JP2007513238A - メタロセン触媒系を用いる重合方法 - Google Patents
メタロセン触媒系を用いる重合方法 Download PDFInfo
- Publication number
- JP2007513238A JP2007513238A JP2006542563A JP2006542563A JP2007513238A JP 2007513238 A JP2007513238 A JP 2007513238A JP 2006542563 A JP2006542563 A JP 2006542563A JP 2006542563 A JP2006542563 A JP 2006542563A JP 2007513238 A JP2007513238 A JP 2007513238A
- Authority
- JP
- Japan
- Prior art keywords
- exemplary embodiment
- catalyst
- metallocene
- group
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000012968 metallocene catalyst Substances 0.000 title claims abstract description 61
- 238000006116 polymerization reaction Methods 0.000 title abstract description 71
- 239000003054 catalyst Substances 0.000 claims abstract description 148
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 claims abstract description 81
- 239000000463 material Substances 0.000 claims abstract description 71
- 150000001875 compounds Chemical class 0.000 claims abstract description 40
- -1 polyethylene Polymers 0.000 claims description 93
- 229920000642 polymer Polymers 0.000 claims description 75
- 239000000203 mixture Substances 0.000 claims description 69
- 238000000034 method Methods 0.000 claims description 66
- 230000008569 process Effects 0.000 claims description 29
- 230000000694 effects Effects 0.000 claims description 28
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 23
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 22
- 239000005977 Ethylene Substances 0.000 claims description 22
- 239000002245 particle Substances 0.000 claims description 17
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 16
- 239000002689 soil Substances 0.000 claims description 15
- 229910052731 fluorine Inorganic materials 0.000 claims description 13
- 239000000126 substance Substances 0.000 claims description 13
- 239000004698 Polyethylene Substances 0.000 claims description 11
- 239000010439 graphite Substances 0.000 claims description 11
- 229910002804 graphite Inorganic materials 0.000 claims description 11
- 229920000573 polyethylene Polymers 0.000 claims description 11
- 239000000377 silicon dioxide Substances 0.000 claims description 11
- 239000011737 fluorine Substances 0.000 claims description 10
- 239000011148 porous material Substances 0.000 claims description 10
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 7
- 239000004711 α-olefin Substances 0.000 claims description 6
- 239000002216 antistatic agent Substances 0.000 claims description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 4
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 22
- 239000002184 metal Substances 0.000 abstract description 21
- 239000012190 activator Substances 0.000 abstract description 16
- 238000011068 loading method Methods 0.000 abstract description 14
- 125000004429 atom Chemical group 0.000 description 35
- 229920000098 polyolefin Polymers 0.000 description 32
- 239000003446 ligand Substances 0.000 description 25
- 229910052719 titanium Inorganic materials 0.000 description 19
- 239000010936 titanium Substances 0.000 description 19
- 239000000047 product Substances 0.000 description 17
- 229910052726 zirconium Inorganic materials 0.000 description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- 125000000217 alkyl group Chemical group 0.000 description 16
- 239000007789 gas Substances 0.000 description 16
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 15
- 150000001336 alkenes Chemical class 0.000 description 15
- 125000003118 aryl group Chemical group 0.000 description 15
- 238000006243 chemical reaction Methods 0.000 description 15
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 15
- 125000005842 heteroatom Chemical group 0.000 description 14
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 13
- 229910052757 nitrogen Inorganic materials 0.000 description 13
- 239000002002 slurry Substances 0.000 description 13
- 239000000243 solution Substances 0.000 description 13
- 125000001424 substituent group Chemical group 0.000 description 13
- 125000002877 alkyl aryl group Chemical group 0.000 description 12
- 229910052799 carbon Inorganic materials 0.000 description 12
- 239000000178 monomer Substances 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 10
- 239000000654 additive Substances 0.000 description 9
- 125000004432 carbon atom Chemical group C* 0.000 description 9
- 230000000875 corresponding effect Effects 0.000 description 9
- 125000001183 hydrocarbyl group Chemical group 0.000 description 9
- 238000002156 mixing Methods 0.000 description 9
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 9
- 229910052760 oxygen Inorganic materials 0.000 description 9
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- 229910052804 chromium Inorganic materials 0.000 description 8
- 239000011651 chromium Substances 0.000 description 8
- 239000010408 film Substances 0.000 description 8
- 239000008187 granular material Substances 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- 125000002947 alkylene group Chemical group 0.000 description 7
- 125000004104 aryloxy group Chemical group 0.000 description 7
- 239000003085 diluting agent Substances 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 239000008188 pellet Substances 0.000 description 7
- 239000012071 phase Substances 0.000 description 7
- 229910052710 silicon Inorganic materials 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 6
- 150000007942 carboxylates Chemical class 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 125000004122 cyclic group Chemical group 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 239000000945 filler Substances 0.000 description 6
- 150000002222 fluorine compounds Chemical group 0.000 description 6
- 235000013305 food Nutrition 0.000 description 6
- 229910052732 germanium Inorganic materials 0.000 description 6
- 229910052736 halogen Inorganic materials 0.000 description 6
- 150000004678 hydrides Chemical class 0.000 description 6
- 150000002430 hydrocarbons Chemical class 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
- 125000003545 alkoxy group Chemical group 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 5
- 229910052735 hafnium Inorganic materials 0.000 description 5
- 125000005843 halogen group Chemical group 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 5
- 238000004806 packaging method and process Methods 0.000 description 5
- IUGYQRQAERSCNH-UHFFFAOYSA-M pivalate Chemical compound CC(C)(C)C([O-])=O IUGYQRQAERSCNH-UHFFFAOYSA-M 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229920006395 saturated elastomer Polymers 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 4
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- 238000001354 calcination Methods 0.000 description 4
- 125000000753 cycloalkyl group Chemical group 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- 230000007935 neutral effect Effects 0.000 description 4
- XYFCBTPGUUZFHI-UHFFFAOYSA-N phosphine group Chemical group P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 150000003973 alkyl amines Chemical class 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910052796 boron Inorganic materials 0.000 description 3
- 239000000969 carrier Substances 0.000 description 3
- 239000012876 carrier material Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 125000001153 fluoro group Chemical group F* 0.000 description 3
- 125000003709 fluoroalkyl group Chemical group 0.000 description 3
- 125000004216 fluoromethyl group Chemical group [H]C([H])(F)* 0.000 description 3
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 3
- 125000000623 heterocyclic group Chemical group 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 229950010765 pivalate Drugs 0.000 description 3
- 239000002685 polymerization catalyst Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 238000007613 slurry method Methods 0.000 description 3
- 125000000547 substituted alkyl group Chemical group 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 125000003944 tolyl group Chemical group 0.000 description 3
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 3
- GBXQPDCOMJJCMJ-UHFFFAOYSA-M trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCCCCC[N+](C)(C)C GBXQPDCOMJJCMJ-UHFFFAOYSA-M 0.000 description 3
- 125000004642 (C1-C12) alkoxy group Chemical group 0.000 description 2
- 125000003161 (C1-C6) alkylene group Chemical group 0.000 description 2
- 125000002733 (C1-C6) fluoroalkyl group Chemical group 0.000 description 2
- 125000006710 (C2-C12) alkenyl group Chemical group 0.000 description 2
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 2
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- HBAQYPYDRFILMT-UHFFFAOYSA-N 8-[3-(1-cyclopropylpyrazol-4-yl)-1H-pyrazolo[4,3-d]pyrimidin-5-yl]-3-methyl-3,8-diazabicyclo[3.2.1]octan-2-one Chemical class C1(CC1)N1N=CC(=C1)C1=NNC2=C1N=C(N=C2)N1C2C(N(CC1CC2)C)=O HBAQYPYDRFILMT-UHFFFAOYSA-N 0.000 description 2
- VLOOGSDCMKSQPK-UHFFFAOYSA-N C1=CC=C2C([Zr])C(C)=CC2=C1 Chemical compound C1=CC=C2C([Zr])C(C)=CC2=C1 VLOOGSDCMKSQPK-UHFFFAOYSA-N 0.000 description 2
- JAKYKQHNJUDFCT-UHFFFAOYSA-N C1=CC=C2C([Zr])C=CC2=C1 Chemical compound C1=CC=C2C([Zr])C=CC2=C1 JAKYKQHNJUDFCT-UHFFFAOYSA-N 0.000 description 2
- RVEYJJWOHLDJPA-UHFFFAOYSA-N CC1=C(C)C(C)=C(C)C1(C)[Zr]C1(C)C(C)=C(C)C(C)=C1C Chemical compound CC1=C(C)C(C)=C(C)C1(C)[Zr]C1(C)C(C)=C(C)C(C)=C1C RVEYJJWOHLDJPA-UHFFFAOYSA-N 0.000 description 2
- FQJDUPMEJJGIKK-UHFFFAOYSA-N C[SiH](C)[Zr](C1C(=CC=C1)C)C1(C(=C(C(=C1)C)C)C)C Chemical compound C[SiH](C)[Zr](C1C(=CC=C1)C)C1(C(=C(C(=C1)C)C)C)C FQJDUPMEJJGIKK-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 2
- 229910005965 SO 2 Inorganic materials 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- JFWBIRAGFWPMTI-UHFFFAOYSA-N [Zr].[CH]1C=CC=C1 Chemical compound [Zr].[CH]1C=CC=C1 JFWBIRAGFWPMTI-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000002252 acyl group Chemical group 0.000 description 2
- 125000004442 acylamino group Chemical group 0.000 description 2
- 125000004423 acyloxy group Chemical group 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 125000004453 alkoxycarbonyl group Chemical group 0.000 description 2
