FR3039431B1 - Nouvelle composition catalytique a base de nickel et d'un ligand de type phosphine complexe au nickel et son utilisation dans un procede d'oligomerisation des olefines - Google Patents

Nouvelle composition catalytique a base de nickel et d'un ligand de type phosphine complexe au nickel et son utilisation dans un procede d'oligomerisation des olefines Download PDF

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Publication number
FR3039431B1
FR3039431B1 FR1557248A FR1557248A FR3039431B1 FR 3039431 B1 FR3039431 B1 FR 3039431B1 FR 1557248 A FR1557248 A FR 1557248A FR 1557248 A FR1557248 A FR 1557248A FR 3039431 B1 FR3039431 B1 FR 3039431B1
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France
Prior art keywords
nickel
catalytic composition
ligand
olefin oligomerization
oligomerization process
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FR1557248A
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English (en)
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FR3039431A1 (fr
Inventor
Pierre-Alain BREUIL
Olivia CHAUMET-MARTIN
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IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
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Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR1557248A priority Critical patent/FR3039431B1/fr
Priority to CN201680044321.9A priority patent/CN108136382B/zh
Priority to PCT/EP2016/058807 priority patent/WO2017016688A1/fr
Priority to US15/748,494 priority patent/US10300473B2/en
Priority to TW105123792A priority patent/TWI727962B/zh
Publication of FR3039431A1 publication Critical patent/FR3039431A1/fr
Priority to SA518390803A priority patent/SA518390803B1/ar
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Publication of FR3039431B1 publication Critical patent/FR3039431B1/fr
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

L'invention concerne une composition catalytique comprenant: au moins un précurseur de nickel de degré d'oxydation (+II) et contenant un ligand phosphine complexé au nickel, au moins une base de Lewis, et au moins un agent activateur choisi dans le groupe formé par les composés chlorés ou bromés d'hydrocarbylaluminium, pris seuls ou en mélange, tel que le rapport molaire de l'ensemble base de Lewis et ligand phosphine complexé au nickel de la composition sur le nickel soit compris entre 5 et 30. L'invention concerne également l'utilisation de la dite composition catalytique.
FR1557248A 2015-07-29 2015-07-29 Nouvelle composition catalytique a base de nickel et d'un ligand de type phosphine complexe au nickel et son utilisation dans un procede d'oligomerisation des olefines Active FR3039431B1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
FR1557248A FR3039431B1 (fr) 2015-07-29 2015-07-29 Nouvelle composition catalytique a base de nickel et d'un ligand de type phosphine complexe au nickel et son utilisation dans un procede d'oligomerisation des olefines
CN201680044321.9A CN108136382B (zh) 2015-07-29 2016-04-20 包含镍和与镍配合的膦型配体的新型催化组合物及其在烯烃低聚方法中的用途
PCT/EP2016/058807 WO2017016688A1 (fr) 2015-07-29 2016-04-20 Nouvelle composition catalytique à base de nickel et d'un ligand de type phosphine complexé au nickel et son utilisation dans un procédé d'oligomérisation des oléfines
US15/748,494 US10300473B2 (en) 2015-07-29 2016-04-20 Catalytic composition comprising nickel and a ligand of the phosphane complexed with nickel type, and use thereof in a olefin oligomerisation method
TW105123792A TWI727962B (zh) 2015-07-29 2016-07-27 新穎的基於鎳與鎳-錯合膦類型配體之催化組合物及其於寡聚烯烴製程之用途
SA518390803A SA518390803B1 (ar) 2015-07-29 2018-01-25 تركيبة حفزية جديدة تشمل نيكل ومركب ترابطي من معقد فوسفين من نوع نيكل، واستخدامها في طريقة أوليجومرية أولفين

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1557248A FR3039431B1 (fr) 2015-07-29 2015-07-29 Nouvelle composition catalytique a base de nickel et d'un ligand de type phosphine complexe au nickel et son utilisation dans un procede d'oligomerisation des olefines
FR1557248 2015-07-29

