JPS6125703B2 - - Google Patents
Info
- Publication number
- JPS6125703B2 JPS6125703B2 JP535782A JP535782A JPS6125703B2 JP S6125703 B2 JPS6125703 B2 JP S6125703B2 JP 535782 A JP535782 A JP 535782A JP 535782 A JP535782 A JP 535782A JP S6125703 B2 JPS6125703 B2 JP S6125703B2
- Authority
- JP
- Japan
- Prior art keywords
- compounds
- compound
- reaction
- isomer
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 aromatic amino compound Chemical class 0.000 claims description 65
- 238000006243 chemical reaction Methods 0.000 claims description 60
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 42
- 150000001875 compounds Chemical class 0.000 claims description 29
- 238000000034 method Methods 0.000 claims description 25
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 23
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 22
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 22
- 125000003118 aryl group Chemical group 0.000 claims description 20
- 229910052751 metal Inorganic materials 0.000 claims description 18
- 239000002184 metal Substances 0.000 claims description 18
- 239000003054 catalyst Substances 0.000 claims description 17
- 239000010948 rhodium Substances 0.000 claims description 17
- 229910052736 halogen Inorganic materials 0.000 claims description 16
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 15
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 15
- 150000002367 halogens Chemical class 0.000 claims description 15
- 150000004010 onium ions Chemical class 0.000 claims description 14
- 239000007800 oxidant agent Substances 0.000 claims description 14
- 150000002828 nitro derivatives Chemical class 0.000 claims description 13
- 229910052763 palladium Inorganic materials 0.000 claims description 12
- 150000001450 anions Chemical class 0.000 claims description 11
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 229910052703 rhodium Inorganic materials 0.000 claims description 8
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 8
- 229910001882 dioxygen Inorganic materials 0.000 claims description 7
- 229910052740 iodine Inorganic materials 0.000 claims description 4
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 3
- 150000003868 ammonium compounds Chemical class 0.000 claims description 3
- 239000011630 iodine Substances 0.000 claims description 3
- 150000002941 palladium compounds Chemical class 0.000 claims 1
- 150000003284 rhodium compounds Chemical class 0.000 claims 1
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 239000001257 hydrogen Substances 0.000 description 9
- 229910052739 hydrogen Inorganic materials 0.000 description 9
- JNMIXMFEVJHFNY-UHFFFAOYSA-M methyl(triphenyl)phosphanium;iodide Chemical compound [I-].C=1C=CC=CC=1[P+](C=1C=CC=CC=1)(C)C1=CC=CC=C1 JNMIXMFEVJHFNY-UHFFFAOYSA-M 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 150000004714 phosphonium salts Chemical class 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 125000003277 amino group Chemical group 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 6
- 238000006479 redox reaction Methods 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- 125000002723 alicyclic group Chemical group 0.000 description 5
- 125000004093 cyano group Chemical group *C#N 0.000 description 5
- 229910000765 intermetallic Inorganic materials 0.000 description 5
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- VUEDNLCYHKSELL-UHFFFAOYSA-N arsonium Chemical class [AsH4+] VUEDNLCYHKSELL-UHFFFAOYSA-N 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 239000001569 carbon dioxide Substances 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 4
- LBKPGNUOUPTQKA-UHFFFAOYSA-N ethyl n-phenylcarbamate Chemical compound CCOC(=O)NC1=CC=CC=C1 LBKPGNUOUPTQKA-UHFFFAOYSA-N 0.000 description 4
- 150000004677 hydrates Chemical class 0.000 description 4
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 4
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 101150003085 Pdcl gene Proteins 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 125000002877 alkyl aryl group Chemical group 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 125000003368 amide group Chemical group 0.000 description 3
- JFDZBHWFFUWGJE-UHFFFAOYSA-N benzonitrile Chemical compound N#CC1=CC=CC=C1 JFDZBHWFFUWGJE-UHFFFAOYSA-N 0.000 description 3
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 3
- 150000001768 cations Chemical group 0.000 description 3
- 150000001805 chlorine compounds Chemical class 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 125000004185 ester group Chemical group 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- 125000005843 halogen group Chemical group 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 239000003446 ligand Substances 0.000 description 3
- 229910052753 mercury Inorganic materials 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- VLZLOWPYUQHHCG-UHFFFAOYSA-N nitromethylbenzene Chemical compound [O-][N+](=O)CC1=CC=CC=C1 VLZLOWPYUQHHCG-UHFFFAOYSA-N 0.000 description 3
- 150000002902 organometallic compounds Chemical class 0.000 description 3
- 150000002989 phenols Chemical class 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 239000011669 selenium Substances 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- 125000001174 sulfone group Chemical group 0.000 description 3
- 125000003375 sulfoxide group Chemical group 0.000 description 3
- 229910052716 thallium Inorganic materials 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 229910052720 vanadium Inorganic materials 0.000 description 3
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- BBMCTIGTTCKYKF-UHFFFAOYSA-N 1-heptanol Chemical compound CCCCCCCO BBMCTIGTTCKYKF-UHFFFAOYSA-N 0.000 description 2
- VOZKAJLKRJDJLL-UHFFFAOYSA-N 2,4-diaminotoluene Chemical compound CC1=CC=C(N)C=C1N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000002841 Lewis acid Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 125000003710 aryl alkyl group Chemical group 0.000 description 2
- 239000010425 asbestos Substances 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 229910052797 bismuth Inorganic materials 0.000 description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical class C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 239000013522 chelant Substances 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 2
- 229960002089 ferrous chloride Drugs 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- MTAUFTAICGOFHS-UHFFFAOYSA-N iodoarsenic Chemical compound I[As] MTAUFTAICGOFHS-UHFFFAOYSA-N 0.000 description 2
- 229910052741 iridium Inorganic materials 0.000 description 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 2
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 2
- 150000007517 lewis acids Chemical class 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 239000002808 molecular sieve Substances 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- ZWRUINPWMLAQRD-UHFFFAOYSA-N nonan-1-ol Chemical compound CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- 229910052762 osmium Inorganic materials 0.000 description 2
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 2
- REIUXOLGHVXAEO-UHFFFAOYSA-N pentadecan-1-ol Chemical compound CCCCCCCCCCCCCCCO REIUXOLGHVXAEO-UHFFFAOYSA-N 0.000 description 2
- 150000003003 phosphines Chemical class 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229910052895 riebeckite Inorganic materials 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- 229910052711 selenium Inorganic materials 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 229910052714 tellurium Inorganic materials 0.000 description 2
- 125000005497 tetraalkylphosphonium group Chemical group 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- AEFPPQGZJFTXDR-UHFFFAOYSA-M tetraphenylphosphanium;iodide Chemical compound [I-].C1=CC=CC=C1[P+](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 AEFPPQGZJFTXDR-UHFFFAOYSA-M 0.000 description 2
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- 239000011135 tin Substances 0.000 description 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- KJIOQYGWTQBHNH-UHFFFAOYSA-N undecanol Chemical compound CCCCCCCCCCCO KJIOQYGWTQBHNH-UHFFFAOYSA-N 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- BOSAWIQFTJIYIS-UHFFFAOYSA-N 1,1,1-trichloro-2,2,2-trifluoroethane Chemical compound FC(F)(F)C(Cl)(Cl)Cl BOSAWIQFTJIYIS-UHFFFAOYSA-N 0.000 description 1
- ZATPKSSOFSKEHN-UHFFFAOYSA-N 1,1-bis(nitromethyl)cyclohexane Chemical compound [O-][N+](=O)CC1(C[N+]([O-])=O)CCCCC1 ZATPKSSOFSKEHN-UHFFFAOYSA-N 0.000 description 1
- SFCLUGLYUWEHFR-UHFFFAOYSA-N 1,1-dinitrobutane Chemical compound CCCC([N+]([O-])=O)[N+]([O-])=O SFCLUGLYUWEHFR-UHFFFAOYSA-N 0.000 description 1
- OWJVEZJJRYZWNI-UHFFFAOYSA-N 1,1-dinitrocyclohexane Chemical compound [O-][N+](=O)C1([N+]([O-])=O)CCCCC1 OWJVEZJJRYZWNI-UHFFFAOYSA-N 0.000 description 1
- SXIFBSOJAOXBRP-UHFFFAOYSA-N 1,1-dinitrodecane Chemical compound CCCCCCCCCC([N+]([O-])=O)[N+]([O-])=O SXIFBSOJAOXBRP-UHFFFAOYSA-N 0.000 description 1