- 125000005248 alkyl aryloxy group Chemical group 0.000 description 2
- 125000005115 alkyl carbamoyl group Chemical group 0.000 description 2
- 125000005599 alkyl carboxylate group Chemical group 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 125000005161 aryl oxy carbonyl group Chemical group 0.000 description 2
- 125000000732 arylene group Chemical group 0.000 description 2
- CUFNKYGDVFVPHO-UHFFFAOYSA-N azulene Chemical compound C1=CC=CC2=CC=CC2=C1 CUFNKYGDVFVPHO-UHFFFAOYSA-N 0.000 description 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 2
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 150000001805 chlorine compounds Chemical class 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 238000000748 compression moulding Methods 0.000 description 2
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- 125000005117 dialkylcarbamoyl group Chemical group 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 125000004407 fluoroaryl group Chemical group 0.000 description 2
- 125000001207 fluorophenyl group Chemical group 0.000 description 2
- 238000012685 gas phase polymerization Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 238000001802 infusion Methods 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 229910052809 inorganic oxide Inorganic materials 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 239000001282 iso-butane Substances 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- 229910052752 metalloid Inorganic materials 0.000 description 2
- 150000002738 metalloids Chemical class 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 125000001624 naphthyl group Chemical group 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 239000002530 phenolic antioxidant Substances 0.000 description 2
- 150000003003 phosphines Chemical class 0.000 description 2
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 2
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 229920005672 polyolefin resin Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000001376 precipitating effect Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 125000003107 substituted aryl group Chemical group 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- AHAREKHAZNPPMI-AATRIKPKSA-N (3e)-hexa-1,3-diene Chemical compound CC\C=C\C=C AHAREKHAZNPPMI-AATRIKPKSA-N 0.000 description 1
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
- 125000000027 (C1-C10) alkoxy group Chemical group 0.000 description 1
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 1
- 125000006832 (C1-C10) alkylene group Chemical group 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- ABFCPWCUXLLRSC-UHFFFAOYSA-N 1,1-bis(2,4-ditert-butylphenyl)-2,2-bis(hydroxymethyl)propane-1,3-diol Chemical compound C(C)(C)(C)C1=C(C=CC(=C1)C(C)(C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1)C(C)(C)C)C(C)(C)C ABFCPWCUXLLRSC-UHFFFAOYSA-N 0.000 description 1
- MFEVGQHCNVXMER-UHFFFAOYSA-L 1,3,2$l^{2}-dioxaplumbetan-4-one Chemical compound [Pb+2].[O-]C([O-])=O MFEVGQHCNVXMER-UHFFFAOYSA-L 0.000 description 1
- JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical compound C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 description 1
- VNQNXQYZMPJLQX-UHFFFAOYSA-N 1,3,5-tris[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-1,3,5-triazinane-2,4,6-trione Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CN2C(N(CC=3C=C(C(O)=C(C=3)C(C)(C)C)C(C)(C)C)C(=O)N(CC=3C=C(C(O)=C(C=3)C(C)(C)C)C(C)(C)C)C2=O)=O)=C1 VNQNXQYZMPJLQX-UHFFFAOYSA-N 0.000 description 1
- VYXHVRARDIDEHS-UHFFFAOYSA-N 1,5-cyclooctadiene Chemical compound C1CC=CCCC=C1 VYXHVRARDIDEHS-UHFFFAOYSA-N 0.000 description 1
- 239000004912 1,5-cyclooctadiene Substances 0.000 description 1
- YBCVSZCMASDRCS-UHFFFAOYSA-N 1-[ethoxy-[ethoxy-(2-methoxyphenoxy)-propoxymethyl]sulfanyl-propoxymethoxy]-2-methoxybenzene Chemical compound C=1C=CC=C(OC)C=1OC(OCC)(OCCC)SC(OCC)(OCCC)OC1=CC=CC=C1OC YBCVSZCMASDRCS-UHFFFAOYSA-N 0.000 description 1
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- CORHDXNAYKUXRI-UHFFFAOYSA-N 1h-cyclopenta[12]annulene Chemical compound C1=CC=CC=CC=CC=CC2=C1CC=C2 CORHDXNAYKUXRI-UHFFFAOYSA-N 0.000 description 1
- QIJIUJYANDSEKG-UHFFFAOYSA-N 2,4,4-trimethylpentan-2-amine Chemical compound CC(C)(C)CC(C)(C)N QIJIUJYANDSEKG-UHFFFAOYSA-N 0.000 description 1
- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-Hydroxyoctadecanoic acid Natural products CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 description 1
- QWUAEFUHELCUHK-UHFFFAOYSA-N 2-hydroxy-2-methylicosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCC(C)(O)C(O)=O QWUAEFUHELCUHK-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- AIBRSVLEQRWAEG-UHFFFAOYSA-N 3,9-bis(2,4-ditert-butylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP1OCC2(COP(OC=3C(=CC(=CC=3)C(C)(C)C)C(C)(C)C)OC2)CO1 AIBRSVLEQRWAEG-UHFFFAOYSA-N 0.000 description 1
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 description 1
- 125000004975 3-butenyl group Chemical group C(CC=C)* 0.000 description 1
- BBDKZWKEPDTENS-UHFFFAOYSA-N 4-Vinylcyclohexene Chemical compound C=CC1CCC=CC1 BBDKZWKEPDTENS-UHFFFAOYSA-N 0.000 description 1
- 239000004915 4-vinylcyclohex-1-ene Substances 0.000 description 1
- INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 description 1
- KLAWFKRMCIXRFS-UHFFFAOYSA-N 5-ethenylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C=C)CC1C=C2 KLAWFKRMCIXRFS-UHFFFAOYSA-N 0.000 description 1
- 125000006043 5-hexenyl group Chemical group 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- KRMHZSCNBPXDSN-UHFFFAOYSA-N C(C(C)C)C1(C=CC=C1)[Zr]C1(C=CC=C1)CC(C)C Chemical compound C(C(C)C)C1(C=CC=C1)[Zr]C1(C=CC=C1)CC(C)C KRMHZSCNBPXDSN-UHFFFAOYSA-N 0.000 description 1
- NJNGPXRQMNQRLL-UHFFFAOYSA-N C(C)(C)=[Zr](C1C=CC=C1)C1C=CC=C1 Chemical compound C(C)(C)=[Zr](C1C=CC=C1)C1C=CC=C1 NJNGPXRQMNQRLL-UHFFFAOYSA-N 0.000 description 1
- VCRCERYZVRNAEN-UHFFFAOYSA-N C(C)(C)C1(C=CC=C1)[Zr]C1(C=CC=C1)C(C)C Chemical compound C(C)(C)C1(C=CC=C1)[Zr]C1(C=CC=C1)C(C)C VCRCERYZVRNAEN-UHFFFAOYSA-N 0.000 description 1
- IIJHUYBZCHWWOZ-UHFFFAOYSA-N C(C)C1(C=CC=C1)[Zr]C1(C=CC=C1)CC Chemical compound C(C)C1(C=CC=C1)[Zr]C1(C=CC=C1)CC IIJHUYBZCHWWOZ-UHFFFAOYSA-N 0.000 description 1
- SVBLJDGZIHTZBY-UHFFFAOYSA-N C(CC)C1(C=CC=C1)[Hf]C1(C=CC=C1)CCC Chemical compound C(CC)C1(C=CC=C1)[Hf]C1(C=CC=C1)CCC SVBLJDGZIHTZBY-UHFFFAOYSA-N 0.000 description 1
- SHVPYXKAEZZGDZ-UHFFFAOYSA-N C(CC)C1(C=CC=C1)[Zr]C1(C=CC=C1)CCC Chemical compound C(CC)C1(C=CC=C1)[Zr]C1(C=CC=C1)CCC SHVPYXKAEZZGDZ-UHFFFAOYSA-N 0.000 description 1
- VXMDASHPMJSFJT-UHFFFAOYSA-N C(CCC)C1(C=CC=C1)[Zr]C1(C=CC=C1)CCCC Chemical compound C(CCC)C1(C=CC=C1)[Zr]C1(C=CC=C1)CCCC VXMDASHPMJSFJT-UHFFFAOYSA-N 0.000 description 1
- CSFPNOAPBHFFJZ-UHFFFAOYSA-N C(CCC)C1=CC=CC1[Hf] Chemical compound C(CCC)C1=CC=CC1[Hf] CSFPNOAPBHFFJZ-UHFFFAOYSA-N 0.000 description 1
- QLAKHLDSFWPUJU-UHFFFAOYSA-N C(CCCC)C1(C=CC=C1)[Hf]C1(C=CC=C1)CCCCC Chemical compound C(CCCC)C1(C=CC=C1)[Hf]C1(C=CC=C1)CCCCC QLAKHLDSFWPUJU-UHFFFAOYSA-N 0.000 description 1
- OHTFCJZLPZAOEL-UHFFFAOYSA-N C(CCCC)C1(C=CC=C1)[Zr]C1(C=CC=C1)CCCCC Chemical compound C(CCCC)C1(C=CC=C1)[Zr]C1(C=CC=C1)CCCCC OHTFCJZLPZAOEL-UHFFFAOYSA-N 0.000 description 1
- LMPMWQGGEIYLCE-UHFFFAOYSA-N C(CCCCCCC)C1(C=CC=C1)[Zr]C1(C=CC=C1)CCCCCCCC Chemical compound C(CCCCCCC)C1(C=CC=C1)[Zr]C1(C=CC=C1)CCCCCCCC LMPMWQGGEIYLCE-UHFFFAOYSA-N 0.000 description 1
- WDZPGDNNHKWMLM-UHFFFAOYSA-N C(CCCCCCCCCCC)C1(C=CC=C1)[Zr]C1(C=CC=C1)CCCCCCCCCCCC Chemical compound C(CCCCCCCCCCC)C1(C=CC=C1)[Zr]C1(C=CC=C1)CCCCCCCCCCCC WDZPGDNNHKWMLM-UHFFFAOYSA-N 0.000 description 1
- SEHNXJYYFATSKM-UHFFFAOYSA-N C1(=CC=CC=C1)C(C1=CC=CC=C1)=[Zr](C1C2=CC=CC=C2C=2C=CC=CC1=2)C1C=CC=C1 Chemical compound C1(=CC=CC=C1)C(C1=CC=CC=C1)=[Zr](C1C2=CC=CC=C2C=2C=CC=CC1=2)C1C=CC=C1 SEHNXJYYFATSKM-UHFFFAOYSA-N 0.000 description 1
- XUSXIRPYTWGUMA-UHFFFAOYSA-N C1(=CC=CC=C1)C(C1=CC=CC=C1)=[Zr](C1C=CC2=CC=CC=C12)C1C=CC=C1 Chemical compound C1(=CC=CC=C1)C(C1=CC=CC=C1)=[Zr](C1C=CC2=CC=CC=C12)C1C=CC=C1 XUSXIRPYTWGUMA-UHFFFAOYSA-N 0.000 description 1
- VJZOFTJUGPKSGT-UHFFFAOYSA-N C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)[Zr](C1C=C(C=C1)CCC)C1(C(=C(C(=C1)C)C)C)C Chemical compound C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)[Zr](C1C=C(C=C1)CCC)C1(C(=C(C(=C1)C)C)C)C VJZOFTJUGPKSGT-UHFFFAOYSA-N 0.000 description 1
- JCBHGTBOAGRXKA-UHFFFAOYSA-N C1(C=CC=C1)[Zr]C1(C(=C(C(=C1)C)C)C)C Chemical compound C1(C=CC=C1)[Zr]C1(C(=C(C(=C1)C)C)C)C JCBHGTBOAGRXKA-UHFFFAOYSA-N 0.000 description 1
- WJZMFTYEIIOPIC-UHFFFAOYSA-N C1(C=CC=C1)[Zr]C1C=CC2=CC=CC=C12 Chemical compound C1(C=CC=C1)[Zr]C1C=CC2=CC=CC=C12 WJZMFTYEIIOPIC-UHFFFAOYSA-N 0.000 description 1
- KVYVOZSYFGWUOJ-UHFFFAOYSA-N C12=CC=CC=C2C(CCC)C2=C1C=CC=C2[Hf]C1=C2C(CCC)C3=CC=CC=C3C2=CC=C1 Chemical compound C12=CC=CC=C2C(CCC)C2=C1C=CC=C2[Hf]C1=C2C(CCC)C3=CC=CC=C3C2=CC=C1 KVYVOZSYFGWUOJ-UHFFFAOYSA-N 0.000 description 1
- TTYJQSDXHJSQEA-UHFFFAOYSA-N C12=CC=CC=C2C(CCCC)C2=C1C=CC=C2[Hf]C1=C2C(CCCC)C3=CC=CC=C3C2=CC=C1 Chemical compound C12=CC=CC=C2C(CCCC)C2=C1C=CC=C2[Hf]C1=C2C(CCCC)C3=CC=CC=C3C2=CC=C1 TTYJQSDXHJSQEA-UHFFFAOYSA-N 0.000 description 1
- ABESHTPCAFNLIL-UHFFFAOYSA-N C12=CC=CC=C2C2=CC=CC=C2C1[Zr]([SiH](C)C)C1C2=CC=CC=C2C2=CC=CC=C21 Chemical compound C12=CC=CC=C2C2=CC=CC=C2C1[Zr]([SiH](C)C)C1C2=CC=CC=C2C2=CC=CC=C21 ABESHTPCAFNLIL-UHFFFAOYSA-N 0.000 description 1
- PFPCPMROWZEVNH-UHFFFAOYSA-N C1=CC(C(=CC=C2C)C)=C2C1[Zr]C1C(C(C)=CC=C2C)=C2C=C1 Chemical compound C1=CC(C(=CC=C2C)C)=C2C1[Zr]C1C(C(C)=CC=C2C)=C2C=C1 PFPCPMROWZEVNH-UHFFFAOYSA-N 0.000 description 1
- PJQXFWWAJLAYCD-UHFFFAOYSA-N C1=CC(C=C1)[Zr](C1c2ccccc2-c2ccccc12)[SiH](c1ccccc1)c1ccccc1 Chemical compound C1=CC(C=C1)[Zr](C1c2ccccc2-c2ccccc12)[SiH](c1ccccc1)c1ccccc1 PJQXFWWAJLAYCD-UHFFFAOYSA-N 0.000 description 1
- XUIAKXYIMMDVGY-UHFFFAOYSA-N C1=CC2=CC=CC=C2C1[Zr](C1C2=CC=CC=C2C=C1)[SiH](C=1C=CC=CC=1)C1=CC=CC=C1 Chemical compound C1=CC2=CC=CC=C2C1[Zr](C1C2=CC=CC=C2C=C1)[SiH](C=1C=CC=CC=1)C1=CC=CC=C1 XUIAKXYIMMDVGY-UHFFFAOYSA-N 0.000 description 1
