JPH0339525B2 - - Google Patents
Info
- Publication number
- JPH0339525B2 JPH0339525B2 JP22895184A JP22895184A JPH0339525B2 JP H0339525 B2 JPH0339525 B2 JP H0339525B2 JP 22895184 A JP22895184 A JP 22895184A JP 22895184 A JP22895184 A JP 22895184A JP H0339525 B2 JPH0339525 B2 JP H0339525B2
- Authority
- JP
- Japan
- Prior art keywords
- butene
- copolymer
- based random
- random copolymer
- titanium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 207
- 229920005604 random copolymer Polymers 0.000 claims description 66
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 claims description 24
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 21
- 239000004711 α-olefin Substances 0.000 claims description 18
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 17
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims description 17
- 238000009835 boiling Methods 0.000 claims description 17
- 125000004432 carbon atom Chemical group C* 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 17
- 239000012046 mixed solvent Substances 0.000 claims description 10
- 238000002844 melting Methods 0.000 claims description 7
- 230000008018 melting Effects 0.000 claims description 7
- 150000001336 alkenes Chemical class 0.000 claims description 6
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 claims description 6
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 6
- 238000002441 X-ray diffraction Methods 0.000 claims description 4
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 description 65
- 239000010936 titanium Substances 0.000 description 45
- 239000003054 catalyst Substances 0.000 description 35
- 229910052719 titanium Inorganic materials 0.000 description 31
- -1 polypropylene Polymers 0.000 description 29
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 28
- 150000001875 compounds Chemical class 0.000 description 27
- 150000002681 magnesium compounds Chemical class 0.000 description 23
- 150000003609 titanium compounds Chemical class 0.000 description 20
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 16
- 229910052736 halogen Inorganic materials 0.000 description 15
- 150000002367 halogens Chemical class 0.000 description 14
- 238000006116 polymerization reaction Methods 0.000 description 14
- 230000035882 stress Effects 0.000 description 14
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 12
- 229920000642 polymer Polymers 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- 125000005234 alkyl aluminium group Chemical group 0.000 description 9
- 238000007334 copolymerization reaction Methods 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- 238000000465 moulding Methods 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 9
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 9
- 229920005989 resin Polymers 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 8
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 8
- 150000001991 dicarboxylic acids Chemical class 0.000 description 8
- 238000009826 distribution Methods 0.000 description 8
- 229910052749 magnesium Inorganic materials 0.000 description 8
- 239000011777 magnesium Substances 0.000 description 8
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 7
- 230000000903 blocking effect Effects 0.000 description 7
- 150000005690 diesters Chemical class 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 230000032683 aging Effects 0.000 description 6
- 235000010210 aluminium Nutrition 0.000 description 6
- 150000002430 hydrocarbons Chemical group 0.000 description 6
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 239000013078 crystal Substances 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 150000003961 organosilicon compounds Chemical class 0.000 description 5
- 230000000704 physical effect Effects 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 5
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 5
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 4
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical class OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Chemical group OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 4
- 125000004429 atom Chemical group 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 4
- 238000000605 extraction Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000007791 liquid phase Substances 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000011976 maleic acid Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 150000003377 silicon compounds Chemical class 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 2
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 2
- HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 description 2
- OEUSNWDYXDEXDR-UHFFFAOYSA-N 1h-pyrrole-2,3-dicarboxylic acid Chemical compound OC(=O)C=1C=CNC=1C(O)=O OEUSNWDYXDEXDR-UHFFFAOYSA-N 0.000 description 2
- RYPKRALMXUUNKS-UHFFFAOYSA-N 2-Hexene Natural products CCCC=CC RYPKRALMXUUNKS-UHFFFAOYSA-N 0.000 description 2
- WXUAQHNMJWJLTG-UHFFFAOYSA-N 2-methylbutanedioic acid Chemical compound OC(=O)C(C)CC(O)=O WXUAQHNMJWJLTG-UHFFFAOYSA-N 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 229910010199 LiAl Inorganic materials 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000002723 alicyclic group Chemical group 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical group O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 2
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 2
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- ZZNQQQWFKKTOSD-UHFFFAOYSA-N diethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OCC)(OCC)C1=CC=CC=C1 ZZNQQQWFKKTOSD-UHFFFAOYSA-N 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- MGDOJPNDRJNJBK-UHFFFAOYSA-N ethylaluminum Chemical compound [Al].C[CH2] MGDOJPNDRJNJBK-UHFFFAOYSA-N 0.000 description 2
- 239000001530 fumaric acid Chemical class 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 150000002366 halogen compounds Chemical class 0.000 description 2
- 239000012456 homogeneous solution Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 150000002689 maleic acids Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- VAMFXQBUQXONLZ-UHFFFAOYSA-N n-alpha-eicosene Natural products CCCCCCCCCCCCCCCCCCC=C VAMFXQBUQXONLZ-UHFFFAOYSA-N 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- 229920006280 packaging film Polymers 0.000 description 2
- 239000012785 packaging film Substances 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- GJAWHXHKYYXBSV-UHFFFAOYSA-N quinolinic acid Chemical compound OC(=O)C1=CC=CN=C1C(O)=O GJAWHXHKYYXBSV-UHFFFAOYSA-N 0.000 description 2
- 239000012429 reaction media Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 235000011044 succinic acid Nutrition 0.000 description 2
- 238000009864 tensile test Methods 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- DENFJSAFJTVPJR-UHFFFAOYSA-N triethoxy(ethyl)silane Chemical compound CCO[Si](CC)(OCC)OCC DENFJSAFJTVPJR-UHFFFAOYSA-N 0.000 description 2
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 2
- JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 description 2
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 2
- ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- AFINAILKDBCXMX-PBHICJAKSA-N (2s,3r)-2-amino-3-hydroxy-n-(4-octylphenyl)butanamide Chemical compound CCCCCCCCC1=CC=C(NC(=O)[C@@H](N)[C@@H](C)O)C=C1 AFINAILKDBCXMX-PBHICJAKSA-N 0.000 description 1
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 1
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 1
- FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-naphthoquinone Chemical compound C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 description 1
- 229940106006 1-eicosene Drugs 0.000 description 1
- FIKTURVKRGQNQD-UHFFFAOYSA-N 1-eicosene Natural products CCCCCCCCCCCCCCCCCC=CC(O)=O FIKTURVKRGQNQD-UHFFFAOYSA-N 0.000 description 1
- MBNROFBGTNXXMX-UHFFFAOYSA-N 1h-indole-2,3-dicarboxylic acid Chemical compound C1=CC=C2C(C(O)=O)=C(C(=O)O)NC2=C1 MBNROFBGTNXXMX-UHFFFAOYSA-N 0.000 description 1
- XVNUKANXEBCRAC-UHFFFAOYSA-N 2,3-dihydrofuran-4,5-dicarboxylic acid Chemical compound OC(=O)C1=C(C(O)=O)OCC1 XVNUKANXEBCRAC-UHFFFAOYSA-N 0.000 description 1
- KLZYRCVPDWTZLH-UHFFFAOYSA-N 2,3-dimethylsuccinic acid Chemical compound OC(=O)C(C)C(C)C(O)=O KLZYRCVPDWTZLH-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- FDYJJKHDNNVUDR-UHFFFAOYSA-N 2-ethyl-2-methylbutanedioic acid Chemical compound CCC(C)(C(O)=O)CC(O)=O FDYJJKHDNNVUDR-UHFFFAOYSA-N 0.000 description 1
- RVHOBHMAPRVOLO-UHFFFAOYSA-N 2-ethylbutanedioic acid Chemical compound CCC(C(O)=O)CC(O)=O RVHOBHMAPRVOLO-UHFFFAOYSA-N 0.000 description 1
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 1
- 239000004808 2-ethylhexylester Substances 0.000 description 1
- CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 description 1
- DQEUFPARIOFOAI-UHFFFAOYSA-N 2-propan-2-ylpropanedioic acid Chemical compound CC(C)C(C(O)=O)C(O)=O DQEUFPARIOFOAI-UHFFFAOYSA-N 0.000 description 1
- PFANXOISJYKQRP-UHFFFAOYSA-N 2-tert-butyl-4-[1-(5-tert-butyl-4-hydroxy-2-methylphenyl)butyl]-5-methylphenol Chemical compound C=1C(C(C)(C)C)=C(O)C=C(C)C=1C(CCC)C1=CC(C(C)(C)C)=C(O)C=C1C PFANXOISJYKQRP-UHFFFAOYSA-N 0.000 description 1
- QEKTUWKOACIUSM-UHFFFAOYSA-N 2h-chromene-3,4-dicarboxylic acid Chemical compound C1=CC=C2OCC(C(=O)O)=C(C(O)=O)C2=C1 QEKTUWKOACIUSM-UHFFFAOYSA-N 0.000 description 1
- KSCAZPYHLGGNPZ-UHFFFAOYSA-N 3-chloropropyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)CCCCl KSCAZPYHLGGNPZ-UHFFFAOYSA-N 0.000 description 1
- LDTAOIUHUHHCMU-UHFFFAOYSA-N 3-methylpent-1-ene Chemical compound CCC(C)C=C LDTAOIUHUHHCMU-UHFFFAOYSA-N 0.000 description 1
- ZDZVKPXKLLLOOA-UHFFFAOYSA-N Allylmalonic acid Chemical compound OC(=O)C(C(O)=O)CC=C ZDZVKPXKLLLOOA-UHFFFAOYSA-N 0.000 description 1
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Natural products OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 1
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 description 1
- YVUCTVVBKZTOPU-UHFFFAOYSA-N C(C)(C)O[SiH3].C(C)[Si](OCC)(OCC)OCC Chemical compound C(C)(C)O[SiH3].C(C)[Si](OCC)(OCC)OCC YVUCTVVBKZTOPU-UHFFFAOYSA-N 0.000 description 1
- CDUJMDNHYLCBJI-UHFFFAOYSA-N C(CCC)[O-].C(CCC)[Al+2].C(CCC)[O-].C(CCC)[O-].C(CCC)[Al+2] Chemical compound C(CCC)[O-].C(CCC)[Al+2].C(CCC)[O-].C(CCC)[O-].C(CCC)[Al+2] CDUJMDNHYLCBJI-UHFFFAOYSA-N 0.000 description 1
- XBVQSAIISGFAAS-UHFFFAOYSA-N CC(C)O[Mg] Chemical compound CC(C)O[Mg] XBVQSAIISGFAAS-UHFFFAOYSA-N 0.000 description 1
- ZNEGVQGQHBETJB-UHFFFAOYSA-M CC=1C(=C(O[Mg])C=CC=1)C Chemical compound CC=1C(=C(O[Mg])C=CC=1)C ZNEGVQGQHBETJB-UHFFFAOYSA-M 0.000 description 1
- ZPHMYHCMBKTAND-UHFFFAOYSA-N CCCCC(CC)CO[Mg] Chemical compound CCCCC(CC)CO[Mg] ZPHMYHCMBKTAND-UHFFFAOYSA-N 0.000 description 1
- UDISFXVHGUKXSU-UHFFFAOYSA-N CCCCCCCCCC[Mg]CCCCCCCCCC Chemical compound CCCCCCCCCC[Mg]CCCCCCCCCC UDISFXVHGUKXSU-UHFFFAOYSA-N 0.000 description 1
- ZKCNZMISGOLOOY-UHFFFAOYSA-N CCCCCCCCO[Mg] Chemical compound CCCCCCCCO[Mg] ZKCNZMISGOLOOY-UHFFFAOYSA-N 0.000 description 1
- UNCRKDFOOFDWDK-UHFFFAOYSA-N CCCCC[Mg]CCCCC Chemical compound CCCCC[Mg]CCCCC UNCRKDFOOFDWDK-UHFFFAOYSA-N 0.000 description 1
- HIDWBDFPTDXCHL-UHFFFAOYSA-N CCCCO[Mg] Chemical compound CCCCO[Mg] HIDWBDFPTDXCHL-UHFFFAOYSA-N 0.000 description 1
- MVECFARLYQAUNR-UHFFFAOYSA-N CCCC[Mg]CC Chemical compound CCCC[Mg]CC MVECFARLYQAUNR-UHFFFAOYSA-N 0.000 description 1
- RYWDKWWDJJOYEA-UHFFFAOYSA-N CCCC[Mg]OCC Chemical compound CCCC[Mg]OCC RYWDKWWDJJOYEA-UHFFFAOYSA-N 0.000 description 1
- ABXKXVWOKXSBNR-UHFFFAOYSA-N CCC[Mg]CCC Chemical compound CCC[Mg]CCC ABXKXVWOKXSBNR-UHFFFAOYSA-N 0.000 description 1
- ZFAGXQVYYWOLNK-UHFFFAOYSA-N CCO[Mg] Chemical compound CCO[Mg] ZFAGXQVYYWOLNK-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- 239000004805 Cyclohexane-1,2-dicarboxylic acid Substances 0.000 description 1
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- ZDQWESQEGGJUCH-UHFFFAOYSA-N Diisopropyl adipate Chemical compound CC(C)OC(=O)CCCCC(=O)OC(C)C ZDQWESQEGGJUCH-UHFFFAOYSA-N 0.000 description 1
- 239000003508 Dilauryl thiodipropionate Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-N Formic acid Chemical class OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical class [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 229920003182 Surlyn® Polymers 0.000 description 1
- 229910003074 TiCl4 Inorganic materials 0.000 description 1
- 229910010386 TiI4 Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 238000002083 X-ray spectrum Methods 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- OHLJPYMGJFINNA-UHFFFAOYSA-M [Cl-].CCCCC[Mg+] Chemical compound [Cl-].CCCCC[Mg+] OHLJPYMGJFINNA-UHFFFAOYSA-M 0.000 description 1
- XFJNAOUAGWZUHZ-UHFFFAOYSA-M [Mg+]C.[O-]C1=CC=CC=C1 Chemical compound [Mg+]C.[O-]C1=CC=CC=C1 XFJNAOUAGWZUHZ-UHFFFAOYSA-M 0.000 description 1
- TZSQRHNPVPIZHV-UHFFFAOYSA-M [Mg]OC1=CC=CC=C1 Chemical compound [Mg]OC1=CC=CC=C1 TZSQRHNPVPIZHV-UHFFFAOYSA-M 0.000 description 1
- SZNWCVFYBNVQOI-UHFFFAOYSA-N [O-]CC.C(C)[Al+2].[O-]CC.[O-]CC.C(C)[Al+2] Chemical compound [O-]CC.C(C)[Al+2].[O-]CC.[O-]CC.C(C)[Al+2] SZNWCVFYBNVQOI-UHFFFAOYSA-N 0.000 description 1
- NOZAQBYNLKNDRT-UHFFFAOYSA-N [diacetyloxy(ethenyl)silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)C=C NOZAQBYNLKNDRT-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- CGBYBGVMDAPUIH-UHFFFAOYSA-N acide dimethylmaleique Natural products OC(=O)C(C)=C(C)C(O)=O CGBYBGVMDAPUIH-UHFFFAOYSA-N 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000004103 aminoalkyl group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- LJWBIAMZBJWAOW-UHFFFAOYSA-N benzhydryloxysilane Chemical compound C=1C=CC=CC=1C(O[SiH3])C1=CC=CC=C1 LJWBIAMZBJWAOW-UHFFFAOYSA-N 0.000 description 1
- NIDNOXCRFUCAKQ-UHFFFAOYSA-N bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2C(O)=O NIDNOXCRFUCAKQ-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- YKGYQYOQRGPFTO-UHFFFAOYSA-N bis(8-methylnonyl) hexanedioate Chemical compound CC(C)CCCCCCCOC(=O)CCCCC(=O)OCCCCCCCC(C)C YKGYQYOQRGPFTO-UHFFFAOYSA-N 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- XGZGKDQVCBHSGI-UHFFFAOYSA-N butyl(triethoxy)silane Chemical compound CCCC[Si](OCC)(OCC)OCC XGZGKDQVCBHSGI-UHFFFAOYSA-N 0.000 description 1
- OCFSGVNHPVWWKD-UHFFFAOYSA-N butylaluminum Chemical compound [Al].[CH2]CCC OCFSGVNHPVWWKD-UHFFFAOYSA-N 0.000 description 1
- QQHRHLXGCZWTDK-UHFFFAOYSA-L butylaluminum(2+);dibromide Chemical compound [Br-].[Br-].CCCC[Al+2] QQHRHLXGCZWTDK-UHFFFAOYSA-L 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- JEZFASCUIZYYEV-UHFFFAOYSA-N chloro(triethoxy)silane Chemical compound CCO[Si](Cl)(OCC)OCC JEZFASCUIZYYEV-UHFFFAOYSA-N 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- IFDVQVHZEKPUSC-UHFFFAOYSA-N cyclohex-3-ene-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCC=CC1C(O)=O IFDVQVHZEKPUSC-UHFFFAOYSA-N 0.000 description 1
- ILUAAIDVFMVTAU-UHFFFAOYSA-N cyclohex-4-ene-1,2-dicarboxylic acid Chemical compound OC(=O)C1CC=CCC1C(O)=O ILUAAIDVFMVTAU-UHFFFAOYSA-N 0.000 description 1
- QSAWQNUELGIYBC-UHFFFAOYSA-N cyclohexane-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCCCC1C(O)=O QSAWQNUELGIYBC-UHFFFAOYSA-N 0.000 description 1
- YZFOGXKZTWZVFN-UHFFFAOYSA-N cyclopentane-1,1-dicarboxylic acid Chemical compound OC(=O)C1(C(O)=O)CCCC1 YZFOGXKZTWZVFN-UHFFFAOYSA-N 0.000 description 1
- ASJCSAKCMTWGAH-UHFFFAOYSA-N cyclopentane-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCCC1C(O)=O ASJCSAKCMTWGAH-UHFFFAOYSA-N 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
- KBLZFQBDODEHJH-UHFFFAOYSA-N dibutylalumane Chemical compound C(CCC)[AlH]CCCC KBLZFQBDODEHJH-UHFFFAOYSA-N 0.000 description 1
- VTZJFPSWNQFPCQ-UHFFFAOYSA-N dibutylaluminum Chemical compound CCCC[Al]CCCC VTZJFPSWNQFPCQ-UHFFFAOYSA-N 0.000 description 1
- RFUDQCRVCDXBGK-UHFFFAOYSA-L dichloro(propyl)alumane Chemical compound [Cl-].[Cl-].CCC[Al+2] RFUDQCRVCDXBGK-UHFFFAOYSA-L 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- HJXBDPDUCXORKZ-UHFFFAOYSA-N diethylalumane Chemical compound CC[AlH]CC HJXBDPDUCXORKZ-UHFFFAOYSA-N 0.000 description 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
- KEVMYFLMMDUPJE-UHFFFAOYSA-N diisoamyl Natural products CC(C)CCCCC(C)C KEVMYFLMMDUPJE-UHFFFAOYSA-N 0.000 description 1
- 235000019304 dilauryl thiodipropionate Nutrition 0.000 description 1
- JJQZDUKDJDQPMQ-UHFFFAOYSA-N dimethoxy(dimethyl)silane Chemical compound CO[Si](C)(C)OC JJQZDUKDJDQPMQ-UHFFFAOYSA-N 0.000 description 1
- AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 description 1
- CVQVSVBUMVSJES-UHFFFAOYSA-N dimethoxy-methyl-phenylsilane Chemical compound CO[Si](C)(OC)C1=CC=CC=C1 CVQVSVBUMVSJES-UHFFFAOYSA-N 0.000 description 1
- YYLGKUPAFFKGRQ-UHFFFAOYSA-N dimethyldiethoxysilane Chemical compound CCO[Si](C)(C)OCC YYLGKUPAFFKGRQ-UHFFFAOYSA-N 0.000 description 1
- KZLUHGRPVSRSHI-UHFFFAOYSA-N dimethylmagnesium Chemical compound C[Mg]C KZLUHGRPVSRSHI-UHFFFAOYSA-N 0.000 description 1
