IL97679A - Catalyst components and catalysts for the polymerization of olefins - Google Patents

Catalyst components and catalysts for the polymerization of olefins

Info

Publication number: IL97679A
Authority: IL; Israel
Prior art keywords: dimethoxypropane; ether; heteroatom; halogen; group
Prior art date: 1990-03-30

Application number

IL9767991A

Other languages

English (en)

Hebrew (he)

Other versions

IL97679A0 (en

Inventor

Enrico Albizzati

Giampiero Morini

Umberto Giannini

Luisa Barino

Raimondo Scordamaglia

Pier C Barbe

Luciano Noristi

Original Assignee

Himont Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-03-30

Filing date

1991-03-26

Publication date

1994-06-24

1991-03-26 Application filed by Himont Inc filed Critical Himont Inc

1992-06-21 Publication of IL97679A0 publication Critical patent/IL97679A0/xx

1994-06-24 Publication of IL97679A publication Critical patent/IL97679A/en

Links

239000003054 catalyst Substances 0.000 title claims abstract description 55
238000006116 polymerization reaction Methods 0.000 title claims abstract description 18
150000001336 alkenes Chemical class 0.000 title claims abstract description 16
-1 titanium halide Chemical class 0.000 claims abstract description 92
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 33
150000001875 compounds Chemical class 0.000 claims abstract description 32
239000011777 magnesium Substances 0.000 claims abstract description 23
125000005842 heteroatom Chemical group 0.000 claims abstract description 22
229910052749 magnesium Inorganic materials 0.000 claims abstract description 20
125000005843 halogen group Chemical group 0.000 claims abstract description 19
239000010936 titanium Substances 0.000 claims abstract description 12
229910052757 nitrogen Inorganic materials 0.000 claims abstract description 11
229910052698 phosphorus Inorganic materials 0.000 claims abstract description 11
239000011949 solid catalyst Substances 0.000 claims abstract description 10
229910052719 titanium Inorganic materials 0.000 claims abstract description 10
229910052710 silicon Inorganic materials 0.000 claims abstract description 9
229910052717 sulfur Inorganic materials 0.000 claims abstract description 9
125000001033 ether group Chemical group 0.000 claims abstract description 3
125000004432 carbon atom Chemical group C* 0.000 claims description 24
239000004215 Carbon black (E152) Substances 0.000 claims description 16
229930195733 hydrocarbon Natural products 0.000 claims description 16
229910052736 halogen Inorganic materials 0.000 claims description 10
239000007787 solid Substances 0.000 claims description 10
229910052799 carbon Inorganic materials 0.000 claims description 9
229910052739 hydrogen Inorganic materials 0.000 claims description 8
239000001257 hydrogen Substances 0.000 claims description 8
238000000605 extraction Methods 0.000 claims description 6
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
150000002367 halogens Chemical class 0.000 claims description 5
125000001183 hydrocarbyl group Chemical group 0.000 claims description 4
125000004122 cyclic group Chemical group 0.000 claims description 3
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
239000007795 chemical reaction product Substances 0.000 claims 1
XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims 1
238000006243 chemical reaction Methods 0.000 abstract description 16
150000002170 ethers Chemical class 0.000 abstract description 13
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 19
229910003074 TiCl4 Inorganic materials 0.000 description 18
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 12
238000000034 method Methods 0.000 description 12
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 12
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 10
238000002360 preparation method Methods 0.000 description 10
229920000642 polymer Polymers 0.000 description 8
150000002430 hydrocarbons Chemical class 0.000 description 6
229910001629 magnesium chloride Inorganic materials 0.000 description 6
