KR920701306A - 폴리카르보네이트-폴리디메틸실옥산 혼성중합체 및 그 제조방법 - Google Patents
폴리카르보네이트-폴리디메틸실옥산 혼성중합체 및 그 제조방법Info
- Publication number
- KR920701306A KR920701306A KR1019910700222A KR910700222A KR920701306A KR 920701306 A KR920701306 A KR 920701306A KR 1019910700222 A KR1019910700222 A KR 1019910700222A KR 910700222 A KR910700222 A KR 910700222A KR 920701306 A KR920701306 A KR 920701306A
- Authority
- KR
- South Korea
- Prior art keywords
- polydimethylsiloxane
- polycarbonate
- weight
- interpolymer
- integer
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/18—Block or graft polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/445—Block-or graft-polymers containing polysiloxane sequences containing polyester sequences
- C08G77/448—Block-or graft-polymers containing polysiloxane sequences containing polyester sequences containing polycarbonate sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/18—Block or graft polymers
- C08G64/186—Block or graft polymers containing polysiloxane sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 실시예2에서 제조한 폴리카르보네이트-폴리디메틸옥산 혼성중합체의 양성자 핵자기공명(1H-NMR)스펙트럼이며, 제2도는 사용한 폴리카르보네이트-폴리디메틸실옥산 혼성중합체에 있어서 폴리디메틸실옥산 부분의 디메틸실란옥시단위수와 성형품의 아이조드충격강도와의 관계를 표시한 그래프.
Claims (5)
- 일반식〔식중, R1및 R2은 각각 수소, 탄소수 1-4의 알킬기를 표시하며, R3및 R4는 각각 수소, 할로겐, 탄소수1-20의 알킬기 또는 아릴기를 표시하고, x는 1-5의 정수를 표시하고 y는 1-4의 정수를 표시하며 n은 1-100의 정수를 표시한다〕로 표시되는 폴리카르보네이트 블록 및 일반식〔식중, R5및 R6는 각각 방향족을 포함하는 유기잔기를 표시하며, m은 100이상의 정수를 표시한다.〕로 표시되는 폴리디메틸실옥산블록으로된 혼성중합체이며, 이 혼성중합체중의 폴리디메틸실옥산블록부분의 비율이 0.5-10중량%인 동시에 혼성중합체의 n-헥산가용분이 1.0중량%이하이고, 점도 평균분자량이 10,000-50,000인 것을 특징으로 하는 폴리카르보네이트-폴리디메틸실옥산혼성 중합체.
- 제1항에 있어서, R5및 R6가 독립적으로 3-(O-히드록시페닐)프로필기, 2-(p-히드록시페닐)에틸기, 식으로 표시된 기와 식으로 표시된 폴리카르보네이트-폴리디메틸실옥산혼성중합체.
- 제1항에 있어서, 일반식〔식중, R1, R2, R4및 y는 전기한 것과 동일하다.〕로 표시되는 유기디히드록시 화합물 및 일반식〔식중, R5, R6및 m은 전기한 것과 동일하다〕로 표시되는 폴리디메틸실옥산과 탄산에스테르형 성형유도체와를 액체매매중에서 분자량조절제의 존재하에서 반응시키는 것을 특징으로 하는 폴리카르보네이트-폴리디메틸실옥산혼성중합체의 제조방법.
- 제1항의 폴리카르보네이트-폴리디메틸실옥산 혼성중합체 40-90중량% 및 무기 충전제 60-10중량%로 된 수지조성물.
