DE60327691D1 - Waschmittel mit blockcopolymer - Google Patents
Waschmittel mit blockcopolymerInfo
- Publication number
- DE60327691D1 DE60327691D1 DE60327691T DE60327691T DE60327691D1 DE 60327691 D1 DE60327691 D1 DE 60327691D1 DE 60327691 T DE60327691 T DE 60327691T DE 60327691 T DE60327691 T DE 60327691T DE 60327691 D1 DE60327691 D1 DE 60327691D1
- Authority
- DE
- Germany
- Prior art keywords
- block
- detergent
- block copolymer
- triblock copolymers
- copolymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3784—(Co)polymerised monomers containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/378—(Co)polymerised monomers containing sulfur, e.g. sulfonate
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US35606002P | 2002-02-11 | 2002-02-11 | |
PCT/EP2003/001317 WO2003068899A1 (en) | 2002-02-11 | 2003-02-11 | Detergent composition comprising a block copolymer |
Publications (1)
Publication Number | Publication Date |
---|---|
DE60327691D1 true DE60327691D1 (de) | 2009-07-02 |
Family
ID=27734600
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE60327691T Expired - Lifetime DE60327691D1 (de) | 2002-02-11 | 2003-02-11 | Waschmittel mit blockcopolymer |
Country Status (7)
Country | Link |
---|---|
US (3) | US20030158078A1 (de) |
EP (1) | EP1483362B2 (de) |
JP (1) | JP4538232B2 (de) |
AT (1) | ATE431844T1 (de) |
AU (1) | AU2003210236A1 (de) |
DE (1) | DE60327691D1 (de) |
WO (1) | WO2003068899A1 (de) |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040149311A1 (en) * | 2002-11-15 | 2004-08-05 | The Procter & Gamble Company | Method for cleaning cookware and tableware with film-forming liquid dishwashing compositions, and compositions therefore |
WO2004092316A1 (en) * | 2003-03-05 | 2004-10-28 | Rhodia, Inc. | Use of sulfonated polystyrene polymers in hard surface cleaners to provide easier cleaning benefit |
US20050049162A1 (en) * | 2003-08-29 | 2005-03-03 | Schlosser Ted M. | Petroleum-free, ammonia-free cleaner for firearms and ordnance |
US20060276371A1 (en) * | 2005-06-01 | 2006-12-07 | Anthony Schreiner | Coacervate systems having soil anti-adhesion and anti-deposition properties on hydrophilic surfaces |
DE102005026544A1 (de) * | 2005-06-08 | 2006-12-14 | Henkel Kgaa | Verstärkung der Reinigungsleistung von Waschmitteln durch Polymer |
DE102005041349A1 (de) * | 2005-08-31 | 2007-03-01 | Basf Ag | Reinigungsformulierungen für die maschinelle Geschirrreinigung enthaltend hydrophil modifizierte Polycarboxylate |
DE102005041347A1 (de) | 2005-08-31 | 2007-03-01 | Basf Ag | Reinigungsformulierungen für die maschinelle Geschirrreinigung enthaltend hydrophil modifizierte Polycarboxylate |
GB0522658D0 (en) * | 2005-11-07 | 2005-12-14 | Reckitt Benckiser Nv | Composition |
GB0625586D0 (en) * | 2006-12-21 | 2007-01-31 | Reckitt Benckiser Nv | Composition |
EP2152843A2 (de) * | 2007-04-27 | 2010-02-17 | Bernd Schwegmann Gmbh&co. Kg | Mischung, welche ein alkylpolyglucosid, ein cotensid und ein polymeres additiv umfasst |
ATE550417T1 (de) * | 2007-05-29 | 2012-04-15 | Procter & Gamble | Verfahren zum reinigen von geschirr |
NZ580429A (en) * | 2007-05-31 | 2012-04-27 | Sepracor Inc | Phenyl substituted cycloalkylamines as monoamine reuptake inhibitors |
