JPH08512347A - 汚れ放出剤を含んでなる洗剤組成物 - Google Patents
汚れ放出剤を含んでなる洗剤組成物Info
- Publication number
- JPH08512347A JPH08512347A JP7504014A JP50401495A JPH08512347A JP H08512347 A JPH08512347 A JP H08512347A JP 7504014 A JP7504014 A JP 7504014A JP 50401495 A JP50401495 A JP 50401495A JP H08512347 A JPH08512347 A JP H08512347A
- Authority
- JP
- Japan
- Prior art keywords
- ester
- units
- oxy
- soil release
- poly
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
- C08G63/688—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur
- C08G63/6884—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/6886—Dicarboxylic acids and dihydroxy compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3715—Polyesters or polycarbonates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1. 水溶性または水分散性の汚れ放出剤であって、 A) 分子量が500〜8,000の範囲にある実質的に線状のスルホン化した ポリ−エトキシ/プロポキシ末端キャップしたエステルであって、該エステルは モル基準で i) 1〜2モルの、式 (MO3S)(CH2)m(CH2CH2O)(RO)n− (式中、Mは、ナトリウムまたはテトラアルキルアンモニウムのような塩形成カ チオンであり、mは0または1であり、Rはエチレン、プロピレンまたはそれら の混合物であり、nは0〜2である)を有するスルホン化ポリ−エトキシ/プロ ポキシ末端キャッピング単位、およびその混合物、 ii) 0.5〜66モルの、 a) オキシエチレンオキシ単位、 b) オキシエチレンオキシおよびオキシ−1,2−プロピレンオキシ 単位の混合物であって、前記オキシエチレンオキシ単位が、オキシエチレンオキ シ対オキシ−1,2−プロピレンオキシのモル比が0.5:1〜10:1の範囲 で含まれているもの、および c) a)またはb)とポリ(オキシエチレン)オキシ単位との混合物であ って、前記ポリ(オキシエチレン)オキシ単位の重合度が2〜4であり、但し、 前記ポリ(オキシエチレン)オキシ単位の重合度が2であるときには、ポリ(オ キシエチレン)オキシ単位対群ii)の全単位のモル比が0:1〜0.33:1で あり、前記ポリ(オキシエチレン)オキシ単位の重合度が3であるときには、ポ リ(オキシエチレン)オキシ単位対群ii)の全単位のモル比が0:1〜0.22 :1であり、前記ポリ(オキシエチレン)オキシ単位の重合度が4であるときに は、 ポリ(オキシエチレン)オキシ単位対群ii)の全単位のモル比が0:1〜0.1 4:1であるもの、 からなる群から選択される単位、 iii) 1.5〜40モルのテレフタロイル単位、および iv) 0〜26モルの式−(O)C(C6H3)(SO3M)C(O)− (式中、Mは塩形成カチオンである)を有する5−スルホイソフタロイル単位か ら本質的になるものであり、該エステルを少なくとも10重量%と、そして B) 1種類以上の結晶化減少安定剤を、エステルに対して0.5重量%〜20 重量% 含んでなることを特徴とする、水溶性または水分散性の汚れ放出剤。 2. 結晶化減少安定剤が、 i) a) (R1)nAr−SO3M、 b) (R2)Ar(SO3M)−O−(R2)Ar(SO3M)、および c) それらの混合物であって、Arが芳香族炭化水素基であり、それぞ れのR1が水素ラジカルであるかまたはC1〜C4アルキル基であり、それぞれの R2がC1〜C18アルキル基であり、nが0〜3であり、Mがアルカリ金属また はテトラアルキルアンモニウムイオンであるもの からなる群から選択される芳香族スルホン酸または置換芳香族スルホン酸のアル カリ金属およびテトラアルキルアンモニウム塩、 ii) 線状または分岐アルキルベンゼンスルホン酸のアルカリ金属およびテ トラアルキルアンモニウム塩であって、アルキル基がC5〜C16、好ましくはC1 1 〜C13であるもの、 iii) 熱安定性を有するアルキル鎖スルホン酸であって、アルキル鎖が4〜 20個の炭素原子を含むもの、および iv) それらの混合物 からなる群から選択される、請求の範囲第1項に記載の汚れ放出剤。 3. 実験式(CAP)x(EG/PG)y(T) (式中、(CAP)は前記スルホン化末端キャッピング単位i)のナトリウム塩の 形態を表わし、(EG/PG)は、前記オキシエチレンオキシ、オキシ−1,2 −プロピレンオキシおよびポリ(オキシエチレン)オキシ単位ii)を表わし、 (T)は、前記テレフタロイル単位iii)を表わし、xは1〜2、好ましくは2で あり、yは0.5〜7、好ましくは1〜6であり、zは1.5〜7、好ましくは 2〜6であり、オキシエチレンオキシ:オキシ−1,2−プロピレンオキシのモ ル比は1:1〜10:1の範囲にあり、x、yおよびzは、前記エステル1モル 当たりの対応する単位のモル数の平均値を表わす)を有するエステル25重量% 〜100重量%を含む、請求の範囲第1項に記載の汚れ放出剤。 4. 