NO310112B1 - Fremgangsmåte for fremstilling, blanding og anvendelse av en blanding som inneholder etylen-polymerer - Google Patents

Fremgangsmåte for fremstilling, blanding og anvendelse av en blanding som inneholder etylen-polymerer Download PDF

Info

Publication number: NO310112B1
Authority: NO; Norway
Prior art keywords: polymer; ethylene; catalyst; weight; alpha
Prior art date: 1992-12-21

Application number

NO934729A

Other languages

English (en)

Norwegian (no)

Other versions

NO934729D0 (no

NO934729L (no

Inventor

Michel Promel

Original Assignee

Solvay

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-12-21

Filing date

1993-12-20

Publication date

2001-05-21

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=3886598&utm_source=***_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=NO310112(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1993-12-20 Application filed by Solvay filed Critical Solvay

1993-12-20 Publication of NO934729D0 publication Critical patent/NO934729D0/no

1994-06-22 Publication of NO934729L publication Critical patent/NO934729L/no

2001-05-21 Publication of NO310112B1 publication Critical patent/NO310112B1/no

Links

239000000203 mixture Substances 0.000 title claims abstract description 53
229920000573 polyethylene Polymers 0.000 title claims abstract description 29
238000000034 method Methods 0.000 title claims description 52
230000008569 process Effects 0.000 title claims description 19
238000002360 preparation method Methods 0.000 title claims description 4
238000002156 mixing Methods 0.000 title description 2
239000004711 α-olefin Substances 0.000 claims abstract description 28
239000000155 melt Substances 0.000 claims abstract description 24
238000009826 distribution Methods 0.000 claims abstract description 15
229920000642 polymer Polymers 0.000 claims description 89
239000003054 catalyst Substances 0.000 claims description 52
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 41
239000005977 Ethylene Substances 0.000 claims description 41
238000006116 polymerization reaction Methods 0.000 claims description 41
238000004519 manufacturing process Methods 0.000 claims description 17
238000002844 melting Methods 0.000 claims description 15
230000008018 melting Effects 0.000 claims description 15
-1 aluminum compound Chemical class 0.000 claims description 13
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 11
229910052723 transition metal Inorganic materials 0.000 claims description 10
150000003624 transition metals Chemical class 0.000 claims description 10
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 8
229910052782 aluminium Inorganic materials 0.000 claims description 7
239000003426 co-catalyst Substances 0.000 claims description 7
230000009849 deactivation Effects 0.000 claims description 7
229910052736 halogen Inorganic materials 0.000 claims description 7
150000002367 halogens Chemical class 0.000 claims description 7
239000011777 magnesium Substances 0.000 claims description 6
239000000725 suspension Substances 0.000 claims description 6
239000010936 titanium Substances 0.000 claims description 6
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 5
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 5
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
229910052749 magnesium Inorganic materials 0.000 claims description 5
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
230000000737 periodic effect Effects 0.000 claims description 4
229910052719 titanium Inorganic materials 0.000 claims description 4
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
239000000460 chlorine Substances 0.000 claims description 2
229910052801 chlorine Inorganic materials 0.000 claims description 2
229920001038 ethylene copolymer Polymers 0.000 claims description 2
229920001519 homopolymer Polymers 0.000 claims description 2
238000001125 extrusion Methods 0.000 abstract description 7
238000003490 calendering Methods 0.000 abstract description 6
125000004432 carbon atom Chemical group C* 0.000 abstract description 6
150000001993 dienes Chemical class 0.000 abstract description 5
238000010101 extrusion blow moulding Methods 0.000 abstract 3
239000001257 hydrogen Substances 0.000 description 17
229910052739 hydrogen Inorganic materials 0.000 description 17
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 15
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 11
239000003085 diluting agent Substances 0.000 description 9
239000004698 Polyethylene Substances 0.000 description 6
150000001875 compounds Chemical class 0.000 description 6
239000004215 Carbon black (E152) Substances 0.000 description 5
229930195733 hydrocarbon Natural products 0.000 description 5
150000002430 hydrocarbons Chemical class 0.000 description 5
229920002959 polymer blend Polymers 0.000 description 5
KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 4