- HLUAPIYZVLAARK-UHFFFAOYSA-N 1,1-dinitrohexane Chemical compound CCCCCC([N+]([O-])=O)[N+]([O-])=O HLUAPIYZVLAARK-UHFFFAOYSA-N 0.000 description 1
- RELMFMZEBKVZJC-UHFFFAOYSA-N 1,2,3-trichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1Cl RELMFMZEBKVZJC-UHFFFAOYSA-N 0.000 description 1
- QCLAIJAGQWBGCN-UHFFFAOYSA-N 1,2-bis(nitromethyl)benzene Chemical group [O-][N+](=O)CC1=CC=CC=C1C[N+]([O-])=O QCLAIJAGQWBGCN-UHFFFAOYSA-N 0.000 description 1
- CMVQZRLQEOAYSW-UHFFFAOYSA-N 1,2-dichloro-3-nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC(Cl)=C1Cl CMVQZRLQEOAYSW-UHFFFAOYSA-N 0.000 description 1
- UXGRXJVMQSSUGS-UHFFFAOYSA-N 1,2-dinitroethane Chemical compound [O-][N+](=O)CC[N+]([O-])=O UXGRXJVMQSSUGS-UHFFFAOYSA-N 0.000 description 1
- XNKFCDGEFCOQOM-UHFFFAOYSA-N 1,2-dinitronaphthalene Chemical compound C1=CC=CC2=C([N+]([O-])=O)C([N+](=O)[O-])=CC=C21 XNKFCDGEFCOQOM-UHFFFAOYSA-N 0.000 description 1
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 1
- WDCYWAQPCXBPJA-UHFFFAOYSA-N 1,3-dinitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC([N+]([O-])=O)=C1 WDCYWAQPCXBPJA-UHFFFAOYSA-N 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- ZUTCJXFCHHDFJS-UHFFFAOYSA-N 1,5-dinitronaphthalene Chemical compound C1=CC=C2C([N+](=O)[O-])=CC=CC2=C1[N+]([O-])=O ZUTCJXFCHHDFJS-UHFFFAOYSA-N 0.000 description 1
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 1
- MLRVZFYXUZQSRU-UHFFFAOYSA-N 1-chlorohexane Chemical compound CCCCCCCl MLRVZFYXUZQSRU-UHFFFAOYSA-N 0.000 description 1
- JTPNRXUCIXHOKM-UHFFFAOYSA-N 1-chloronaphthalene Chemical compound C1=CC=C2C(Cl)=CC=CC2=C1 JTPNRXUCIXHOKM-UHFFFAOYSA-N 0.000 description 1
- JOLQKTGDSGKSKJ-UHFFFAOYSA-N 1-ethoxypropan-2-ol Chemical compound CCOCC(C)O JOLQKTGDSGKSKJ-UHFFFAOYSA-N 0.000 description 1
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 1
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical class C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 1
- RUFPHBVGCFYCNW-UHFFFAOYSA-N 1-naphthylamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1 RUFPHBVGCFYCNW-UHFFFAOYSA-N 0.000 description 1
- BKCTVUNGRBZYRR-UHFFFAOYSA-N 1-nitro-1-[(1-nitrocyclohexyl)methyl]cyclohexane Chemical compound C1CCCCC1([N+]([O-])=O)CC1([N+](=O)[O-])CCCCC1 BKCTVUNGRBZYRR-UHFFFAOYSA-N 0.000 description 1
- CGLMICLDWFELRK-UHFFFAOYSA-N 1-nitro-2-[(4-nitrophenyl)methyl]benzene Chemical compound C1=CC([N+](=O)[O-])=CC=C1CC1=CC=CC=C1[N+]([O-])=O CGLMICLDWFELRK-UHFFFAOYSA-N 0.000 description 1
- NALZTFARIYUCBY-UHFFFAOYSA-N 1-nitrobutane Chemical compound CCCC[N+]([O-])=O NALZTFARIYUCBY-UHFFFAOYSA-N 0.000 description 1
- GOLOHAZKJYGKKQ-UHFFFAOYSA-N 1-nitrodecane Chemical compound CCCCCCCCCC[N+]([O-])=O GOLOHAZKJYGKKQ-UHFFFAOYSA-N 0.000 description 1
- FEYJIFXFOHFGCC-UHFFFAOYSA-N 1-nitrohexane Chemical compound CCCCCC[N+]([O-])=O FEYJIFXFOHFGCC-UHFFFAOYSA-N 0.000 description 1
- RJKGJBPXVHTNJL-UHFFFAOYSA-N 1-nitronaphthalene Chemical compound C1=CC=C2C([N+](=O)[O-])=CC=CC2=C1 RJKGJBPXVHTNJL-UHFFFAOYSA-N 0.000 description 1
- BVALZCVRLDMXOQ-UHFFFAOYSA-N 1-nitropentane Chemical compound CCCCC[N+]([O-])=O BVALZCVRLDMXOQ-UHFFFAOYSA-N 0.000 description 1
- JSZOAYXJRCEYSX-UHFFFAOYSA-N 1-nitropropane Chemical compound CCC[N+]([O-])=O JSZOAYXJRCEYSX-UHFFFAOYSA-N 0.000 description 1
- DHPRWWYQIUXCQM-UHFFFAOYSA-N 2,2-dinitropropane Chemical compound [O-][N+](=O)C(C)(C)[N+]([O-])=O DHPRWWYQIUXCQM-UHFFFAOYSA-N 0.000 description 1
- RUPDGJAVWKTTJW-UHFFFAOYSA-N 2,3-dinitropyridine Chemical compound [O-][N+](=O)C1=CC=CN=C1[N+]([O-])=O RUPDGJAVWKTTJW-UHFFFAOYSA-N 0.000 description 1
- DYSXLQBUUOPLBB-UHFFFAOYSA-N 2,3-dinitrotoluene Chemical compound CC1=CC=CC([N+]([O-])=O)=C1[N+]([O-])=O DYSXLQBUUOPLBB-UHFFFAOYSA-N 0.000 description 1
- WKFQMDFSDQFAIC-UHFFFAOYSA-N 2,4-dimethylthiolane 1,1-dioxide Chemical compound CC1CC(C)S(=O)(=O)C1 WKFQMDFSDQFAIC-UHFFFAOYSA-N 0.000 description 1
- RLYCRLGLCUXUPO-UHFFFAOYSA-N 2,6-diaminotoluene Chemical compound CC1=C(N)C=CC=C1N RLYCRLGLCUXUPO-UHFFFAOYSA-N 0.000 description 1
- XTRDKALNCIHHNI-UHFFFAOYSA-N 2,6-dinitrotoluene Chemical compound CC1=C([N+]([O-])=O)C=CC=C1[N+]([O-])=O XTRDKALNCIHHNI-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- UTNMPUFESIRPQP-UHFFFAOYSA-N 2-[(4-aminophenyl)methyl]aniline Chemical compound C1=CC(N)=CC=C1CC1=CC=CC=C1N UTNMPUFESIRPQP-UHFFFAOYSA-N 0.000 description 1
- WFSMVVDJSNMRAR-UHFFFAOYSA-N 2-[2-(2-ethoxyethoxy)ethoxy]ethanol Chemical compound CCOCCOCCOCCO WFSMVVDJSNMRAR-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- PPDFQRAASCRJAH-UHFFFAOYSA-N 2-methylthiolane 1,1-dioxide Chemical compound CC1CCCS1(=O)=O PPDFQRAASCRJAH-UHFFFAOYSA-N 0.000 description 1
- HLTDBMHJSBSAOM-UHFFFAOYSA-N 2-nitropyridine Chemical compound [O-][N+](=O)C1=CC=CC=N1 HLTDBMHJSBSAOM-UHFFFAOYSA-N 0.000 description 1
- PLAZTCDQAHEYBI-UHFFFAOYSA-N 2-nitrotoluene Chemical compound CC1=CC=CC=C1[N+]([O-])=O PLAZTCDQAHEYBI-UHFFFAOYSA-N 0.000 description 1
- IICDIWXEZHHCEN-UHFFFAOYSA-N 3,3-dinitropentane Chemical compound CCC(CC)([N+]([O-])=O)[N+]([O-])=O IICDIWXEZHHCEN-UHFFFAOYSA-N 0.000 description 1
- JHUUPUMBZGWODW-UHFFFAOYSA-N 3,6-dihydro-1,2-dioxine Chemical compound C1OOCC=C1 JHUUPUMBZGWODW-UHFFFAOYSA-N 0.000 description 1
- ZXVONLUNISGICL-UHFFFAOYSA-N 4,6-dinitro-o-cresol Chemical group CC1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O ZXVONLUNISGICL-UHFFFAOYSA-N 0.000 description 1
- ZPTVNYMJQHSSEA-UHFFFAOYSA-N 4-nitrotoluene Chemical compound CC1=CC=C([N+]([O-])=O)C=C1 ZPTVNYMJQHSSEA-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- KSSJBGNOJJETTC-UHFFFAOYSA-N COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC Chemical compound COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC KSSJBGNOJJETTC-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical class OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 101100030361 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) pph-3 gene Proteins 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229910001252 Pd alloy Inorganic materials 0.000 description 1
- 229910021069 PdâCo Inorganic materials 0.000 description 1
- 229910021065 PdâFe Inorganic materials 0.000 description 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 1
- 229910000629 Rh alloy Inorganic materials 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000003927 aminopyridines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- RBFQJDQYXXHULB-UHFFFAOYSA-N arsane Chemical class [AsH3] RBFQJDQYXXHULB-UHFFFAOYSA-N 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 150000001495 arsenic compounds Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- KAMGOKSXKBHPHL-UHFFFAOYSA-N benzene-1,2,3,4-tetramine Chemical compound NC1=CC=C(N)C(N)=C1N KAMGOKSXKBHPHL-UHFFFAOYSA-N 0.000 description 1
- RUOKPLVTMFHRJE-UHFFFAOYSA-N benzene-1,2,3-triamine Chemical compound NC1=CC=CC(N)=C1N RUOKPLVTMFHRJE-UHFFFAOYSA-N 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- 229940106691 bisphenol a Drugs 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical class OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Chemical class 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- PCZGZQPGIPQNDK-UHFFFAOYSA-N bromo(tetramethyl)-lambda5-arsane Chemical compound C[As](C)(C)(C)Br PCZGZQPGIPQNDK-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000007810 chemical reaction solvent Substances 0.000 description 1
- 238000006757 chemical reactions by type Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
- QCRFMSUKWRQZEM-UHFFFAOYSA-N cycloheptanol Chemical compound OC1CCCCCC1 QCRFMSUKWRQZEM-UHFFFAOYSA-N 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 description 1
- 229940117389 dichlorobenzene Drugs 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- KXTODIWODVFMGH-UHFFFAOYSA-M diethyl(methyl)sulfanium;bromide Chemical compound [Br-].CC[S+](C)CC KXTODIWODVFMGH-UHFFFAOYSA-M 0.000 description 1
- FCBBAKYJDIFLLL-UHFFFAOYSA-M diethyl(methyl)sulfanium;iodide Chemical compound [I-].CC[S+](C)CC FCBBAKYJDIFLLL-UHFFFAOYSA-M 0.000 description 1
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 1
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 1
- FSBVERYRVPGNGG-UHFFFAOYSA-N dimagnesium dioxido-bis[[oxido(oxo)silyl]oxy]silane hydrate Chemical compound O.[Mg+2].[Mg+2].[O-][Si](=O)O[Si]([O-])([O-])O[Si]([O-])=O FSBVERYRVPGNGG-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- ZGSBKNYSPZRUIW-UHFFFAOYSA-M dimethyl(phenyl)sulfanium;bromide Chemical compound [Br-].C[S+](C)C1=CC=CC=C1 ZGSBKNYSPZRUIW-UHFFFAOYSA-M 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- VYSYZMNJHYOXGN-UHFFFAOYSA-N ethyl n-aminocarbamate Chemical compound CCOC(=O)NN VYSYZMNJHYOXGN-UHFFFAOYSA-N 0.000 description 1
- ZXFWRDUUBDVSMJ-UHFFFAOYSA-M ethyl(trimethyl)phosphanium;bromide Chemical compound [Br-].CC[P+](C)(C)C ZXFWRDUUBDVSMJ-UHFFFAOYSA-M 0.000 description 1
- NCHUDIWSIORHHB-UHFFFAOYSA-M ethyl(trimethyl)phosphanium;chloride Chemical compound [Cl-].CC[P+](C)(C)C NCHUDIWSIORHHB-UHFFFAOYSA-M 0.000 description 1