- AIIMWBOOVDEVAR-UHFFFAOYSA-N C1=CC2=CC=CC=C2C1[Zr]([SiH](C)C)C1C2=CC=CC=C2C=C1 Chemical compound C1=CC2=CC=CC=C2C1[Zr]([SiH](C)C)C1C2=CC=CC=C2C=C1 AIIMWBOOVDEVAR-UHFFFAOYSA-N 0.000 description 1
- VHNNPTGLWYHNHE-UHFFFAOYSA-N C1=CC2=CC=CC=C2C1[Zr]C1C2=CC=CC=C2C=C1 Chemical compound C1=CC2=CC=CC=C2C1[Zr]C1C2=CC=CC=C2C=C1 VHNNPTGLWYHNHE-UHFFFAOYSA-N 0.000 description 1
- RCQBROWWBGPIHM-UHFFFAOYSA-N C1=CC=C2C([Zr])C(CCC)=CC2=C1 Chemical compound C1=CC=C2C([Zr])C(CCC)=CC2=C1 RCQBROWWBGPIHM-UHFFFAOYSA-N 0.000 description 1
- DFOXRVQVIPUPIJ-UHFFFAOYSA-N C1=CC=C2C([Zr])C(CCCC)=CC2=C1 Chemical compound C1=CC=C2C([Zr])C(CCCC)=CC2=C1 DFOXRVQVIPUPIJ-UHFFFAOYSA-N 0.000 description 1
- OLYFEVQPCGPWKL-UHFFFAOYSA-N C1=CC=CC1[Zr]([SiH](C)C)C1C=CC=C1 Chemical compound C1=CC=CC1[Zr]([SiH](C)C)C1C=CC=C1 OLYFEVQPCGPWKL-UHFFFAOYSA-N 0.000 description 1
- QFOICTIPVHCPDX-UHFFFAOYSA-N C1C=CC=C2C([Zr])CCC21 Chemical compound C1C=CC=C2C([Zr])CCC21 QFOICTIPVHCPDX-UHFFFAOYSA-N 0.000 description 1
- FPUMMLSEJRFVMI-UHFFFAOYSA-N C1CC2CC=CC=C2C1[Zr]([SiH](C)C)C1C2=CC=CCC2CC1 Chemical compound C1CC2CC=CC=C2C1[Zr]([SiH](C)C)C1C2=CC=CCC2CC1 FPUMMLSEJRFVMI-UHFFFAOYSA-N 0.000 description 1
- ZKVNQSMSDNDFEQ-UHFFFAOYSA-N C1CCCC2=C1C([Zr][SiH](C)C)C=C2 Chemical compound C1CCCC2=C1C([Zr][SiH](C)C)C=C2 ZKVNQSMSDNDFEQ-UHFFFAOYSA-N 0.000 description 1
- ADJIJYXHZGRXEE-UHFFFAOYSA-N C1CCCC2=C1C=CC2[Zr](C=1C=CC=CC=1)C1=CC=CC=C1 Chemical compound C1CCCC2=C1C=CC2[Zr](C=1C=CC=CC=1)C1=CC=CC=C1 ADJIJYXHZGRXEE-UHFFFAOYSA-N 0.000 description 1
- 125000006374 C2-C10 alkenyl group Chemical group 0.000 description 1
- 125000005914 C6-C14 aryloxy group Chemical group 0.000 description 1
- SYJFIDBZVVLNQY-UHFFFAOYSA-N CC(C)=[Zr](C1C=CC(C)=C1)C1c2ccccc2-c2ccccc12 Chemical compound CC(C)=[Zr](C1C=CC(C)=C1)C1c2ccccc2-c2ccccc12 SYJFIDBZVVLNQY-UHFFFAOYSA-N 0.000 description 1
- CZVRJNPXQKIDCS-UHFFFAOYSA-N CC(C)=[Zr](C1C=CC=C1)C1C2=CC=CC=C2C2=C1C=CC=C2 Chemical compound CC(C)=[Zr](C1C=CC=C1)C1C2=CC=CC=C2C2=C1C=CC=C2 CZVRJNPXQKIDCS-UHFFFAOYSA-N 0.000 description 1
- DIFXASDUHAWGGQ-UHFFFAOYSA-N CC(C)CC1([Zr]C2(CC(C)C)C=CC(C)=C2)C=CC(C)=C1 Chemical compound CC(C)CC1([Zr]C2(CC(C)C)C=CC(C)=C2)C=CC(C)=C1 DIFXASDUHAWGGQ-UHFFFAOYSA-N 0.000 description 1
- TZYQADPFBSMPOR-UHFFFAOYSA-N CC1(C=CC=C1)[Zr] Chemical compound CC1(C=CC=C1)[Zr] TZYQADPFBSMPOR-UHFFFAOYSA-N 0.000 description 1
- MBVIIPUAENVLDG-UHFFFAOYSA-N CC1(C=CC=C1)[Zr]C1(C=CC=C1)C Chemical compound CC1(C=CC=C1)[Zr]C1(C=CC=C1)C MBVIIPUAENVLDG-UHFFFAOYSA-N 0.000 description 1
- KPVJSSFBDURLMF-UHFFFAOYSA-N CC1=C(C(=C(C1(C)[Zr]C1(C=CC=C1)CCC)C)C)C Chemical compound CC1=C(C(=C(C1(C)[Zr]C1(C=CC=C1)CCC)C)C)C KPVJSSFBDURLMF-UHFFFAOYSA-N 0.000 description 1
- RPEDGPTWFDTTDH-UHFFFAOYSA-N CC1=C(C(=C(C1[Zr])C)C)C Chemical compound CC1=C(C(=C(C1[Zr])C)C)C RPEDGPTWFDTTDH-UHFFFAOYSA-N 0.000 description 1
- DPSOUODMTOWXTB-UHFFFAOYSA-N CC1=C(C)C(C)([Ti])C(C)=C1C Chemical compound CC1=C(C)C(C)([Ti])C(C)=C1C DPSOUODMTOWXTB-UHFFFAOYSA-N 0.000 description 1
- WVEXUUVXOWAJID-UHFFFAOYSA-N CC1=C(C)C(C)([Zr])C(C)=C1C Chemical compound CC1=C(C)C(C)([Zr])C(C)=C1C WVEXUUVXOWAJID-UHFFFAOYSA-N 0.000 description 1
- RTZXYIZTIJWCCU-UHFFFAOYSA-N CC1=CC(C)([Zr])C(C)=C1 Chemical compound CC1=CC(C)([Zr])C(C)=C1 RTZXYIZTIJWCCU-UHFFFAOYSA-N 0.000 description 1
- HYEXFYMWBDOQSX-UHFFFAOYSA-N CC1=CC2=CC=CC=C2C1[Zr](C1C2=CC=CC=C2C=C1C)[SiH](C=1C=CC=CC=1)C1=CC=CC=C1 Chemical compound CC1=CC2=CC=CC=C2C1[Zr](C1C2=CC=CC=C2C=C1C)[SiH](C=1C=CC=CC=1)C1=CC=CC=C1 HYEXFYMWBDOQSX-UHFFFAOYSA-N 0.000 description 1
- VCIHUYZBPKTJDL-UHFFFAOYSA-N CC1=CC2=CC=CC=C2C1[Zr]([GeH](C)C)C1C2=CC=CC=C2C=C1C Chemical compound CC1=CC2=CC=CC=C2C1[Zr]([GeH](C)C)C1C2=CC=CC=C2C=C1C VCIHUYZBPKTJDL-UHFFFAOYSA-N 0.000 description 1
- WWIITDUPFGNCIZ-UHFFFAOYSA-N CC1=CC2=CC=CC=C2C1[Zr]([SiH](C)C)C1C2=CC=CC=C2C=C1C Chemical compound CC1=CC2=CC=CC=C2C1[Zr]([SiH](C)C)C1C2=CC=CC=C2C=C1C WWIITDUPFGNCIZ-UHFFFAOYSA-N 0.000 description 1
- WZXCHZRPKZCHQE-UHFFFAOYSA-N CC1=CC2=CC=CC=C2C1[Zr]C1C2=CC=CC=C2C=C1C Chemical compound CC1=CC2=CC=CC=C2C1[Zr]C1C2=CC=CC=C2C=C1C WZXCHZRPKZCHQE-UHFFFAOYSA-N 0.000 description 1
- YFHMEOSFSFOBHX-UHFFFAOYSA-N CC1C(C(CC1)([Ti])C)(C)C Chemical compound CC1C(C(CC1)([Ti])C)(C)C YFHMEOSFSFOBHX-UHFFFAOYSA-N 0.000 description 1
- HOZGGOHINMFWKT-UHFFFAOYSA-N CC1C([Zr])=Cc2ccccc12 Chemical compound CC1C([Zr])=Cc2ccccc12 HOZGGOHINMFWKT-UHFFFAOYSA-N 0.000 description 1
- MHKTVZDLZJRBMA-UHFFFAOYSA-N CC=1C(=C(C(C=1)(C)[Zr]C1(C=CC=C1)CCC)C)C Chemical compound CC=1C(=C(C(C=1)(C)[Zr]C1(C=CC=C1)CCC)C)C MHKTVZDLZJRBMA-UHFFFAOYSA-N 0.000 description 1
- VZOFRVBSMRIDLZ-UHFFFAOYSA-N CC=1C(=C(C(C=1)(C)[Zr]C1C(=C(C=C1C)C)C)C)C Chemical compound CC=1C(=C(C(C=1)(C)[Zr]C1C(=C(C=C1C)C)C)C)C VZOFRVBSMRIDLZ-UHFFFAOYSA-N 0.000 description 1
- MEMJUNKWYGNDQP-UHFFFAOYSA-N CC=1C(=C(C(C=1)(C)[Zr]C1C(=CC2=CC=CC=C12)C)C)C Chemical compound CC=1C(=C(C(C=1)(C)[Zr]C1C(=CC2=CC=CC=C12)C)C)C MEMJUNKWYGNDQP-UHFFFAOYSA-N 0.000 description 1
- RWICLBNAQGUKDD-UHFFFAOYSA-N CC=1C(=C(C(C=1)(C)[Zr]C1C=C(C=C1)C)C)C Chemical compound CC=1C(=C(C(C=1)(C)[Zr]C1C=C(C=C1)C)C)C RWICLBNAQGUKDD-UHFFFAOYSA-N 0.000 description 1
- JZQXMWDHCZEOPB-UHFFFAOYSA-N CCC1([Zr]C2(CC)C=CC=C2C)C=CC=C1C Chemical compound CCC1([Zr]C2(CC)C=CC=C2C)C=CC=C1C JZQXMWDHCZEOPB-UHFFFAOYSA-N 0.000 description 1
- YSCUEKXITMZXFU-UHFFFAOYSA-N CCC1=CC(C)([Zr]C2(C)C=CC(CC)=C2)C=C1 Chemical compound CCC1=CC(C)([Zr]C2(C)C=CC(CC)=C2)C=C1 YSCUEKXITMZXFU-UHFFFAOYSA-N 0.000 description 1
- MIJWKCIKTGLDEF-UHFFFAOYSA-N CCCC1([Hf]C2(CCC)C=CC=C2C)C=CC=C1C Chemical compound CCCC1([Hf]C2(CCC)C=CC=C2C)C=CC=C1C MIJWKCIKTGLDEF-UHFFFAOYSA-N 0.000 description 1
- XBOVCIASHFPKEK-UHFFFAOYSA-N CCCC1=CC(C)([Zr]C2(C)C=CC(CCC)=C2)C=C1 Chemical compound CCCC1=CC(C)([Zr]C2(C)C=CC(CCC)=C2)C=C1 XBOVCIASHFPKEK-UHFFFAOYSA-N 0.000 description 1
- VQKFRGCZHXKQFG-UHFFFAOYSA-N CCCC1=CC2=CC=CC=C2C1[Hf]C1=C2C(CCC)C3=CC=CC=C3C2=CC=C1 Chemical compound CCCC1=CC2=CC=CC=C2C1[Hf]C1=C2C(CCC)C3=CC=CC=C3C2=CC=C1 VQKFRGCZHXKQFG-UHFFFAOYSA-N 0.000 description 1
- DJOFVNURTOARHS-UHFFFAOYSA-N CCCC1=CC2=CC=CC=C2C1[Hf]C1C2=CC=CC=C2C=C1CCC Chemical compound CCCC1=CC2=CC=CC=C2C1[Hf]C1C2=CC=CC=C2C=C1CCC DJOFVNURTOARHS-UHFFFAOYSA-N 0.000 description 1
- KXRSJALNBFKDSC-UHFFFAOYSA-N CCCC1=CC2=CC=CC=C2C1[Zr](C1C2=CC=CC=C2C=C1CCC)[SiH](C=1C=CC=CC=1)C1=CC=CC=C1 Chemical compound CCCC1=CC2=CC=CC=C2C1[Zr](C1C2=CC=CC=C2C=C1CCC)[SiH](C=1C=CC=CC=1)C1=CC=CC=C1 KXRSJALNBFKDSC-UHFFFAOYSA-N 0.000 description 1
- HMUYRZAUVCQWMT-UHFFFAOYSA-N CCCC1=CC2=CC=CC=C2C1[Zr]([SiH](C)C)C1C2=CC=CC=C2C=C1CCC Chemical compound CCCC1=CC2=CC=CC=C2C1[Zr]([SiH](C)C)C1C2=CC=CC=C2C=C1CCC HMUYRZAUVCQWMT-UHFFFAOYSA-N 0.000 description 1
- UYRKBEPDJPXDBY-UHFFFAOYSA-N CCCC1=CC=CC1[Hf](C1C=CC=C1CCC)[SiH](C)C Chemical compound CCCC1=CC=CC1[Hf](C1C=CC=C1CCC)[SiH](C)C UYRKBEPDJPXDBY-UHFFFAOYSA-N 0.000 description 1
- YXEKOFJLLZHCTR-UHFFFAOYSA-N CCCC1C([Zr])=Cc2ccccc12 Chemical compound CCCC1C([Zr])=Cc2ccccc12 YXEKOFJLLZHCTR-UHFFFAOYSA-N 0.000 description 1
- RKLCUOCYNFGCBT-UHFFFAOYSA-N CCCCC1([Hf]C2(CCCC)C=CC=C2)C=CC=C1 Chemical compound CCCCC1([Hf]C2(CCCC)C=CC=C2)C=CC=C1 RKLCUOCYNFGCBT-UHFFFAOYSA-N 0.000 description 1
- RDYRIARHZLCVDL-UHFFFAOYSA-N CCCCC1([Zr]C2(CCCC)C=CC(C)=C2)C=CC(C)=C1 Chemical compound CCCCC1([Zr]C2(CCCC)C=CC(C)=C2)C=CC(C)=C1 RDYRIARHZLCVDL-UHFFFAOYSA-N 0.000 description 1
- JXJRSFWDVFGRAP-UHFFFAOYSA-N CCCCC1=CC(CCC)([Zr]C2(CCC)C=CC(CCCC)=C2)C=C1 Chemical compound CCCCC1=CC(CCC)([Zr]C2(CCC)C=CC(CCCC)=C2)C=C1 JXJRSFWDVFGRAP-UHFFFAOYSA-N 0.000 description 1
- KJOBGSOJIWASOR-UHFFFAOYSA-N CCCCC1=CC(CCCC)([Zr]C2(CCCC)C=CC(CCCC)=C2)C=C1 Chemical compound CCCCC1=CC(CCCC)([Zr]C2(CCCC)C=CC(CCCC)=C2)C=C1 KJOBGSOJIWASOR-UHFFFAOYSA-N 0.000 description 1
- KFMWNJXNLPLTQJ-UHFFFAOYSA-N CCCCC1=CC([Hf])(CCC)C=C1 Chemical compound CCCCC1=CC([Hf])(CCC)C=C1 KFMWNJXNLPLTQJ-UHFFFAOYSA-N 0.000 description 1
- GQOSVGYTKXMFNX-UHFFFAOYSA-N CCCCC1=CC2=CC=CC=C2C1[Hf]C1C2=CC=CC=C2C=C1CCCC Chemical compound CCCCC1=CC2=CC=CC=C2C1[Hf]C1C2=CC=CC=C2C=C1CCCC GQOSVGYTKXMFNX-UHFFFAOYSA-N 0.000 description 1
- VRIAVZKACUIPBI-UHFFFAOYSA-N CCCCC1=CC2=CC=CC=C2C1[Zr](C1C2=CC=CC=C2C=C1CCCC)[SiH](C=1C=CC=CC=1)C1=CC=CC=C1 Chemical compound CCCCC1=CC2=CC=CC=C2C1[Zr](C1C2=CC=CC=C2C=C1CCCC)[SiH](C=1C=CC=CC=1)C1=CC=CC=C1 VRIAVZKACUIPBI-UHFFFAOYSA-N 0.000 description 1
- XVPUXXAYQJMQBQ-UHFFFAOYSA-N CCCCC1=CC2=CC=CC=C2C1[Zr]([SiH](C)C)C1C2=CC=CC=C2C=C1CCCC Chemical compound CCCCC1=CC2=CC=CC=C2C1[Zr]([SiH](C)C)C1C2=CC=CC=C2C=C1CCCC XVPUXXAYQJMQBQ-UHFFFAOYSA-N 0.000 description 1
- SSRFNPROTPIMLF-UHFFFAOYSA-N CCCCC1C([Zr])=Cc2ccccc12 Chemical compound CCCCC1C([Zr])=Cc2ccccc12 SSRFNPROTPIMLF-UHFFFAOYSA-N 0.000 description 1
- NVUOPZONYBQFOM-UHFFFAOYSA-N C[GeH](C)[Zr](C1C=C(C=C1)C(C)C)C1(C(=CC=C1)C)C Chemical compound C[GeH](C)[Zr](C1C=C(C=C1)C(C)C)C1(C(=CC=C1)C)C NVUOPZONYBQFOM-UHFFFAOYSA-N 0.000 description 1
- NLNGSBVZCDKHDH-UHFFFAOYSA-N C[SiH](C)[Hf](C1(C=CC=C1)CCCC)C1(C=CC=C1)CCCC Chemical compound C[SiH](C)[Hf](C1(C=CC=C1)CCCC)C1(C=CC=C1)CCCC NLNGSBVZCDKHDH-UHFFFAOYSA-N 0.000 description 1
- SFWALIRBLJWJDO-UHFFFAOYSA-N C[SiH](C)[Zr](C1(C)C=CC(C)=C1C)C1(C)C=C(C)C(C)=C1C Chemical compound C[SiH](C)[Zr](C1(C)C=CC(C)=C1C)C1(C)C=C(C)C(C)=C1C SFWALIRBLJWJDO-UHFFFAOYSA-N 0.000 description 1
- NULBQUYVQQQJRW-UHFFFAOYSA-N C[SiH](C)[Zr](C1(C)C=CC=C1C)C1(C)C=C(C)C(C)=C1C Chemical compound C[SiH](C)[Zr](C1(C)C=CC=C1C)C1(C)C=C(C)C(C)=C1C NULBQUYVQQQJRW-UHFFFAOYSA-N 0.000 description 1
- UTWFODRYOJYRIY-UHFFFAOYSA-N C[SiH](C)[Zr](C1=CC=CC=2C3=CC=CC=C3CC12)C1C(=CC2=CC=CC=C12)C Chemical compound C[SiH](C)[Zr](C1=CC=CC=2C3=CC=CC=C3CC12)C1C(=CC2=CC=CC=C12)C UTWFODRYOJYRIY-UHFFFAOYSA-N 0.000 description 1
- UZCKAVZAROHTQV-UHFFFAOYSA-N C[SiH](C)[Zr](C1C(C)=C(C)C(C)=C1C)C1C(C)=C(C)C(C)=C1C Chemical compound C[SiH](C)[Zr](C1C(C)=C(C)C(C)=C1C)C1C(C)=C(C)C(C)=C1C UZCKAVZAROHTQV-UHFFFAOYSA-N 0.000 description 1
- QVEAMQSNWYWIIQ-UHFFFAOYSA-N C[SiH](C)[Zr](C1C=CC2=CC=CC=C12)C1C=CC=C1 Chemical compound C[SiH](C)[Zr](C1C=CC2=CC=CC=C12)C1C=CC=C1 QVEAMQSNWYWIIQ-UHFFFAOYSA-N 0.000 description 1
- AUCFLBLJELGUAX-UHFFFAOYSA-N C[SiH](C)[Zr](C1C=CC=C1)C1(C(=C(C(=C1)C)C)C)C Chemical compound C[SiH](C)[Zr](C1C=CC=C1)C1(C(=C(C(=C1)C)C)C)C AUCFLBLJELGUAX-UHFFFAOYSA-N 0.000 description 1