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 6
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 6
230000000707 stereoselective effect Effects 0.000 description 6
229920005989 resin Polymers 0.000 description 5
239000011347 resin Substances 0.000 description 5
150000003609 titanium compounds Chemical class 0.000 description 5
UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
238000001228 spectrum Methods 0.000 description 4
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
125000000217 alkyl group Chemical group 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
150000002148 esters Chemical class 0.000 description 3
238000001914 filtration Methods 0.000 description 3
125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
239000000203 mixture Substances 0.000 description 3
239000000178 monomer Substances 0.000 description 3
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
239000002904 solvent Substances 0.000 description 3
SPEUIVXLLWOEMJ-UHFFFAOYSA-N 1,1-dimethoxyethane Chemical compound COC(C)OC SPEUIVXLLWOEMJ-UHFFFAOYSA-N 0.000 description 2
BHDSGQOSIWVMJW-UHFFFAOYSA-N 1-(2-chloroethoxy)propane Chemical compound CCCOCCCl BHDSGQOSIWVMJW-UHFFFAOYSA-N 0.000 description 2
RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical group CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 2
UXLFNMJTGIDIMV-UHFFFAOYSA-N 4-(methoxymethyl)bicyclo[2.2.1]hept-2-ene Chemical compound C1CC2C=CC1(COC)C2 UXLFNMJTGIDIMV-UHFFFAOYSA-N 0.000 description 2
IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
238000002083 X-ray spectrum Methods 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 description 2
MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
230000000694 effects Effects 0.000 description 2
239000000706 filtrate Substances 0.000 description 2
239000007789 gas Substances 0.000 description 2
150000004820 halides Chemical class 0.000 description 2
229910052809 inorganic oxide Inorganic materials 0.000 description 2
ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
239000007788 liquid Substances 0.000 description 2
239000012071 phase Substances 0.000 description 2
150000003021 phthalic acid derivatives Chemical class 0.000 description 2
150000003377 silicon compounds Chemical class 0.000 description 2
239000012265 solid product Substances 0.000 description 2
RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 2
239000004711 α-olefin Substances 0.000 description 2
DTWTUTRXBBRMHX-UHFFFAOYSA-N 1,1,1-trifluoro-2,2-bis(methoxymethyl)-4-methylpentane Chemical compound COCC(COC)(CC(C)C)C(F)(F)F DTWTUTRXBBRMHX-UHFFFAOYSA-N 0.000 description 1
CHRJZRDFSQHIFI-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;styrene Chemical compound C=CC1=CC=CC=C1.C=CC1=CC=CC=C1C=C CHRJZRDFSQHIFI-UHFFFAOYSA-N 0.000 description 1
REFOELNRCDIIOU-UHFFFAOYSA-N 1-[1-methoxy-2-(methoxymethyl)pentan-2-yl]piperidine Chemical compound CCCC(COC)(COC)N1CCCCC1 REFOELNRCDIIOU-UHFFFAOYSA-N 0.000 description 1
OMCKZNLSJMZESR-UHFFFAOYSA-N 1-chloro-4-(2,4-dimethoxybutyl)cyclohexane Chemical compound COCCC(CC1CCC(CC1)Cl)OC OMCKZNLSJMZESR-UHFFFAOYSA-N 0.000 description 1
XOUXKPPTFKREBE-UHFFFAOYSA-N 1-chloro-4-(2-chloro-1,3-dimethoxypropan-2-yl)benzene Chemical compound COCC(Cl)(COC)C1=CC=C(Cl)C=C1 XOUXKPPTFKREBE-UHFFFAOYSA-N 0.000 description 1
BYVFFSDRJHHMNT-UHFFFAOYSA-N 1-chloro-4-(2-chloro-1,3-dimethoxypropan-2-yl)cyclohexane Chemical compound COCC(Cl)(COC)C1CCC(Cl)CC1 BYVFFSDRJHHMNT-UHFFFAOYSA-N 0.000 description 1
RJRGWSCSXNMGGT-UHFFFAOYSA-N 1-chloro-4-(methoxymethyl)-1,2,3,4,4a,5,6,7,8,8a-decahydronaphthalene Chemical compound COCC1CCC(C2CCCCC12)Cl RJRGWSCSXNMGGT-UHFFFAOYSA-N 0.000 description 1
WYZNBPDYRFRINI-UHFFFAOYSA-N 1-chloro-4-[2-(4-chlorocyclohexyl)-1,3-dimethoxypropan-2-yl]cyclohexane Chemical compound C1CC(Cl)CCC1C(COC)(COC)C1CCC(Cl)CC1 WYZNBPDYRFRINI-UHFFFAOYSA-N 0.000 description 1
RNMJNXYUKDUSNQ-UHFFFAOYSA-N 1-chloro-7,7-bis(methoxymethyl)-2,2,8-trimethylnon-4-ene Chemical compound COCC(COC)(C(C)C)CC=CCC(C)(C)CCl RNMJNXYUKDUSNQ-UHFFFAOYSA-N 0.000 description 1