- CGBYBGVMDAPUIH-ARJAWSKDSA-N dimethylmaleic acid Chemical compound OC(=O)C(/C)=C(/C)C(O)=O CGBYBGVMDAPUIH-ARJAWSKDSA-N 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 229940069096 dodecene Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- WOXXJEVNDJOOLV-UHFFFAOYSA-N ethenyl-tris(2-methoxyethoxy)silane Chemical compound COCCO[Si](OCCOC)(OCCOC)C=C WOXXJEVNDJOOLV-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- GCPCLEKQVMKXJM-UHFFFAOYSA-N ethoxy(diethyl)alumane Chemical compound CCO[Al](CC)CC GCPCLEKQVMKXJM-UHFFFAOYSA-N 0.000 description 1
- RSIHJDGMBDPTIM-UHFFFAOYSA-N ethoxy(trimethyl)silane Chemical compound CCO[Si](C)(C)C RSIHJDGMBDPTIM-UHFFFAOYSA-N 0.000 description 1
- SBRXLTRZCJVAPH-UHFFFAOYSA-N ethyl(trimethoxy)silane Chemical compound CC[Si](OC)(OC)OC SBRXLTRZCJVAPH-UHFFFAOYSA-N 0.000 description 1
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- UKFXDFUAPNAMPJ-UHFFFAOYSA-N ethylmalonic acid Chemical compound CCC(C(O)=O)C(O)=O UKFXDFUAPNAMPJ-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- SYLAFCZSYRXBJF-UHFFFAOYSA-N furan-3,4-dicarboxylic acid Chemical compound OC(=O)C1=COC=C1C(O)=O SYLAFCZSYRXBJF-UHFFFAOYSA-N 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 125000001188 haloalkyl group Chemical group 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- UWNADWZGEHDQAB-UHFFFAOYSA-N i-Pr2C2H4i-Pr2 Natural products CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- TYQCGQRIZGCHNB-JLAZNSOCSA-N l-ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(O)=C(O)C1=O TYQCGQRIZGCHNB-JLAZNSOCSA-N 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- OTCKOJUMXQWKQG-UHFFFAOYSA-L magnesium bromide Chemical compound [Mg+2].[Br-].[Br-] OTCKOJUMXQWKQG-UHFFFAOYSA-L 0.000 description 1
- 229910001623 magnesium bromide Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- ORUIBWPALBXDOA-UHFFFAOYSA-L magnesium fluoride Chemical compound [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 description 1
- 229910001635 magnesium fluoride Inorganic materials 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- BLQJIBCZHWBKSL-UHFFFAOYSA-L magnesium iodide Chemical compound [Mg+2].[I-].[I-] BLQJIBCZHWBKSL-UHFFFAOYSA-L 0.000 description 1
- 229910001641 magnesium iodide Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- KJJBSBKRXUVBMX-UHFFFAOYSA-N magnesium;butane Chemical compound [Mg+2].CCC[CH2-].CCC[CH2-] KJJBSBKRXUVBMX-UHFFFAOYSA-N 0.000 description 1
- QUXHCILOWRXCEO-UHFFFAOYSA-M magnesium;butane;chloride Chemical compound [Mg+2].[Cl-].CCC[CH2-] QUXHCILOWRXCEO-UHFFFAOYSA-M 0.000 description 1
- YJCTUQFSSZSZPO-UHFFFAOYSA-L magnesium;chloride;phenoxide Chemical compound [Cl-].[Mg+]OC1=CC=CC=C1 YJCTUQFSSZSZPO-UHFFFAOYSA-L 0.000 description 1
- BJZBHTNKDCBDNQ-UHFFFAOYSA-L magnesium;dodecanoate Chemical compound [Mg+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O BJZBHTNKDCBDNQ-UHFFFAOYSA-L 0.000 description 1
- DLPASUVGCQPFFO-UHFFFAOYSA-N magnesium;ethane Chemical compound [Mg+2].[CH2-]C.[CH2-]C DLPASUVGCQPFFO-UHFFFAOYSA-N 0.000 description 1
- YCCXQARVHOPWFJ-UHFFFAOYSA-M magnesium;ethane;chloride Chemical compound [Mg+2].[Cl-].[CH2-]C YCCXQARVHOPWFJ-UHFFFAOYSA-M 0.000 description 1
- KRTCPMDBLDWJQY-UHFFFAOYSA-M magnesium;ethanolate;chloride Chemical compound [Mg+2].[Cl-].CC[O-] KRTCPMDBLDWJQY-UHFFFAOYSA-M 0.000 description 1
- RVOYYLUVELMWJF-UHFFFAOYSA-N magnesium;hexane Chemical compound [Mg+2].CCCCC[CH2-].CCCCC[CH2-] RVOYYLUVELMWJF-UHFFFAOYSA-N 0.000 description 1
- GBRJQTLHXWRDOV-UHFFFAOYSA-M magnesium;hexane;chloride Chemical compound [Mg+2].[Cl-].CCCCC[CH2-] GBRJQTLHXWRDOV-UHFFFAOYSA-M 0.000 description 1
- ZHLDMBMNKCIBQN-UHFFFAOYSA-M magnesium;methanolate;chloride Chemical compound [Cl-].CO[Mg+] ZHLDMBMNKCIBQN-UHFFFAOYSA-M 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- CFXDAHURBQNVFG-UHFFFAOYSA-M magnesium;propan-2-olate;chloride Chemical compound [Mg+2].[Cl-].CC(C)[O-] CFXDAHURBQNVFG-UHFFFAOYSA-M 0.000 description 1
- RYEXTBOQKFUPOE-UHFFFAOYSA-M magnesium;propane;chloride Chemical compound [Mg+2].[Cl-].CC[CH2-] RYEXTBOQKFUPOE-UHFFFAOYSA-M 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 150000002691 malonic acids Chemical class 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 229920001179 medium density polyethylene Polymers 0.000 description 1
- 239000004701 medium-density polyethylene Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- POPACFLNWGUDSR-UHFFFAOYSA-N methoxy(trimethyl)silane Chemical compound CO[Si](C)(C)C POPACFLNWGUDSR-UHFFFAOYSA-N 0.000 description 1
- PFAUUICEGIRNHU-UHFFFAOYSA-N methyl(phenylmethoxy)silicon Chemical compound C[Si]OCC1=CC=CC=C1 PFAUUICEGIRNHU-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- ZIYVHBGGAOATLY-UHFFFAOYSA-N methylmalonic acid Chemical compound OC(=O)C(C)C(O)=O ZIYVHBGGAOATLY-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- CNWUDMDXRVLRRB-UHFFFAOYSA-N n-[diethoxy(phenyl)silyl]-n-ethylethanamine Chemical compound CCO[Si](OCC)(N(CC)CC)C1=CC=CC=C1 CNWUDMDXRVLRRB-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- KHARCSTZAGNHOT-UHFFFAOYSA-N naphthalene-2,3-dicarboxylic acid Chemical compound C1=CC=C2C=C(C(O)=O)C(C(=O)O)=CC2=C1 KHARCSTZAGNHOT-UHFFFAOYSA-N 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229960005235 piperonyl butoxide Drugs 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- OBRKWFIGZSMARO-UHFFFAOYSA-N propylalumane Chemical compound [AlH2]CCC OBRKWFIGZSMARO-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- WWYDYZMNFQIYPT-UHFFFAOYSA-N ru78191 Chemical compound OC(=O)C(C(O)=O)C1=CC=CC=C1 WWYDYZMNFQIYPT-UHFFFAOYSA-N 0.000 description 1
- JIYNFFGKZCOPKN-UHFFFAOYSA-N sbb061129 Chemical compound O=C1OC(=O)C2C1C1C=C(C)C2C1 JIYNFFGKZCOPKN-UHFFFAOYSA-N 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 150000003444 succinic acids Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- LCZVKKUAUWQDPX-UHFFFAOYSA-N tert-butyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]amino]ethyl]amino]acetate Chemical compound CC(=O)OC1=CC=CC=C1CN(CC(=O)OC(C)(C)C)CCN(CC(=O)OC(C)(C)C)CC1=CC=CC=C1OC(C)=O LCZVKKUAUWQDPX-UHFFFAOYSA-N 0.000 description 1
- UQMOLLPKNHFRAC-UHFFFAOYSA-N tetrabutyl silicate Chemical compound CCCCO[Si](OCCCC)(OCCCC)OCCCC UQMOLLPKNHFRAC-UHFFFAOYSA-N 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- ZWWLLYJRPKYTDF-UHFFFAOYSA-N thiophene-3,4-dicarboxylic acid Chemical compound OC(=O)C1=CSC=C1C(O)=O ZWWLLYJRPKYTDF-UHFFFAOYSA-N 0.000 description 1
- UBZYKBZMAMTNKW-UHFFFAOYSA-J titanium tetrabromide Chemical compound Br[Ti](Br)(Br)Br UBZYKBZMAMTNKW-UHFFFAOYSA-J 0.000 description 1
- NLLZTRMHNHVXJJ-UHFFFAOYSA-J titanium tetraiodide Chemical compound I[Ti](I)(I)I NLLZTRMHNHVXJJ-UHFFFAOYSA-J 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 235000019149 tocopherols Nutrition 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- SGCFZHOZKKQIBU-UHFFFAOYSA-N tributoxy(ethenyl)silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)C=C SGCFZHOZKKQIBU-UHFFFAOYSA-N 0.000 description 1
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
- OJAJJFGMKAZGRZ-UHFFFAOYSA-N trimethyl(phenoxy)silane Chemical compound C[Si](C)(C)OC1=CC=CC=C1 OJAJJFGMKAZGRZ-UHFFFAOYSA-N 0.000 description 1
- 238000004056 waste incineration Methods 0.000 description 1
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/08—Butenes
- C08F210/10—Isobutene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Description
ãç£æ¥äžã®å©çšåéã
æ¬çºæã¯ãåªããæçšæ§ãæããåŸæ¥ç¥ãããŠ
ããªãæ°èŠãªïŒâããã³ç³»ã©ã³ãã å ±éåäœã«é¢
ãããããã«è©³çŽ°ã«ã¯ãéææ§ãè¡šé¢éç²çæ§ã
åŒåŒµç¹æ§åã³ãã®ä»ã®æ§è³ªã«åªããïŒâããã³ç³»
ã©ã³ãã å ±éåäœãããšãã°éææ§ãèãããã
ã³ã°æ§ãªã©ã«åªããå è£ çšãã€ã«ã ãã·ãŒãç¶
ç©ããã®ä»ã®æº¶èæ圢ç©ã®æ圢ã«é©ããïŒâãã
ã³ç³»ã©ã³ãã å ±éåäœã®æäŸã«é¢ããã ãåŸæ¥ã®æè¡ã åŸæ¥ãè»è³ªãããã¯å硬質暹èã®æ圢å¿çšåé
ã«ãããŠã¯å¡©åããã«æš¹èã®äœ¿çšãåªäœã«ãã€ã
ããå»æ£ç©çŒåŽæã«ãããè é£æ§ã¬ã¹ã®çºçãæ®
çã¢ãããŒãå¯å¡å€ã«å¯Ÿããå®å šæ§ãžã®æžå¿µãªã©
ã®åé¡ãããªã¬ãã€ã³ç³»ã®è»è³ªãããã¯å硬質暹
èãžã®è»¢æãæãŸããããã«ãªã€ãŠããã æè¿ããã®ãããªè»è³ªãããã¯å硬質暹èã®æ
圢å¿çšåéã«ãããŠå©çšããããªã¬ãã€ã³ç³»æš¹è
ãšããŠã¯ããšãã¬ã³ç³»å ±éåäœããããã¬ã³ç³»å ±
éåäœãïŒâããã³ç³»å ±éåäœãªã©ã®ãªã¬ãã€ã³
ç³»å ±éåäœãããããããã®ãªã¬ãã€ã³ç³»ã®è»è³ª
ãããã¯å硬質暹èã®ãã¡ã§ãïŒâããã³ãäž»æ
åãšããïŒâããã³ãšãããã¬ã³ãããªãè»è³ªã®
ïŒâããã³ç³»ã©ã³ãã å ±éåäœã«é¢ããŠã¯ãå€æ°
ã®ææ¡ãããããããã®äžã§ç±³åœç¹èš±ç¬¬3278504
å·æ现æžãç±³åœç¹èš±ç¬¬3332921å·æ现æžãç±³åœç¹
蚱第4168361å·æ现æžãè±åœç¹èš±ç¬¬1018341å·æ现
æžã«ã¯ãäžå¡©åãã¿ã³ãåå¡©åãã¿ã³ç³»è§Šåªãçš
ããŠè£œé ããïŒâããã³ç³»ã©ã³ãã å ±éåäœãé
瀺ãããŠããããããããããã®ïŒâããã³ç³»ã©
ã³ãã å ±éåäœã«å ±éããŠããããšã¯ãæ²žéš°é ¢é ž
ã¡ãã«å¯æº¶ååã³ã¢ã»ãã³ã»ïœâãã«ã³æ··å溶åª
ïŒå®¹éæ¯ïŒïŒïŒïŒå¯æº¶åãªã©ã®äœååéåäœæå
ã®å«æçãå€ãããŸãçµæååžãååéååžãåº
ãã®ã§ããããã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœ
ãã圢æããæ圢äœãç¹ã«ãã€ã«ã ãã·ãŒããªã©
ã¯è¡šé¢ç²çæ§ã倧ãããããããã³ã°æ§ãèã
ãããŸãããã®ã»ãšãã©ã®ãã®ã¯ã©ã³ãã æ§ãäœ
ããïœâãããµã³äžæº¶ç©ãå€ãéææ§ã«ãå£ã€ãŠ
ãããåå䟡å€ã®é«ãæ圢åãåŸãããšãã§ããª
ãã€ãã åèšç±³åœç¹èš±ç¬¬3278504å·æ现æžã«ã¯ãïŒâã
ãã³å«æéã30ãªãã70ã¢ã«ïŒ ã®ãããã¬ã³ã»ïŒ
âããã³å ±éåäœãææ¡ãããŠããã該ïŒâãã
ã³ç³»å ±éåäœã¯åå¡©åãã¿ã³ãäžå¡©åãã¿ã³ãçš
ããŠè£œé ãããããšãèšèŒãããŠãããããã®ã
ããªè§Šåªç³»ã§è£œé ãããå ±éåäœã¯æ²žéš°é ¢é žã¡ã
ã«å¯æº¶åã®å«æéãïŒééïŒ ãè¶ãããããã¢ã»
ãã³ã»ïœâãã«ã³æ··å溶åªïŒå®¹éæ¯ïŒïŒïŒïŒå¯æº¶
åã®å«æéãå€ããè¡šé¢ç²çæ§ããããéææ§ã«
å£ãè»è³ªæš¹èã§ããã åèšç±³åœç¹èš±ç¬¬332921å·æ现æžåã³è±åœç¹èš±ç¬¬
1084953å·æ现æžã«ãäžå¡©åãã¿ã³è§ŠåªãçšããŠ
補é ããïŒâããã³å«æçã®ç°ãªãçš®ã ã®ïŒâã
ãã³ç³»å ±éåäœãææ¡ãããŠãããããããã®å ±
éåäœã®äžã§ïŒâããã³å«æéã60ãªãã99ã¢ã«
ïŒ ã®ïŒâããã³ç³»å ±éåäœã¯åèšç±³åœç¹èš±ç¬¬
3278504å·æ现æžææ¡ã®ïŒâããã³ç³»å ±éåäœãš
åæ§ã®æ§è³ªãæããŠããã ãŸããåèšè±åœç¹èš±ç¬¬1018341å·æ现æžã«ãã
ã°ãäžå¡©åãã¿ã³ã®ãããªé·ç§»éå±ãã©ã€ããšãª
ã³é žã®èªå°äœã䜵çšããŠïŒâããã³å«æéã25ãª
ãã90ã¢ã«ïŒ ã®å ±éåäœãåŸãŠããããã®ææ¡ã«
ãããŠå ·äœçã«é瀺ãããå ±éåäœã®ãã¡ã§ãïŒ
âããã³ã®å«æéã50ãªãã90ã¢ã«ïŒ ã®ïŒâãã
ã³ç³»å ±éåäœã«é¢ããŠã¿ããšãã¢ã»ãã³å¯æº¶åã
1.5ééïŒ ä»¥äžã®ãã®ã®ã¿ãé瀺ãããŠãããæ¬
çºæè çã®æ€èšã«ããã°ããããã®å ±éåäœã¯æ²ž
éš°é ¢é žã¡ãã«å¯æº¶åãïŒééïŒ ããããŠããã«å€
ãããŸãã¢ã»ãã³ã»ïœâãã«ã³æ··å溶åªïŒå®¹éæ¯
ïŒïŒïŒïŒå¯æº¶åã®å«æçãïŒÃãηã-1.2ééïŒ ã
è¶ ããŠå€ãã該ïŒâããã³ç³»å ±éåäœããã¯è¡šé¢
ç²çæ§ã倧ãããéææ§ã«å£ã€ãæ圢äœããåŸã
ããšãã§ããªãããšãããã€ãã ããã«ãåèšç±³åœç¹èš±ç¬¬4168361å·æ现æžã«ã¯
ãããã¬ã³ãå«æçã40ãªãã90ã¢ã«ïŒ ã®ç¯å²ã«
ãããããã¬ã³ã»ïŒâããã³å ±éåäœãé瀺ãã
ãŠãããããããã®å ±éåäœã®ãã¡ã§ïŒâããã³
å«æçã50ãªãã60ã¢ã«ïŒ ã®å ±éåäœã«é¢ããŠã
åèšåæ§ã«ãæ¬çºæè çã®æ€èšã«ããã°ãã¢ã»ã
ã³ã»ïœâãã«ã³æ··å溶åªå¯æº¶åã®å«æçãå€ãã
該ïŒâããã³ç³»å ±éåäœããã¯è¡šé¢ç²çæ§ã倧ã
ããéææ§ã«å£ã€ãæ圢äœããåŸãããšãã§ããª
ãã äžæ¹ãäžå¡©åãã¿ã³ç³»è§ŠåªãçšããŠé«æž©ã§éå
ãè¡ãéæ¶è³ªã®ã©ã³ãã å ±éåäœãåŸãæ¹æ³ãç¹
éæ50â38787å·å ¬å ±ã«ææ¡ãããŠããã ãã®æ¹æ³ã§ã¯æ²žéš°ïœâãããµã³äžæº¶åã®å°ãªã
å ±éåäœã¯åŸãããããæ¬çºæè çã®æ€èšã«ãã
ã°ãé ¢é žã¡ãã«å¯æº¶åãïŒééïŒ ããå€ããåŒåŒµ
ç¹æ§ã«é¢ããŠãå£ããæš¹èççšéã«äœ¿çšã§ããª
ãã ãŸããæ¬åºé¡äººã¯ãç¹éæ54â85293å·å ¬å ±ã«
ãããŠçµæååžãçããæ²žéš°é ¢é žã¡ãã«å¯æº¶åã
å°ãªããè¡šé¢ç²çæ§ã®å°ããïŒâããã³ãäž»æå
ãšããïŒâããã³ã»ãããã¬ã³ã©ã³ãã å ±éåäœ
ãææ¡ãããããããªããããã®ææ¡ã«ããæäŸ
ãããïŒâããã³ã»ãããã¬ã³å ±éåäœã®äœåå
éæåã®å«æçããšãã«æ²žéš°é ¢é žã¡ãã«å¯æº¶åã§
è¡šããããäœååééåäœã®å«æçåã³è©²å ±éå
äœãããªãæ圢åã®è¡šé¢ç²çæ§ã¯åŸæ¥ã®ãã®ã«ã
ãã¹ãŠããªãæ¹åãããããšãæããã§ãããã
該ïŒâããã³ç³»ã©ã³ãã å ±éåäœäžã®äœååéé
åäœæåããšãã«ã¢ã»ãã³ã»ïœâãã«ã³æ··å溶åª
ïŒå®¹éæ¯ïŒïŒïŒïŒå¯æº¶åã§è¡šããããäœååéé
åäœæåã®å«æçããªãå€ããèè¡ææ§ã®æ¹åã®
ããã«ããªãããã¬ã³æš¹èã«è©²ïŒâããã³ã»ãã
ãã¬ã³ã©ã³ãã å ±éåäœãé åããæš¹èçµæç©ã®
æ圢åãããšãã°ãã€ã«ã ã¯çµæçã«è¡šé¢ç²çæ§
ãå¢å ãæããªã©ã®æ¬ ç¹ãååšããè¡šé¢éç²çæ§
åã³éææ§ãªã©ã®æ§èœãé«åºŠã«èŠæ±ãããåéã®
çšéã«ãªãå åã§ãããšã¯èšãé£ãã€ãããŸãã
ããã«ãã®ææ¡ã«ãã該ïŒâããã³ã»ãããã¬ã³
ã©ã³ãã å ±éåäœã¯äœçµæ¶æ§ã§ãããåæ§ãªã©å
åŠçç©æ§ã«å£ãããããã®ååŠçç©æ§ãé«åºŠã«èŠ
æ±ãããåéã®çšéã«ããªãäžå åã§ãã€ãã ãçºæã解決ããããšããåé¡ç¹ã æ¬çºæè ãã¯ãåŸæ¥ã®ïŒâããã³ç³»ã©ã³ãã å ±
éåäœã¯äœååéåäœã®å«æçãå€ãã該ïŒâã
ãã³ç³»ã©ã³ãã å ±éåäœããåŸãæ圢äœãè¡šé¢é
ç²çæ§ãéææ§ãåæ§ãªã©ã®ååŠçç©æ§ã«å£ã€ãŠ
ããããšãèªèããåŸæ¥ã®ïŒâããã³ç³»ã©ã³ãã
å ±éåäœã«æ¯ããŠãããã®ç©æ§ã®æ¹åãããïŒâ
ããã³ç³»ã©ã³ãã å ±éåäœãæäŸããããšãç®ç
ãšããŠéçºç 究ãè¡ã€ãŠããã ãã®çµæãæ¬çºæè ãã¯ãïŒâããã³æååã³
ççŽ ååæ°ãïŒä»¥äžã®Î±âãªã¬ãã€ã³æåãããª
ããïŒâããã³æåãäž»æåãšããïŒâããã³ç³»
ã©ã³ãã å ±éåäœã§ãã€ãŠããã€åŸèš(A)ãªãã(I)
ã§å®çŸ©ãããç¹æ§å€ãå ŒåããåŸæ¥å ¬ç¥æç®æªèš
èŒã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœãååšã§ãã
ããšãçºèŠããã€ãã®åæã«æåããã ããã«ããã®æ°èŠïŒâããã³ç³»ã©ã³ãã å ±éå
äœã¯ãåŸæ¥å ¬ç¥ã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœ
ã«ããã¹ãŠäœååééåäœæåããšãã«æ²žéš°é ¢é ž
ã¡ãã«ãžã®å¯æº¶ååã³ã¢ã»ãã³ã»ïœâãã«ã³æ··å
溶åªïŒå®¹éæ¯ïŒïŒïŒïŒãžã®å¯æº¶åã®äž¡è ã§è¡šãã
ããäœååééåäœæåã®å«æçãå°ãªãã該ïŒ
âããã³ç³»ã©ã³ãã å ±éåäœããåŸãæ圢äœã¯è¡š
é¢éç²çæ§ãéææ§ãåæ§ãªã©ã®ååŠçç©æ§ã«ãš
ãã«åªããŠããããšãçºèŠããã åŸã€ãŠãæ¬çºæã®ç®çã¯äž»æåéã®ïŒâããã³
æåãšå°éå²åã®ççŽ ååæ°ãïŒä»¥äžã®Î±âãªã¬
ãã€ã³æåãããªãæ°èŠïŒâããã³ç³»ã©ã³ãã å ±
éåäœãæäŸããããšã«ããã æ¬çºæã®äžèšç®çãªãã³ã«ããã«å€ãã®ä»ã®ç®
çãªãã³ã«å©ç¹ã¯ä»¥äžã®èšèŒã«ããäžå±€æããã«
ãªãã§ãããã ãåé¡ç¹ã解決ããããã®æ段åã³äœçšã æ¬çºæã«ããã°ãïŒâããã³æååã³ççŽ åå
æ°ãïŒä»¥äžã®Î±âãªã¬ãã€ã³æåãããªãïŒâã
ãã³ç³»ã©ã³ãã å ±éåäœã§ãã€ãŠã (A) ãã®çµæããïŒâããã³æåã50ãªãã99ã¢
ã«ïŒ åã³è©²Î±âãªã¬ãã€ã³æåãïŒãªãã50ã¢
ã«ïŒ ã®ç¯å²ã«ããããšã (B) ãã«ãªã³äžã§135âã§æž¬å®ãã極éç²åºŠïŒ»Î·ïŒœ
ã0.5ãªããïŒdlïŒïœã®ç¯å²ã«ããããšã (C) 瀺差走æ»ç±éèšã«ãã€ãŠæž¬å®ããèç¹
Tmã30ãªãã120âã®ç¯å²ã«ããããšã (D) ç·åææ³ã«ãã€ãŠæž¬å®ããçµæ¶å床ãïŒãª
ãã60ïŒ ã®ç¯å²ã«ããããšã (E) æ²žéš°é ¢é žã¡ãã«ãžã®å¯æº¶åéW1ééïŒ ïŒœ
ãïŒééïŒ ä»¥äžã®ç¯å²ã«ããããšã (F) 10âã«ãããã¢ã»ãã³ã»ïœâãã«ã³æ··å溶åª
ïŒå®¹éæ¯ïŒïŒïŒïŒãžã®å¯æº¶åéW2ééïŒ ïŒœã
ïŒÃη-1.2ééïŒ æªæºã®ç¯å²ã«ããããšã (G) éäŒç¹å¿åã10ãªãã200KgïŒcm2ã®ç¯å²ã«ã
ãããšã (H) ç Žæç¹å¿åã100ãªãã1000KgïŒcm2ã®ç¯å²ã«
ããããšã (I) ç Žæç¹äŒžã³ã300ïŒ ä»¥äžã§ããããšã ã«ãã€ãŠç¹åŸŽã¥ããããïŒâããã³ç³»ã©ã³ãã å ±
éåäœãæäŸãããã æ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã«ãã
ãŠãè©²å ±éåäœã®çµæ(A)ã¯ãïŒâããã³æåã50
ãªãã99ã¢ã«ïŒ ã奜ãŸããã¯60ãªãã98ã¢ã«ïŒ ã®
ç¯å²ã«ãããççŽ ååæ°ãïŒä»¥äžã®Î±âãªã¬ãã€
ã³æåãïŒãªãã50ã¢ã«ïŒ ã奜ãŸããã¯ïŒãªãã
40ã¢ã«ïŒ ã®ç¯å²ã«ãããè©²å ±éåäœäžã®ïŒâãã
ã³æåã®å«æçã50ã¢ã«ïŒ ããå°ãããªããã€è©²
αâãªã¬ãã€ã³æåã®å«æçã50ã¢ã«ïŒ ãã倧ã
ããªããšãè©²å ±éåäœã®è¡šé¢éç²çæ§ãåŒåŒµç¹æ§
ãäœäžããããã«ãªããïŒâããã³æåã®å«æç
ã99ã¢ã«ïŒ ãã倧ãããªããã€è©²Î±âãªã¬ãã€ã³
æåã®å«æçãïŒã¢ã«ïŒ ããå°ãããªããšãè©²å ±
éåäœã®éææ§ãäœäžããããã«ãªããæ¬çºæã®
ïŒâããã³ç³»ã©ã³ãã å ±éåäœãæ§æããççŽ å
åæ°ãïŒä»¥äžã®Î±âãªã¬ãã€ã³æåãšããŠã¯ãïŒ
âãã³ãã³ãïŒâããã»ã³ãïŒâã¡ãã«âïŒâã
ã³ãã³ãïŒâã¡ãã«âïŒâãã³ãã³ãïŒâãªã¯ã
ã³ãïŒâãã»ã³ãïŒâããã»ã³ãïŒâããã©ãã»
ã³ãïŒâãããµãã»ã³ãïŒâãªã¯ãã»ã³ãïŒâãš
ã€ã³ã»ã³ãªã©ã®ççŽ ååæ°ãïŒãªãã20ã®Î±âãª
ã¬ãã€ã³ãäŸç€ºããããšãã§ããã æ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã«ãã
ãŠã135âã®ãã«ãªã³äžã§æž¬å®ãã極éç²åºŠãηã
(B)ã¯0.5ãªããïŒã奜ãŸããã¯ïŒãªããïŒdlïŒïœ
ã®ç¯å²ã«ãããηãïŒdlïŒïœãè¶ãããšå ±é
åäœã¯æ圢æ§ãå£ãã0.5dlïŒïœæªæºã§ãããšæ©
械ç匷床ã«å£ãããã®ç¹æ§å€ã¯æ¬çºæã®ïŒâãã
ã³ç³»ã©ã³ãã å ±éåäœã®ååéã瀺ã尺床ã§ã
ããä»ã®ç¹æ§å€ãšçµåããããšã«ãããåè¿°ã®åª
ããæ§è³ªã®ã©ã³ãã å ±éåäœã®æäŸã«çŽç«ã€ãŠã
ãã æ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã®ç€ºå·®
èµ°æ»åç±éèšã«ãã€ãŠæž¬å®ããèç¹ã以äžã
DSCèç¹ãšç¥èšããããšãããã(C)ã¯ã30ãªã
ã120âã奜ãŸããã¯40ãªãã115âã®ç¯å²ã«ã
ããèç¹ã120âãè¶ãããšå ±éåäœã¯æè»æ§ã«
æ¬ ãã30âæªæºã§ãããšããããã³ã°ãããããª
ãã¹ãªããæ§ãäœäžããã該DSCèç¹ãååšã
ãããšã¯ãåŸæ¥ã®éæ¶è³ªã®ïŒâããã³ç³»ã©ã³ãã
å ±éåäœãšåºå¥ãããçµæ¶æ§ãæããå ±éåäœã§
ããããšã瀺ã尺床ã§ãã€ãŠãä»ã®ç¹æ§å€ãšçµå
ããããšã«ãã€ãŠåè¿°ã®åªããæ§è³ªã®å ±éåäœã®
æäŸã«åœ¹ç«ã€ãŠãããããã§ãDSCèç¹ã¯æ圢
20æéçµéåŸã®åã0.1mmã®ãã¬ã¹ã·ãŒãã10
âïŒminã®ææž©é床ã§ïŒã200âãŸã§æž¬å®ããæ
倧åžç±ããŒã¯ãTmãšããã æ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã®ïŒžç·
åææ³ã«ãã€ãŠæž¬å®ããçµæ¶å床(D)ã¯ãïŒãªãã
60ïŒ ã奜ãŸããã¯10ãªãã55ïŒ ã®ç¯å²ã«ãããçµ
æ¶å床ã60ïŒ ãè¶ãããšå ±éåäœã¯æè»æ§ã«æ¬
ããïŒïŒ æªæºã§ãããšããããã³ã°ãããããªã
ã¹ãªããæ§ãäœäžããããã®ç¹æ§å€ã¯ãæ¬çºæã®
ïŒâããã³ç³»ã©ã³ãã å ±éåäœãåŒåŒµç¹æ§ã«åªã
ãããšã瀺ã尺床ã§ãããä»ã®ç¹æ§å€ãšçµåãã
ããšã«ããåè¿°ã®åªããæ§è³ªã®ã©ã³ãã å ±éåäœ
ã®æäŸã«åœ¹ç«ã€ãŠãããçµæ¶å床ã¯æ圢åŸ20æé
çµéåŸã®åã1.5mmã®ãã¬ã¹ã·ãŒãã®ïŒžç·åæ枬
å®ã«ããæ±ããã æ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã«ãã
ãŠãæ²žéš°é ¢é žã¡ãã«ãžã®å¯æº¶åéãW1ééïŒ ã
(E)ã¯ãè©²å ±éåäœã®ééã«åºã¥ããŠïŒééïŒ ä»¥
äžãããšãã°0.01ãïŒééïŒ ã奜ãŸããã¯0.02ã
ïŒééïŒ ã®ç¯å²ã«ããããŸãã該ïŒâããã³ç³»ã©
ã³ãã å ±éåäœã®æ²žéš°é ¢é žã¡ãã«å¯æº¶åéãW1
ééïŒ ãã¯ãããšãã°äžè¬åŒ 0.01âŠW1âŠ0.02aïŒ1.0 ããã«ã¯ã0.02âŠW1âŠ0.015aïŒ0.7 ãšãã«ã¯ã0.03âŠW1âŠ0.01aïŒ0.5 ãåŒäžãïœã¯è©²Î±âãªã¬ãã€ã³æåã®å«æçïŒã¢
ã«ïŒ ïŒã瀺ããã§è¡šããããç¯å²ã«ããã®ã奜ãŸ
ããããã®ç¹æ§å€ã¯æ¬çºæã®ïŒâããã³ç³»ã©ã³ã
ã å ±éåäœã«ãããäœååééåäœæåã®å«æç
ã瀺ããã€è©²å ±éåäœã®çµæååžåã³ååéååž
ã®åºçã瀺ã尺床ã§ãããåŸæ¥ããææ¡ãããŠã
ãïŒâããã«ç³»ã©ã³ãã å ±éåäœã¯è©²æ²žéš°é ¢é žã¡
ãã«å¯æº¶åéãå€ããè¡šé¢éç²çæ§ã«å£ãããã
ããã³ã°æ§ã倧ããåå ã«ãªã€ãŠãããæ¬çºæã®
ïŒâããã³ç³»ã©ã³ãã å ±éåäœã«ããããã®ç¹æ§
å€ã¯ãä»ã®ç¹æ§å€ãšçµåããããšã«ããåè¿°ã®åª
ããæ§è³ªã®å ±éåäœã®æäŸã«åœ¹ç«ã€ãŠãããæ¬çº
æã«ãããŠãè©²æ²žéš°é ¢é žã¡ãã«å¯æº¶åéã¯æ¬¡ã®æ¹
æ³ã§æž¬å®ãããããªãã¡ãïŒmmÃïŒmmÃïŒmmçšåºŠ
ã®çŽ°çè©Šæãåçã¬ã©ã¹ãã€ã«ã¿ãŒã«å ¥ãããªã
ã©ãã¯ã¹é »åºŠãïŒåïŒïŒåçšåºŠã«ããŠãœãã¯ã¹ã¬
ãŒæœåºåšã§ïŒæéæœåºããæœåºæ®åãç空也ç¥åš
ïŒç空床10mmHg以äžïŒã§æéã«ãªããŸã§ä¹Ÿç¥ããŠ
ãã®ééãæ±ããåè©Šæãšã®ééå·®ããæ²žéš°é ¢é ž
ã¡ãã«å¯æº¶åééãæ±ãããæ²žéš°é ¢é žã¡ãã«å¯æº¶
åéãW1ãã¯è©²æ²žéš°é ¢é žã¡ãã«å¯æº¶åééã®å
è©Šæééã«å¯ŸããçŸåçãšããŠæ±ããã æ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã«ãã
ãŠã10âã«ãããã¢ã»ãã³ã»ïœâãã«ã³æ··å溶åª
ïŒæº¶éæ¯ïŒïŒïŒïŒãžã®å¯æº¶åéãW2ééïŒ ã(F)
ã¯ãè©²å ±éåäœã®ééã«åºã¥ããŠãïŒÃãηã-1.2
ééïŒ æªæºãããšãã°0.1Ããηã-1.2ãïŒÃãηã-1.
ïŒééïŒ ã奜ãŸããã¯0.2Ããηã-1.2ãïŒÃãηã-1.