- MBNRZWNSGRHNOI-UHFFFAOYSA-N C[SiH](C)[Zr](C1C=CC=C1)C1C2=CC=CC=C2C2=C1C=CC=C2 Chemical compound C[SiH](C)[Zr](C1C=CC=C1)C1C2=CC=CC=C2C2=C1C=CC=C2 MBNRZWNSGRHNOI-UHFFFAOYSA-N 0.000 description 1
- RHSVJDJSVQIJNS-UHFFFAOYSA-N C[SiH]C.CC1=CC(C)([Zr]C2C=CC(=C2)C(C)(C)C)C(C)=C1C Chemical compound C[SiH]C.CC1=CC(C)([Zr]C2C=CC(=C2)C(C)(C)C)C(C)=C1C RHSVJDJSVQIJNS-UHFFFAOYSA-N 0.000 description 1
- HEDBCIJCSMXCQD-UHFFFAOYSA-N C[Si](C)(C)C1(C=CC=C1)[Hf]C1(C=CC=C1)[Si](C)(C)C Chemical compound C[Si](C)(C)C1(C=CC=C1)[Hf]C1(C=CC=C1)[Si](C)(C)C HEDBCIJCSMXCQD-UHFFFAOYSA-N 0.000 description 1
- NXNNTBTYTUJMHX-UHFFFAOYSA-N C[Si](C)(C)C1(C=CC=C1)[Zr]C1(C=CC=C1)[Si](C)(C)C Chemical compound C[Si](C)(C)C1(C=CC=C1)[Zr]C1(C=CC=C1)[Si](C)(C)C NXNNTBTYTUJMHX-UHFFFAOYSA-N 0.000 description 1
- QFCAQLCVAAUQMA-UHFFFAOYSA-N C[Si](C)(C)C1=CC([Zr]C2(C=CC(=C2)[Si](C)(C)C)[Si](C)(C)C)(C=C1)[Si](C)(C)C Chemical compound C[Si](C)(C)C1=CC([Zr]C2(C=CC(=C2)[Si](C)(C)C)[Si](C)(C)C)(C=C1)[Si](C)(C)C QFCAQLCVAAUQMA-UHFFFAOYSA-N 0.000 description 1
- JEMOTBOESUJOAE-UHFFFAOYSA-N C[Si](CCC1(C=CC=C1)[Hf]C1(C=CC=C1)CC[Si](C)(C)C)(C)C Chemical compound C[Si](CCC1(C=CC=C1)[Hf]C1(C=CC=C1)CC[Si](C)(C)C)(C)C JEMOTBOESUJOAE-UHFFFAOYSA-N 0.000 description 1
- 101100419874 Caenorhabditis elegans snr-2 gene Proteins 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229940126062 Compound A Drugs 0.000 description 1
- URXZXNYJPAJJOQ-UHFFFAOYSA-N Erucic acid Natural products CCCCCCC=CCCCCCCCCCCCC(O)=O URXZXNYJPAJJOQ-UHFFFAOYSA-N 0.000 description 1
- 229910005269 GaF 3 Inorganic materials 0.000 description 1
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 229910000003 Lead carbonate Inorganic materials 0.000 description 1
- 239000009566 Mao-to Substances 0.000 description 1
- 229910015275 MoF 6 Inorganic materials 0.000 description 1
- 229910017855 NH 4 F Inorganic materials 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229910019595 ReF 6 Inorganic materials 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical group [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- JGRKCXSBLBPASV-UHFFFAOYSA-N [Ti+4].C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CC1)[N-]C1(C(=C(C(=C1)C)C)C)C Chemical compound [Ti+4].C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CC1)[N-]C1(C(=C(C(=C1)C)C)C)C JGRKCXSBLBPASV-UHFFFAOYSA-N 0.000 description 1
- OGHSLLALFBRFKX-UHFFFAOYSA-N [Ti+4].C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCC1)[N-]C1(C(=C(C(=C1)C)C)C)C Chemical compound [Ti+4].C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCC1)[N-]C1(C(=C(C(=C1)C)C)C)C OGHSLLALFBRFKX-UHFFFAOYSA-N 0.000 description 1
- NWOHEUFHONHLPK-UHFFFAOYSA-N [Ti+4].C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C Chemical compound [Ti+4].C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C NWOHEUFHONHLPK-UHFFFAOYSA-N 0.000 description 1
- PLNWQIHXBKFTHY-UHFFFAOYSA-N [Ti+4].C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C Chemical compound [Ti+4].C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C PLNWQIHXBKFTHY-UHFFFAOYSA-N 0.000 description 1
- UZKRGPNOQZUJCV-UHFFFAOYSA-N [Ti+4].C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C Chemical compound [Ti+4].C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C UZKRGPNOQZUJCV-UHFFFAOYSA-N 0.000 description 1
- MUTIEYDSJRWRHC-UHFFFAOYSA-N [Ti+4].C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C Chemical compound [Ti+4].C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C MUTIEYDSJRWRHC-UHFFFAOYSA-N 0.000 description 1
- KWQGVBXKQUXYKJ-UHFFFAOYSA-N [Ti+4].C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C Chemical compound [Ti+4].C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C KWQGVBXKQUXYKJ-UHFFFAOYSA-N 0.000 description 1
- WUHNXUSBKRNKEK-UHFFFAOYSA-N [Ti+4].C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C Chemical compound [Ti+4].C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C WUHNXUSBKRNKEK-UHFFFAOYSA-N 0.000 description 1
- CJYFGRSWOFIAHL-UHFFFAOYSA-N [Ti+4].C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C Chemical compound [Ti+4].C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)C1(CCCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C CJYFGRSWOFIAHL-UHFFFAOYSA-N 0.000 description 1
- IQTAMBGXHFQPTF-UHFFFAOYSA-N [Ti+4].C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)CCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)CCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)CCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)CCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C Chemical compound [Ti+4].C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)CCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)CCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)CCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C.C1(=CC=CC=C1)[SiH](C1=CC=CC=C1)CCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C IQTAMBGXHFQPTF-UHFFFAOYSA-N 0.000 description 1
- BHTFMHPOXVAODU-UHFFFAOYSA-N [Ti+4].C[SiH](C)C1(CCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C Chemical compound [Ti+4].C[SiH](C)C1(CCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C BHTFMHPOXVAODU-UHFFFAOYSA-N 0.000 description 1
- PFIKWTLDBZIVSZ-UHFFFAOYSA-N [Ti+4].C[SiH](C)C1(CCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C Chemical compound [Ti+4].C[SiH](C)C1(CCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C PFIKWTLDBZIVSZ-UHFFFAOYSA-N 0.000 description 1
- LSEZUFRDBVQRRB-UHFFFAOYSA-N [Ti+4].C[SiH](C)C1(CCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C Chemical compound [Ti+4].C[SiH](C)C1(CCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C LSEZUFRDBVQRRB-UHFFFAOYSA-N 0.000 description 1
- CXQPHHFZNOLEAE-UHFFFAOYSA-N [Ti+4].C[SiH](C)C1(CCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C Chemical compound [Ti+4].C[SiH](C)C1(CCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C CXQPHHFZNOLEAE-UHFFFAOYSA-N 0.000 description 1
- OVRGSRMIEZJJEC-UHFFFAOYSA-N [Ti+4].C[SiH](C)C1(CCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C Chemical compound [Ti+4].C[SiH](C)C1(CCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C OVRGSRMIEZJJEC-UHFFFAOYSA-N 0.000 description 1
- HUVUVAIBJQMHRH-UHFFFAOYSA-N [Ti+4].C[SiH](C)C1(CCCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C Chemical compound [Ti+4].C[SiH](C)C1(CCCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)C1(CCCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C HUVUVAIBJQMHRH-UHFFFAOYSA-N 0.000 description 1
- SRILATUYPLVDBX-UHFFFAOYSA-N [Ti+4].C[SiH](C)CCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)CCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)CCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)CCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C Chemical compound [Ti+4].C[SiH](C)CCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)CCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)CCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C)CCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C SRILATUYPLVDBX-UHFFFAOYSA-N 0.000 description 1
- YBLPKXHYKGQGNA-UHFFFAOYSA-N [Ti+4].C[SiH](C1=CC=CC=C1)C1(CC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CC1)[N-]C1(C(=C(C(=C1)C)C)C)C Chemical compound [Ti+4].C[SiH](C1=CC=CC=C1)C1(CC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CC1)[N-]C1(C(=C(C(=C1)C)C)C)C YBLPKXHYKGQGNA-UHFFFAOYSA-N 0.000 description 1
- UKUNSGLTYUIAIU-UHFFFAOYSA-N [Ti+4].C[SiH](C1=CC=CC=C1)C1(CCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCC1)[N-]C1(C(=C(C(=C1)C)C)C)C Chemical compound [Ti+4].C[SiH](C1=CC=CC=C1)C1(CCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCC1)[N-]C1(C(=C(C(=C1)C)C)C)C UKUNSGLTYUIAIU-UHFFFAOYSA-N 0.000 description 1
- WINZWVDPNQXSSJ-UHFFFAOYSA-N [Ti+4].C[SiH](C1=CC=CC=C1)C1(CCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C Chemical compound [Ti+4].C[SiH](C1=CC=CC=C1)C1(CCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C WINZWVDPNQXSSJ-UHFFFAOYSA-N 0.000 description 1
- JDQZNBIQHYPXRI-UHFFFAOYSA-N [Ti+4].C[SiH](C1=CC=CC=C1)C1(CCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C Chemical compound [Ti+4].C[SiH](C1=CC=CC=C1)C1(CCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C JDQZNBIQHYPXRI-UHFFFAOYSA-N 0.000 description 1
- JKOTWTDOFOGRBD-UHFFFAOYSA-N [Ti+4].C[SiH](C1=CC=CC=C1)C1(CCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C Chemical compound [Ti+4].C[SiH](C1=CC=CC=C1)C1(CCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C JKOTWTDOFOGRBD-UHFFFAOYSA-N 0.000 description 1
- UYJULYLNPDFPKY-UHFFFAOYSA-N [Ti+4].C[SiH](C1=CC=CC=C1)C1(CCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C Chemical compound [Ti+4].C[SiH](C1=CC=CC=C1)C1(CCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C UYJULYLNPDFPKY-UHFFFAOYSA-N 0.000 description 1
- GLWKCTHCLKVCKL-UHFFFAOYSA-N [Ti+4].C[SiH](C1=CC=CC=C1)C1(CCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C Chemical compound [Ti+4].C[SiH](C1=CC=CC=C1)C1(CCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C GLWKCTHCLKVCKL-UHFFFAOYSA-N 0.000 description 1
- AIHUMQCVZPZCHM-UHFFFAOYSA-N [Ti+4].C[SiH](C1=CC=CC=C1)C1(CCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C Chemical compound [Ti+4].C[SiH](C1=CC=CC=C1)C1(CCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C AIHUMQCVZPZCHM-UHFFFAOYSA-N 0.000 description 1
- QGJOBSJKSSXPFF-UHFFFAOYSA-N [Ti+4].C[SiH](C1=CC=CC=C1)C1(CCCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C Chemical compound [Ti+4].C[SiH](C1=CC=CC=C1)C1(CCCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)C1(CCCCCCCCCCC1)[N-]C1(C(=C(C(=C1)C)C)C)C QGJOBSJKSSXPFF-UHFFFAOYSA-N 0.000 description 1
- YIQDBBDFCGWDJR-UHFFFAOYSA-N [Ti+4].C[SiH](C1=CC=CC=C1)CCCCCCCCCCCCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)CCCCCCCCCCCCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)CCCCCCCCCCCCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)CCCCCCCCCCCCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C Chemical compound [Ti+4].C[SiH](C1=CC=CC=C1)CCCCCCCCCCCCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)CCCCCCCCCCCCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)CCCCCCCCCCCCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)CCCCCCCCCCCCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C YIQDBBDFCGWDJR-UHFFFAOYSA-N 0.000 description 1