FMRWQLAJBBKXDM-UHFFFAOYSA-N 2,2,5,5-tetramethylpyrrolidine Chemical group CC1(C)CCC(C)(C)N1 FMRWQLAJBBKXDM-UHFFFAOYSA-N 0.000 description 1
LTMRRSWNXVJMBA-UHFFFAOYSA-L 2,2-diethylpropanedioate Chemical compound CCC(CC)(C([O-])=O)C([O-])=O LTMRRSWNXVJMBA-UHFFFAOYSA-L 0.000 description 1
OKYYDLKNVBEQRG-UHFFFAOYSA-N 2,3-dichloro-1-methoxy-2-(methoxymethyl)-4,4-dimethylpentane Chemical compound COCC(Cl)(COC)C(Cl)C(C)(C)C OKYYDLKNVBEQRG-UHFFFAOYSA-N 0.000 description 1
NPTOAUGGHFJJKI-UHFFFAOYSA-N 2-chloro-1,1,1-trifluoro-3-methoxy-2-(methoxymethyl)propane Chemical compound COCC(Cl)(C(F)(F)F)COC NPTOAUGGHFJJKI-UHFFFAOYSA-N 0.000 description 1
HDYCVVOFBRKURF-UHFFFAOYSA-N 2-chloro-1-(2-chloroethoxy)-2-(2-chloroethoxymethyl)pentane Chemical compound ClCCOCC(Cl)(CCC)COCCCl HDYCVVOFBRKURF-UHFFFAOYSA-N 0.000 description 1
FKTBPXRDGNRGGU-UHFFFAOYSA-N 2-chloro-1-(2-chloroethoxy)-2-(methoxymethyl)butane Chemical compound COCC(Cl)(CC)COCCCl FKTBPXRDGNRGGU-UHFFFAOYSA-N 0.000 description 1
WPEWLQUBIZNQOZ-UHFFFAOYSA-N 2-chloro-1-(2-chloroethoxy)-2-(methoxymethyl)pentane Chemical compound CCCC(Cl)(COC)COCCCl WPEWLQUBIZNQOZ-UHFFFAOYSA-N 0.000 description 1
PBIJVUVDJZHLFX-UHFFFAOYSA-N 2-chloro-4,4-bis(methoxymethyl)heptane Chemical compound CCCC(COC)(COC)CC(C)Cl PBIJVUVDJZHLFX-UHFFFAOYSA-N 0.000 description 1
FCAZHKLWGAPKHF-UHFFFAOYSA-N 2-ethylsulfonyl-1-methoxy-2-(methoxymethyl)-3-methylbutane Chemical compound CCS(=O)(=O)C(COC)(COC)C(C)C FCAZHKLWGAPKHF-UHFFFAOYSA-N 0.000 description 1
IPWZXDDVIQBHDA-UHFFFAOYSA-N 2-tert-butylsulfanyl-1-methoxy-2-(methoxymethyl)butane Chemical compound COCC(CC)(COC)SC(C)(C)C IPWZXDDVIQBHDA-UHFFFAOYSA-N 0.000 description 1
CYMXBMPSMSIOHX-UHFFFAOYSA-N 3-chloro-1-(methoxymethyl)bicyclo[2.2.1]heptane Chemical compound COCC12CCC(C(C1)Cl)C2 CYMXBMPSMSIOHX-UHFFFAOYSA-N 0.000 description 1
VLRGXXKFHVJQOL-UHFFFAOYSA-N 3-chloropentane-2,4-dione Chemical compound CC(=O)C(Cl)C(C)=O VLRGXXKFHVJQOL-UHFFFAOYSA-N 0.000 description 1
ILKDFBLABKGPRX-UHFFFAOYSA-N 4-(3-cyclohex-3-en-1-yl-1,4-dimethoxybutan-2-yl)cyclohexene Chemical compound C1CC=CCC1C(COC)C(COC)C1CCC=CC1 ILKDFBLABKGPRX-UHFFFAOYSA-N 0.000 description 1
JWDRNBDNASWFTB-UHFFFAOYSA-N 4-[2-(cyclohex-3-en-1-ylmethyl)-3-methoxy-2-(methoxymethyl)propyl]cyclohexene Chemical compound C1CC=CCC1CC(COC)(COC)CC1CCC=CC1 JWDRNBDNASWFTB-UHFFFAOYSA-N 0.000 description 1
VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 1
MZYLSMLTQSIOGI-UHFFFAOYSA-N 4-chloro-2-(methoxymethyl)-1-propan-2-ylcyclohexane Chemical compound CC(C)C1CCC(CC1COC)Cl MZYLSMLTQSIOGI-UHFFFAOYSA-N 0.000 description 1
CTTCFVZEPXFEIY-UHFFFAOYSA-N 5,5-bis(methoxymethyl)-3,7-dimethyloct-2-ene Chemical compound COCC(COC)(CC(C)C)CC(C)=CC CTTCFVZEPXFEIY-UHFFFAOYSA-N 0.000 description 1
FFNHGJOLHSXVPU-UHFFFAOYSA-N 5,5-bis(methoxymethyl)-6-methyl-n,n-bis(2-methylpropyl)hept-2-en-1-amine Chemical compound COCC(COC)(C(C)C)CC=CCN(CC(C)C)CC(C)C FFNHGJOLHSXVPU-UHFFFAOYSA-N 0.000 description 1
FJNORHVWZOSHSE-UHFFFAOYSA-N 5-[1-methoxy-2-(methoxymethyl)-3-methylbutan-2-yl]bicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C(COC)(C(C)C)COC)CC1C=C2 FJNORHVWZOSHSE-UHFFFAOYSA-N 0.000 description 1
SMWOHIVBVYXSTD-UHFFFAOYSA-N 6,6-bis(methoxymethyl)-3,8-dimethylnon-3-ene Chemical compound CCC(C)=CCC(COC)(COC)CC(C)C SMWOHIVBVYXSTD-UHFFFAOYSA-N 0.000 description 1
DFWQUIAJLPLXEH-UHFFFAOYSA-N 6-chloro-1-(methoxymethyl)-1,2,3,4-tetrahydronaphthalene Chemical compound ClC1=CC=C2C(COC)CCCC2=C1 DFWQUIAJLPLXEH-UHFFFAOYSA-N 0.000 description 1
DKMROQRQHGEIOW-UHFFFAOYSA-N Diethyl succinate Chemical compound CCOC(=O)CCC(=O)OCC DKMROQRQHGEIOW-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical class OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
238000002441 X-ray diffraction Methods 0.000 description 1
KSCPOLMSSJBNEC-UHFFFAOYSA-N [1-butoxy-2-(butoxymethyl)pentan-2-yl]oxy-trimethylsilane Chemical compound CCCCOCC(CCC)(O[Si](C)(C)C)COCCCC KSCPOLMSSJBNEC-UHFFFAOYSA-N 0.000 description 1