WO2009060966A1 (en) * | 2007-11-09 | 2009-05-14 | Nippon Shokubai Co., Ltd. | Cleaning compositions with monocarboxylic acid monomers, dicarboxylic monomers, and monomers comprising sulfonic acid groups |
ES2568784T5 (es) * | 2008-01-04 | 2023-09-13 | Procter & Gamble | Una composición detergente para lavado de ropa que comprende glicosil hidrolasa |
US20090229629A1 (en) * | 2008-03-14 | 2009-09-17 | Air Products And Chemicals, Inc. | Stripper For Copper/Low k BEOL Clean |
CN101952351B (zh) * | 2008-03-31 | 2015-12-16 | 株式会社日本触媒 | 含磺酸基的马来酸类水溶性共聚物水溶液和通过干燥该水溶液获得的粉末 |
JP2012136694A (ja) * | 2010-12-27 | 2012-07-19 | Rohm & Haas Co | 高−界面活性剤配合物のためのポリマー |
US8740993B2 (en) | 2012-03-23 | 2014-06-03 | Ecolab Usa Inc. | Method for reduced encrustation of textiles using a polymer comprising maleic acid, vinyl acetate, and alkyl acrylate |
US8623151B2 (en) | 2012-03-23 | 2014-01-07 | Ecolab Usa Inc. | Terpolymer containing maleic acid, vinyl acetate, and alkyl acrylate monomers for aluminum protection |
DE102013106363B3 (de) * | 2013-06-18 | 2014-12-11 | Geting Solutions Gmbh | Mittel zur Entfernung von Flecken und Ablagerungen |
EP3039111B2 (de) | 2013-08-29 | 2021-03-03 | Colgate-Palmolive Company | Wässrige flüssige zusammensetzungen |
EP2896637A1 (de) * | 2014-01-21 | 2015-07-22 | Rhodia Operations | Copolymer mit Einheiten des Typs A, abgeleitet von Carbonsäuremonomeren und Einheiten von Typ B, abgeleitet von Sulfonsäuremonomeren |
USD815838S1 (en) | 2016-07-15 | 2018-04-24 | Colgate-Palmolive Company | Toothbrush |
US11292992B2 (en) * | 2017-10-23 | 2022-04-05 | Dow Global Technologies Llc | Gradient copolymers for use in automatic dishwashing systems |
CN108341956B (zh) * | 2018-01-31 | 2021-03-05 | 杭州美高华颐化工有限公司 | 一种涤棉通用型亚胺改性嵌段有机硅柔软剂的制备方法 |
CN113490699A (zh) * | 2019-02-28 | 2021-10-08 | 罗地亚经营管理公司 | 用于高度稳定乳液的组合物 |
US11912934B2 (en) | 2019-03-12 | 2024-02-27 | Rhodia Operations | Stabilized friction reducer emulsions |
Family Cites Families (68)
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US1985424A (en) * | 1933-03-23 | 1934-12-25 | Ici Ltd | Alkylene-oxide derivatives of polyhydroxyalkyl-alkylamides |
US2182306A (en) * | 1935-05-10 | 1939-12-05 | Ig Farbenindustrie Ag | Polymerization of ethylene imines |
US2208095A (en) * | 1937-01-05 | 1940-07-16 | Ig Farbenindustrie Ag | Process of producing insoluble condensation products containing sulphur and nitrogen |
US2553696A (en) * | 1944-01-12 | 1951-05-22 | Union Carbide & Carbon Corp | Method for making water-soluble polymers of lower alkylene imines |
US2703798A (en) * | 1950-05-25 | 1955-03-08 | Commercial Solvents Corp | Detergents from nu-monoalkyl-glucamines |
US2806839A (en) * | 1953-02-24 | 1957-09-17 | Arnold Hoffman & Co Inc | Preparation of polyimines from 2-oxazolidone |
US2792372A (en) * | 1954-09-15 | 1957-05-14 | Petrolite Corp | Process for breaking petroleum emulsions employing certain oxyalkylated higher polyethylene amines |
DE1072347B (de) | 1956-05-14 | |||
BE615597A (de) * | 1958-06-19 | |||
US3308067A (en) * | 1963-04-01 | 1967-03-07 | Procter & Gamble | Polyelectrolyte builders and detergent compositions |