- WMBSHDGIMQBFEP-UHFFFAOYSA-N [Ti+4].C[SiH](C1=CC=CC=C1)CCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)CCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)CCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)CCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C Chemical compound [Ti+4].C[SiH](C1=CC=CC=C1)CCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)CCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)CCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C.C[SiH](C1=CC=CC=C1)CCCCCCCC[N-]C1(C(=C(C(=C1)C)C)C)C WMBSHDGIMQBFEP-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 125000004054 acenaphthylenyl group Chemical group C1(=CC2=CC=CC3=CC=CC1=C23)* 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 125000004414 alkyl thio group Chemical group 0.000 description 1
- 150000001356 alkyl thiols Chemical group 0.000 description 1
- 125000000304 alkynyl group Chemical group 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- 229940063655 aluminum stearate Drugs 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 150000003931 anilides Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 229910052586 apatite Inorganic materials 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 125000003435 aroyl group Chemical group 0.000 description 1
- 125000005239 aroylamino group Chemical group 0.000 description 1
- 125000001769 aryl amino group Chemical group 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- RSOILICUEWXSLA-UHFFFAOYSA-N bis(1,2,2,6,6-pentamethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)N(C)C(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)N(C)C(C)(C)C1 RSOILICUEWXSLA-UHFFFAOYSA-N 0.000 description 1
- XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 150000001638 boron Chemical class 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- ZCZLQYAECBEUBH-UHFFFAOYSA-L calcium;octadec-9-enoate Chemical compound [Ca+2].CCCCCCCCC=CCCCCCCCC([O-])=O.CCCCCCCCC=CCCCCCCCC([O-])=O ZCZLQYAECBEUBH-UHFFFAOYSA-L 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 125000000609 carbazolyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3NC12)* 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000013626 chemical specie Substances 0.000 description 1
- 125000004803 chlorobenzyl group Chemical group 0.000 description 1
- TYYBBNOTQFVVKN-UHFFFAOYSA-N chromium(2+);cyclopenta-1,3-diene Chemical compound [Cr+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 TYYBBNOTQFVVKN-UHFFFAOYSA-N 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000003426 co-catalyst Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 125000001485 cycloalkadienyl group Chemical group 0.000 description 1
- 125000001995 cyclobutyl group Chemical group [H]C1([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000004663 dialkyl amino group Chemical group 0.000 description 1
- 125000005265 dialkylamine group Chemical group 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical class [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- LJSQFQKUNVCTIA-UHFFFAOYSA-N diethyl sulfide Chemical compound CCSCC LJSQFQKUNVCTIA-UHFFFAOYSA-N 0.000 description 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
- 125000006001 difluoroethyl group Chemical group 0.000 description 1
- 125000001028 difluoromethyl group Chemical group [H]C(F)(F)* 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- QKIUAMUSENSFQQ-UHFFFAOYSA-N dimethylazanide Chemical compound C[N-]C QKIUAMUSENSFQQ-UHFFFAOYSA-N 0.000 description 1
- ZTJBELXDHFJJEU-UHFFFAOYSA-N dimethylboron Chemical compound C[B]C ZTJBELXDHFJJEU-UHFFFAOYSA-N 0.000 description 1
- YOTZYFSGUCFUKA-UHFFFAOYSA-N dimethylphosphine Chemical compound CPC YOTZYFSGUCFUKA-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 229940069096 dodecene Drugs 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 238000007580 dry-mixing Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000010096 film blowing Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 150000002221 fluorine Chemical class 0.000 description 1
- 125000003784 fluoroethyl group Chemical group [H]C([H])(F)C([H])([H])* 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000013611 frozen food Nutrition 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000004746 geotextile Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 230000026030 halogenation Effects 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001145 hydrido group Chemical group *[H] 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- QLNAVQRIWDRPHA-UHFFFAOYSA-N iminophosphane Chemical compound P=N QLNAVQRIWDRPHA-UHFFFAOYSA-N 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910001504 inorganic chloride Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- QWDJLDTYWNBUKE-UHFFFAOYSA-L magnesium bicarbonate Chemical compound [Mg+2].OC([O-])=O.OC([O-])=O QWDJLDTYWNBUKE-UHFFFAOYSA-L 0.000 description 1
- 229910000022 magnesium bicarbonate Inorganic materials 0.000 description 1
- 235000014824 magnesium bicarbonate Nutrition 0.000 description 1
- 239000002370 magnesium bicarbonate Substances 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- AXLHVTKGDPVANO-UHFFFAOYSA-N methyl 2-amino-3-[(2-methylpropan-2-yl)oxycarbonylamino]propanoate Chemical compound COC(=O)C(N)CNC(=O)OC(C)(C)C AXLHVTKGDPVANO-UHFFFAOYSA-N 0.000 description 1
- MHERPFVRWOTBSF-UHFFFAOYSA-N methyl(phenyl)phosphane Chemical compound CPC1=CC=CC=C1 MHERPFVRWOTBSF-UHFFFAOYSA-N 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- APRJFNLVTJWEPP-UHFFFAOYSA-M n,n-diethylcarbamate Chemical compound CCN(CC)C([O-])=O APRJFNLVTJWEPP-UHFFFAOYSA-M 0.000 description 1
- DWLVWMUCHSLGSU-UHFFFAOYSA-M n,n-dimethylcarbamate Chemical compound CN(C)C([O-])=O DWLVWMUCHSLGSU-UHFFFAOYSA-M 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- LPNBBFKOUUSUDB-UHFFFAOYSA-M p-toluate Chemical compound CC1=CC=C(C([O-])=O)C=C1 LPNBBFKOUUSUDB-UHFFFAOYSA-M 0.000 description 1
- 125000001037 p-tolyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 1
- GUVXZFRDPCKWEM-UHFFFAOYSA-N pentalene Chemical compound C1=CC2=CC=CC2=C1 GUVXZFRDPCKWEM-UHFFFAOYSA-N 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical class C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 229910052615 phyllosilicate Inorganic materials 0.000 description 1
- 238000002464 physical blending Methods 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 150000004291 polyenes Chemical class 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920003053 polystyrene-divinylbenzene Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 125000000168 pyrrolyl group Chemical group 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000002644 respiratory therapy Methods 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 238000007363 ring formation reaction Methods 0.000 description 1
- 238000001175 rotational moulding Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229920006300 shrink film Polymers 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 235000011888 snacks Nutrition 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229920006302 stretch film Polymers 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 125000005415 substituted alkoxy group Chemical group 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000001721 transfer moulding Methods 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- LPEBYPDZMWMCLZ-CVBJKYQLSA-L zinc;(z)-octadec-9-enoate Chemical compound [Zn+2].CCCCCCCC\C=C/CCCCCCCC([O-])=O.CCCCCCCC\C=C/CCCCCCCC([O-])=O LPEBYPDZMWMCLZ-CVBJKYQLSA-L 0.000 description 1
- HEPBQSXQJMTVFI-UHFFFAOYSA-N zinc;butane Chemical compound [Zn+2].CCC[CH2-].CCC[CH2-] HEPBQSXQJMTVFI-UHFFFAOYSA-N 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/48—Zirconium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Description
本開示及びその効果のより完全な理解は、添付の図面に関連して以下の記述を参考することにより得ることができる。
発明の概要
(a)エチレン及びC4〜C8α−オレフィンより成る群から選択される少なくとも一種のコモノマー;と、
(b)メチルアルミノキサンにより活性化されたメタロセン触媒化合物及び担体物質を含む担持型触媒系であって、メチルアルミノキサンが担体物質1グラムあたり3〜9mmolの範囲で存在し、メタロセンは担体物質1グラムあたり0.01〜1.0mmolの範囲で存在するもの;
を接触させることを含むオレフィンの重合方法であって、触媒が、少なくとも2,500gポリエチレン/g触媒化合物・時間の活性を有し、且つ該方法が、少なくとも0.30g/cm3の嵩密度を有するポリマーを製造するものである方法を提供する。
序論
本発明は、一般に、最適化された金属担持量及び活性剤濃度を有するメタロセン触媒化合物の存在下でのオレフィンの重合方法、及びある例示的な実施態様において、メチルアルミノキサン(MAO)で活性化された担持型メタロセンを用いるエチレン及びC3〜C20オレフィンの重合方法に関する。
元素の周期表の「族」について本明細書において用いた場合、周期表の族についての「新規な」番号付け方式は、CRC HANDBOOK OF CHEMISTRY AND PHYSICS(David R. Lide編集、CRC Press社、第81版、2000年)におけるように用いられるものである。
本発明において有用な触媒系は、本明細書に記載されたような少なくとも1種のメタロセン触媒成分を含む。メタロセン触媒化合物は一般的に、例えば1 & 2 METALLOCENE-BASED POLYOLEFINS(John Scheirs及びW. Kaminsky編、John Wiley and Sons社、2000);G.G. Hlatky、181 COORDINATION CHEM. REV. 243-296(1999)に全体にわたって記載されており、特にポリエチレンの合成における使用については1 METALLOCENE-BASED POLYOLEFINS 261-377(2000)に記載されている。本明細書に記載されるメタロセン触媒化合物には、少なくとも1つの第3族〜第12族金属原子に結合した1以上のCp配位子(シクロペンタジエニル及びシクロペンタジエニルにアイソローバルな配位子)及び少なくとも1つの金属原子に結合した1以上の脱離基を有する「ハーフサンドイッチ」化合物及び「フルサンドイッチ」化合物が包含される。以下においては、これらの化合物を「メタロセン」又は「メタロセン触媒成分」と称する。メタロセン触媒成分は、以下にさらに説明するように特定の例示的な実施態様においては担体物質上に担持され、他の触媒成分と共に又は他の触媒成分なしで担持させることができる。
CpACpBMXn (I)
(ここで、Mは前記の通りであり、
各XはMに化学結合し、
各Cp基はMに化学結合し、
nは0又は1〜4の整数であり、特定的な例示的な実施態様においては1又は2である。)
CpA(A)CpBMXn (II)
式(II)で表わされるこれらの架橋化合物は、「架橋メタロセン」として知られている。構造(II)中の要素CpA、CpB、M、X及びnは、式(I)について上で定義した通りであり;各Cp配位子はMに化学結合し、(A)は各Cpに化学結合する。架橋基(A)の非限定的な例には、少なくとも1個の第13〜16族原子(例えば炭素、酸素、窒素、ケイ素、アルミニウム、ホウ素、ゲルマニウム及び錫原子並びにそれらの組合せであり、ただしこれらに限定されない)を含有する二価炭化水素基が包含され、ここで、これらのヘテロ原子はまた、中性原子価を満たすためにC1〜C12アルキル又はアリール置換されていてもよい。架橋基(A)はまた、ハロゲン基及び鉄を含めて、(式(I)について)上で規定した通りの置換基Rを含有していてもよい。架橋基(A)のより一層特定的な非限定的例は、C1〜C6アルキレン、置換C1〜C6アルキレン、酸素、硫黄、R'2C=、R'2Si=、=Si(R')2Si(R'2)=、R'2Ge=、R'P=(ここで、「=」は2個の化学結合を表わす)で表され、ここで、R'はヒドリド、ヒドロカルビル、置換ヒドロカルビル、ハロカルビル、置換ハロカルビル、ヒドロカルビル置換有機メタロイド、ハロカルビル置換有機メタロイド、二置換ホウ素、二置換第15族原子、置換第16族原子及びハロゲン基より成る群から独立に選択され;2以上のR'が結合して環又は環系を形成してもよい。1つの例示的な実施態様において、式(II)の架橋メタロセン触媒成分は、2以上の架橋基(A)を有する。
CpA(A)QMXn (III)
(ここで、CpAは上で定義したものであってMに結合し、
(A)はQ及びCpAに結合する架橋基であり、
Q基からの原子がMに結合し、且つnは整数0、1又は2である。)
CpAMQqXw (IVa)
(ここで、CpAは、(I)中のCp基についてと同様に定義され、Mに結合する配位子であり、