125000005234 alkyl aluminium group Chemical group 0.000 description 4
230000001105 regulatory effect Effects 0.000 description 4
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 4
PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000007789 gas Substances 0.000 description 3
239000012071 phase Substances 0.000 description 3
PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
150000001335 aliphatic alkanes Chemical class 0.000 description 2
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminum chloride Substances Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
238000005336 cracking Methods 0.000 description 2
238000002270 exclusion chromatography Methods 0.000 description 2
PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
238000012417 linear regression Methods 0.000 description 2
150000002681 magnesium compounds Chemical class 0.000 description 2
TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
CRSOQBOWXPBRES-UHFFFAOYSA-N neopentane Chemical compound CC(C)(C)C CRSOQBOWXPBRES-UHFFFAOYSA-N 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
239000007787 solid Substances 0.000 description 2
239000011949 solid catalyst Substances 0.000 description 2
238000005507 spraying Methods 0.000 description 2
239000003643 water by type Substances 0.000 description 2
OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 1
PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
NMVXHZSPDTXJSJ-UHFFFAOYSA-L 2-methylpropylaluminum(2+);dichloride Chemical compound CC(C)C[Al](Cl)Cl NMVXHZSPDTXJSJ-UHFFFAOYSA-L 0.000 description 1
YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 description 1
MLXMFSLAGRVEIP-UHFFFAOYSA-N 4,7,7-trimethyl-2-methylidenebicyclo[2.2.1]hept-5-ene Chemical compound C1=CC2(C)CC(=C)C1C2(C)C MLXMFSLAGRVEIP-UHFFFAOYSA-N 0.000 description 1
BBDKZWKEPDTENS-UHFFFAOYSA-N 4-Vinylcyclohexene Chemical compound C=CC1CCC=CC1 BBDKZWKEPDTENS-UHFFFAOYSA-N 0.000 description 1
WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical class CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
241000251468 Actinopterygii Species 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
SPAGIJMPHSUYSE-UHFFFAOYSA-N Magnesium peroxide Chemical compound [Mg+2].[O-][O-] SPAGIJMPHSUYSE-UHFFFAOYSA-N 0.000 description 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
230000008901 benefit Effects 0.000 description 1
BSDOQSMQCZQLDV-UHFFFAOYSA-N butan-1-olate;zirconium(4+) Chemical compound [Zr+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] BSDOQSMQCZQLDV-UHFFFAOYSA-N 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
150000001924 cycloalkanes Chemical class 0.000 description 1
125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 1
238000007872 degassing Methods 0.000 description 1
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
GCPCLEKQVMKXJM-UHFFFAOYSA-N ethoxy(diethyl)alumane Chemical compound CCO[Al](CC)CC GCPCLEKQVMKXJM-UHFFFAOYSA-N 0.000 description 1
UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 1
DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
239000001282 iso-butane Substances 0.000 description 1
239000007788 liquid Substances 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
XDKQUSKHRIUJEO-UHFFFAOYSA-N magnesium;ethanolate Chemical compound [Mg+2].CC[O-].CC[O-] XDKQUSKHRIUJEO-UHFFFAOYSA-N 0.000 description 1
239000000178 monomer Substances 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
239000006069 physical mixture Substances 0.000 description 1
PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
230000002028 premature Effects 0.000 description 1
239000000047 product Substances 0.000 description 1
230000002441 reversible effect Effects 0.000 description 1
239000000126 substance Substances 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
238000003856 thermoforming Methods 0.000 description 1
239000002562 thickening agent Substances 0.000 description 1
150000003623 transition metal compounds Chemical class 0.000 description 1
MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/02—Ziegler natta catalyst
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/04—Philipps catalyst

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Inorganic Chemistry (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Compositions Of Macromolecular Compounds (AREA)
Processes Of Treating Macromolecular Substances (AREA)
Medicinal Preparation (AREA)
Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
Orthopedics, Nursing, And Contraception (AREA)

NO934729A 1992-12-21 1993-12-20 Fremgangsmåte for fremstilling, blanding og anvendelse av en blanding som inneholder etylen-polymerer NO310112B1 (no)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
BE9201117A BE1006439A3 (fr)	1992-12-21	1992-12-21	Procede de preparation d'une composition de polymeres d'ethylene, composition de polymeres d'ethylene et son utilisation.