実験式(CAP)x(EG/PG)y (T)z(SIP)q (式中、(CAP)は前記スルホン化末端キャッピング単位i)のナトリウム塩の 形態を表わし、(EG/PG)は、前記オキシエチレンオキシ、オキシ−1,2 −プロピレンオキシおよびポリ(オキシエチレン)オキシ単位ii)を表わし、 (T)は、前記テレフタロイル単位iii)を表わし、(SIP)は、前記5−スル ホイソフタロイル単位iv)のナトリウム塩の形態を表わし、xは1〜2、好まし くは2であり、yは0.5〜66、好ましくは3〜18、更に好ましくは5であ り、zは1.5〜40、好ましくは3〜15、更に好ましくは5であり、qは0 .05〜26、好ましくは0.5〜4、更に好ましくは1であり、オキシエチレ ンオキシ:オキシ−1,2−プロピレンオキシのモル比は0.5:1〜1:0の 範囲にあり、x,yおよびzは、前記エステル1モル当たりの対応する単位のモ ル数の平均値を表わす)を有するエステル25重量%〜100重量%を含む、請 求の範囲第1項に記載の汚れ放出剤。 5. 分子量が500〜5,000の範囲にある前記エステルを少なくとも5 0重量%と、前記安定剤を少なくとも3重量%とを含む、請求の範囲第3項また は第4項に記載の汚れ放出剤。 6. A) テレフタル酸ジメチル、 B) a) エチレングリコール、 b) エチレングリコールとプロピレングリコールとの混合物、 c) a)またはb)と、ジエチレングリコール、トリエチレングリコー ル、テトラエチレングリコール、またはそれらの混合物との混合物 からなる群から選択される1種類以上の反応物、 C) スルホイソフタル酸ジメチル、および D) 前記スルホン化ポリ−エトキシ/プロポキシ末端キャップの一価の カチオン塩からなる群から選択される化合物を、少なくとも1種類の通常のエス テル交換触媒および1種類以上の結晶化減少安定剤の存在下にて、反応させる1 段階を少なくとも含んでなる方法によって誘導される、請求の範囲第3項または 第4項に記載の水溶性または分散性の汚れ放出剤。 7. 布帛を洗濯して、同時に汚れ放出仕上を施す方法において、前記布帛を 、通常の洗剤成分、および請求の範囲第1項に記載の汚れ放出剤1〜50ppm を含む洗濯水溶液と接触させてなる、方法。 8. 前記の通常の洗剤成分が1種類以上の通常のアニオン性界面活性剤を含 み、前記汚れ放出剤が前記洗濯水溶液中に2.5〜30ppmの濃度で含まれて いる、請求の範囲第7項に記載の方法。 9. 前記布帛を、それぞれのサイクルが a) 前記の布帛を、通常の自動洗濯機でまたは手洗いによって、前記の洗濯 水溶液と約5分〜約1時間接触させ、 b) 前記布帛を水で濯ぎ、 c) 前記布帛をラインまたは回転乾燥し、 d) 前記布帛を、通常の着衣または家事使用により汚れに暴露する 順序の段階からなる2以上のサイクルに付す、請求の範囲第7項に記載の方法。 10. 洗剤用界面活性剤5重量%〜80重量%、および請求の範囲第1項、 第3項または第4項のいずれか1項に記載の汚れ放出剤を少なくとも0.1重量 %含んでなる、洗剤組成物。 11. 予備成型したペルオキシ酸漂白剤を更に含んでなる、請求の範囲第1 0項に記載の組成物。 12. 過酸素漂白剤、好ましくは過炭酸ナトリウム1%〜20%、および漂 白活性剤0.5%〜20%を更に含んでなる、請求の範囲第10項に記載の組成 物。 13. 前記界面活性剤がノニオン性の第一アルコールエトキシレートであり 、セルラーゼ酵素を少なくとも0.001%、および色素移り抑制剤0.5%〜 10%を更に含んでなる、請求の範囲第10項に記載の組成物。 14. 1種類以上の結晶化減少安定剤を、請求の範囲第1項、第3項または 第4項のいずれか1項に記載のオリゴマー性汚れ放出剤と組み合わせてなる、オ リゴマーエステルの結晶化を減少させる方法。 15. 結晶化減少安定剤が、 i) a) (R1)nAr−SO3M、 b) (R2)Ar(SO3M)−O−(R2)Ar(SO3M)、および c) それらの混合物であって、Arが芳香族炭化水素基であり、それぞれ のR1が水素ラジカルであるかまたはC1〜C4アルキル基であり、それぞれのR2 がC1〜C18アルキル基であり、nが0〜3であり、Mがアルカリ金属またはテ トラアルキルアンモニウムイオンであるもの からなる群から選択される芳香族スルホン酸または置換芳香族スルホン酸のアル カリ金属およびテトラアルキルアンモニウム塩、 ii) 線状または分岐アルキルベンゼンスルホン酸のアルカリ金属およびテ トラアルキルアンモニウム塩であって、アルキル基がC5〜C16、好ましくはC1 1 〜C13であるもの、 iii) 熱安定性を有するアルキル鎖スルホン酸であって、アルキル鎖が4〜 20個の炭素原子を含むもの、および iv) それらの混合物 からなる群から選択される、請求の範囲第14項に記載の方法。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US8870793A | 1993-07-08 | 1993-07-08 | |
US08/088,707 | 1993-07-08 | ||
US08/123,303 | 1993-09-17 | ||
US08/123,303 US5415807A (en) | 1993-07-08 | 1993-09-17 | Sulfonated poly-ethoxy/propoxy end-capped ester oligomers suitable as soil release agents in detergent compositions |
PCT/US1994/001527 WO1995002028A1 (en) | 1993-07-08 | 1994-02-10 | Detergent compositions comprising soil release agents |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH08512347A true JPH08512347A (ja) | 1996-12-24 |
Family
ID=26778972