各Qは独立にMに結合し、
Xは(I)において上に記載したような脱離基であり、
wは0〜3の範囲であり、1つの例示的な実施態様においては0又は3であり、
qは0〜3の範囲であり、1つの例示的な実施態様においては0又は3である。)
CpAM(W2GZ)Xy 又は (IVb)
T(CpAM(W2GZ)Xy)m
{ここで、M、CpA、及びXは上で定義した通りであり、
W2GZは多座配位子単位(例えばピバレート)を形成し、ここで、W基の少なくとも1つはMとの結合を形成し、各Wが−O−、−NR−、−CR2−及び−S−より成る群から独立に選択されるように規定され;Gは炭素又は珪素であり;Zは、R、−OR、−NR2、−CR3、−SR、−SiR3、−PR2及びヒドリドより成る群から選択され、但し、Wが−NR−である場合には、Zは−OR、−NR2、−SR、−SiR3、−PR2より成る群から選択され、また、Wについての中性原子価はZによって満たされ;ここで、各Rは、C1〜C10ヘテロ原子含有基、C1〜C10アルキル、C6〜C12アリール、C6〜C12アルキルアリール、C1〜C10アルコキシ及びC6〜C12アリールオキシより成る群から独立に選択され;
yは特定の実施態様においては1又は2であり、
TはC1〜C10アルキレン、C6〜C12アリーレン及びC1〜C10ヘテロ原子含有基及びC6〜C12ヘテロ環式基より成る群から選択される架橋基であり、各T基は隣接する「CpAM(W2GZ)Xy」基を架橋するものであって、CpA基に化学結合し;
mは1〜7の整数である。より特定の例示的な実施態様においてはmは2〜6の整数である。}
(Va−i)及び(Va−ii)中のQは、ハロゲンイオン、アルキル、アルキレン、アリール、アリーレン、アルコキシ、アリールオキシ、アミン、アルキルアミン、ホスフィン、アルキルホスフィン、置換アルキル、置換アリール、置換アルコキシ、置換アリールオキシ、置換アミン、置換アルキルアミン、置換ホスフィン、置換アルキルホスフィン、カルバメート、ヘテロアリル、カルボキシレート(好適なカルバメート及びカルボキシレートの非限定的な例には、トリメチルアセテート、トリメチルアセテート、メチルアセテート、p−トルエート、ベンゾエート、ジエチルカルバメート及びジメチルカルバメートが包含される)、フッ素化アルキル、フッ素化アリール及びフッ素化アルキルカルボキシレートより成る群から選択され、
qは1〜3の範囲の整数であり、
各R*は独立に、1つの例示的な実施態様においてはヒドロカルビル及びヘテロ原子含有ヒドロカルビルより成る群から選択され、別の例示的な実施態様においてはアルキレン、置換アルキレン及びヘテロ原子含有ヒドロカルビルより成る群から選択され、より特定の例示的な実施態様においてはC1〜C12アルキレン、C1〜C12置換アルキレン及びC1〜C12ヘテロ原子含有炭化水素より成る群から選択され、さらにより一層特定の例示的な実施態様においてはC1〜C4アルキレンより成る群から選択され、別の例示的な実施態様においては構造(Vb)〜(Vd)中の両方のR*基は同一であり、
Aは構造(II)中の(A)について上で記載した通りであり、より特定的には、1つの例示的な実施態様においては−O−、−S−、−SO2−、−NR−、=SiR2、=GeR2、=SnR2、−R2SiSiR2−、RP=、C1〜C12アルキレン、置換C1〜C12アルキレン、二価C4〜C12環状炭化水素並びに置換及び非置換アリール基より成る群から選択され、より特定の例示的な実施態様においてはC5〜C8環状炭化水素、−CH2CH2−、=CR2及び=SiR2より成る群から選択され、ここで、Rは1つの例示的な実施態様においてはアルキル、シクロアルキル、アリール、アルコキシ、フルオロアルキル及びヘテロ原子含有炭化水素より成る群から選択され、より特定の例示的な実施態様においては、RはC1〜C6アルキル、置換フェニル、フェニル及びC1〜C6アルコキシより成る群から選択され、さらにより一層特定的な例示的な実施態様においては、Rはメトキシ、メチル、フェノキシ及びフェニルより成る群から選択され、
Aはさらに別の例示的な実施態様においては存在していなくてもよく、その場合には各R*はR1〜R12についてと同様に定義され、
各Xは(I)において上で記載した通りであり、
nは整数0〜4、別の例示的な実施態様においては1〜3、さらに別の例示的な実施態様においては1又は2であり、
R1〜R12は独立に、1つの例示的な実施態様においては水素基、ハロゲン基、C1〜C12アルキル、C2〜C12アルケニル、C6〜C12アリール、C7〜C20アルキルアリール、C1〜C12アルコキシ、C1〜C12フルオロアルキル、C6〜C12フルオロアリール及びC1〜C12ヘテロ原子含有炭化水素並びにそれらの置換誘導体より成る群から選択され、より特定的な例示的な実施態様においては水素基、フッ素基、塩素基、臭素基、C1〜C6アルキル、C2〜C6アルケニル、C7〜C18アルキルアリール、C1〜C6フルオロアルキル、C2〜C6フルオロアルケニル、C7〜C18フルオロアルキルアリールより成る群から選択され、さらにより一層特定的な例示的な実施態様においては水素基、フッ素基、塩素基、メチル、エチル、プロピル、イソプロピル、ブチル、イソブチル、t−ブチル、ヘキシル、フェニル、2,6−ジメチルフェニル及び4−t−ブチルフェニル基より成る群から選択され、ここで、隣接するR基は、飽和、一部飽和又は完全飽和の環を形成してもよい。)
シクロペンタジエニルジルコニウムXn、
インデニルジルコニウムXn、
(1−メチルインデニル)ジルコニウムXn、
(2−メチルインデニル)ジルコニウムXn、
(1−プロピルインデニル)ジルコニウムXn、
(2−プロピルインデニル)ジルコニウムXn、
(1−ブチルインデニル)ジルコニウムXn、
(2−ブチルインデニル)ジルコニウムXn、
(メチルシクロペンタジエニル)ジルコニウムXn、
テトラヒドロインデニルジルコニウムXn、
(ペンタメチルシクロペンタジエニル)ジルコニウムXn、
シクロペンタジエニルジルコニウムXn、
ペンタメチルシクロペンタジエニルチタンXn、
テトラメチルシクロペンチルチタンXn、
1,2,4−トリメチルシクロペンタジエニルジルコニウムXn、
ジメチルシリル(1,2,3,4−テトラメチルシクロペンタジエニル)(シクロペンタジエニル)ジルコニウムXn、
ジメチルシリル(1,2,3,4−テトラメチルシクロペンタジエニル)(1,2,3−トリメチルシクロペンタジエニル)ジルコニウムXn、
ジメチルシリル(1,2,3,4−テトラメチルシクロペンタジエニル)(1,2−ジメチルシクロペンタジエニル)ジルコニウムXn、
ジメチルシリル(1,2,3,4−テトラメチルシクロペンタジエニル)(2−メチルシクロペンタジエニル)ジルコニウムXn、
ジメチルシリル(シクロペンタジエニル)(インデニル)ジルコニウムXn、
ジメチルシリル(2−メチルインデニル)(フルオレニル)ジルコニウムXn、
ジフェニルシリル(1,2,3,4−テトラメチルシクロペンタジエニル)(3−プロピルシクロペンタジエニル)ジルコニウムXn、
ジメチルシリル(1,2,3,4−テトラメチルシクロペンタジエニル)(3−t−ブチルシクロペンタジエニル)ジルコニウムXn、
ジメチルゲルミル(1,2−ジメチルシクロペンタジエニル)(3−イソプロピルシクロペンタジエニル)ジルコニウムXn、
ジメチルシリル(1,2,3,4−テトラメチルシクロペンタジエニル)(3−メチルシクロペンタジエニル)ジルコニウムXn、
ジフェニルメチリデン(シクロペンタジエニル)(9−フルオレニル)ジルコニウムXn、
ジフェニルメチリデン(シクロペンタジエニル)(インデニル)ジルコニウムXn、
イソプロピリデンビス(シクロペンタジエニル)ジルコニウムXn、
イソプロピリデン(シクロペンタジエニル)(9−フルオレニル)ジルコニウムXn、
イソプロピリデン(3−メチルシクロペンタジエニル)(9−フルオレニル)ジルコニウムXn、
エチレンビス(9−フルオレニル)ジルコニウムXn、
メソエチレンビス(1−インデニル)ジルコニウムXn、
エチレンビス(1−インデニル)ジルコニウムXn、
エチレンビス(2−メチル−1−インデニル)ジルコニウムXn、
エチレンビス(2−メチル−4,5,6,7−テトラヒドロ−1−インデニル)ジルコニウムXn、
エチレンビス(2−プロピル−4,5,6,7−テトラヒドロ−1−インデニル)ジルコニウムXn、
エチレンビス(2−イソプロピル−4,5,6,7−テトラヒドロ−1−インデニル)ジルコニウムXn、
エチレンビス(2−ブチル−4,5,6,7−テトラヒドロ−1−インデニル)ジルコニウムXn、
エチレンビス(2−イソブチル−4,5,6,7−テトラヒドロ−1−インデニル)ジルコニウムXn、
ジメチルシリル(4,5,6,7−テトラヒドロ−1−インデニル)ジルコニウムXn、
ジフェニル(4,5,6,7−テトラヒドロ−1−インデニル)ジルコニウムXn、
エチレンビス(4,5,6,7−テトラヒドロ−1−インデニル)ジルコニウムXn、
ジメチルシリルビス(シクロペンタジエニル)ジルコニウムXn、
ジメチルシリルビス(9−フルオレニル)ジルコニウムXn、
ジメチルシリルビス(1−インデニル)ジルコニウムXn、
ジメチルシリルビス(2−メチルインデニル)ジルコニウムXn、
ジメチルシリルビス(2−プロピルインデニル)ジルコニウムXn、
ジメチルシリルビス(2−ブチルインデニル)ジルコニウムXn、
ジフェニルシリルビス(2−メチルインデニル)ジルコニウムXn、
ジフェニルシリルビス(2−プロピルインデニル)ジルコニウムXn、
ジフェニルシリルビス(2−ブチルインデニル)ジルコニウムXn、
ジメチルゲルミルビス(2−メチルインデニル)ジルコニウムXn、
ジメチルシリルビス(テトラヒドロインデニル)ジルコニウムXn、
ジメチルシリルビス(テトラメチルシクロペンタジエニル)ジルコニウムXn、
ジメチルシリル(シクロペンタジエニル)(9−フルオレニル)ジルコニウムXn、
ジフェニルシリル(シクロペンタジエニル)(9−フルオレニル)ジルコニウムXn、
ジフェニルシリルビス(インデニル)ジルコニウムXn、
シクロトリメチレンシリル(テトラメチルシクロペンタジエニル)(シクロペンタジエニル)ジルコニウムXn、
シクロテトラメチレンシリル(テトラメチルシクロペンタジエニル)(シクロペンタジエニル)ジルコニウムXn、
シクロトリメチレンシリル(テトラメチルシクロペンタジエニル)(2−メチルインデニル)ジルコニウムXn、
シクロトリメチレンシリル(テトラメチルシクロペンタジエニル)(3−メチルシクロペンタジエニル)ジルコニウムXn、
シクロトリメチレンシリルビス(2−メチルインデニル)ジルコニウムXn、
シクロトリメチレンシリル(テトラメチルシクロペンタジエニル)(2,3,5−トリメチルシクロペンタジエニル)ジルコニウムXn、
シクロトリメチレンシリルビス(テトラメチルシクロペンタジエニル)ジルコニウムXn、
ジメチルシリル(テトラメチルシクロペンタジエニル)(N−t−ブチルアミド)チタンXn、
ビス(シクロペンタジエニル)クロムXn、
ビス(シクロペンタジエニル)ジルコニウムXn、
ビス(n−ブチルシクロペンタジエニル)ジルコニウムXn、
ビス(n−ドデシルシクロペンタジエニル)ジルコニウムXn、
ビス(エチルシクロペンタジエニル)ジルコニウムXn、
ビス(イソブチルシクロペンタジエニル)ジルコニウムXn、
ビス(イソプロピルシクロペンタジエニル)ジルコニウムXn、
ビス(メチルシクロペンタジエニル)ジルコニウムXn、
ビス(n−オクチルシクロペンタジエニル)ジルコニウムXn、
ビス(n−ペンチルシクロペンタジエニル)ジルコニウムXn、
ビス(n−プロピルシクロペンタジエニル)ジルコニウムXn、
ビス(トリメチルシリルシクロペンタジエニル)ジルコニウムXn、
ビス(1,3−ビス(トリメチルシリル)シクロペンタジエニル)ジルコニウムXn、
ビス(1−エチル−2−メチルシクロペンタジエニル)ジルコニウムXn、
ビス(1−エチル−3−メチルシクロペンタジエニル)ジルコニウムXn、
ビス(ペンタメチルシクロペンタジエニル)ジルコニウムXn、
ビス(ペンタメチルシクロペンタジエニル)ジルコニウムXn、
ビス(1−プロピル−3−メチルシクロペンタジエニル)ジルコニウムXn、
ビス(1−n−ブチル−3−メチルシクロペンタジエニル)ジルコニウムXn、
ビス(1−イソブチル−3−メチルシクロペンタジエニル)ジルコニウムXn、
ビス(1−プロピル−3−ブチルシクロペンタジエニル)ジルコニウムXn、
ビス(1−n−ブチル−3−n−ブチルシクロペンタジエニル)ジルコニウムXn、
ビス(1,3−メチル−n−ブチルシクロペンタジエニル)ジルコニウムXn、
ビス(4,7−ジメチルインデニル)ジルコニウムXn、
ビス(インデニル)ジルコニウムXn、
ビス(2−メチルインデニル)ジルコニウムXn、
シクロペンタジエニルインデニルジルコニウムXn、
(テトラメチルシクロペンタジエニル)(n−プロピルシクロペンタジエニル)ジルコニウムXn、
(ペンタメチルシクロペンタジエニル)(n−プロピルシクロペンタジエニル)ジルコニウムXn、
ビス(n−プロピルシクロペンタジエニル)ハフニウムXn、
ビス(n−ブチルシクロペンタジエニル)ハフニウムXn、
ビス(n−ペンチルシクロペンタジエニル)ハフニウムXn、
(n−プロピルシクロペンタジエニル)(n−ブチルシクロペンタジエニル)ハフニウムXn、
ビス[(2−トリメチルシリルエチル)シクロペンタジエニル]ハフニウムXn、
ビス(トリメチルシリルシクロペンタジエニル)ハフニウムXn、
ビス(2−n−プロピルインデニル)ハフニウムXn、
ビス(2−n−ブチルインデニル)ハフニウムXn、
ジメチルシリルビス(n−プロピルシクロペンタジエニル)ハフニウムXn、
ジメチルシリルビス(n−ブチルシクロペンタジエニル)ハフニウムXn、
ビス(9−n−プロピルフルオレニル)ハフニウムXn、
ビス(9−n−ブチルフルオレニル)ハフニウムXn、
(9−n−プロピルフルオレニル)(2−n−プロピルインデニル)ハフニウムXn、
ビス(1−n−プロピル−2−メチルシクロペンタジエニル)ハフニウムXn、
(n−プロピルシクロペンタジエニル)(1−n−プロピル−3−n−ブチルシクロペンタジエニル)ハフニウムXn、
ジメチルシリル(テトラメチルシクロペンタジエニル)(シクロプロピルアミド)チタンXn、
ジメチルシリル(テトラメチルシクロペンタジエニル)(シクロブチルアミド)チタンXn、
ジメチルシリル(テトラメチルシクロペンタジエニル)(シクロペンチルアミド)チタンXn、
ジメチルシリル(テトラメチルシクロペンタジエニル)(シクロヘキシルアミド)チタンXn、
ジメチルシリル(テトラメチルシクロペンタジエニル)(シクロヘプチルアミド)チタンXn、
ジメチルシリル(テトラメチルシクロペンタジエニル)(シクロオクチルアミド)チタンXn、
ジメチルシリル(テトラメチルシクロペンタジエニル)(シクロノニルアミド)チタンXn、
ジメチルシリル(テトラメチルシクロペンタジエニル)(シクロデシルアミド)チタンXn、
ジメチルシリル(テトラメチルシクロペンタジエニル)(シクロウンデシルアミド)チタンXn、
ジメチルシリル(テトラメチルシクロペンタジエニル)(シクロドデシルアミド)チタンXn、
ジメチルシリル(テトラメチルシクロペンタジエニル)(sec−ブチルアミド)チタンXn、
ジメチルシリル(テトラメチルシクロペンタジエニル)(n−オクチルアミド)チタンXn、
ジメチルシリル(テトラメチルシクロペンタジエニル)(n−デシルアミド)チタンXn、
ジメチルシリル(テトラメチルシクロペンタジエニル)(n−オクタデシルアミド)チタンXn、
メチルフェニルシリル(テトラメチルシクロペンタジエニル)(シクロプロピルアミド)チタンXn、
メチルフェニルシリル(テトラメチルシクロペンタジエニル)(シクロブチルアミド)チタンXn、
メチルフェニルシリル(テトラメチルシクロペンタジエニル)(シクロペンチルアミド)チタンXn、
メチルフェニルシリル(テトラメチルシクロペンタジエニル)(シクロヘキシルアミド)チタンXn、
メチルフェニルシリル(テトラメチルシクロペンタジエニル)(シクロヘプチルアミド)チタンXn、
メチルフェニルシリル(テトラメチルシクロペンタジエニル)(シクロオクチルアミド)チタンXn、
メチルフェニルシリル(テトラメチルシクロペンタジエニル)(シクロノニルアミド)チタンXn、
メチルフェニルシリル(テトラメチルシクロペンタジエニル)(シクロデシルアミド)チタンXn、
メチルフェニルシリル(テトラメチルシクロペンタジエニル)(シクロウンデシルアミド)チタンXn、
メチルフェニルシリル(テトラメチルシクロペンタジエニル)(シクロドデシルアミド)チタンXn、
メチルフェニルシリル(テトラメチルシクロペンタジエニル)(sec−ブチルアミド)チタンXn、
メチルフェニルシリル(テトラメチルシクロペンタジエニル)(n−オクチルアミド)チタンXn、
メチルフェニルシリル(テトラメチルシクロペンタジエニル)(n−デシルアミド)チタンXn、
メチルフェニルシリル(テトラメチルシクロペンタジエニル)(n−オクタデシルアミド)チタンXn、
ジフェニルシリル(テトラメチルシクロペンタジエニル)(シクロプロピルアミド)チタンXn、
ジフェニルシリル(テトラメチルシクロペンタジエニル)(シクロブチルアミド)チタンXn、
ジフェニルシリル(テトラメチルシクロペンタジエニル)(シクロペンチルアミド)チタンXn、
ジフェニルシリル(テトラメチルシクロペンタジエニル)(シクロヘキシルアミド)チタンXn、
ジフェニルシリル(テトラメチルシクロペンタジエニル)(シクロヘプチルアミド)チタンXn、
ジフェニルシリル(テトラメチルシクロペンタジエニル)(シクロオクチルアミド)チタンXn、
ジフェニルシリル(テトラメチルシクロペンタジエニル)(シクロノニルアミド)チタンXn、
ジフェニルシリル(テトラメチルシクロペンタジエニル)(シクロデシルアミド)チタンXn、
ジフェニルシリル(テトラメチルシクロペンタジエニル)(シクロウンデシルアミド)チタンXn、
ジフェニルシリル(テトラメチルシクロペンタジエニル)(シクロドデシルアミド)チタンXn、
ジフェニルシリル(テトラメチルシクロペンタジエニル)(sec−ブチルアミド)チタンXn、
ジフェニルシリル(テトラメチルシクロペンタジエニル)(n−オクチルアミド)チタンXn、
ジフェニルシリル(テトラメチルシクロペンタジエニル)(n−デシルアミド)チタンXn、
ジフェニルシリル(テトラメチルシクロペンタジエニル)(n−オクタデシルアミド)チタンXn、
及びそれらの誘導体(ここで、nの値は、1,2又は3である)。「それらの誘導体」とは、1つの例示的な実施態様においては構造(Va)〜(Vd)について上に記載したような任意の置換又は環形成を意味し、特に、金属「M」(Cr、Zr、Ti又はHf)のCr、Zr、Hf及びTiより成る群から選択される原子による置き換え、並びに「X」基のC1〜C5アルキル、C6アリール、C6〜C10アルキルアリール、フッ素、塩素又は臭素のいずれかによる置き換えを意味する。
本発明の触媒組成物と共に使用される活性剤は、メチルアルミノキサン(「MAO」)である。好適なMAO源は、ルイジアナ州バトンルージュのアルバールマル社(Albemarle Cooporation)から購入できる30重量%MAO溶液である。一般に、MAOは、本発明の触媒組成物中に3〜9mmolMAO/g担持物質の範囲の量で存在する。ある好ましい実施態様においては、MAOは、4〜7.7mmolMAO/g担持物質の範囲の量で存在する。あるより好ましい実施態様においては、5〜6.5mmolMAO/g担持物質の範囲の量で存在する。ある最も好ましい実施態様においては、6〜6.5mmolMAO/g担持物質の範囲の量で存在する。MAO活性剤は、Gregory G. HlatkyによってHeterogeneous Single-Site Catalysts for Olefin Polymerization 100(4) CHEMICAL REVIEWS 1347-1374 (2000)に記載されたように、触媒成分(例えばメタロセン)と一緒に又は触媒成分とは別に、担体と連結させたり担体に結合させたりすることができる。
本発明の触媒系の一部として担体を存在させることもできる。メタロセンのようなシングルサイト触媒用の担体、担持方法、変性方法及び担体活性化方法は、例えば1 METALLOCENE-BASED POLYOLEFINS 173-218(J. Scheirs及びW. Kaminsky編、John Wiley and Sons Ltd. 2000)に議論されている。本明細書において用いた場合の用語「担体」と「キャリヤー」とは互換的に用いられ、任意の担体物質をいい、無機担体物質も有機担体物質も含む。1つの例示的な実施態様においては多孔質担体物質であり得る。担体物質の非限定的な例には、無機酸化物及び無機塩化物、特にタルク、クレー、シリカ、アルミナ、マグネシア、ジルコニア、酸化鉄、ボリア、酸化カルシウム、酸化亜鉛、酸化バリウム、トリア、リン酸アルミニウムゲルのような材料、並びにポリ塩化ビニル及び置換ポリスチレンのようなポリマー、ポリスチレン ジビニルベンゼン ポリオレフィン又はポリマー化合物のような官能化又は架橋有機担体、並びにそれらの混合物、並びにグラファイト、その様々な形態の内の任意のもの、が包含される。
本発明の重合方法は、任意の好適な方法、例えば、溶液、スラリー、高圧、及び気相を用いて行うことができる。本発明に係るポリオレフィンポリマーを製造する特に望ましい方法は、気相重合方法、好ましくは流動床反応器を用いるものである。このタイプの反応器及び反応器の操作手段は、周知であり、例えば、米国特許第3,709,853号、米国特許第4,003,712号、米国特許第4,011,382号、米国特許第4,302,566号、米国特許第4,51399号、米国特許第4,882,400号、米国特許第5,352,749号、米国特許第5,541,270号、ヨーロッパ特許公開第0802202号及びベルギー特許第839,380号の各明細書に完全に記載されている。これらの特許は、重合媒体が、気体状モノマー及び希釈剤の連続的な流れにより、機械的に撹拌又は流動化のいずれかに付される、気相重合方法を開示している。
(a)リサイクル流(エチレン及びα−オレフィンモノマーを含む)を反応器に導入する;
(b)担持型触媒系を導入する;
(c)反応器からリサイクル流を取り出す;
(d)リサイクル流を冷却する;
(e)追加のモノマーを反応器に導入して重合されたモノマーを置き換える;
(f)リサイクル流又はその一部を反応器に再導入する;及び
(g)反応器からポリマー生成物を取り出す;
を含む、連続的気相法である。
