FR3045414B1 - Nouvelle composition catalytique a base de nickel et de ligand de type phosphine et d'une base de lewis et son utilisation dans un procede d'oligomerisation des olefines - Google Patents

Nouvelle composition catalytique a base de nickel et de ligand de type phosphine et d'une base de lewis et son utilisation dans un procede d'oligomerisation des olefines Download PDF

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Publication number
FR3045414B1
FR3045414B1 FR1562756A FR1562756A FR3045414B1 FR 3045414 B1 FR3045414 B1 FR 3045414B1 FR 1562756 A FR1562756 A FR 1562756A FR 1562756 A FR1562756 A FR 1562756A FR 3045414 B1 FR3045414 B1 FR 3045414B1
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Prior art keywords
nickel
lewis base
catalytic composition
composition based
olefin oligomerization
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FR1562756A
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FR3045414A1 (fr
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Pierre-Alain BREUIL
Olivia CHAUMET-MARTIN
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IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
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Priority to FR1562756A priority Critical patent/FR3045414B1/fr
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to BR112018012279-3A priority patent/BR112018012279B1/pt
Priority to PCT/EP2016/080737 priority patent/WO2017102689A1/fr
Priority to RU2018126310A priority patent/RU2744575C2/ru
Priority to US16/062,725 priority patent/US10646860B2/en
Priority to JP2018530900A priority patent/JP6876702B2/ja
Priority to KR1020187020748A priority patent/KR102621942B1/ko
Priority to CN201680074034.2A priority patent/CN108430627B/zh
Priority to PL425935A priority patent/PL239961B1/pl
Priority to CA3007314A priority patent/CA3007314C/fr
Priority to TW105141685A priority patent/TWI756197B/zh
Publication of FR3045414A1 publication Critical patent/FR3045414A1/fr
Priority to SA518391752A priority patent/SA518391752B1/ar
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0204—Ethers
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    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
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    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255—Phosphorus containing compounds
    • B01J31/0267—Phosphines or phosphonium compounds, i.e. phosphorus bonded to at least one carbon atom, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, the other atoms bonded to phosphorus being either carbon or hydrogen
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    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
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    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
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    • B01J31/22—Organic complexes
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    • B01J31/2208—Oxygen, e.g. acetylacetonates
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
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    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
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    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
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    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
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    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1088—Olefins
    • C10G2300/1092—C2-C4 olefins
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    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
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    • C10G2400/20—C2-C4 olefins
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    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/22—Higher olefins

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  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

L'invention concerne une composition catalytique comprenant : au moins un précurseur de nickel de degré d'oxydation (+II), au moins un ligand phosphine de formule PR1 R2R3 dans lequel les groupements R1, R2 et R3, identiques ou différents entre eux, liés ou non entre eux, et au moins une base de Lewis, ladite composition présentant un rapport molaire du ligand phosphine sur le précurseur de nickel inférieur ou égal à 5 et un rapport molaire de l'ensemble base de Lewis et ligand phosphine sur le précurseur de nickel supérieur ou égal à 5.
FR1562756A 2015-12-18 2015-12-18 Nouvelle composition catalytique a base de nickel et de ligand de type phosphine et d'une base de lewis et son utilisation dans un procede d'oligomerisation des olefines Active FR3045414B1 (fr)

Priority Applications (12)