US3646015A (en) * | 1969-07-31 | 1972-02-29 | Procter & Gamble | Optical brightener compounds and detergent and bleach compositions containing same |
US3812044A (en) * | 1970-12-28 | 1974-05-21 | Procter & Gamble | Detergent composition containing a polyfunctionally-substituted aromatic acid sequestering agent |
CA989557A (en) * | 1971-10-28 | 1976-05-25 | The Procter And Gamble Company | Compositions and process for imparting renewable soil release finish to polyester-containing fabrics |
GB1440913A (en) | 1972-07-12 | 1976-06-30 | Unilever Ltd | Detergent compositions |
US3959230A (en) * | 1974-06-25 | 1976-05-25 | The Procter & Gamble Company | Polyethylene oxide terephthalate polymers |
US3929678A (en) * | 1974-08-01 | 1975-12-30 | Procter & Gamble | Detergent composition having enhanced particulate soil removal performance |
US4000093A (en) * | 1975-04-02 | 1976-12-28 | The Procter & Gamble Company | Alkyl sulfate detergent compositions |
US4201824A (en) * | 1976-12-07 | 1980-05-06 | Rhone-Poulenc Industries | Hydrophilic polyurethanes and their application as soil-release, anti-soil redeposition, and anti-static agents for textile substrates |
US4228044A (en) * | 1978-06-26 | 1980-10-14 | The Procter & Gamble Company | Laundry detergent compositions having enhanced particulate soil removal and antiredeposition performance |
FR2407980A1 (fr) * | 1977-11-02 | 1979-06-01 | Rhone Poulenc Ind | Nouvelles compositions anti-salissure et anti-redeposition utilisables en detergence |
DE3277630D1 (en) | 1981-05-30 | 1987-12-17 | Procter & Gamble | Detergent composition containing performance additive and copolymeric compatibilizing agent therefor |
US4565647B1 (en) * | 1982-04-26 | 1994-04-05 | Procter & Gamble | Foaming surfactant compositions |
US4664848A (en) * | 1982-12-23 | 1987-05-12 | The Procter & Gamble Company | Detergent compositions containing cationic compounds having clay soil removal/anti-redeposition properties |
US4525524A (en) * | 1984-04-16 | 1985-06-25 | The Goodyear Tire & Rubber Company | Polyester composition |
US4790856A (en) * | 1984-10-17 | 1988-12-13 | Colgate-Palmolive Company | Softening and anti-static nonionic detergent composition with sulfosuccinamate detergent |
US4579681A (en) * | 1984-11-08 | 1986-04-01 | Gaf Corporation | Laundry detergent composition |
US4702857A (en) * | 1984-12-21 | 1987-10-27 | The Procter & Gamble Company | Block polyesters and like compounds useful as soil release agents in detergent compositions |
GB8504733D0 (en) | 1985-02-23 | 1985-03-27 | Procter & Gamble Ltd | Detergent compositions |
DE3536530A1 (de) * | 1985-10-12 | 1987-04-23 | Basf Ag | Verwendung von pfropfcopolymerisaten aus polyalkylenoxiden und vinylacetat als vergrauungsinhibitoren beim waschen und nachbehandeln von synthesefasern enthaltendem textilgut |
US4663071A (en) * | 1986-01-30 | 1987-05-05 | The Procter & Gamble Company | Ether carboxylate detergent builders and process for their preparation |
US4711730A (en) * | 1986-04-15 | 1987-12-08 | The Procter & Gamble Company | Capped 1,2-propylene terephthalate-polyoxyethylene terephthalate polyesters useful as soil release agents |
US4704233A (en) * | 1986-11-10 | 1987-11-03 | The Procter & Gamble Company | Detergent compositions containing ethylenediamine-N,N'-disuccinic acid |
