KR910007974A - 알루미늄 알킬의 첨가에 의해 개선된 올레핀 중합용 메탈로센 촉매 - Google Patents

알루미늄 알킬의 첨가에 의해 개선된 올레핀 중합용 메탈로센 촉매 Download PDF

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KR910007974A
KR910007974A KR1019900016067A KR900016067A KR910007974A KR 910007974 A KR910007974 A KR 910007974A KR 1019900016067 A KR1019900016067 A KR 1019900016067A KR 900016067 A KR900016067 A KR 900016067A KR 910007974 A KR910007974 A KR 910007974A
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윤 존
제이. 엘더 마이클
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피나 테크놀로지. 인코포레이티드
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    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
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Abstract

내용 없음

Description

알루미늄 알킬의 첨가에 의해 개선된 올레핀 중합용 메탈로센 촉매
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (32)

  1. a) 알루미늄 알킬을 올레핀과 혼합시키고, b) 메탈로센 촉매를 제조하고, c) 촉매를 알루미늄 알킬-올레핀 혼합물과 혼합시킴을 특징으로 하는 올레핀의 중합화 방법.
    상기에서, 알루미늄 알킬의 일반식이 AlR3이며, R이 할로겐, 산소, 수소화물, 알킬, 알콕시 또는 아릴이고, R은 각각 동일하거나 다르며, 하나 이상의 R은 알킬이고, 메탈로센은 중성 메탈로센 화합물 및 이온화 화합물로 부터 형성된 이온쌍이다.
  2. 제1항에 있어서, R이 탄소수 6이하의 알킬 또는 알콕시이거나 탄소수 10이항의 아릴인 방법.
  3. 제2항에 있어서, 메탈로센 : 이온화 화합물 : 알루미늄 알킬의 몰비가 0.5 : 1: 0.5 내지 5: 1: 350인 방법.
  4. 제3항에 있어서, 메탈로센 : 이온화 화합물 : 알루미늄 알킬의 몰비가 0.625 : 1: 1.5 내지 1:5 : 1 :77인 방법.
  5. 제4항에 있어서, 메탈로센 : 이온화 화합물 : 알루미늄 알킬의 몰비가 1: 1: 1인 방법.
  6. 제5항에 있어서, 알루미늄 알킬이 트리에틸알루미늄 및 트리메틸알루미늄으로 이루어진 그룹중에서 선택되는 방법.
  7. 제6항에 있어서, 알루미늄 알킬이 트리에틸알루미늄인 방법.
  8. 제1항에 있어서, (a) 이온화 이온계 화합물을 메탈로센의 중성 메틸유도체와 혼합하고, (b) 이온화 이온계 화합물과 메탈로센의 중성 메틸유도체 사이에서 접촉시켜, 메탈로센 양이온이 촉매로서 작용하는 이온쌍을 생성시키는 단계를 포함하는 방법으로 촉매를 제조하고, 여기에서, 메탈로센의 중성 유도체의 일반식은 Cp2MR*p이며, 이때 Cp는 시클로펜타디에닐 또는 치환된 시클로펜타디에닐그룹이고, 이때 각각의 Cp는 동일하거나 상이하며, M은 제III, IV, V 또는 VI족 금속이고, R*는 수화물, 할로겐, 아미드 또는 히드로카빌 라디칼이며, 이때 각각의 R*는 동일하거나 상이하고, 단 단지 1개의 R*만은 수화물이며 p는 1내지 4이고, 또한 이온화 이온계 화합물은 환성부분을 함유하지 않으며, 카보늄, 옥소늄 또는 설포늄 양이온을 함유하고, 또한, 이온화 이온계 화합물의 양이온은 배위되지 않거나 단지 느슨하게 메탈로센 양이온과 배위할 뿐이며, 메탈로센 양이온과는 화학적으로 반응하지 않는 방법.
  9. 제8항에 있어서, 올레핀이 프로필렌인 방법.
  10. 제8항에 있어서, R이, 탄소수가 20이하인 알킬, 아릴, 알케닐, 알킬아릴 및 아릴알킬중에서 선택한 히드로카빌 라디칼인 방법.
  11. 제10항에 있어서, M이, 티탄, 지르코늄 및 하프늄 중에서 선택한 제IV족 금속인 방법.
  12. 제11항에 있어서, M이 하프늄 또는 지르코늄인 방법.
  13. 제12항에 있어서, 메탈로센의 중성 메틸유도체를 에틸렌비스(테트라히드로인데닐) 지르코늄 디메틸, 에틸렌비스(인데닐)지르코늄 디메틸, 메틸렌비스(인데닐)하프늄 디메틸 및 이소프로필리덴(시클로펜타디에닐-1-플루오레닐)지르코늄 디메틸중에서 선택하는 방법.
  14. 제13항에 있어서, 이온화 이온계 화합물이 트리페닐카베늄 테트라키스(펜타플루오로페닐)보로네이트인 방법.
  15. 제1항에 있어서, (a) 1개의 양자와 반응할 수 있는 1개 이상의 치환체를 함유하며 또한 티탄, 지르코늄 및 하프늄중에서 선택한 금속을 함유하는 메탈로센의 중성 메틸 유도체로 이루어진 1개 이상의 제1화합물과, 1개의 양자를 수여할 수 있는 양이온 및 두 화합물 사이에서의 반응의 결과로서 형성된 음이온을 함유하는 1개 이상의 제2화합물을 적합한 용매 또는 희석제중에서 혼합하고, (b) 제2화합물의 양이온에 의해 제공된 양자가 제1화합물의 리간드와 반응하기에 충분한 시간 동안 단계 (a)에서의 접촉을 유지시키고, (c) 활성 촉매를 단계(b)로부터인 직접 생성물로서 또는 단계(b)로부터인 1개 이상의 직접적인 생성물의 분해생성물로서 회수하는 단계를 포함하여 촉매를 제조하는 방법.