- YPNLZDRHOPRKDR-UHFFFAOYSA-M ethyl(trimethyl)phosphanium;iodide Chemical compound [I-].CC[P+](C)(C)C YPNLZDRHOPRKDR-UHFFFAOYSA-M 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 150000004675 formic acid derivatives Chemical class 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 description 1
- TZMQHOJDDMFGQX-UHFFFAOYSA-N hexane-1,1,1-triol Chemical compound CCCCCC(O)(O)O TZMQHOJDDMFGQX-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical class I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical class O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
- YPLPZEKZDGQOOQ-UHFFFAOYSA-M iron oxychloride Chemical compound [O][Fe]Cl YPLPZEKZDGQOOQ-UHFFFAOYSA-M 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- AUHZEENZYGFFBQ-UHFFFAOYSA-N mesitylene Substances CC1=CC(C)=CC(C)=C1 AUHZEENZYGFFBQ-UHFFFAOYSA-N 0.000 description 1
- 125000001827 mesitylenyl group Chemical group [H]C1=C(C(*)=C(C([H])=C1C([H])([H])[H])C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- LIRNEANXNQTOCP-UHFFFAOYSA-N methyl n-(3-amino-4-methylphenyl)carbamate Chemical compound COC(=O)NC1=CC=C(C)C(N)=C1 LIRNEANXNQTOCP-UHFFFAOYSA-N 0.000 description 1
- HAEHENMGEBQTGO-UHFFFAOYSA-N methyl n-(5-amino-2-methylphenyl)carbamate Chemical compound COC(=O)NC1=CC(N)=CC=C1C HAEHENMGEBQTGO-UHFFFAOYSA-N 0.000 description 1
- IAGUPODHENSJEZ-UHFFFAOYSA-N methyl n-phenylcarbamate Chemical compound COC(=O)NC1=CC=CC=C1 IAGUPODHENSJEZ-UHFFFAOYSA-N 0.000 description 1
- INYLUNGIXBNRCW-UHFFFAOYSA-M methyl(diphenyl)sulfanium;iodide Chemical compound [I-].C=1C=CC=CC=1[S+](C)C1=CC=CC=C1 INYLUNGIXBNRCW-UHFFFAOYSA-M 0.000 description 1
- DZNSDJOECKUZDH-UHFFFAOYSA-M methyl(triphenyl)arsanium;bromide Chemical compound [Br-].C=1C=CC=CC=1[As+](C=1C=CC=CC=1)(C)C1=CC=CC=C1 DZNSDJOECKUZDH-UHFFFAOYSA-M 0.000 description 1
- GHLKOMSNOFJXDT-UHFFFAOYSA-M methyl(triphenyl)arsanium;iodide Chemical compound [I-].C=1C=CC=CC=1[As+](C=1C=CC=CC=1)(C)C1=CC=CC=C1 GHLKOMSNOFJXDT-UHFFFAOYSA-M 0.000 description 1
- LSEFCHWGJNHZNT-UHFFFAOYSA-M methyl(triphenyl)phosphanium;bromide Chemical compound [Br-].C=1C=CC=CC=1[P+](C=1C=CC=CC=1)(C)C1=CC=CC=C1 LSEFCHWGJNHZNT-UHFFFAOYSA-M 0.000 description 1
- UNFUYWDGSFDHCW-UHFFFAOYSA-N monochlorocyclohexane Chemical compound ClC1CCCCC1 UNFUYWDGSFDHCW-UHFFFAOYSA-N 0.000 description 1
- PYLWMHQQBFSUBP-UHFFFAOYSA-N monofluorobenzene Chemical compound FC1=CC=CC=C1 PYLWMHQQBFSUBP-UHFFFAOYSA-N 0.000 description 1
- DADSZOFTIIETSV-UHFFFAOYSA-N n,n-dichloroaniline Chemical compound ClN(Cl)C1=CC=CC=C1 DADSZOFTIIETSV-UHFFFAOYSA-N 0.000 description 1
- KUDPGZONDFORKU-UHFFFAOYSA-N n-chloroaniline Chemical compound ClNC1=CC=CC=C1 KUDPGZONDFORKU-UHFFFAOYSA-N 0.000 description 1
- VBEGHXKAFSLLGE-UHFFFAOYSA-N n-phenylnitramide Chemical compound [O-][N+](=O)NC1=CC=CC=C1 VBEGHXKAFSLLGE-UHFFFAOYSA-N 0.000 description 1
- NTNWKDHZTDQSST-UHFFFAOYSA-N naphthalene-1,2-diamine Chemical compound C1=CC=CC2=C(N)C(N)=CC=C21 NTNWKDHZTDQSST-UHFFFAOYSA-N 0.000 description 1
- KQSABULTKYLFEV-UHFFFAOYSA-N naphthalene-1,5-diamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1N KQSABULTKYLFEV-UHFFFAOYSA-N 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- IPVBXZMWDWJWHR-UHFFFAOYSA-N nitrocyclobutane Chemical compound [O-][N+](=O)C1CCC1 IPVBXZMWDWJWHR-UHFFFAOYSA-N 0.000 description 1
- NJNQUTDUIPVROZ-UHFFFAOYSA-N nitrocyclohexane Chemical compound [O-][N+](=O)C1CCCCC1 NJNQUTDUIPVROZ-UHFFFAOYSA-N 0.000 description 1
- CJSZWOGCKKDSJG-UHFFFAOYSA-N nitrocyclopentane Chemical compound [O-][N+](=O)C1CCCC1 CJSZWOGCKKDSJG-UHFFFAOYSA-N 0.000 description 1
- MCSAJNNLRCFZED-UHFFFAOYSA-N nitroethane Chemical compound CC[N+]([O-])=O MCSAJNNLRCFZED-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical class [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 1
- RNVCVTLRINQCPJ-UHFFFAOYSA-N o-toluidine Chemical compound CC1=CC=CC=C1N RNVCVTLRINQCPJ-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000013110 organic ligand Substances 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 150000003891 oxalate salts Chemical class 0.000 description 1
- PZKNFJIOIKQCPA-UHFFFAOYSA-N oxalic acid palladium Chemical compound [Pd].OC(=O)C(O)=O PZKNFJIOIKQCPA-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 1
- RZXMPPFPUUCRFN-UHFFFAOYSA-N p-toluidine Chemical compound CC1=CC=C(N)C=C1 RZXMPPFPUUCRFN-UHFFFAOYSA-N 0.000 description 1
- JKDRQYIYVJVOPF-FDGPNNRMSA-L palladium(ii) acetylacetonate Chemical compound [Pd+2].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O JKDRQYIYVJVOPF-FDGPNNRMSA-L 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- APXBXAJWVZTKSE-UHFFFAOYSA-N pyridine-2,3,4-triamine Chemical compound NC1=CC=NC(N)=C1N APXBXAJWVZTKSE-UHFFFAOYSA-N 0.000 description 1
- ZZYXNRREDYWPLN-UHFFFAOYSA-N pyridine-2,3-diamine Chemical compound NC1=CC=CN=C1N ZZYXNRREDYWPLN-UHFFFAOYSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000002468 redox effect Effects 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical class O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- OUULRIDHGPHMNQ-UHFFFAOYSA-N stibane Chemical class [SbH3] OUULRIDHGPHMNQ-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 150000004772 tellurides Chemical class 0.000 description 1
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 1
- LAJZODKXOMJMPK-UHFFFAOYSA-N tellurium dioxide Chemical compound O=[Te]=O LAJZODKXOMJMPK-UHFFFAOYSA-N 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- WHOVMGYAGDQXSZ-UHFFFAOYSA-M tetraethylarsanium;bromide Chemical compound [Br-].CC[As+](CC)(CC)CC WHOVMGYAGDQXSZ-UHFFFAOYSA-M 0.000 description 1
- YEFZWQZXZVQKSS-UHFFFAOYSA-M tetraethylarsanium;iodide Chemical compound [I-].CC[As+](CC)(CC)CC YEFZWQZXZVQKSS-UHFFFAOYSA-M 0.000 description 1
- LIXPXSXEKKHIRR-UHFFFAOYSA-M tetraethylphosphanium;bromide Chemical compound [Br-].CC[P+](CC)(CC)CC LIXPXSXEKKHIRR-UHFFFAOYSA-M 0.000 description 1
- FBOJNMRAZJRCNS-UHFFFAOYSA-M tetraethylphosphanium;chloride Chemical compound [Cl-].CC[P+](CC)(CC)CC FBOJNMRAZJRCNS-UHFFFAOYSA-M 0.000 description 1
- WKSYTZHMRBAPAO-UHFFFAOYSA-M tetraethylphosphanium;iodide Chemical compound [I-].CC[P+](CC)(CC)CC WKSYTZHMRBAPAO-UHFFFAOYSA-M 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- KEFJVVFCFZNVQM-UHFFFAOYSA-M tetramethylarsanium;iodide Chemical compound [I-].C[As+](C)(C)C KEFJVVFCFZNVQM-UHFFFAOYSA-M 0.000 description 1
- ZTXFOCMYRCGSMU-UHFFFAOYSA-M tetramethylphosphanium;bromide Chemical compound [Br-].C[P+](C)(C)C ZTXFOCMYRCGSMU-UHFFFAOYSA-M 0.000 description 1
- NJFUXFRJVIXVSG-UHFFFAOYSA-M tetramethylphosphanium;chloride Chemical compound [Cl-].C[P+](C)(C)C NJFUXFRJVIXVSG-UHFFFAOYSA-M 0.000 description 1
- TVVPMLFGPYQGTG-UHFFFAOYSA-M tetramethylphosphanium;iodide Chemical compound [I-].C[P+](C)(C)C TVVPMLFGPYQGTG-UHFFFAOYSA-M 0.000 description 1
- NZUQEBQRKNZZDO-UHFFFAOYSA-M tetraphenylarsanium;bromide Chemical compound [Br-].C1=CC=CC=C1[As+](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 NZUQEBQRKNZZDO-UHFFFAOYSA-M 0.000 description 1
- NTIVEBOPRSMRSY-UHFFFAOYSA-M tetraphenylarsanium;iodide Chemical compound [I-].C1=CC=CC=C1[As+](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 NTIVEBOPRSMRSY-UHFFFAOYSA-M 0.000 description 1
- BRKFQVAOMSWFDU-UHFFFAOYSA-M tetraphenylphosphanium;bromide Chemical compound [Br-].C1=CC=CC=C1[P+](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 BRKFQVAOMSWFDU-UHFFFAOYSA-M 0.000 description 1
- WAGFXJQAIZNSEQ-UHFFFAOYSA-M tetraphenylphosphonium chloride Chemical compound [Cl-].C1=CC=CC=C1[P+](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 WAGFXJQAIZNSEQ-UHFFFAOYSA-M 0.000 description 1
- BXUBVWQDEZEPIY-UHFFFAOYSA-M thiopyrylium;iodide Chemical compound [I-].C1=CC=[S+]C=C1 BXUBVWQDEZEPIY-UHFFFAOYSA-M 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229940087291 tridecyl alcohol Drugs 0.000 description 1
- JLGLQAWTXXGVEM-UHFFFAOYSA-N triethylene glycol monomethyl ether Chemical compound COCCOCCOCCO JLGLQAWTXXGVEM-UHFFFAOYSA-N 0.000 description 1
- ANUSMYJRISPAKG-UHFFFAOYSA-M triethylsulfanium;bromide Chemical compound [Br-].CC[S+](CC)CC ANUSMYJRISPAKG-UHFFFAOYSA-M 0.000 description 1
- LKDQWVKWYGOVJW-UHFFFAOYSA-M triethylsulfanium;iodide Chemical compound [I-].CC[S+](CC)CC LKDQWVKWYGOVJW-UHFFFAOYSA-M 0.000 description 1
- GOTIICCWNAPLMN-UHFFFAOYSA-M trimethylsulfanium;bromide Chemical compound [Br-].C[S+](C)C GOTIICCWNAPLMN-UHFFFAOYSA-M 0.000 description 1
- OWUGVJBQKGQQKJ-UHFFFAOYSA-M trimethylsulfanium;chloride Chemical compound [Cl-].C[S+](C)C OWUGVJBQKGQQKJ-UHFFFAOYSA-M 0.000 description 1
- VFJYIHQDILEQNR-UHFFFAOYSA-M trimethylsulfanium;iodide Chemical compound [I-].C[S+](C)C VFJYIHQDILEQNR-UHFFFAOYSA-M 0.000 description 1
- VMJFYMAHEGJHFH-UHFFFAOYSA-M triphenylsulfanium;bromide Chemical compound [Br-].C1=CC=CC=C1[S+](C=1C=CC=CC=1)C1=CC=CC=C1 VMJFYMAHEGJHFH-UHFFFAOYSA-M 0.000 description 1
- CVJLQNNJZBCTLI-UHFFFAOYSA-M triphenylsulfanium;iodide Chemical compound [I-].C1=CC=CC=C1[S+](C=1C=CC=CC=1)C1=CC=CC=C1 CVJLQNNJZBCTLI-UHFFFAOYSA-M 0.000 description 1