UNHYSYXXWUMXMV-UHFFFAOYSA-N [1-methoxy-2-(methoxymethyl)pentan-2-yl] 2,2-dimethylpropanoate Chemical compound CCCC(COC)(COC)OC(=O)C(C)(C)C UNHYSYXXWUMXMV-UHFFFAOYSA-N 0.000 description 1
QCWIXJBVWUHWFY-UHFFFAOYSA-N [1-methoxy-2-(methoxymethyl)pentan-2-yl] benzoate Chemical compound CCCC(COC)(COC)OC(=O)C1=CC=CC=C1 QCWIXJBVWUHWFY-UHFFFAOYSA-N 0.000 description 1
XMPMICXLFQZGAS-UHFFFAOYSA-N [2,2-bis(methoxymethyl)-3-trimethylsilylpropyl]-trimethylsilane Chemical compound COCC(COC)(C[Si](C)(C)C)C[Si](C)(C)C XMPMICXLFQZGAS-UHFFFAOYSA-N 0.000 description 1
CWBHBUILGHXVCU-UHFFFAOYSA-N [2-chloro-1-(2-chloroethoxy)-3-methoxypropan-2-yl]benzene Chemical compound ClCCOCC(Cl)(COC)C1=CC=CC=C1 CWBHBUILGHXVCU-UHFFFAOYSA-N 0.000 description 1
VJGPAPFCEZGWDR-UHFFFAOYSA-N [4-[2-(4-diphenylphosphanylphenyl)-1,3-dimethoxypropan-2-yl]phenyl]-diphenylphosphane Chemical compound C=1C=C(P(C=2C=CC=CC=2)C=2C=CC=CC=2)C=CC=1C(COC)(COC)C(C=C1)=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 VJGPAPFCEZGWDR-UHFFFAOYSA-N 0.000 description 1
REDBPKFBXLDWAM-UHFFFAOYSA-N [4-[2-[4-(2,2-dimethylpropanoyloxy)phenyl]-1,3-dimethoxypropan-2-yl]phenyl] 2,2-dimethylpropanoate Chemical compound C=1C=C(OC(=O)C(C)(C)C)C=CC=1C(COC)(COC)C1=CC=C(OC(=O)C(C)(C)C)C=C1 REDBPKFBXLDWAM-UHFFFAOYSA-N 0.000 description 1
AQUOBFFOTBPJLL-UHFFFAOYSA-N [4-methoxy-3-(methoxymethyl)butyl]-trimethylsilane Chemical compound COCC(COC)CC[Si](C)(C)C AQUOBFFOTBPJLL-UHFFFAOYSA-N 0.000 description 1
CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical group [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 description 1
238000013019 agitation Methods 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
150000001350 alkyl halides Chemical class 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
150000005840 aryl radicals Chemical class 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
UXXXZMDJQLPQPH-UHFFFAOYSA-N bis(2-methylpropyl) carbonate Chemical compound CC(C)COC(=O)OCC(C)C UXXXZMDJQLPQPH-UHFFFAOYSA-N 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
230000000536 complexating effect Effects 0.000 description 1
125000000753 cycloalkyl group Chemical group 0.000 description 1
150000001993 dienes Chemical class 0.000 description 1
ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 1
DWNAQMUDCDVSLT-UHFFFAOYSA-N diphenyl phthalate Chemical compound C=1C=CC=C(C(=O)OC=2C=CC=CC=2)C=1C(=O)OC1=CC=CC=C1 DWNAQMUDCDVSLT-UHFFFAOYSA-N 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
YCNSGSUGQPDYTK-UHFFFAOYSA-N ethyl phenyl carbonate Chemical compound CCOC(=O)OC1=CC=CC=C1 YCNSGSUGQPDYTK-UHFFFAOYSA-N 0.000 description 1
125000001475 halogen functional group Chemical group 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
150000002596 lactones Chemical class 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
150000002681 magnesium compounds Chemical class 0.000 description 1
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
NDMWNXVHZWMKJC-UHFFFAOYSA-N methyl 1-methoxy-2-(methoxymethyl)butane-2-sulfonate Chemical compound COCC(CC)(COC)S(=O)(=O)OC NDMWNXVHZWMKJC-UHFFFAOYSA-N 0.000 description 1
125000004433 nitrogen atom Chemical group N* 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
239000002245 particle Substances 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
125000005498 phthalate group Chemical class 0.000 description 1
238000003918 potentiometric titration Methods 0.000 description 1
239000000047 product Substances 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
239000005049 silicon tetrachloride Substances 0.000 description 1
APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
239000012798 spherical particle Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
150000003900 succinic acid esters Chemical class 0.000 description 1
125000004434 sulfur atom Chemical group 0.000 description 1
239000000725 suspension Substances 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/10—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of alkaline earth metals, zinc, cadmium, mercury, copper or silver
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