- 제4항에 있어서, 무기충전제가 유리섬유 또는 탄소섬유인 수지 조성물.※ 참고사항 : 최초출원 내용에 의하여 공개되는 것임.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP174046/1989 | 1989-07-07 | ||
JP89-174046 | 1989-07-07 | ||
JP17404689 | 1989-07-07 | ||
PCT/JP1990/000864 WO1991000885A1 (en) | 1989-07-07 | 1990-07-05 | Polycarbonate-polydimethylsiloxane copolymer and method of production thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
KR920701306A true KR920701306A (ko) | 1992-08-11 |
KR970002664B1 KR970002664B1 (ko) | 1997-03-07 |
Family
ID=15971675
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019910700222A KR970002664B1 (ko) | 1989-07-07 | 1990-07-05 | 폴리카르보네이트-폴리디메틸실옥산 혼성중합체 및 그 제조방법 |
Country Status (7)
Country | Link |
---|---|
US (1) | US5502134A (ko) |
EP (1) | EP0434848B1 (ko) |
KR (1) | KR970002664B1 (ko) |
BR (1) | BR9006848A (ko) |
DE (1) | DE69022567T2 (ko) |
ES (1) | ES2080147T3 (ko) |
WO (1) | WO1991000885A1 (ko) |
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EP0500129B1 (en) * | 1991-02-22 | 1996-07-31 | Mitsubishi Gas Chemical Company, Inc. | Polycarbonate resin solution for film formation by casting |
EP0500131B1 (en) * | 1991-02-22 | 2001-01-10 | Mitsubishi Gas Chemical Company, Inc. | Polycarbonate resin solution for film formation by casting |
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JP5379424B2 (ja) * | 2008-08-07 | 2013-12-25 | 出光興産株式会社 | 摺動用ポリカーボネート系樹脂組成物、および同樹脂組成物を用いた成形品 |
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KR101963566B1 (ko) * | 2012-11-07 | 2019-03-29 | 다우 코닝 도레이 캄파니 리미티드 | 백금 함량이 감소된 페놀-개질된 폴리오르가노실록산, 이의 제조 방법, 및 이를 함유하는 유기 수지용 개질제 |
KR102149134B1 (ko) * | 2013-03-29 | 2020-08-28 | 이데미쓰 고산 가부시키가이샤 | 폴리오르가노실록산 및 폴리카보네이트-폴리오르가노실록산 공중합체 |
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KR20160067714A (ko) | 2014-12-04 | 2016-06-14 | 주식회사 엘지화학 | 코폴리카보네이트 및 이를 포함하는 물품 |
KR101685665B1 (ko) | 2014-12-04 | 2016-12-12 | 주식회사 엘지화학 | 코폴리카보네이트 및 이를 포함하는 조성물 |
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KR102543776B1 (ko) * | 2015-08-27 | 2023-06-14 | 이데미쓰 고산 가부시키가이샤 | 폴리카보네이트계 수지 조성물 및 그 성형품 |
CN108368332A (zh) | 2015-12-11 | 2018-08-03 | 沙特基础工业全球技术有限公司 | 用于增材制造的高冲击强度聚碳酸酯组合物 |
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-
1990
- 1990-07-05 DE DE69022567T patent/DE69022567T2/de not_active Expired - Lifetime
- 1990-07-05 EP EP90910185A patent/EP0434848B1/en not_active Expired - Lifetime
- 1990-07-05 WO PCT/JP1990/000864 patent/WO1991000885A1/ja active IP Right Grant
- 1990-07-05 ES ES90910185T patent/ES2080147T3/es not_active Expired - Lifetime
- 1990-07-05 BR BR909006848A patent/BR9006848A/pt not_active IP Right Cessation
- 1990-07-05 KR KR1019910700222A patent/KR970002664B1/ko not_active IP Right Cessation
-
1994
- 1994-07-28 US US08/282,157 patent/US5502134A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE69022567D1 (de) | 1995-10-26 |
EP0434848B1 (en) | 1995-09-20 |
WO1991000885A1 (en) | 1991-01-24 |
EP0434848A4 (en) | 1991-09-25 |
BR9006848A (pt) | 1991-08-27 |
EP0434848A1 (en) | 1991-07-03 |
KR970002664B1 (ko) | 1997-03-07 |
US5502134A (en) | 1996-03-26 |
DE69022567T2 (de) | 1996-02-22 |
ES2080147T3 (es) | 1996-02-01 |
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