US4721580A (en) * | 1987-01-07 | 1988-01-26 | The Procter & Gamble Company | Anionic end-capped oligomeric esters as soil release agents in detergent compositions |
US4877896A (en) * | 1987-10-05 | 1989-10-31 | The Procter & Gamble Company | Sulfoaroyl end-capped ester of oligomers suitable as soil-release agents in detergent compositions and fabric-conditioner articles |
US4787989A (en) * | 1988-01-13 | 1988-11-29 | Gaf Corporation | Anionic soil release compositions |
DE3826670C2 (de) | 1988-08-05 | 1994-11-17 | Framatome Connectors Int | Flachkontaktsteckhülse |
US4968451A (en) * | 1988-08-26 | 1990-11-06 | The Procter & Gamble Company | Soil release agents having allyl-derived sulfonated end caps |
US4956447A (en) * | 1989-05-19 | 1990-09-11 | The Procter & Gamble Company | Rinse-added fabric conditioning compositions containing fabric sofening agents and cationic polyester soil release polymers and preferred cationic soil release polymers therefor |
JPH0797779B2 (ja) | 1989-08-25 | 1995-10-18 | 松下電器産業株式会社 | 90度移相器とデータ受信機 |
GB8927361D0 (en) | 1989-12-04 | 1990-01-31 | Unilever Plc | Liquid detergents |
DE4016002A1 (de) | 1990-05-18 | 1991-11-21 | Basf Ag | Verwendung von wasserloeslichen oder wasserdispergierbaren gepfropften proteinen als zusatz zu wasch- und reinigungsmitteln |
CZ286994A3 (en) * | 1992-05-21 | 1995-08-16 | Unilever Nv | Copolymers and detergents containing thereof |
DE4237337A1 (de) * | 1992-11-05 | 1994-05-11 | Basf Ag | Blockcopolyacetale, Verfahren zu ihrer Herstellung und ihre Verwendung in Wasch- und Reinigungsmitteln |
GB9300983D0 (en) * | 1993-01-19 | 1993-03-10 | Unilever Plc | Machine dishwashing and rinse aid compositions |
US5431846A (en) * | 1993-05-20 | 1995-07-11 | Lever Brothers Company, Division Of Conopco, Inc. | Copolymers and detergent compositions containing them |
US5415807A (en) * | 1993-07-08 | 1995-05-16 | The Procter & Gamble Company | Sulfonated poly-ethoxy/propoxy end-capped ester oligomers suitable as soil release agents in detergent compositions |
CN1094515C (zh) | 1993-09-14 | 2002-11-20 | 普罗格特-甘布尔公司 | 洗碟用柔性含蛋白酶的液体或凝胶洗涤组合物 |
US5755992A (en) * | 1994-04-13 | 1998-05-26 | The Procter & Gamble Company | Detergents containing a surfactant and a delayed release peroxyacid bleach system |
US5691298A (en) * | 1994-12-14 | 1997-11-25 | The Procter & Gamble Company | Ester oligomers suitable as soil release agents in detergent compositions |
US5763548A (en) | 1995-03-31 | 1998-06-09 | Carnegie-Mellon University | (Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization |
CN1137144C (zh) | 1996-07-10 | 2004-02-04 | 纳幕尔杜邦公司 | 具有活性特征的聚合作用 |
GB9625884D0 (en) | 1996-12-12 | 1997-01-29 | Unilever Plc | Improvements relating to aqueous light duty cleaning compositions |
PL334376A1 (en) | 1996-12-20 | 2000-02-28 | Procter & Gamble | Washing up detergent compositions containing organic diamines |
FR2764892B1 (fr) | 1997-06-23 | 2000-03-03 | Rhodia Chimie Sa | Procede de synthese de polymeres a blocs |
WO1999003894A1 (en) | 1997-07-15 | 1999-01-28 | Ciba Specialty Chemicals Holding Inc. | Polymerizable compositions containing alkoxyamine compounds derived from nitroso- or nitrone compounds |
