the following reaction conditions:
- a polycarbonate (PC) is melted (approx. 250 to 300 ° C).
- a polyamide with COOH groups (COOH-PA) is metered into the melt.
- the weight ratio (PC) to (COOH-PA) is preferably 10:90 to 90:10, particularly preferably 30:70 to 70:30, particularly preferably 55:45 to 45:55 and most preferably 50:50.
- the (COOH-PA) is melted and reacts with the (PC).
- the additive formed by this reactive blend process can e.g. drawn off as a strand, cooled, granulated and dried.
- n is preferably from 1 to 3, particularly preferably 2.
- Any polycarbonate can be used as the polycarbonate in the reaction described above, preferably a polycarbonate derived from the starting compounds described in connection with CE1 and CE2.
- the polycarbonate is preferably a polycarbonate composed of bisphenol A or bisphenol F.
- the polycarbonate preferably has a molecular weight of 10,000 to 30,000, particularly preferably 18,000 to 24,000 and most preferably 20,000.
- Any polyamide can be used as the polyamide for producing the additive. Illustrative examples are described above.
- the polyamide is preferably a polyamide 6.
- the polyamide preferably has a molecular weight of 5,000 to 30,000, more preferably 10,000 to 20,000 and particularly preferably 12,000 to 17,000.
- the production of -COOH groups in the polyamide can be ensured by known methods. For example, a polyamide can be reacted with an acid anhydride, such as trimellitic anhydride, or with a free acid, such as adipic acid, in the melt.
- the additive according to the invention can be used particularly advantageously in the processing of polyamide 4.6.
- Polyamide 4.6 has a very high melting point for polyamides (> 290 °) and at the same time a very narrow processing window. That only a very narrow temperature range is available for processing, in which polyamide 4.6 can be processed without any signs of decomposition.
- the strict control of the process parameters required for this during processing is complex and cost-intensive.
- Example I Preparation of an Additive According to the Invention
- An additive according to the invention is produced here in a two-stage process; however, production can also be achieved in a one-step process (see I.3).
- Step 1 Production of a polyamide 6 with COOH groups
- Polyamide 6 and polyamide 6.6 were modified at a throughput of 8 kg / h in the above-mentioned twin-screw extruder with well-mixing but low-shear screws. An extrusion of the pure polymer is given as a comparison. The melt index and notched impact strength were determined as characteristic values. The measured values obtained are given in Table 1.
- Polyamide 6 was condensed at three different throughputs, two different temperatures and with two different screws (good mixing and low shear [screw A] or good mixing and high shear [screw B]).
- the additive concentration (M 1251) was 1% each as a comparison the corresponding tests without additive are given in each case.
- the notched impact strength and the melt index were again determined as characteristic values. The measurement results obtained are shown in Table 2
- the varying throughput represents a variation of the reaction time, since with increasing throughput the dwell time and thus the time available for the reaction is shortened
- the additive according to the invention enables rapid condensation, since a significant increase in molecular weight is achieved even at the highest throughput. Inhomogeneities such as gels did not occur, as studies on the solution viscosity and the values for the notched impact strength show. Strongly inhomogeneous samples would show deteriorated values. This also shows that the additive according to the invention has no influence on the end product via the placement of the dosage site.
- Polyamide 6 was extruded several times in moist and dry form, with and without the addition of an additive.
- the melt index and notched impact strength were again determined as characteristic values. The results obtained are shown in Table 3. The extrusion was carried out with the extruder described above.
- Stable product properties, especially MFIs, with multiple processing are important for applications of the condensed polyamides in areas in which a lot of polymer waste is obtained in pure form. It should be possible to use it again without complex intermediate steps, in order to keep costs down and conserve resources.
- Polyamide 6 (Miramid PA 6, trade name) was modified with the various additives from I 1 and I 2 (test conditions as in the evaluation of the influence of the additive concentration). The results of the melt index and impact strength determination are given in Table 4
- Additive B8 in particular shows an inexpensive variant owing to the high carbonate content.
- Additive B9 shows that additives which have been produced in a one-step process can also be used successfully for condensation.
- Polyamide 6 (as in the previous experiments) was compounded with various additives and processed without an additive, with an additive according to the invention and with an additive of the prior art.
- the melt index (MFI), the bending strength (BF), the b-value in the ClELab system (b) and the impact strength according to Charpy (SZC) were determined as characteristic values.
- the measured values obtained are given in the following table.
- the additives were metered in right at the start.
- the additives were metered in as such.
- the b-values show that the additive according to the invention only produces a slight yellowing which is in an acceptable range (increasingly positive b-value means an increase in yellowing).