- 229940057402 undecyl alcohol Drugs 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical class O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Catalysts (AREA)
Description
æ¬çºæã¯è³éŠæãŠã¬ã¿ã³ã®è£œé æ¹æ³ã«é¢ããã
ããã«è©³ããã¯é žåå€ã®ååšäžã«è³éŠæã¢ããå
åç©ãäžé žåççŽ åã³ææ©ããããã·ã«ååç©ãš
åå¿ãããŠé žåçã«ã«ã«ããã«åããããšã«ãã€
ãŠè³éŠæãŠã¬ã¿ã³ã補é ããæ¹æ³ã«é¢ããã è³éŠæãŠã¬ã¿ã³é¡ã¯ã«ãŒãã¡ã€ã系蟲è¬ãªã©ã«
çšããããéèŠãªååç©ã§ãããæè¿ã§ã¯ãã¹ã²
ã³ã䜿çšããªãè³éŠæã€ãœã·ã¢ããŒãé¡è£œé ã®å
æãšããŠããã®å®äŸ¡ãªè£œé æ¹æ³ãèŠæãããŠã
ãã åŸæ¥ãäžé žåççŽ ãçšããè³éŠæãŠã¬ã¿ã³åå
ç©ã®è£œæ³ãšããŠãäž»ã«ïŒæ¹æ³ãææ¡ãããŠããã
ããªãã¡ãïŒã€ã®æ¹æ³ã¯ã¢ã«ã³ãŒã«é¡ã®ååšäžã
è³éŠæãããååç©ãéå çã«ãŠã¬ã¿ã³åããæ¹
æ³ã§ãããäŸãã°ããããã³ãŒã³ã®å Žåã¯æ¬¡ã®ã
ããªåŒã§è¡šããããã ããããªãããã®åå¿ã«ãããŠã¯ãããããã³
ãŒã³ïŒã¢ã«åœããäžé žåççŽ ã¯ïŒã¢ã«å¿ èŠã§ã
ãããã®ãã¡ã®ïŒã¢ã«ã®äžé žåççŽ ã¯ç¡äŸ¡å€ãªäº
é žåççŽ ã«ãªãã®ã§ãäžé žåççŽ ã¯äœ¿çšéã®1/3
ããæå¹ã«å©çšãããªããšããæ¬ ç¹ãããããã
ããã®åå¿ãé£ç¶çã«è¡ãã«ã¯ãäžé žåççŽ ãšäº
é žåççŽ ãšã®æ··åã¬ã¹ããäºé žåççŽ ãåé¢ãã
ã°ãªããããã®ããšãå·¥æ¥çã«å®æœããäžã«ãã
ãŠæ¬ ç¹ãšãªã€ãŠããã ä»ã®ïŒã€ã®æ¹æ³ãšããŠé žçŽ åã¯ææ©ãããåå
ç©ãªã©ã®é žåå€ã®ååšäžãè³éŠæã¢ããååç©ã«
äžé žåççŽ åã³ã¢ã«ã³ãŒã«ãåå¿ãããé žåçã«
ãŠã¬ã¿ã³åããæ¹æ³ãæè¿ææ¡ãããŠããããã®
æ¹æ³ã¯ãåèšã®æ¹æ³ã«æ¯ã¹ãŠäžé žåççŽ ã¯æå¹ã«
å©çšãããŠããããã奜ãŸããæ¹æ³ãšããããã
å©è§ŠåªãšããŠå¡©åé ãå¡©åéããªãã·å¡©åéãå¡©
åãããžãŠã ããªãã·å¡©åãããžãŠã ãªã©ã®ãã«
ã€ã¹é žã§ãã€ãŠããããåå¿ç³»ã«ãããŠã¬ããã¯
ã¹åå¿ãè¡ãªãããšã®ã§ããå çŽ ã®å¡©åç©ãåå¿
ç³»äžã«æº¶è§£ãããŠããå¿ èŠãããïŒç¹éæ55â
120551å·å ¬å ±ãç¹éæ55â124750å·å ¬å ±ïŒããã
ããªãã溶解ãããããã®å¡©åç©ã¯åå¿å®¹åšãé
管ããã«ããªã©ã®éå±ææã«å¯Ÿããè é£æ§ã倧ã
ãããã®ããé«äŸ¡ãªéå±ææã䜿çšããªããã°ãª
ããªããšããèšåäžã®åé¡ããããããã«æº¶è§£ã
ããããã®å¡©åç©ãè³éŠæãŠã¬ã¿ã³ãããã¯åå¿
å¯çç©ã§ãããžã¢ãªãŒã«å°¿çŽ ã®ãããªé«æ²žç¹çæ
ç©ããåé¢ã»ååããããã«ã¯ãã¯ãéãªæäœãš
å€å€§ã®è²»çšãèŠãããšããæ¬ ç¹ãããã°ããã§ãª
ãããããã®å©è§Šåªã¯ã¬ããã¯ã¹åå¿ã«ãã€ãŠé
å ãããç¶æ ã®æã«çæããå¡©åæ°ŽçŽ ãæªåå¿ã®
ã¢ããªã³ã®å¡©é žå¡©ãšãªããããåå¿ç³»ã§ã®åé žå
ã«ãã€ãŠãå ã®å¡©åç©ã«ã¯å®å šã«æ»ãããååã
ããæã«ã¯éšåçã«éå ããããã®ãååšããå
å¿ãç¹°ãè¿ãå Žåã«ã¯ããããã®å©è§Šåªãå調補
ããªããã°ãªããªããšããæ¬ ç¹ããã€ãã æ¬çºæè ãã¯ããããã®æ¬ ç¹ãå æãã¹ããè³
éŠæã¢ããååç©ãé žåçã«ãŠã¬ã¿ã³åããŠè³éŠ
æãŠã¬ã¿ã³ååç©ã補é ããæ¹æ³ã«ã€ããŠéæç
究ãéããçµæããããã®æ¬ ç¹ã®äž»èŠåå ãšãªã€
ãŠããã«ã€ã¹é žãã¬ããã¯ã¹åå¿ãè¡ãªãå çŽ ã®
å¡©åç©ãçšããªãã§æ¥è§Šçã«åå¿ãé²è¡ããåŸã
å šãæ°ãã觊åªç³»ãèŠåºãããã®ç¥èŠã«åºã¥ããŠ
æ¬çºæãå®æããã«å°ã€ãã ããªãã¡ãæ¬çºæã¯é žåå€ã®ååšäžã«è³éŠæã¢
ããååç©ãäžé žåççŽ åã³ææ©ããããã·ã«å
åç©ãšåå¿ãããŠè³éŠæãŠã¬ã¿ã³ã補é ããæ¹æ³
ã«ãããŠã çœéæéå±ããã³çœéæå çŽ ãå«ãååç©ã®
äžããéžã°ããå°ããšãïŒçš®ããš é°ã€ãªã³ãããã²ã³ã§ãããªããŠã ååç©
ïŒäœããã¢ã³ã¢ããŠã ååç©ã¯é€ãïŒããã³å
å¿ç³»ã§ããããçæããããšã®ã§ããååç©ã®
äžããéžã°ããå°ããšãïŒçš® ãšããæã觊åªç³»ãçšããããšãç¹åŸŽãšããè³éŠ
æãŠã¬ã¿ã³ã®è£œé æ¹æ³ãæäŸããããšã«ããã ãã®ããã«æ¬çºæã®å€§ããªç¹åŸŽã¯çœéæéå±ã
ãã³çœéæå çŽ ãå«ãååç©ã®äžããéžã°ããå°
ããšãïŒçš®ãšé°ã€ãªã³ãããã²ã³ã§ãããªããŠã
ååç©ã®äžããéžã°ããå°ããšãïŒçš®ãšãçµåã
ãã觊åªç³»ãçšããããšã«ãã€ãŠè³éŠæã¢ããå
åç©ããéžææ§ããããŸãé«åçã§è³éŠæãŠã¬ã¿
ã³ãåŸãããããšã«ããã ãããã®äºå®ã¯ä»ãŸã§å šãç¥ãããŠããªãã€ã
å®ã«é©ãã¹ãããšã§ãã€ãŠåè¿°ã®å è¡æè¡ïŒç¹é
æ55â120551å·å ¬å ±ãç¹éæ55â124750å·å ¬å ±ïŒ
ãããå šãäºæ³ã§ããªãã€ãããšã§ãããããªã
ã¡ãå è¡æè¡ã«ãããŠã¯çœéæååç©ã䞻觊åªãš
ããåå¿ç³»ã«ãããŠã¬ããã¯ã¹åå¿ãè¡ãªãããš
ã®ã§ããå çŽ ã®å¡©åç©ãå©è§Šåªãšãã觊åªç³»ãçš
ããŠãããå®æœäŸã«èŠããã代衚çãªè§Šåªç³»ã¯å¡©
åãã©ãžãŠã ã«å¡©å第ïŒéãçµåããããã®ã§ã
ãããã®ãããªç³»ã«ãããŠã¯ïŒäŸ¡ã®ãã©ãžãŠã ã
åå¿ã«é¢äžããŠããåå¿ã®é²è¡ãšãšãã«éå ãã
ãŠïŒäŸ¡ã®ãã©ãžãŠã ã«ãªãããããå¡©å第ïŒéã«
ãã€ãŠåé žåãããŠïŒäŸ¡ã®ãã©ãžãŠã ã«æ»ããšå
æã«å¡©å第ïŒéã¯éå ãããŠå¡©å第ïŒéãšãªãã
ããã«ãã®å¡©å第ïŒéãé žåå€ã«ãã€ãŠåé žåã
ããŠå¡©å第ïŒéã«æ»ããããããã¯ãã«ãŒåå¿å
ã®è§Šåªãµã€ã¯ã«ã«ãã€ãŠäž»çæç©ã§ããè³éŠæãŠ
ã¬ã¿ã³ãäžããŠãããã®ãšèããããã ãã®ããã«å è¡æè¡ã®æ¹æ³ã§ã¯åå¿ç³»ã«ãããŠ
ã¬ããã¯ã¹äœçšãæããå çŽ ã®å¡©åç©ã䞻觊åªã®
åé žåå€ãšããŠå¿ é ã§ããããšã瀺ãããŠããã
ãã®ãããªæ©èœãæããå çŽ ãšããŠã¯åšæè¡šã®
ïœïœæããã³ïœãïœæã®å çŽ ã®äžããéžã°
ããã¬ããã¯ã¹åå¿ãåããããšã®ã§ãããã®ã§
ãã€ãŠå ·äœçã«ã¯ãé ãäºéãæ°Žéãã¿ãªãŠã ã
ã¹ãºããã¿ã³ããçŽ ãã¢ã³ãã¢ã³ããã¹ãã¹ãã
ããžãŠã ãã¯ãã ãã¢ãªããã³ãã¿ã³ã°ã¹ãã³ã
ãã³ã¬ã³ãéãã³ãã«ããããã±ã«ãæããããŠ
ããããã®äžã§ãé ããããžãŠã ããã³ã¬ã³ãé
ã®ã¿ãå®æœäŸã«èšèŒãããŠããã«éããªãã ããã«åããŠæ¬çºæã®æ¹æ³ã¯ãé°ã€ãªã³ããã
ã²ã³ã§ãããªããŠã ååç©ãŸãã¯ããããåå¿ç³»
ã§çæããããšã®ã§ããååç©ãçšãããã®ã§ã
ã€ãŠããããã®ååç©ã¯å šãéå±æåãå«ãã§ã
ãªããããããã¯éåžžã®åå¿æ¡ä»¶äžã§ã«ããªã³éš
ã¯ã¬ããã¯ã¹åå¿ãè¡ãªããªããã®ã§ããã åŸã€ãŠæ¬çºæã®åå¿ã¯å è¡æè¡ã«èšèŒãããŠã
ãåå¿ãšã¯å šãç°ãªãåå¿æ©æ§ã§é²è¡ããŠããã
ã®ãšæšå®ãããã ãã®ãããªé°ã€ãªã³ãããã²ã³ã§ãããªããŠã
ååç©ãæ¬çºæã®åå¿ã«ãããŠã©ã®ãããªæ©æ§ã§
äœçšããŠãããã¯äžæã§ããããçœéæéå±ãŸã
ã¯çœéæå çŽ ãå«ãååç©ãšçµã¿åãããå Žå
ã«ãè³éŠæã¢ããååç©ã®é žåçãŠã¬ã¿ã³ååå¿
ã®è§ŠåªæåãšããŠéèŠãªäœçšãããŠããããšã¯æ
ããã§ããã ããªãã¡ãé°ã€ãªã³ãããã²ã³ã§ãããªããŠã
ååç©ã®ã¿ã§ã¯æ¬åå¿ã®è³éŠæãŠã¬ã¿ã³ååå¿ã¯
å šãé²è¡ããªããããŸãçœéæéå±ãŸãã¯çœéæ
å çŽ ãå«ãååç©ã®ã¿ã§ãæ¬åå¿ã®æ¡ä»¶äžã§ã¯è³
éŠæãŠã¬ã¿ã³ååå¿ã¯æ®ãã©é²è¡ããªããããã
ãã¯é²è¡ããã«ããŠãå°éã®è³éŠæãŠã¬ã¿ã³ãäž
ããã«éããªããç¹ã«éå±ç¶æ ã®çœéæå çŽ ã®ã¿
ãçšããå Žåã¯è³éŠæãŠã¬ã¿ã³ã¯æ®ãã©åŸãããª
ããäŸãã°ããã©ãžãŠã ã¯æ¬åå¿ã«æå¹ãªè§Šåªæ
åã®ïŒã€ã§ããããïŒäŸ¡ã®éå±ãã©ãžãŠã ã§ãã
ãã©ãžãŠã é»ã®ã¿ã§ã¯æ¬åå¿ã¯å®è³ªçã«æ®ãã©é²
è¡ããªãããããã«é°ã€ãªã³ãããã²ã³ã§ãããª
ããŠã ååç©ãäŸãã°ãšãŠåã¡ãã«ããªããšãã«
ãã¹ãããŠã ãå ãããšãã»ãŒå®éçã«è³éŠæãŠ
ã¬ã¿ã³ãåŸãããããã«ãªãã ãã®ããã«æ¬çºæã®æ¹æ³ã§ã¯éå±ç¶æ ã®åºäœã®
çœéæååç©ãã觊åªæåã®ïŒã€ãšããŠçšããã
ãšãã§ããããã®ããšã¯é«äŸ¡ãªçœéæååç©ã®å
å¿ç³»ããã®åé¢ã»ååããéãªã©ã®ç°¡åãªæ¹æ³ã§
å®æœã§ããããšã瀺ããŠããã æ¬çºæã«ãããŠçšããããçœéæéå±ããã³çœ
éæå çŽ ãå«ãååç©ãšã¯ãæåãšããŠãã©ãžãŠ
ã ãããžãŠã ãçœéãã«ãããŠã ãã€ãªãžãŠã ã
ãªã¹ããŠã ãªã©ã®çœéæå çŽ ããéžã°ããå°ããš
ãïŒçš®ãå«ããã®ã§ãã€ãŠããããã®å çŽ ãéå±
ç¶æ ã«ãããã®ããŸãã¯ååç©ã圢æããæåãš
ãªã€ãŠãããã®ãè¡šããããŸãããããã®è§Šåªæ
åã¯æŽ»æ§çãã°ã©ãã¢ã€ããã·ãªã«ãã¢ã«ããã
ã·ãªã«âã¢ã«ãããã·ãªã«âãã¿ãã¢ããã¿ã
ã¢ããžã«ã³ãã¢ãç¡«é žããªãŠã ãçé žã«ã«ã·ãŠ
ã ãã¢ã¹ãã¹ãããã³ããã€ããã±ã€ãœãŠåãã
ãªããŒãã€ãªã³äº€ææš¹èããŒãªã©ã€ããã¢ã¬ããŠ
ã©ãŒã·ãŒããã±ã€é žãã°ãã·ãŠã ããã°ãã·ã¢ãª
ã©ã®æ äœã«æ æããããã®ã§ãã€ãŠãããã éå±ç¶æ ã®çœéæå çŽ ãšããŠãäŸãã°ãã©ãžãŠ
ã ãããžãŠã ãçœéãã«ãããŠã ãã€ãªãžãŠã å
ã³ãªã¹ããŠã ãªã©ã®éå±ããããã®éå±é»ããã
ãã®éå±ã€ãªã³ãå«ã觊åªæåãåèšã®ãããªæ
äœã«æ æããã®ã¡ãæ°ŽçŽ ãããã«ã ã¢ã«ãããã§
éå åŠçãããã®ãåã³ãããã®éå±ãå«ãåé
ãããã¯éå±éååç©ãªã©ãçšããããããŸãã
åéãããã¯éå±éååç©ã¯ãããã®çœéæéå±
å士ã®ãã®ã§ãã€ãŠãããããä»ã®å çŽ ãäŸãã°
ã»ã¬ã³ããã«ã«ãã€ãªãŠãã¢ã³ãã¢ã³ããã¹ã
ã¹ãé ãéãéãäºéãã¹ãºããããžãŠã ãéã
ã³ãã«ããããã±ã«ãæ°Žéãéãã¿ãªãŠã ãã¯ã
ã ãã¢ãªããã³ãã¿ã³ã°ã¹ãã³ãªã©ãå«ããã®ã§
ãã€ãŠãããã äžæ¹ãçœéæå çŽ ãå«ãååç©ãšããŠã¯ãäŸã
ã°ããã²ã³åç©ãç¡«é žå¡©ãç¡é žå¡©ããªã³é žå¡©ãã
ãŠé žå¡©ãªã©ã®ç¡æ©å¡©é¡ïŒé ¢é žå¡©ãã·ãŠãŠé žå¡©ãã®
é žå¡©ãªã©ã®ææ©é žå¡©é¡ïŒã·ã¢ã³åç©é¡ïŒæ°Žé žåç©
é¡ïŒé žåç©é¡ïŒç¡«åç©é¡ïŒãããåºãã·ã¢ãåºã
ããã²ã³ãã·ãŠãŠé žã€ãªã³ãªã©ã®ã¢ããªã³ãå«ã
éå±é žå¡©åã³ã¢ã³ã¢ãã¢ãã¢ãã³é¡ããã¹ãã€ã³
é¡ãäžé žåççŽ ããã¬ãŒãé äœåãªã©ãå«ãå¡©å
ã¯é¯äœãªã©ã®éå±ã®é¯ååç©é¡ïŒææ©é äœååã¯
ææ©åºãæããææ©éå±ååç©é¡ãªã©ããããã
ãã ãããã®è§Šåªæåã®äžã§ã¯ããã©ãžãŠã åã¯ã
ãžãŠã è¥ããã¯ãã®äž¡æ¹ãå«ããã®ãç¹ã«å¥œãŸã
ãããã®ãããªãã®ãšããŠã¯ãäŸãã°Pdé»ïŒPd
âãPdâAl2O3ãPdâSiO2ãPdâTiO2ãPdâ
ZrO2ãPdâBaSO4ãPdâCaCO3ãPdâã¢ã¹ãã¹
ããPdâãŒãªã©ã€ããPdâã¢ã¬ããŠã©ãŒã·ãŒã
ãªã©ã®æ æãã©ãžãŠã 觊åªé¡ïŒPdâPbãPdâ
SeãPdâTeãPdâHgãPdâTlãPdâãPdâ
CuãPdâAgãPdâFeãPdâCoãPdâNiãPdâ
Rhãªã©ã®åéåã¯éå±éååç©é¡ïŒåã³ããã
ã®åéåã¯éå±éååç©ãåèšã®ãããªæ æã«æ
æãããã®ïŒPdCl2ãPdBr2ãPdI2ãPd
ïŒNO3ïŒ2ãPdSO4ãªã©ã®ç¡æ©å¡©é¡ïŒPd
ïŒOCOCH3ïŒ2ãã·ãŠãŠé žãã©ãžãŠã ãªã©ã®ææ©é ž
å¡©é¡ïŒPdïŒCNïŒ2ïŒPdOïŒPdSïŒM2ãPdXâ²4ããM2
ãPdXâ²6ãã§è¡šãããããã©ãžãŠã é žå¡©é¡ïŒïŒã¯ã¢
ã«ã«ãªéå±åã¯ã¢ã³ã¢ããŠã ã€ãªã³ãè¡šããã
Xâ²ã¯ãããåºåã¯ã·ã¢ãåºåã¯ããã²ã³ãè¡šã
ããïŒïŒãPdïŒNH3ïŒ4ãXâ²2ããPdïŒenïŒ2ãXâ²2ãªã©
ã®ãã©ãžãŠã ã®ã¢ã³ãã³é¯äœé¡ïŒXâ²ã¯äžèšãšå
ãæå³ããã¡ãenã¯ãšãã¬ã³ãžã¢ãã³ãè¡šã
ãïŒïŒPdCl2ïŒPhCNïŒ2ãPdCl2ïŒPR3ïŒ2ãPd
ïŒCOïŒïŒPR3ïŒ3ãPdïŒPPh3ïŒ4ãPdClïŒïŒ²ïŒ
ïŒPPh3ïŒ2ãPdïŒC2H4ïŒïŒPPh3ïŒ2ãPdïŒC3H5ïŒ2ãªã©
ã®é¯ååç©åã¯ææ©éå±ååç©é¡ïŒïŒ²ã¯ææ©åºã
è¡šããïŒïŒPdïŒacacïŒ2ãªã©ã®ãã¬ãŒãé äœåã
é äœããé¯ååç©é¡ïŒRhé»ïŒPdãšåæ§ãªæ æã
ãžãŠã 觊åªé¡ïŒPdãšåæ§ãªRhåéåã¯éå±éå
åç©é¡åã³ããããæ äœã«æ æãããã®ïŒRhCl3
åã³æ°Žåç©ãRhBr3åã³æ°Žåç©ãRhI3åã³æ°Žå
ç©ãRh2ïŒSO4ïŒ3åã³æ°Žåç©ãªã©ã®ç¡æ©å¡©é¡ïŒRh2
ïŒOCOCH3ïŒ4ïŒRh2O3ãRhO2ïŒM3ãRhXâ²6ãåã³
æ°Žåç©ïŒïŒãXâ²ã¯åèšãšåãæå³ããã€ïŒïŒ
ãRhïŒNH3ïŒ5ãXâ²3ããRhïŒenïŒ3ãXâ²3ãªã©ã®ããž
ãŠã ã®ã¢ã³ãã³é¯äœé¡ïŒRh4ïŒCOïŒ12ãRh6
ïŒCOïŒ16ãªã©ã®ããžãŠã ã«ã«ããã«ã¯ã©ã¹ã¿ãŒ
é¡ïŒãRhClïŒCOïŒ2ã2ãRhCl3ïŒPR3ïŒ3ãRhCl
ïŒPPh3ïŒ3ãRhXâ²ïŒCOïŒL2ïŒXâ²ã¯åèšãšåãæå³
ããã¡ãã¯ææ©ãªã³ååç©åã³ææ©ãçŽ ååç©
ãããªãé äœåã§ããïŒãRhHïŒCOïŒïŒPPh3ïŒ3ãª
ã©ã®é¯ååç©åã¯ææ©éå±ååç©é¡ããããã
ãã ãããã®çœéæéå±ãŸãã¯çœéæå çŽ ãå«ãå
åç©ã¯ïŒçš®ã ãã§çšããããšãã§ããããããã
ã¯ïŒçš®ä»¥äžãæ··åããŠçšããããšãã§ããã ãŸãæ¬çºæã§çšãããããé°ã€ãªã³ãããã²ã³
ã§ãããªããŠã ååç©ïŒäœããã¢ã³ã¢ããŠã åå
ç©ã¯é€ãïŒãšã¯ãå€ç«é»å察ããã€å çŽ ãå«ãå
åç©ã«ãããŠããããã®å€ç«é»å察ã«ãããã³ã
ããã¯ä»ã®éœã€ãªã³åœ¢ã®è©Šè¬ãçµåããŠå€ç«é»å
察ããã€å çŽ ãå ±æçµååå䟡ïŒãå¢å ããŠéœã€
ãªã³ãšãªã€ãŠãããã®ã§ãã€ãŠã察ã€ãªã³ãšããŠ
ããã²ã³ã¢ããªã³ãæãããã®ã§ããã ãã®ãããªãªããŠã ååç©ãšããŠã¯ããã¹ãã
ãŠã ååç©ïŒãR1R2R3R4PãïŒãã¢ã«ãœããŠ
ã ååç©ïŒãR1R2R3R4AsãïŒãã¹ããããŠ
ã ååç©ïŒãR1R2R3R4SbããããªããœããŠ
ã ååç©ïŒãR1R2R3OãïŒãã¹ã«ãããŠã
ååç©ïŒãR1R2R3SãïŒããªãã·ã¹ã«ãããŠ
ã ååç©ïŒãR1R2R3SïŒïŒ¯ïŒãïŒãã»ã¬ãã
ãŠã ååç©ïŒãR1R2R3SeãïŒããã«ãããŠ
ã ååç©ïŒãR1R2R3TeãïŒãã¹ã¿ã³ãããŠ
ã ååç©ïŒãR1R2R3SnãïŒããšãŠãããŠã
ååç©ïŒãR1R2IãïŒãªã©ããããããã
ããã§R1ãR2ãR3ãR4ã¯æ°ŽçŽ ãŸãã¯èèªæåºã
è³éŠæåºãèç°æåºãè³éŠèèªæåºããéžã°ãã
åºãè¡šããããããããåãã§ãã€ãŠããããã
ãŸãå Žåã«ãã€ãŠã¯å€ç«é»å察ãæããå çŽ ãå«
ãç°ã®æ§æèŠçŽ ã§ãã€ãŠãããããŸãã¯ïŒŠã
ClãBrãããéžã°ããããã²ã³ãè¡šããã ãã®ãããªé°ã€ãªã³ãããã²ã³ã§ãããªããŠã
ååç©ã§ããããã²ã³åãªããŠã ååç©ã¯ããã
ã²ã³åæ°ŽçŽ ãŸãã¯ææ©ããã²ã³åç©ãšçžåœããã
ã¹ãã€ã³ååç©ãã¢ã«ã·ã³ååç©ãã¹ããã³åå
ç©ããªãã·ååç©ãã¹ã«ãã€ãååç©ãã¹ã«ãã
ã·ãååç©ãã»ã¬ããååç©ããã«ãªãååç©ãª