本発明のポリオレフィンは、添加剤とブレンドして、物品の製造にその後に使用できる組成物を形成しうる。それらの添加剤として、抗酸化剤、核化剤、酸捕捉剤、可塑剤、安定剤、腐食防止剤、膨張剤、連鎖遮断性抗酸化剤等の他のUV吸収剤、消光剤、帯電防止剤、滑剤、顔料、染料、及び充填剤、並びに過酸化物等の硬化剤が挙げられる。これら及びポリオレフィン産業で一般的な他の添加剤は、ポリオレフィン組成物中に、一つの例示的実施態様において0.01〜50重量%、他の例示的実施態様において0.1〜20重量%、そしてさらに他の例示的実施態様において1〜5重量%存在することができ、望ましい範囲は、任意の上限重量%と任意の下限重量%の任意の組合せを包含しうる。
担持型メタロセン触媒の調製
実施例1
撹拌バーを備えた125mlのガラスバイアル中に、トルエン20ml及び30重量%のメチルアルミノキサン(MAO)溶液6.64ml(1.85gMAO、6.40mmol/gシリカ)(Baton Rouge, LouisianaのAlbemarle Corporationから入手)を嫌気性条件下に加えた。撹拌しながら、トルエン2mlに溶解した二フッ化ビス(1,3−メチル−n−ブチルシクロペンタジエニル)ジルコニウムメタロセン0.082g(0.038mmol/gシリカ)をそのガラスバイアルに加えた。混合物を室温(25℃)で15分間撹拌した後、ES−757シリカ(600℃で脱水)(Warrington, UKのIneos Silicasから入手)5gを溶液に加えた。ES−757シリカは、以下の物性を示す。
物性 ES−757
表面積(M2/g) 316
細孔容積(cm3/g) 1.59
10番目の%μ 9
50番目の%μ 25
90番目の%μ 45
次いで、混合物を15分間撹拌し、その後、触媒を75℃で、固体が自由に流動するようになるまで乾燥した。
Claims (13)
- 反応器中で、
(a)エチレン及びC4〜C8α−オレフィンより成る群から選択される少なくとも一種のコモノマー;と、
(b)メチルアルミノキサンにより活性化されたメタロセン触媒化合物及び担体物質を含む担持型触媒であって、メチルアルミノキサンが担体物質1グラムあたり3〜9mmolの範囲で存在し、前記メタロセン触媒化合物は担体物質1グラムあたり0.01〜1.0mmolの範囲で存在するもの;
を接触させることを含むオレフィンの重合方法であって、触媒が、少なくとも2,500gポリエチレン/g触媒化合物・時間の活性を有し、且つ該方法が、少なくとも0.30g/cm3の嵩密度を有するポリマーを製造するものである方法。 - 担体物質が、シリカ、アルミナ、シリカ−アルミナ、塩化マグネシウム、グラファイト、及びそれらの混合物より成る群から選択される、請求項1の方法。
- メタロセン触媒化合物が、少なくとも1種のフッ化物又はフッ素含有脱離基を含む置換ビスシクロペンタジエニルジルコノセン触媒化合物である、請求項1又は2の方法。
- メチルアルミノキサンが、担体物質1グラムあたり4〜7.7mmolの範囲で存在する、先行請求項のいずれかの方法。
- メタロセン触媒化合物が、担体物質1グラムあたり0.04〜0.1mmolの範囲で存在する、先行請求項のいずれかの方法。
- 反応器が、2以下の範囲の汚れ指数を示す、先行請求項のいずれかの方法。
- 汚れ指数が1以下である、先行請求項のいずれかの方法。
- 汚れ指数が0である、先行請求項のいずれかの方法。
- 帯電防止剤が触媒組成物に存在しないか、実質的に存在しない、先行請求項のいずれかの方法。
- 帯電防止剤が、触媒組成物の4重量%未満の量で触媒組成物中に存在する、先行請求項のいずれかの方法。
- 担体物質が150〜450m2/gの範囲の表面積を有するものである、先行請求項のいずれかの方法。
- 担体物質が1〜2.5cm3/gの範囲の細孔容積を有するものである、先行請求項のいずれかの方法。
- 担体物質が10〜50μmの範囲の平均粒径を有するものである、先行請求項のいずれかの方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/730,525 US7244795B2 (en) | 2003-12-08 | 2003-12-08 | Polymerization process using metallocene catalyst systems |
PCT/US2004/033263 WO2005061557A1 (en) | 2003-12-08 | 2004-10-07 | Polymerization process using metallocene catalyst systems |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2007513238A true JP2007513238A (ja) | 2007-05-24 |
Family
ID=34634187
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2006542563A Pending JP2007513238A (ja) | 2003-12-08 | 2004-10-07 | メタロセン触媒系を用いる重合方法 |
Country Status (9)
Country | Link |
---|---|
US (2) | US7244795B2 (ja) |
EP (1) | EP1692190A4 (ja) |
JP (1) | JP2007513238A (ja) |
KR (1) | KR20070000404A (ja) |
CN (1) | CN1890268B (ja) |
BR (1) | BRPI0417151B1 (ja) |
CA (1) | CA2547190A1 (ja) |
RU (1) | RU2360930C2 (ja) |
WO (1) | WO2005061557A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011500937A (ja) * | 2007-10-22 | 2011-01-06 | ユニベーション・テクノロジーズ・エルエルシー | メタロセン触媒及び重合方法におけるそれらの使用 |
Families Citing this family (56)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7838708B2 (en) | 2001-06-20 | 2010-11-23 | Grt, Inc. | Hydrocarbon conversion process improvements |
US20050038310A1 (en) | 2003-07-15 | 2005-02-17 | Lorkovic Ivan M. | Hydrocarbon synthesis |
US20050171393A1 (en) | 2003-07-15 | 2005-08-04 | Lorkovic Ivan M. | Hydrocarbon synthesis |
US7244795B2 (en) * | 2003-12-08 | 2007-07-17 | Univation Technologies, Llc | Polymerization process using metallocene catalyst systems |
GB0401348D0 (en) * | 2004-01-22 | 2004-02-25 | Bp Chem Int Ltd | Polymerisation process |
US20080275284A1 (en) | 2004-04-16 | 2008-11-06 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
US7244867B2 (en) | 2004-04-16 | 2007-07-17 | Marathon Oil Company | Process for converting gaseous alkanes to liquid hydrocarbons |
US8642822B2 (en) | 2004-04-16 | 2014-02-04 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor |
US7674941B2 (en) | 2004-04-16 | 2010-03-09 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
US20060100469A1 (en) | 2004-04-16 | 2006-05-11 | Waycuilis John J | Process for converting gaseous alkanes to olefins and liquid hydrocarbons |
US8173851B2 (en) | 2004-04-16 | 2012-05-08 | Marathon Gtf Technology, Ltd. | Processes for converting gaseous alkanes to liquid hydrocarbons |
US7857977B2 (en) * | 2005-07-12 | 2010-12-28 | Rockwell Medical Technologies, Inc. | Packaging of ferric pyrophosphate for dialysis |
US7323526B2 (en) * | 2005-07-29 | 2008-01-29 | Univation Technologies, Llc | Supported metallocene-alkyl catalyst composition |
MY153701A (en) | 2006-02-03 | 2015-03-13 | Grt Inc | Separation of light gases from halogens |
NZ588129A (en) | 2006-02-03 | 2012-06-29 | Grt Inc | Continuous process for converting natural gas to liquid hydrocarbons |
JP5825755B2 (ja) * | 2006-05-30 | 2015-12-02 | アルベマール・コーポレーシヨン | シングルサイト触媒活性化剤、これらの製造方法、および触媒およびオレフィンの重合におけるこれらの使用 |
GB0610668D0 (en) * | 2006-05-30 | 2006-07-12 | Nova Chem Int Sa | Supported antistatic polymerization catalysts |
MX2009000270A (es) * | 2006-06-27 | 2009-02-17 | Univation Tech Llc | Copolimeros de etileno-alfa olefina y procesos de polimerizacion para hacerlos. |
CN101472964B (zh) * | 2006-06-27 | 2012-09-05 | 尤尼威蒂恩技术有限责任公司 | 使用茂金属催化剂的改进聚合方法、其聚合产物及最终用途 |
US7998438B2 (en) | 2007-05-24 | 2011-08-16 | Grt, Inc. | Zone reactor incorporating reversible hydrogen halide capture and release |
US8436114B2 (en) | 2010-10-21 | 2013-05-07 | Exxonmobil Chemical Patents Inc. | Polyethylene and process for production thereof |
US8431661B2 (en) | 2010-10-21 | 2013-04-30 | Exxonmobil Chemical Patents Inc. | Polyethylene and process for production thereof |
US8282810B2 (en) | 2008-06-13 | 2012-10-09 | Marathon Gtf Technology, Ltd. | Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery |
NZ591207A (en) | 2008-07-18 | 2013-03-28 | Grt Inc | Continuous process for converting natural gas to liquid hydrocarbons |
MY159256A (en) | 2010-02-18 | 2016-12-30 | Univation Tech Llc | Methods for operating a polymerization reactor |
US8198495B2 (en) | 2010-03-02 | 2012-06-12 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
US8367884B2 (en) | 2010-03-02 | 2013-02-05 | Marathon Gtf Technology, Ltd. | Processes and systems for the staged synthesis of alkyl bromides |
WO2011129956A1 (en) | 2010-04-13 | 2011-10-20 | Univation Technologies, Llc | Polymer blends and films made therefrom |
WO2012009215A1 (en) | 2010-07-16 | 2012-01-19 | Univation Technologies, Llc | Systems and methods for measuring static charge on particulates |
EP2593217B1 (en) | 2010-07-16 | 2014-07-02 | Univation Technologies, LLC | Systems and methods for measuring particle accumulation on reactor surfaces |
WO2012015898A1 (en) | 2010-07-28 | 2012-02-02 | Univation Technologies, Llc | Systems and methods for measuring velocity of a particle/fluid mixture |
WO2012096698A2 (en) * | 2010-10-21 | 2012-07-19 | Exxonmobil Chemical Patents Inc. | Polyethylene and process for production thereof |
EP2651982B1 (en) | 2010-12-17 | 2018-04-11 | Univation Technologies, LLC | Systems and methods for recovering hydrocarbons from a polyolefin purge gas product |
KR101824760B1 (ko) | 2011-01-14 | 2018-02-01 | 더블유.알. 그레이스 앤드 캄파니-콘. | 개질된 메탈로센 촉매 제조 방법, 제조된 촉매 및 이의 용도 |
US8815050B2 (en) | 2011-03-22 | 2014-08-26 | Marathon Gtf Technology, Ltd. | Processes and systems for drying liquid bromine |
US9243092B2 (en) | 2011-06-09 | 2016-01-26 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
US8436220B2 (en) | 2011-06-10 | 2013-05-07 | Marathon Gtf Technology, Ltd. | Processes and systems for demethanization of brominated hydrocarbons |
US8829256B2 (en) | 2011-06-30 | 2014-09-09 | Gtc Technology Us, Llc | Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons |
US8802908B2 (en) | 2011-10-21 | 2014-08-12 | Marathon Gtf Technology, Ltd. | Processes and systems for separate, parallel methane and higher alkanes' bromination |
US9193641B2 (en) | 2011-12-16 | 2015-11-24 | Gtc Technology Us, Llc | Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems |
CN108106968B (zh) | 2012-09-07 | 2020-09-25 | 尤尼威蒂恩技术有限责任公司 | 控制聚合反应器的*** |
CN104277279A (zh) * | 2013-07-04 | 2015-01-14 | 东港市远东节水灌溉设备有限公司 | 一种阻燃抗静电聚乙烯管材及其制作方法 |
US9023959B2 (en) | 2013-07-15 | 2015-05-05 | Chevron Phillips Chemical Company Lp | Methods for producing fluorided-chlorided silica-coated alumina activator-supports and catalyst systems containing the same |
US10329365B2 (en) | 2014-11-25 | 2019-06-25 | Univation Technologies, Llc | Methods of monitoring and controlling the melt index of a polyolefin product during production |
CN107001527B (zh) | 2014-11-25 | 2020-12-11 | 尤尼威蒂恩技术有限责任公司 | 改变聚烯烃生产条件以减轻聚烯烃物品中的小凝胶的方法 |
CA2967417C (en) | 2014-11-25 | 2023-09-12 | Univation Technologies, Llc | Methods of changing polyolefin production rate with the composition of the induced condensing agents |
EP3223939B1 (en) | 2014-11-25 | 2022-05-25 | Univation Technologies, LLC | Methods of controlling polyolefin melt index while increasing catalyst productivity |
WO2016164451A1 (en) | 2015-04-08 | 2016-10-13 | Univation Technologies, Llc | Closed reactor transitions between metallocene catalysts |
KR102433606B1 (ko) * | 2016-11-08 | 2022-08-22 | 유니베이션 테크놀로지즈, 엘엘씨 | 폴리에틸렌 조성물 |
RU2660907C1 (ru) * | 2018-02-19 | 2018-07-11 | Публичное акционерное общество "Нефтяная компания "Роснефть" (ПАО "НК "Роснефть") | Катализатор для получения синтетических высоковязких масел и способ его приготовления |
EP3941950A1 (en) | 2019-03-21 | 2022-01-26 | ExxonMobil Chemical Patents Inc. | Methods for improving production in gas phase polymerization |
CN113677713A (zh) | 2019-03-21 | 2021-11-19 | 埃克森美孚化学专利公司 | 改进气相聚合的方法 |
EP4007780A4 (en) | 2019-08-02 | 2022-09-14 | ExxonMobil Chemical Patents Inc. | METALLOCENES AND RELATED METHODS |
TWI797784B (zh) | 2020-10-22 | 2023-04-01 | 美商恩特葛瑞斯股份有限公司 | 環戊二烯的選擇性烷基化 |
WO2023096802A1 (en) | 2021-11-29 | 2023-06-01 | Entegris, Inc. | Monoalkyl cyclopentadiene compounds and processes for preparing same |
WO2023096782A1 (en) | 2021-11-29 | 2023-06-01 | Entegris, Inc. | Organometallic compounds and processes for preparing same |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH09309909A (ja) * | 1995-11-28 | 1997-12-02 | Union Carbide Chem & Plast Technol Corp | 向上された共単量体反応性を有する触媒組成物 |
JPH10114805A (ja) * | 1996-07-26 | 1998-05-06 | Daelim Ind Co Ltd | アンカー鎖によってキャリアと連結したメタロセンを有する触媒系 |
JP2000119314A (ja) * | 1998-10-19 | 2000-04-25 | Maruzen Petrochem Co Ltd | オレフィン重合用固体触媒およびこれを用いたオレフィン系重合体の製造方法 |