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Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

IL9767991A 1990-03-30 1991-03-26 Catalyst components and catalysts for the polymerization of olefins IL97679A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
IT19891A IT1241093B (it)	1990-03-30	1990-03-30	Componenti e catalizzatori per la polimerizzazione di olefine

Publications (2)

Publication Number	Publication Date
IL97679A0 IL97679A0 (en)	1992-06-21
IL97679A true IL97679A (en)	1994-06-24

Family

ID=11162104

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IL9767991A IL97679A (en)	1990-03-30	1991-03-26	Catalyst components and catalysts for the polymerization of olefins

Country Status (24)

Country	Link
US (1)	US5068213A (fi)
EP (2)	EP0891988B1 (fi)
JP (1)	JP3307658B2 (fi)
KR (1)	KR0169489B1 (fi)
CN (1)	CN1019580B (fi)
AT (1)	ATE179996T1 (fi)
AU (1)	AU633712B2 (fi)
BR (1)	BR9101279A (fi)
CA (1)	CA2039443A1 (fi)
CS (1)	CS87891A2 (fi)
DE (2)	DE69133274T2 (fi)
DK (1)	DK0451645T3 (fi)
ES (2)	ES2132075T3 (fi)
FI (1)	FI106382B (fi)
HU (1)	HUT57800A (fi)
IL (1)	IL97679A (fi)
IT (1)	IT1241093B (fi)
NO (1)	NO178153C (fi)
PH (1)	PH27575A (fi)
PT (1)	PT97208A (fi)
RU (1)	RU2087485C1 (fi)
TW (1)	TW198043B (fi)
YU (1)	YU56391A (fi)
ZA (1)	ZA912288B (fi)