Publications (3)

Publication Number	Publication Date
NO934729D0 NO934729D0 (no)	1993-12-20
NO934729L NO934729L (no)	1994-06-22
NO310112B1 true NO310112B1 (no)	2001-05-21

Family

ID=3886598

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO934729A NO310112B1 (no)	1992-12-21	1993-12-20	Fremgangsmåte for fremstilling, blanding og anvendelse av en blanding som inneholder etylen-polymerer

Country Status (16)

Country	Link
US (3)	US6136924A (hu)
EP (6)	EP1364971A3 (hu)
AT (1)	ATE191724T1 (hu)
BE (1)	BE1006439A3 (hu)
BR (1)	BR9305106A (hu)
CZ (1)	CZ291571B6 (hu)
DE (1)	DE69328345T2 (hu)
ES (1)	ES2147192T3 (hu)
FI (1)	FI112243B (hu)
GR (1)	GR3033922T3 (hu)
HU (1)	HU220636B1 (hu)
NO (1)	NO310112B1 (hu)
PL (1)	PL174588B1 (hu)
PT (1)	PT603935E (hu)
SA (1)	SA94150085B1 (hu)
ZA (1)	ZA939588B (hu)

Families Citing this family (62)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FI942949A0 (fi) *	1994-06-20	1994-06-20	Borealis Polymers Oy	Prokatalysator foer producering av etenpolymerer och foerfarande foer framstaellning daerav
DE19515678B4 (de) *	1995-04-28	2007-12-27	Basell Polyolefine Gmbh	Rohr aus Polyethylen mit verbesserten mechanischen Eigenschaften
BE1009308A3 (fr) *	1995-04-28	1997-02-04	Solvay	Polymere d'ethylene et procedes pour son obtention.
BR9609604A (pt)	1995-07-10	1999-05-25	Borealis Polymers Oy	ComposiçÃo de revestimento
EP0832905B1 (fr) *	1996-09-13	2001-06-06	Fina Research S.A.	Procédé de préparation de polyéthylène ayant une distribution large de poids moléculaire
EP0829495A1 (fr) *	1996-09-13	1998-03-18	Fina Research S.A.	Procédé de préparation de polyéthylène ayant une distribution large de poids moléculaire
GB9712663D0 (en)	1997-06-16	1997-08-20	Borealis As	Process
BE1011333A3 (fr) *	1997-08-20	1999-07-06	Solvay	Procede de fabrication d'une composition de polymeres d'ethylene.
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1992
- 1992-12-21 BE BE9201117A patent/BE1006439A3/fr not_active IP Right Cessation
1993
- 1993-12-13 EP EP03077609A patent/EP1364971A3/fr not_active Withdrawn
- 1993-12-13 EP EP93203496A patent/EP0603935B1/fr not_active Revoked
- 1993-12-13 DE DE69328345T patent/DE69328345T2/de not_active Revoked
- 1993-12-13 EP EP99107093A patent/EP0940411A3/fr not_active Withdrawn
- 1993-12-13 EP EP04077468A patent/EP1482008A1/fr not_active Withdrawn
- 1993-12-13 PT PT93203496T patent/PT603935E/pt unknown
- 1993-12-13 EP EP04075456A patent/EP1420046B1/fr not_active Revoked
- 1993-12-13 EP EP05075023A patent/EP1544244A1/fr not_active Ceased
- 1993-12-13 ES ES93203496T patent/ES2147192T3/es not_active Expired - Lifetime
- 1993-12-13 AT AT93203496T patent/ATE191724T1/de active
- 1993-12-17 BR BR9305106A patent/BR9305106A/pt not_active IP Right Cessation
- 1993-12-20 NO NO934729A patent/NO310112B1/no not_active IP Right Cessation
- 1993-12-21 FI FI935772A patent/FI112243B/fi not_active IP Right Cessation
- 1993-12-21 ZA ZA939588A patent/ZA939588B/xx unknown
- 1993-12-21 CZ CZ19932853A patent/CZ291571B6/cs not_active IP Right Cessation
- 1993-12-21 PL PL93301589A patent/PL174588B1/pl not_active IP Right Cessation
- 1993-12-21 HU HU9303699A patent/HU220636B1/hu not_active IP Right Cessation
1994
- 1994-07-20 SA SA94150085A patent/SA94150085B1/ar unknown
1995
- 1995-12-13 US US08/571,684 patent/US6136924A/en not_active Expired - Fee Related
2000
- 2000-04-14 US US09/549,580 patent/US6344522B1/en not_active Expired - Fee Related
- 2000-04-14 US US09/549,581 patent/US6407185B1/en not_active Expired - Fee Related
- 2000-07-10 GR GR20000401607T patent/GR3033922T3/el not_active IP Right Cessation