- the experiments without an additive show an expected high MFI, ie a condensation only insignificant took place here.
- the tests with an additive not according to the invention show acceptable values, but handling was difficult.
- condensation in the presence of AX and VAS was only possible with increased use of additive, since disturbing side reactions occurred again the superior effect of the additives according to the invention which do not show such side reactions
- the oily liquid obtained was an oligocarbonate with an average of 3
- the synthesized additives OC I and OC II were used in laboratory kneading tests for the condensation of polyamide 6.
- Test conditions Haake laboratory kneader, electrically heated chamber
- the torques shown in the table show that additives with a small number of carbonate units used according to the invention can also be used effectively for the condensation.
- the increase in the torque values shows that a condensation reaction takes place.
- Polyamide 6 (Ultramid type) was mixed with polycarbonate (Lexan type) in a Haake twin-screw extruder with a special compounding screw (shaft diameter 16 mm) with a throughput of 2 kg / h with addition of the amount of additive specified in Table 7 (B5: Processed polyamide 6-polycarbonate block copolymer from Example 1). Pure polycarbonate was used as a comparative example. After granulation, the products were immediately dried in a vacuum at 90 ° C, so that no water could be absorbed by the polyamide. Then it was processed into test specimens by injection molding. The test specimens were tested under injection molding dry conditions for tensile strength (maximum stress) and modulus of elasticity. The results obtained are shown in Table 7.
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyamides (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU49138/00A AU4913800A (en) | 1999-05-03 | 2000-04-26 | Method for condensing polyamides |
PL00351688A PL351688A1 (en) | 1999-05-03 | 2000-04-26 | Carboxyl functional additive for condensing polyamides |
DE50001509T DE50001509D1 (de) | 1999-05-03 | 2000-04-26 | Carboxylfunktionelles additiv zur aufkondensierung von polyamiden |
US10/018,597 US7005481B1 (en) | 1999-05-03 | 2000-04-26 | Process for the condensation of polyamides |
JP2000615677A JP3453363B2 (ja) | 1999-05-03 | 2000-04-26 | ポリアミドの縮合方法 |
CA002372986A CA2372986C (en) | 1999-05-03 | 2000-04-26 | Process for the condensation of polyamides |
EP00931073A EP1189970B1 (de) | 1999-05-03 | 2000-04-26 | Carboxylfunktionelles additiv zur aufkondensierung von polyamiden |
AT00931073T ATE234884T1 (de) | 1999-05-03 | 2000-04-26 | Carboxylfunktionelles additiv zur aufkondensierung von polyamiden |
DK00931073T DK1189970T3 (da) | 1999-05-03 | 2000-04-26 | Carboxyfunktionelt additiv til kondensation af polyamider |
KR10-2001-7014071A KR100505938B1 (ko) | 1999-05-03 | 2000-04-26 | 폴리아미드의 축합 방법 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19920336A DE19920336C2 (de) | 1999-05-03 | 1999-05-03 | Verfahren zur Aufkondensierung von Polyamiden |
DE19920336.9 | 1999-05-03 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2000066650A2 true WO2000066650A2 (de) | 2000-11-09 |
WO2000066650A3 WO2000066650A3 (de) | 2001-04-26 |
Family
ID=7906834
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2000/003757 WO2000066650A2 (de) | 1999-05-03 | 2000-04-26 | Carboxylfunktionelles additiv zur aufkondensierung von polyamiden |
Country Status (17)
Country | Link |
---|---|
US (1) | US7005481B1 (de) |
EP (1) | EP1189970B1 (de) |
JP (1) | JP3453363B2 (de) |
KR (1) | KR100505938B1 (de) |
CN (1) | CN100378142C (de) |
AT (1) | ATE234884T1 (de) |