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EP0452156B1 (en) *	1990-04-13	1997-08-13	Mitsui Petrochemical Industries, Ltd.	Solid titanium catalyst component for olefin polymerization, olefin polymerization catalyst, prepolymerized polyolefin-containing catalyst and method of olefin polymerization
US5726262A (en) *	1990-04-13	1998-03-10	Mitsui Petrochemical Industries, Ltd.	Solid titanium catalyst component for olefin polymerization, olefin polymerization catalyst, prepolymerized polyolefin-containing catalyst and method of olefin polymerization
IT1246614B (it)	1991-06-03	1994-11-24	Himont Inc	Procedimento per la polimerizzazione in fase gas delle olefine
IT1255523B (it) *	1992-09-24	1995-11-09	Himont Inc	Componenti e catalizzatori per la polimerizzazione di olefine
TW354792B (en) *	1993-08-13	1999-03-21	Mitsui Petrochemical Ind	Olefin polymerization catalyst and process for preparing polypropylene and propylene block copolymer
IT1270842B (it) *	1993-10-01	1997-05-13	Himont Inc	Componenti e catalizzatori per la polimerizzazione di olefine
KR0162685B1 (ko) *	1994-02-18	1999-01-15	고다 시게노리	에틸렌 중합체와 그 제조방법
FI96214C (fi) *	1994-05-31	1996-05-27	Borealis As	Olefiinien polymerointiin tarkoitettu stereospesifinen katalyyttisysteemi
IT1270125B (it) *	1994-10-05	1997-04-28	Spherilene Srl	Processo per la ( co) polimerizzazione di olefine
US7049377B1 (en) *	1995-02-21	2006-05-23	Basell Poliolefine Italia S.R.L.	1,3-diethers and components and catalysts for the polymerization of olefins, containing said diethers
IL117114A (en) *	1995-02-21	2000-02-17	Montell North America Inc	Components and catalysts for the polymerization ofolefins
IT1274253B (it) *	1995-02-21	1997-07-15	Himont Inc	Processo per la preparazione di componenti catalitici solidi per la polimerizzazione di olefine
IT1274469B (it)	1995-05-11	1997-07-17	Spherilene Spa	Composizioni poliolefiniche vulcanizzabili dinamicamente
US5747407A (en) *	1996-08-29	1998-05-05	Phillips Petroleum Company	Method of making a Ziegler-Natta olefin polymerization catalyst
KR20000068886A (ko) *	1997-09-03	2000-11-25	간디 지오프레이 에이치.	올레핀 중합용 성분 및 촉매
ES2198098T3 (es)	1998-03-09	2004-01-16	Basell Poliolefine Italia S.P.A.	Procedimiento multietapas para la polimerizacion de olefinas.
ES2208301T3 (es)	1999-03-09	2004-06-16	Basell Polyolefine Gmbh	Procedimiento multietapa para la (co)polimerizacion de olefinas.
US6436864B1 (en)	1999-10-06	2002-08-20	Sri International	Unsaturated nitrogenous compounds as electron donors for use with ziegler-natta catalysts
CN1367184A (zh) *	2001-01-12	2002-09-04	弗纳技术股份有限公司	生产超高熔体流动聚丙烯树脂的方法
US7365137B2 (en)	2001-07-17	2008-04-29	Basell Polyolefine Gmbh	Multistep process for the (co) polymerization of olefins
AU2002349445A1 (en)	2001-11-21	2003-06-10	Daishinku Corporation	Optical filter, production method for this optical filter and optical device using this optical filter and housing structure for this optical filter
US7700690B2 (en)	2002-06-26	2010-04-20	Basell Poliolefine Italia S.R.L.	Impact-resistant polyolefin compositions
BR0305248A (pt)	2002-06-26	2004-09-21	Basell Poliolefine Spa	Composições de poliolefinas resistentes ao impacto
AU2004287638A1 (en)	2003-11-06	2005-05-19	Basell Poliolefine Italia S.R.L.	Polypropylene composition
US20070260099A1 (en) *	2004-02-16	2007-11-08	Sumit Bhaduri	Catalytic System for Polymerisation of Lower Alpha Alkene
US8039540B2 (en)	2004-06-08	2011-10-18	Basell Poliolefine Italia S.R.L.	Polyolefin composition having a high balance of stiffness, impact strength and elongation at break and low thermal shrinkage
CN100389133C (zh) *	2004-10-29	2008-05-21	中国石油化工股份有限公司	一种用于烯烃聚合的催化剂及其应用
CN101153062B (zh) *	2006-09-29	2010-09-22	中国石油化工股份有限公司	一种烯烃聚合固体催化剂组分及制备方法与应用
CN101688004B (zh)	2007-06-29	2013-11-20	巴塞尔聚烯烃意大利有限责任公司	含非酚稳定剂的受辐射聚合物组合物
EP2247424B1 (en)	2008-02-29	2012-07-04	Basell Poliolefine Italia S.r.l.	Polyolefin compositions
US7935740B2 (en)	2008-12-30	2011-05-03	Basell Poliolefine Italia S.R.L.	Process for producing high melt strength polypropylene