Application Number Priority Date Filing Date Title
FR1562756A FR3045414B1 (fr) 2015-12-18 2015-12-18 Nouvelle composition catalytique a base de nickel et de ligand de type phosphine et d'une base de lewis et son utilisation dans un procede d'oligomerisation des olefines
PL425935A PL239961B1 (pl) 2015-12-18 2016-12-13 Kompozycja katalityczna zawierająca nikiel, ligand typu fosfinowego oraz zasadę Lewisa oraz jej zastosowanie w sposobie oligomeryzacji olefin
RU2018126310A RU2744575C2 (ru) 2015-12-18 2016-12-13 Новая каталитическая композиция на основе никеля и лиганда фосфинового типа и основания льюиса и его применение в способе олигомеризации олефинов
US16/062,725 US10646860B2 (en) 2015-12-18 2016-12-13 Catalytic composition comprising nickel, a phosphine-type ligand and a Lewis base, and use thereof in an olefin oligomerisation method
JP2018530900A JP6876702B2 (ja) 2015-12-18 2016-12-13 ニッケル、ホスフィン型配位子およびルイス塩基を含む触媒組成物とオレフィンオリゴマー化法におけるその使用
KR1020187020748A KR102621942B1 (ko) 2015-12-18 2016-12-13 니켈, 포스핀-유형 리간드 및 루이스 염기를 포함하는 촉매 조성물, 및 올레핀 올리고머화 방법에서의 그 용도
BR112018012279-3A BR112018012279B1 (pt) 2015-12-18 2016-12-13 Composição catalítica à base de níquel e de ligando do tipo fosfina e de uma base de lewis e sua utilização em um processo de oligomerização das olefinas
PCT/EP2016/080737 WO2017102689A1 (fr) 2015-12-18 2016-12-13 Composition catalytique a base de nickel et de ligand de type phosphine et d'une base de lewis et son utilisation dans un procede d'oligomerisation des olefines
CA3007314A CA3007314C (fr) 2015-12-18 2016-12-13 Composition catalytique a base de nickel et de ligand de type phosphine et d'une base de lewis et son utilisation dans un procede d'oligomerisation des olefines
CN201680074034.2A CN108430627B (zh) 2015-12-18 2016-12-13 包含镍、膦型配体和路易斯碱的催化组合物和其在烯烃低聚方法中的用途
TW105141685A TWI756197B (zh) 2015-12-18 2016-12-16 新穎的基於鎳與膦類型配體及路易士鹼之催化組合物，及其於烯烴寡聚製程中的用途
SA518391752A SA518391752B1 (ar) 2015-12-18 2018-06-07 تركيب حفزي يشمل نيكل، ربيطة من نوع فوسفين وقاعدة لويس، واستخدامه في طريقة إجراء أوليجومرية لأولفين

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Application Number Priority Date Filing Date Title
FR1562756 2015-12-18
FR1562756A FR3045414B1 (fr) 2015-12-18 2015-12-18 Nouvelle composition catalytique a base de nickel et de ligand de type phosphine et d'une base de lewis et son utilisation dans un procede d'oligomerisation des olefines

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FR3045414A1 FR3045414A1 (fr) 2017-06-23
FR3045414B1 true FR3045414B1 (fr) 2019-12-27

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FR1562756A Active FR3045414B1 (fr) 2015-12-18 2015-12-18 Nouvelle composition catalytique a base de nickel et de ligand de type phosphine et d'une base de lewis et son utilisation dans un procede d'oligomerisation des olefines

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US (1) US10646860B2 (fr)
JP (1) JP6876702B2 (fr)
KR (1) KR102621942B1 (fr)
CN (1) CN108430627B (fr)
BR (1) BR112018012279B1 (fr)
CA (1) CA3007314C (fr)
FR (1) FR3045414B1 (fr)
PL (1) PL239961B1 (fr)
RU (1) RU2744575C2 (fr)
SA (1) SA518391752B1 (fr)
TW (1) TWI756197B (fr)
WO (1) WO2017102689A1 (fr)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3039430B1 (fr) * 2015-07-29 2019-07-05 IFP Energies Nouvelles Nouvelle composition catalytique a base de nickel et de ligand de type phosphine et son utilisation dans un procede d'oligomerisation des olefines
FR3068620B1 (fr) 2017-07-10 2020-06-26 IFP Energies Nouvelles Procede d’oligomerisation mettant en oeuvre un dispositf reactionnel comprenant un moyen de dispersion
FR3068621B1 (fr) 2017-07-10 2020-06-26 IFP Energies Nouvelles Procede d’oligomerisation mettant en oeuvre un vortex
FR3083235B1 (fr) 2018-06-29 2021-12-03 Ifp Energies Now Procede d'oligomerisation en cascade de reacteurs gaz liquide agites avec injection etagee d'ethylene
FR3086288A1 (fr) 2018-09-21 2020-03-27 IFP Energies Nouvelles Procede d'oligomerisation d'ethylene dans un reacteur gaz/liquide compartimente
FR3086551A1 (fr) * 2018-09-28 2020-04-03 IFP Energies Nouvelles Composition catalytique a base de nickel (ii)
FR3096587B1 (fr) 2019-05-28 2021-06-11 Ifp Energies Now Reacteur d’oligomerisation compartimente
FR3099476B1 (fr) 2019-07-31 2021-07-30 Ifp Energies Now Procede d’oligomerisation mettant en œuvre un recycle du ciel gazeux
FR3102685B1 (fr) 2019-11-06 2021-10-29 Ifp Energies Now Procédé d’oligomérisation d’oléfines dans un réacteur d’oligomérisation
FR3105019B1 (fr) 2019-12-18 2022-07-22 Ifp Energies Now Reacteur gaz/liquide d’oligomerisation a zones successives de diametre variable
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FR3045414A1 (fr) 2017-06-23
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