  16. 제15항에 있어서, 올레핀이 프로필렌인 방법.
  17. 제16항에 있어서, 메탈로센의 중성 메틸 유도체가 하기 일반식을 갖는 방법.
    Cp2MR'p
    상기식에서, Cp는 각각 동일하거나 상이하며, 사이클로펜타디에닐 또는 치환된 사이클로펜타디에닐 그룹이고, M은 그룹 (III), (IV), (V) 또는 (VI) 금속이며 R'는 각각 동일하거나 상이하며, 하이드로카빌 라디칼이고, p는 1내지 4이다.
  18. 제17항에 있어서, M을 티타늄, 지르코늄 및 하프늄 중에서 선택하는 방법.
  19. 제18항에 있어서, M이 지르코늄인 방법.
  20. 제19항에 있어서, R'를 탄소수 20이하의 알킬, 아릴, 알케닐, 알킬아릴 및 아릴알킬 중에서 선택하는 방법.
  21. 제10항에 있어서, 메탈로센의 중성 메틸 유도체를 에틸렌 비스(테트라하이드로인데닐)지르코늄 디메틸 및 에틸렌 비스(인데닐)지르코늄 디메틸중에서 선택하는 방법.
  22. 제21항에 있어서, 첫번째 화합물이 에틸렌 비스(인데닐) 지르코늄 디메틸인 방법.
  23. 제22항에 있어서, 두번째 화합물이 N,N-디메틸아닐륨 테트라키스 (펜타플루오로페닐) 보로네이트인 방법.
  24. 제1항에 있어서, 촉매를 a) 일반식 Cp2MR"2(R"X) [여기서, Cp는 사이클로펜타디에닐 또는 치환된 사이클로펜타디에닐이고, M은 그룹 (III), (IV), (V) 또는 (VI) 금속이며, X는 할로겐이고, R'은 합한 알킬이다]의 사이클로펜타디에닐 금속 화합물을 테트라페닐보레이트 금속 화합물과 합하고, b) 테트라페닐보레이트 금속 화합물의 금속에 의해 사이클로펜디에닐 금속 화합물로부터 X-또는 R-이온의 추출을 허용하기에 충분한 시간동안 단계 a)중에서의 접촉을 유지시키고, c) 일반식 [Cp2MR"]+[BPh1]-의 이온쌍을 형성시키는 단계에 의해 제조하는 방법.
  25. 하기 일반식의 메탈로센 촉매 및 일반식 AlR3(여기서, R은 동일하거나 상이하며, 各各 할로겐, 산소, 수화물, 알킬, 알콕시 또는 아릴이고, R중의 하나 이상은 알킬이다)의 알루미늄 알킬을 포함함을 특징으로 하는 촉매계.
    [Cp2MR"P-1]+[A]-
    상기식에서, [Cp2MR"P-1]+는 메탈로센 양이온이고, Cp는 동일하거나 상이하며, 사이클로펜타디에닐 또는 치환된 펜타디에닐이고, M은 동일하거나 상이하며, 각각 수화물, 할로겐, 아미드 또는 하이드로카빌 라디칼이고, 하나의 R"를 제외한 나머지 R"은 수화물이고, p는 1내지 4이고, [A]-는 음이온이다.
  26. 제25항에 있어서, R이 알킬, 아릴, 알케닐, 알킬아릴 및 20개 이하의 탄소원자를 갖는 아릴알킬로 이루어진 그룹중에서 선택된 하이드로카빌 라디칼인 촉매.
  27. 제26항에 있어서, R이 알킬, 탄소수 6개 이하의 알콕시 또는 탄소수 10개 이하의 아릴인 촉매.
  28. 제27항에 있어서, M이 티탄, 지르코늄 및 하프늄으로 이루어진 그룹중에서 선택된 그룹(IV)금속인 촉매.
  29. 제28항에 있어서, 메탈로센의 천연 메틸 유도체가 에틸렌비스(테트라하이드로인데닐)지르코늄 디메틸, 에틸렌비스(인데닐) 지르코늄 디메틸, 에틸렌비스(인데닐)하프늄 디메틸 및 이소프로필리덴(사이클로펜타디에닐-1-플로오로레닐) 지르코늄 디메틸로 이루어진 그룹중에서 선택된 촉매.
  30. 제29항에 있어서, 음이온이 테트라키스(펜타플루오로레닐)보레이토 음이온인 촉매.
  31. 제30항에 있어서, 알루미늄 알킬이 트리에틸알루미늄 및 트리메틸알루미늄으로 이루어진 그룹중에서 선택된 촉매.
  32. 제31항에 있어서, 알루미늄 알킬이 트리에틸알루미늄인 촉매.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900016067A 1989-10-30 1990-10-10 알루미늄 알킬의 첨가에 의해 개선된 올레핀 중합용 메탈로센 촉매 KR100196613B1 (ko)

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US419222 1989-10-10
US41922289A 1989-10-30 1989-10-30

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Families Citing this family (216)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5241025A (en) * 1987-01-30 1993-08-31 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5153157A (en) * 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5391629A (en) * 1987-01-30 1995-02-21 Exxon Chemical Patents Inc. Block copolymers from ionic catalysts
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5384299A (en) * 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
IE904007A1 (en) * 1989-11-08 1991-05-08 Mount Isa Mines Condensation of metal vapours in a fluidized bed
US6294625B1 (en) 1990-03-20 2001-09-25 Exxonmobil Chemical Patents Inc. Catalyst system of enhanced productivity and its use in polymerization process
WO1992001723A1 (en) * 1990-07-24 1992-02-06 Mitsui Toatsu Chemicals, Incorporated CATALYST FOR α-OLEFIN POLYMERIZATION AND PRODUCTION OF POLY-α-OLEFIN THEREWITH
ATE134658T1 (de) * 1990-09-14 1996-03-15 Exxon Chemical Patents Inc Ionischer katalysator zur herstellung von polyalphaolefinen mit kontrollierter takticität
EP0513380B2 (en) † 1990-11-30 2011-02-23 Idemitsu Kosan Company Limited Process for producing olefinic polymer
JP2888648B2 (ja) * 1990-12-28 1999-05-10 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
TW300901B (ko) 1991-08-26 1997-03-21 Hoechst Ag
TW309523B (ko) * 1991-11-30 1997-07-01 Hoechst Ag
WO1993014132A1 (en) * 1992-01-06 1993-07-22 The Dow Chemical Company Improved catalyst composition
US5296433A (en) * 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
US5434116A (en) 1992-06-05 1995-07-18 Tosoh Corporation Organic transition metal compound having π-bonding heterocyclic ligand and method of polymerizing olefin by using the same
BE1005957A5 (fr) 1992-06-05 1994-04-05 Solvay Procede de preparation d'un systeme catalytique, procede de (co)polymerisation d'olefines et (co)polymeres d'au moins une olefine.