Publications (2)

Publication Number Publication Date
FR3039431A1 FR3039431A1 (fr) 2017-02-03
FR3039431B1 true FR3039431B1 (fr) 2019-05-31

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FR1557248A Active FR3039431B1 (fr) 2015-07-29 2015-07-29 Nouvelle composition catalytique a base de nickel et d'un ligand de type phosphine complexe au nickel et son utilisation dans un procede d'oligomerisation des olefines

Country Status (6)

Country Link
US (1) US10300473B2 (fr)
CN (1) CN108136382B (fr)
FR (1) FR3039431B1 (fr)
SA (1) SA518390803B1 (fr)
TW (1) TWI727962B (fr)
WO (1) WO2017016688A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3045414B1 (fr) * 2015-12-18 2019-12-27 IFP Energies Nouvelles Nouvelle composition catalytique a base de nickel et de ligand de type phosphine et d'une base de lewis et son utilisation dans un procede d'oligomerisation des olefines
FR3074065B1 (fr) * 2017-11-30 2019-12-13 IFP Energies Nouvelles Nouvelle composition catalytique a base de nickel, d’un phosphonium et son utilisation pour l’oligomerisation des olefines
FR3082759A1 (fr) * 2018-06-22 2019-12-27 IFP Energies Nouvelles Composition catalytique a base de nickel et d'un reducteur organique

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
LU51826A1 (fr) * 1965-09-06 1966-10-26
FR1588162A (fr) 1966-04-14 1970-04-10
DE1568729A1 (de) * 1966-12-09 1970-03-26 Gelsenberg Benzin Ag Katalysator fuer die Oligomerisation von Olefinen und Polymerisation von 1,3-Diolefinen
US3485881A (en) * 1967-10-09 1969-12-23 Phillips Petroleum Co Dimerization of olefins
US3485892A (en) * 1967-11-22 1969-12-23 Sun Oil Co Catalyst system and process for polymerization of olefins
US4176086A (en) 1977-08-25 1979-11-27 Phillips Petroleum Company Catalyst preparation
US4242531A (en) 1978-08-14 1980-12-30 Phillips Petroleum Company Olefin dimerization
US5237118A (en) 1992-08-21 1993-08-17 Phillips Petroleum Company Ethylene oligomerization
EP0646413B1 (fr) * 1993-09-22 2000-03-01 Institut Français du Pétrole Nouvelle composition contenant du nickel pour la catalyse et procédé de dimérisation et d'oligomérisation des oléfines
DE10303931B4 (de) 2002-02-04 2013-04-18 Institut Français du Pétrole Katalytische Zusammensetzung zur Dimerisierung, Co-Dimerisierung, Oligomerisierung und Polymerisation der Olefine
CN1204155C (zh) * 2002-09-03 2005-06-01 中国石油化工股份有限公司 用于烯烃聚合催化剂的配体及其过渡金属配合物
US7232869B2 (en) * 2005-05-17 2007-06-19 Novolen Technology Holdings, C.V. Catalyst composition for olefin polymerization
FR2895406B1 (fr) 2005-12-22 2010-08-13 Inst Francais Du Petrole Procede pour la fabrication de 2,3-dimethylbut-1-ene
CN108129590A (zh) * 2010-12-31 2018-06-08 株式会社普利司通 使用基于镍的催化剂***的共轭二烯本体聚合

Also Published As

Publication number Publication date
CN108136382A (zh) 2018-06-08
WO2017016688A1 (fr) 2017-02-02
TWI727962B (zh) 2021-05-21
US20180221861A1 (en) 2018-08-09
CN108136382B (zh) 2021-06-15
TW201709982A (zh) 2017-03-16
SA518390803B1 (ar) 2022-03-06
US10300473B2 (en) 2019-05-28
FR3039431A1 (fr) 2017-02-03

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