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Publication number	Priority date	Publication date	Assignee	Title
BE588131A (fi) *	1958-09-17
DE1445225B2 (de) *	1960-09-24	1971-11-18	Badische Anilin & Soda Fabrik AG, 6700 Ludwigshafen	Verfahren zur polymerisation von monoalpha olefinen mit drei oder mehr kohlenstoffatomen
US4098976A (en) *	1971-07-13	1978-07-04	Imperial Chemical Industries Limited	Process for the production of olefin polymers using an organo-phosphorus catalyst compound
US4397763A (en) *	1977-12-13	1983-08-09	Phillips Petroleum Company	Catalyst and process of polymerization of alpha-monoolefins
GB2097411B (en) *	1981-04-23	1985-07-03	Showa Denko Kk	Catalyst for ethylene polymerisation
IT1190683B (it) *	1982-02-12	1988-02-24	Montedison Spa	Componenti e catalizzatori per la polimerizzazione di olefine
DE3247919A1 (de) *	1982-12-24	1984-06-28	Basf Ag, 6700 Ludwigshafen	Verfahren zum herstellen von homo- und copolymerisaten von (alpha)-monoolefinen mittels einer ziegler-natta-katalysatorsystems
JPS60130607A (ja) *	1983-12-19	1985-07-12	Mitsubishi Petrochem Co Ltd	α−オレフイン重合用触媒成分の製造法
US4701505A (en) *	1984-09-26	1987-10-20	Mitsubishi Petrochemical Company Limited	Process for production of olefin polymers
IT1227259B (it) *	1988-09-30	1991-03-28	Himont Inc	Catalizzatori per la polimerizzazione di olefine.
IT1227258B (it) *	1988-09-30	1991-03-28	Himont Inc	Componenti e catalizzatori per la polimerizzazione di olefine
EP0452156B1 (en) *	1990-04-13	1997-08-13	Mitsui Petrochemical Industries, Ltd.	Solid titanium catalyst component for olefin polymerization, olefin polymerization catalyst, prepolymerized polyolefin-containing catalyst and method of olefin polymerization

1990
- 1990-03-30 IT IT19891A patent/IT1241093B/it active IP Right Grant
1991
- 1991-03-26 US US07/675,234 patent/US5068213A/en not_active Expired - Lifetime
- 1991-03-26 ZA ZA912288A patent/ZA912288B/xx unknown
- 1991-03-26 NO NO911238A patent/NO178153C/no not_active IP Right Cessation
- 1991-03-26 IL IL9767991A patent/IL97679A/en not_active IP Right Cessation
- 1991-03-27 FI FI911507A patent/FI106382B/fi active
- 1991-03-27 PH PH42220A patent/PH27575A/en unknown
- 1991-03-27 AU AU73860/91A patent/AU633712B2/en not_active Ceased
- 1991-03-28 CA CA002039443A patent/CA2039443A1/en not_active Abandoned
- 1991-03-28 DE DE69133274T patent/DE69133274T2/de not_active Expired - Fee Related
- 1991-03-28 ES ES91105043T patent/ES2132075T3/es not_active Expired - Lifetime
- 1991-03-28 AT AT91105043T patent/ATE179996T1/de active
- 1991-03-28 EP EP98119781A patent/EP0891988B1/en not_active Expired - Lifetime
- 1991-03-28 PT PT97208A patent/PT97208A/pt not_active Application Discontinuation
- 1991-03-28 CN CN91102627A patent/CN1019580B/zh not_active Expired
- 1991-03-28 EP EP91105043A patent/EP0451645B1/en not_active Expired - Lifetime
- 1991-03-28 DE DE69131219T patent/DE69131219T2/de not_active Expired - Fee Related
- 1991-03-28 YU YU56391A patent/YU56391A/sh unknown
- 1991-03-28 DK DK91105043T patent/DK0451645T3/da active
- 1991-03-28 ES ES98119781T patent/ES2200252T3/es not_active Expired - Lifetime
- 1991-03-29 RU SU914895116A patent/RU2087485C1/ru active
- 1991-03-29 CS CS91878A patent/CS87891A2/cs unknown
- 1991-03-29 HU HU911057A patent/HUT57800A/hu unknown
- 1991-03-30 KR KR1019910005149A patent/KR0169489B1/ko not_active IP Right Cessation
- 1991-03-30 JP JP09326391A patent/JP3307658B2/ja not_active Expired - Fee Related
- 1991-04-01 BR BR919101279A patent/BR9101279A/pt not_active IP Right Cessation
- 1991-04-25 TW TW080102405A patent/TW198043B/zh active