ã©ãšã®åå¿ã«ãã€ãŠå®¹æã«åŸããããã®ã§ããã
ãããã¯åå¿ç³»å€ã§è£œé ããããã®ãçšããŠãã
ãããåå¿ç³»å ã§ããããçæãããŠããããã
ã¡ããä»ã®æ¹æ³ã§è£œé ããããã®ã§ãã€ãŠããã
ããä»ã®æ¹æ³ã«ãã€ãŠåå¿ç³»å ã§çæããããã®
ã§ãã€ãŠãããã ãããã®äžã§å¥œãŸããã®ã¯ããã²ã³åãã¹ãã
ãŠã ååç©ãããã²ã³åã¢ã«ãœããŠã ååç©ãã
ã³ããã²ã³åã¹ã«ãããŠã ååç©ã§ãç¹ã«å¥œãŸã
ãã®ã¯ããã²ã³åãã¹ãããŠã ååç©ã§ããã ããã²ã³åãã¹ããŠã ååç©ãšããŠã¯äŸãã°å¡©
åããã©ã¡ãã«ãã¹ãããŠã ãèåããã©ã¡ãã«
ãã¹ãããŠã ããšãŠåããã©ã¡ãã«ãã¹ãããŠ
ã ãå¡©åããã©ãšãã«ãã¹ãããŠã ãèåããã©
ãšãã«ãã¹ãããŠã ããšãŠåããã©ãšãã«ãã¹ã
ããŠã çã®å¯Ÿç§°åœ¢ããã©ã¢ã«ãã«ãã¹ãããŠã å
åç©é¡ïŒå¡©åã¡ãã«ããªããšãã«ãã¹ãããŠã ã
èåã¡ãã«ããªããšãã«ãã¹ãããŠã ããšãŠåã¡
ãã«ããªããšãã«ãã¹ãããŠã çã®ã¢ã«ãã«ã¢ãª
ãŒã«æ··åãã¹ãããŠã ååç©é¡ïŒå¡©åããã©ããš
ãã«ãã¹ãããŠã ãèåããã©ããšãã«ãã¹ãã
ãŠã ããšãŠåããã©ããšãã«ãã¹ãããŠã çã®å¯Ÿ
称圢ããã©ã¢ãªãŒã«ãã¹ãããŠã ååç©é¡ïŒå¡©å
ãšãã«ããªã¡ãã«ãã¹ãããŠã ãèåãšãã«ããª
ã¡ãã«ãã¹ãããŠã ããšãŠåãšãã«ããªã¡ãã«ã
ã¹ãããŠã çã®é察称圢ããã©ã¢ã«ãã«ãã¹ãã
ãŠã ååç©é¡ãªã©ã奜ãŸããçšããããã ããã²ã³åã¢ã«ãœããŠã ååç©ãšããŠã¯äŸãã°
èåããã©ã¡ãã«ã¢ã«ãœããŠã ããšãŠåããã©ã¡
ãã«ã¢ã«ãœããŠã ãèåããã©ãšãã«ã¢ã«ãœããŠ
ã ããšãŠåããã©ãšãã«ã¢ã«ãœããŠã çã®å¯Ÿç§°åœ¢
ããã©ã¢ã«ãã«ã¢ã«ãœããŠã ååç©é¡ïŒèåã¡ã
ã«ããªããšãã«ã¢ã«ãœããŠã ããšãŠåã¡ãã«ããª
ããšãã«ã¢ã«ãœããŠã çã®ã¢ã«ãã«ã¢ãªãŒã«æ··å
ãã¹ãããŠã ååç©é¡ïŒèåããã©ããšãã«ã¢ã«
ãœããŠã ããšãŠåããã©ããšãã«ã¢ã«ãœããŠã ç
ã®å¯Ÿç§°åœ¢ããã©ã¢ãªãŒã«ã¢ã«ãœããŠã ååç©é¡ïŒ
ãšãŠåã¡ãã«ããªãšãã«ã¢ã«ãœããŠã ããšãŠåãž
ã¡ãã«ãžãšãã«ã¢ã«ãœããŠã çã®é察称圢ããã©
ã¢ã«ãã«ã¢ã«ãœããŠã ååç©é¡ãªã©ã奜ãŸããçš
ããããã ãŸãããã²ã³åã¹ã«ãããŠã ååç©ãšããŠã¯äŸ
ãã°å¡©åããªã¡ãã«ã¹ã«ãããŠã ãèåããªã¡ã
ã«ã¹ã«ãããŠã ããšãŠåããªã¡ãã«ã¹ã«ãããŠ
ã ãèåããªãšãã«ã¹ã«ãããŠã ããšãŠåããªãš
ãã«ã¹ã«ãããŠã ãèåã¡ãã«ãžãšãã«ã¹ã«ãã
ãŠã ããšãŠåã¡ãã«ãžãšãã«ã¹ã«ãããŠã çã®ã¢
ã«ãã«ã¹ã«ãããŠã ååç©é¡ïŒèåãžã¡ãã«ããš
ãã«ã¹ã«ãããŠã ããšãŠåã¡ãã«ãžããšãã«ã¹ã«
ãããŠã çã®ã¢ã«ãã«ã¢ãªãŒã«æ··åãã¹ãããŠã
ååç©é¡ïŒèåããªããšãã«ã¹ã«ãããŠã ããšãŠ
åããªããšãã«ã¹ã«ãããŠã çã®ã¢ãªãŒã«ãã¹ã
ããŠã ååç©é¡ïŒãšãŠåãã·ã¯ãâïŒïŒïŒïŒïŒ
ïŒïŒâããã¿ã³âïŒâã¹ã«ãããŠã ããšãŠåããª
ããªãªãŠã çã®ç°ç¶ã¹ã«ãããŠã ååç©é¡ãªã©ã
奜ãŸããçšããããã ãããã®ããã²ã³åãªããŠã ååç©ã¯ïŒçš®ã ã
ã§çšããããšãã§ããããïŒçš®ä»¥äžãæ··åããŠçš
ããããšãã§ããããã¡ããïŒååå ã«ããã²ã³
åãªããŠã ã°ã«ãŒããïŒå以äžå«ããã®ã§ãã€ãŠ
ãããã ãŸããã®ãããªããã²ã³åãªããŠã ååç©ã®äž
ã§ããã²ã³çš®ãèçŽ ãŸãã¯ãšãŠçŽ ã§ãããã®ã奜
ãŸããçšããããç¹ã«å¥œãŸããã®ã¯ãšãŠçŽ ãå«ã
ãã®ã§ããã æ¬çºæã®åæãšããŠçšããè³éŠæã¢ããååç©
ãšããŠã¯ãã¢ããåºåã¯ã¢ã眮æã¢ããåºãè³éŠ
ç°ã«çŽæ¥çµåãããã®ã§ããã°ã©ã®ãããªãã®ã§
ãããããç¹ã«è³éŠæ第äžçŽã¢ãã³ã奜ãŸããã
ãã®ãããªè³éŠæ第äžçŽã¢ãã³ãšããŠã¯ãäŸãã°
ã¢ããªã³ããžã¢ãããã³ãŒã³ïŒåç°æ§äœïŒãããª
ã¢ãããã³ãŒã³ïŒåç°æ§äœïŒãããã©ã¢ãããã³
ãŒã³ïŒåç°æ§äœïŒãã¢ããããªãžã³ïŒåç°æ§äœïŒã
ãžã¢ããããªãžã³ïŒåç°æ§äœïŒãããªã¢ããããª
ãžã³ïŒåç°æ§äœïŒãã¢ããããã¿ã¬ã³ïŒåç°æ§
äœïŒããžã¢ããããã¿ã¬ã³ïŒåç°æ§äœïŒãããªã¢ã
ãããã¿ã¬ã³ïŒåç°æ§äœïŒãããã©ã¢ããããã¿
ã¬ã³ïŒåç°æ§äœïŒåã³æ¬¡ã®äžè¬åŒïŒïŒã§è¡šãã
ãããžããšãã«ååç©ã®ã¢ãã¢ãã³ããžã¢ãã³ã
ããªã¢ãã³ãããã©ã¢ãã³ã®åç°æ§äœé¡ãããã
ããã ïŒåŒäžïŒ¡ã¯åãªãååŠçµåãåã¯ââãâ
âãâSO2âãâCOâãâCONHâãâCOO
âãâïŒR5ïŒïŒR6ïŒâåã³âïŒR5ïŒâããéžã°
ããäºäŸ¡ã®åºãè¡šããããŸãR5ãR6ã¯ïŒšãèèª
æåºãèç°æåºã§ããïŒ ãŸãããããã®è³éŠæ第äžçŽã¢ãã³ã«ãããŠã
è³éŠç°äžã®å°ãªããšãïŒåã®æ°ŽçŽ ãä»ã®çœ®æåºã
äŸãã°ããã²ã³ååããããåºãã·ã¢ãåºãã¢ã«
ãã«åºãèç°æåºãè³éŠæåºãã¢ã©ãã«åºãã¢ã«
ã³ãã·åºãã¹ã«ããã·ãåºãã¹ã«ãã³åºãã«ã«ã
ãã«åºããšã¹ãã«åºãã¢ããåºãªã©ã«ãã€ãŠçœ®æ
ãããŠããŠãããã ãããã®è³éŠæã¢ããååç©ã®äžã§ç¹ã«å¥œãŸã
ããã®ã¯ã¢ããªã³ãïŒïŒïŒâåã³ïŒïŒïŒâãžã¢ã
ããã«ãšã³ãã¯ãã«ã¢ããªã³ïŒåç°æ§äœïŒããžã¯
ãã«ã¢ããªã³ïŒåç°æ§äœïŒãïŒïŒ4â²âåã³ïŒïŒ
4â²âãžã¢ãããžããšãã«ã¡ã¿ã³ãïŒïŒïŒâãžã¢ã
ãããã¿ã¬ã³ã§ããã æ¬çºæã«çšããææ©ããããã·ã«ååç©ã¯ãäž
䟡åã¯å€äŸ¡ã®ã¢ã«ã³ãŒã«é¡ããããã¯äžäŸ¡åã¯å€
䟡ã®ããšããŒã«é¡ã§ããããã®ãããªã¢ã«ã³ãŒã«
é¡ãšããŠã¯ãäŸãã°ççŽ æ°ïŒã20ã®çŽéåã¯åæ
éã®äžäŸ¡åã¯å€äŸ¡ã¢ã«ã«ããŒã«ãã¢ã«ã±ããŒã«ã
äžäŸ¡åã¯å€äŸ¡ã®ã·ã¯ãã¢ã«ã«ããŒã«ãã·ã¯ãã¢ã«
ã±ããŒã«ãã¢ã©ã«ãã«ã¢ã«ã³ãŒã«ãªã©ããããã
ããããã«ãããã®ã¢ã«ã³ãŒã«é¡ã¯äžæŽ»æ§ãªä»ã®
眮æåºãäŸãã°ããã²ã³ååãã·ã¢ãåºãã¢ã«ã³
ãã·åºãã¹ã«ããã·ãåºãã¹ã«ãã³åºãã«ã«ãã
ã«åºããšã¹ãã«åºãã¢ããåºãªã©ãå«ãã§ããŠã
ããã ãã®ãããªã¢ã«ã³ãŒã«é¡ã®å ·äœäŸãšããŠãã¡ã¿
ããŒã«ããšã¿ããŒã«ããããããŒã«ïŒåç°æ§
äœïŒããã¿ããŒã«ïŒåç°æ§äœïŒããã³ã¿ããŒã«ïŒå
ç°æ§äœïŒããããµããŒã«ïŒåç°æ§äœïŒãããã¿ããŒ
ã«ïŒåç°æ§äœïŒããªã¯ã¿ããŒã«ïŒåç°æ§äœïŒããã
ã«ã¢ã«ã³ãŒã«ïŒåç°æ§äœïŒããã·ã«ã¢ã«ã³ãŒã«
ïŒåç°æ§äœïŒããŠã³ãã·ã«ã¢ã«ã³ãŒã«ïŒåç°æ§
äœïŒãã©ãŠãªã«ã¢ã«ã³ãŒã«ïŒåç°æ§äœïŒãããªãã·
ã«ã¢ã«ã³ãŒã«ïŒåç°æ§äœïŒãããã©ãã·ã«ã¢ã«ã³
ãŒã«ïŒåç°æ§äœïŒããã³ã¿ãã·ã«ã¢ã«ã³ãŒã«ïŒå
ç°æ§äœïŒãªã©ã®èèªæã¢ã«ã³ãŒã«é¡ïŒã·ã¯ããã
ãµããŒã«ãã·ã¯ãããã¿ããŒã«ãªã©ã®ã·ã¯ãã¢ã«
ã«ããŒã«é¡ïŒãšãã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒ
ãã«ããšãã¬ã³ã°ãªã³ãŒã«ã¢ããšãã«ãšãŒãã«ã
ãžãšãã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒãã«ããžãš
ãã¬ã³ã°ãªã³ãŒã«ã¢ããšãã«ãšãŒãã«ãããªãšã
ã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒãã«ãããªãšãã¬
ã³ã°ãªã³ãŒã«ã¢ããšãã«ãšãŒãã«ããããã¬ã³ã°
ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒãã«ããããã¬ã³ã°ãªã³
ãŒã«ã¢ããšãã«ãšãŒãã«ãªã©ã®ã¢ã«ãã¬ã³ã°ãªã³
ãŒã«ã¢ããšãŒãã«é¡ïŒãšãã¬ã³ã°ãªã³ãŒã«ããã
ãã¬ã³ã°ãªã³ãŒã«ããžãšãã¬ã³ã°ãªã³ãŒã«ããžã
ããã¬ã³ã°ãªã³ãŒã«ãã°ãªã»ãªã³ããããµã³ããª
ãªãŒã«ãããªã¡ãããŒã«ãããã³ãªã©ã®å€äŸ¡ã¢ã«
ã³ãŒã«é¡ïŒãã³ãžã«ã¢ã«ã³ãŒã«ãªã©ã®ã¢ã©ãã«ã¢
ã«ã³ãŒã«é¡ãªã©ãçšããããã ãŸãããšããŒã«é¡ãšããŠã¯äŸãã°ãããšããŒã«
åçš®ã¢ã«ãã«ããšããŒã«ãåçš®ã¢ã«ã³ãã·ããšã
ãŒã«ãåçš®ããã²ã³åããšããŒã«ããžããããã·
ãã³ãŒã³ãïŒïŒ4â²âãžããããã·âãžããšãã«ã¡
ã¿ã³ããã¹ããšããŒã«âãããããã·ããã¿ã¬
ã³ãªã©ãçšããããã æ¬çºæã«ãããŠçšããããé žåå€ãšããŠã¯éåžž
ã®é žåå€ã䜿çšã§ãããã奜ãŸããã®ã¯ååç¶é ž
çŽ ãŸãã¯ææ©ãããååç©ããã³ãããã®æ··åç©
ã§ãããç¹ã«å¥œãŸããã®ã¯ååç¶é žçŽ ã§ããã ååç¶é žçŽ ãšã¯çŽé žçŽ ãããã¯é žçŽ ãå«ããã®
ã§ãã€ãŠç©ºæ°ã§ããããã空æ°ãŸãã¯çŽé žçŽ ãå
å¿ãé»å®³ããªãä»ã®ã¬ã¹ãããšãã°ãçªçŽ ãã¢ã«
ãŽã³ãããªãŠã ãçé žã¬ã¹ãªã©ã®äžæŽ»æ§ã¬ã¹ã§çš
éãããã®ã§ãã€ãŠãããããŸãå Žåã«ãã€ãŠ
ã¯ãæ°ŽçŽ ãäžé žåççŽ ãçåæ°ŽçŽ ãããã²ã³åç
åæ°ŽçŽ ãªã©ã®ã¬ã¹ãå«ãã§ããŠãããã ãŸãææ©ãããååéšãšããŠã¯èç°æãèèª
æãããã³è³éŠæãããã®ãããååç©ã§ãã€ãŠ
ããããèç°æãããååç©ãšããŠã¯äŸãã°ãã
ããã·ã¯ããã¿ã³ããããã·ã¯ããã³ã¿ã³ããã
ãã·ã¯ããããµã³ããžãããã·ã¯ããããµã³ïŒå
ç°æ§äœïŒããã¹âïŒãããã·ã¯ãããã·ã«ïŒâã¡
ã¿ã³ããããèèªæãããååç©ãšããŠã¯äŸã
ã°ããããã¡ã¿ã³ãããããšã¿ã³ããããããã
ã³ïŒåç°æ§äœïŒãããããã¿ã³ïŒåç°æ§äœïŒããã
ããã³ã¿ã³ïŒåç°æ§äœïŒãããããããµã³ïŒåç°
æ§äœïŒãããããã«ã³ïŒåç°æ§äœïŒãïŒïŒïŒâãžã
ãããšã¿ã³ããžããããããã³ïŒåç°æ§äœïŒããž
ããããã¿ã³ïŒåç°æ§äœïŒããžããããã³ã¿ã³
ïŒåç°æ§äœïŒããžããããããµã³ïŒåç°æ§äœïŒããž
ããããã«ã³ïŒåç°æ§äœïŒãããšãã«ãããã¡ã¿
ã³ããã¹âïŒãããã¡ãã«ïŒâã·ã¯ããããµã³ã
ãã¹âïŒãããã¡ãã«ïŒâãã³ãŒã³ã³ããããè³
éŠæãããååç©ãšããŠã¯äŸãã°ããããã³ãŒ
ã³ããžããããã³ãŒã³ïŒåç°æ§äœïŒãããããã«
ãšã³ïŒåç°æ§äœïŒããžããããã«ãšã³ïŒåç°æ§
äœïŒããããããªãžã³ïŒåç°æ§äœïŒããžãããããª
ãžã³ïŒåç°æ§äœïŒããããããã¿ã¬ã³ïŒåç°æ§
äœïŒããžãããããã¿ã¬ã³ïŒåç°æ§äœïŒåã³åèš
äžè¬åŒ()ã§è¡šãããããžããšãã«ååç©ã®ã¢ã
ãããååç©ããžãããååç©ã®åç°æ§äœé¡ãã
ããããã ãŸãããããã®ãããååç©ã«ãããŠãå°ãªã
ãšãïŒåã®æ°ŽçŽ ãä»ã®çœ®æåºãäŸãã°ããã²ã³å
åãã¢ããåºãã·ã¢ãåºãã¢ã«ãã«åºãèç°æ
åºãè³éŠæåºãã¢ã©ã«ãã«åºãã¢ã«ã³ãã·åºãã¹
ã«ããã·ãåºãã¹ã«ãã³åºãã«ã«ããã«åºããšã¹
ãã«åºãã¢ããåºãªã©ã§çœ®æãããŠããŠãããã
ãããã®ãããååç©ã®äžã§è³éŠæãããåå
ç©ã奜ãŸãããç¹ã«å¥œãŸãããã®ã¯ããããã³ãŒ
ã³ãããããã«ãšã³ïŒåç°æ§äœïŒããããã¢ããª
ã³ïŒåç°æ§äœïŒãïŒïŒïŒâåã³ïŒïŒïŒâãžããã
ãã«ãšã³ããžã¯ãã«ããããã³ãŒã³ïŒåç°æ§
äœïŒãïŒïŒ4â²âåã³ïŒïŒ4â²âãžããããžããšãã«
ã¡ã¿ã³ãïŒïŒïŒâãžãããããã¿ã¬ã³ã§ããã é žåå€ãååç¶é žçŽ ã®å Žåã¯ãåå¿ã¯æ¬¡ã®ãã
ãªäžè¬çãªåå¿åŒã«åŸã€ãŠé²è¡ããã ArïŒNH2ïŒïœïŒ0.5yã»O2ïŒïœã»COïŒïœã»ROH
âArïŒNHCOORïŒïœïŒïœã»H2O ïŒããã§Arã¯è³éŠæåºããã¯ææ©åºããïœ
ã¯è³éŠæã¢ããååç©ïŒååäžã®ã¢ããåºã®æ°ã
è¡šããïŒ ååç¶é žåã¯åœéãããå°ãªããŠããå€ããŠã
ããããé žçŽ ïŒäžé žåççŽ åã¯é žçŽ ïŒææ©ããã
ãã·ã«ååç©ã®æ··åç©ã¯ççºéçå€ã§äœ¿çšãã¹ã
ã§ããã ãŸããææ©ãããååç©ãé žåå€ãšããŠçšãã
å Žåãææ©ãããååç©èªäœãåå¿ã«äžãããŠã¬
ã¿ã³ãšãªãã®ã§ããã®æ§é ãè³éŠæã¢ããååç©
ãšç°ãªãã°ããããã®æ§é ã«å¿ãããŠã¬ã¿ã³åå
ç©ãåŸãããäž¡è ã®æ§é ãåãã§ããã°åãè³éŠ
æãŠã¬ã¿ã³ååç©ãåŸãããããšã¯ãããŸã§ããª
ãã ãã®å ŽåããŠã¬ã¿ã³ååå¿ã¯äŸãã°æ¬¡ã®ãããª
åå¿åŒã«åŸã€ãŠé²è¡ããã 2ArïŒNH2ïŒïœïŒRâ²ïŒNO2ïŒïœïŒ3yã»COïŒ
3yã»ROHâ2ArïŒNHCOORïŒïœïŒ
Râ²ïŒNHCOORïŒïœïŒ2yã»H2O ïŒArãïœãã¯åèšãšåãæå³ããã¡ãRâ²ã¯
ææ©ãããååç©ã®ãããåºä»¥å€ã®æ®åºãè¡šã
ãïŒ ææ©ãããååç©ã ããé žåå€ãšããŠçšããå Ž
åãè³éŠæã¢ããååç©ãšææ©ãããååç©ã®é
æ¯ã¯ãã¢ããåºïŒã¢ã«åœããããåºïŒã¢ã«ãšãªã
ããã«ããã®ã奜ãŸãããããã¡ãããã®ååŠé
è«éæ¯ããé¢ãããšããã§å®æœããŠãããŸããª
ããäžè¬ã«ã¢ããåºã®ãããåºã«å¯Ÿããåœéæ¯ã¯
1.1ïŒïŒãªããïŒïŒïŒã奜ãŸããã¯1.5ïŒïŒãªãã
2.5ïŒïŒã§å®æœãããã ãã¡ããååç¶é žçŽ ãããã¯ãã®ä»ã®é žåå€ã
åæã«äœ¿çšããå Žåã«ã¯ææ©ãããååç©ã¯éè«
éããå°ãªããŠããã æ¬çºææ¹æ³ã«ãããŠæã奜ãŸããææ©ãããå
åç©ã¯è³éŠæã¢ããååç©ãšåãéªšæ Œãæããè³
éŠæãããååç©ã§ããã æ¬çºææ¹æ³ã«ãããŠã¯ãåå¿æº¶åªãšããŠææ©ã
ãããã·ã«ååç©ãéå°ã«çšããããšã奜ãŸãã
ããå¿ èŠã«å¿ããŠåå¿ã«æªåœ±é¿ãåãŒããªã溶åª
ãçšããããšãã§ããããã®ãããªæº¶åªãšããŠ
ã¯ãäŸãã°ãã³ãŒã³ããã«ãšã³ããã·ã¬ã³ãã¡ã·
ãã¬ã³ãªã©ã®è³éŠæçåæ°ŽçŽ é¡ïŒã¯ãã«ãã³ãŒ
ã³ããžã¯ãã«ãã³ãŒã³ãããªã¯ãã«ãã³ãŒã³ãã
ã«ãªããã³ãŒã³ãã¯ãã«ãã«ãšã³ãã¯ãã«ããã¿
ã¬ã³ãããã ããã¿ãªã³ãªã©ã®ããã²ã³åè³éŠæ
çåæ°ŽçŽ é¡ïŒã¯ãã«ãããµã³ãã¯ãã«ã·ã¯ããã
ãµã³ãããªã¯ãã«ããªãã«ãªããšã¿ã³ãå¡©åã¡ã
ã¬ã³ãåå¡©åççŽ ãªã©ã®ããã²ã³åèèªæçåæ°Ž
çŽ ãããã¯ããã²ã³åèç°æçåæ°ŽçŽ é¡ïŒã¢ã»ã
ãããªã«ããã³ãŸãããªã«ãªã©ã®ãããªã«é¡ïŒã¹
ã«ãã©ã³ãã¡ãã«ã¹ã«ãã©ã³ããžã¡ãã«ã¹ã«ãã©
ã³ãªã©ã®ã¹ã«ãã³é¡ïŒããã©ããããã©ã³ãïŒïŒ
ïŒâãžãªããµã³ãïŒïŒïŒâãžã¡ããã·ãšã¿ã³ãªã©
ã®ãšãŒãã«é¡ïŒã¢ã»ãã³ãã¡ãã«ãšãã«ã±ãã³ãª
ã©ã®ã±ãã³é¡ïŒé ¢é žãšãã«ãå®æ¯éŠé žãšãã«ãªã©
ã®ãšã¹ãã«é¡ïŒïŒ®ïŒïŒ®âãžã¡ãã«ãã«ã ã¢ããã
ïŒïŒ®âãžã¡ãã«ã¢ã»ãã¢ãããâã¡ãã«ãã
ãªãã³ããããµã¡ãã«ãã¹ãã«ã¢ãããªã©ã®ã¢ã
ãé¡ãªã©ããããããã æ¬çºæã«ãããŠçšãããã觊åªã®éã¯ãããã§
ãããããçœéæå çŽ ãå«ãæåã¯è³éŠæã¢ãã
ååç©ã«å¯ŸããŠãéåžž0.0001ã50ã¢ã«ïŒ ã®ç¯å²ã
奜ãŸããããŸãé°ã€ãªã³ãšããŠããã²ã³ãæãã
ãªããŠã ååç©ã¯äœ¿çšãããçœéæå çŽ ãå«ãæ
åã®äžã®éå±å çŽ ã®éã«å¯ŸããŠãéåžž0.001ãã
10000åã¢ã«ã®ç¯å²ã§äœ¿çšãããã®ã奜ãŸããã ãŸãé žåå€ã®éãè³éŠæã¢ããååç©ã«å¯ŸããŠ
éè«é以äžãçšããããšã奜ãŸãããããã¡ãã
