KR970706234A - 3, 4-디하이드록시-5-니트로벤즈알데히드의 신규 제조방법 - Google Patents
3, 4-디하이드록시-5-니트로벤즈알데히드의 신규 제조방법Info
- Publication number
- KR970706234A KR970706234A KR1019970701878A KR19970701878A KR970706234A KR 970706234 A KR970706234 A KR 970706234A KR 1019970701878 A KR1019970701878 A KR 1019970701878A KR 19970701878 A KR19970701878 A KR 19970701878A KR 970706234 A KR970706234 A KR 970706234A
- Authority
- KR
- South Korea
- Prior art keywords
- nitrobenzaldehyde
- zinc chloride
- pct
- ethoxy
- hydroxy
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
- C07C205/44—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by —CHO groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
- C07C201/06—Preparation of nitro compounds
- C07C201/12—Preparation of nitro compounds by reactions not involving the formation of nitro groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
- C07C201/06—Preparation of nitro compounds
- C07C201/16—Separation; Purification; Stabilisation; Use of additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Saccharide Compounds (AREA)
Abstract
본 발명은 염화아연, 물 및 염화수소로 이루어진 시약과 3-에폭시-4-하이드록시-5-니트로벤즈알데히드와의 반응에 의해 3,4-디하이드록시-5-니트로벤즈알데히드를 제조하는 방법을 제공한다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (10)
- 3-에톡시-4-하이드록시-5-니트로벤즈알데히드를 염화아연, 물 및 염화수소로 이루어진 시약과 반응시키는 것을 특징으로 하는 3,4-디하이드록시-5-니트로벤즈알데히드를 제조하는 방법
- 제1항에 있어서, 염화아연의 양이 3-에톡시-4-하이드록시-5-니트로벤즈알데히드 1㎏당 1.5-25㎏인 것을 특징으로 하는 방법
- 제2항에 있어서, 염화아연의 양이 3-에톡시-4-하이드록시-5-니트로벤즈알데히드 1㎏당 2.5-4㎏인 것을 특징으로 하는 방법
- 제1항에 있어서, 상기 염산의 양이 염화아연 1㎏당 0.17-0.6L인 것을 특징으로 하는 방법
- 제4항에 있어서, 상기 염산의 양이 염화아연 1㎏당 0.22-0.4L인 것을 특징으로 하는 방법
- 제1항에 있어서, 상기 염산의 농도가 10-38%인 것을 특징으로 하는 방법
- 제6항에 있어서, 상기 염산의 농도가 20-40%인 것을 특징으로 하는 방법
- 제1항에 있어서, 상기 온도가 70-130℃인 것을 특징으로 하는 방법
- 제8항에 있어서, 상기 온도가 80-110℃인 것을 특징으로 하는 방법
- 제1항에 있어서, 조생성물(crude product) 을 톨루엔으로부터 더 결정화되는 것을 특징으로 하는 방법※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9419274A GB9419274D0 (en) | 1994-09-23 | 1994-09-23 | New method for the preparation of 3,4-dihydroxy-5-nitrobenzaldehyde |
GB9419274.7 | 1994-09-23 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR970706234A true KR970706234A (ko) | 1997-11-03 |
KR100368163B1 KR100368163B1 (ko) | 2003-03-26 |
Family
ID=10761838
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019970701878A KR100368163B1 (ko) | 1994-09-23 | 1995-05-22 | 3,4-디하이드록시-5-니트로벤즈알데히드의신규제조방법 |
Country Status (28)
Country | Link |
---|---|
US (1) | US5710343A (ko) |
EP (1) | EP0782559B1 (ko) |
JP (1) | JP3717933B2 (ko) |
KR (1) | KR100368163B1 (ko) |
CN (1) | CN1064673C (ko) |
AT (1) | ATE175660T1 (ko) |
AU (1) | AU684672B2 (ko) |
BG (1) | BG61912B1 (ko) |
BR (1) | BR9508852A (ko) |
CA (1) | CA2200227C (ko) |
CZ (1) | CZ288684B6 (ko) |
DE (1) | DE69507309T2 (ko) |
DK (1) | DK0782559T3 (ko) |
ES (1) | ES2127552T3 (ko) |
GB (1) | GB9419274D0 (ko) |
GR (1) | GR3029815T3 (ko) |
HU (1) | HU224821B1 (ko) |
IL (1) | IL115122A (ko) |
LV (1) | LV11831B (ko) |
MX (1) | MX9702064A (ko) |
NO (1) | NO306670B1 (ko) |
NZ (1) | NZ292187A (ko) |
PL (1) | PL180016B1 (ko) |
RO (1) | RO119540B1 (ko) |
RU (1) | RU2130449C1 (ko) |
SI (1) | SI9520102A (ko) |
SK (1) | SK281789B6 (ko) |
WO (1) | WO1996009274A1 (ko) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9419274D0 (en) * | 1994-09-23 | 1994-11-09 | Orion Yhtymae Oy | New method for the preparation of 3,4-dihydroxy-5-nitrobenzaldehyde |
ES2644049T3 (es) * | 2007-01-31 | 2017-11-27 | Bial - Portela & Ca., S.A. | Régimen de dosificación para inhibidores de COMT |