JPH11236593A (ja) * | 1997-12-17 | 1999-08-31 | Kao Corp | 洗浄剤組成物 |
WO1999031144A1 (en) | 1997-12-18 | 1999-06-24 | E.I. Du Pont De Nemours And Company | Polymerization process with living characteristics and polymers made therefrom |
FR2773161B1 (fr) | 1997-12-31 | 2000-01-21 | Rhodia Chimie Sa | Procede de synthese de polymeres a blocs |
US6812291B1 (en) | 1997-12-31 | 2004-11-02 | Rhodia Chimie | Method for block polymer synthesis by controlled radical polymerization from dithiocarbamate compounds |
DE19839054A1 (de) | 1998-08-28 | 2000-03-02 | Forschungszentrum Juelich Gmbh | Verfahren zur Effizienzsteigerung von Tensiden bei simultaner Unterdrückung lamellarer Mesophasen sowie Tenside, welchen ein Additiv beigefügt ist |
ES2293899T3 (es) * | 1999-05-26 | 2008-04-01 | THE PROCTER & GAMBLE COMPANY | Composiciones detergentes liquidas que comprenden potenciadores de las jabonaduras de tipo polimero de bloques. |
FR2794463B1 (fr) * | 1999-06-04 | 2005-02-25 | Rhodia Chimie Sa | Procede de synthese de polymeres par polymerisation radicalaire controlee a l'aide de xanthates halogenes |
US6410005B1 (en) * | 2000-06-15 | 2002-06-25 | Pmd Holdings Corp. | Branched/block copolymers for treatment of keratinous substrates |
DE10029696A1 (de) * | 2000-06-16 | 2001-12-20 | Basf Ag | Waschaktive Zubereitung |
FR2811885B1 (fr) * | 2000-07-18 | 2003-06-06 | Oreal | Composition cosmetique contenant un copolymere sequence constitue de sequences a indices de refraction differents |
FR2812293B1 (fr) * | 2000-07-28 | 2002-12-27 | Rhodia Chimie Sa | Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee |
FR2814168B1 (fr) * | 2000-09-18 | 2006-11-17 | Rhodia Chimie Sa | Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee en presence d'un compose disulfure |
US6569969B2 (en) | 2000-09-28 | 2003-05-27 | Symyx Technologies, Inc. | Control agents for living-type free radical polymerization, methods of polymerizing and polymers with same |
-
2003
- 2003-02-11 EP EP03739467A patent/EP1483362B2/de not_active Expired - Lifetime
- 2003-02-11 JP JP2003568014A patent/JP4538232B2/ja not_active Expired - Fee Related
- 2003-02-11 AU AU2003210236A patent/AU2003210236A1/en not_active Abandoned
- 2003-02-11 AT AT03739467T patent/ATE431844T1/de not_active IP Right Cessation
- 2003-02-11 US US10/364,224 patent/US20030158078A1/en not_active Abandoned
- 2003-02-11 DE DE60327691T patent/DE60327691D1/de not_active Expired - Lifetime
- 2003-02-11 WO PCT/EP2003/001317 patent/WO2003068899A1/en active Application Filing
-
2006
- 2006-04-13 US US11/403,761 patent/US20060183661A1/en not_active Abandoned
-
2009
- 2009-02-20 US US12/390,233 patent/US8192552B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
AU2003210236A1 (en) | 2003-09-04 |
US8192552B2 (en) | 2012-06-05 |
WO2003068899A1 (en) | 2003-08-21 |
US20090186794A1 (en) | 2009-07-23 |
JP4538232B2 (ja) | 2010-09-08 |
JP2005517765A (ja) | 2005-06-16 |
EP1483362B1 (de) | 2009-05-20 |
EP1483362B2 (de) | 2012-12-26 |
US20030158078A1 (en) | 2003-08-21 |
US20060183661A1 (en) | 2006-08-17 |
ATE431844T1 (de) | 2009-06-15 |
EP1483362A1 (de) | 2004-12-08 |
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