2
ééïŒ ããšãã«å¥œãŸããã¯0.3Ããηã-1.2ãïŒÃ
ãηã-1.2ã®ç¯å²ã«ããïŒããã§ããηãã¯è©²å ±éå
äœã®æ¥µéç²åºŠã®æ°å€ã§ãã€ãŠããã€ã¡ã³ãžãšã³ã
é€ããå€ã瀺ããïŒããã®ç¹æ§å€ã¯ãæ¬çºæã®ïŒâ
ããã³ç³»ã©ã³ãã å ±éåäœã«ãããäœååééå
äœæåã®å«æçã瀺ããã€è©²å ±éåäœã®çµæååž
åã³ååéã®åºçã瀺ã尺床ã§ãããåŸæ¥ããç¥
ãããŠããïŒâããã³ç³»ã©ã³ãã å ±éåäœã¯è©²æ²ž
éš°é ¢é žã¡ãã«å¯æº¶åãå€ããè¡šé¢éç²çæ§ã«å£
ããããããã³æ§ã倧ããåå ã«ãªã€ãŠãããæ¬
çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã«ãããã
ã®ç¹æ§å€ã¯ãä»ã®ç¹æ§å€ãšçµåããããšã«ããã
åè¿°ã®åªããæ§è³ªã®å ±éåäœã®æäŸã«åœ¹ç«ã€ãŠã
ããæ¬çºæã«ãããŠã該混å溶åªäžãžã®å ±éåäœ
ã®å¯æº¶åéã¯æ¬¡ã®æ¹æ³ã«ãã€ãŠæž¬å®æ±ºå®ãããã
ããªãã¡ãæ¹æçŸœæ ¹ä»150mlã®ãã©ã¹ã³ã«ãïŒïœ
ã®å ±éåäœè©Šæã0.05ïœã®ïŒïŒïŒâãžtertâãã
ã«âïŒâã¡ãã«ããšããŒã«ã50mlã®ïœâãã«ã³ã
å ¥ãã120âã®æ²¹æµŽäžã§æº¶è§£ãããã溶解åŸ30å
é宀枩äžã§èªç¶æŸä»€ãã次ãã§50mlã®ã¢ã»ãã³ã
30ç§ã§æ·»å ãã10âã®æ°ŽæµŽäžã§60åéå·åŽããã
æåºããå ±éåäœãšäœååééåäœæåã®æº¶è§£ã
ã溶液ãã°ã©ã¹ãã€ã«ã¿ãŒã§éåé¢ãã溶液ã
10mmHgã§150âã§æéã«ãªããŸã§ä¹Ÿç¥ãããã®é
éã枬å®ããåèšæ··å溶åªäžãžã®å ±éåäœã®å¯æº¶
åéãè©Šæå ±éåäœã®ééã«å¯ŸããçŸåçãšããŠ
ç®åºæ±ºå®ããããªããåèšæž¬å®æ³ã«ãããŠæ¹æã¯
溶解æããéã®çŽåãŸã§é£ç¶ããŠè¡ã€ãã æ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã«ãã
ãŠãFIS K7113ã®æ¹æ³ã«ãã€ãŠæž¬å®ããéäŒç¹å¿
å(G)ã¯10ãªãã200KgïŒcm2ã奜ãŸããã¯20ãªãã
150KgïŒcm2ã®ç¯å²ã«ãããJIS K7113ã®æ¹æ³ã«ã
ã€ãŠæž¬å®ããç Žæç¹å¿å(H)ã¯100ãªãã1000KgïŒ
cm2ã奜ãŸããã¯120ãªãã600KgïŒcm2ã®ç¯å²ã«ã
ããJIS K7113ã®æ¹æ³ã«ãã€ãŠæž¬å®ããç Žæç¹äŒž
ã³(I)ã¯300ïŒ ä»¥äžã奜ãŸããã¯500ãªãã1500ïŒ ã®
ç¯å²ã«ãããéäŒç¹å¿åã200KgïŒcm2ãè¶ ãããã
ç Žæç¹å¿åã1000KgïŒcm2ãè¶ ããããããšå ±éå
äœã¯æè»æ§ã«æ¬ ããéäŒç¹å¿åãïŒKgïŒcm2æªæºã§
ãã€ãããç Žæç¹å¿åã100KgïŒcm2æªæºã®å ±éå
äœã¯æ©æ¢°ç匷床ã«å£ããåç Žæç¹äŒžã³ã300ïŒ æª
æºã®ãã®ã¯æè»æ§ã«æ¬ ãããæ¬çºæã®ïŒâããã³
ç³»ã©ã³ãã å ±éåäœã®éäŒç¹å¿å(G)ãç Žæç¹å¿å
(H)åã³ç Žæç¹äŒžã³(I)ã®ç¹æ§å€ã¯ãåè¿°ã®ä»ã®ç¹æ§
å€ãšçµåããããšã«ãããåè¿°ã®åªããè«žæ§è³ªã
åããå ±éåäœãæäŸããã®ã«åœ¹ç«ã€ãŠããããª
ããæ¬çºæã«ãããŠãåèšéäŒç¹å¿å(G)ãç Žæç¹
å¿å(H)åã³ç Žæç¹äŒžã³(I)ã®ç¹æ§å€ã¯JIS K7113ã®
åŒåŒµè©Šéšã®æ¹æ³ã«åŸã€ãŠæž¬å®ãããããªãã¡ãè©Š
æã¯JIS K6758ã«ãã€ãŠæ圢ããåãïŒmmã®ãã¬
ã¹ã·ãŒãããæ圢19æéåŸã«æã¡æããJIS
K7113ã®ïŒå·åœ¢è©Šéšçãçšãã25âã®é°å²æ°äžã§
åŒåŒµé床50mmïŒminã§äžèšãã¬ã¹ã·ãŒãæ圢20æ
éåŸã«æž¬å®ãããéäŒç¹ãæçã«çŸãããªãå Žå
ã«ã¯ã20ïŒ ã®äŒžã³å¿åãéäŒç¹å¿åãšããã æ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã¯ã以
äžã«è¿°ã¹ã(A)ãªãã(I)ã®ç¹æ§å€ã«ãã€ãŠè¡šããã
ãçµåå åãæºè¶³ããããã«å¥œãŸããæ¬çºæã®ïŒ
âããã³ç³»ã©ã³ãã å ±éåäœã¯æ¬¡ã®(J)ãªãã(L)ã®
ç¹æ§å€ããå 足ããã æ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã®JIS
K6745ã®æ¹æ³ã«ãã€ãŠæž¬å®ãããããåæ§ç(J)ã¯
ããšãã°100ãªãã2000KgïŒcm2ã奜ãŸããã¯150ãª
ãã1500KgïŒcm2ã®ç¯å²ã«ããããããåæ§çã®æž¬
å®æ¹æ³ãšããŠã¯ãJIS K6758ã«ãã€ãŠæ圢ããå
ãïŒmmã®ãã¬ã¹ã·ãŒãããæ圢ïŒæ¥åŸã«æã¡æã
ã瞊64mmã暪635mmã®çåç¶è©Šéšçãçšãããã¬
ã¹ã·ãŒãæ圢10æ¥åŸã25âã®é°å²æ°äžã50ãªãã
60床ã®ãããè§ã§å éåŸïŒç§ã®ã®ã¡ã®å€ã枬å®ã
ãã ãŸããæ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœ
ã®JIS K7113ã®æ¹æ³ã«ãã€ãŠæž¬å®ããã€ã³ã°ç(K)
ã¯ããšãã°200ãªãã4000KgïŒcm2ã奜ãŸããã¯300
ãªãã3000KgïŒcm2ã®ç¯å²ã«ããããŸããæ¬çºæã®
ïŒâããã³ç³»ã©ã³ãã å ±éåäœã®ã€ã³ã°ç(K)ã¯ã
該αâãªã¬ãã€ã³æåã®å«æçïœã¢ã«ïŒ ãšã®é¢ä¿
ã«ãããŠå¥œãŸããã¯äžè¬åŒ 3000â30bâ§ïŒ«â§1000â15b ã«ãã€ãŠè¡šãããããã€ã³ã°çã®æž¬å®ã¯ãåèš
(G)ã(H)åã³(I)ã®æž¬å®ãšåæ§ã®åŒåŒµè©Šéšã®æ¹æ³ã«ã
ã€ãŠè¡ã€ãã æ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã®ïŒâ
ããã³å«æçã®æšæºåå·®å€Ï(L)ã¯ããšãã°0.4αã¢
ã«ïŒ 以äžã奜ãŸããã¯0.3αã¢ã«ïŒ 以äžã§ããïŒåŒ
äžãαã¯è©²ïŒâããã³ç³»ã©ã³ãã å ±éåäœäžã®ç
çŽ ååæ°ãïŒä»¥äžã®Î±âãªã¬ãã€ã³æåã®å«æç
ã¢ã«ïŒ ã瀺ããïŒã該æšæºåå·®å€Ïã¯è©²ïŒâããã³
ç³»ã©ã³ãã å ±éåäœã®ã©ã³ãã æ§ã瀺ã尺床ã§ã
ã€ãŠãåèšç¹æ§å€(A)ãªãã(K)ã«å ããŠããã«ç¹æ§
å€(L)ãæºè¶³ããå ±éåäœã¯ããåªããç©æ§ã瀺
ããæ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã®æš
æºåå·®å€Ïã¯ãè©²å ±éåäœã®çµæååžã«åºã¥ããŠ
次åŒã«ãã€ãŠç®åºæ±ºå®ããããªããè©²å ±éåäœã®
çµæååžã¯ãïœâãã·ã¬ã³æº¶åªã§æœåºæž©åºŠãïŒãª
ãã130âãŸã§ïŒâæ¯ã®æ®µéçã«å€åãããæœåº
åã«ã©ã åå¥æ³ã«ãã€ãŠæž¬å®ãããã®éäžå®æž©åºŠ
ã§ã®æœåºã«ã¯å ±éåäœè©Šæ10ïœã«å¯ŸããŠïœâãã·
ã¬ã³ïŒãçšããïŒæéã®æœåºãè¡ã€ãã ÏïŒãâ«100 0ïŒâïœïŒ2fïŒïœïŒdxã1/2 ããã§ãã¯å ±éåäœã®ïŒâããã³ã®å¹³åå«æ
çïŒã¢ã«ïŒ ïŒã瀺ããïœã¯ïŒâããã³å«æçïŒã¢
ã«ïŒ ïŒãïœïŒïœïŒã¯ïŒâããã³å«æéïœïŒã¢ã«ïŒ ïŒ
ãæã€æåã®åŸ®åééåçã瀺ãã æ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã¯ãçµ
æ¶åãåã«åºå®ãããã®ã§ç©æ§ã®çµæå€åãå°
ãããšããç¹åŸŽããããããã«å¯ŸããŠãããšãã°
ïŒâããã³ã®åç¬éåäœã«ã¯ïŒçš®é¡ã®çµæ¶åïŒ
åãåããã³åïŒãååšãã枩床ãæéã®å€
åã«ã€ããŠçžäºã®çµæ¶è»¢ç§»ãèµ·ããããšãç¥ãã
ãŠããããšãã«å®€æž©äžã§ã¯çŽå®å®ãªåçµæ¶åœ¢æ
ããå®å®ãªåçµæ¶åœ¢æ ãžã®è»¢ç§»ãé ãããã«ã
å®éã®æ圢åãžã®å¿çšã«éããŠã¯æ圢åã®å€åœ¢ã
ç©æ§ã®çµæå€åçã®çš®ã ã®å°é£ã䌎ãªããªã©ã®æ¬
ç¹ããã€ãã æ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã«ã¯ã
åè¿°ã®è«žç©æ§ãæãªãããšããªãéãã埮éã®ä»
ã®Î±âãªã¬ãã€ã³ãããšãã°ãšãã¬ã³ããããã¬
ã³ãªã©ãå ±éåãããŠããŠãããã æ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã¯ãã
ãšãã°ã (a) ãã°ãã·ãŠã ååç©ããã¿ã³ååç©ããžãšã¹
ãã«åã³å¿ èŠã«å¿ããŠããã²ã³ååç©ïŒãã°ã
ã·ãŠã ååç©åã¯ãã¿ã³ååç©ãããã²ã³åå
ãå«ãå Žåã«ã¯å¿ ããããå¿ èŠãšããªãïŒãçž
äºã«åå¿ãããããšã«ãã€ãŠåœ¢æããããã°ã
ã·ãŠã ããã¿ã³ãããã²ã³åã³ãžãšã¹ãã«ãå¿
é æåãšããé«æŽ»æ§ãã¿ã³è§Šåªæåã (b) ææ©ã¢ã«ãããŠã ååç©è§Šåªæåãåã³ (c) Siââçµåãæããææ©ç¡ çŽ ååç©è§Šåª
æåã ãã圢æããã觊åªã®ååšäžã«ãçŽ20ãªããçŽ
200âã®æž©åºŠã§ïŒâããã³åã³Î±âãªã¬ãã€ã³ã
å ±éåãããããšã«ãã€ãŠåŸãããšãã§ããã觊
åªæåãå ±éåæ¡ä»¶ããã®ä»ã®å ±éåäœè£œé æ¡ä»¶
ã¯ä»¥äžã«è©³ããè¿°ã¹ãããã«ãæ¬çºæã®å ±éåäœ
ã«åèšç¹æ§(A)ãªãã(I)ãç®å®ãšããŠãå®éšçã«å®¹
æã«éžæèšå®ããããšãã§ãããæ¬çºæã«ãã
ãŠãåŸæ¥ã®æç®æªèšèŒã®ç¹æ§å€ãæããæ¬çºæã®
ïŒâããã³ç³»ã©ã³ãã å ±éåäœã®ååšãªãã³ã«ã
ã®å ±éåäœã®ååšãªãã³ã«ãã®å ±éåäœã®åªãã
æ§è³ªãæããã«ããããã®ã§ãããããæ¬çºæã®
å ±éåäœã«ç¹å®ãããç¹æ§å€(A)ãªãã(I)ãããã«
è£å©çãªç¹æ§å€(J)ãªããã(L)ãç®å®ã«ããŠãæ¬çº
æã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã®è£œé æ¡ä»¶ã
å®éšçã«å®æã«ãã€é©å®ã«éžæèšå®ããããšãã§
ããã é«æŽ»æ§ãã¿ã³è§Šåªæå(a)ã¯ããã°ãã·ãŠã ãã
ã¿ã³ãããã²ã³ããã³ãžãšã¹ãã«ãå¿ é æåãšã
ãŠå«æããããã®ãããªãã¿ã³è§Šåªæå(a)ãšããŠ
ã¯ããã°ãã·ãŠã ïŒãã¿ã³ïŒååæ¯ïŒã奜ãŸãã
ã¯çŽïŒãªããçŽ100ãäžå±€å¥œãŸããã¯çŽïŒãªãã
çŽ70ãããã²ã³ïŒãã¿ã³ïŒååæ¯ïŒã奜ãŸããã¯
çŽïŒãªããçŽ100ãäžå±€å¥œãŸããã¯çŽïŒãªããçŽ
40ããžãšã¹ãã«ïŒãã¿ã³ïŒã¢ã«æ¯ïŒã奜ãŸããã¯
çŽ0.2ãªããçŽ10ãäžå±€å¥œãŸããã¯çŽ0.4ãªããçŽ
ïŒã®ç¯å²ã«ããã®ã奜ãŸããããŸãããã®æ¯è¡šé¢
ç©ã¯ã奜ãŸããã¯çŽïŒm2ïŒïœä»¥äžãäžå±€å¥œãŸãã
ã¯çŽ40m2ïŒïœä»¥äžãããã«å¥œãŸããã¯çŽ100m2ïŒ
ïœãªããçŽ800m2ïŒïœã§ããã ãã®ãããªãã¿ã³è§Šåªæå(a)ã¯ã宀枩ã«ããã
ãããµã³æŽæµã®ãããªç°¡åãªæ段ã«ãã€ãŠå®è³ªç
ã«ãã¿ã³ååç©ãè±é¢ããªãã®ãæ®éã§ãããã
ã®ïŒžç·ã¹ãã¯ãã«ã觊åªèª¿è£œã«çšããåæãã°ã
ã·ãŠã ååç©ã®åŠäœã«ãããããããã°ãã·ãŠã
ååç©ã«é¢ããŠéæ¶æ§ã瀺ããããŸãã¯ãã°ãã·
ãŠã ãžãã©ã€ãã®éåžžã®åžè²©åã®ããã«æ¯ã¹ã奜
ãŸããã¯éåžžã«éæ¶åãããç¶æ ã«ããã ãã¿ã³è§Šåªæå(a)ã¯ãåèšå¿ é æå以å€ã«ã觊
åªæ§èœã倧ããæªåãããªãé床ã«ãããŠãä»ã®
å çŽ ãéå±ãå®èœåºãé»åäŸäžäœãªã©ãå«æããŠ
ããŠããããããã«æç¡ãç¡æ©ã®åžéå€ã§åžéã
ããŠããŠããããä»ã®å çŽ ãéå±ãåžéå€ãªã©ã
å«æããå Žåã«ã¯ãæ¯è¡šé¢ç©ãéæ¶æ§ã«åœ±é¿ãå
ãŒãããšãããããã®å Žåã«ã¯ããã®ãããªä»æ
åãé€å»ãããšãã«åè¿°ãããããªæ¯è¡šé¢ç©ã®å€
ã瀺ããã€éæ¶æ§ã瀺ããã®ã§ããããšã奜ãŸã
ãã ãã¿ã³è§Šåªæå(a)ã補é ããã«ã¯ããã°ãã·ãŠ
ã ååç©ïŒãŸãã¯ãã°ãã·ãŠã éå±ïŒããã¿ã³å
åç©ããã³ãžãšã¹ãã«ãŸãã¯ãžãšã¹ãã«åœ¢ææ§å
åç©ïŒãžãšã¹ãã«ã圢æããååç©ïŒããä»ã®å
å¿è©Šå€ãçšããŸãã¯çšããããŠçžäºã«æ¥è§Šããã
æ¹æ³ãæ¡çšããã®ãããããã®èª¿è£œã¯ããã°ãã·
ãŠã ããã¿ã³ãããã²ã³ããã³é»åäŸäžäœãå¿ é
æåãšããåŸæ¥å ¬ç¥ã®é«æŽ»æ§ãã¿ã³è§Šåªæåã®èª¿
補æ³ãšåæ§ã«è¡ãããšãã§ãããäŸãã°ãç¹éæ
50â108385å·ãå50â126590å·ãå50â20297å·ã
å51â28189å·ãå51â64586å·ãå51â92885å·ã
å51â136625å·ãå52â87489å·ãå52â100596
å·ãå52â147688å·ãå52â104593å·ãå53â
2580å·ãå53â40093å·ãå53â43094å·ãå55â
135102å·ãå55â135103å·ãå56â811å·ãå56
â11908å·ãå56â118606å·ãªã©ã«é瀺ãããæ¹
æ³ã«æºããŠè£œé ããããšãã§ããã ããããã¿ã³è§Šåªæå(a)ã®è£œé æ¹æ³ã®æ°äŸã«ã€
ããŠã以äžã«äŸç€ºããã (1) ãã°ãã·ãŠã ååç©ãããã¯ãã°ãã·ãŠã å
åç©ãšé»åäŸäžäœã®é¯ååç©ããé»åäŸäžäœã
ç²ç å©å€çã®ååšäžãŸãã¯äžååšäžã«ãç²ç ã
ãŸãã¯ç²ç ããããšãªããé»åäŸäžäœããã³ïŒ
ãŸãã¯ææ©ã¢ã«ãããŠã ååç©ãããã²ã³å«æ
ã±ã€çŽ ååç©ã®ãããªåå¿å©å€ã§äºååŠçãã
ãŸãã¯äºååŠçããã«åŸãåºäœãšãåå¿æ¡ä»¶äž
ã«æ¶²çžããªããã¿ã³ååç©ãšãåå¿ããããäœ
ããäžèšé»åäŸäžäœãå°ãªããšãäžåã¯äœ¿çšã
ãã (2) éå èœãæããªããã°ãã·ãŠã ååç©ã®æ¶²ç¶
ç©ãšã液ç¶ãã¿ã³ååç©ãé»åäŸäžäœã®ååšäž
ã§åå¿ãããŠåºäœç¶ã®ãã¿ã³è€åäœãæåºãã
ãã (3) (2)ã§åŸããããã®ã«ããã¿ã³ååç©ãããã«
åå¿ãããã (4) (1)ã(2)ã§åŸããããã®ã«é»åäŸäžäœããã³ã
ã¿ã³ååç©ãããã«åå¿ãããã (5) ãã°ãã·ãŠã ååç©ãããã¯ãã°ãã·ãŠã å
åç©ãšé»åäŸäžäœã®é¯ååç©ããé»åäŸäžäœã
ç²ç å©å€çã®ååšäžãŸãã¯äžååšäžã«ãããã³
ãã¿ã³ååç©ã®ååšäžã«ç²ç ããé»åäŸäžäœã
ãã³ïŒãŸãã¯ææ©ã¢ã«ãããŠã ååç©ãããã²
ã³å«æã±ã€çŽ ååç©ã®ãããªåå¿å©å€ã§äºååŠ
çãããŸãã¯äºååŠçããã«åŸãåºäœãããã
ã²ã³ãŸãã¯ããã²ã³ååç©ãŸãã¯è³éŠæçåæ°Ž
çŽ ã§åŠçãããäœããäžèšé»åäŸäžäœãå°ãªã
ãšãäžåã¯äœ¿çšããã ãããã®èª¿è£œæ³ã®äžã§ã¯ã觊åªèª¿è£œã«ãããŠã
液ç¶ã®ããã²ã³åãã¿ã³ã䜿çšãããã®ãããã¯
ãã¿ã³ååç©äœ¿çšåŸããããã¯äœ¿çšã®éã«ããã²
ã³åçåæ°ŽçŽ ã䜿çšãããã®ã奜ãŸããã äžèšèª¿è£œã«ãããŠçšããããé»åäŸäžäœã¯ããž
ãšã¹ãšã«ãŸãã¯ãžãšã¹ãã«åœ¢ææ§ååç©ã®ã¿ã§ã
ãå¿ èŠã¯ãªããããšãã°ã¢ã«ã³ãŒã«ãããšããŒ
ã«ãã¢ã«ããããã±ãã³ããšãŒãã«ãã«ã«ãã³
é žãã«ã«ãã³é žç¡æ°Žç©ãçé žãšã¹ãã«ãã¢ããšã¹
ãã«ãã¢ãã³ãªã©ãžãšã¹ãã«ä»¥å€ã®é»åäŸäžäœã
䜿çšããããšãã§ããã é«æŽ»æ§ãã¿ã³è§Šåªæå(a)äžã®å¿ é æåã§ãããž
ãšã¹ãã«ãšããŠã¯ãïŒåã®ççŽ ååã«ïŒåã®ã«ã«
ããã·ã«åºãçµåããŠãããžã«ã«ãã³é žã®ãšã¹ã
ã«ãããã¯çžé£ãïŒåã®ççŽ ååã«ããããã«ã«
ããã·ã«åºãçµåããŠãããžã«ã«ãã³é žã®ãšã¹ã
ã«ã§ããããšã奜ãŸããããã®ãããªãžã«ã«ãã³
é žã®ãšã¹ãã«ã«ããããžã«ã«ãã³é žã®äŸãšããŠ
ã¯ãããã³é žã眮æããã³é žãã³ãã¯é žã眮æã³
ãã¯é žããã¬ã€ã³é žã眮æãã¬ã€ã³é žãããã«
é žã眮æããã«é žãèç°ã圢æããïŒåã®ççŽ å
åã«ïŒåã®ã«ã«ããã·ã«åºãçµåããèç°ãžã«ã«
ãã³é žãèç°ã圢æããçžé£ãïŒåã®ççŽ ååã«
ããããã«ã«ããã·ã«åºãçµåããèç°ãžã«ã«ã
ã³é žããªã«ãœäœã«ã«ã«ããã·ã«åºãæããè³éŠæ
ãžã«ã«ãã³é žãè€çŽ ç°ã圢æããçžé£ãïŒåã®ç
çŽ ååã«ã«ã«ããã·ã«åºãæããè€çŽ ç°ãžã«ã«ã
ã³é žãªã©ã®ãžã«ã«ãã³é žã®ãšã¹ãã«ãæããããš
ãã§ããã äžèšãžã«ã«ãã³é žã®ããå ·äœçãªäŸãšããŠã¯ã
ããã³é žïŒã¡ãã«ããã³é žããšãã«ããã³é žãã€
ãœãããã«ããã³é žãã¢ãªã«ïŒallylïŒããã³é žã
ããšãã«ããã³é žããªã©ã®çœ®æããã³é žïŒã³ãã¯
é žïŒã¡ãã«ã³ãã¯é žããžã¡ãã«ã³ãã¯é žããšãã«
ã³ãã¯é žãã¡ãã«ãšãã«ã³ãã¯é žãã€ã¿ã³ã³é žãª
ã©ã®çœ®æã³ãã¯é žïŒãã¬ã€ã³é žïŒã·ãã©ã³ã³é žã
ãžã¡ãã«ãã¬ã€ã³é žãªã©ã®çœ®æãã¬ã€ã³é žïŒã·ã¯
ããã³ã¿ã³âïŒïŒïŒâãžã«ã«ãã³é žãã·ã¯ããã³
ã¿ã³âïŒïŒïŒâãžã«ã«ãã³é žãã·ã¯ããããµã³â
ïŒïŒïŒâãžã«ã«ãã³é žãã·ã¯ãããã»ã³âïŒïŒïŒ
âãžã«ã«ãã³é žãã·ã¯ãããã»ã³âïŒïŒïŒâãžã«
ã«ãã³é žãã·ã¯ãããã»ã³âïŒïŒïŒâãžã«ã«ãã³
é žãããžãã¯é žãã¡ãã«ããžãã¯é žãïŒâã¢ãªã«
ã·ã¯ããããµã³âïŒïŒïŒâãžã«ã«ãã³é žãªã©ã®è
ç°æãžã«ã«ãã³é žïŒãã¿ã«é žãããã¿ãªã³âïŒïŒ
ïŒâãžã«ã«ãã³é žãããã¿ãªã³âïŒïŒïŒâãžã«ã«
ãã³é žãªã©ã®è³éŠæãžã«ã«ãã³é žïŒãã©ã³âïŒïŒ
ïŒâãžã«ã«ãã³é žãïŒïŒïŒâãžããããã©ã³â
ïŒïŒïŒâãžã«ã«ãã³é žããã³ãŸãã©ã³âïŒïŒïŒâ
ãžã«ã«ãã³é žããããŒã«âïŒïŒïŒâãžã«ã«ãã³
é žãããªãžã³âïŒïŒïŒâãžã«ã«ãã³é žãããªããš
ã³âïŒïŒïŒâãžã«ã«ãã³é žãã€ã³ããŒã«âïŒïŒïŒ
âãžã«ã«ãã³é žãªã©ã®è€çŽ ç°ãžã«ã«ãã³é žïŒã®åŠ
ããžã«ã«ãã³é žãäŸç€ºããããšãã§ããã äžèšãžã«ã«ãã³é žã®ãšã¹ãã«ã®ã¢ã«ã³ãŒã«æå
ã®ãã¡å°ãªããšãäžæ¹ãççŽ æ°ïŒä»¥äžããšãã«ã¯
ççŽ æ°ïŒä»¥äžã®ãã®ã奜ãŸããããšãããäž¡ã¢ã«
ã³ãŒã«æåãšãã«ççŽ æ°ïŒä»¥äžããšãã«ãªççŽ æ°
ïŒä»¥äžã®ãã®ã奜ãŸãããäŸãã°äžèšãžã«ã«ãã³
é žã®ãžãšãã«ãšã¹ãã«ããžã€ãœãããã«ãšã¹ã
ã«ããžïœâãããã«ãšã¹ãã«ããžïœâããã«ãšã¹
ãã«ããžã€ãœããã«ãšã¹ãã«ããžâtertâããã«
ãšã¹ãã«ããžã€ãœã¢ãã«ãšã¹ãã«ããžïœâããã·
ã«ãšã¹ãã«ããžâïŒâãšãã«ããã·ã«ãšã¹ãã«ã