Also Published As

Publication number	Publication date
AU670976B2 (en)	1996-08-08
ZA939588B (en)	1994-08-11
ES2147192T3 (es)	2000-09-01
DE69328345T2 (de)	2000-12-07
NO934729D0 (no)	1993-12-20
CZ285393A3 (en)	1994-07-13
FI935772A (fi)	1994-06-22
HU220636B1 (hu)	2002-03-28
EP1482008A1 (fr)	2004-12-01
PL174588B1 (pl)	1998-08-31
EP0940411A2 (fr)	1999-09-08
EP0603935B1 (fr)	2000-04-12
EP1544244A1 (fr)	2005-06-22
SA94150085B1 (ar)	2005-11-12
PL301589A1 (en)	1994-06-27
FI935772A0 (fi)	1993-12-21
HUT66491A (en)	1994-11-28
BR9305106A (pt)	1994-06-28
FI112243B (fi)	2003-11-14
EP0940411A3 (fr)	2000-08-02
HU9303699D0 (en)	1994-04-28
EP0603935A1 (fr)	1994-06-29
US6136924A (en)	2000-10-24
CZ291571B6 (cs)	2003-04-16
EP1364971A2 (fr)	2003-11-26
BE1006439A3 (fr)	1994-08-30
AU5249693A (en)	1994-06-30
PT603935E (pt)	2000-10-31
NO934729L (no)	1994-06-22
DE69328345D1 (de)	2000-05-18
US6407185B1 (en)	2002-06-18
EP1420046A1 (fr)	2004-05-19
EP1364971A3 (fr)	2004-05-12
ATE191724T1 (de)	2000-04-15
GR3033922T3 (en)	2000-11-30
US6344522B1 (en)	2002-02-05
EP1420046B1 (fr)	2012-09-12

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2011-07-25	MM1K	Lapsed by not paying the annual fees

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JPS6357446B2 (hu)	1988-11-11
JPH11189605A (ja)	1999-07-13	幅広い分子量分布を有するポリエチレンの製造
JP2000191726A (ja)	2000-07-11	多頂性ポリエチレンの製造
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JPH0253811A (ja)	1990-02-22	エチレン共重合体
EP0618239B1 (en)	2000-08-09	Ethylene (co)polymerization process
JPH02132109A (ja)	1990-05-21	エチレン共重合体
KR20220040944A (ko)	2022-03-31	초저밀도 고탄성을 갖는 폴리올레핀 엘라스토머 공중합체의 제조방법 및 그에 의해 제조된 폴리올레핀 엘라스토머 공중합체
NO300849B1 (no)	1997-08-04	Fremgangsmåte for fremstilling av etylenkopolymer
JPH07258326A (ja)	1995-10-09	エチレン系共重合体の製造方法
JPH0415820B2 (hu)	1992-03-19
JPH0318645B2 (hu)	1991-03-13
JPS6330508A (ja)	1988-02-09	エチレン共重合体の製造方法
JPH09176220A (ja)	1997-07-08	オレフィン重合体の製造方法