US5710222A (en) 1992-06-22 1998-01-20 Fina Technology, Inc. Method for controlling the melting points and molecular weights of syndiotactic polyolefins using metallocene catalyst systems
CA2105889A1 (en) * 1992-09-10 1994-03-11 Yoshio Tajima Catalyst component for the polymerization of olefins and process for preparing olefin polymers using same
US5461127A (en) * 1992-09-22 1995-10-24 Idemitsu Kosan Co., Ltd. Polymerization catalysts and process for producing polymers
ES2136132T3 (es) * 1992-10-05 1999-11-16 Exxon Chemical Patents Inc Procedimiento de polimerizacion que emplea un sistema catalizador con productividad mejorada.
US5317036A (en) * 1992-10-16 1994-05-31 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization reactions utilizing soluble unsupported catalysts
GB9226905D0 (en) * 1992-12-24 1993-02-17 Wellcome Found Pharmaceutical preparation
KR100311244B1 (ko) * 1993-02-22 2001-12-15 가지와라 야스시 에틸렌/α-올레핀공중합체의제조방법
BE1006880A3 (fr) * 1993-03-01 1995-01-17 Solvay Precurseur solide d'un systeme catalytique pour la polymerisation d'olefines, procede pour sa preparation, systeme catalytique comprenant ce precurseur solide et procede de polymerisation d'olefines en presence de ce systeme catalytique.
DE69431222T2 (de) * 1993-06-07 2003-04-17 Mitsui Chemicals Inc Übergangsmetallverbindung, und diese enthaltender Polymerisationkatalysator
EP1070729B1 (en) * 1993-06-07 2011-09-28 Mitsui Chemicals, Inc. Transition metal compound, olefin polymerization catalyst component comprising said compound, olefin polymerization catalyst containing said component, process for olefin polymerization using said catalyst, propylene homopolymer, propylene copolymer and propylene elastomer
JP3189175B2 (ja) * 1993-07-02 2001-07-16 出光興産株式会社 芳香族ビニル化合物共重合体の製造方法
JPH0733812A (ja) * 1993-07-02 1995-02-03 Idemitsu Kosan Co Ltd スチレン系重合体製造触媒及びそれを用いたスチレン系重合体の製造方法
US5631202A (en) * 1993-09-24 1997-05-20 Montell Technology Company B.V. Stereospecific metallocene catalysts with stereolocking α-CP substituents
DE4333569A1 (de) * 1993-10-01 1995-04-06 Hoechst Ag Verfahren zur Olefinpolymerisation
FI945959A (fi) * 1993-12-21 1995-06-22 Hoechst Ag Metalloseenejä ja niiden käyttö katalyytteinä
CN1104443C (zh) * 1994-04-11 2003-04-02 三井化学株式会社 丙烯聚合物组合物的制备方法和丙烯聚合物组合物
DE69511023T2 (de) * 1994-04-11 2000-01-27 Mitsui Chemicals Inc Verfahren zur herstellung einer propylen-polymerzusammensetzung und propylen-polymerzusammensetzung
DE4424227A1 (de) 1994-07-09 1996-01-11 Hoechst Ag Organometallverbindung
TW369547B (en) * 1994-09-21 1999-09-11 Mitsui Chemicals Inc Olefin polymerization catalyst and process for olefin polymerization
DE4434640C1 (de) 1994-09-28 1996-02-01 Hoechst Ag Verfahren zur Herstellung verbrückter Metallocene
DE4436113A1 (de) 1994-10-10 1996-04-11 Hoechst Ag Metallocenverbindung
EP0710663A1 (en) 1994-11-01 1996-05-08 Japan Polyolefins Co., Ltd. Boron-containing compound, its polymer, catalyst comprising the polymer and metallocene compound, and process for producing polyolefin
CA2183650C (en) * 1994-12-20 2006-01-03 Toshiyuki Tsutsui Process for preparing ethylene polymer and ethylene polymer
CN1076282C (zh) 1995-03-02 2001-12-19 三井化学株式会社 聚丙烯复合膜
TW401445B (en) * 1995-07-13 2000-08-11 Mitsui Petrochemical Ind Polyamide resin composition
US6403772B1 (en) * 1995-09-11 2002-06-11 Montell Technology Company, Bv Open-pentadienyl metallocenes, precursors thereof and polymerization catalysts therefrom
JP3766439B2 (ja) 1995-09-13 2006-04-12 三井化学株式会社 樹脂組成物の製造方法
EP0856526B1 (en) 1995-10-18 2002-08-28 Chisso Corporation Olefin (co)polymer composition, process for producing the same, catalyst for (co)polymerizing olefin, and process for producing the same
DE19546501A1 (de) 1995-12-13 1997-06-19 Hoechst Ag Metallocenverbindung
DE19546500A1 (de) 1995-12-13 1997-06-19 Hoechst Ag Verfahren zur Herstellung eines Cycloolefincopolymeren
HUP9603449A3 (en) 1995-12-15 2000-03-28 Union Carbide Chem Plastic Process for production of long-chain branched polyolefins, polyethylene composition and product