ãžïœâãªã¯ãã«ãšã¹ãã«ããžã€ãœãã·ã«ãšã¹ã
ã«ããšãã«ïœâããã«ãšã¹ãã«ãªã©ãäŸç€ºããã
ãšãã§ããã åèšé«æŽ»æ§ãã¿ã³è§Šåªæå(a)ã®èª¿è£œã«çšããã
ããã°ãã·ãŠã ååç©ã¯éå èœãæãããŸãã¯æ
ããªããã°ãã·ãŠã ååç©ã§ãããåè ã®äŸãšã
ãŠã¯ãã°ãã·ãŠã ã»ççŽ çµåããã°ãã·ãŠã ã»æ°Ž
çŽ çµåãæãããã°ãã·ãŠã ååç©ãäŸãã°ãžã¡
ãã«ãã°ãã·ãŠã ããžãšãã«ãã°ãã·ãŠã ããžã
ããã«ãã°ãã·ãŠã ããžããã«ãã°ãã·ãŠã ããž
ã¢ãã«ãã°ãã·ãŠã ããžããã·ã«ãã°ãã·ãŠã ã
ãžãã·ã«ãã°ãã·ãŠã ããšãã«å¡©åãã°ãã·ãŠ
ã ããããã«å¡©åãã°ãã·ãŠã ãããã«å¡©åãã°
ãã·ãŠã ãããã·ã«å¡©åãã°ãã·ãŠã ãã¢ãã«å¡©
åãã°ãã·ãŠã ãããã«ãšããã·ãã°ãã·ãŠã ã
ãšãã«ããã«ãã°ãã·ãŠã ãããã«ãã°ãã·ãŠã
ãã€ãã©ã€ããªã©ãããããããããããã°ãã·
ãŠã ååç©ã¯ãäŸãã°ææ©ã¢ã«ãããŠã çãšã®é¯
ååç©ã®ç³»ã§çšããäºãã§ãããŸã液ç¶ç¶æ ã§ã
ã€ãŠãåºäœç¶æ ã§ãã€ãŠããããåŸè ã®éå èœã
æããªããã°ãã·ãŠã ååç©ã®äŸãšããŠã¯ãå¡©å
ãã°ãã·ãŠã ãèåãã°ãã·ãŠã ãæ²åãã°ãã·
ãŠã ãåŒåãã°ãã·ãŠã ã®ãããªããã²ã³åãã°
ãã·ãŠã ïŒã¡ããã·å¡©åãã°ãã·ãŠã ããšããã·
å¡©åãã°ãã·ãŠã ãã€ãœããããã·å¡©åãã°ãã·
ãŠã ããããã·å¡©åãã°ãã·ãŠã ããªã¯ããã·å¡©
åãã°ãã·ãŠã ã®ãããªã¢ã«ã³ãã·ãã°ãã·ãŠã
ãã©ã€ãïŒããšããã·å¡©åãã°ãã·ãŠã ãã¡ãã«
ããšããã·å¡©åãã°ãã·ãŠã ã®ãããªã¢ãªããã·
ãã°ãã·ãŠã ãã©ã€ãïŒãšããã·ãã°ãã·ãŠã ã
ã€ãœããããã·ãã°ãã·ãŠã ããããã·ãã°ãã·
ãŠã ãïœâãªã¯ããã·ãã°ãã·ãŠã ãïŒâãšãã«
ãããœãã·ãã°ãã·ãŠã ã®ãããªã¢ã«ã³ãã·ãã°
ãã·ãŠã ïŒããšããã·ãã°ãã·ãŠã ããžã¡ãã«ã
ãšããã·ãã°ãã·ãŠã ã®ãããªã¢ãªããã·ãã°ã
ã·ãŠã ïŒã©ãŠãªã³é žãã°ãã·ãŠã ãã¹ãã¢ãªã³é ž
ãã°ãã·ãŠã ã®ãããªãã°ãã·ãŠã ã®ã«ã«ãã³é ž
å¡©ãªã©ãäŸç€ºããããšãã§ããããŸãããããé
å èœãæããªããã°ãã·ãŠã ååç©ã¯ãäžè¿°ãã
éå èœãæãããã°ãã·ãŠã ååç©ããèªå°ãã
ãã®ãããã¯ã觊åªæåã®èª¿è£œæã«èªå°ãããã®
ã§ãã€ãŠãããããŸãã該ãã°ãã·ãŠã ååç©ã¯
éå±ãšã®é¯ååç©ãè€ååç©ãããã¯ä»ã®éå±å
åç©ãšã®æ··åç©ã§ãã€ãŠããããããã«ãããã®
ååç©ã®ïŒçš®ä»¥äžã®æ··åç©ã§ãã€ãŠãããããã
ãã®äžã§å¥œãŸãããã°ãã·ãŠã ååç©ã¯éå èœã
æããªãååç©ã§ãããç¹ã«å¥œãŸããã¯ããã²ã³
å«æãã°ãã·ãŠã ååç©ããšãããå¡©åãã°ãã·
ãŠã ãã¢ã«ã³ãã·å¡©åãã°ãã·ãŠã ãã¢ãªããã·
å¡©åãã°ãã·ãŠã ã§ããã ãã¿ã³è§Šåªæå(a)ã®èª¿è£œã«çšãããããã¿ã³å
åç©ãšããŠäŸãã°TiïŒORïŒgX4-gïŒïŒ²ã¯çåæ°ŽçŽ
åºãã¯ããã²ã³ãïŒâŠïœâŠïŒïŒã§ç€ºãããïŒäŸ¡
ã®ãã¿ã³ååç©ã奜é©ã§ãããããå ·äœçã«ã¯ã
TiCl4ãTiBr4ãTiI4ãªã©ã®ããã©ããã²ã³åã
ã¿ã³ïŒTiïŒOCH3ïŒCl3ãTiïŒOc2H5ïŒCl3ãTiïŒOn
âC4H9ïŒCl3ãTiïŒOC2H5ïŒBr3ãTiïŒOi80C4H9ïŒ
Br3ãªã©ã®ããªããã²ã³åã¢ã«ã³ãã·ãã¿ã³ïŒ TiïŒOCH3ïŒ2Cl2ãTiïŒOC2H5ïŒ2Cl2ãTiïŒOnâ
C4H9ïŒCl3ãTiïŒOC2H5ïŒ2Br2ãªã©ã®ãžããã²ã³å
ã¢ã«ã³ãã·ãã¿ã³ïŒTiïŒOCH3ïŒ3ClãTiïŒOC2H5ïŒ
ClãTiïŒOnâC4H9ïŒ3ClãTiïŒOC2H5ïŒ3Brãªã©ã®ã¢
ãããã²ã³åããªã¢ã«ã³ãã·ãã¿ã³ïŒTi
ïŒOCH3ïŒ4ãTiïŒOC2H5ïŒ4ãTiïŒOnâC4H9ïŒ4ãªã©ã®
ããã©ã¢ã«ã³ãã·ãã¿ã³ãªã©ãäŸç€ºããããšãã§
ããããããã®äžã§å¥œãŸãããã®ã¯ããã²ã³å«æ
ãã¿ã³ååç©ããšãã«ã¯ããã©ããã²ã³åãã¿ã³
ã§ããããšãã«å¥œãŸããã®ã¯åå¡©åãã¿ã³ã§ã
ããããããã¿ã³ååç©ã¯åå³ã§çšããŠããã
ããæ··åç©ã®åœ¢ã§çšããŠãããããããã¯çåæ°Ž
çŽ ãããã²ã³çåæ°ŽçŽ ãªã©ã«åžéããŠçšããŠãã
ãã ãã¿ã³è§Šåªæå(a)ã®èª¿è£œã«ãããŠããã¿ã³åå
ç©ããã°ãã·ãŠã ååç©ããã³æ æãã¹ãé»åäŸ
äžäœãããã«å¿ èŠã«å¿ããŠäœ¿çšãããããšã®ãã
é»åäŸå®¹äœãäŸãã°ã¢ã«ã³ãŒã«ãããšããŒã«ãã¢
ãã«ã«ãã³é žãšã¹ãã«ãªã©ãã±ã€çŽ ååç©ãã¢ã«
ãããŠã ååç©ãªã©ã®äœ¿çšéã¯ã調補æ¹æ³ã«ãã€
ãŠç°ãªãäžæŠã«èŠå®ã§ããªãããäŸãã°ããã°ã
ã·ãŠã ååç©ïŒã¢ã«åœããæ æãã¹ãé»åäŸäžäœ
çŽ0.1ãªããçŽ10ã¢ã«ããã¿ã³ååç©çŽ0.05ãªã
ãçŽ1000ã¢ã«çšåºŠã®å²åãäŸç€ºããããšãã§ã
ãã 以äžã®ããã«ããŠåŸãããé«æŽ»æ§ãã¿ã³è§Šåªæ
å(a)ãšãææ©ã¢ã«ãããŠã ååç©è§Šåªæåïœãã
ã³Siââçµåãæããææ©ã±ã€çŽ ååç©è§Šåª
æå(c)ã®çµåã觊åªãçšããã äžèš(d)æåãšããŠã¯ãïŒïŒå°ãªããšãååå
ã«ïŒåã®AlâççŽ çµåãæããææ©ã¢ã«ãããŠ
ã ååç©ãäŸãã°äžè¬åŒ R1mAlïŒOR2ïŒnHpXq ïŒããã§R1ããã³R2ã¯ççŽ ååãéåžžïŒãªãã
15åã奜ãŸããã¯ïŒã®ãªããïŒåãå«ãçåæ°ŽçŽ
åºã§äºãã«åäžã§ãç°ãªã€ãŠããŠããããã¯ã
ãã²ã³ãïœã¯ïŒïŒïœâŠïŒãïŒâŠïœïŒïŒãïœã¯ïŒâŠ
ïœïŒïŒãïœã¯ïŒâŠïœïŒïŒã®æ°ã§ãã€ãŠããããïœ
ïŒïœïŒïœïŒïœïŒïŒã§ããïŒã§è¡šããããææ©ã¢ã«
ãããŠã ååç©ãïŒïŒäžè¬åŒ M1AlR1 ïŒããã§M1ã¯LiãNaãã§ãããR1ã¯åèšãšå
ãïŒã§è¡šãããã第ïŒæéå±ãšã¢ã«ãããŠã ãšã®
é¯ã¢ã«ãã«åç©ãªã©ãæããããšãã§ããã åèšã®ïŒïŒã«å±ããææ©ã¢ã«ãããŠã ååç©
ãšããŠã¯ã次ã®ãã®ãäŸç€ºã§ãããäžè¬åŒ R1mAlïŒOR2ïŒ3-n ïŒããã§R1ã¯åèšãšåããã¯ããã²ã³ãïœã¯
奜ãŸããã¯ïŒïŒïœïŒïŒã§ãããïŒãäžè¬åŒ R1mAlH3-n ïŒããã§R1ã¯åèšãšåããïœã¯å¥œãŸããã¯ïŒâŠ
ïœïŒïŒã§ãããïŒãäžè¬åŒ R1mAlïŒOR2ïŒnXq ïŒããã§R1ããã³R2ã¯åèšãšåããã¯ããã²
ã³ãïŒïŒïœâŠïŒãïŒâŠïœïŒïŒãïŒâŠïœïŒïŒã§ãïœ
ïŒïœïŒïœïŒïŒã§ããïŒã§è¡šãããããã®ãªã©äŸç€º
ã§ããã ïŒïŒã«å±ããã¢ã«ãããŠã ååç©ã®äŸãšããŠ
ã¯ã以äžã®åŠãååç©ãäŸç€ºããŠãããããªãšã
ã«ã¢ã«ãããŠã ãããªããã«ã¢ã«ãããŠã ãªã©ã
ããªã¢ã«ãã«ã¢ã«ãããŠã ïŒããªã€ãœãã¬ãã«ã¢
ã«ãããŠã ã®ãããªããªã¢ã«ã±ãã«ã¢ã«ãããŠ
ã ïŒãžãšãã«ã¢ã«ãããŠã ãšããã·ãããžããã«
ã¢ã«ããŠã ãããã·ããªã©ã®åŠããžã¢ãã«ã¢ã«ã
ããŠã ã¢ã«ã³ãã·ãïŒãšãã«ã¢ã«ãããŠã ã»ã¹ã
ãšããã·ããããã«ã¢ã«ãããŠã ã»ã¹ããããã·
ããªã©ã®åŠãã¢ã«ãã«ã¢ã«ãããŠã ã»ã¹ãã¢ã«ã³
ãã·ãã®ã»ãã«ãR1 2.5AlïŒOR2ïŒ0.5ãªã©ã§è¡šããã
ãå¹³åçµæãæããéšåçã«ã¢ã«ã³ãã·åããã
ã¢ã«ãã«ã¢ã«ãããŠã ïŒãžãšãã«ã¢ã«ãããŠã ã¯
ããªãããžããã«ã¢ã«ãããŠã ã¯ããªãããžãšã
ã«ã¢ã«ãããŠã ããããã®ãããªãžã¢ã«ãã«ã¢ã«
ãããŠã ãã©ã€ãïŒãšãã«ã¢ã«ãããŠã ã»ã¹ãã¯
ããªããããã«ã¢ã«ãããŠã ã»ã¹ãã¯ããªãããš
ãã«ã¢ã«ãããŠã ã»ã¹ãããããã®ãããªã¢ã«ã
ã«ã¢ã«ãããŠã ã»ã¹ããã©ã€ãïŒãšãã«ã¢ã«ãã
ãŠã ãžã¯ããªãããããã«ã¢ã«ãããŠã ãžã¯ããª
ããããã«ã¢ã«ãããŠã ãžãããããªã©ã®ãããª
ã¢ã«ãã«ã¢ã«ãããŠã ãžãã©ã€ããªã©ã®éšåçã«
ããã²ã³åãããã¢ã«ãã«ã¢ã«ãããŠã ïŒãžãšã
ã«ã¢ã«ãããŠã ãããªãããžããã«ã¢ã«ãããŠã
ãããªããªã©ã®åŠããžã¢ã«ãã«ã¢ã«ãããŠã ãã
ãªãïŒãšãã«ã¢ã«ãããŠã ãžãããªãããããã«
ã¢ã«ãããŠã ãžãããªããªã©ã®åŠãã¢ã«ãã«ã¢ã«
ãããŠã ãžãããªããªã©ããã®ä»ã®éšåçã«æ°ŽçŽ
åãããã¢ã«ãã«ã¢ã«ãããŠã ïŒãšãã«ã¢ã«ãã
ãŠã ãšããã·ã¯ããªããããã«ã¢ã«ãããŠã ãã
ãã·ã¯ããªãããšãã«ã¢ã«ãããŠã ãšããã·ãã
ãããªã©ã®éšåçã«ã¢ã«ã³ãã·åããã³ããã²ã³
åãããã¢ã«ãã«ã¢ã«ãããŠã ã åèšïŒïŒã«å±ããååç©ãšããŠã¯ãLiAl
ïŒC2H5ïŒ4ãLiAlïŒC7H15ïŒ4ãªã©ãäŸç€ºã§ããã ãŸãïŒïŒã«é¡äŒŒããååç©ãšããŠé žçŽ ååã
çªçŽ ååãä»ããŠïŒä»¥äžã®ã¢ã«ãããŠã ãçµåã
ãææ©ã¢ã«ãããŠã ååç©ã§ãã€ãŠãããããã®
ãããªååç©ãšããŠãäŸãã°ïŒC2H5ïŒ2AlOAl
ïŒC2H5ïŒ2ãïŒC4H9ïŒ2AlOAlïŒC4H9ïŒ2ã
ããªãæ°èŠãªïŒâããã³ç³»ã©ã³ãã å ±éåäœã«é¢
ãããããã«è©³çŽ°ã«ã¯ãéææ§ãè¡šé¢éç²çæ§ã
åŒåŒµç¹æ§åã³ãã®ä»ã®æ§è³ªã«åªããïŒâããã³ç³»
ã©ã³ãã å ±éåäœãããšãã°éææ§ãèãããã
ã³ã°æ§ãªã©ã«åªããå è£ çšãã€ã«ã ãã·ãŒãç¶
ç©ããã®ä»ã®æº¶èæ圢ç©ã®æ圢ã«é©ããïŒâãã
ã³ç³»ã©ã³ãã å ±éåäœã®æäŸã«é¢ããã ãåŸæ¥ã®æè¡ã åŸæ¥ãè»è³ªãããã¯å硬質暹èã®æ圢å¿çšåé
ã«ãããŠã¯å¡©åããã«æš¹èã®äœ¿çšãåªäœã«ãã€ã
ããå»æ£ç©çŒåŽæã«ãããè é£æ§ã¬ã¹ã®çºçãæ®
çã¢ãããŒãå¯å¡å€ã«å¯Ÿããå®å šæ§ãžã®æžå¿µãªã©
ã®åé¡ãããªã¬ãã€ã³ç³»ã®è»è³ªãããã¯å硬質暹
èãžã®è»¢æãæãŸããããã«ãªã€ãŠããã æè¿ããã®ãããªè»è³ªãããã¯å硬質暹èã®æ
圢å¿çšåéã«ãããŠå©çšããããªã¬ãã€ã³ç³»æš¹è
ãšããŠã¯ããšãã¬ã³ç³»å ±éåäœããããã¬ã³ç³»å ±
éåäœãïŒâããã³ç³»å ±éåäœãªã©ã®ãªã¬ãã€ã³
ç³»å ±éåäœãããããããã®ãªã¬ãã€ã³ç³»ã®è»è³ª
ãããã¯å硬質暹èã®ãã¡ã§ãïŒâããã³ãäž»æ
åãšããïŒâããã³ãšãããã¬ã³ãããªãè»è³ªã®
ïŒâããã³ç³»ã©ã³ãã å ±éåäœã«é¢ããŠã¯ãå€æ°
ã®ææ¡ãããããããã®äžã§ç±³åœç¹èš±ç¬¬3278504
å·æ现æžãç±³åœç¹èš±ç¬¬3332921å·æ现æžãç±³åœç¹
蚱第4168361å·æ现æžãè±åœç¹èš±ç¬¬1018341å·æ现
æžã«ã¯ãäžå¡©åãã¿ã³ãåå¡©åãã¿ã³ç³»è§Šåªãçš
ããŠè£œé ããïŒâããã³ç³»ã©ã³ãã å ±éåäœãé
瀺ãããŠããããããããããã®ïŒâããã³ç³»ã©
ã³ãã å ±éåäœã«å ±éããŠããããšã¯ãæ²žéš°é ¢é ž
ã¡ãã«å¯æº¶ååã³ã¢ã»ãã³ã»ïœâãã«ã³æ··å溶åª
ïŒå®¹éæ¯ïŒïŒïŒïŒå¯æº¶åãªã©ã®äœååéåäœæå
ã®å«æçãå€ãããŸãçµæååžãååéååžãåº
ãã®ã§ããããã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœ
ãã圢æããæ圢äœãç¹ã«ãã€ã«ã ãã·ãŒããªã©
ã¯è¡šé¢ç²çæ§ã倧ãããããããã³ã°æ§ãèã
ãããŸãããã®ã»ãšãã©ã®ãã®ã¯ã©ã³ãã æ§ãäœ
ããïœâãããµã³äžæº¶ç©ãå€ãéææ§ã«ãå£ã€ãŠ
ãããåå䟡å€ã®é«ãæ圢åãåŸãããšãã§ããª
ãã€ãã åèšç±³åœç¹èš±ç¬¬3278504å·æ现æžã«ã¯ãïŒâã
ãã³å«æéã30ãªãã70ã¢ã«ïŒ ã®ãããã¬ã³ã»ïŒ
âããã³å ±éåäœãææ¡ãããŠããã該ïŒâãã
ã³ç³»å ±éåäœã¯åå¡©åãã¿ã³ãäžå¡©åãã¿ã³ãçš
ããŠè£œé ãããããšãèšèŒãããŠãããããã®ã
ããªè§Šåªç³»ã§è£œé ãããå ±éåäœã¯æ²žéš°é ¢é žã¡ã
ã«å¯æº¶åã®å«æéãïŒééïŒ ãè¶ãããããã¢ã»
ãã³ã»ïœâãã«ã³æ··å溶åªïŒå®¹éæ¯ïŒïŒïŒïŒå¯æº¶
åã®å«æéãå€ããè¡šé¢ç²çæ§ããããéææ§ã«
å£ãè»è³ªæš¹èã§ããã åèšç±³åœç¹èš±ç¬¬332921å·æ现æžåã³è±åœç¹èš±ç¬¬
1084953å·æ现æžã«ãäžå¡©åãã¿ã³è§ŠåªãçšããŠ
補é ããïŒâããã³å«æçã®ç°ãªãçš®ã ã®ïŒâã
ãã³ç³»å ±éåäœãææ¡ãããŠãããããããã®å ±
éåäœã®äžã§ïŒâããã³å«æéã60ãªãã99ã¢ã«
ïŒ ã®ïŒâããã³ç³»å ±éåäœã¯åèšç±³åœç¹èš±ç¬¬
3278504å·æ现æžææ¡ã®ïŒâããã³ç³»å ±éåäœãš
åæ§ã®æ§è³ªãæããŠããã ãŸããåèšè±åœç¹èš±ç¬¬1018341å·æ现æžã«ãã
ã°ãäžå¡©åãã¿ã³ã®ãããªé·ç§»éå±ãã©ã€ããšãª
ã³é žã®èªå°äœã䜵çšããŠïŒâããã³å«æéã25ãª
ãã90ã¢ã«ïŒ ã®å ±éåäœãåŸãŠããããã®ææ¡ã«
ãããŠå ·äœçã«é瀺ãããå ±éåäœã®ãã¡ã§ãïŒ
âããã³ã®å«æéã50ãªãã90ã¢ã«ïŒ ã®ïŒâãã
ã³ç³»å ±éåäœã«é¢ããŠã¿ããšãã¢ã»ãã³å¯æº¶åã
1.5ééïŒ ä»¥äžã®ãã®ã®ã¿ãé瀺ãããŠãããæ¬
çºæè çã®æ€èšã«ããã°ããããã®å ±éåäœã¯æ²ž
éš°é ¢é žã¡ãã«å¯æº¶åãïŒééïŒ ããããŠããã«å€
ãããŸãã¢ã»ãã³ã»ïœâãã«ã³æ··å溶åªïŒå®¹éæ¯
ïŒïŒïŒïŒå¯æº¶åã®å«æçãïŒÃãηã-1.2ééïŒ ã
è¶ ããŠå€ãã該ïŒâããã³ç³»å ±éåäœããã¯è¡šé¢
ç²çæ§ã倧ãããéææ§ã«å£ã€ãæ圢äœããåŸã
ããšãã§ããªãããšãããã€ãã ããã«ãåèšç±³åœç¹èš±ç¬¬4168361å·æ现æžã«ã¯
ãããã¬ã³ãå«æçã40ãªãã90ã¢ã«ïŒ ã®ç¯å²ã«
ãããããã¬ã³ã»ïŒâããã³å ±éåäœãé瀺ãã
ãŠãããããããã®å ±éåäœã®ãã¡ã§ïŒâããã³
å«æçã50ãªãã60ã¢ã«ïŒ ã®å ±éåäœã«é¢ããŠã
åèšåæ§ã«ãæ¬çºæè çã®æ€èšã«ããã°ãã¢ã»ã
ã³ã»ïœâãã«ã³æ··å溶åªå¯æº¶åã®å«æçãå€ãã
該ïŒâããã³ç³»å ±éåäœããã¯è¡šé¢ç²çæ§ã倧ã
ããéææ§ã«å£ã€ãæ圢äœããåŸãããšãã§ããª
ãã äžæ¹ãäžå¡©åãã¿ã³ç³»è§ŠåªãçšããŠé«æž©ã§éå
ãè¡ãéæ¶è³ªã®ã©ã³ãã å ±éåäœãåŸãæ¹æ³ãç¹
éæ50â38787å·å ¬å ±ã«ææ¡ãããŠããã ãã®æ¹æ³ã§ã¯æ²žéš°ïœâãããµã³äžæº¶åã®å°ãªã
å ±éåäœã¯åŸãããããæ¬çºæè çã®æ€èšã«ãã
ã°ãé ¢é žã¡ãã«å¯æº¶åãïŒééïŒ ããå€ããåŒåŒµ
ç¹æ§ã«é¢ããŠãå£ããæš¹èççšéã«äœ¿çšã§ããª
ãã ãŸããæ¬åºé¡äººã¯ãç¹éæ54â85293å·å ¬å ±ã«
ãããŠçµæååžãçããæ²žéš°é ¢é žã¡ãã«å¯æº¶åã
å°ãªããè¡šé¢ç²çæ§ã®å°ããïŒâããã³ãäž»æå
ãšããïŒâããã³ã»ãããã¬ã³ã©ã³ãã å ±éåäœ
ãææ¡ãããããããªããããã®ææ¡ã«ããæäŸ
ãããïŒâããã³ã»ãããã¬ã³å ±éåäœã®äœåå
éæåã®å«æçããšãã«æ²žéš°é ¢é žã¡ãã«å¯æº¶åã§
è¡šããããäœååééåäœã®å«æçåã³è©²å ±éå
äœãããªãæ圢åã®è¡šé¢ç²çæ§ã¯åŸæ¥ã®ãã®ã«ã
ãã¹ãŠããªãæ¹åãããããšãæããã§ãããã
該ïŒâããã³ç³»ã©ã³ãã å ±éåäœäžã®äœååéé
åäœæåããšãã«ã¢ã»ãã³ã»ïœâãã«ã³æ··å溶åª
ïŒå®¹éæ¯ïŒïŒïŒïŒå¯æº¶åã§è¡šããããäœååéé
åäœæåã®å«æçããªãå€ããèè¡ææ§ã®æ¹åã®
ããã«ããªãããã¬ã³æš¹èã«è©²ïŒâããã³ã»ãã
ãã¬ã³ã©ã³ãã å ±éåäœãé åããæš¹èçµæç©ã®
æ圢åãããšãã°ãã€ã«ã ã¯çµæçã«è¡šé¢ç²çæ§
ãå¢å ãæããªã©ã®æ¬ ç¹ãååšããè¡šé¢éç²çæ§
åã³éææ§ãªã©ã®æ§èœãé«åºŠã«èŠæ±ãããåéã®
çšéã«ãªãå åã§ãããšã¯èšãé£ãã€ãããŸãã
ããã«ãã®ææ¡ã«ãã該ïŒâããã³ã»ãããã¬ã³
ã©ã³ãã å ±éåäœã¯äœçµæ¶æ§ã§ãããåæ§ãªã©å
åŠçç©æ§ã«å£ãããããã®ååŠçç©æ§ãé«åºŠã«èŠ
æ±ãããåéã®çšéã«ããªãäžå åã§ãã€ãã ãçºæã解決ããããšããåé¡ç¹ã æ¬çºæè ãã¯ãåŸæ¥ã®ïŒâããã³ç³»ã©ã³ãã å ±
éåäœã¯äœååéåäœã®å«æçãå€ãã該ïŒâã
ãã³ç³»ã©ã³ãã å ±éåäœããåŸãæ圢äœãè¡šé¢é
ç²çæ§ãéææ§ãåæ§ãªã©ã®ååŠçç©æ§ã«å£ã€ãŠ
ããããšãèªèããåŸæ¥ã®ïŒâããã³ç³»ã©ã³ãã
å ±éåäœã«æ¯ããŠãããã®ç©æ§ã®æ¹åãããïŒâ
ããã³ç³»ã©ã³ãã å ±éåäœãæäŸããããšãç®ç
ãšããŠéçºç 究ãè¡ã€ãŠããã ãã®çµæãæ¬çºæè ãã¯ãïŒâããã³æååã³
ççŽ ååæ°ãïŒä»¥äžã®Î±âãªã¬ãã€ã³æåãããª
ããïŒâããã³æåãäž»æåãšããïŒâããã³ç³»
ã©ã³ãã å ±éåäœã§ãã€ãŠããã€åŸèš(A)ãªãã(I)
ã§å®çŸ©ãããç¹æ§å€ãå ŒåããåŸæ¥å ¬ç¥æç®æªèš
èŒã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœãååšã§ãã
ããšãçºèŠããã€ãã®åæã«æåããã ããã«ããã®æ°èŠïŒâããã³ç³»ã©ã³ãã å ±éå
äœã¯ãåŸæ¥å ¬ç¥ã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœ
ã«ããã¹ãŠäœååééåäœæåããšãã«æ²žéš°é ¢é ž
ã¡ãã«ãžã®å¯æº¶ååã³ã¢ã»ãã³ã»ïœâãã«ã³æ··å
溶åªïŒå®¹éæ¯ïŒïŒïŒïŒãžã®å¯æº¶åã®äž¡è ã§è¡šãã
ããäœååééåäœæåã®å«æçãå°ãªãã該ïŒ
âããã³ç³»ã©ã³ãã å ±éåäœããåŸãæ圢äœã¯è¡š
é¢éç²çæ§ãéææ§ãåæ§ãªã©ã®ååŠçç©æ§ã«ãš
ãã«åªããŠããããšãçºèŠããã åŸã€ãŠãæ¬çºæã®ç®çã¯äž»æåéã®ïŒâããã³
æåãšå°éå²åã®ççŽ ååæ°ãïŒä»¥äžã®Î±âãªã¬
ãã€ã³æåãããªãæ°èŠïŒâããã³ç³»ã©ã³ãã å ±
éåäœãæäŸããããšã«ããã æ¬çºæã®äžèšç®çãªãã³ã«ããã«å€ãã®ä»ã®ç®
çãªãã³ã«å©ç¹ã¯ä»¥äžã®èšèŒã«ããäžå±€æããã«