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP7504014A Ceased JPH08512347A (ja) | 1993-07-08 | 1994-02-10 | 汚れ放出剤を含んでなる洗剤組成物 |
Country Status (16)
Country | Link |
---|---|
US (1) | US5415807A (ja) |
EP (1) | EP0707625B1 (ja) |
JP (1) | JPH08512347A (ja) |
CN (2) | CN1061368C (ja) |
AT (1) | ATE178936T1 (ja) |
AU (1) | AU6812694A (ja) |
BR (1) | BR9406947A (ja) |
CA (1) | CA2166275C (ja) |
CZ (1) | CZ4696A3 (ja) |
DE (1) | DE69417894T2 (ja) |
ES (1) | ES2132405T3 (ja) |
HU (1) | HUT74080A (ja) |
MX (1) | MX9401195A (ja) |
TR (1) | TR28128A (ja) |
TW (1) | TW282487B (ja) |
WO (1) | WO1995002028A1 (ja) |
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- 1993-09-17 US US08/123,303 patent/US5415807A/en not_active Expired - Lifetime
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1994
- 1994-02-10 BR BR9406947A patent/BR9406947A/pt not_active IP Right Cessation
- 1994-02-10 CN CN94193151A patent/CN1061368C/zh not_active Expired - Fee Related
- 1994-02-10 AT AT94916490T patent/ATE178936T1/de not_active IP Right Cessation
- 1994-02-10 DE DE69417894T patent/DE69417894T2/de not_active Expired - Lifetime
- 1994-02-10 ES ES94916490T patent/ES2132405T3/es not_active Expired - Lifetime
- 1994-02-10 HU HU9503745A patent/HUT74080A/hu unknown
- 1994-02-10 CA CA002166275A patent/CA2166275C/en not_active Expired - Fee Related
- 1994-02-10 WO PCT/US1994/001527 patent/WO1995002028A1/en active IP Right Grant
- 1994-02-10 JP JP7504014A patent/JPH08512347A/ja not_active Ceased
- 1994-02-10 AU AU68126/94A patent/AU6812694A/en not_active Abandoned
- 1994-02-10 EP EP94916490A patent/EP0707625B1/en not_active Expired - Lifetime
- 1994-02-10 CZ CZ9646A patent/CZ4696A3/cs unknown
- 1994-02-15 TR TR00120/94A patent/TR28128A/xx unknown
- 1994-02-15 MX MX9401195A patent/MX9401195A/es unknown
- 1994-03-18 TW TW083102377A patent/TW282487B/zh active
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HU9503745D0 (en) | 1996-02-28 |
TW282487B (ja) | 1996-08-01 |
CA2166275C (en) | 1999-09-28 |
EP0707625A1 (en) | 1996-04-24 |
BR9406947A (pt) | 1996-08-06 |
ES2132405T3 (es) | 1999-08-16 |
US5415807A (en) | 1995-05-16 |
EP0707625B1 (en) | 1999-04-14 |
AU6812694A (en) | 1995-02-06 |
ATE178936T1 (de) | 1999-04-15 |
DE69417894T2 (de) | 1999-11-25 |
MX9401195A (es) | 1995-01-31 |
TR28128A (tr) | 1996-01-30 |
CN1225385A (zh) | 1999-08-11 |
WO1995002028A1 (en) | 1995-01-19 |
DE69417894D1 (de) | 1999-05-20 |
CN1061368C (zh) | 2001-01-31 |
CA2166275A1 (en) | 1995-01-19 |
HUT74080A (en) | 1996-10-28 |
CN1129459A (zh) | 1996-08-21 |
CN1121484C (zh) | 2003-09-17 |
CZ4696A3 (en) | 1996-07-17 |
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