DE19549352A1 (de) * 1995-12-22 1997-06-26 Gerhard Edwin Herberich Übergangsmetallverbindung der Formel Ln Am MXK (M=Metall der Gruppe IIIb oder Vb) und Verfahren zur Herstellung der Verbindung sowie Verwendung der Verbindung als Katalysatorkomponente bei der Polymerisation von Olefinen
DE19622207A1 (de) 1996-06-03 1997-12-04 Hoechst Ag Chemische Verbindung
US5959044A (en) * 1996-07-08 1999-09-28 Villar; Juan Carlos Method of controlling continuous ethylene-limited metallocene-catalyzed copolymerization systems
TW425414B (en) * 1997-02-18 2001-03-11 Chisso Corp Preactivated catalyst for olefin (co)polymerization, catalyst for olefin (co)polymerization and olefin (co)polymer composition and their manufacturing method
EP0972800A4 (en) 1997-04-02 2004-06-16 Chisso Corp MODIFIED OLEFIN (CO) POLYMER COMPOSITION, METHOD FOR THE PRODUCTION THEREOF AND MODIFIED OLEFIN (CO) POLYMER MOLD
US6303696B1 (en) 1997-04-11 2001-10-16 Chisso Corporation Propylene (co)polymer composition using metallocene catalyst
JP3817015B2 (ja) * 1997-04-14 2006-08-30 三井化学株式会社 環状オレフィン系共重合体およびその用途
TWI246520B (en) 1997-04-25 2006-01-01 Mitsui Chemicals Inc Processes for olefin polymerization
US6160072A (en) * 1997-05-02 2000-12-12 Ewen; John A. Process for polymerizing tactioselective polyolefins in condensed phase using titanocenes
TW504515B (en) 1997-08-07 2002-10-01 Chisso Corp Olefin (co)polymer composition
US6025407A (en) * 1997-10-30 2000-02-15 Occidental Chemical Corporation Photo-polymerization of vinyl chloride using metallocene catalysts
FI980342A0 (fi) * 1997-11-07 1998-02-13 Borealis As Polymerroer och -roerkopplingar
TW562810B (en) 1998-04-16 2003-11-21 Mitsui Chemicals Inc Catalyst for olefinic polymerization and method for polymerizing olefine
US6225427B1 (en) 1998-10-15 2001-05-01 Uniroyal Chemical Company, Inc. Olefin polymerization process employing metallocene catalyst provided by cocatalyst activation of a metallocene procatalyst
US6486088B1 (en) 1998-10-23 2002-11-26 Exxonmobil Chemical Patents Inc. High activity carbenium-activated polymerization catalysts
US6300433B1 (en) * 1998-10-23 2001-10-09 Exxonmobil Chemical Patents Inc. Olefin copolymerization process with bridged hafnocenes
TW576843B (en) 1998-12-25 2004-02-21 Mitsui Chemicals Inc Olefin polymerization catalyst and process for olefin polymerization using the olefin polymerization catalyst
JP2000351813A (ja) 1999-04-09 2000-12-19 Mitsui Chemicals Inc エチレン・α−オレフィン共重合体およびその製造方法ならびにその用途
US6632885B2 (en) 1999-04-13 2003-10-14 Mitsui Chemicals, Inc. Soft syndiotactic polypropylene composition and molded product
US6291386B1 (en) 1999-05-25 2001-09-18 Equistar Chemicals, Lp Process for the in-situ preparation of single-site transition metal catalysts and polymerization process
JP3808243B2 (ja) 1999-07-27 2006-08-09 三井化学株式会社 軟質樹脂組成物
US6399535B1 (en) 1999-11-01 2002-06-04 W. R. Grace & Co.-Conn. Coordination catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
US6559090B1 (en) 1999-11-01 2003-05-06 W. R. Grace & Co.-Conn. Metallocene and constrained geometry catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
EP1197500B1 (en) 2000-01-26 2011-05-18 Mitsui Chemicals, Inc. Olefin triblock copolymers and production processes thereof
CN1128168C (zh) 2000-03-31 2003-11-19 三井化学株式会社 聚烯烃组合物的制备方法
US6635733B2 (en) 2000-05-23 2003-10-21 Chisso Corporation Elastomeric polypropylene
US6846943B2 (en) 2000-05-23 2005-01-25 Chisso Corporation Metallocene compound, olefin polymerization catalyst containing the compound, and method for producing an olefin polymer by use of the catalyst
US7053159B2 (en) 2000-07-04 2006-05-30 Mitsui Chemicals, Inc. Process for producing polar olefin copolymer and polar olefin copolymer obtained thereby
JP2002020417A (ja) 2000-07-04 2002-01-23 Mitsui Chemicals Inc オレフィンの重合方法
DE50105207D1 (de) 2000-07-06 2005-03-03 Basf Ag Metallverbindungen und ihre verwendung zur polymerisation von olefinen
KR100467277B1 (ko) 2000-07-26 2005-01-24 미쓰이 가가쿠 가부시키가이샤 분기형 폴리올레핀 및 그 제조방법
ES2276731T3 (es) 2000-09-07 2007-07-01 Mitsui Chemicals, Inc. Copolimero de olefina que contiene un grupo polar, procedimiento para preparar el mismo, composicion de resina termoplastica que contiene el copolimero y usos de los mismos.