ããããå°ãéã§ãã€ãŠãããã æ¬çºææ¹æ³ã«ãããŠãåå¿ãããå¹æçã«è¡ã
ããã«å¿ èŠã«å¿ããŠä»ã®æ·»å ç©ãåå¿ç³»ã«å ãã
ããšãã§ããããã®ãããªæ·»å ç©ãšããŠãäŸãã°
ãŒãªã©ã€ãé¡ãå«çªçŽ ååç©ãšããã²ã³åæ°ŽçŽ ãš
ã®å¡©é¡ãïŒçŽã¢ã³ã¢ãããŠã å¡©é¡ãïŒçŽã¢ãã³é¡
ããã³ããã²ã³åæ°ŽçŽ ãããŠé žãã¢ã«ãã³é žãç
é žãã±ã€é žãææ©é žãªã©ã®ã¢ã«ã«ãªéå±å¡©ãã¢ã«
ã«ãªåé¡éå±å¡©é¡ã奜é©ã§ããã æ¬çºææ¹æ³ã«ãããŠãåå¿ã¯éåžž80ã300âã
奜ãŸããã¯120ã220âã®æž©åºŠç¯å²ã§è¡ãããããŸ
ãåå¿å§åã¯ïŒã500KgïŒcm2ã奜ãŸããã¯20ã300
KgïŒcm2ã®ç¯å²ã§ãããåå¿æéã¯åå¿ç³»ã觊åªç³»
åã³ãã®ä»ã®åå¿æ¡ä»¶ã«ãã€ãŠç°ãªãããéåžžæ°
åãæ°æéã§ããã ãŸããæ¬çºæã®åå¿ã¯åååŒã§ãå®æœããã
ããé£ç¶çã«åå¿æåãäŸçµŠããªããé£ç¶çã«å
å¿æ¶²ãæãåºãé£ç¶æ¹åŒã§ãå®æœãããã 次ã«å®æœäŸã«ãã€ãŠæ¬çºæãããã«è©³çŽ°ã«èª¬æ
ããããæ¬çºæã¯ãããã®å®æœäŸã«éå®ãããã
ã®ã§ã¯ãªãã å®æœäŸ ïŒ å 容ç©140mlã®æ¹æåŒãªãŒãã¯ã¬ãŒãã«ã¢ããª
ã³40mmolããšã¿ããŒã«40mlããã©ãžãŠã é»0.5mg
atomããšãŠåã¡ãã«ããªããšãã«ãã¹ãããŠã
5mmolãå ¥ãç³»å ãäžé žåççŽ ã§çœ®æããåŸãäž
é žåççŽ ã80KgïŒcm2ã次ãã§é žçŽ ïŒKgïŒcm2ãå§å ¥
ãå šå§ã86KgïŒcm2ã«ãããæ¹æããªãã160âã§
ïŒæéåå¿ãããåŸãåå¿æ··åç©ããéããŠã液
ãåæããçµæãã¢ããªã³ã®åå¿çã¯80ïŒ ãâ
ããšãã«ã«ã«ããã³é žãšãã«ã®åçã¯75ïŒ ã§éžæ
çã¯94ïŒ ã§ãã€ãã å®æœäŸ ïŒãïŒ ãšãŠåã¡ãã«ããªããšãã«ãã¹ãããŠã ã®ä»£ã
ã«çš®ã ã®ããã²ã³åãªããŠã ååç©5mmolçšãã
以å€ã¯å®æœäŸïŒãšåæ§ã®åå¿ãè¡ãªã€ãçµæãè¡š
ïŒã«ç€ºãã
ããã«è©³ããã¯é žåå€ã®ååšäžã«è³éŠæã¢ããå
åç©ãäžé žåççŽ åã³ææ©ããããã·ã«ååç©ãš
åå¿ãããŠé žåçã«ã«ã«ããã«åããããšã«ãã€
ãŠè³éŠæãŠã¬ã¿ã³ã補é ããæ¹æ³ã«é¢ããã è³éŠæãŠã¬ã¿ã³é¡ã¯ã«ãŒãã¡ã€ã系蟲è¬ãªã©ã«
çšããããéèŠãªååç©ã§ãããæè¿ã§ã¯ãã¹ã²
ã³ã䜿çšããªãè³éŠæã€ãœã·ã¢ããŒãé¡è£œé ã®å
æãšããŠããã®å®äŸ¡ãªè£œé æ¹æ³ãèŠæãããŠã
ãã åŸæ¥ãäžé žåççŽ ãçšããè³éŠæãŠã¬ã¿ã³åå
ç©ã®è£œæ³ãšããŠãäž»ã«ïŒæ¹æ³ãææ¡ãããŠããã
ããªãã¡ãïŒã€ã®æ¹æ³ã¯ã¢ã«ã³ãŒã«é¡ã®ååšäžã
è³éŠæãããååç©ãéå çã«ãŠã¬ã¿ã³åããæ¹
æ³ã§ãããäŸãã°ããããã³ãŒã³ã®å Žåã¯æ¬¡ã®ã
ããªåŒã§è¡šããããã ããããªãããã®åå¿ã«ãããŠã¯ãããããã³
ãŒã³ïŒã¢ã«åœããäžé žåççŽ ã¯ïŒã¢ã«å¿ èŠã§ã
ãããã®ãã¡ã®ïŒã¢ã«ã®äžé žåççŽ ã¯ç¡äŸ¡å€ãªäº
é žåççŽ ã«ãªãã®ã§ãäžé žåççŽ ã¯äœ¿çšéã®1/3
ããæå¹ã«å©çšãããªããšããæ¬ ç¹ãããããã
ããã®åå¿ãé£ç¶çã«è¡ãã«ã¯ãäžé žåççŽ ãšäº
é žåççŽ ãšã®æ··åã¬ã¹ããäºé žåççŽ ãåé¢ãã
ã°ãªããããã®ããšãå·¥æ¥çã«å®æœããäžã«ãã
ãŠæ¬ ç¹ãšãªã€ãŠããã ä»ã®ïŒã€ã®æ¹æ³ãšããŠé žçŽ åã¯ææ©ãããåå
ç©ãªã©ã®é žåå€ã®ååšäžãè³éŠæã¢ããååç©ã«
äžé žåççŽ åã³ã¢ã«ã³ãŒã«ãåå¿ãããé žåçã«
ãŠã¬ã¿ã³åããæ¹æ³ãæè¿ææ¡ãããŠããããã®
æ¹æ³ã¯ãåèšã®æ¹æ³ã«æ¯ã¹ãŠäžé žåççŽ ã¯æå¹ã«
å©çšãããŠããããã奜ãŸããæ¹æ³ãšããããã
å©è§ŠåªãšããŠå¡©åé ãå¡©åéããªãã·å¡©åéãå¡©
åãããžãŠã ããªãã·å¡©åãããžãŠã ãªã©ã®ãã«
ã€ã¹é žã§ãã€ãŠããããåå¿ç³»ã«ãããŠã¬ããã¯
ã¹åå¿ãè¡ãªãããšã®ã§ããå çŽ ã®å¡©åç©ãåå¿
ç³»äžã«æº¶è§£ãããŠããå¿ èŠãããïŒç¹éæ55â
120551å·å ¬å ±ãç¹éæ55â124750å·å ¬å ±ïŒããã
ããªãã溶解ãããããã®å¡©åç©ã¯åå¿å®¹åšãé
管ããã«ããªã©ã®éå±ææã«å¯Ÿããè é£æ§ã倧ã
ãããã®ããé«äŸ¡ãªéå±ææã䜿çšããªããã°ãª
ããªããšããèšåäžã®åé¡ããããããã«æº¶è§£ã
ããããã®å¡©åç©ãè³éŠæãŠã¬ã¿ã³ãããã¯åå¿
å¯çç©ã§ãããžã¢ãªãŒã«å°¿çŽ ã®ãããªé«æ²žç¹çæ
ç©ããåé¢ã»ååããããã«ã¯ãã¯ãéãªæäœãš
å€å€§ã®è²»çšãèŠãããšããæ¬ ç¹ãããã°ããã§ãª
ãããããã®å©è§Šåªã¯ã¬ããã¯ã¹åå¿ã«ãã€ãŠé
å ãããç¶æ ã®æã«çæããå¡©åæ°ŽçŽ ãæªåå¿ã®
ã¢ããªã³ã®å¡©é žå¡©ãšãªããããåå¿ç³»ã§ã®åé žå
ã«ãã€ãŠãå ã®å¡©åç©ã«ã¯å®å šã«æ»ãããååã
ããæã«ã¯éšåçã«éå ããããã®ãååšããå
å¿ãç¹°ãè¿ãå Žåã«ã¯ããããã®å©è§Šåªãå調補
ããªããã°ãªããªããšããæ¬ ç¹ããã€ãã æ¬çºæè ãã¯ããããã®æ¬ ç¹ãå æãã¹ããè³
éŠæã¢ããååç©ãé žåçã«ãŠã¬ã¿ã³åããŠè³éŠ
æãŠã¬ã¿ã³ååç©ã補é ããæ¹æ³ã«ã€ããŠéæç
究ãéããçµæããããã®æ¬ ç¹ã®äž»èŠåå ãšãªã€
ãŠããã«ã€ã¹é žãã¬ããã¯ã¹åå¿ãè¡ãªãå çŽ ã®
å¡©åç©ãçšããªãã§æ¥è§Šçã«åå¿ãé²è¡ããåŸã
å šãæ°ãã觊åªç³»ãèŠåºãããã®ç¥èŠã«åºã¥ããŠ
æ¬çºæãå®æããã«å°ã€ãã ããªãã¡ãæ¬çºæã¯é žåå€ã®ååšäžã«è³éŠæã¢
ããååç©ãäžé žåççŽ åã³ææ©ããããã·ã«å
åç©ãšåå¿ãããŠè³éŠæãŠã¬ã¿ã³ã補é ããæ¹æ³
ã«ãããŠã çœéæéå±ããã³çœéæå çŽ ãå«ãååç©ã®
äžããéžã°ããå°ããšãïŒçš®ããš é°ã€ãªã³ãããã²ã³ã§ãããªããŠã ååç©
ïŒäœããã¢ã³ã¢ããŠã ååç©ã¯é€ãïŒããã³å
å¿ç³»ã§ããããçæããããšã®ã§ããååç©ã®
äžããéžã°ããå°ããšãïŒçš® ãšããæã觊åªç³»ãçšããããšãç¹åŸŽãšããè³éŠ
æãŠã¬ã¿ã³ã®è£œé æ¹æ³ãæäŸããããšã«ããã ãã®ããã«æ¬çºæã®å€§ããªç¹åŸŽã¯çœéæéå±ã
ãã³çœéæå çŽ ãå«ãååç©ã®äžããéžã°ããå°
ããšãïŒçš®ãšé°ã€ãªã³ãããã²ã³ã§ãããªããŠã
ååç©ã®äžããéžã°ããå°ããšãïŒçš®ãšãçµåã
ãã觊åªç³»ãçšããããšã«ãã€ãŠè³éŠæã¢ããå
åç©ããéžææ§ããããŸãé«åçã§è³éŠæãŠã¬ã¿
ã³ãåŸãããããšã«ããã ãããã®äºå®ã¯ä»ãŸã§å šãç¥ãããŠããªãã€ã
å®ã«é©ãã¹ãããšã§ãã€ãŠåè¿°ã®å è¡æè¡ïŒç¹é
æ55â120551å·å ¬å ±ãç¹éæ55â124750å·å ¬å ±ïŒ
ãããå šãäºæ³ã§ããªãã€ãããšã§ãããããªã
ã¡ãå è¡æè¡ã«ãããŠã¯çœéæååç©ã䞻觊åªãš
ããåå¿ç³»ã«ãããŠã¬ããã¯ã¹åå¿ãè¡ãªãããš
ã®ã§ããå çŽ ã®å¡©åç©ãå©è§Šåªãšãã觊åªç³»ãçš
ããŠãããå®æœäŸã«èŠããã代衚çãªè§Šåªç³»ã¯å¡©
åãã©ãžãŠã ã«å¡©å第ïŒéãçµåããããã®ã§ã
ãããã®ãããªç³»ã«ãããŠã¯ïŒäŸ¡ã®ãã©ãžãŠã ã
åå¿ã«é¢äžããŠããåå¿ã®é²è¡ãšãšãã«éå ãã
ãŠïŒäŸ¡ã®ãã©ãžãŠã ã«ãªãããããå¡©å第ïŒéã«
ãã€ãŠåé žåãããŠïŒäŸ¡ã®ãã©ãžãŠã ã«æ»ããšå
æã«å¡©å第ïŒéã¯éå ãããŠå¡©å第ïŒéãšãªãã
ããã«ãã®å¡©å第ïŒéãé žåå€ã«ãã€ãŠåé žåã
ããŠå¡©å第ïŒéã«æ»ããããããã¯ãã«ãŒåå¿å
ã®è§Šåªãµã€ã¯ã«ã«ãã€ãŠäž»çæç©ã§ããè³éŠæãŠ
ã¬ã¿ã³ãäžããŠãããã®ãšèããããã ãã®ããã«å è¡æè¡ã®æ¹æ³ã§ã¯åå¿ç³»ã«ãããŠ
ã¬ããã¯ã¹äœçšãæããå çŽ ã®å¡©åç©ã䞻觊åªã®
åé žåå€ãšããŠå¿ é ã§ããããšã瀺ãããŠããã
ãã®ãããªæ©èœãæããå çŽ ãšããŠã¯åšæè¡šã®
ïœïœæããã³ïœãïœæã®å çŽ ã®äžããéžã°
ããã¬ããã¯ã¹åå¿ãåããããšã®ã§ãããã®ã§
ãã€ãŠå ·äœçã«ã¯ãé ãäºéãæ°Žéãã¿ãªãŠã ã
ã¹ãºããã¿ã³ããçŽ ãã¢ã³ãã¢ã³ããã¹ãã¹ãã
ããžãŠã ãã¯ãã ãã¢ãªããã³ãã¿ã³ã°ã¹ãã³ã
ãã³ã¬ã³ãéãã³ãã«ããããã±ã«ãæããããŠ
ããããã®äžã§ãé ããããžãŠã ããã³ã¬ã³ãé
ã®ã¿ãå®æœäŸã«èšèŒãããŠããã«éããªãã ããã«åããŠæ¬çºæã®æ¹æ³ã¯ãé°ã€ãªã³ããã
ã²ã³ã§ãããªããŠã ååç©ãŸãã¯ããããåå¿ç³»
ã§çæããããšã®ã§ããååç©ãçšãããã®ã§ã
ã€ãŠããããã®ååç©ã¯å šãéå±æåãå«ãã§ã
ãªããããããã¯éåžžã®åå¿æ¡ä»¶äžã§ã«ããªã³éš
ã¯ã¬ããã¯ã¹åå¿ãè¡ãªããªããã®ã§ããã åŸã€ãŠæ¬çºæã®åå¿ã¯å è¡æè¡ã«èšèŒãããŠã
ãåå¿ãšã¯å šãç°ãªãåå¿æ©æ§ã§é²è¡ããŠããã
ã®ãšæšå®ãããã ãã®ãããªé°ã€ãªã³ãããã²ã³ã§ãããªããŠã
ååç©ãæ¬çºæã®åå¿ã«ãããŠã©ã®ãããªæ©æ§ã§
äœçšããŠãããã¯äžæã§ããããçœéæéå±ãŸã
ã¯çœéæå çŽ ãå«ãååç©ãšçµã¿åãããå Žå
ã«ãè³éŠæã¢ããååç©ã®é žåçãŠã¬ã¿ã³ååå¿
ã®è§ŠåªæåãšããŠéèŠãªäœçšãããŠããããšã¯æ
ããã§ããã ããªãã¡ãé°ã€ãªã³ãããã²ã³ã§ãããªããŠã
ååç©ã®ã¿ã§ã¯æ¬åå¿ã®è³éŠæãŠã¬ã¿ã³ååå¿ã¯
å šãé²è¡ããªããããŸãçœéæéå±ãŸãã¯çœéæ
å çŽ ãå«ãååç©ã®ã¿ã§ãæ¬åå¿ã®æ¡ä»¶äžã§ã¯è³
éŠæãŠã¬ã¿ã³ååå¿ã¯æ®ãã©é²è¡ããªããããã
ãã¯é²è¡ããã«ããŠãå°éã®è³éŠæãŠã¬ã¿ã³ãäž
ããã«éããªããç¹ã«éå±ç¶æ ã®çœéæå çŽ ã®ã¿
ãçšããå Žåã¯è³éŠæãŠã¬ã¿ã³ã¯æ®ãã©åŸãããª
ããäŸãã°ããã©ãžãŠã ã¯æ¬åå¿ã«æå¹ãªè§Šåªæ
åã®ïŒã€ã§ããããïŒäŸ¡ã®éå±ãã©ãžãŠã ã§ãã
ãã©ãžãŠã é»ã®ã¿ã§ã¯æ¬åå¿ã¯å®è³ªçã«æ®ãã©é²
è¡ããªãããããã«é°ã€ãªã³ãããã²ã³ã§ãããª
ããŠã ååç©ãäŸãã°ãšãŠåã¡ãã«ããªããšãã«
ãã¹ãããŠã ãå ãããšãã»ãŒå®éçã«è³éŠæãŠ
ã¬ã¿ã³ãåŸãããããã«ãªãã ãã®ããã«æ¬çºæã®æ¹æ³ã§ã¯éå±ç¶æ ã®åºäœã®
çœéæååç©ãã觊åªæåã®ïŒã€ãšããŠçšããã
ãšãã§ããããã®ããšã¯é«äŸ¡ãªçœéæååç©ã®å
å¿ç³»ããã®åé¢ã»ååããéãªã©ã®ç°¡åãªæ¹æ³ã§
å®æœã§ããããšã瀺ããŠããã æ¬çºæã«ãããŠçšããããçœéæéå±ããã³çœ
éæå çŽ ãå«ãååç©ãšã¯ãæåãšããŠãã©ãžãŠ
ã ãããžãŠã ãçœéãã«ãããŠã ãã€ãªãžãŠã ã
ãªã¹ããŠã ãªã©ã®çœéæå çŽ ããéžã°ããå°ããš
ãïŒçš®ãå«ããã®ã§ãã€ãŠããããã®å çŽ ãéå±
ç¶æ ã«ãããã®ããŸãã¯ååç©ã圢æããæåãš
ãªã€ãŠãããã®ãè¡šããããŸãããããã®è§Šåªæ
åã¯æŽ»æ§çãã°ã©ãã¢ã€ããã·ãªã«ãã¢ã«ããã
ã·ãªã«âã¢ã«ãããã·ãªã«âãã¿ãã¢ããã¿ã
ã¢ããžã«ã³ãã¢ãç¡«é žããªãŠã ãçé žã«ã«ã·ãŠ
ã ãã¢ã¹ãã¹ãããã³ããã€ããã±ã€ãœãŠåãã
ãªããŒãã€ãªã³äº€ææš¹èããŒãªã©ã€ããã¢ã¬ããŠ
ã©ãŒã·ãŒããã±ã€é žãã°ãã·ãŠã ããã°ãã·ã¢ãª
ã©ã®æ äœã«æ æããããã®ã§ãã€ãŠãããã éå±ç¶æ ã®çœéæå çŽ ãšããŠãäŸãã°ãã©ãžãŠ
ã ãããžãŠã ãçœéãã«ãããŠã ãã€ãªãžãŠã å
ã³ãªã¹ããŠã ãªã©ã®éå±ããããã®éå±é»ããã
ãã®éå±ã€ãªã³ãå«ã觊åªæåãåèšã®ãããªæ
äœã«æ æããã®ã¡ãæ°ŽçŽ ãããã«ã ã¢ã«ãããã§
éå åŠçãããã®ãåã³ãããã®éå±ãå«ãåé
ãããã¯éå±éååç©ãªã©ãçšããããããŸãã
åéãããã¯éå±éååç©ã¯ãããã®çœéæéå±
å士ã®ãã®ã§ãã€ãŠãããããä»ã®å çŽ ãäŸãã°
ã»ã¬ã³ããã«ã«ãã€ãªãŠãã¢ã³ãã¢ã³ããã¹ã
ã¹ãé ãéãéãäºéãã¹ãºããããžãŠã ãéã
ã³ãã«ããããã±ã«ãæ°Žéãéãã¿ãªãŠã ãã¯ã
ã ãã¢ãªããã³ãã¿ã³ã°ã¹ãã³ãªã©ãå«ããã®ã§
ãã€ãŠãããã äžæ¹ãçœéæå çŽ ãå«ãååç©ãšããŠã¯ãäŸã
ã°ããã²ã³åç©ãç¡«é žå¡©ãç¡é žå¡©ããªã³é žå¡©ãã
ãŠé žå¡©ãªã©ã®ç¡æ©å¡©é¡ïŒé ¢é žå¡©ãã·ãŠãŠé žå¡©ãã®
é žå¡©ãªã©ã®ææ©é žå¡©é¡ïŒã·ã¢ã³åç©é¡ïŒæ°Žé žåç©
é¡ïŒé žåç©é¡ïŒç¡«åç©é¡ïŒãããåºãã·ã¢ãåºã
ããã²ã³ãã·ãŠãŠé žã€ãªã³ãªã©ã®ã¢ããªã³ãå«ã
éå±é žå¡©åã³ã¢ã³ã¢ãã¢ãã¢ãã³é¡ããã¹ãã€ã³
é¡ãäžé žåççŽ ããã¬ãŒãé äœåãªã©ãå«ãå¡©å
ã¯é¯äœãªã©ã®éå±ã®é¯ååç©é¡ïŒææ©é äœååã¯
ææ©åºãæããææ©éå±ååç©é¡ãªã©ããããã
ãã ãããã®è§Šåªæåã®äžã§ã¯ããã©ãžãŠã åã¯ã
ãžãŠã è¥ããã¯ãã®äž¡æ¹ãå«ããã®ãç¹ã«å¥œãŸã
ãããã®ãããªãã®ãšããŠã¯ãäŸãã°Pdé»ïŒPd
âãPdâAl2O3ãPdâSiO2ãPdâTiO2ãPdâ
ZrO2ãPdâBaSO4ãPdâCaCO3ãPdâã¢ã¹ãã¹
ããPdâãŒãªã©ã€ããPdâã¢ã¬ããŠã©ãŒã·ãŒã
ãªã©ã®æ æãã©ãžãŠã 觊åªé¡ïŒPdâPbãPdâ
SeãPdâTeãPdâHgãPdâTlãPdâãPdâ
CuãPdâAgãPdâFeãPdâCoãPdâNiãPdâ
Rhãªã©ã®åéåã¯éå±éååç©é¡ïŒåã³ããã
ã®åéåã¯éå±éååç©ãåèšã®ãããªæ æã«æ
æãããã®ïŒPdCl2ãPdBr2ãPdI2ãPd
ïŒNO3ïŒ2ãPdSO4ãªã©ã®ç¡æ©å¡©é¡ïŒPd
ïŒOCOCH3ïŒ2ãã·ãŠãŠé žãã©ãžãŠã ãªã©ã®ææ©é ž
å¡©é¡ïŒPdïŒCNïŒ2ïŒPdOïŒPdSïŒM2ãPdXâ²4ããM2
ãPdXâ²6ãã§è¡šãããããã©ãžãŠã é žå¡©é¡ïŒïŒã¯ã¢
ã«ã«ãªéå±åã¯ã¢ã³ã¢ããŠã ã€ãªã³ãè¡šããã
Xâ²ã¯ãããåºåã¯ã·ã¢ãåºåã¯ããã²ã³ãè¡šã
ããïŒïŒãPdïŒNH3ïŒ4ãXâ²2ããPdïŒenïŒ2ãXâ²2ãªã©
ã®ãã©ãžãŠã ã®ã¢ã³ãã³é¯äœé¡ïŒXâ²ã¯äžèšãšå
ãæå³ããã¡ãenã¯ãšãã¬ã³ãžã¢ãã³ãè¡šã
ãïŒïŒPdCl2ïŒPhCNïŒ2ãPdCl2ïŒPR3ïŒ2ãPd
ïŒCOïŒïŒPR3ïŒ3ãPdïŒPPh3ïŒ4ãPdClïŒïŒ²ïŒ
ïŒPPh3ïŒ2ãPdïŒC2H4ïŒïŒPPh3ïŒ2ãPdïŒC3H5ïŒ2ãªã©
ã®é¯ååç©åã¯ææ©éå±ååç©é¡ïŒïŒ²ã¯ææ©åºã
è¡šããïŒïŒPdïŒacacïŒ2ãªã©ã®ãã¬ãŒãé äœåã
é äœããé¯ååç©é¡ïŒRhé»ïŒPdãšåæ§ãªæ æã
ãžãŠã 觊åªé¡ïŒPdãšåæ§ãªRhåéåã¯éå±éå
åç©é¡åã³ããããæ äœã«æ æãããã®ïŒRhCl3
åã³æ°Žåç©ãRhBr3åã³æ°Žåç©ãRhI3åã³æ°Žå
ç©ãRh2ïŒSO4ïŒ3åã³æ°Žåç©ãªã©ã®ç¡æ©å¡©é¡ïŒRh2
ïŒOCOCH3ïŒ4ïŒRh2O3ãRhO2ïŒM3ãRhXâ²6ãåã³
æ°Žåç©ïŒïŒãXâ²ã¯åèšãšåãæå³ããã€ïŒïŒ
ãRhïŒNH3ïŒ5ãXâ²3ããRhïŒenïŒ3ãXâ²3ãªã©ã®ããž
ãŠã ã®ã¢ã³ãã³é¯äœé¡ïŒRh4ïŒCOïŒ12ãRh6
ïŒCOïŒ16ãªã©ã®ããžãŠã ã«ã«ããã«ã¯ã©ã¹ã¿ãŒ
é¡ïŒãRhClïŒCOïŒ2ã2ãRhCl3ïŒPR3ïŒ3ãRhCl
ïŒPPh3ïŒ3ãRhXâ²ïŒCOïŒL2ïŒXâ²ã¯åèšãšåãæå³
ããã¡ãã¯ææ©ãªã³ååç©åã³ææ©ãçŽ ååç©
ãããªãé äœåã§ããïŒãRhHïŒCOïŒïŒPPh3ïŒ3ãª
ã©ã®é¯ååç©åã¯ææ©éå±ååç©é¡ããããã
ãã ãããã®çœéæéå±ãŸãã¯çœéæå çŽ ãå«ãå
åç©ã¯ïŒçš®ã ãã§çšããããšãã§ããããããã