ãªãã§ãããã ãåé¡ç¹ã解決ããããã®æ段åã³äœçšã æ¬çºæã«ããã°ãïŒâããã³æååã³ççŽ åå
æ°ãïŒä»¥äžã®Î±âãªã¬ãã€ã³æåãããªãïŒâã
ãã³ç³»ã©ã³ãã å ±éåäœã§ãã€ãŠã (A) ãã®çµæããïŒâããã³æåã50ãªãã99ã¢
ã«ïŒ åã³è©²Î±âãªã¬ãã€ã³æåãïŒãªãã50ã¢
ã«ïŒ ã®ç¯å²ã«ããããšã (B) ãã«ãªã³äžã§135âã§æž¬å®ãã極éç²åºŠïŒ»Î·ïŒœ
ã0.5ãªããïŒdlïŒïœã®ç¯å²ã«ããããšã (C) 瀺差走æ»ç±éèšã«ãã€ãŠæž¬å®ããèç¹
Tmã30ãªãã120âã®ç¯å²ã«ããããšã (D) ç·åææ³ã«ãã€ãŠæž¬å®ããçµæ¶å床ãïŒãª
ãã60ïŒ ã®ç¯å²ã«ããããšã (E) æ²žéš°é ¢é žã¡ãã«ãžã®å¯æº¶åéW1ééïŒ ïŒœ
ãïŒééïŒ ä»¥äžã®ç¯å²ã«ããããšã (F) 10âã«ãããã¢ã»ãã³ã»ïœâãã«ã³æ··å溶åª
ïŒå®¹éæ¯ïŒïŒïŒïŒãžã®å¯æº¶åéW2ééïŒ ïŒœã
ïŒÃη-1.2ééïŒ æªæºã®ç¯å²ã«ããããšã (G) éäŒç¹å¿åã10ãªãã200KgïŒcm2ã®ç¯å²ã«ã
ãããšã (H) ç Žæç¹å¿åã100ãªãã1000KgïŒcm2ã®ç¯å²ã«
ããããšã (I) ç Žæç¹äŒžã³ã300ïŒ ä»¥äžã§ããããšã ã«ãã€ãŠç¹åŸŽã¥ããããïŒâããã³ç³»ã©ã³ãã å ±
éåäœãæäŸãããã æ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã«ãã
ãŠãè©²å ±éåäœã®çµæ(A)ã¯ãïŒâããã³æåã50
ãªãã99ã¢ã«ïŒ ã奜ãŸããã¯60ãªãã98ã¢ã«ïŒ ã®
ç¯å²ã«ãããççŽ ååæ°ãïŒä»¥äžã®Î±âãªã¬ãã€
ã³æåãïŒãªãã50ã¢ã«ïŒ ã奜ãŸããã¯ïŒãªãã
40ã¢ã«ïŒ ã®ç¯å²ã«ãããè©²å ±éåäœäžã®ïŒâãã
ã³æåã®å«æçã50ã¢ã«ïŒ ããå°ãããªããã€è©²
αâãªã¬ãã€ã³æåã®å«æçã50ã¢ã«ïŒ ãã倧ã
ããªããšãè©²å ±éåäœã®è¡šé¢éç²çæ§ãåŒåŒµç¹æ§
ãäœäžããããã«ãªããïŒâããã³æåã®å«æç
ã99ã¢ã«ïŒ ãã倧ãããªããã€è©²Î±âãªã¬ãã€ã³
æåã®å«æçãïŒã¢ã«ïŒ ããå°ãããªããšãè©²å ±
éåäœã®éææ§ãäœäžããããã«ãªããæ¬çºæã®
ïŒâããã³ç³»ã©ã³ãã å ±éåäœãæ§æããççŽ å
åæ°ãïŒä»¥äžã®Î±âãªã¬ãã€ã³æåãšããŠã¯ãïŒ
âãã³ãã³ãïŒâããã»ã³ãïŒâã¡ãã«âïŒâã
ã³ãã³ãïŒâã¡ãã«âïŒâãã³ãã³ãïŒâãªã¯ã
ã³ãïŒâãã»ã³ãïŒâããã»ã³ãïŒâããã©ãã»
ã³ãïŒâãããµãã»ã³ãïŒâãªã¯ãã»ã³ãïŒâãš
ã€ã³ã»ã³ãªã©ã®ççŽ ååæ°ãïŒãªãã20ã®Î±âãª
ã¬ãã€ã³ãäŸç€ºããããšãã§ããã æ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã«ãã
ãŠã135âã®ãã«ãªã³äžã§æž¬å®ãã極éç²åºŠãηã
(B)ã¯0.5ãªããïŒã奜ãŸããã¯ïŒãªããïŒdlïŒïœ
ã®ç¯å²ã«ãããηãïŒdlïŒïœãè¶ãããšå ±é
åäœã¯æ圢æ§ãå£ãã0.5dlïŒïœæªæºã§ãããšæ©
械ç匷床ã«å£ãããã®ç¹æ§å€ã¯æ¬çºæã®ïŒâãã
ã³ç³»ã©ã³ãã å ±éåäœã®ååéã瀺ã尺床ã§ã
ããä»ã®ç¹æ§å€ãšçµåããããšã«ãããåè¿°ã®åª
ããæ§è³ªã®ã©ã³ãã å ±éåäœã®æäŸã«çŽç«ã€ãŠã
ãã æ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã®ç€ºå·®
èµ°æ»åç±éèšã«ãã€ãŠæž¬å®ããèç¹ã以äžã
DSCèç¹ãšç¥èšããããšãããã(C)ã¯ã30ãªã
ã120âã奜ãŸããã¯40ãªãã115âã®ç¯å²ã«ã
ããèç¹ã120âãè¶ãããšå ±éåäœã¯æè»æ§ã«
æ¬ ãã30âæªæºã§ãããšããããã³ã°ãããããª
ãã¹ãªããæ§ãäœäžããã該DSCèç¹ãååšã
ãããšã¯ãåŸæ¥ã®éæ¶è³ªã®ïŒâããã³ç³»ã©ã³ãã
å ±éåäœãšåºå¥ãããçµæ¶æ§ãæããå ±éåäœã§
ããããšã瀺ã尺床ã§ãã€ãŠãä»ã®ç¹æ§å€ãšçµå
ããããšã«ãã€ãŠåè¿°ã®åªããæ§è³ªã®å ±éåäœã®
æäŸã«åœ¹ç«ã€ãŠãããããã§ãDSCèç¹ã¯æ圢
20æéçµéåŸã®åã0.1mmã®ãã¬ã¹ã·ãŒãã10
âïŒminã®ææž©é床ã§ïŒã200âãŸã§æž¬å®ããæ
倧åžç±ããŒã¯ãTmãšããã æ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã®ïŒžç·
åææ³ã«ãã€ãŠæž¬å®ããçµæ¶å床(D)ã¯ãïŒãªãã
60ïŒ ã奜ãŸããã¯10ãªãã55ïŒ ã®ç¯å²ã«ãããçµ
æ¶å床ã60ïŒ ãè¶ãããšå ±éåäœã¯æè»æ§ã«æ¬
ããïŒïŒ æªæºã§ãããšããããã³ã°ãããããªã
ã¹ãªããæ§ãäœäžããããã®ç¹æ§å€ã¯ãæ¬çºæã®
ïŒâããã³ç³»ã©ã³ãã å ±éåäœãåŒåŒµç¹æ§ã«åªã
ãããšã瀺ã尺床ã§ãããä»ã®ç¹æ§å€ãšçµåãã
ããšã«ããåè¿°ã®åªããæ§è³ªã®ã©ã³ãã å ±éåäœ
ã®æäŸã«åœ¹ç«ã€ãŠãããçµæ¶å床ã¯æ圢åŸ20æé
çµéåŸã®åã1.5mmã®ãã¬ã¹ã·ãŒãã®ïŒžç·åæ枬
å®ã«ããæ±ããã æ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã«ãã
ãŠãæ²žéš°é ¢é žã¡ãã«ãžã®å¯æº¶åéãW1ééïŒ ã
(E)ã¯ãè©²å ±éåäœã®ééã«åºã¥ããŠïŒééïŒ ä»¥
äžãããšãã°0.01ãïŒééïŒ ã奜ãŸããã¯0.02ã
ïŒééïŒ ã®ç¯å²ã«ããããŸãã該ïŒâããã³ç³»ã©
ã³ãã å ±éåäœã®æ²žéš°é ¢é žã¡ãã«å¯æº¶åéãW1
ééïŒ ãã¯ãããšãã°äžè¬åŒ 0.01âŠW1âŠ0.02aïŒ1.0 ããã«ã¯ã0.02âŠW1âŠ0.015aïŒ0.7 ãšãã«ã¯ã0.03âŠW1âŠ0.01aïŒ0.5 ãåŒäžãïœã¯è©²Î±âãªã¬ãã€ã³æåã®å«æçïŒã¢
ã«ïŒ ïŒã瀺ããã§è¡šããããç¯å²ã«ããã®ã奜ãŸ
ããããã®ç¹æ§å€ã¯æ¬çºæã®ïŒâããã³ç³»ã©ã³ã
ã å ±éåäœã«ãããäœååééåäœæåã®å«æç
ã瀺ããã€è©²å ±éåäœã®çµæååžåã³ååéååž
ã®åºçã瀺ã尺床ã§ãããåŸæ¥ããææ¡ãããŠã
ãïŒâããã«ç³»ã©ã³ãã å ±éåäœã¯è©²æ²žéš°é ¢é žã¡
ãã«å¯æº¶åéãå€ããè¡šé¢éç²çæ§ã«å£ãããã
ããã³ã°æ§ã倧ããåå ã«ãªã€ãŠãããæ¬çºæã®
ïŒâããã³ç³»ã©ã³ãã å ±éåäœã«ããããã®ç¹æ§
å€ã¯ãä»ã®ç¹æ§å€ãšçµåããããšã«ããåè¿°ã®åª
ããæ§è³ªã®å ±éåäœã®æäŸã«åœ¹ç«ã€ãŠãããæ¬çº
æã«ãããŠãè©²æ²žéš°é ¢é žã¡ãã«å¯æº¶åéã¯æ¬¡ã®æ¹
æ³ã§æž¬å®ãããããªãã¡ãïŒmmÃïŒmmÃïŒmmçšåºŠ
ã®çŽ°çè©Šæãåçã¬ã©ã¹ãã€ã«ã¿ãŒã«å ¥ãããªã
ã©ãã¯ã¹é »åºŠãïŒåïŒïŒåçšåºŠã«ããŠãœãã¯ã¹ã¬
ãŒæœåºåšã§ïŒæéæœåºããæœåºæ®åãç空也ç¥åš
ïŒç空床10mmHg以äžïŒã§æéã«ãªããŸã§ä¹Ÿç¥ããŠ
ãã®ééãæ±ããåè©Šæãšã®ééå·®ããæ²žéš°é ¢é ž
ã¡ãã«å¯æº¶åééãæ±ãããæ²žéš°é ¢é žã¡ãã«å¯æº¶
åéãW1ãã¯è©²æ²žéš°é ¢é žã¡ãã«å¯æº¶åééã®å
è©Šæééã«å¯ŸããçŸåçãšããŠæ±ããã æ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã«ãã
ãŠã10âã«ãããã¢ã»ãã³ã»ïœâãã«ã³æ··å溶åª
ïŒæº¶éæ¯ïŒïŒïŒïŒãžã®å¯æº¶åéãW2ééïŒ ã(F)
ã¯ãè©²å ±éåäœã®ééã«åºã¥ããŠãïŒÃãηã-1.2
ééïŒ æªæºãããšãã°0.1Ããηã-1.2ãïŒÃãηã-1.
ïŒééïŒ ã奜ãŸããã¯0.2Ããηã-1.2ãïŒÃãηã-1.
2
ééïŒ ããšãã«å¥œãŸããã¯0.3Ããηã-1.2ãïŒÃ
ãηã-1.2ã®ç¯å²ã«ããïŒããã§ããηãã¯è©²å ±éå
äœã®æ¥µéç²åºŠã®æ°å€ã§ãã€ãŠããã€ã¡ã³ãžãšã³ã
é€ããå€ã瀺ããïŒããã®ç¹æ§å€ã¯ãæ¬çºæã®ïŒâ
ããã³ç³»ã©ã³ãã å ±éåäœã«ãããäœååééå
äœæåã®å«æçã瀺ããã€è©²å ±éåäœã®çµæååž
åã³ååéã®åºçã瀺ã尺床ã§ãããåŸæ¥ããç¥
ãããŠããïŒâããã³ç³»ã©ã³ãã å ±éåäœã¯è©²æ²ž
éš°é ¢é žã¡ãã«å¯æº¶åãå€ããè¡šé¢éç²çæ§ã«å£
ããããããã³æ§ã倧ããåå ã«ãªã€ãŠãããæ¬
çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã«ãããã
ã®ç¹æ§å€ã¯ãä»ã®ç¹æ§å€ãšçµåããããšã«ããã
åè¿°ã®åªããæ§è³ªã®å ±éåäœã®æäŸã«åœ¹ç«ã€ãŠã
ããæ¬çºæã«ãããŠã該混å溶åªäžãžã®å ±éåäœ
ã®å¯æº¶åéã¯æ¬¡ã®æ¹æ³ã«ãã€ãŠæž¬å®æ±ºå®ãããã
ããªãã¡ãæ¹æçŸœæ ¹ä»150mlã®ãã©ã¹ã³ã«ãïŒïœ
ã®å ±éåäœè©Šæã0.05ïœã®ïŒïŒïŒâãžtertâãã
ã«âïŒâã¡ãã«ããšããŒã«ã50mlã®ïœâãã«ã³ã
å ¥ãã120âã®æ²¹æµŽäžã§æº¶è§£ãããã溶解åŸ30å
é宀枩äžã§èªç¶æŸä»€ãã次ãã§50mlã®ã¢ã»ãã³ã
30ç§ã§æ·»å ãã10âã®æ°ŽæµŽäžã§60åéå·åŽããã
æåºããå ±éåäœãšäœååééåäœæåã®æº¶è§£ã
ã溶液ãã°ã©ã¹ãã€ã«ã¿ãŒã§éåé¢ãã溶液ã
10mmHgã§150âã§æéã«ãªããŸã§ä¹Ÿç¥ãããã®é
éã枬å®ããåèšæ··å溶åªäžãžã®å ±éåäœã®å¯æº¶
åéãè©Šæå ±éåäœã®ééã«å¯ŸããçŸåçãšããŠ
ç®åºæ±ºå®ããããªããåèšæž¬å®æ³ã«ãããŠæ¹æã¯
溶解æããéã®çŽåãŸã§é£ç¶ããŠè¡ã€ãã æ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã«ãã
ãŠãFIS K7113ã®æ¹æ³ã«ãã€ãŠæž¬å®ããéäŒç¹å¿
å(G)ã¯10ãªãã200KgïŒcm2ã奜ãŸããã¯20ãªãã
150KgïŒcm2ã®ç¯å²ã«ãããJIS K7113ã®æ¹æ³ã«ã
ã€ãŠæž¬å®ããç Žæç¹å¿å(H)ã¯100ãªãã1000KgïŒ
cm2ã奜ãŸããã¯120ãªãã600KgïŒcm2ã®ç¯å²ã«ã
ããJIS K7113ã®æ¹æ³ã«ãã€ãŠæž¬å®ããç Žæç¹äŒž
ã³(I)ã¯300ïŒ ä»¥äžã奜ãŸããã¯500ãªãã1500ïŒ ã®
ç¯å²ã«ãããéäŒç¹å¿åã200KgïŒcm2ãè¶ ãããã
ç Žæç¹å¿åã1000KgïŒcm2ãè¶ ããããããšå ±éå
äœã¯æè»æ§ã«æ¬ ããéäŒç¹å¿åãïŒKgïŒcm2æªæºã§
ãã€ãããç Žæç¹å¿åã100KgïŒcm2æªæºã®å ±éå
äœã¯æ©æ¢°ç匷床ã«å£ããåç Žæç¹äŒžã³ã300ïŒ æª
æºã®ãã®ã¯æè»æ§ã«æ¬ ãããæ¬çºæã®ïŒâããã³
ç³»ã©ã³ãã å ±éåäœã®éäŒç¹å¿å(G)ãç Žæç¹å¿å
(H)åã³ç Žæç¹äŒžã³(I)ã®ç¹æ§å€ã¯ãåè¿°ã®ä»ã®ç¹æ§
å€ãšçµåããããšã«ãããåè¿°ã®åªããè«žæ§è³ªã
åããå ±éåäœãæäŸããã®ã«åœ¹ç«ã€ãŠããããª
ããæ¬çºæã«ãããŠãåèšéäŒç¹å¿å(G)ãç Žæç¹
å¿å(H)åã³ç Žæç¹äŒžã³(I)ã®ç¹æ§å€ã¯JIS K7113ã®
åŒåŒµè©Šéšã®æ¹æ³ã«åŸã€ãŠæž¬å®ãããããªãã¡ãè©Š
æã¯JIS K6758ã«ãã€ãŠæ圢ããåãïŒmmã®ãã¬
ã¹ã·ãŒãããæ圢19æéåŸã«æã¡æããJIS
K7113ã®ïŒå·åœ¢è©Šéšçãçšãã25âã®é°å²æ°äžã§
åŒåŒµé床50mmïŒminã§äžèšãã¬ã¹ã·ãŒãæ圢20æ
éåŸã«æž¬å®ãããéäŒç¹ãæçã«çŸãããªãå Žå
ã«ã¯ã20ïŒ ã®äŒžã³å¿åãéäŒç¹å¿åãšããã æ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã¯ã以
äžã«è¿°ã¹ã(A)ãªãã(I)ã®ç¹æ§å€ã«ãã€ãŠè¡šããã
ãçµåå åãæºè¶³ããããã«å¥œãŸããæ¬çºæã®ïŒ
âããã³ç³»ã©ã³ãã å ±éåäœã¯æ¬¡ã®(J)ãªãã(L)ã®
ç¹æ§å€ããå 足ããã æ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã®JIS
K6745ã®æ¹æ³ã«ãã€ãŠæž¬å®ãããããåæ§ç(J)ã¯
ããšãã°100ãªãã2000KgïŒcm2ã奜ãŸããã¯150ãª
ãã1500KgïŒcm2ã®ç¯å²ã«ããããããåæ§çã®æž¬
å®æ¹æ³ãšããŠã¯ãJIS K6758ã«ãã€ãŠæ圢ããå
ãïŒmmã®ãã¬ã¹ã·ãŒãããæ圢ïŒæ¥åŸã«æã¡æã
ã瞊64mmã暪635mmã®çåç¶è©Šéšçãçšãããã¬
ã¹ã·ãŒãæ圢10æ¥åŸã25âã®é°å²æ°äžã50ãªãã
60床ã®ãããè§ã§å éåŸïŒç§ã®ã®ã¡ã®å€ã枬å®ã
ãã ãŸããæ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœ
ã®JIS K7113ã®æ¹æ³ã«ãã€ãŠæž¬å®ããã€ã³ã°ç(K)
ã¯ããšãã°200ãªãã4000KgïŒcm2ã奜ãŸããã¯300
ãªãã3000KgïŒcm2ã®ç¯å²ã«ããããŸããæ¬çºæã®
ïŒâããã³ç³»ã©ã³ãã å ±éåäœã®ã€ã³ã°ç(K)ã¯ã
該αâãªã¬ãã€ã³æåã®å«æçïœã¢ã«ïŒ ãšã®é¢ä¿
ã«ãããŠå¥œãŸããã¯äžè¬åŒ 3000â30bâ§ïŒ«â§1000â15b ã«ãã€ãŠè¡šãããããã€ã³ã°çã®æž¬å®ã¯ãåèš
(G)ã(H)åã³(I)ã®æž¬å®ãšåæ§ã®åŒåŒµè©Šéšã®æ¹æ³ã«ã
ã€ãŠè¡ã€ãã æ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã®ïŒâ
ããã³å«æçã®æšæºåå·®å€Ï(L)ã¯ããšãã°0.4αã¢
ã«ïŒ 以äžã奜ãŸããã¯0.3αã¢ã«ïŒ 以äžã§ããïŒåŒ
äžãαã¯è©²ïŒâããã³ç³»ã©ã³ãã å ±éåäœäžã®ç
çŽ ååæ°ãïŒä»¥äžã®Î±âãªã¬ãã€ã³æåã®å«æç
ã¢ã«ïŒ ã瀺ããïŒã該æšæºåå·®å€Ïã¯è©²ïŒâããã³
ç³»ã©ã³ãã å ±éåäœã®ã©ã³ãã æ§ã瀺ã尺床ã§ã
ã€ãŠãåèšç¹æ§å€(A)ãªãã(K)ã«å ããŠããã«ç¹æ§
å€(L)ãæºè¶³ããå ±éåäœã¯ããåªããç©æ§ã瀺
ããæ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã®æš
æºåå·®å€Ïã¯ãè©²å ±éåäœã®çµæååžã«åºã¥ããŠ
次åŒã«ãã€ãŠç®åºæ±ºå®ããããªããè©²å ±éåäœã®
çµæååžã¯ãïœâãã·ã¬ã³æº¶åªã§æœåºæž©åºŠãïŒãª
ãã130âãŸã§ïŒâæ¯ã®æ®µéçã«å€åãããæœåº
åã«ã©ã åå¥æ³ã«ãã€ãŠæž¬å®ãããã®éäžå®æž©åºŠ
ã§ã®æœåºã«ã¯å ±éåäœè©Šæ10ïœã«å¯ŸããŠïœâãã·
ã¬ã³ïŒãçšããïŒæéã®æœåºãè¡ã€ãã ÏïŒãâ«100 0ïŒâïœïŒ2fïŒïœïŒdxã1/2 ããã§ãã¯å ±éåäœã®ïŒâããã³ã®å¹³åå«æ
çïŒã¢ã«ïŒ ïŒã瀺ããïœã¯ïŒâããã³å«æçïŒã¢
ã«ïŒ ïŒãïœïŒïœïŒã¯ïŒâããã³å«æéïœïŒã¢ã«ïŒ ïŒ
ãæã€æåã®åŸ®åééåçã瀺ãã æ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã¯ãçµ
æ¶åãåã«åºå®ãããã®ã§ç©æ§ã®çµæå€åãå°
ãããšããç¹åŸŽããããããã«å¯ŸããŠãããšãã°
ïŒâããã³ã®åç¬éåäœã«ã¯ïŒçš®é¡ã®çµæ¶åïŒ
åãåããã³åïŒãååšãã枩床ãæéã®å€
åã«ã€ããŠçžäºã®çµæ¶è»¢ç§»ãèµ·ããããšãç¥ãã
ãŠããããšãã«å®€æž©äžã§ã¯çŽå®å®ãªåçµæ¶åœ¢æ
ããå®å®ãªåçµæ¶åœ¢æ ãžã®è»¢ç§»ãé ãããã«ã
å®éã®æ圢åãžã®å¿çšã«éããŠã¯æ圢åã®å€åœ¢ã
ç©æ§ã®çµæå€åçã®çš®ã ã®å°é£ã䌎ãªããªã©ã®æ¬
ç¹ããã€ãã æ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã«ã¯ã
åè¿°ã®è«žç©æ§ãæãªãããšããªãéãã埮éã®ä»
ã®Î±âãªã¬ãã€ã³ãããšãã°ãšãã¬ã³ããããã¬
ã³ãªã©ãå ±éåãããŠããŠãããã æ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã¯ãã
ãšãã°ã (a) ãã°ãã·ãŠã ååç©ããã¿ã³ååç©ããžãšã¹
ãã«åã³å¿ èŠã«å¿ããŠããã²ã³ååç©ïŒãã°ã
ã·ãŠã ååç©åã¯ãã¿ã³ååç©ãããã²ã³åå
ãå«ãå Žåã«ã¯å¿ ããããå¿ èŠãšããªãïŒãçž
äºã«åå¿ãããããšã«ãã€ãŠåœ¢æããããã°ã
ã·ãŠã ããã¿ã³ãããã²ã³åã³ãžãšã¹ãã«ãå¿
é æåãšããé«æŽ»æ§ãã¿ã³è§Šåªæåã (b) ææ©ã¢ã«ãããŠã ååç©è§Šåªæåãåã³ (c) Siââçµåãæããææ©ç¡ çŽ ååç©è§Šåª
æåã ãã圢æããã觊åªã®ååšäžã«ãçŽ20ãªããçŽ
200âã®æž©åºŠã§ïŒâããã³åã³Î±âãªã¬ãã€ã³ã
å ±éåãããããšã«ãã€ãŠåŸãããšãã§ããã觊
åªæåãå ±éåæ¡ä»¶ããã®ä»ã®å ±éåäœè£œé æ¡ä»¶
ã¯ä»¥äžã«è©³ããè¿°ã¹ãããã«ãæ¬çºæã®å ±éåäœ
ã«åèšç¹æ§(A)ãªãã(I)ãç®å®ãšããŠãå®éšçã«å®¹
æã«éžæèšå®ããããšãã§ãããæ¬çºæã«ãã
ãŠãåŸæ¥ã®æç®æªèšèŒã®ç¹æ§å€ãæããæ¬çºæã®
ïŒâããã³ç³»ã©ã³ãã å ±éåäœã®ååšãªãã³ã«ã
ã®å ±éåäœã®ååšãªãã³ã«ãã®å ±éåäœã®åªãã
æ§è³ªãæããã«ããããã®ã§ãããããæ¬çºæã®
å ±éåäœã«ç¹å®ãããç¹æ§å€(A)ãªãã(I)ãããã«
è£å©çãªç¹æ§å€(J)ãªããã(L)ãç®å®ã«ããŠãæ¬çº
æã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã®è£œé æ¡ä»¶ã
å®éšçã«å®æã«ãã€é©å®ã«éžæèšå®ããããšãã§
ããã é«æŽ»æ§ãã¿ã³è§Šåªæå(a)ã¯ããã°ãã·ãŠã ãã
ã¿ã³ãããã²ã³ããã³ãžãšã¹ãã«ãå¿ é æåãšã
ãŠå«æããããã®ãããªãã¿ã³è§Šåªæå(a)ãšããŠ
ã¯ããã°ãã·ãŠã ïŒãã¿ã³ïŒååæ¯ïŒã奜ãŸãã
ã¯çŽïŒãªããçŽ100ãäžå±€å¥œãŸããã¯çŽïŒãªãã
çŽ70ãããã²ã³ïŒãã¿ã³ïŒååæ¯ïŒã奜ãŸããã¯
çŽïŒãªããçŽ100ãäžå±€å¥œãŸããã¯çŽïŒãªããçŽ
40ããžãšã¹ãã«ïŒãã¿ã³ïŒã¢ã«æ¯ïŒã奜ãŸããã¯
çŽ0.2ãªããçŽ10ãäžå±€å¥œãŸããã¯çŽ0.4ãªããçŽ
ïŒã®ç¯å²ã«ããã®ã奜ãŸããããŸãããã®æ¯è¡šé¢
ç©ã¯ã奜ãŸããã¯çŽïŒm2ïŒïœä»¥äžãäžå±€å¥œãŸãã
ã¯çŽ40m2ïŒïœä»¥äžãããã«å¥œãŸããã¯çŽ100m2ïŒ
ïœãªããçŽ800m2ïŒïœã§ããã ãã®ãããªãã¿ã³è§Šåªæå(a)ã¯ã宀枩ã«ããã
ãããµã³æŽæµã®ãããªç°¡åãªæ段ã«ãã€ãŠå®è³ªç
ã«ãã¿ã³ååç©ãè±é¢ããªãã®ãæ®éã§ãããã
ã®ïŒžç·ã¹ãã¯ãã«ã觊åªèª¿è£œã«çšããåæãã°ã
ã·ãŠã ååç©ã®åŠäœã«ãããããããã°ãã·ãŠã
ååç©ã«é¢ããŠéæ¶æ§ã瀺ããããŸãã¯ãã°ãã·