KR100844062B1 (ko) 2001-02-21 2008-07-07 미쓰이 가가쿠 가부시키가이샤 올레핀 중합용 촉매 및 이 촉매를 사용하는 올레핀중합체의 제조방법
US6946420B2 (en) 2001-04-30 2005-09-20 W. R. Grace & Co.-Conn Coordination catalyst systems employing chromium support-agglomerate and method of their preparation
EP1399491B1 (en) 2001-04-30 2006-08-23 W.R. Grace & Co.-Conn. Supported dual transition metal catalyst systems
US6943224B2 (en) 2001-04-30 2005-09-13 W. R. Grace & Co.-Conn. Process for preparing supported transition metal catalyst systems and catalyst systems prepared thereby
KR100628620B1 (ko) 2001-04-30 2006-09-26 더블유.알. 그레이스 앤드 캄파니-콘. 이종 크롬 촉매 및 이를 사용하는 올레핀의 중합 방법
KR100540049B1 (ko) 2001-04-30 2006-01-20 더블유.알. 그레이스 앤드 캄파니-콘. 지지된 전이 금속 중합 촉매의 제조 방법 및 이 방법으로형성된 조성물
CN1276018C (zh) 2001-06-22 2006-09-20 埃克森美孚化学专利公司 作为抗冲改性剂的茂金属生产的极低密聚乙烯或线型低密度聚乙烯
US7019157B2 (en) 2001-08-06 2006-03-28 Chisso Corporation Metallocene compounds, production process for olefin polymers using catalysts containing them and olefin polymers produced by the production process
EP1449853B1 (en) 2001-10-19 2015-06-03 Asahi Kasei Chemicals Corporation Process for polymerization of olefins
DE10211386A1 (de) 2002-03-14 2003-09-25 Basf Ag Verfahren zur Oligomerisierung von Olefinen unter Verwendung eines Cycloalkylalkyl-substituierten Triazacyclohexans
US7153571B2 (en) 2002-07-31 2006-12-26 Exxonmobil Chemical Patents Inc. Silane crosslinkable polyethylene
US6995279B2 (en) 2002-08-02 2006-02-07 Chisso Corporation Metallocene compounds, processes for the production of olefin polymers using catalysts containing the compounds, and olefin polymers produced by the processes
DE60321007D1 (de) 2002-09-05 2008-06-26 Exxonmobil Chem Patents Inc Schrumpffolie
DE60335634D1 (de) 2002-09-05 2011-02-17 Exxonmobil Chem Patents Inc Stretchfoliewickelverfahren
KR100456396B1 (ko) * 2002-09-17 2004-11-10 삼성전자주식회사 반도체 소자 테스트 장치의 프로브 팁 샌딩 제어방법 및샌딩 제어장치
EP2465879B1 (en) 2002-09-27 2019-04-24 Mitsui Chemicals, Inc. Bridged metallocene compound for olefin polymerization and method of polymerizing olefin using the same
EP1555272B1 (en) 2002-10-23 2010-12-08 Mitsui Chemicals, Inc. Supported olefin polymerisation catalyst
DE10251513A1 (de) 2002-11-04 2004-05-19 Basf Ag Übergangsmetallkatalysatoren für (Co)Polymerisation von olefinischen Monomeren
KR101004338B1 (ko) 2003-03-28 2010-12-28 미쓰이 가가쿠 가부시키가이샤 프로필렌／1―부텐 공중합체, 폴리프로필렌 조성물 및 그 용도, 및 폴리프로필렌 복합 필름
US7453005B2 (en) 2004-01-28 2008-11-18 Idemitsu Kosan Co., Ltd. Transition metal compound and catalyst for olefin polymerization
EP1661921B1 (en) 2004-11-26 2019-07-17 Mitsui Chemicals, Inc. Synthetic lubricating oil and lubricating oil composition thereof
KR100886442B1 (ko) * 2004-12-22 2009-03-04 미쓰이 가가쿠 가부시키가이샤 프로필렌계 중합체, 그 중합체를 함유하는 조성물 및이들로부터 얻어지는 성형체
JP5438256B2 (ja) 2006-11-17 2014-03-12 三井化学株式会社 ポリプロピレン系樹脂フィルムおよびその用途
EP2275451B1 (en) 2005-05-18 2016-10-19 Mitsui Chemicals, Inc. Method for producing propylene-based copolymer
US7282546B2 (en) * 2005-06-22 2007-10-16 Fina Technology, Inc. Cocatalysts for reduction of production problems in metallocene-catalyzed polymerizations
CA2615982C (en) 2005-07-19 2012-02-21 Exxonmobil Chemical Patents Inc. Polyalpha-olefin compositions and processes to produce the same
US20070080483A1 (en) * 2005-10-07 2007-04-12 Mitsui Chemicals, Inc. Process for producing injection molded product
US20070225423A1 (en) * 2005-10-07 2007-09-27 Mitsui Chemicals, Inc. Process for producing blow molded product by blow molding
KR101289591B1 (ko) 2005-10-26 2013-07-26 다우 글로벌 테크놀로지스 엘엘씨 다층 사전-연신된 탄성 물품
US7605208B2 (en) 2005-10-31 2009-10-20 Mitsui Chemicals, Inc. Process for producing thermoplastic resin composition
CN101003595B (zh) 2006-01-18 2010-12-15 住友化学株式会社 制备乙烯-α-烯烃-多烯无规共聚物的方法
EP1992658A4 (en) * 2006-02-15 2011-04-06 Mitsui Chemicals Inc ENVIRONMENTALLY RESTRICTED STRESS RESISTANCE MODIFIER AND MODIFIED RESIN COMPOSITION IN RESISTANCE TO ENVIRONMENTALLY CONTAINING BREAKAGE CONTAINING THE SAME
CN101384627A (zh) * 2006-02-15 2009-03-11 三井化学株式会社 乙烯系树脂以及由其形成的吹塑成型体
EP1995037B1 (en) 2006-03-10 2011-07-06 Mitsui Chemicals, Inc. Process for production of moldings by the inflation method
US20090166911A1 (en) 2006-03-27 2009-07-02 Mitsui Chemicals, Inc. Process for Producing Molded Article by T-Die Molding
JP2007261201A (ja) 2006-03-29 2007-10-11 Mitsui Chemicals Inc ブロー成形による成形体の製造方法
WO2007114009A1 (ja) 2006-03-30 2007-10-11 Mitsui Chemicals, Inc. 射出成形による成形体の製造方法
US7951873B2 (en) 2006-05-05 2011-05-31 Exxonmobil Chemical Patents Inc. Linear low density polymer blends and articles made therefrom
KR101096836B1 (ko) 2006-07-31 2011-12-22 가부시키가이샤 프라임 폴리머 에틸렌계 수지 또는 에틸렌계 수지 조성물로 이루어지는 필름 또는 적층체
CA2666807C (en) 2006-10-20 2012-05-29 Mitsui Chemicals, Inc. Copolymer, lubricating oil viscosity modifier, and lubricating oil composition
DE102006057822A1 (de) 2006-12-06 2008-06-26 Basell Poliolefine Italia S.R.L. Mehrschichtiges Verbundmaterial mit inhärent latentem Schutz gegenüber Verformung unter Temperatureinwirkung als Ausgleich des Bi-Metalleffektes
DE102006060459A1 (de) * 2006-12-19 2008-06-26 Basell Poliolefine Italia S.R.L. Mehrschichtiges Verbundmaterial mit mindestens einer Glasschicht
EP2096126A1 (en) 2006-12-19 2009-09-02 Mitsui Chemicals, Inc. Solid catalyst for olefin polymerization, olefin polymerization method, and olefin polymer particle produced by the method
EP2105464B1 (en) * 2007-01-16 2012-03-28 Prime Polymer Co., Ltd. Ethylene resin composition for blow molded body, and blow molded body obtained from the same
CN101679702B (zh) 2007-06-14 2012-07-04 三井化学株式会社 热塑性弹性体组合物
JP5226973B2 (ja) 2007-06-15 2013-07-03 三井化学株式会社 エチレン系共重合体、該共重合体を含む組成物ならびにその用途
CN101687776B (zh) 2007-07-04 2015-07-01 三井化学株式会社 过渡金属配位化合物、含有该化合物的烯烃聚合用催化剂以及在该催化剂存在下进行的烯烃聚合物的制造方法
WO2009066689A1 (ja) 2007-11-19 2009-05-28 Mitsui Chemicals, Inc. 架橋メタロセン化合物およびそれを用いたオレフィン重合用触媒、ならびに該触媒を用いて得られるエチレン系重合体
DE102007057606A1 (de) 2007-11-28 2009-06-04 Basell Polyolefine Gmbh Modular aufgebaute Rotationstrommel für Elektro- und Haushaltsgeräte
CA2709566A1 (en) * 2007-12-17 2009-06-25 Gliamed, Inc. Stem-like cells and method for reprogramming adult mammalian somatic cells
WO2009119536A1 (ja) 2008-03-27 2009-10-01 三井化学株式会社 樹脂組成物およびその用途
US9469756B2 (en) 2008-03-31 2016-10-18 Mitsui Chemicals, Inc. Resin composition and melt bag
JP5754940B2 (ja) 2008-08-19 2015-07-29 三井化学株式会社 混合触媒によるプロピレン重合体の製造方法
US20100317711A1 (en) * 2008-12-17 2010-12-16 Gliamed, Inc. Stem-like cells and method for reprogramming adult mammalian somatic cells
BRPI1013726B1 (pt) 2009-04-21 2019-10-08 Mitsui Chemicals, Inc. Método para a produção de polímero de olefina
US8309749B2 (en) 2009-06-11 2012-11-13 W R Grace & Co-Conn Process of making aluminoxane and catalysts containing thus prepared aluminoxane
US9017593B2 (en) 2009-06-16 2015-04-28 Exxonmobil Chemical Patents Inc. Composite materials comprising propylene-based polymer blend coatings
US8791284B2 (en) 2009-07-01 2014-07-29 Mitsui Chemicals, Inc. Organometallic compound and production method thereof
WO2011011124A1 (en) 2009-07-23 2011-01-27 Exxonmobil Chemical Patents Inc. Polypropylene-based elastomer coating compositions
US9005739B2 (en) 2009-07-23 2015-04-14 Exxonmobil Chemical Patents Inc. Laminated articles and their production
WO2011020582A1 (en) 2009-08-18 2011-02-24 Basell Polyolefine Gmbh Plastic fuel container for motor bikes or automotive hybrid cars
BR112012003425B1 (pt) 2009-08-18 2019-12-17 Basell Polyolefine Gmbh alojamento apropriado para compreender múltiplas células de energia elétrica em veículos automotivos acionados eletricamente
US9879160B2 (en) 2009-10-29 2018-01-30 Exxonmobil Chemical Patents Inc. Pressure-sensitive hot melt adhesive compositions
EP2518089B1 (en) 2009-12-21 2014-11-26 Mitsui Chemicals, Inc. Process for production of syndiotactic alpha-olefin polymer
US20120135903A1 (en) 2010-05-11 2012-05-31 Mitsui Chemicals, Inc. Lubricating oil composition