JP2002523530A (ja) * | 1998-08-21 | 2002-07-30 | ユニベーション・テクノロジーズ・エルエルシー | 改良された嵩高な配位子のメタロセン型触媒系を使用する重合方法 |
JP2003073414A (ja) * | 2001-09-03 | 2003-03-12 | Mitsui Chemicals Inc | オレフィン重合用固体触媒成分の製造方法およびこれを用いたオレフィンの重合方法 |
JP2005162838A (ja) * | 2003-12-01 | 2005-06-23 | Maruzen Petrochem Co Ltd | オレフィン重合用触媒及びそれを用いたオレフィンの重合方法 |
JP2007533786A (ja) * | 2003-06-18 | 2007-11-22 | ユニベーション・テクノロジーズ・エルエルシー | メタロセン触媒系を使用した重合方法 |
Family Cites Families (46)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3248179A (en) | 1962-02-26 | 1966-04-26 | Phillips Petroleum Co | Method and apparatus for the production of solid polymers of olefins |
US4271060A (en) | 1979-09-17 | 1981-06-02 | Phillips Petroleum Company | Solution polymerization process |
US4613484A (en) | 1984-11-30 | 1986-09-23 | Phillips Petroleum Company | Loop reactor settling leg system for separation of solid polymers and liquid diluent |
US5001205A (en) | 1988-06-16 | 1991-03-19 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst |
NZ235032A (en) | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
US5763547A (en) | 1992-10-02 | 1998-06-09 | The Dow Chemical Company | Supported catalyst complexes for olefin in polymerization |
US5026798A (en) | 1989-09-13 | 1991-06-25 | Exxon Chemical Patents Inc. | Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system |
FR2660926B1 (fr) | 1990-04-11 | 1992-07-31 | Bp Chemicals Snc | Prepolymere d'alpha-olefine contenant un metal de transition et procede de polymerisation d'alpha-olefine en phase gazeuse mettant en óoeuvre le prepolymere. |
US5236998A (en) | 1991-03-07 | 1993-08-17 | Occidental Chemical Corporation | Process for the manufacture of linear polyethylene containing α-alkene commonomers |
TW218884B (ja) | 1991-05-01 | 1994-01-11 | Mitsubishi Kakoki Kk | |
US5589555A (en) | 1991-10-03 | 1996-12-31 | Novacor Chemicals (International) S.A. | Control of a solution process for polymerization of ethylene |
US5667375A (en) * | 1993-08-16 | 1997-09-16 | Sebastiani; Enrico | Gas combustion apparatus and method for controlling the same |
US6245705B1 (en) | 1993-11-18 | 2001-06-12 | Univation Technologies | Cocatalysts for metallocene-based olefin polymerization catalyst systems |
US5595950A (en) | 1993-12-20 | 1997-01-21 | Exxon Chemical Patents, Inc. | Polymerization catalyst systems, their production and use |
US6533988B2 (en) * | 1995-05-02 | 2003-03-18 | Borealis Technology Oy | Rotational moulding process of ethylene polymers or copolymers having a controlled particle size and morphology |
US5677375A (en) | 1995-07-21 | 1997-10-14 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing an in situ polyethylene blend |
ES2154417T3 (es) | 1995-08-22 | 2001-04-01 | Basf Ag | Polimeros del etileno con una elevada resistencia a la fisuracion por tensiones y un sistema catalizador para su obtencion. |
JP3582181B2 (ja) | 1995-10-04 | 2004-10-27 | 住友化学工業株式会社 | オレフィン重合触媒用担体、オレフィン重合触媒及びオレフィン重合体の製造方法 |
US6486089B1 (en) | 1995-11-09 | 2002-11-26 | Exxonmobil Oil Corporation | Bimetallic catalyst for ethylene polymerization reactions with uniform component distribution |
US6090740A (en) * | 1996-02-08 | 2000-07-18 | Exxon Chemical Patents Inc. | Supported metallocene catalyst systems |
US5665818A (en) | 1996-03-05 | 1997-09-09 | Union Carbide Chemicals & Plastics Technology Corporation | High activity staged reactor process |
US6011127A (en) * | 1996-05-20 | 2000-01-04 | Showa Denko K.K. | Process for the production of ethylenic polymers |
KR20000022440A (ko) | 1996-07-04 | 2000-04-25 | 스타르크, 카르크 | 담지된 전이 금속 촉매의 제조 방법 |
US5847059A (en) * | 1996-12-20 | 1998-12-08 | Fina Technology, Inc. | Catalyst yield from supported metallocene catalysts |
US5747406A (en) | 1997-01-10 | 1998-05-05 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst composition for the production of olefin polymers |
US6048817A (en) | 1997-04-25 | 2000-04-11 | Mitsubishi Chemical Corporation | Polymerization of olefins |
EP0882740A1 (en) | 1997-06-06 | 1998-12-09 | Fina Research S.A. | Titanated chromium-based catalysts to produce polyethylene exhibiting better environmental stress crack resistance |
US6153551A (en) | 1997-07-14 | 2000-11-28 | Mobil Oil Corporation | Preparation of supported catalyst using trialkylaluminum-metallocene contact products |
DE69821528T2 (de) | 1997-12-08 | 2004-07-01 | Albemarle Corp. | Katalysatorzusammensetzungen mit gesteigertem leistungsvermögen |
US6069213A (en) | 1997-12-16 | 2000-05-30 | Union Carbide Chemicals & Plastics Technology Corporation | Mixed catalyst system |
US6015766A (en) | 1997-12-18 | 2000-01-18 | Mobil Oil Corporation | Catalyst systems for olefin polymerization based on metallocene complexes and oligoalkylaluminates with sterically hindered alkyl groups as cocatalysts |
US6300271B1 (en) | 1998-05-18 | 2001-10-09 | Phillips Petroleum Company | Compositions that can produce polymers |
US6165929A (en) | 1998-05-18 | 2000-12-26 | Phillips Petroleum Company | Compositions that can produce polymers |
US6107230A (en) | 1998-05-18 | 2000-08-22 | Phillips Petroleum Company | Compositions that can produce polymers |
EP0962469A1 (en) | 1998-06-05 | 1999-12-08 | Fina Research S.A. | Titanated chromium catalyst supported on silica-aluminophosphate |
US7354880B2 (en) | 1998-07-10 | 2008-04-08 | Univation Technologies, Llc | Catalyst composition and methods for its preparation and use in a polymerization process |
CA2338603C (en) * | 1998-08-26 | 2008-11-18 | Exxon Chemical Patents, Inc. | Highly active supported catalyst compositions |
KR100367463B1 (ko) * | 1999-03-03 | 2003-01-14 | 주식회사 엘지화학 | 메탈로센 화합물 및 이를 이용한 올레핀 중합 |
US6355594B1 (en) | 1999-09-27 | 2002-03-12 | Phillips Petroleum Company | Organometal catalyst compositions |
US6395666B1 (en) | 1999-09-29 | 2002-05-28 | Phillips Petroleum Company | Organometal catalyst compositions |
US6548441B1 (en) | 1999-10-27 | 2003-04-15 | Phillips Petroleum Company | Organometal catalyst compositions |
US6548442B1 (en) | 1999-12-03 | 2003-04-15 | Phillips Petroleum Company | Organometal compound catalyst |
US6583240B2 (en) | 2001-05-23 | 2003-06-24 | Equistar Chemicals, Lp | Ethylene polymerization process |
US6583242B2 (en) * | 2001-08-02 | 2003-06-24 | Equistar Chemicals, Lp | Supported olefin polymerization catalysts |
CN1137909C (zh) * | 2001-10-26 | 2004-02-11 | 中国科学院长春应用化学研究所 | 插层型负载茂金属催化剂及其催化烯烃聚合 |
US7244795B2 (en) | 2003-12-08 | 2007-07-17 | Univation Technologies, Llc | Polymerization process using metallocene catalyst systems |
-
2003
- 2003-12-08 US US10/730,525 patent/US7244795B2/en not_active Expired - Lifetime
-
2004
- 2004-10-07 KR KR1020067010579A patent/KR20070000404A/ko not_active Application Discontinuation
- 2004-10-07 CA CA002547190A patent/CA2547190A1/en not_active Abandoned
- 2004-10-07 BR BRPI0417151-9A patent/BRPI0417151B1/pt active IP Right Grant
- 2004-10-07 WO PCT/US2004/033263 patent/WO2005061557A1/en active Application Filing
- 2004-10-07 RU RU2006124404/04A patent/RU2360930C2/ru active
- 2004-10-07 JP JP2006542563A patent/JP2007513238A/ja active Pending
- 2004-10-07 CN CN200480036512.8A patent/CN1890268B/zh active Active
- 2004-10-07 EP EP04794576A patent/EP1692190A4/en not_active Ceased
-
2007
- 2007-01-31 US US11/700,620 patent/US7579415B2/en active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH09309909A (ja) * | 1995-11-28 | 1997-12-02 | Union Carbide Chem & Plast Technol Corp | 向上された共単量体反応性を有する触媒組成物 |
JPH10114805A (ja) * | 1996-07-26 | 1998-05-06 | Daelim Ind Co Ltd | アンカー鎖によってキャリアと連結したメタロセンを有する触媒系 |
JP2002523530A (ja) * | 1998-08-21 | 2002-07-30 | ユニベーション・テクノロジーズ・エルエルシー | 改良された嵩高な配位子のメタロセン型触媒系を使用する重合方法 |
JP2000119314A (ja) * | 1998-10-19 | 2000-04-25 | Maruzen Petrochem Co Ltd | オレフィン重合用固体触媒およびこれを用いたオレフィン系重合体の製造方法 |
JP2003073414A (ja) * | 2001-09-03 | 2003-03-12 | Mitsui Chemicals Inc | オレフィン重合用固体触媒成分の製造方法およびこれを用いたオレフィンの重合方法 |
JP2007533786A (ja) * | 2003-06-18 | 2007-11-22 | ユニベーション・テクノロジーズ・エルエルシー | メタロセン触媒系を使用した重合方法 |
JP2005162838A (ja) * | 2003-12-01 | 2005-06-23 | Maruzen Petrochem Co Ltd | オレフィン重合用触媒及びそれを用いたオレフィンの重合方法 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011500937A (ja) * | 2007-10-22 | 2011-01-06 | ユニベーション・テクノロジーズ・エルエルシー | メタロセン触媒及び重合方法におけるそれらの使用 |
Also Published As
Publication number | Publication date |
---|---|
US20070135599A1 (en) | 2007-06-14 |
RU2006124404A (ru) | 2008-01-27 |
CN1890268A (zh) | 2007-01-03 |
BRPI0417151B1 (pt) | 2014-12-02 |
CN1890268B (zh) | 2014-06-04 |
BRPI0417151A (pt) | 2007-03-06 |
US20050124487A1 (en) | 2005-06-09 |
EP1692190A4 (en) | 2010-03-17 |
EP1692190A1 (en) | 2006-08-23 |
US7244795B2 (en) | 2007-07-17 |
CA2547190A1 (en) | 2005-07-07 |
US7579415B2 (en) | 2009-08-25 |
RU2360930C2 (ru) | 2009-07-10 |
KR20070000404A (ko) | 2007-01-02 |
WO2005061557A1 (en) | 2005-07-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US7244795B2 (en) | Polymerization process using metallocene catalyst systems | |
US8067518B2 (en) | Polymers made with metallocene catalysts, for use in rotomolding and injection molding products | |
KR20060136374A (ko) | 메탈로센 촉매계를 이용하는 중합 방법 | |
JP4563401B2 (ja) | ハフノセン触媒ポリエチレンからの高引裂強度フィルム | |
JP4979703B2 (ja) | 粒度分布が改善された担体材料を含む触媒組成物 | |
RU2315776C2 (ru) | Способ получения бимодального полиолефина и пленок на его основе | |
US20070276106A1 (en) | Polymerization process using spray-dried catalyst | |
JP2005538214A (ja) | 気相重合法 | |
JP2006526667A (ja) | 2金属触媒、重合方法及びそれらからの2モードポリオレフィン | |
US20080194780A1 (en) | Ziegler-Type Catalysts Having Increased Productivity | |
JP4343231B2 (ja) | 重合方法及びポリマー組成物特性の調節 | |
WO2008045171A2 (en) | Supported olefin polymerization catalysts and their use in polymerization processes | |
EP2274341B1 (en) | Methods for preparing catalyst systems |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20070508 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20100113 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100119 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20100419 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20100426 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20100519 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20110426 |