Also Published As

Publication number	Publication date
NO911238D0 (no)	1991-03-26
IT9019891A1 (it)	1991-09-30
IT9019891A0 (it)	1990-03-30
PH27575A (en)	1993-08-18
ZA912288B (en)	1992-11-25
CN1019580B (zh)	1992-12-23
FI106382B (fi)	2001-01-31
ES2132075T3 (es)	1999-08-16
EP0891988A3 (en)	2000-05-17
DE69133274T2 (de)	2004-05-13
PT97208A (pt)	1992-01-31
EP0451645B1 (en)	1999-05-12
NO911238L (no)	1991-10-01
TW198043B (fi)	1993-01-11
DE69131219D1 (de)	1999-06-17
FI911507A (fi)	1991-10-01
EP0891988A2 (en)	1999-01-20
JP3307658B2 (ja)	2002-07-24
AU7386091A (en)	1991-10-03
CS87891A2 (en)	1991-11-12
NO178153C (no)	1996-01-31
CN1055933A (zh)	1991-11-06
ATE179996T1 (de)	1999-05-15
ES2200252T3 (es)	2004-03-01
DK0451645T3 (da)	1999-11-01
DE69133274D1 (de)	2003-07-10
IL97679A0 (en)	1992-06-21
AU633712B2 (en)	1993-02-04
US5068213A (en)	1991-11-26
KR0169489B1 (ko)	1999-03-20
YU56391A (sh)	1994-05-10
RU2087485C1 (ru)	1997-08-20
EP0891988B1 (en)	2003-06-04
IT1241093B (it)	1993-12-29
BR9101279A (pt)	1991-11-05
EP0451645A2 (en)	1991-10-16
HU911057D0 (en)	1991-10-28
NO178153B (no)	1995-10-23
CA2039443A1 (en)	1991-10-01
HUT57800A (en)	1991-12-30
DE69131219T2 (de)	1999-11-04
EP0451645A3 (en)	1992-09-02
JPH0687921A (ja)	1994-03-29
FI911507A0 (fi)	1991-03-27
KR910016778A (ko)	1991-11-05

Legal Events

Date	Code	Title
1997-07-13	KB	Patent renewed
1997-11-20	HC	Change of name of proprietor(s)
2001-06-14	KB	Patent renewed
2006-01-15	MM9K	Patent not in force due to non-payment of renewal fees

Publication	Publication Date	Title
EP0451645B1 (en)	1999-05-12	Components and catalysts for the polymerization of olefins
EP0362705B1 (en)	1995-01-11	Catalysts for the polymerization of olefins
US4971937A (en)	1990-11-20	Components and catalysts for the polymerization of olefins
KR100572935B1 (ko)	2006-09-07	프로필렌을 중합하기 위한 폴리올레핀 촉매 및이들의 제조 및사용방법.
US5106807A (en)	1992-04-21	Components and catalysts for the polymerization of olefins
KR20030029821A (ko)	2003-04-16	올레핀 (공)중합용 성분 및 촉매
KR20000068056A (ko)	2000-11-25	올레핀 중합용 성분 및 촉매
EP0410443B1 (en)	1995-01-11	Organosilane compounds
US20070197381A1 (en)	2007-08-23	Preparation of a magnesium halide support for olefin polymerization and a catalyst composition using the same
WO2005123784A2 (en)	2005-12-29	Components and catalysts for the polymerization of olefins
US9777084B2 (en)	2017-10-03	Catalyst system for olefin polymerization and method for producing olefin polymer
US10124324B1 (en)	2018-11-13	Olefin polymerization catalyst components and process for the production of olefin polymers therewith
US10822438B2 (en)	2020-11-03	Catalyst system for enhanced stereo-specificity of olefin polymerization and method for producing olefin polymer
WO2024035392A1 (en)	2024-02-15	Carbonate compounds as activity limiting agents in ziegler-natta catalyst compositions for olefin polymerization