JP5688236B2 (ja) 2010-05-25 2015-03-25 出光興産株式会社 触媒組成物及び当該触媒組成物を用いるオレフィン系重合体の製造方法
SG188465A1 (en) 2010-10-15 2013-05-31 Exxonmobil Chem Patents Inc Polypropylene-based adhesive compositions
CA2824771A1 (en) 2011-01-14 2012-07-19 W.R. Grace & Co.-Conn. Process of making modified metallocene catalyst, catalyst produced and use thereof
WO2012157709A1 (ja) 2011-05-18 2012-11-22 三井化学株式会社 プロピレン系共重合体、プロピレン系共重合体組成物、その成形体およびその発泡体、およびそれらの製造方法
EP2766458B1 (en) 2011-10-10 2018-03-28 ExxonMobil Chemical Patents Inc. Process to produce poly alpha olefin compositions
JP5769821B2 (ja) 2011-12-27 2015-08-26 三井化学株式会社 ４−メチル−１−ペンテン（共）重合体組成物、該組成物からなるフィルムおよび中空成形体
JP5943941B2 (ja) 2011-12-28 2016-07-05 三井化学株式会社 エチレン系重合体組成物、及びこれから得られる成形体
US8664461B2 (en) 2012-03-19 2014-03-04 Exxonmobil Chemical Patents Inc. Catalysts for producing polyalpha-olefins and processes related thereto
WO2013140991A1 (ja) 2012-03-21 2013-09-26 三井化学株式会社 オレフィン重合体の製造方法
CN104247042B (zh) 2012-03-28 2016-07-06 三井化学株式会社 太阳能电池密封材及太阳能电池模块
CN102796008A (zh) * 2012-07-05 2012-11-28 河南颖泰化工有限责任公司 一种mea生产中排放气体回收再利用的工艺
KR101640356B1 (ko) 2012-09-25 2016-07-15 미쓰이 가가쿠 가부시키가이샤 올레핀 중합체의 제조 방법 및 올레핀 중합체
US9458261B2 (en) 2012-09-25 2016-10-04 Mitsui Chemicals, Inc. Transition metal compound, olefin polymerization catalyst, and olefin polymer production process
KR101394943B1 (ko) 2012-11-19 2014-05-14 대림산업 주식회사 에틸렌과 알파-올레핀의 공중합체 및 그 제조방법
SG11201506544UA (en) 2013-02-20 2015-09-29 Prime Polymer Co Ltd Biaxially-stretched film and ethylene polymer composition
BR112015020451A2 (pt) 2013-02-27 2017-07-18 Mitsui Chemicals Inc catalisador para multimerização de olefina e método para produzir multímero de olefina na presença de um catalisador para multimerização de olefina
EP2975069B1 (en) 2013-03-12 2018-09-05 Mitsui Chemicals, Inc. Method for producing olefin polymer and catalyst for olefin polymerization
JP6161716B2 (ja) 2013-10-18 2017-07-12 三井化学株式会社 エチレン・α−オレフィン共重合体を含有する接着剤
BR112016016396B1 (pt) 2014-02-13 2021-08-10 Mitsui Chemicals, Inc. Processo para a produção de copolímero de etileno/a-olefina
US10919997B2 (en) 2014-02-13 2021-02-16 Mitsui Chemicals, Inc. Ethylene α-olefin non-conjugated polyene copolymer, use thereof, and manufacturing method thereof
JP6259842B2 (ja) 2014-02-14 2018-01-10 三井化学株式会社 エチレン・α−オレフィン・非共役ポリエン共重合体、その製造方法ならびに用途
US10004293B2 (en) 2014-02-28 2018-06-26 Mitsui Chemicals, Inc. Crosslinked product, method for producing the same and the use thereof, and ethylene copolymer
MX2016012449A (es) 2014-03-28 2017-01-06 Mitsui Chemicals Inc Resina de olefina y metodo para producirla.
EP3124505A4 (en) 2014-03-28 2017-12-06 Mitsui Chemicals, Inc. Ethylene/alpha-olefin copolymer and lubricating oil
KR101850233B1 (ko) 2014-03-28 2018-04-18 미쓰이 가가쿠 가부시키가이샤 올레핀계 수지, 그의 제조 방법 및 프로필렌계 수지 조성물
CN106795449B (zh) 2014-09-10 2020-08-07 三井化学株式会社 润滑油组合物
CN106715487B (zh) 2014-09-11 2021-02-26 三井化学株式会社 包含来源于1-丁烯的构成单元的烯烃(共)聚合物的制造方法
WO2016093266A1 (ja) 2014-12-09 2016-06-16 三井化学株式会社 プロピレン系樹脂組成物
US10280293B2 (en) 2015-03-20 2019-05-07 Mitsui Chemicals, Inc. Thermoplastic elastomer composition and method for producing same
JP6439039B2 (ja) 2015-03-20 2018-12-19 三井化学株式会社 熱可塑性エラストマー組成物、その用途、その製造方法、エチレン・α−オレフィン・非共役ポリエン共重合体およびその用途
CN107406646B (zh) 2015-03-31 2020-06-09 三井化学株式会社 树脂组合物及其用途
US20180320102A1 (en) 2015-11-09 2018-11-08 Mitsui Chemicals, Inc. Viscosity modifier for lubricating oils, additive composition for lubricating oils, and lubricating oil compositions
CA3004086C (en) 2015-12-16 2020-06-02 Exxonmobil Chemical Patents Inc. Low crystalline polymer compositions
WO2017150612A1 (ja) 2016-03-04 2017-09-08 三井化学株式会社 積層体およびその用途
SG11201807680TA (en) 2016-03-31 2018-10-30 Exxonmobil Chemical Patents Inc Low crystalline polymer compositions prepared in a dual reactor
KR102208021B1 (ko) 2017-01-16 2021-01-26 미쓰이 가가쿠 가부시키가이샤 자동차 기어용 윤활유 조성물
MX2019009837A (es) 2017-02-20 2019-10-04 Mitsui Chemicals Inc Laminado.
MX2019009838A (es) 2017-02-20 2019-10-04 Mitsui Chemicals Inc Laminado.