ã¯ïŒçš®ä»¥äžãæ··åããŠçšããããšãã§ããã ãŸãæ¬çºæã§çšãããããé°ã€ãªã³ãããã²ã³
ã§ãããªããŠã ååç©ïŒäœããã¢ã³ã¢ããŠã åå
ç©ã¯é€ãïŒãšã¯ãå€ç«é»å察ããã€å çŽ ãå«ãå
åç©ã«ãããŠããããã®å€ç«é»å察ã«ãããã³ã
ããã¯ä»ã®éœã€ãªã³åœ¢ã®è©Šè¬ãçµåããŠå€ç«é»å
察ããã€å çŽ ãå ±æçµååå䟡ïŒãå¢å ããŠéœã€
ãªã³ãšãªã€ãŠãããã®ã§ãã€ãŠã察ã€ãªã³ãšããŠ
ããã²ã³ã¢ããªã³ãæãããã®ã§ããã ãã®ãããªãªããŠã ååç©ãšããŠã¯ããã¹ãã
ãŠã ååç©ïŒãR1R2R3R4PãïŒãã¢ã«ãœããŠ
ã ååç©ïŒãR1R2R3R4AsãïŒãã¹ããããŠ
ã ååç©ïŒãR1R2R3R4SbããããªããœããŠ
ã ååç©ïŒãR1R2R3OãïŒãã¹ã«ãããŠã
ååç©ïŒãR1R2R3SãïŒããªãã·ã¹ã«ãããŠ
ã ååç©ïŒãR1R2R3SïŒïŒ¯ïŒãïŒãã»ã¬ãã
ãŠã ååç©ïŒãR1R2R3SeãïŒããã«ãããŠ
ã ååç©ïŒãR1R2R3TeãïŒãã¹ã¿ã³ãããŠ
ã ååç©ïŒãR1R2R3SnãïŒããšãŠãããŠã
ååç©ïŒãR1R2IãïŒãªã©ããããããã
ããã§R1ãR2ãR3ãR4ã¯æ°ŽçŽ ãŸãã¯èèªæåºã
è³éŠæåºãèç°æåºãè³éŠèèªæåºããéžã°ãã
åºãè¡šããããããããåãã§ãã€ãŠããããã
ãŸãå Žåã«ãã€ãŠã¯å€ç«é»å察ãæããå çŽ ãå«
ãç°ã®æ§æèŠçŽ ã§ãã€ãŠãããããŸãã¯ïŒŠã
ClãBrãããéžã°ããããã²ã³ãè¡šããã ãã®ãããªé°ã€ãªã³ãããã²ã³ã§ãããªããŠã
ååç©ã§ããããã²ã³åãªããŠã ååç©ã¯ããã
ã²ã³åæ°ŽçŽ ãŸãã¯ææ©ããã²ã³åç©ãšçžåœããã
ã¹ãã€ã³ååç©ãã¢ã«ã·ã³ååç©ãã¹ããã³åå
ç©ããªãã·ååç©ãã¹ã«ãã€ãååç©ãã¹ã«ãã
ã·ãååç©ãã»ã¬ããååç©ããã«ãªãååç©ãª
ã©ãšã®åå¿ã«ãã€ãŠå®¹æã«åŸããããã®ã§ããã
ãããã¯åå¿ç³»å€ã§è£œé ããããã®ãçšããŠãã
ãããåå¿ç³»å ã§ããããçæãããŠããããã
ã¡ããä»ã®æ¹æ³ã§è£œé ããããã®ã§ãã€ãŠããã
ããä»ã®æ¹æ³ã«ãã€ãŠåå¿ç³»å ã§çæããããã®
ã§ãã€ãŠãããã ãããã®äžã§å¥œãŸããã®ã¯ããã²ã³åãã¹ãã
ãŠã ååç©ãããã²ã³åã¢ã«ãœããŠã ååç©ãã
ã³ããã²ã³åã¹ã«ãããŠã ååç©ã§ãç¹ã«å¥œãŸã
ãã®ã¯ããã²ã³åãã¹ãããŠã ååç©ã§ããã ããã²ã³åãã¹ããŠã ååç©ãšããŠã¯äŸãã°å¡©
åããã©ã¡ãã«ãã¹ãããŠã ãèåããã©ã¡ãã«
ãã¹ãããŠã ããšãŠåããã©ã¡ãã«ãã¹ãããŠ
ã ãå¡©åããã©ãšãã«ãã¹ãããŠã ãèåããã©
ãšãã«ãã¹ãããŠã ããšãŠåããã©ãšãã«ãã¹ã
ããŠã çã®å¯Ÿç§°åœ¢ããã©ã¢ã«ãã«ãã¹ãããŠã å
åç©é¡ïŒå¡©åã¡ãã«ããªããšãã«ãã¹ãããŠã ã
èåã¡ãã«ããªããšãã«ãã¹ãããŠã ããšãŠåã¡
ãã«ããªããšãã«ãã¹ãããŠã çã®ã¢ã«ãã«ã¢ãª
ãŒã«æ··åãã¹ãããŠã ååç©é¡ïŒå¡©åããã©ããš
ãã«ãã¹ãããŠã ãèåããã©ããšãã«ãã¹ãã
ãŠã ããšãŠåããã©ããšãã«ãã¹ãããŠã çã®å¯Ÿ
称圢ããã©ã¢ãªãŒã«ãã¹ãããŠã ååç©é¡ïŒå¡©å
ãšãã«ããªã¡ãã«ãã¹ãããŠã ãèåãšãã«ããª
ã¡ãã«ãã¹ãããŠã ããšãŠåãšãã«ããªã¡ãã«ã
ã¹ãããŠã çã®é察称圢ããã©ã¢ã«ãã«ãã¹ãã
ãŠã ååç©é¡ãªã©ã奜ãŸããçšããããã ããã²ã³åã¢ã«ãœããŠã ååç©ãšããŠã¯äŸãã°
èåããã©ã¡ãã«ã¢ã«ãœããŠã ããšãŠåããã©ã¡
ãã«ã¢ã«ãœããŠã ãèåããã©ãšãã«ã¢ã«ãœããŠ
ã ããšãŠåããã©ãšãã«ã¢ã«ãœããŠã çã®å¯Ÿç§°åœ¢
ããã©ã¢ã«ãã«ã¢ã«ãœããŠã ååç©é¡ïŒèåã¡ã
ã«ããªããšãã«ã¢ã«ãœããŠã ããšãŠåã¡ãã«ããª
ããšãã«ã¢ã«ãœããŠã çã®ã¢ã«ãã«ã¢ãªãŒã«æ··å
ãã¹ãããŠã ååç©é¡ïŒèåããã©ããšãã«ã¢ã«
ãœããŠã ããšãŠåããã©ããšãã«ã¢ã«ãœããŠã ç
ã®å¯Ÿç§°åœ¢ããã©ã¢ãªãŒã«ã¢ã«ãœããŠã ååç©é¡ïŒ
ãšãŠåã¡ãã«ããªãšãã«ã¢ã«ãœããŠã ããšãŠåãž
ã¡ãã«ãžãšãã«ã¢ã«ãœããŠã çã®é察称圢ããã©
ã¢ã«ãã«ã¢ã«ãœããŠã ååç©é¡ãªã©ã奜ãŸããçš
ããããã ãŸãããã²ã³åã¹ã«ãããŠã ååç©ãšããŠã¯äŸ
ãã°å¡©åããªã¡ãã«ã¹ã«ãããŠã ãèåããªã¡ã
ã«ã¹ã«ãããŠã ããšãŠåããªã¡ãã«ã¹ã«ãããŠ
ã ãèåããªãšãã«ã¹ã«ãããŠã ããšãŠåããªãš
ãã«ã¹ã«ãããŠã ãèåã¡ãã«ãžãšãã«ã¹ã«ãã
ãŠã ããšãŠåã¡ãã«ãžãšãã«ã¹ã«ãããŠã çã®ã¢
ã«ãã«ã¹ã«ãããŠã ååç©é¡ïŒèåãžã¡ãã«ããš
ãã«ã¹ã«ãããŠã ããšãŠåã¡ãã«ãžããšãã«ã¹ã«
ãããŠã çã®ã¢ã«ãã«ã¢ãªãŒã«æ··åãã¹ãããŠã
ååç©é¡ïŒèåããªããšãã«ã¹ã«ãããŠã ããšãŠ
åããªããšãã«ã¹ã«ãããŠã çã®ã¢ãªãŒã«ãã¹ã
ããŠã ååç©é¡ïŒãšãŠåãã·ã¯ãâïŒïŒïŒïŒïŒ
ïŒïŒâããã¿ã³âïŒâã¹ã«ãããŠã ããšãŠåããª
ããªãªãŠã çã®ç°ç¶ã¹ã«ãããŠã ååç©é¡ãªã©ã
奜ãŸããçšããããã ãããã®ããã²ã³åãªããŠã ååç©ã¯ïŒçš®ã ã
ã§çšããããšãã§ããããïŒçš®ä»¥äžãæ··åããŠçš
ããããšãã§ããããã¡ããïŒååå ã«ããã²ã³
åãªããŠã ã°ã«ãŒããïŒå以äžå«ããã®ã§ãã€ãŠ
ãããã ãŸããã®ãããªããã²ã³åãªããŠã ååç©ã®äž
ã§ããã²ã³çš®ãèçŽ ãŸãã¯ãšãŠçŽ ã§ãããã®ã奜
ãŸããçšããããç¹ã«å¥œãŸããã®ã¯ãšãŠçŽ ãå«ã
ãã®ã§ããã æ¬çºæã®åæãšããŠçšããè³éŠæã¢ããååç©
ãšããŠã¯ãã¢ããåºåã¯ã¢ã眮æã¢ããåºãè³éŠ
ç°ã«çŽæ¥çµåãããã®ã§ããã°ã©ã®ãããªãã®ã§
ãããããç¹ã«è³éŠæ第äžçŽã¢ãã³ã奜ãŸããã
ãã®ãããªè³éŠæ第äžçŽã¢ãã³ãšããŠã¯ãäŸãã°
ã¢ããªã³ããžã¢ãããã³ãŒã³ïŒåç°æ§äœïŒãããª
ã¢ãããã³ãŒã³ïŒåç°æ§äœïŒãããã©ã¢ãããã³
ãŒã³ïŒåç°æ§äœïŒãã¢ããããªãžã³ïŒåç°æ§äœïŒã
ãžã¢ããããªãžã³ïŒåç°æ§äœïŒãããªã¢ããããª
ãžã³ïŒåç°æ§äœïŒãã¢ããããã¿ã¬ã³ïŒåç°æ§
äœïŒããžã¢ããããã¿ã¬ã³ïŒåç°æ§äœïŒãããªã¢ã
ãããã¿ã¬ã³ïŒåç°æ§äœïŒãããã©ã¢ããããã¿
ã¬ã³ïŒåç°æ§äœïŒåã³æ¬¡ã®äžè¬åŒïŒïŒã§è¡šãã
ãããžããšãã«ååç©ã®ã¢ãã¢ãã³ããžã¢ãã³ã
ããªã¢ãã³ãããã©ã¢ãã³ã®åç°æ§äœé¡ãããã
ããã ïŒåŒäžïŒ¡ã¯åãªãååŠçµåãåã¯ââãâ
âãâSO2âãâCOâãâCONHâãâCOO
âãâïŒR5ïŒïŒR6ïŒâåã³âïŒR5ïŒâããéžã°
ããäºäŸ¡ã®åºãè¡šããããŸãR5ãR6ã¯ïŒšãèèª
æåºãèç°æåºã§ããïŒ ãŸãããããã®è³éŠæ第äžçŽã¢ãã³ã«ãããŠã
è³éŠç°äžã®å°ãªããšãïŒåã®æ°ŽçŽ ãä»ã®çœ®æåºã
äŸãã°ããã²ã³ååããããåºãã·ã¢ãåºãã¢ã«
ãã«åºãèç°æåºãè³éŠæåºãã¢ã©ãã«åºãã¢ã«
ã³ãã·åºãã¹ã«ããã·ãåºãã¹ã«ãã³åºãã«ã«ã
ãã«åºããšã¹ãã«åºãã¢ããåºãªã©ã«ãã€ãŠçœ®æ
ãããŠããŠãããã ãããã®è³éŠæã¢ããååç©ã®äžã§ç¹ã«å¥œãŸã
ããã®ã¯ã¢ããªã³ãïŒïŒïŒâåã³ïŒïŒïŒâãžã¢ã
ããã«ãšã³ãã¯ãã«ã¢ããªã³ïŒåç°æ§äœïŒããžã¯
ãã«ã¢ããªã³ïŒåç°æ§äœïŒãïŒïŒ4â²âåã³ïŒïŒ
4â²âãžã¢ãããžããšãã«ã¡ã¿ã³ãïŒïŒïŒâãžã¢ã
ãããã¿ã¬ã³ã§ããã æ¬çºæã«çšããææ©ããããã·ã«ååç©ã¯ãäž
䟡åã¯å€äŸ¡ã®ã¢ã«ã³ãŒã«é¡ããããã¯äžäŸ¡åã¯å€
䟡ã®ããšããŒã«é¡ã§ããããã®ãããªã¢ã«ã³ãŒã«
é¡ãšããŠã¯ãäŸãã°ççŽ æ°ïŒã20ã®çŽéåã¯åæ
éã®äžäŸ¡åã¯å€äŸ¡ã¢ã«ã«ããŒã«ãã¢ã«ã±ããŒã«ã
äžäŸ¡åã¯å€äŸ¡ã®ã·ã¯ãã¢ã«ã«ããŒã«ãã·ã¯ãã¢ã«
ã±ããŒã«ãã¢ã©ã«ãã«ã¢ã«ã³ãŒã«ãªã©ããããã
ããããã«ãããã®ã¢ã«ã³ãŒã«é¡ã¯äžæŽ»æ§ãªä»ã®
眮æåºãäŸãã°ããã²ã³ååãã·ã¢ãåºãã¢ã«ã³
ãã·åºãã¹ã«ããã·ãåºãã¹ã«ãã³åºãã«ã«ãã
ã«åºããšã¹ãã«åºãã¢ããåºãªã©ãå«ãã§ããŠã
ããã ãã®ãããªã¢ã«ã³ãŒã«é¡ã®å ·äœäŸãšããŠãã¡ã¿
ããŒã«ããšã¿ããŒã«ããããããŒã«ïŒåç°æ§
äœïŒããã¿ããŒã«ïŒåç°æ§äœïŒããã³ã¿ããŒã«ïŒå
ç°æ§äœïŒããããµããŒã«ïŒåç°æ§äœïŒãããã¿ããŒ
ã«ïŒåç°æ§äœïŒããªã¯ã¿ããŒã«ïŒåç°æ§äœïŒããã
ã«ã¢ã«ã³ãŒã«ïŒåç°æ§äœïŒããã·ã«ã¢ã«ã³ãŒã«
ïŒåç°æ§äœïŒããŠã³ãã·ã«ã¢ã«ã³ãŒã«ïŒåç°æ§
äœïŒãã©ãŠãªã«ã¢ã«ã³ãŒã«ïŒåç°æ§äœïŒãããªãã·
ã«ã¢ã«ã³ãŒã«ïŒåç°æ§äœïŒãããã©ãã·ã«ã¢ã«ã³
ãŒã«ïŒåç°æ§äœïŒããã³ã¿ãã·ã«ã¢ã«ã³ãŒã«ïŒå
ç°æ§äœïŒãªã©ã®èèªæã¢ã«ã³ãŒã«é¡ïŒã·ã¯ããã
ãµããŒã«ãã·ã¯ãããã¿ããŒã«ãªã©ã®ã·ã¯ãã¢ã«
ã«ããŒã«é¡ïŒãšãã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒ
ãã«ããšãã¬ã³ã°ãªã³ãŒã«ã¢ããšãã«ãšãŒãã«ã
ãžãšãã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒãã«ããžãš
ãã¬ã³ã°ãªã³ãŒã«ã¢ããšãã«ãšãŒãã«ãããªãšã
ã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒãã«ãããªãšãã¬
ã³ã°ãªã³ãŒã«ã¢ããšãã«ãšãŒãã«ããããã¬ã³ã°
ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒãã«ããããã¬ã³ã°ãªã³
ãŒã«ã¢ããšãã«ãšãŒãã«ãªã©ã®ã¢ã«ãã¬ã³ã°ãªã³
ãŒã«ã¢ããšãŒãã«é¡ïŒãšãã¬ã³ã°ãªã³ãŒã«ããã
ãã¬ã³ã°ãªã³ãŒã«ããžãšãã¬ã³ã°ãªã³ãŒã«ããžã
ããã¬ã³ã°ãªã³ãŒã«ãã°ãªã»ãªã³ããããµã³ããª
ãªãŒã«ãããªã¡ãããŒã«ãããã³ãªã©ã®å€äŸ¡ã¢ã«
ã³ãŒã«é¡ïŒãã³ãžã«ã¢ã«ã³ãŒã«ãªã©ã®ã¢ã©ãã«ã¢
ã«ã³ãŒã«é¡ãªã©ãçšããããã ãŸãããšããŒã«é¡ãšããŠã¯äŸãã°ãããšããŒã«
åçš®ã¢ã«ãã«ããšããŒã«ãåçš®ã¢ã«ã³ãã·ããšã
ãŒã«ãåçš®ããã²ã³åããšããŒã«ããžããããã·
ãã³ãŒã³ãïŒïŒ4â²âãžããããã·âãžããšãã«ã¡
ã¿ã³ããã¹ããšããŒã«âãããããã·ããã¿ã¬
ã³ãªã©ãçšããããã æ¬çºæã«ãããŠçšããããé žåå€ãšããŠã¯éåžž
ã®é žåå€ã䜿çšã§ãããã奜ãŸããã®ã¯ååç¶é ž
çŽ ãŸãã¯ææ©ãããååç©ããã³ãããã®æ··åç©
ã§ãããç¹ã«å¥œãŸããã®ã¯ååç¶é žçŽ ã§ããã ååç¶é žçŽ ãšã¯çŽé žçŽ ãããã¯é žçŽ ãå«ããã®
ã§ãã€ãŠç©ºæ°ã§ããããã空æ°ãŸãã¯çŽé žçŽ ãå
å¿ãé»å®³ããªãä»ã®ã¬ã¹ãããšãã°ãçªçŽ ãã¢ã«
ãŽã³ãããªãŠã ãçé žã¬ã¹ãªã©ã®äžæŽ»æ§ã¬ã¹ã§çš
éãããã®ã§ãã€ãŠãããããŸãå Žåã«ãã€ãŠ
ã¯ãæ°ŽçŽ ãäžé žåççŽ ãçåæ°ŽçŽ ãããã²ã³åç
åæ°ŽçŽ ãªã©ã®ã¬ã¹ãå«ãã§ããŠãããã ãŸãææ©ãããååéšãšããŠã¯èç°æãèèª
æãããã³è³éŠæãããã®ãããååç©ã§ãã€ãŠ
ããããèç°æãããååç©ãšããŠã¯äŸãã°ãã
ããã·ã¯ããã¿ã³ããããã·ã¯ããã³ã¿ã³ããã
ãã·ã¯ããããµã³ããžãããã·ã¯ããããµã³ïŒå
ç°æ§äœïŒããã¹âïŒãããã·ã¯ãããã·ã«ïŒâã¡
ã¿ã³ããããèèªæãããååç©ãšããŠã¯äŸã
ã°ããããã¡ã¿ã³ãããããšã¿ã³ããããããã
ã³ïŒåç°æ§äœïŒãããããã¿ã³ïŒåç°æ§äœïŒããã
ããã³ã¿ã³ïŒåç°æ§äœïŒãããããããµã³ïŒåç°
æ§äœïŒãããããã«ã³ïŒåç°æ§äœïŒãïŒïŒïŒâãžã
ãããšã¿ã³ããžããããããã³ïŒåç°æ§äœïŒããž
ããããã¿ã³ïŒåç°æ§äœïŒããžããããã³ã¿ã³
ïŒåç°æ§äœïŒããžããããããµã³ïŒåç°æ§äœïŒããž
ããããã«ã³ïŒåç°æ§äœïŒãããšãã«ãããã¡ã¿
ã³ããã¹âïŒãããã¡ãã«ïŒâã·ã¯ããããµã³ã
ãã¹âïŒãããã¡ãã«ïŒâãã³ãŒã³ã³ããããè³
éŠæãããååç©ãšããŠã¯äŸãã°ããããã³ãŒ
ã³ããžããããã³ãŒã³ïŒåç°æ§äœïŒãããããã«
ãšã³ïŒåç°æ§äœïŒããžããããã«ãšã³ïŒåç°æ§
äœïŒããããããªãžã³ïŒåç°æ§äœïŒããžãããããª
ãžã³ïŒåç°æ§äœïŒããããããã¿ã¬ã³ïŒåç°æ§
äœïŒããžãããããã¿ã¬ã³ïŒåç°æ§äœïŒåã³åèš
äžè¬åŒ()ã§è¡šãããããžããšãã«ååç©ã®ã¢ã
ãããååç©ããžãããååç©ã®åç°æ§äœé¡ãã
ããããã ãŸãããããã®ãããååç©ã«ãããŠãå°ãªã
ãšãïŒåã®æ°ŽçŽ ãä»ã®çœ®æåºãäŸãã°ããã²ã³å
åãã¢ããåºãã·ã¢ãåºãã¢ã«ãã«åºãèç°æ
åºãè³éŠæåºãã¢ã©ã«ãã«åºãã¢ã«ã³ãã·åºãã¹
ã«ããã·ãåºãã¹ã«ãã³åºãã«ã«ããã«åºããšã¹
ãã«åºãã¢ããåºãªã©ã§çœ®æãããŠããŠãããã
ãããã®ãããååç©ã®äžã§è³éŠæãããåå
ç©ã奜ãŸãããç¹ã«å¥œãŸãããã®ã¯ããããã³ãŒ
ã³ãããããã«ãšã³ïŒåç°æ§äœïŒããããã¢ããª
ã³ïŒåç°æ§äœïŒãïŒïŒïŒâåã³ïŒïŒïŒâãžããã
ãã«ãšã³ããžã¯ãã«ããããã³ãŒã³ïŒåç°æ§
äœïŒãïŒïŒ4â²âåã³ïŒïŒ4â²âãžããããžããšãã«
ã¡ã¿ã³ãïŒïŒïŒâãžãããããã¿ã¬ã³ã§ããã é žåå€ãååç¶é žçŽ ã®å Žåã¯ãåå¿ã¯æ¬¡ã®ãã
ãªäžè¬çãªåå¿åŒã«åŸã€ãŠé²è¡ããã ArïŒNH2ïŒïœïŒ0.5yã»O2ïŒïœã»COïŒïœã»ROH
âArïŒNHCOORïŒïœïŒïœã»H2O ïŒããã§Arã¯è³éŠæåºããã¯ææ©åºããïœ
ã¯è³éŠæã¢ããååç©ïŒååäžã®ã¢ããåºã®æ°ã
è¡šããïŒ ååç¶é žåã¯åœéãããå°ãªããŠããå€ããŠã
ããããé žçŽ ïŒäžé žåççŽ åã¯é žçŽ ïŒææ©ããã
ãã·ã«ååç©ã®æ··åç©ã¯ççºéçå€ã§äœ¿çšãã¹ã
ã§ããã ãŸããææ©ãããååç©ãé žåå€ãšããŠçšãã
å Žåãææ©ãããååç©èªäœãåå¿ã«äžãããŠã¬
ã¿ã³ãšãªãã®ã§ããã®æ§é ãè³éŠæã¢ããååç©
ãšç°ãªãã°ããããã®æ§é ã«å¿ãããŠã¬ã¿ã³åå
ç©ãåŸãããäž¡è ã®æ§é ãåãã§ããã°åãè³éŠ
æãŠã¬ã¿ã³ååç©ãåŸãããããšã¯ãããŸã§ããª
ãã ãã®å ŽåããŠã¬ã¿ã³ååå¿ã¯äŸãã°æ¬¡ã®ãããª
åå¿åŒã«åŸã€ãŠé²è¡ããã 2ArïŒNH2ïŒïœïŒRâ²ïŒNO2ïŒïœïŒ3yã»COïŒ
3yã»ROHâ2ArïŒNHCOORïŒïœïŒ
Râ²ïŒNHCOORïŒïœïŒ2yã»H2O ïŒArãïœãã¯åèšãšåãæå³ããã¡ãRâ²ã¯
ææ©ãããååç©ã®ãããåºä»¥å€ã®æ®åºãè¡šã
ãïŒ ææ©ãããååç©ã ããé žåå€ãšããŠçšããå Ž
åãè³éŠæã¢ããååç©ãšææ©ãããååç©ã®é
æ¯ã¯ãã¢ããåºïŒã¢ã«åœããããåºïŒã¢ã«ãšãªã
ããã«ããã®ã奜ãŸãããããã¡ãããã®ååŠé
è«éæ¯ããé¢ãããšããã§å®æœããŠãããŸããª
ããäžè¬ã«ã¢ããåºã®ãããåºã«å¯Ÿããåœéæ¯ã¯
1.1ïŒïŒãªããïŒïŒïŒã奜ãŸããã¯1.5ïŒïŒãªãã
2.5ïŒïŒã§å®æœãããã ãã¡ããååç¶é žçŽ ãããã¯ãã®ä»ã®é žåå€ã
åæã«äœ¿çšããå Žåã«ã¯ææ©ãããååç©ã¯éè«
éããå°ãªããŠããã æ¬çºææ¹æ³ã«ãããŠæã奜ãŸããææ©ãããå
åç©ã¯è³éŠæã¢ããååç©ãšåãéªšæ Œãæããè³
éŠæãããååç©ã§ããã æ¬çºææ¹æ³ã«ãããŠã¯ãåå¿æº¶åªãšããŠææ©ã
ãããã·ã«ååç©ãéå°ã«çšããããšã奜ãŸãã
ããå¿ èŠã«å¿ããŠåå¿ã«æªåœ±é¿ãåãŒããªã溶åª
ãçšããããšãã§ããããã®ãããªæº¶åªãšããŠ