AU (1) | AU4913800A (de) |
CA (1) | CA2372986C (de) |
CZ (1) | CZ298957B6 (de) |
DE (2) | DE19920336C2 (de) |
DK (1) | DK1189970T3 (de) |
ES (1) | ES2193080T3 (de) |
HU (1) | HUP0201912A3 (de) |
PL (1) | PL351688A1 (de) |
PT (1) | PT1189970E (de) |
RU (1) | RU2222551C2 (de) |
WO (1) | WO2000066650A2 (de) |
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EP1512710A2 (de) * | 2003-08-16 | 2005-03-09 | Degussa AG | Verfahren zur Erhöhung des Molkulargewichts bei Polyamiden |
EP1690889A1 (de) * | 2005-02-15 | 2006-08-16 | Degussa GmbH | Verfahren zur Herstellung von Formteilen unter Erhöhung der Schmelzesteifigkeit |
EP1690890A1 (de) * | 2005-02-15 | 2006-08-16 | Degussa AG | Verfahren zur Herstellung von Formteilen unter Erhöhung der Schmelzesteifigkeit |
DE102007040683A1 (de) | 2007-08-29 | 2009-03-05 | Evonik Degussa Gmbh | Umhüllte Rohrleitung |
DE102008001678A1 (de) | 2007-10-17 | 2009-04-23 | Evonik Degussa Gmbh | Verwendung einer Polyamidformmasse zur Auskleidung von Rohrleitungen |
DE102008044224A1 (de) | 2008-12-01 | 2010-06-02 | Evonik Degussa Gmbh | Verwendung einer Zusammensetzung für den Kontakt mit überkritischen Medien |
DE102008044225A1 (de) | 2008-12-01 | 2010-06-02 | Evonik Degussa Gmbh | Verfahren zur Herstellung einer Formmasse oder eines Formteils mit erhöhter Schmelzesteifigkeit |
DE102009001001A1 (de) | 2009-02-19 | 2010-09-02 | Evonik Degussa Gmbh | Verwendung eines Leitungsrohrs zur Herstellung einer im Wasser verlegten Rohrleitung |
DE102011007104A1 (de) | 2011-04-11 | 2012-10-11 | Evonik Degussa Gmbh | Mit Polyamid umhüllte Stahlkonstruktionsrohre für Offshore-Bauwerke |
EP2610279A1 (de) | 2011-12-29 | 2013-07-03 | Evonik Degussa GmbH | Verfahren zur Herstellung eines Formteils aus einer Polyamidformmasse mit verbesserter Hydrolysebeständigkeit |
EP2639261A1 (de) | 2012-03-16 | 2013-09-18 | Evonik Degussa GmbH | Elektrisch leitfähigen Kohlenstoff enthaltende Polyamidzusammensetzung |
US8927737B2 (en) | 2011-08-09 | 2015-01-06 | Basf Se | Process for purifying ionic liquids |
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US20130065005A1 (en) * | 2010-05-17 | 2013-03-14 | Mitsubishi Gas Chemical Company, Inc. | Polyamide resin composition |
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EP3296345B1 (de) | 2014-08-26 | 2021-02-24 | Evonik Operations GmbH | Hydrolysestabile polyamidmischung |
MX2020002840A (es) | 2017-09-28 | 2020-10-12 | Dupont Polymers Inc | Proceso de polimerizacion. |
WO2019112910A1 (en) * | 2017-12-05 | 2019-06-13 | A. Schulman, Inc. | High performance polyamide compounds and uses thereof |
EP3553113A1 (de) | 2018-04-13 | 2019-10-16 | L. Brüggemann GmbH & Co. KG | Verfahren zur kontrolle der molekularen struktur von polyamiden |
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- 2000-04-26 CN CNB008083657A patent/CN100378142C/zh not_active Expired - Fee Related
- 2000-04-26 RU RU2001129302/04A patent/RU2222551C2/ru not_active IP Right Cessation
- 2000-04-26 JP JP2000615677A patent/JP3453363B2/ja not_active Expired - Fee Related
- 2000-04-26 CA CA002372986A patent/CA2372986C/en not_active Expired - Fee Related
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- 2000-04-26 DE DE50001509T patent/DE50001509D1/de not_active Expired - Lifetime
- 2000-04-26 HU HU0201912A patent/HUP0201912A3/hu unknown
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Cited By (21)
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EP1512710A3 (de) * | 2003-08-16 | 2005-12-28 | Degussa AG | Verfahren zur Erhöhung des Molkulargewichts bei Polyamiden |
EP1512710A2 (de) * | 2003-08-16 | 2005-03-09 | Degussa AG | Verfahren zur Erhöhung des Molkulargewichts bei Polyamiden |