EP3642313A1 (en) 2017-06-22 2020-04-29 ExxonMobil Research and Engineering Company Low viscosity lubricants based on methyl paraffin containing hydrocarbon fluids
CN110869337A (zh) 2017-07-06 2020-03-06 三井化学株式会社 烯烃多聚化用催化剂及在该催化剂存在下进行的烯烃多聚体的制造方法
EP3862361A1 (en) * 2017-09-28 2021-08-11 Univation Technologies, LLC Synthesis of cyclic organic compounds and metallocenes
US11905348B2 (en) 2018-03-20 2024-02-20 Mitsui Chemicals, Inc. Ethylene/alpha-olefin/non-conjugated polyene copolymer, method for producing the same, and use thereof
EP3853191A4 (en) 2018-09-17 2022-08-24 ExxonMobil Chemical Patents Inc. PROCESS FOR THE PREPARATION OF POLYALPHA OLEFIN TRIMER AND APPARATUS THEREOF
EP3892649B1 (en) 2018-12-04 2024-02-14 Mitsui Chemicals, Inc. Resin composition containing 4-methyl-1-pentene copolymer, and film for capacitors
WO2020189676A1 (ja) 2019-03-19 2020-09-24 三井化学株式会社 プロピレン系樹脂組成物、成形体およびプロピレン重合体
KR20210139404A (ko) 2019-03-26 2021-11-22 미쓰이 가가쿠 가부시키가이샤 내연 기관용 윤활유 조성물 및 그의 제조 방법
US20220186134A1 (en) 2019-03-26 2022-06-16 Mitsui Chemicals, Inc. Lubricating oil composition for internal combustion engines and method for producing the same
KR20210139403A (ko) 2019-03-26 2021-11-22 미쓰이 가가쿠 가부시키가이샤 공업 기어용 윤활유 조성물 및 그의 제조 방법
KR20210139400A (ko) 2019-03-26 2021-11-22 미쓰이 가가쿠 가부시키가이샤 자동차 기어용 윤활유 조성물 및 그의 제조 방법
EP3950894A4 (en) 2019-03-26 2022-08-17 Mitsui Chemicals, Inc. LUBRICANT OIL COMPOSITION AND PROCESS FOR PRODUCTION THEREOF
CN113614208A (zh) 2019-03-26 2021-11-05 三井化学株式会社 润滑油组合物及其制造方法
CN113574150A (zh) 2019-03-26 2021-10-29 三井化学株式会社 汽车变速箱油用润滑油组合物及其制造方法
KR20210138717A (ko) 2019-03-26 2021-11-19 미쓰이 가가쿠 가부시키가이샤 작동유용 윤활유 조성물 및 그의 제조 방법
WO2020194550A1 (ja) 2019-03-26 2020-10-01 三井化学株式会社 グリース組成物およびその製造方法
WO2020194551A1 (ja) 2019-03-26 2020-10-01 三井化学株式会社 圧縮機油用潤滑油組成物およびその製造方法
CN113366036B (zh) 2019-03-29 2023-10-24 三井化学株式会社 树脂组合物
JP7284821B2 (ja) 2019-08-08 2023-05-31 株式会社プライムポリマー プロピレン系重合体組成物および成形体
WO2021029938A1 (en) 2019-08-09 2021-02-18 Exxonmobil Chemical Patents Inc. Processes for producing poly alpha olefins and method of analysis and apparatuses therefor
WO2021029939A1 (en) 2019-08-09 2021-02-18 Exxonmobil Chemical Patents Inc. Processes for producing poly alpha olefins and apparatuses therefor
WO2021070811A1 (ja) 2019-10-07 2021-04-15 三井化学株式会社 エチレン・α－オレフィン共重合体組成物およびその用途
EP4051656A1 (en) 2019-10-28 2022-09-07 ExxonMobil Chemical Patents Inc. Dimer selective metallocene catalysts, non-aromatic hydrocarbon soluble activators, and processes to produce poly alpha-olefin oligmers therewith
EP4053210A4 (en) 2019-10-29 2023-12-06 Mitsui Chemicals, Inc. ETHYLENE-BASED COPOLYMER COMPOSITION AND USE THEREOF
KR20220123062A (ko) 2020-01-30 2022-09-05 미쓰이 가가쿠 가부시키가이샤 폴리아마이드 조성물
WO2022075350A1 (ja) 2020-10-06 2022-04-14 三井化学株式会社 樹脂組成物
JPWO2022154126A1 (ko) 2021-01-18 2022-07-21
WO2022186053A1 (ja) 2021-03-05 2022-09-09 三井化学株式会社 熱可塑性エラストマー組成物
WO2022210845A1 (ja) 2021-03-31 2022-10-06 三井化学株式会社 エチレン系樹脂組成物および成形体
WO2022210844A1 (ja) 2021-03-31 2022-10-06 三井化学株式会社 エチレン－α－オレフィン共重合体、熱可塑性樹脂組成物、およびフィルム
EP4316833A1 (en) 2021-03-31 2024-02-07 Mitsui Chemicals, Inc. ETHYLENE-a-OLEFIN COPOLYMER, THERMOPLASTIC RESIN COMPOSITION, FILM, AND LAMINATE
JPWO2022244879A1 (ko) 2021-05-20 2022-11-24
WO2023090308A1 (ja) 2021-11-16 2023-05-25 三井化学株式会社 樹脂組成物およびその用途

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3242099A (en) * 1964-03-27 1966-03-22 Union Carbide Corp Olefin polymerization catalysts
US3756998A (en) * 1968-10-14 1973-09-04 Union Carbide Corp L catalysts polymerization of olefins using supported pi arenechromium tricarbony
US3709853A (en) * 1971-04-29 1973-01-09 Union Carbide Corp Polymerization of ethylene using supported bis-(cyclopentadienyl)chromium(ii)catalysts
CA1238145A (en) * 1982-09-30 1988-06-14 Kenneth W. Powers Modified lewis acid catalyzed polymerization
US4808561A (en) * 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
CA1268754A (en) * 1985-06-21 1990-05-08 Howard Curtis Welborn, Jr. Supported polymerization catalyst
US5153157A (en) * 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
IL85097A (en) * 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5241025A (en) * 1987-01-30 1993-08-31 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
DK0426637T4 (da) * 1989-10-30 2002-01-14 Fina Technology Fremgangsmåde til fremstilling af metallocenkatalysatorer til polymerisation af olefiner

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ATE137247T1 (de) 1996-05-15
CN1111641A (zh) 1995-11-15
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EP0426638B2 (en) 2005-03-02
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CN1037685C (zh) 1998-03-11
CN1051365A (zh) 1991-05-15
JP2939321B2 (ja) 1999-08-25
CN1037686C (zh) 1998-03-11
US5519100A (en) 1996-05-21
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