ã¯ãäŸãã°ãã³ãŒã³ããã«ãšã³ããã·ã¬ã³ãã¡ã·
ãã¬ã³ãªã©ã®è³éŠæçåæ°ŽçŽ é¡ïŒã¯ãã«ãã³ãŒ
ã³ããžã¯ãã«ãã³ãŒã³ãããªã¯ãã«ãã³ãŒã³ãã
ã«ãªããã³ãŒã³ãã¯ãã«ãã«ãšã³ãã¯ãã«ããã¿
ã¬ã³ãããã ããã¿ãªã³ãªã©ã®ããã²ã³åè³éŠæ
çåæ°ŽçŽ é¡ïŒã¯ãã«ãããµã³ãã¯ãã«ã·ã¯ããã
ãµã³ãããªã¯ãã«ããªãã«ãªããšã¿ã³ãå¡©åã¡ã
ã¬ã³ãåå¡©åççŽ ãªã©ã®ããã²ã³åèèªæçåæ°Ž
çŽ ãããã¯ããã²ã³åèç°æçåæ°ŽçŽ é¡ïŒã¢ã»ã
ãããªã«ããã³ãŸãããªã«ãªã©ã®ãããªã«é¡ïŒã¹
ã«ãã©ã³ãã¡ãã«ã¹ã«ãã©ã³ããžã¡ãã«ã¹ã«ãã©
ã³ãªã©ã®ã¹ã«ãã³é¡ïŒããã©ããããã©ã³ãïŒïŒ
ïŒâãžãªããµã³ãïŒïŒïŒâãžã¡ããã·ãšã¿ã³ãªã©
ã®ãšãŒãã«é¡ïŒã¢ã»ãã³ãã¡ãã«ãšãã«ã±ãã³ãª
ã©ã®ã±ãã³é¡ïŒé ¢é žãšãã«ãå®æ¯éŠé žãšãã«ãªã©
ã®ãšã¹ãã«é¡ïŒïŒ®ïŒïŒ®âãžã¡ãã«ãã«ã ã¢ããã
ïŒïŒ®âãžã¡ãã«ã¢ã»ãã¢ãããâã¡ãã«ãã
ãªãã³ããããµã¡ãã«ãã¹ãã«ã¢ãããªã©ã®ã¢ã
ãé¡ãªã©ããããããã æ¬çºæã«ãããŠçšãããã觊åªã®éã¯ãããã§
ãããããçœéæå çŽ ãå«ãæåã¯è³éŠæã¢ãã
ååç©ã«å¯ŸããŠãéåžž0.0001ã50ã¢ã«ïŒ ã®ç¯å²ã
奜ãŸããããŸãé°ã€ãªã³ãšããŠããã²ã³ãæãã
ãªããŠã ååç©ã¯äœ¿çšãããçœéæå çŽ ãå«ãæ
åã®äžã®éå±å çŽ ã®éã«å¯ŸããŠãéåžž0.001ãã
10000åã¢ã«ã®ç¯å²ã§äœ¿çšãããã®ã奜ãŸããã ãŸãé žåå€ã®éãè³éŠæã¢ããååç©ã«å¯ŸããŠ
éè«é以äžãçšããããšã奜ãŸãããããã¡ãã
ããããå°ãéã§ãã€ãŠãããã æ¬çºææ¹æ³ã«ãããŠãåå¿ãããå¹æçã«è¡ã
ããã«å¿ èŠã«å¿ããŠä»ã®æ·»å ç©ãåå¿ç³»ã«å ãã
ããšãã§ããããã®ãããªæ·»å ç©ãšããŠãäŸãã°
ãŒãªã©ã€ãé¡ãå«çªçŽ ååç©ãšããã²ã³åæ°ŽçŽ ãš
ã®å¡©é¡ãïŒçŽã¢ã³ã¢ãããŠã å¡©é¡ãïŒçŽã¢ãã³é¡
ããã³ããã²ã³åæ°ŽçŽ ãããŠé žãã¢ã«ãã³é žãç
é žãã±ã€é žãææ©é žãªã©ã®ã¢ã«ã«ãªéå±å¡©ãã¢ã«
ã«ãªåé¡éå±å¡©é¡ã奜é©ã§ããã æ¬çºææ¹æ³ã«ãããŠãåå¿ã¯éåžž80ã300âã
奜ãŸããã¯120ã220âã®æž©åºŠç¯å²ã§è¡ãããããŸ
ãåå¿å§åã¯ïŒã500KgïŒcm2ã奜ãŸããã¯20ã300
KgïŒcm2ã®ç¯å²ã§ãããåå¿æéã¯åå¿ç³»ã觊åªç³»
åã³ãã®ä»ã®åå¿æ¡ä»¶ã«ãã€ãŠç°ãªãããéåžžæ°
åãæ°æéã§ããã ãŸããæ¬çºæã®åå¿ã¯åååŒã§ãå®æœããã
ããé£ç¶çã«åå¿æåãäŸçµŠããªããé£ç¶çã«å
å¿æ¶²ãæãåºãé£ç¶æ¹åŒã§ãå®æœãããã 次ã«å®æœäŸã«ãã€ãŠæ¬çºæãããã«è©³çŽ°ã«èª¬æ
ããããæ¬çºæã¯ãããã®å®æœäŸã«éå®ãããã
ã®ã§ã¯ãªãã å®æœäŸ ïŒ å 容ç©140mlã®æ¹æåŒãªãŒãã¯ã¬ãŒãã«ã¢ããª
ã³40mmolããšã¿ããŒã«40mlããã©ãžãŠã é»0.5mg
atomããšãŠåã¡ãã«ããªããšãã«ãã¹ãããŠã
5mmolãå ¥ãç³»å ãäžé žåççŽ ã§çœ®æããåŸãäž
é žåççŽ ã80KgïŒcm2ã次ãã§é žçŽ ïŒKgïŒcm2ãå§å ¥
ãå šå§ã86KgïŒcm2ã«ãããæ¹æããªãã160âã§
ïŒæéåå¿ãããåŸãåå¿æ··åç©ããéããŠã液
ãåæããçµæãã¢ããªã³ã®åå¿çã¯80ïŒ ãâ
ããšãã«ã«ã«ããã³é žãšãã«ã®åçã¯75ïŒ ã§éžæ
çã¯94ïŒ ã§ãã€ãã å®æœäŸ ïŒãïŒ ãšãŠåã¡ãã«ããªããšãã«ãã¹ãããŠã ã®ä»£ã
ã«çš®ã ã®ããã²ã³åãªããŠã ååç©5mmolçšãã
以å€ã¯å®æœäŸïŒãšåæ§ã®åå¿ãè¡ãªã€ãçµæãè¡š
ïŒã«ç€ºãã
ãè¡šã
æ¯èŒäŸ ïŒ
ãšãŠåã¡ãã«ããªããšãã«ãã¹ãããŠã ãçšã
ãªãã§ãã©ãžãŠã é»ã®ã¿ãçšããŠå®äŸïŒãšåæ§ã®
åå¿ãè¡ãªã€ãçµæãã¢ããªã³ã®åå¿çã¯ïŒïŒ
ã§ãâããšãã«ã«ã«ããã³é žãšãã«ã¯ããã
1.9ïŒ ã®åçã§çæããŠããã«éããªãã€ãã å®æœäŸ ïŒ å 容ç©200mlã®æ¹æåŒãªãŒãã¯ã¬ãŒãã«ã¢ããª
ã³50mmolããšã¿ããŒã«50mlã掻æ§çã«5WïŒ ã®ã
ãžãŠã ãæ æããRhïŒC1gããšãŠåã¡ãã«ããª
ããšãã«ãã¹ãããŠã 6mmolãå ¥ããç³»å ãäžé ž
åççŽ ã§çœ®æããåŸãäžé žåççŽ ã80KgïŒcm2ã次
ãã§é žçŽ ïŒKgïŒcm2ãå§å ¥ãå šå§ã86KgïŒcm2ã«ã
ããæ¹æããªãã160âã§ïŒæéåå¿ãããåŸã
åå¿æ··åç©ããéããŠã液ãåæããçµæãã¢ã
ãªã³ã®åå¿çã¯73ïŒ ããâããšãã«ã«ã«ããã³
é žãšãã«ã®åçã¯59ïŒ ã§éžæçã¯81ïŒ ã§ãã€ãã æ¯èŒäŸ ïŒ ãšãŠåã¡ãã«ããªããšãã«ãã¹ãããŠã ãçšã
ãªãã§å®æœäŸïŒãšåãåå¿ãè¡ãªã€ãããã¢ããª
ã³ã®åå¿çã¯ïŒïŒ ã§ïŒ®âããšãã«ã«ã«ããã³é žãš
ãã«ã®åçã¯ïŒïŒ 以äžã§ãã€ãã å®æœäŸ ïŒã15 å®æœäŸïŒã«ãããŠPdé»ã®ä»£ãã«çš®ã ã®çœéæ
éå±ãŸãã¯çœéæå çŽ ãå«ãååç©ãçšããŠåæ§
ã®åå¿ãè¡ãªã€ãçµæãè¡šïŒã«ç€ºãã
ãªãã§ãã©ãžãŠã é»ã®ã¿ãçšããŠå®äŸïŒãšåæ§ã®
åå¿ãè¡ãªã€ãçµæãã¢ããªã³ã®åå¿çã¯ïŒïŒ
ã§ãâããšãã«ã«ã«ããã³é žãšãã«ã¯ããã
1.9ïŒ ã®åçã§çæããŠããã«éããªãã€ãã å®æœäŸ ïŒ å 容ç©200mlã®æ¹æåŒãªãŒãã¯ã¬ãŒãã«ã¢ããª
ã³50mmolããšã¿ããŒã«50mlã掻æ§çã«5WïŒ ã®ã
ãžãŠã ãæ æããRhïŒC1gããšãŠåã¡ãã«ããª
ããšãã«ãã¹ãããŠã 6mmolãå ¥ããç³»å ãäžé ž
åççŽ ã§çœ®æããåŸãäžé žåççŽ ã80KgïŒcm2ã次
ãã§é žçŽ ïŒKgïŒcm2ãå§å ¥ãå šå§ã86KgïŒcm2ã«ã
ããæ¹æããªãã160âã§ïŒæéåå¿ãããåŸã
åå¿æ··åç©ããéããŠã液ãåæããçµæãã¢ã
ãªã³ã®åå¿çã¯73ïŒ ããâããšãã«ã«ã«ããã³
é žãšãã«ã®åçã¯59ïŒ ã§éžæçã¯81ïŒ ã§ãã€ãã æ¯èŒäŸ ïŒ ãšãŠåã¡ãã«ããªããšãã«ãã¹ãããŠã ãçšã
ãªãã§å®æœäŸïŒãšåãåå¿ãè¡ãªã€ãããã¢ããª
ã³ã®åå¿çã¯ïŒïŒ ã§ïŒ®âããšãã«ã«ã«ããã³é žãš
ãã«ã®åçã¯ïŒïŒ 以äžã§ãã€ãã å®æœäŸ ïŒã15 å®æœäŸïŒã«ãããŠPdé»ã®ä»£ãã«çš®ã ã®çœéæ
éå±ãŸãã¯çœéæå çŽ ãå«ãååç©ãçšããŠåæ§
ã®åå¿ãè¡ãªã€ãçµæãè¡šïŒã«ç€ºãã
ãè¡šã
ãªããããã®å®æœäŸã«ãããŠçœéæéå±ãŸãã¯
çœéæååç©ã¯éå±å çŽ ãšããŠ0.5mgatomãçš
ããïŒ è¡šç€ºã¯æ æããã觊åªæåã®ééïŒ ã瀺
ããPdâTeïŒïŒ£ã¯æŽ»æ§çã«å¡©åãã©ãžãŠã ãšäº
é žåãã«ã«ãã¢ã«æ¯ã§10察ïŒã®å²åã§å ±æ æãã
åŸã350âã§æ°ŽçŽ éå ãããã®ã§ããã å®æœäŸ 16 å 容ç©200mlã®æ¹æåŒãªãŒãã¯ã¬ãŒãã«ã¢ããª
ã³30mmolãããããã³ãŒã³15mmolãã¡ã¿ããŒã«
50mlãå¡©åãã©ãžãŠã 0.5mmolããšãŠåã¡ãã«ã
ãªããšãã«ãã¹ãããŠã 5mmolãå ¥ããç³»å ãäž
é žåççŽ ã§çœ®æããåŸãäžé žåççŽ ã120KgïŒcm2
å§å ¥ãããæ¹æããªãã180âã§ïŒæéåå¿ãã
ããåå¿æ¶²ãåæããçµæãã¢ããªã³ããã³ãã
ããã³ãŒã³ã®åå¿çã¯ãããã16ïŒ ãããã³22ïŒ
ã§ãâããšãã«ã«ã«ããã³é žã¡ãã«ã6mmolç
æããŠããã å®æœäŸ 17 å 容ç©300mlã®ãªãŒãã¯ã¬ãŒãã«ïŒïŒïŒâãžã¢
ãããã«ãšã³30mmolãã¡ã¿ããŒã«50mlã掻æ§ç
ã«10WïŒ ã®ãã©ãžãŠã ãæ æããPdïŒC1gããšãŠ
åããã©ããšãã«ãã¹ãããŠã 6mmolãå ¥ããç³»
å ãäžé žåççŽ ã§çœ®æããåŸãäžé žåççŽ ã120
KgïŒcm2ã次ãã§é žçŽ ïŒKgïŒcm2ãå§å ¥ãããæ¹æã
ãªãã160âã§ïŒæéåå¿ãããåŸãåå¿æ··åç©
ããéããŠã液ãåæããçµæãïŒïŒïŒâãžã¢ã
ããã«ãšã³ã®åå¿çã¯79ïŒ ã§ãããªã¬ã³âïŒïŒïŒ
âãžã«ã«ããã³é žãžã¡ãã«ãåç65ïŒ ã§ããŸãã¡
ãã«âïŒâã¢ããâïŒâã¡ãã«ã«ã«ããã¬ãŒããš
ã¡ãã«âïŒâã¡ãã«âïŒâã¢ããã«ã«ããã¬ãŒã
ãšã®æ··åç©ã§ããã¢ããã¢ããŠã¬ã¿ã³ãåçïŒïŒ
ã§çæããŠããããšãããã€ãããŠã¬ã¿ã³åã«ã
ããåèšéžæçã¯92ïŒ ã§ãã€ãã
çœéæååç©ã¯éå±å çŽ ãšããŠ0.5mgatomãçš
ããïŒ è¡šç€ºã¯æ æããã觊åªæåã®ééïŒ ã瀺
ããPdâTeïŒïŒ£ã¯æŽ»æ§çã«å¡©åãã©ãžãŠã ãšäº
é žåãã«ã«ãã¢ã«æ¯ã§10察ïŒã®å²åã§å ±æ æãã
åŸã350âã§æ°ŽçŽ éå ãããã®ã§ããã å®æœäŸ 16 å 容ç©200mlã®æ¹æåŒãªãŒãã¯ã¬ãŒãã«ã¢ããª
ã³30mmolãããããã³ãŒã³15mmolãã¡ã¿ããŒã«
50mlãå¡©åãã©ãžãŠã 0.5mmolããšãŠåã¡ãã«ã
ãªããšãã«ãã¹ãããŠã 5mmolãå ¥ããç³»å ãäž
é žåççŽ ã§çœ®æããåŸãäžé žåççŽ ã120KgïŒcm2
å§å ¥ãããæ¹æããªãã180âã§ïŒæéåå¿ãã
ããåå¿æ¶²ãåæããçµæãã¢ããªã³ããã³ãã
ããã³ãŒã³ã®åå¿çã¯ãããã16ïŒ ãããã³22ïŒ
ã§ãâããšãã«ã«ã«ããã³é žã¡ãã«ã6mmolç
æããŠããã å®æœäŸ 17 å 容ç©300mlã®ãªãŒãã¯ã¬ãŒãã«ïŒïŒïŒâãžã¢
ãããã«ãšã³30mmolãã¡ã¿ããŒã«50mlã掻æ§ç
ã«10WïŒ ã®ãã©ãžãŠã ãæ æããPdïŒC1gããšãŠ
åããã©ããšãã«ãã¹ãããŠã 6mmolãå ¥ããç³»
å ãäžé žåççŽ ã§çœ®æããåŸãäžé žåççŽ ã120
KgïŒcm2ã次ãã§é žçŽ ïŒKgïŒcm2ãå§å ¥ãããæ¹æã
ãªãã160âã§ïŒæéåå¿ãããåŸãåå¿æ··åç©
ããéããŠã液ãåæããçµæãïŒïŒïŒâãžã¢ã
ããã«ãšã³ã®åå¿çã¯79ïŒ ã§ãããªã¬ã³âïŒïŒïŒ
âãžã«ã«ããã³é žãžã¡ãã«ãåç65ïŒ ã§ããŸãã¡
ãã«âïŒâã¢ããâïŒâã¡ãã«ã«ã«ããã¬ãŒããš
ã¡ãã«âïŒâã¡ãã«âïŒâã¢ããã«ã«ããã¬ãŒã
ãšã®æ··åç©ã§ããã¢ããã¢ããŠã¬ã¿ã³ãåçïŒïŒ
ã§çæããŠããããšãããã€ãããŠã¬ã¿ã³åã«ã
ããåèšéžæçã¯92ïŒ ã§ãã€ãã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ é žåå€ã®ååšäžã«è³éŠæã¢ããååç©ãäžé ž
åççŽ ããã³ææ©ããããã·ã«ååç©ãšåå¿ãã
ãŠè³éŠæãŠã¬ã¿ã³ã補é ããæ¹æ³ã«ãããŠã çœéæéå±ããã³çœéæå çŽ ãå«ãååç©ã®
äžããéžã°ããå°ããšãïŒçš®ãš é°ã€ãªã³ãããã²ã³ã§ããããªããŠã ååç©
ïŒäœããã¢ã³ã¢ããŠã ååç©ã¯é€ãïŒããã³å
å¿ç³»ã§ããããçæããããšã®ã§ããååç©ã®
äžããéžã°ããå°ããšãïŒçš® ãšããæã觊åªç³»ãçšããããšãç¹åŸŽãšããè³éŠ
æãŠã¬ã¿ã³ã®è£œæ³ã ïŒ é žåå€ãååç¶é žçŽ ããã³ææ©ãããååç©
ããéžã°ããå°ããšãïŒçš®ã§ããç¹èš±è«æ±ã®ç¯å²
第ïŒé èšèŒã®æ¹æ³ã ïŒ é žåå€ãååç¶é žçŽ ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé èšèŒã®æ¹æ³ã ïŒ çœéæéå±ããã³çœéæå çŽ ãå«ãååç©ã
ãã©ãžãŠã ãããžãŠã ããã©ãžãŠã ååç©ããã³
ããžãŠã ååç©ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã第
ïŒé ã®ããããïŒé ã«èšèŒã®æ¹æ³ã ïŒ ãªããŠã ååç©ããã¹ãããŠã ååç©ãã¢ã«
ãœããŠã ååç©ãã¹ã«ãããŠã ååç©ã§ããç¹èš±
è«æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒé ã®ããããïŒé ã«èšèŒ
ã®æ¹æ³ã ïŒ ããã²ã³çš®ããšãŠçŽ ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé ã第ïŒé ã®ããããïŒé ã«èšèŒã®æ¹æ³ã
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP535782A JPS58124757A (ja) | 1982-01-19 | 1982-01-19 | è³éŠæãŠã¬ã¿ã³ã®è£œæ³ |
| EP19820111989 EP0083096B1 (en) | 1981-12-25 | 1982-12-24 | Production of urethane compounds |
| DE8282111989T DE3275464D1 (en) | 1981-12-25 | 1982-12-24 | Production of urethane compounds |
| US06/681,061 US4621149A (en) | 1981-12-25 | 1984-12-10 | Production of urethane compounds |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP535782A JPS58124757A (ja) | 1982-01-19 | 1982-01-19 | è³éŠæãŠã¬ã¿ã³ã®è£œæ³ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58124757A JPS58124757A (ja) | 1983-07-25 |
| JPS6125703B2 true JPS6125703B2 (ja) | 1986-06-17 |
Family
ID=11608920
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP535782A Granted JPS58124757A (ja) | 1981-12-25 | 1982-01-19 | è³éŠæãŠã¬ã¿ã³ã®è£œæ³ |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58124757A (ja) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0619427U (ja) * | 1992-04-28 | 1994-03-15 | äžæ²³ãã¯ãã³æ ªåŒäŒç€Ÿ | å±å€ã«ãããéè³çšæ€ç©ã®æ€æšé¢ |
-
1982
- 1982-01-19 JP JP535782A patent/JPS58124757A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS58124757A (ja) | 1983-07-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4621149A (en) | Production of urethane compounds | |
| EP0083096B1 (en) | Production of urethane compounds | |
| JPS6125703B2 (ja) | ||
| JPS6132306B2 (ja) | ||
| JPS6125704B2 (ja) | ||
| JPS639505B2 (ja) | ||
| JPS6045873B2 (ja) | è³éŠæãŠã¬ã¿ã³ã®è£œé æ¹æ³ | |
| JPH035387B2 (ja) | ||
| JPS6116383B2 (ja) | ||
| JPS6124384B2 (ja) | ||
| JPS6056703B2 (ja) | ãŠã¬ã¿ã³ã®è£œé æ¹æ³ | |
| JPH0259827B2 (ja) | ||
| JPS58128358A (ja) | ãŠã¬ã¿ã³ã®è£œé æ¹æ³ | |
| JPS6310146B2 (ja) | ||
| JPS58146549A (ja) | ãŠã¬ã¿ã³ã®è£œé æ³ | |
| JPS6332346B2 (ja) | ||
| JPS6132307B2 (ja) | ||
| JPS6313431B2 (ja) | ||
| JPS6123181B2 (ja) | ||
| JPS58118552A (ja) | è³éŠæãŠã¬ã¿ã³ã®è£œé æ¹æ³ | |
| JPS58146547A (ja) | ãŠã¬ã¿ã³ã®è£œé æ¹æ³ | |
| JPS6154783B2 (ja) | ||
| JPH0417946B2 (ja) | ||
| JPS634820B2 (ja) | ||
| JPS6045874B2 (ja) | è³éŠæãŠã¬ã¿ã³ååç©ã®è£œé æ¹æ³ |