ãŠã ãžãã©ã€ãã®éåžžã®åžè²©åã®ããã«æ¯ã¹ã奜
ãŸããã¯éåžžã«éæ¶åãããç¶æ ã«ããã ãã¿ã³è§Šåªæå(a)ã¯ãåèšå¿ é æå以å€ã«ã觊
åªæ§èœã倧ããæªåãããªãé床ã«ãããŠãä»ã®
å çŽ ãéå±ãå®èœåºãé»åäŸäžäœãªã©ãå«æããŠ
ããŠããããããã«æç¡ãç¡æ©ã®åžéå€ã§åžéã
ããŠããŠããããä»ã®å çŽ ãéå±ãåžéå€ãªã©ã
å«æããå Žåã«ã¯ãæ¯è¡šé¢ç©ãéæ¶æ§ã«åœ±é¿ãå
ãŒãããšãããããã®å Žåã«ã¯ããã®ãããªä»æ
åãé€å»ãããšãã«åè¿°ãããããªæ¯è¡šé¢ç©ã®å€
ã瀺ããã€éæ¶æ§ã瀺ããã®ã§ããããšã奜ãŸã
ãã ãã¿ã³è§Šåªæå(a)ã補é ããã«ã¯ããã°ãã·ãŠ
ã ååç©ïŒãŸãã¯ãã°ãã·ãŠã éå±ïŒããã¿ã³å
åç©ããã³ãžãšã¹ãã«ãŸãã¯ãžãšã¹ãã«åœ¢ææ§å
åç©ïŒãžãšã¹ãã«ã圢æããååç©ïŒããä»ã®å
å¿è©Šå€ãçšããŸãã¯çšããããŠçžäºã«æ¥è§Šããã
æ¹æ³ãæ¡çšããã®ãããããã®èª¿è£œã¯ããã°ãã·
ãŠã ããã¿ã³ãããã²ã³ããã³é»åäŸäžäœãå¿ é
æåãšããåŸæ¥å ¬ç¥ã®é«æŽ»æ§ãã¿ã³è§Šåªæåã®èª¿
補æ³ãšåæ§ã«è¡ãããšãã§ãããäŸãã°ãç¹éæ
50â108385å·ãå50â126590å·ãå50â20297å·ã
å51â28189å·ãå51â64586å·ãå51â92885å·ã
å51â136625å·ãå52â87489å·ãå52â100596
å·ãå52â147688å·ãå52â104593å·ãå53â
2580å·ãå53â40093å·ãå53â43094å·ãå55â
135102å·ãå55â135103å·ãå56â811å·ãå56
â11908å·ãå56â118606å·ãªã©ã«é瀺ãããæ¹
æ³ã«æºããŠè£œé ããããšãã§ããã ããããã¿ã³è§Šåªæå(a)ã®è£œé æ¹æ³ã®æ°äŸã«ã€
ããŠã以äžã«äŸç€ºããã (1) ãã°ãã·ãŠã ååç©ãããã¯ãã°ãã·ãŠã å
åç©ãšé»åäŸäžäœã®é¯ååç©ããé»åäŸäžäœã
ç²ç å©å€çã®ååšäžãŸãã¯äžååšäžã«ãç²ç ã
ãŸãã¯ç²ç ããããšãªããé»åäŸäžäœããã³ïŒ
ãŸãã¯ææ©ã¢ã«ãããŠã ååç©ãããã²ã³å«æ
ã±ã€çŽ ååç©ã®ãããªåå¿å©å€ã§äºååŠçãã
ãŸãã¯äºååŠçããã«åŸãåºäœãšãåå¿æ¡ä»¶äž
ã«æ¶²çžããªããã¿ã³ååç©ãšãåå¿ããããäœ
ããäžèšé»åäŸäžäœãå°ãªããšãäžåã¯äœ¿çšã
ãã (2) éå èœãæããªããã°ãã·ãŠã ååç©ã®æ¶²ç¶
ç©ãšã液ç¶ãã¿ã³ååç©ãé»åäŸäžäœã®ååšäž
ã§åå¿ãããŠåºäœç¶ã®ãã¿ã³è€åäœãæåºãã
ãã (3) (2)ã§åŸããããã®ã«ããã¿ã³ååç©ãããã«
åå¿ãããã (4) (1)ã(2)ã§åŸããããã®ã«é»åäŸäžäœããã³ã
ã¿ã³ååç©ãããã«åå¿ãããã (5) ãã°ãã·ãŠã ååç©ãããã¯ãã°ãã·ãŠã å
åç©ãšé»åäŸäžäœã®é¯ååç©ããé»åäŸäžäœã
ç²ç å©å€çã®ååšäžãŸãã¯äžååšäžã«ãããã³
ãã¿ã³ååç©ã®ååšäžã«ç²ç ããé»åäŸäžäœã
ãã³ïŒãŸãã¯ææ©ã¢ã«ãããŠã ååç©ãããã²
ã³å«æã±ã€çŽ ååç©ã®ãããªåå¿å©å€ã§äºååŠ
çãããŸãã¯äºååŠçããã«åŸãåºäœãããã
ã²ã³ãŸãã¯ããã²ã³ååç©ãŸãã¯è³éŠæçåæ°Ž
çŽ ã§åŠçãããäœããäžèšé»åäŸäžäœãå°ãªã
ãšãäžåã¯äœ¿çšããã ãããã®èª¿è£œæ³ã®äžã§ã¯ã觊åªèª¿è£œã«ãããŠã
液ç¶ã®ããã²ã³åãã¿ã³ã䜿çšãããã®ãããã¯
ãã¿ã³ååç©äœ¿çšåŸããããã¯äœ¿çšã®éã«ããã²
ã³åçåæ°ŽçŽ ã䜿çšãããã®ã奜ãŸããã äžèšèª¿è£œã«ãããŠçšããããé»åäŸäžäœã¯ããž
ãšã¹ãšã«ãŸãã¯ãžãšã¹ãã«åœ¢ææ§ååç©ã®ã¿ã§ã
ãå¿ èŠã¯ãªããããšãã°ã¢ã«ã³ãŒã«ãããšããŒ
ã«ãã¢ã«ããããã±ãã³ããšãŒãã«ãã«ã«ãã³
é žãã«ã«ãã³é žç¡æ°Žç©ãçé žãšã¹ãã«ãã¢ããšã¹
ãã«ãã¢ãã³ãªã©ãžãšã¹ãã«ä»¥å€ã®é»åäŸäžäœã
䜿çšããããšãã§ããã é«æŽ»æ§ãã¿ã³è§Šåªæå(a)äžã®å¿ é æåã§ãããž
ãšã¹ãã«ãšããŠã¯ãïŒåã®ççŽ ååã«ïŒåã®ã«ã«
ããã·ã«åºãçµåããŠãããžã«ã«ãã³é žã®ãšã¹ã
ã«ãããã¯çžé£ãïŒåã®ççŽ ååã«ããããã«ã«
ããã·ã«åºãçµåããŠãããžã«ã«ãã³é žã®ãšã¹ã
ã«ã§ããããšã奜ãŸããããã®ãããªãžã«ã«ãã³
é žã®ãšã¹ãã«ã«ããããžã«ã«ãã³é žã®äŸãšããŠ
ã¯ãããã³é žã眮æããã³é žãã³ãã¯é žã眮æã³
ãã¯é žããã¬ã€ã³é žã眮æãã¬ã€ã³é žãããã«
é žã眮æããã«é žãèç°ã圢æããïŒåã®ççŽ å
åã«ïŒåã®ã«ã«ããã·ã«åºãçµåããèç°ãžã«ã«
ãã³é žãèç°ã圢æããçžé£ãïŒåã®ççŽ ååã«
ããããã«ã«ããã·ã«åºãçµåããèç°ãžã«ã«ã
ã³é žããªã«ãœäœã«ã«ã«ããã·ã«åºãæããè³éŠæ
ãžã«ã«ãã³é žãè€çŽ ç°ã圢æããçžé£ãïŒåã®ç
çŽ ååã«ã«ã«ããã·ã«åºãæããè€çŽ ç°ãžã«ã«ã
ã³é žãªã©ã®ãžã«ã«ãã³é žã®ãšã¹ãã«ãæããããš
ãã§ããã äžèšãžã«ã«ãã³é žã®ããå ·äœçãªäŸãšããŠã¯ã
ããã³é žïŒã¡ãã«ããã³é žããšãã«ããã³é žãã€
ãœãããã«ããã³é žãã¢ãªã«ïŒallylïŒããã³é žã
ããšãã«ããã³é žããªã©ã®çœ®æããã³é žïŒã³ãã¯
é žïŒã¡ãã«ã³ãã¯é žããžã¡ãã«ã³ãã¯é žããšãã«
ã³ãã¯é žãã¡ãã«ãšãã«ã³ãã¯é žãã€ã¿ã³ã³é žãª
ã©ã®çœ®æã³ãã¯é žïŒãã¬ã€ã³é žïŒã·ãã©ã³ã³é žã
ãžã¡ãã«ãã¬ã€ã³é žãªã©ã®çœ®æãã¬ã€ã³é žïŒã·ã¯
ããã³ã¿ã³âïŒïŒïŒâãžã«ã«ãã³é žãã·ã¯ããã³
ã¿ã³âïŒïŒïŒâãžã«ã«ãã³é žãã·ã¯ããããµã³â
ïŒïŒïŒâãžã«ã«ãã³é žãã·ã¯ãããã»ã³âïŒïŒïŒ
âãžã«ã«ãã³é žãã·ã¯ãããã»ã³âïŒïŒïŒâãžã«
ã«ãã³é žãã·ã¯ãããã»ã³âïŒïŒïŒâãžã«ã«ãã³
é žãããžãã¯é žãã¡ãã«ããžãã¯é žãïŒâã¢ãªã«
ã·ã¯ããããµã³âïŒïŒïŒâãžã«ã«ãã³é žãªã©ã®è
ç°æãžã«ã«ãã³é žïŒãã¿ã«é žãããã¿ãªã³âïŒïŒ
ïŒâãžã«ã«ãã³é žãããã¿ãªã³âïŒïŒïŒâãžã«ã«
ãã³é žãªã©ã®è³éŠæãžã«ã«ãã³é žïŒãã©ã³âïŒïŒ
ïŒâãžã«ã«ãã³é žãïŒïŒïŒâãžããããã©ã³â
ïŒïŒïŒâãžã«ã«ãã³é žããã³ãŸãã©ã³âïŒïŒïŒâ
ãžã«ã«ãã³é žããããŒã«âïŒïŒïŒâãžã«ã«ãã³
é žãããªãžã³âïŒïŒïŒâãžã«ã«ãã³é žãããªããš
ã³âïŒïŒïŒâãžã«ã«ãã³é žãã€ã³ããŒã«âïŒïŒïŒ
âãžã«ã«ãã³é žãªã©ã®è€çŽ ç°ãžã«ã«ãã³é žïŒã®åŠ
ããžã«ã«ãã³é žãäŸç€ºããããšãã§ããã äžèšãžã«ã«ãã³é žã®ãšã¹ãã«ã®ã¢ã«ã³ãŒã«æå
ã®ãã¡å°ãªããšãäžæ¹ãççŽ æ°ïŒä»¥äžããšãã«ã¯
ççŽ æ°ïŒä»¥äžã®ãã®ã奜ãŸããããšãããäž¡ã¢ã«
ã³ãŒã«æåãšãã«ççŽ æ°ïŒä»¥äžããšãã«ãªççŽ æ°
ïŒä»¥äžã®ãã®ã奜ãŸãããäŸãã°äžèšãžã«ã«ãã³
é žã®ãžãšãã«ãšã¹ãã«ããžã€ãœãããã«ãšã¹ã
ã«ããžïœâãããã«ãšã¹ãã«ããžïœâããã«ãšã¹
ãã«ããžã€ãœããã«ãšã¹ãã«ããžâtertâããã«
ãšã¹ãã«ããžã€ãœã¢ãã«ãšã¹ãã«ããžïœâããã·
ã«ãšã¹ãã«ããžâïŒâãšãã«ããã·ã«ãšã¹ãã«ã
ãžïœâãªã¯ãã«ãšã¹ãã«ããžã€ãœãã·ã«ãšã¹ã
ã«ããšãã«ïœâããã«ãšã¹ãã«ãªã©ãäŸç€ºããã
ãšãã§ããã åèšé«æŽ»æ§ãã¿ã³è§Šåªæå(a)ã®èª¿è£œã«çšããã
ããã°ãã·ãŠã ååç©ã¯éå èœãæãããŸãã¯æ
ããªããã°ãã·ãŠã ååç©ã§ãããåè ã®äŸãšã
ãŠã¯ãã°ãã·ãŠã ã»ççŽ çµåããã°ãã·ãŠã ã»æ°Ž
çŽ çµåãæãããã°ãã·ãŠã ååç©ãäŸãã°ãžã¡
ãã«ãã°ãã·ãŠã ããžãšãã«ãã°ãã·ãŠã ããžã
ããã«ãã°ãã·ãŠã ããžããã«ãã°ãã·ãŠã ããž
ã¢ãã«ãã°ãã·ãŠã ããžããã·ã«ãã°ãã·ãŠã ã
ãžãã·ã«ãã°ãã·ãŠã ããšãã«å¡©åãã°ãã·ãŠ
ã ããããã«å¡©åãã°ãã·ãŠã ãããã«å¡©åãã°
ãã·ãŠã ãããã·ã«å¡©åãã°ãã·ãŠã ãã¢ãã«å¡©
åãã°ãã·ãŠã ãããã«ãšããã·ãã°ãã·ãŠã ã
ãšãã«ããã«ãã°ãã·ãŠã ãããã«ãã°ãã·ãŠã
ãã€ãã©ã€ããªã©ãããããããããããã°ãã·
ãŠã ååç©ã¯ãäŸãã°ææ©ã¢ã«ãããŠã çãšã®é¯
ååç©ã®ç³»ã§çšããäºãã§ãããŸã液ç¶ç¶æ ã§ã
ã€ãŠãåºäœç¶æ ã§ãã€ãŠããããåŸè ã®éå èœã
æããªããã°ãã·ãŠã ååç©ã®äŸãšããŠã¯ãå¡©å
ãã°ãã·ãŠã ãèåãã°ãã·ãŠã ãæ²åãã°ãã·
ãŠã ãåŒåãã°ãã·ãŠã ã®ãããªããã²ã³åãã°
ãã·ãŠã ïŒã¡ããã·å¡©åãã°ãã·ãŠã ããšããã·
å¡©åãã°ãã·ãŠã ãã€ãœããããã·å¡©åãã°ãã·
ãŠã ããããã·å¡©åãã°ãã·ãŠã ããªã¯ããã·å¡©
åãã°ãã·ãŠã ã®ãããªã¢ã«ã³ãã·ãã°ãã·ãŠã
ãã©ã€ãïŒããšããã·å¡©åãã°ãã·ãŠã ãã¡ãã«
ããšããã·å¡©åãã°ãã·ãŠã ã®ãããªã¢ãªããã·
ãã°ãã·ãŠã ãã©ã€ãïŒãšããã·ãã°ãã·ãŠã ã
ã€ãœããããã·ãã°ãã·ãŠã ããããã·ãã°ãã·
ãŠã ãïœâãªã¯ããã·ãã°ãã·ãŠã ãïŒâãšãã«
ãããœãã·ãã°ãã·ãŠã ã®ãããªã¢ã«ã³ãã·ãã°
ãã·ãŠã ïŒããšããã·ãã°ãã·ãŠã ããžã¡ãã«ã
ãšããã·ãã°ãã·ãŠã ã®ãããªã¢ãªããã·ãã°ã
ã·ãŠã ïŒã©ãŠãªã³é žãã°ãã·ãŠã ãã¹ãã¢ãªã³é ž
ãã°ãã·ãŠã ã®ãããªãã°ãã·ãŠã ã®ã«ã«ãã³é ž
å¡©ãªã©ãäŸç€ºããããšãã§ããããŸãããããé
å èœãæããªããã°ãã·ãŠã ååç©ã¯ãäžè¿°ãã
éå èœãæãããã°ãã·ãŠã ååç©ããèªå°ãã
ãã®ãããã¯ã觊åªæåã®èª¿è£œæã«èªå°ãããã®
ã§ãã€ãŠãããããŸãã該ãã°ãã·ãŠã ååç©ã¯
éå±ãšã®é¯ååç©ãè€ååç©ãããã¯ä»ã®éå±å
åç©ãšã®æ··åç©ã§ãã€ãŠããããããã«ãããã®
ååç©ã®ïŒçš®ä»¥äžã®æ··åç©ã§ãã€ãŠãããããã
ãã®äžã§å¥œãŸãããã°ãã·ãŠã ååç©ã¯éå èœã
æããªãååç©ã§ãããç¹ã«å¥œãŸããã¯ããã²ã³
å«æãã°ãã·ãŠã ååç©ããšãããå¡©åãã°ãã·
ãŠã ãã¢ã«ã³ãã·å¡©åãã°ãã·ãŠã ãã¢ãªããã·
å¡©åãã°ãã·ãŠã ã§ããã ãã¿ã³è§Šåªæå(a)ã®èª¿è£œã«çšãããããã¿ã³å
åç©ãšããŠäŸãã°TiïŒORïŒgX4-gïŒïŒ²ã¯çåæ°ŽçŽ
åºãã¯ããã²ã³ãïŒâŠïœâŠïŒïŒã§ç€ºãããïŒäŸ¡
ã®ãã¿ã³ååç©ã奜é©ã§ãããããå ·äœçã«ã¯ã
TiCl4ãTiBr4ãTiI4ãªã©ã®ããã©ããã²ã³åã
ã¿ã³ïŒTiïŒOCH3ïŒCl3ãTiïŒOc2H5ïŒCl3ãTiïŒOn
âC4H9ïŒCl3ãTiïŒOC2H5ïŒBr3ãTiïŒOi80C4H9ïŒ
Br3ãªã©ã®ããªããã²ã³åã¢ã«ã³ãã·ãã¿ã³ïŒ TiïŒOCH3ïŒ2Cl2ãTiïŒOC2H5ïŒ2Cl2ãTiïŒOnâ
C4H9ïŒCl3ãTiïŒOC2H5ïŒ2Br2ãªã©ã®ãžããã²ã³å
ã¢ã«ã³ãã·ãã¿ã³ïŒTiïŒOCH3ïŒ3ClãTiïŒOC2H5ïŒ
ClãTiïŒOnâC4H9ïŒ3ClãTiïŒOC2H5ïŒ3Brãªã©ã®ã¢
ãããã²ã³åããªã¢ã«ã³ãã·ãã¿ã³ïŒTi
ïŒOCH3ïŒ4ãTiïŒOC2H5ïŒ4ãTiïŒOnâC4H9ïŒ4ãªã©ã®
ããã©ã¢ã«ã³ãã·ãã¿ã³ãªã©ãäŸç€ºããããšãã§
ããããããã®äžã§å¥œãŸãããã®ã¯ããã²ã³å«æ
ãã¿ã³ååç©ããšãã«ã¯ããã©ããã²ã³åãã¿ã³
ã§ããããšãã«å¥œãŸããã®ã¯åå¡©åãã¿ã³ã§ã
ããããããã¿ã³ååç©ã¯åå³ã§çšããŠããã
ããæ··åç©ã®åœ¢ã§çšããŠãããããããã¯çåæ°Ž
çŽ ãããã²ã³çåæ°ŽçŽ ãªã©ã«åžéããŠçšããŠãã
ãã ãã¿ã³è§Šåªæå(a)ã®èª¿è£œã«ãããŠããã¿ã³åå
ç©ããã°ãã·ãŠã ååç©ããã³æ æãã¹ãé»åäŸ
äžäœãããã«å¿ èŠã«å¿ããŠäœ¿çšãããããšã®ãã
é»åäŸå®¹äœãäŸãã°ã¢ã«ã³ãŒã«ãããšããŒã«ãã¢
ãã«ã«ãã³é žãšã¹ãã«ãªã©ãã±ã€çŽ ååç©ãã¢ã«
ãããŠã ååç©ãªã©ã®äœ¿çšéã¯ã調補æ¹æ³ã«ãã€
ãŠç°ãªãäžæŠã«èŠå®ã§ããªãããäŸãã°ããã°ã
ã·ãŠã ååç©ïŒã¢ã«åœããæ æãã¹ãé»åäŸäžäœ
çŽ0.1ãªããçŽ10ã¢ã«ããã¿ã³ååç©çŽ0.05ãªã
ãçŽ1000ã¢ã«çšåºŠã®å²åãäŸç€ºããããšãã§ã
ãã 以äžã®ããã«ããŠåŸãããé«æŽ»æ§ãã¿ã³è§Šåªæ
å(a)ãšãææ©ã¢ã«ãããŠã ååç©è§Šåªæåïœãã
ã³Siââçµåãæããææ©ã±ã€çŽ ååç©è§Šåª
æå(c)ã®çµåã觊åªãçšããã äžèš(d)æåãšããŠã¯ãïŒïŒå°ãªããšãååå
ã«ïŒåã®AlâççŽ çµåãæããææ©ã¢ã«ãããŠ
ã ååç©ãäŸãã°äžè¬åŒ R1mAlïŒOR2ïŒnHpXq ïŒããã§R1ããã³R2ã¯ççŽ ååãéåžžïŒãªãã
15åã奜ãŸããã¯ïŒã®ãªããïŒåãå«ãçåæ°ŽçŽ
åºã§äºãã«åäžã§ãç°ãªã€ãŠããŠããããã¯ã
ãã²ã³ãïœã¯ïŒïŒïœâŠïŒãïŒâŠïœïŒïŒãïœã¯ïŒâŠ
ïœïŒïŒãïœã¯ïŒâŠïœïŒïŒã®æ°ã§ãã€ãŠããããïœ
ïŒïœïŒïœïŒïœïŒïŒã§ããïŒã§è¡šããããææ©ã¢ã«
ãããŠã ååç©ãïŒïŒäžè¬åŒ M1AlR1 ïŒããã§M1ã¯LiãNaãã§ãããR1ã¯åèšãšå
ãïŒã§è¡šãããã第ïŒæéå±ãšã¢ã«ãããŠã ãšã®
é¯ã¢ã«ãã«åç©ãªã©ãæããããšãã§ããã åèšã®ïŒïŒã«å±ããææ©ã¢ã«ãããŠã ååç©
ãšããŠã¯ã次ã®ãã®ãäŸç€ºã§ãããäžè¬åŒ R1mAlïŒOR2ïŒ3-n ïŒããã§R1ã¯åèšãšåããã¯ããã²ã³ãïœã¯
奜ãŸããã¯ïŒïŒïœïŒïŒã§ãããïŒãäžè¬åŒ R1mAlH3-n ïŒããã§R1ã¯åèšãšåããïœã¯å¥œãŸããã¯ïŒâŠ
ïœïŒïŒã§ãããïŒãäžè¬åŒ R1mAlïŒOR2ïŒnXq ïŒããã§R1ããã³R2ã¯åèšãšåããã¯ããã²
ã³ãïŒïŒïœâŠïŒãïŒâŠïœïŒïŒãïŒâŠïœïŒïŒã§ãïœ
ïŒïœïŒïœïŒïŒã§ããïŒã§è¡šãããããã®ãªã©äŸç€º
ã§ããã ïŒïŒã«å±ããã¢ã«ãããŠã ååç©ã®äŸãšããŠ
ã¯ã以äžã®åŠãååç©ãäŸç€ºããŠãããããªãšã
ã«ã¢ã«ãããŠã ãããªããã«ã¢ã«ãããŠã ãªã©ã
ããªã¢ã«ãã«ã¢ã«ãããŠã ïŒããªã€ãœãã¬ãã«ã¢
ã«ãããŠã ã®ãããªããªã¢ã«ã±ãã«ã¢ã«ãããŠ
ã ïŒãžãšãã«ã¢ã«ãããŠã ãšããã·ãããžããã«
ã¢ã«ããŠã ãããã·ããªã©ã®åŠããžã¢ãã«ã¢ã«ã
ããŠã ã¢ã«ã³ãã·ãïŒãšãã«ã¢ã«ãããŠã ã»ã¹ã
ãšããã·ããããã«ã¢ã«ãããŠã ã»ã¹ããããã·
ããªã©ã®åŠãã¢ã«ãã«ã¢ã«ãããŠã ã»ã¹ãã¢ã«ã³
ãã·ãã®ã»ãã«ãR1 2.5AlïŒOR2ïŒ0.5ãªã©ã§è¡šããã
ãå¹³åçµæãæããéšåçã«ã¢ã«ã³ãã·åããã
ã¢ã«ãã«ã¢ã«ãããŠã ïŒãžãšãã«ã¢ã«ãããŠã ã¯
ããªãããžããã«ã¢ã«ãããŠã ã¯ããªãããžãšã
ã«ã¢ã«ãããŠã ããããã®ãããªãžã¢ã«ãã«ã¢ã«
ãããŠã ãã©ã€ãïŒãšãã«ã¢ã«ãããŠã ã»ã¹ãã¯
ããªããããã«ã¢ã«ãããŠã ã»ã¹ãã¯ããªãããš
ãã«ã¢ã«ãããŠã ã»ã¹ãããããã®ãããªã¢ã«ã
ã«ã¢ã«ãããŠã ã»ã¹ããã©ã€ãïŒãšãã«ã¢ã«ãã
ãŠã ãžã¯ããªãããããã«ã¢ã«ãããŠã ãžã¯ããª
ããããã«ã¢ã«ãããŠã ãžãããããªã©ã®ãããª
ã¢ã«ãã«ã¢ã«ãããŠã ãžãã©ã€ããªã©ã®éšåçã«
ããã²ã³åãããã¢ã«ãã«ã¢ã«ãããŠã ïŒãžãšã
ã«ã¢ã«ãããŠã ãããªãããžããã«ã¢ã«ãããŠã
ãããªããªã©ã®åŠããžã¢ã«ãã«ã¢ã«ãããŠã ãã
ãªãïŒãšãã«ã¢ã«ãããŠã ãžãããªãããããã«
ã¢ã«ãããŠã ãžãããªããªã©ã®åŠãã¢ã«ãã«ã¢ã«
ãããŠã ãžãããªããªã©ããã®ä»ã®éšåçã«æ°ŽçŽ
åãããã¢ã«ãã«ã¢ã«ãããŠã ïŒãšãã«ã¢ã«ãã
ãŠã ãšããã·ã¯ããªããããã«ã¢ã«ãããŠã ãã
ãã·ã¯ããªãããšãã«ã¢ã«ãããŠã ãšããã·ãã
ãããªã©ã®éšåçã«ã¢ã«ã³ãã·åããã³ããã²ã³
åãããã¢ã«ãã«ã¢ã«ãããŠã ã åèšïŒïŒã«å±ããååç©ãšããŠã¯ãLiAl
ïŒC2H5ïŒ4ãLiAlïŒC7H15ïŒ4ãªã©ãäŸç€ºã§ããã ãŸãïŒïŒã«é¡äŒŒããååç©ãšããŠé žçŽ ååã
çªçŽ ååãä»ããŠïŒä»¥äžã®ã¢ã«ãããŠã ãçµåã
ãææ©ã¢ã«ãããŠã ååç©ã§ãã€ãŠãããããã®
ãããªååç©ãšããŠãäŸãã°ïŒC2H5ïŒ2AlOAl
ïŒC2H5ïŒ2ãïŒC4H9ïŒ2AlOAlïŒC4H9ïŒ2ã
ãåŒããªã©ãäŸç€ºã§ããã
ãããã®äžã§ã¯ããšãã«ããªã¢ã«ãã«ã¢ã«ãã
ãŠã ãäžèšããïŒä»¥äžã®ã¢ã«ãããŠã ãçµåãã
ã¢ã«ãã«ã¢ã«ãããŠã ã®äœ¿çšã奜ãŸããã Siââçµåãæããææ©ã±ã€çŽ ååç©è§Šåª
æå(c)ã¯ãäŸãã°ã¢ã«ã³ãã·ã·ã©ã³ãã¢ãªãŒãã
ã·ã·ã©ã³ïŒaryloxysilaneïŒãªã©ã§ããããã®ã
ããªååç©ã®äŸãšããŠã¯ãåŒRnSiïŒOR1ïŒ4-oãåŒ
äžãïŒâŠïœâŠïŒãã¯çåæ°ŽçŽ åºãäŸãã°ã¢ã«ã
ã«åºãã·ã¯ãã¢ã«ãã«åºãã¢ãªãŒã«åºãã¢ã«ã±ã
ã«åºãããã¢ã«ãã«åºãã¢ããã¢ã«ãã«åºãªã©ã
ãŸãã¯ããã²ã³ïŒR1ã¯çåæ°ŽçŽ åºãäŸãã°ã¢ã«
ãã«åºãã·ã¯ãã¢ã«ãã«åºãã¢ãªãŒã«åºãã¢ã«ã±
ãã«åºãã¢ã«ã³ãã·ã¢ã«ãã«åºãªã©ïŒäœããïœå
ã®ïŒ²ãïŒïŒâïœïŒåã®OR1åºã¯åäžã§ãç°ã€ãŠã
ãŠããããã§è¡šããããã±ã€çŽ ååç©ãæããã
ãšãã§ããããŸããä»ã®äŸãšããŠã¯ãOR1åºãæ
ããã·ãããµã³é¡ãã«ã«ãã³é¡ã®ã·ãªã«ãšã¹ãã«
ãªã©ãæããããšãã§ããããŸããããã«ä»ã®äŸ
ãšããŠïŒå以äžã®ã±ã€çŽ ååããé žçŽ ãŸãã¯çªçŽ
ååãä»ããŠäºãã«çµåãããŠãããããªååç©
ãæããããšãã§ããã以äžã®ææ©ã±ã€çŽ ååç©
ã¯Siââçµåãæããªãååç©ãšïŒ¯âçµå
ãæããååç©ãäºãåå¿ãããŠããããããã¯
éåã®å Žã§åå¿ãããSiââçµåãæããå