EP2251323B1 (en) | 2009-05-14 | 2014-04-23 | F.I.S.- Fabbrica Italiana Sintetici S.p.A. | Method for the purification of entacapone |
CN102633646B (zh) * | 2012-04-10 | 2014-06-04 | 中国海洋大学 | 一种新的5-硝基水杨醛制备方法 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1330382A (fr) * | 1961-06-21 | 1963-06-21 | Monsanto Chemicals | Procédé de clivage des éthers d'alcoyle o-hydroxyphényle et de préparation simultanée de composés 1-alkyl-2,3-dihydroxyphényliques |
NO107714C (ko) * | 1961-06-21 | |||
US4213920A (en) * | 1977-07-06 | 1980-07-22 | Ciba-Geigy Corporation | Process for the production of substituted benzaldehydes |
DK175069B1 (da) * | 1986-03-11 | 2004-05-24 | Hoffmann La Roche | Pyrocatecholderivater |
YU213587A (en) * | 1986-11-28 | 1989-06-30 | Orion Yhtymae Oy | Process for obtaining new pharmacologic active cateholic derivatives |
DE4012008A1 (de) * | 1990-04-13 | 1991-10-17 | Bayer Ag | Verfahren zur herstellung von o-hydroxy-benzaldehyden |
GB9113431D0 (en) * | 1991-06-20 | 1991-08-07 | Orion Yhytma Oy | Method for the preparation of 3,4-dihydroxy-5-nitrobenzaldehyde |
PT551034E (pt) * | 1991-12-12 | 2001-01-31 | Hoechst Marion Roussel Inc | Antibioticos cefalosporinas com um radical benziloxiimino substituido na posicao 7 |
GB9419274D0 (en) * | 1994-09-23 | 1994-11-09 | Orion Yhtymae Oy | New method for the preparation of 3,4-dihydroxy-5-nitrobenzaldehyde |
-
1994
- 1994-09-23 GB GB9419274A patent/GB9419274D0/en active Pending
-
1995
- 1995-05-22 KR KR1019970701878A patent/KR100368163B1/ko not_active IP Right Cessation
- 1995-08-31 IL IL11512295A patent/IL115122A/xx not_active IP Right Cessation
- 1995-09-20 JP JP51063396A patent/JP3717933B2/ja not_active Expired - Fee Related
- 1995-09-20 RU RU97106330A patent/RU2130449C1/ru not_active IP Right Cessation
- 1995-09-20 HU HU9702258A patent/HU224821B1/hu unknown
- 1995-09-20 CZ CZ1997800A patent/CZ288684B6/cs not_active IP Right Cessation
- 1995-09-20 AT AT95930558T patent/ATE175660T1/de not_active IP Right Cessation
- 1995-09-20 SK SK378-97A patent/SK281789B6/sk unknown
- 1995-09-20 MX MX9702064A patent/MX9702064A/es not_active IP Right Cessation
- 1995-09-20 RO RO97-00574A patent/RO119540B1/ro unknown
- 1995-09-20 CN CN95195222A patent/CN1064673C/zh not_active Expired - Fee Related
- 1995-09-20 NZ NZ292187A patent/NZ292187A/en unknown
- 1995-09-20 AU AU33901/95A patent/AU684672B2/en not_active Ceased
- 1995-09-20 CA CA002200227A patent/CA2200227C/en not_active Expired - Fee Related
- 1995-09-20 ES ES95930558T patent/ES2127552T3/es not_active Expired - Lifetime
- 1995-09-20 DK DK95930558T patent/DK0782559T3/da active
- 1995-09-20 WO PCT/FI1995/000513 patent/WO1996009274A1/en active IP Right Grant
- 1995-09-20 DE DE69507309T patent/DE69507309T2/de not_active Expired - Fee Related
- 1995-09-20 PL PL95319348A patent/PL180016B1/pl not_active IP Right Cessation
- 1995-09-20 EP EP95930558A patent/EP0782559B1/en not_active Expired - Lifetime
- 1995-09-20 BR BR9508852A patent/BR9508852A/pt not_active IP Right Cessation
- 1995-09-20 SI SI9520102A patent/SI9520102A/sl not_active IP Right Cessation
- 1995-09-20 US US08/809,405 patent/US5710343A/en not_active Expired - Fee Related
-
1997
- 1997-03-11 BG BG101309A patent/BG61912B1/bg unknown
- 1997-03-21 NO NO971325A patent/NO306670B1/no unknown
- 1997-04-03 LV LVP-97-54A patent/LV11831B/en unknown
-
1999
- 1999-03-30 GR GR990400905T patent/GR3029815T3/el unknown
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Payment date: 20080103 Year of fee payment: 6 |
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