US8580899B2 (en) | 2005-02-15 | 2013-11-12 | Evonik Degussa Gmbh | Process for producing moldings with an increase in the melt stiffness |
EP1690889A1 (de) * | 2005-02-15 | 2006-08-16 | Degussa GmbH | Verfahren zur Herstellung von Formteilen unter Erhöhung der Schmelzesteifigkeit |
EP1690890A1 (de) * | 2005-02-15 | 2006-08-16 | Degussa AG | Verfahren zur Herstellung von Formteilen unter Erhöhung der Schmelzesteifigkeit |
US8647551B2 (en) | 2005-02-15 | 2014-02-11 | Evonik Degussa Gmbh | Process for producing moldings with an increase in the melt stiffness |
DE102007040683A1 (de) | 2007-08-29 | 2009-03-05 | Evonik Degussa Gmbh | Umhüllte Rohrleitung |
DE102008001678A1 (de) | 2007-10-17 | 2009-04-23 | Evonik Degussa Gmbh | Verwendung einer Polyamidformmasse zur Auskleidung von Rohrleitungen |
DE102008044224A1 (de) | 2008-12-01 | 2010-06-02 | Evonik Degussa Gmbh | Verwendung einer Zusammensetzung für den Kontakt mit überkritischen Medien |
DE102008044225A1 (de) | 2008-12-01 | 2010-06-02 | Evonik Degussa Gmbh | Verfahren zur Herstellung einer Formmasse oder eines Formteils mit erhöhter Schmelzesteifigkeit |
WO2010063568A1 (de) | 2008-12-01 | 2010-06-10 | Evonik Degussa Gmbh | Verfahren zur herstellung einer formmasse oder eines formteils mit erhöhter schmelzesteifigkeit |
WO2010063506A1 (de) | 2008-12-01 | 2010-06-10 | Evonik Degussa Gmbh | Verwendung einer zusammensetzung für den kontakt mit überkritischen medien |
DE102009001001A1 (de) | 2009-02-19 | 2010-09-02 | Evonik Degussa Gmbh | Verwendung eines Leitungsrohrs zur Herstellung einer im Wasser verlegten Rohrleitung |
EP2511430A1 (de) | 2011-04-11 | 2012-10-17 | Evonik Degussa GmbH | Stahlkonstruktion für Offshore-Bauwerke |
DE102011007104A1 (de) | 2011-04-11 | 2012-10-11 | Evonik Degussa Gmbh | Mit Polyamid umhüllte Stahlkonstruktionsrohre für Offshore-Bauwerke |
US8927737B2 (en) | 2011-08-09 | 2015-01-06 | Basf Se | Process for purifying ionic liquids |
EP2610279A1 (de) | 2011-12-29 | 2013-07-03 | Evonik Degussa GmbH | Verfahren zur Herstellung eines Formteils aus einer Polyamidformmasse mit verbesserter Hydrolysebeständigkeit |
DE102011090092A1 (de) | 2011-12-29 | 2013-07-04 | Evonik Degussa Gmbh | Verfahren zur Herstellung eines Formteils aus einer Polyamidformmasse mit verbesserter Hydrolysebeständigkeit |
EP2639261A1 (de) | 2012-03-16 | 2013-09-18 | Evonik Degussa GmbH | Elektrisch leitfähigen Kohlenstoff enthaltende Polyamidzusammensetzung |
DE102012204181A1 (de) | 2012-03-16 | 2013-09-19 | Evonik Degussa Gmbh | Elektrisch leitfähigen Kohlenstoff enthaltende Polyamidzusammensetzung |
US9312043B2 (en) | 2012-03-16 | 2016-04-12 | Evonik Degussa Gmbh | Polyamide composition containing electrically conductive carbon |
Also Published As
Publication number | Publication date |
---|---|
DE19920336A1 (de) | 2000-11-16 |
DE19920336C2 (de) | 2002-10-24 |
CN100378142C (zh) | 2008-04-02 |
PL351688A1 (en) | 2003-06-02 |
CN1354766A (zh) | 2002-06-19 |
JP3453363B2 (ja) | 2003-10-06 |
KR20020016783A (ko) | 2002-03-06 |
HUP0201912A3 (en) | 2010-01-28 |
PT1189970E (pt) | 2003-08-29 |
WO2000066650A3 (de) | 2001-04-26 |
US7005481B1 (en) | 2006-02-28 |
EP1189970B1 (de) | 2003-03-19 |
CZ298957B6 (cs) | 2008-03-19 |
DE50001509D1 (de) | 2003-04-24 |
RU2222551C2 (ru) | 2004-01-27 |
ES2193080T3 (es) | 2003-11-01 |
CA2372986A1 (en) | 2000-11-09 |
AU4913800A (en) | 2000-11-17 |
HUP0201912A2 (en) | 2002-09-28 |
CZ20013906A3 (cs) | 2002-06-12 |
CA2372986C (en) | 2005-02-08 |
DK1189970T3 (da) | 2003-05-05 |
JP2002543257A (ja) | 2002-12-17 |
KR100505938B1 (ko) | 2005-08-03 |
ATE234884T1 (de) | 2003-04-15 |
EP1189970A2 (de) | 2002-03-27 |
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