åç©ã«å€æãããŠçšããŠãããããã®ãããªäŸãš
ããŠãäŸãã°Siââçµåãæããªãããã²ã³
å«æã·ã©ã³ååç©ãŸãã¯ã·ãªã³ã³ãã€ãã©ã€ã
ãšãã¢ã«ã³ãã·åºå«æã¢ã«ãããŠã ååç©ãã¢ã«
ã³ãã·åºå«æãã°ãã·ãŠã ååç©ããã®ä»éå±ã¢
ã«ã³ã©ãŒããã¢ã«ã³ãŒã«ãã®é žãšã¹ãã«ããšãã¬
ã³ãªãã·ãçãšã®äœµçšãäŸç€ºããããšãã§ããã
ææ©ã±ã€çŽ ååç©ãŸãä»ã®éå±ïŒäŸãã°ã¢ã«ãã
ãŠã ãã¹ãºãªã©ïŒãå«æãããã®ã§ãã€ãŠãã
ãã ããå ·äœçã«ã¯ãããªã¡ãã«ã¡ããã·ã·ã©ã³ã
ããªã¡ãã«ãšããã·ã·ã©ã³ããžã¡ãã«ãžã¡ããã·
ã·ã©ã³ããžã¡ãã«ãžãšããã·ã·ã©ã³ããžããšãã«
ãžã¡ããã·ã·ã©ã³ãã¡ãã«ããšãã«ãžã¡ããã·ã·
ã©ã³ããžããšãã«ãžãšããã·ã·ã©ã³ããšãã«ããª
ã¡ããã·ã·ã©ã³ãã¡ãã«ããªã¡ããã·ã·ã©ã³ãã
ãã«ããªã¡ããã·ã·ã©ã³ãããšãã«ããªã¡ããã·
ã·ã©ã³ãγâã¯ãã«ãããã«ããªã¡ããã·ã·ã©
ã³ãã¡ãã«ããªãšããã·ã·ã©ã³ããšãã«ããªãšã
ãã·ã·ã©ã³ãããã«ããªãšããã·ã·ã©ã³ãããã«
ããªãšããã·ã·ã©ã³ãããšãã«ããªãšããã·ã·ã©
ã³ãγâã¢ãããããã«ããªãšããã·ã·ã©ã³ãã¯
ãã«ããªãšããã·ã·ã©ã³ããšãã«ããªã€ãœããã
ãã·ã·ã©ã³ãããã«ããªãããã·ã·ã©ã³ãã±ã€é ž
ãšãã«ãã±ã€é žããã«ãããªã¡ãã«ããšããã·ã·
ã©ã³ãã¡ãã«ããªã¢ãªããã·ïŒallyloxyïŒã·ã©
ã³ãããã«ããªã¹ïŒÎ²âã¡ããã·ãšããã·ïŒã·ã©
ã³ãããã«ããªã¢ã»ããã·ã·ã©ã³ããžãšãã«ãã
ã©ãšããã·ãžã·ãããµã³ãããšãã«ãžãšããã·ãž
ãšãã«ã¢ããã·ã©ã³ãªã©ãäŸç€ºããããšãã§ã
ãããããã®äžã§ãšãã«å¥œãŸããã®ã¯ãã¡ãã«ã
ãªã¡ããã·ã·ã©ã³ãããšãã«ããªã¡ããã·ã·ã©
ã³ãã¡ãã«ããªãšããã·ã·ã©ã³ããšãã«ããªãšã
ãã·ã·ã©ã³ãããã«ããªãšããã·ã·ã©ã³ãããšã
ã«ããªãšããã·ã·ã©ã³ãããã«ããªãããã·ã·ã©
ã³ãã±ã€é žãšãã«ããžããšãã«ã¡ããã·ã·ã©ã³ã
ãžããšãã«ãžãšããã·ã·ã©ã³ãã¡ãã«ããšãã«ã¡
ããã·ã·ã©ã³çã®åèšåŒRnSiïŒOR1ïŒ4ã§ç€ºããã
ãã®ã§ãããäžã§ããã®åŒã«ãããŠïœãïŒãŸãã¯
ïŒã®ãã®ã§ããã ïŒâããã³ãšççŽ ååæ°ãïŒä»¥äžã®Î±âãªã¬ã
ã€ã³ã®å ±éåã¯ã液çžãæ°çžã®äœãã®çžã«ãããŠ
ãè¡ãããšãã§ãããããšãã«æ¶²çžã«ãããŠå ±é
åäœã溶解ããæ¡ä»¶ã§è¡ãã®ã奜ãŸããã液çžã§
å ±éåãè¡ãå Žåã¯ããããµã³ãããã¿ã³ãç¯æ²¹
ã®ãããªäžæŽ»æ§æº¶åªãåå¿åªäœãšããŠããããã
ãªã¬ãã€ã³ããèªä¿¡ãåå¿åªäœãšããããšãã§ã
ãã觊åªã®äœ¿çšéã¯ãåå¿å®¹ç©ïŒåœãã(a)æå
ããã¿ã³ååã«æç®ããŠçŽ0.0001ãªããçŽ1.0ã
ãªã¢ã«ã(b)æåã(a)æåäžã®ãã¿ã³ååïŒã¢ã«ã«
察ãã(b)æåäžã®éå±ååãçŽïŒãªããçŽ2000ã¢
ã«ã奜ãŸããã¯çŽïŒãªããçŽ500ã¢ã«ãšãªããã
ã«ããŸã(c)æåãã(b)æåäžã®éå±ååïŒã¢ã«åœ
ãã(c)æåäžã®SiååãçŽ0.001ãªããçŽ10ã¢ã«ã
奜ãŸããã¯çŽ0.01ãªããçŽïŒã¢ã«ããšãã«å¥œãŸã
ãã¯çŽ0.05ãªããçŽïŒã¢ã«ãšãªãããã«ããã®ã
奜ãŸããã ãããã®å觊åªæå(a)(b)(c)ã¯å ±éåæã«äžè ã
æ¥è§ŠãããŠãè¯ããããŸãå ±éååã«æ¥è§ŠãããŠ
ãè¯ãããã®å ±éååã®æ¥è§Šã«åœã€ãŠã¯ãä»»æã®
äºè ã®ã¿ãèªç±ã«éžæããŠæ¥è§ŠãããŠãè¯ããã
ãŸãåæåã®äžéšãäºè ãªããäžè æ¥è§ŠãããŠã
ããããŸãããã«å ±éååã®åæåã®æ¥è§Šã¯ãäž
掻æ§ã¬ã¹é°å²æ°äžã§ãã€ãŠãè¯ããããªã¬ãã€ã³
é°å²æ°äžã§ãã€ãŠãè¯ãã å ±éå枩床ã¯é©å®ã«éžæã§ãã奜ãŸããã¯çŽ20
ãªããçŽ200âãäžå±€å¥œãŸããã¯çŽ50ãªããçŽ180
âçšåºŠãå§åãé©å®ã«éžæã§ãã倧æ°å§ãªããçŽ
100KgïŒcm2ã奜ãŸããã¯çŽïŒãªããçŽ50KgïŒcm2çš
床ã®å å§æ¡ä»¶äžã§è¡ãã®ã奜ãŸããã 該αâãªã¬ãã€ã³æåã®å«æéãïŒãªãã50ã¢
ã«ïŒ ã®ç¯å²ã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã補
é ããããã®ïŒâããã³ãšè©²Î±âãªã¬ãã€ã³ã®äŸ
絊å²åã¯ãéåå§åãªã©ã«ãã€ãŠé©å®ã«éžæã§ã
ããããšãã°ãéåžžïŒâããã³ïŒè©²Î±âãªã¬ãã€
ã³ïŒã¢ã«æ¯ïŒã0.01ãªãã100çšåºŠã®äŸçµŠå²åã
äŸç€ºã§ããã ååéã®èª¿ç¯ã¯ãéå枩床ãæ¥è§Šæåã®äœ¿çšå²
åãªã©ã®éåèŠä»¶ãå€ããããšã«ãã€ãŠããçšåºŠ
調ç¯ã§ããããéåç³»äžã«æ°ŽçŽ ãæ·»å ããã®ãæ
ãå¹æçã§ããã æ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã¯ãã¹
ãä»ãããªããæ¢è¿°ã®åŠãä»ã«çš®ã ã®ç¹æ§ãåã
ãŠããçã«ãããŠåŸæ¥ææ¡ã®ãã®ãšã¯ç°ãªã€ãŠã
ãããã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã¯ãæŒåº
æ圢ãäžç©ºæ圢ãå°åºæ圢ããã¬ã¹æ圢ãç空æ
圢ãªã©ä»»æã®æ圢æ¹æ³ã«ããããã€ãããã€ã«
ã ãã·ãŒããäžç©ºå®¹åšããã®ä»å皮補åã«æ圢ã§
ããåçš®çšéã«äŸããããšãã§ããããšãã«èã
ãããã³ã°æ§ãããŒãã·ãŒã«æ§ãè¯å¥œã§ãããšã
ããããå è£ çšãã€ã«ã ãšããŠå¥œé©ã§ãããåèš
æ§è³ªã«ãããéå±çã®ä¿è·ãã€ã«ã ãšããŠã奜é©
ã«äœ¿çšã§ããã æ圢ã«éããåçš®å®å®å€ãé žåé²æ¢å€ã玫å€ç·
åžåå€ã垯é»é²æ¢å€ãæ»å€ãå¯æå€ãé¡æãç¡æ©
ãŸãã¯ææ©ã®å å¡«å€ãé åããããšãã§ãããã
ããã®äŸãšããŠãïŒïŒïŒâãžâtertâããã«âïœ
âã¯ã¬ãŸãŒã«ãããã©ãã¹ãã¡ãã¬ã³âïŒâïŒïŒïŒ
ïŒâãžâtertâããã«âïŒâããããã·ããšã
ã«ïŒããããªããŒããã¡ã¿ã³ãïŒïŒ4â²âãããªã
ã³ãã¹ïŒïŒâtertâããã«âïœâã¯ã¬ãŸãŒã«ïŒã
ãã³ããšããŒã«é¡ãã¢ã¹ã³ã«ãã³é žããžã©ãŠãªã«
ããªãžããããªããŒãããªã³é žç³»å®å®å€ãèèªé ž
ã¢ãã°ãªã»ã©ã€ããïŒïŒ®âïŒãã¹âïŒâããã
ãã·ãšãã«ïŒã¢ã«ãã«ã¢ãã³ãïŒâïŒ2â²âããã
ãã·â3â²ïŒ5â²âãžâtertâããã«ããšãã«ïŒâïŒâ
ã¯ãã«ãã³ãŸããªã¢ãŸãŒã«ãã¹ãã¢ãªã³é žã«ã«ã·
ãŠã ãé žåãã°ãã·ãŠã ãæ°Žé žåãã°ãã·ãŠã ã
ã¢ã«ãããæ°Žé žåã¢ã«ãããŠã ãã·ãªã«ããã€ã
ãã¿ã«ãµã€ããã¿ã«ã¯ãã¯ã¬ã€ãç³ãããã¬ã©ã¹
ç¹ç¶ããã¿ãã¢ãçé žã«ã«ã·ãŠã ãã«ãŒãã³ãã©
ãã¯ãç³ç §æš¹èãããªããã³ãã¯ãã¯ã¹ãåæãŸ
ãã¯å€©ç¶ãŽã ãªã©ã§ãã€ãŠãããã æ¬çºæã®å ±éåäœã¯ããŸããä»ã®ç±å¯å¡æ§æš¹è
ãšæ··åããŠçšããããšãã§ããããããã®äŸãšã
ãŠé«å¯åºŠãäžå¯åºŠãŸãã¯äœå¯åºŠã®ããªãšãã¬ã³ã
ããªãããã¬ã³ãããªâïŒâããã³ãããªâïŒâ
ã¡ãã«âïŒâãã³ãã³ããšãã¬ã³ã»é ¢é žããã«å ±
éåäœããµãŒãªã³ïŒ¡ããšãã¬ã³ã»ããã«ã¢ã«ã³ãŒ
ã«å ±éåäœãããªã¹ãã¬ã³ããããã®ç¡æ°Žãã¬ã€
ã³é žã°ã©ããç©ãªã©ãäŸç€ºããããšãã§ããã 次ã«ãæ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœ
ãå®æœäŸã«ãã€ãŠå ·äœçã«èª¬æããã å®æœäŸ ïŒ ïŒãã¿ã³è§Šåªæå(a)ã®èª¿è£œïŒ ç¡æ°Žå¡©åãã°ãã·ãŠã 4.76ïœïŒ50ïœmolïŒãã
ã«ã³25mlããã³ïŒâãšãã«ããã·ã«ã¢ã«ã³ãŒã«
23.4mlïŒ150ïœmolïŒã130âã§ïŒæéå ç±åå¿ã
è¡ãåäžæº¶æ¶²ãšããåŸããã®æº¶æ¶²äžã«ç¡æ°Žãã¿ã«
é ž1.11ïœïŒ7.5ïœmolïŒãæ·»å ãã130âã«ãŠæŽã«
ïŒæéæ¹ææ··åãè¡ããç¡æ°Žãã¿ã«é žã該åäžã«
溶解ãããããã®æ§ã«ããŠåŸãããåäžæº¶æ¶²ã宀
æž©ã«å·åŽããåŸãâ20âã«ä¿æãããåå¡©åãã¿
ã³200mlïŒ1.8ïœmolïŒäžã«ïŒæéã«æž¡ã€ãŠå šé滎
äžè£ å ¥ãããè£ å ¥çµäºåŸããã®æ··å液ã®æž©åºŠãïŒ
æéãããŠ110âã«ææž©ãã110âã«éãããšãã
ã§ãžã€ãœããã«ãã¿ã¬ãŒã2.68mlïŒ12.5ïœmolïŒ
ãæ·»å ãããããïŒæéå枩床ã«ãŠæ¹æäžä¿æã
ããïŒæéã®åå¿çµäºåŸç±éã«ãŠåºäœéšãæ¡å
ãããã®åºäœéšã200mlã®TiCl4ã«ãŠåæžæ¿ãã
ãåŸãåã³110âã§ïŒæéãå ç±åå¿ãè¡ããå
å¿çµäºåŸãåã³ç±éã«ãŠåºäœéšãæ¡åãã110
âãã«ã³åã³ãããµã³ã«ãŠãæŽæ¶²äžã«éé¢ã®ãã¿
ã³ååç©ãæ€åºãããªããªãè¿å åæŽæµããã以
äžã®è£œé æ¹æ³ã«ãŠèª¿è£œããããã¿ã³è§Šåªæå(a)ã¯
ãããµã³ã¹ã©ãªãŒãšããŠä¿åãããããã®ãã¡äž
éšã觊åªçµæã調ã¹ãç®çã§ä¹Ÿç¥ããããã®æ§ã«
ããŠåŸããããã¿ã³è§Šåªæå(a)ã®çµæã¯ãã¿ã³
3.1ééïŒ ãå¡©çŽ 56.0ééïŒ ããã°ãã·ãŠã 17.0wt
ïŒ ããã³ãžã€ãœããã«ãã¿ã¬ãŒã20.9ééïŒ ã§ã
ã€ãã ïŒéåïŒ 200ã®SUS補åå¿éãžãïŒæéåœã70ã®æ¶²
ç¶ïŒâããã³ã30ã®ïŒâã¡ãã«âïŒâãã³ãã³
ïŒä»¥äž4MPãšç¥ãïŒã100ïœmolã®ããªãšãã«ã¢ã«
ãããŠã ã10ïœmolã®ããã«ããªãšããã·ã·ã©
ã³ããã¿ã³ååã«æç®ããŠ0.5ïœmolã®ãã¿ã³è§Š
åªæå(a)ãé£ç¶çã«è£ å ¥ããæ°çžäžã®æ°ŽçŽ åå§ã
1.5KgïŒcm2ã«ä¿ã¡ãéå枩床ã70âã«ä¿ã€ãã åå¿éã®æ¶²éã100ã«ãªãæ§ãéå液ãé£ç¶
çã«æãåºããå°éã®ã¡ã¿ããŒã«ã§éåãåæ¢
ããæªåå¿ã®ã¢ãããŒãé€å»ãããïŒæéåœã
8.5Kgã®å ±éåäœãåŸããããçµæãè¡šïŒã«ç€ºã
ãã å®æœäŸ ïŒãïŒ ïŒâããã³ãš4MPã®è£ å ¥éãè¡šïŒã«èšèŒãã
éã«å€æŽããæ°ŽçŽ åå§ãé©å®å€æŽããŠãå®æœäŸïŒ
ãšåæ§ã«åãããçµæãè¡šïŒã«ç€ºããã å®æœäŸ ïŒ ïŒæéåœãã85ã®ïŒâããã³ãš15ã®ïŒâã
ãã»ã³ã䜿çšããŠãå®æœäŸïŒãšåæ§ã«éåããã
çµæãè¡šïŒã«ç€ºããã å®æœäŸ ïŒ ïŒæéåœãã85ã®ïŒâããã³ãš15ã®ïŒâãª
ã¯ãã³ã䜿çšããŠãå®æœäŸïŒãšåæ§ã«éåããã
çµæãè¡šïŒã«ç€ºããã æ¯èŒäŸ ïŒãïŒ ïŒâããã³ãš4MPã®è£ å ¥éãè¡šïŒã«èšèŒãã
éã«å€æŽããæ°ŽçŽ åå§ãé©å®å€æŽããŠå®æœäŸïŒãš
åæ§ã«éåãããçµæãïŒã«ç€ºããã æ¯èŒäŸ ïŒ 200ã®åå¿éãžãïŒæéåœã70ã®æ¶²äœïŒâ
ããã³ã30ã®4MPã20ïœmolã®ãžãšãã«ã¢ã«ã
ããŠã ã¯ããªã100ïœmolã®äžå¡©åãã¿ã³ïŒæ±éŠ
ãã¿ããŠã 瀟ãTACâ131ïŒãé£ç¶çã«è£ å ¥ãã
æ°ŽçŽ ã®æ°çžåå§ã2.5KgïŒcm2ã«ä¿ã¡ãéå枩床ã
70âã«ä¿ã€ããåå¿éã®æ¶²éã100ã«ãªãæ§ã«
é£ç¶çã«æãåºããïŒæéåœã10ã®ã¡ã¿ããŒã«
ãæ·»å ãã次ãã§æ°ŽæŽããæªåå¿ã¢ãããŒãé€å»
ãããïŒæéåœã6.8Kgã®å ±éåäœãåŸãããã
çµæãè¡šïŒã«ç€ºããã æ¯èŒäŸ ïŒãïŒ è¡šïŒèšèŒã®ã³ã¢ãããŒã䜿çšããè¡šïŒèšèŒã®é
ã®ïŒâããã³ãšã³ã¢ãããŒãè£ å ¥ããæ°ŽçŽ åå§ã
é©å®å€æŽããŠãæ¯èŒäŸïŒãšåæ§ã«éåãããçµæ
ãè¡šïŒã«ç€ºããã
ãŠã ãäžèšããïŒä»¥äžã®ã¢ã«ãããŠã ãçµåãã
ã¢ã«ãã«ã¢ã«ãããŠã ã®äœ¿çšã奜ãŸããã Siââçµåãæããææ©ã±ã€çŽ ååç©è§Šåª
æå(c)ã¯ãäŸãã°ã¢ã«ã³ãã·ã·ã©ã³ãã¢ãªãŒãã
ã·ã·ã©ã³ïŒaryloxysilaneïŒãªã©ã§ããããã®ã
ããªååç©ã®äŸãšããŠã¯ãåŒRnSiïŒOR1ïŒ4-oãåŒ
äžãïŒâŠïœâŠïŒãã¯çåæ°ŽçŽ åºãäŸãã°ã¢ã«ã
ã«åºãã·ã¯ãã¢ã«ãã«åºãã¢ãªãŒã«åºãã¢ã«ã±ã
ã«åºãããã¢ã«ãã«åºãã¢ããã¢ã«ãã«åºãªã©ã
ãŸãã¯ããã²ã³ïŒR1ã¯çåæ°ŽçŽ åºãäŸãã°ã¢ã«
ãã«åºãã·ã¯ãã¢ã«ãã«åºãã¢ãªãŒã«åºãã¢ã«ã±
ãã«åºãã¢ã«ã³ãã·ã¢ã«ãã«åºãªã©ïŒäœããïœå
ã®ïŒ²ãïŒïŒâïœïŒåã®OR1åºã¯åäžã§ãç°ã€ãŠã
ãŠããããã§è¡šããããã±ã€çŽ ååç©ãæããã
ãšãã§ããããŸããä»ã®äŸãšããŠã¯ãOR1åºãæ
ããã·ãããµã³é¡ãã«ã«ãã³é¡ã®ã·ãªã«ãšã¹ãã«
ãªã©ãæããããšãã§ããããŸããããã«ä»ã®äŸ
ãšããŠïŒå以äžã®ã±ã€çŽ ååããé žçŽ ãŸãã¯çªçŽ
ååãä»ããŠäºãã«çµåãããŠãããããªååç©
ãæããããšãã§ããã以äžã®ææ©ã±ã€çŽ ååç©
ã¯Siââçµåãæããªãååç©ãšïŒ¯âçµå
ãæããååç©ãäºãåå¿ãããŠããããããã¯
éåã®å Žã§åå¿ãããSiââçµåãæããå
åç©ã«å€æãããŠçšããŠãããããã®ãããªäŸãš
ããŠãäŸãã°Siââçµåãæããªãããã²ã³
å«æã·ã©ã³ååç©ãŸãã¯ã·ãªã³ã³ãã€ãã©ã€ã
ãšãã¢ã«ã³ãã·åºå«æã¢ã«ãããŠã ååç©ãã¢ã«
ã³ãã·åºå«æãã°ãã·ãŠã ååç©ããã®ä»éå±ã¢
ã«ã³ã©ãŒããã¢ã«ã³ãŒã«ãã®é žãšã¹ãã«ããšãã¬
ã³ãªãã·ãçãšã®äœµçšãäŸç€ºããããšãã§ããã
ææ©ã±ã€çŽ ååç©ãŸãä»ã®éå±ïŒäŸãã°ã¢ã«ãã
ãŠã ãã¹ãºãªã©ïŒãå«æãããã®ã§ãã€ãŠãã
ãã ããå ·äœçã«ã¯ãããªã¡ãã«ã¡ããã·ã·ã©ã³ã
ããªã¡ãã«ãšããã·ã·ã©ã³ããžã¡ãã«ãžã¡ããã·
ã·ã©ã³ããžã¡ãã«ãžãšããã·ã·ã©ã³ããžããšãã«
ãžã¡ããã·ã·ã©ã³ãã¡ãã«ããšãã«ãžã¡ããã·ã·
ã©ã³ããžããšãã«ãžãšããã·ã·ã©ã³ããšãã«ããª
ã¡ããã·ã·ã©ã³ãã¡ãã«ããªã¡ããã·ã·ã©ã³ãã
ãã«ããªã¡ããã·ã·ã©ã³ãããšãã«ããªã¡ããã·
ã·ã©ã³ãγâã¯ãã«ãããã«ããªã¡ããã·ã·ã©
ã³ãã¡ãã«ããªãšããã·ã·ã©ã³ããšãã«ããªãšã
ãã·ã·ã©ã³ãããã«ããªãšããã·ã·ã©ã³ãããã«
ããªãšããã·ã·ã©ã³ãããšãã«ããªãšããã·ã·ã©
ã³ãγâã¢ãããããã«ããªãšããã·ã·ã©ã³ãã¯
ãã«ããªãšããã·ã·ã©ã³ããšãã«ããªã€ãœããã
ãã·ã·ã©ã³ãããã«ããªãããã·ã·ã©ã³ãã±ã€é ž
ãšãã«ãã±ã€é žããã«ãããªã¡ãã«ããšããã·ã·
ã©ã³ãã¡ãã«ããªã¢ãªããã·ïŒallyloxyïŒã·ã©
ã³ãããã«ããªã¹ïŒÎ²âã¡ããã·ãšããã·ïŒã·ã©
ã³ãããã«ããªã¢ã»ããã·ã·ã©ã³ããžãšãã«ãã
ã©ãšããã·ãžã·ãããµã³ãããšãã«ãžãšããã·ãž
ãšãã«ã¢ããã·ã©ã³ãªã©ãäŸç€ºããããšãã§ã
ãããããã®äžã§ãšãã«å¥œãŸããã®ã¯ãã¡ãã«ã
ãªã¡ããã·ã·ã©ã³ãããšãã«ããªã¡ããã·ã·ã©
ã³ãã¡ãã«ããªãšããã·ã·ã©ã³ããšãã«ããªãšã
ãã·ã·ã©ã³ãããã«ããªãšããã·ã·ã©ã³ãããšã
ã«ããªãšããã·ã·ã©ã³ãããã«ããªãããã·ã·ã©
ã³ãã±ã€é žãšãã«ããžããšãã«ã¡ããã·ã·ã©ã³ã
ãžããšãã«ãžãšããã·ã·ã©ã³ãã¡ãã«ããšãã«ã¡
ããã·ã·ã©ã³çã®åèšåŒRnSiïŒOR1ïŒ4ã§ç€ºããã
ãã®ã§ãããäžã§ããã®åŒã«ãããŠïœãïŒãŸãã¯
ïŒã®ãã®ã§ããã ïŒâããã³ãšççŽ ååæ°ãïŒä»¥äžã®Î±âãªã¬ã
ã€ã³ã®å ±éåã¯ã液çžãæ°çžã®äœãã®çžã«ãããŠ
ãè¡ãããšãã§ãããããšãã«æ¶²çžã«ãããŠå ±é
åäœã溶解ããæ¡ä»¶ã§è¡ãã®ã奜ãŸããã液çžã§
å ±éåãè¡ãå Žåã¯ããããµã³ãããã¿ã³ãç¯æ²¹
ã®ãããªäžæŽ»æ§æº¶åªãåå¿åªäœãšããŠããããã
ãªã¬ãã€ã³ããèªä¿¡ãåå¿åªäœãšããããšãã§ã
ãã觊åªã®äœ¿çšéã¯ãåå¿å®¹ç©ïŒåœãã(a)æå
ããã¿ã³ååã«æç®ããŠçŽ0.0001ãªããçŽ1.0ã
ãªã¢ã«ã(b)æåã(a)æåäžã®ãã¿ã³ååïŒã¢ã«ã«
察ãã(b)æåäžã®éå±ååãçŽïŒãªããçŽ2000ã¢
ã«ã奜ãŸããã¯çŽïŒãªããçŽ500ã¢ã«ãšãªããã
ã«ããŸã(c)æåãã(b)æåäžã®éå±ååïŒã¢ã«åœ
ãã(c)æåäžã®SiååãçŽ0.001ãªããçŽ10ã¢ã«ã
奜ãŸããã¯çŽ0.01ãªããçŽïŒã¢ã«ããšãã«å¥œãŸã
ãã¯çŽ0.05ãªããçŽïŒã¢ã«ãšãªãããã«ããã®ã
奜ãŸããã ãããã®å觊åªæå(a)(b)(c)ã¯å ±éåæã«äžè ã
æ¥è§ŠãããŠãè¯ããããŸãå ±éååã«æ¥è§ŠãããŠ
ãè¯ãããã®å ±éååã®æ¥è§Šã«åœã€ãŠã¯ãä»»æã®
äºè ã®ã¿ãèªç±ã«éžæããŠæ¥è§ŠãããŠãè¯ããã
ãŸãåæåã®äžéšãäºè ãªããäžè æ¥è§ŠãããŠã
ããããŸãããã«å ±éååã®åæåã®æ¥è§Šã¯ãäž
掻æ§ã¬ã¹é°å²æ°äžã§ãã€ãŠãè¯ããããªã¬ãã€ã³
é°å²æ°äžã§ãã€ãŠãè¯ãã å ±éå枩床ã¯é©å®ã«éžæã§ãã奜ãŸããã¯çŽ20
ãªããçŽ200âãäžå±€å¥œãŸããã¯çŽ50ãªããçŽ180
âçšåºŠãå§åãé©å®ã«éžæã§ãã倧æ°å§ãªããçŽ
100KgïŒcm2ã奜ãŸããã¯çŽïŒãªããçŽ50KgïŒcm2çš
床ã®å å§æ¡ä»¶äžã§è¡ãã®ã奜ãŸããã 該αâãªã¬ãã€ã³æåã®å«æéãïŒãªãã50ã¢
ã«ïŒ ã®ç¯å²ã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã補
é ããããã®ïŒâããã³ãšè©²Î±âãªã¬ãã€ã³ã®äŸ
絊å²åã¯ãéåå§åãªã©ã«ãã€ãŠé©å®ã«éžæã§ã
ããããšãã°ãéåžžïŒâããã³ïŒè©²Î±âãªã¬ãã€
ã³ïŒã¢ã«æ¯ïŒã0.01ãªãã100çšåºŠã®äŸçµŠå²åã
äŸç€ºã§ããã ååéã®èª¿ç¯ã¯ãéå枩床ãæ¥è§Šæåã®äœ¿çšå²
åãªã©ã®éåèŠä»¶ãå€ããããšã«ãã€ãŠããçšåºŠ
調ç¯ã§ããããéåç³»äžã«æ°ŽçŽ ãæ·»å ããã®ãæ
ãå¹æçã§ããã æ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã¯ãã¹
ãä»ãããªããæ¢è¿°ã®åŠãä»ã«çš®ã ã®ç¹æ§ãåã
ãŠããçã«ãããŠåŸæ¥ææ¡ã®ãã®ãšã¯ç°ãªã€ãŠã
ãããã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœã¯ãæŒåº
æ圢ãäžç©ºæ圢ãå°åºæ圢ããã¬ã¹æ圢ãç空æ
圢ãªã©ä»»æã®æ圢æ¹æ³ã«ããããã€ãããã€ã«
ã ãã·ãŒããäžç©ºå®¹åšããã®ä»å皮補åã«æ圢ã§
ããåçš®çšéã«äŸããããšãã§ããããšãã«èã
ãããã³ã°æ§ãããŒãã·ãŒã«æ§ãè¯å¥œã§ãããšã
ããããå è£ çšãã€ã«ã ãšããŠå¥œé©ã§ãããåèš
æ§è³ªã«ãããéå±çã®ä¿è·ãã€ã«ã ãšããŠã奜é©
ã«äœ¿çšã§ããã æ圢ã«éããåçš®å®å®å€ãé žåé²æ¢å€ã玫å€ç·
åžåå€ã垯é»é²æ¢å€ãæ»å€ãå¯æå€ãé¡æãç¡æ©
ãŸãã¯ææ©ã®å å¡«å€ãé åããããšãã§ãããã
ããã®äŸãšããŠãïŒïŒïŒâãžâtertâããã«âïœ
âã¯ã¬ãŸãŒã«ãããã©ãã¹ãã¡ãã¬ã³âïŒâïŒïŒïŒ
ïŒâãžâtertâããã«âïŒâããããã·ããšã
ã«ïŒããããªããŒããã¡ã¿ã³ãïŒïŒ4â²âãããªã
ã³ãã¹ïŒïŒâtertâããã«âïœâã¯ã¬ãŸãŒã«ïŒã
ãã³ããšããŒã«é¡ãã¢ã¹ã³ã«ãã³é žããžã©ãŠãªã«
ããªãžããããªããŒãããªã³é žç³»å®å®å€ãèèªé ž
ã¢ãã°ãªã»ã©ã€ããïŒïŒ®âïŒãã¹âïŒâããã
ãã·ãšãã«ïŒã¢ã«ãã«ã¢ãã³ãïŒâïŒ2â²âããã
ãã·â3â²ïŒ5â²âãžâtertâããã«ããšãã«ïŒâïŒâ
ã¯ãã«ãã³ãŸããªã¢ãŸãŒã«ãã¹ãã¢ãªã³é žã«ã«ã·
ãŠã ãé žåãã°ãã·ãŠã ãæ°Žé žåãã°ãã·ãŠã ã
ã¢ã«ãããæ°Žé žåã¢ã«ãããŠã ãã·ãªã«ããã€ã
ãã¿ã«ãµã€ããã¿ã«ã¯ãã¯ã¬ã€ãç³ãããã¬ã©ã¹
ç¹ç¶ããã¿ãã¢ãçé žã«ã«ã·ãŠã ãã«ãŒãã³ãã©
ãã¯ãç³ç §æš¹èãããªããã³ãã¯ãã¯ã¹ãåæãŸ
ãã¯å€©ç¶ãŽã ãªã©ã§ãã€ãŠãããã æ¬çºæã®å ±éåäœã¯ããŸããä»ã®ç±å¯å¡æ§æš¹è
ãšæ··åããŠçšããããšãã§ããããããã®äŸãšã
ãŠé«å¯åºŠãäžå¯åºŠãŸãã¯äœå¯åºŠã®ããªãšãã¬ã³ã
ããªãããã¬ã³ãããªâïŒâããã³ãããªâïŒâ
ã¡ãã«âïŒâãã³ãã³ããšãã¬ã³ã»é ¢é žããã«å ±
éåäœããµãŒãªã³ïŒ¡ããšãã¬ã³ã»ããã«ã¢ã«ã³ãŒ
ã«å ±éåäœãããªã¹ãã¬ã³ããããã®ç¡æ°Žãã¬ã€
ã³é žã°ã©ããç©ãªã©ãäŸç€ºããããšãã§ããã 次ã«ãæ¬çºæã®ïŒâããã³ç³»ã©ã³ãã å ±éåäœ
ãå®æœäŸã«ãã€ãŠå ·äœçã«èª¬æããã å®æœäŸ ïŒ ïŒãã¿ã³è§Šåªæå(a)ã®èª¿è£œïŒ ç¡æ°Žå¡©åãã°ãã·ãŠã 4.76ïœïŒ50ïœmolïŒãã
ã«ã³25mlããã³ïŒâãšãã«ããã·ã«ã¢ã«ã³ãŒã«
23.4mlïŒ150ïœmolïŒã130âã§ïŒæéå ç±åå¿ã
è¡ãåäžæº¶æ¶²ãšããåŸããã®æº¶æ¶²äžã«ç¡æ°Žãã¿ã«
é ž1.11ïœïŒ7.5ïœmolïŒãæ·»å ãã130âã«ãŠæŽã«
ïŒæéæ¹ææ··åãè¡ããç¡æ°Žãã¿ã«é žã該åäžã«
溶解ãããããã®æ§ã«ããŠåŸãããåäžæº¶æ¶²ã宀
æž©ã«å·åŽããåŸãâ20âã«ä¿æãããåå¡©åãã¿
ã³200mlïŒ1.8ïœmolïŒäžã«ïŒæéã«æž¡ã€ãŠå šé滎
äžè£ å ¥ãããè£ å ¥çµäºåŸããã®æ··å液ã®æž©åºŠãïŒ
æéãããŠ110âã«ææž©ãã110âã«éãããšãã
ã§ãžã€ãœããã«ãã¿ã¬ãŒã2.68mlïŒ12.5ïœmolïŒ
ãæ·»å ãããããïŒæéå枩床ã«ãŠæ¹æäžä¿æã
ããïŒæéã®åå¿çµäºåŸç±éã«ãŠåºäœéšãæ¡å
ãããã®åºäœéšã200mlã®TiCl4ã«ãŠåæžæ¿ãã
ãåŸãåã³110âã§ïŒæéãå ç±åå¿ãè¡ããå
å¿çµäºåŸãåã³ç±éã«ãŠåºäœéšãæ¡åãã110
âãã«ã³åã³ãããµã³ã«ãŠãæŽæ¶²äžã«éé¢ã®ãã¿
ã³ååç©ãæ€åºãããªããªãè¿å åæŽæµããã以
äžã®è£œé æ¹æ³ã«ãŠèª¿è£œããããã¿ã³è§Šåªæå(a)ã¯
ãããµã³ã¹ã©ãªãŒãšããŠä¿åãããããã®ãã¡äž
éšã觊åªçµæã調ã¹ãç®çã§ä¹Ÿç¥ããããã®æ§ã«
ããŠåŸããããã¿ã³è§Šåªæå(a)ã®çµæã¯ãã¿ã³
3.1ééïŒ ãå¡©çŽ 56.0ééïŒ ããã°ãã·ãŠã 17.0wt
ïŒ ããã³ãžã€ãœããã«ãã¿ã¬ãŒã20.9ééïŒ ã§ã
ã€ãã ïŒéåïŒ 200ã®SUS補åå¿éãžãïŒæéåœã70ã®æ¶²
ç¶ïŒâããã³ã30ã®ïŒâã¡ãã«âïŒâãã³ãã³
ïŒä»¥äž4MPãšç¥ãïŒã100ïœmolã®ããªãšãã«ã¢ã«
ãããŠã ã10ïœmolã®ããã«ããªãšããã·ã·ã©
ã³ããã¿ã³ååã«æç®ããŠ0.5ïœmolã®ãã¿ã³è§Š
åªæå(a)ãé£ç¶çã«è£ å ¥ããæ°çžäžã®æ°ŽçŽ åå§ã
1.5KgïŒcm2ã«ä¿ã¡ãéå枩床ã70âã«ä¿ã€ãã åå¿éã®æ¶²éã100ã«ãªãæ§ãéå液ãé£ç¶
çã«æãåºããå°éã®ã¡ã¿ããŒã«ã§éåãåæ¢
ããæªåå¿ã®ã¢ãããŒãé€å»ãããïŒæéåœã
8.5Kgã®å ±éåäœãåŸããããçµæãè¡šïŒã«ç€ºã
ãã å®æœäŸ ïŒãïŒ ïŒâããã³ãš4MPã®è£ å ¥éãè¡šïŒã«èšèŒãã
éã«å€æŽããæ°ŽçŽ åå§ãé©å®å€æŽããŠãå®æœäŸïŒ
ãšåæ§ã«åãããçµæãè¡šïŒã«ç€ºããã å®æœäŸ ïŒ ïŒæéåœãã85ã®ïŒâããã³ãš15ã®ïŒâã
ãã»ã³ã䜿çšããŠãå®æœäŸïŒãšåæ§ã«éåããã
çµæãè¡šïŒã«ç€ºããã å®æœäŸ ïŒ ïŒæéåœãã85ã®ïŒâããã³ãš15ã®ïŒâãª
ã¯ãã³ã䜿çšããŠãå®æœäŸïŒãšåæ§ã«éåããã
çµæãè¡šïŒã«ç€ºããã æ¯èŒäŸ ïŒãïŒ ïŒâããã³ãš4MPã®è£ å ¥éãè¡šïŒã«èšèŒãã
éã«å€æŽããæ°ŽçŽ åå§ãé©å®å€æŽããŠå®æœäŸïŒãš
åæ§ã«éåãããçµæãïŒã«ç€ºããã æ¯èŒäŸ ïŒ 200ã®åå¿éãžãïŒæéåœã70ã®æ¶²äœïŒâ
ããã³ã30ã®4MPã20ïœmolã®ãžãšãã«ã¢ã«ã
ããŠã ã¯ããªã100ïœmolã®äžå¡©åãã¿ã³ïŒæ±éŠ
ãã¿ããŠã 瀟ãTACâ131ïŒãé£ç¶çã«è£ å ¥ãã
æ°ŽçŽ ã®æ°çžåå§ã2.5KgïŒcm2ã«ä¿ã¡ãéå枩床ã
70âã«ä¿ã€ããåå¿éã®æ¶²éã100ã«ãªãæ§ã«
é£ç¶çã«æãåºããïŒæéåœã10ã®ã¡ã¿ããŒã«
ãæ·»å ãã次ãã§æ°ŽæŽããæªåå¿ã¢ãããŒãé€å»
ãããïŒæéåœã6.8Kgã®å ±éåäœãåŸãããã
çµæãè¡šïŒã«ç€ºããã æ¯èŒäŸ ïŒãïŒ è¡šïŒèšèŒã®ã³ã¢ãããŒã䜿çšããè¡šïŒèšèŒã®é
ã®ïŒâããã³ãšã³ã¢ãããŒãè£ å ¥ããæ°ŽçŽ åå§ã
é©å®å€æŽããŠãæ¯èŒäŸïŒãšåæ§ã«éåãããçµæ
ãè¡šïŒã«ç€ºããã
ãè¡šã
ASTM D1893ã«æºããŠè©äŸ¡ãããå·Ÿ10cmã
é·ã15cmã®ãã€ã«ã åå¿ãéãåãããïŒæã®
ã¬ã©ã¹æ¿ã§ã¯ãã¿ã10Kgã®è·ç©ãä¹ãã50âãš
ã¢ãŒã»ãªãŒãã³äžã«æŸçœ®ãããïŒæ¥åŸããã³ïŒ
æ¥åŸã«ãµã³ãã«ãååºãããã¯ãªåŒ·åºŠãäžèœè©Š
éšæ©ã§æž¬å®ããïŒcmåœãã®ãã¯ãªåŒ·åºŠãããã
ãã³ã°å€ãšããã ã2ã ãã€ã«ã ã®éææ§ äžèšæ¹æ³ã§è£œèãããã€ã«ã ã50âã®ãšã¢ãŒ
ãªãŒãã³äžã§ãšãŒãžã³ã°ããããšãŒãžã³ã°åãš
ãšãŒãžã³ã°ïŒæ¥åŸãïŒæ¥åŸã®ãã€ã«ã ã«ã€ããŠ
ASTM D1003â611ã«æºããŠãã®Hazeã枬å®
ããã ã3ã ãã€ã«ã ã®ã¹ãªããæ§ ASTM D1894ã«æºããŠãäžèšãšãŒãžã³ã°å
ãšãšãŒãžã³ã°ïŒæ¥åŸãïŒæ¥åŸã®ãã€ã«ã ã®éæ©
æŠä¿æ°ããã³åæ©æŠä¿æ°ã枬å®ããã
é·ã15cmã®ãã€ã«ã åå¿ãéãåãããïŒæã®
ã¬ã©ã¹æ¿ã§ã¯ãã¿ã10Kgã®è·ç©ãä¹ãã50âãš
ã¢ãŒã»ãªãŒãã³äžã«æŸçœ®ãããïŒæ¥åŸããã³ïŒ
æ¥åŸã«ãµã³ãã«ãååºãããã¯ãªåŒ·åºŠãäžèœè©Š
éšæ©ã§æž¬å®ããïŒcmåœãã®ãã¯ãªåŒ·åºŠãããã
ãã³ã°å€ãšããã ã2ã ãã€ã«ã ã®éææ§ äžèšæ¹æ³ã§è£œèãããã€ã«ã ã50âã®ãšã¢ãŒ
ãªãŒãã³äžã§ãšãŒãžã³ã°ããããšãŒãžã³ã°åãš
ãšãŒãžã³ã°ïŒæ¥åŸãïŒæ¥åŸã®ãã€ã«ã ã«ã€ããŠ
ASTM D1003â611ã«æºããŠãã®Hazeã枬å®
ããã ã3ã ãã€ã«ã ã®ã¹ãªããæ§ ASTM D1894ã«æºããŠãäžèšãšãŒãžã³ã°å
ãšãšãŒãžã³ã°ïŒæ¥åŸãïŒæ¥åŸã®ãã€ã«ã ã®éæ©
æŠä¿æ°ããã³åæ©æŠä¿æ°ã枬å®ããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ ïŒâããã³æååã³ççŽ ååæ°ãïŒãïŒã®Î±
âãªã¬ãã€ã³æåãããªãïŒâããã³ç³»ã©ã³ãã
å ±éåäœã§ãã€ãŠã (A) ãã®çµæããïŒâããã³æåã50ãªãã99ã¢
ã«ïŒ åã³è©²Î±âãªã¬ãã€ã³æåãïŒãªãã50ã¢
ã«ïŒ ã®ç¯å²ã«ããããšã (B) ãã«ãªã³äžã§135âã§æž¬å®ãã極éç²åºŠïŒ»Î·ïŒœ
ã0.5ãªããïŒdlïŒïœã®ç¯å²ã«ããããšã (C) 瀺差走æ»ç±éèšã«ãã€ãŠæž¬å®ããèç¹
Tmã30ãªãã120âã®ç¯å²ã«ããããšã (D) ç·åææ³ã«ãã€ãŠæž¬å®ããçµæ¶å床ãïŒãª
ãã60ïŒ ã®ç¯å²ã«ããããšã (E) æ²žéš°é ¢é žã¡ãã«ãžã®å¯æº¶åéW1ééïŒ ïŒœ
ãïŒééïŒ ä»¥äžã®ç¯å²ã«ããããšã (F) 10âã«ãããã¢ã»ãã³ã»ïœâãã«ã³æ··å溶åª
ïŒå®¹éæ¯ïŒïŒïŒïŒãžã®å¯æº¶åéW2ééïŒ ïŒœã
ïŒÃη-1.2ééïŒ æªæºã®ç¯å²ã«ããããšã (G) éäŒç¹å¿åã10ãªãã200KgïŒcm2ã®ç¯å²ã«ã
ãããšã (H) ç Žæç¹å¿åã100ãªãã1000KgïŒcm2ã®ç¯å²ã«
ããããšã (I) ç Žæç¹äŒžã³ã300ïŒ ä»¥äžã§ããããšã ã«ãã€ãŠç¹åŸŽã¥ããããïŒâããã³ç³»ã©ã³ãã å ±
éåäœã
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22895184A JPS61108614A (ja) | 1984-11-01 | 1984-11-01 | ïŒâããã³ç³»ã©ã³ãã å ±éåäœ |
| AU49202/85A AU4920285A (en) | 1984-11-01 | 1985-10-30 | Random propylene copolymer composition and laminate |
| DE8585307910T DE3579428D1 (de) | 1984-11-01 | 1985-10-31 | Statistisches 1-butencopolymer. |
| EP85307910A EP0186287B1 (en) | 1984-11-01 | 1985-10-31 | Random 1-butene copolymer |
| CA000494363A CA1262997A (en) | 1984-11-01 | 1985-10-31 | Random 1-butene copolymer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22895184A JPS61108614A (ja) | 1984-11-01 | 1984-11-01 | ïŒâããã³ç³»ã©ã³ãã å ±éåäœ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61108614A JPS61108614A (ja) | 1986-05-27 |
| JPH0339525B2 true JPH0339525B2 (ja) | 1991-06-14 |
Family
ID=16884411
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP22895184A Granted JPS61108614A (ja) | 1984-11-01 | 1984-11-01 | ïŒâããã³ç³»ã©ã³ãã å ±éåäœ |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0186287B1 (ja) |
| JP (1) | JPS61108614A (ja) |
| AU (1) | AU4920285A (ja) |
| CA (1) | CA1262997A (ja) |
| DE (1) | DE3579428D1 (ja) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8513247D0 (en) * | 1985-05-24 | 1985-06-26 | Ici Plc | Multiple-layer polyolefin films |
| JPH0816131B2 (ja) * | 1987-03-19 | 1996-02-21 | åºå ç³æ²¹ååŠæ ªåŒäŒç€Ÿ | ããã³ç³»å ±éåäœ |
| DE60126952T2 (de) * | 2000-07-03 | 2007-10-31 | Mitsui Chemicals, Inc. | Butencopolymer, harzzusammensetzung die dieses enthÀlt sowie formmassen aus der zusammensetzung |
| ATE519789T1 (de) | 2001-06-12 | 2011-08-15 | Basell Polyolefine Gmbh | Verfahren zur polymerisation von buten-1 |
| ATE554113T1 (de) * | 2002-11-28 | 2012-05-15 | Basell Poliolefine Srl | Butencopolymere und verfahren zu ihrer herstellung |
| US7589160B2 (en) | 2002-12-04 | 2009-09-15 | Basell Polyolefine Gmbh | Process for preparing 1-butene polymers |
| DE60329523D1 (de) | 2002-12-04 | 2009-11-12 | Basell Polyolefine Gmbh | 1-Buten-Copolymere und Herstellungsverfahren dafÃŒr |
| US20110003951A1 (en) * | 2008-03-20 | 2011-01-06 | Basell Poliolefine Italia S.R.L. | 1-butene copolymers |
| ATE543870T1 (de) | 2008-03-20 | 2012-02-15 | Basell Poliolefine Srl | Zusammensetzungen aus polymeren auf 1-buten-basis |
| CN111087509B (zh) * | 2018-10-23 | 2023-03-14 | äžåœç³æ²¹åå·¥è¡ä»œæéå ¬åž | äžç§ææ§1-äžç¯èåç©åå ¶å¶å€æ¹æ³ |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6043848B2 (ja) * | 1977-12-21 | 1985-09-30 | äžäºååŠæ ªåŒäŒç€Ÿ | è»è³ªæš¹èããã³ãã®è£œæ³ |
| CA1177599A (en) * | 1980-04-21 | 1984-11-06 | John F. Motier | Compositions for and method of reducing hydrocarbon fluid friction loss in conduits |
| JPS5832611A (ja) * | 1981-08-20 | 1983-02-25 | Mitsubishi Petrochem Co Ltd | ãªã¬ãã€ã³å ±éåäœ |
| US4405772A (en) * | 1982-06-23 | 1983-09-20 | Shell Oil Company | Butene-1/4-vinylcyclohexene copolymer |
-
1984
- 1984-11-01 JP JP22895184A patent/JPS61108614A/ja active Granted
-
1985
- 1985-10-30 AU AU49202/85A patent/AU4920285A/en not_active Abandoned
- 1985-10-31 DE DE8585307910T patent/DE3579428D1/de not_active Expired - Lifetime
- 1985-10-31 CA CA000494363A patent/CA1262997A/en not_active Expired
- 1985-10-31 EP EP85307910A patent/EP0186287B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61108614A (ja) | 1986-05-27 |
| CA1262997A (en) | 1989-11-14 |
| EP0186287A3 (en) | 1987-05-13 |
| DE3579428D1 (de) | 1990-10-04 |
| EP0186287B1 (en) | 1990-08-29 |
| AU4920285A (en) | 1986-05-08 |
| EP0186287A2 (en) | 1986-07-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4600762A (en) | Randum 1-butene copolymer | |
| EP0184324B1 (en) | Propylene copolymer composition for heat-sealable plastics laminate | |
| US4642269A (en) | Crystalline random propylene copolymer composition and composite laminate comprising said composition | |
| JP2538625B2 (ja) | åæαâãªã¬ãã€ã³ç³»ã©ã³ãã å ±éåäœããã³ãã®è£œæ³ | |
| JPH0339525B2 (ja) | ||
| JPH0335322B2 (ja) | ||
| JPH0232106A (ja) | ïŒâã¡ãã«âïŒâãã³ãã³ç³»å ±éåäœã®è£œæ³ | |
| JPH0339526B2 (ja) | ||
| JPS6257406A (ja) | è¶ é«ååéãšãã¬ã³ç³»å ±éåäœ | |
| US5385998A (en) | Random 1-butene/ethylene copolymer | |
| KR910008818B1 (ko) | ê°ì§í ìí-ì¬ë íê³ ì€í©ì²Ž ì¡°ì±ë¬Œ ë° ê·ž ì ì¡°ë°©ë² | |
| US4801672A (en) | Random 1-butene copolymer | |
| JPS6279208A (ja) | ïŒâã¡ãã«âïŒâãã³ãã³ç³»ã©ã³ãã å ±éåäœ | |
| JPH0354686B2 (ja) | ||
| JP2540285B2 (ja) | ç±å¯å¡æ§æš¹èå ±éåäœ | |
| JP2000336130A (ja) | ãããã¬ã³ã»ãšãã¬ã³ãããã¯ã³ããªããŒåã³ãã®è£œé æ¹æ³ | |
| JPH0339524B2 (ja) | ||
| JPH0571602B2 (ja) | ||
| JPH0488003A (ja) | åæαâãªã¬ãã£ã³ã®éåæ¹æ³ | |
| JPH02229807A (ja) | ãããã¬ã³ç³»å ±éåäœã®è£œé æ¹æ³ | |
| JPH0710904B2 (ja) | ããªãªã¬ãã€ã³çµæç©ããã³ãã®è£œæ³ | |
| JPH0725837B2 (ja) | åæαâãªã¬ãã€ã³ç³»éåäœçµæç©ããã³ãã®è£œæ³ | |
| JPH1143564A (ja) | ãã£ã«ã åã³ç©å±€äœ | |
| JPH0417963B2 (ja) | ||
| JPS62241909A (ja) | ïŒâã¡ãã«âïŒâãã³ãã³ç³»ã©ã³ãã å ±éåäœããã³ãã®è£œæ³ |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |