FR3108264B1 - Installation d’oligomérisation d’éthylène pour produire des alpha-oléfines - Google Patents

Installation d’oligomérisation d’éthylène pour produire des alpha-oléfines Download PDF

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Publication number
FR3108264B1
FR3108264B1 FR2002708A FR2002708A FR3108264B1 FR 3108264 B1 FR3108264 B1 FR 3108264B1 FR 2002708 A FR2002708 A FR 2002708A FR 2002708 A FR2002708 A FR 2002708A FR 3108264 B1 FR3108264 B1 FR 3108264B1
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FR
France
Prior art keywords
reactor
olefins
oligomerization
ethylene oligomerization
ethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR2002708A
Other languages
English (en)
Other versions
FR3108264A1 (fr
Inventor
Cyprien Charra
Olivier Cotte
Frederic Favre
Slavik Kasztelan
Jerome Pigourier
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR2002708A priority Critical patent/FR3108264B1/fr
Priority to US17/912,088 priority patent/US20230158471A1/en
Priority to CA3172136A priority patent/CA3172136A1/fr
Priority to PCT/EP2021/056417 priority patent/WO2021185706A1/fr
Publication of FR3108264A1 publication Critical patent/FR3108264A1/fr
Application granted granted Critical
Publication of FR3108264B1 publication Critical patent/FR3108264B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/30—Loose or shaped packing elements, e.g. Raschig rings or Berl saddles, for pouring into the apparatus for mass or heat transfer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14—Fractional distillation or use of a fractionation or rectification column
    • B01D3/143—Fractional distillation or use of a fractionation or rectification column by two or more of a fractionation, separation or rectification step
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J10/00—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006—Controlling or regulating processes
    • B01J19/0013—Controlling the temperature of the process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2455—Stationary reactors without moving elements inside provoking a loop type movement of the reactants
    • B01J19/2465—Stationary reactors without moving elements inside provoking a loop type movement of the reactants externally, i.e. the mixture leaving the vessel and subsequently re-entering it
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212—Plates; Jackets; Cylinders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094—Jackets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00245—Avoiding undesirable reactions or side-effects
    • B01J2219/00247—Fouling of the reactor or the process equipment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00245—Avoiding undesirable reactions or side-effects
    • B01J2219/00252—Formation of deposits other than coke

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La présente invention concerne une installation d’oligomérisation d’éthylène pour produire des alpha-oléfines oligomérisées, avec production d’un sous-produit encrassant sous forme de dépôt, ladite installation comprenant une section réactionnelle comprenant : - un réacteur (c) d’oligomérisation biphasique gaz/liquide ou monophasique tout liquide à partir d’un solvant, d’un catalyseur d’oligomérisation et d’éthylène, et - des moyens de refroidissement associés audit réacteur sous forme d’au moins un circuit de refroidissement externe au réacteur et/ou sous forme d’une double-enveloppe des parois du réacteur. Des garnissages sont disposés dans la section réactionnelle, afin d’augmenter la surface de contact par unité de volume accessible au dépôt du sous-produit. Figure 1 à publier
FR2002708A 2020-03-19 2020-03-19 Installation d’oligomérisation d’éthylène pour produire des alpha-oléfines Active FR3108264B1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
FR2002708A FR3108264B1 (fr) 2020-03-19 2020-03-19 Installation d’oligomérisation d’éthylène pour produire des alpha-oléfines
US17/912,088 US20230158471A1 (en) 2020-03-19 2021-03-12 Ethylene oligomerisation plant for producing alpha-olefins
CA3172136A CA3172136A1 (fr) 2020-03-19 2021-03-12 Installation d'oligomerisation d'ethylene pour produire des alpha-olefines
PCT/EP2021/056417 WO2021185706A1 (fr) 2020-03-19 2021-03-12 Installation d'oligomerisation d'ethylene pour produire des alpha-olefines

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2002708 2020-03-19
FR2002708A FR3108264B1 (fr) 2020-03-19 2020-03-19 Installation d’oligomérisation d’éthylène pour produire des alpha-oléfines

Publications (2)

Publication Number Publication Date
FR3108264A1 FR3108264A1 (fr) 2021-09-24
FR3108264B1 true FR3108264B1 (fr) 2022-04-08

Family

ID=70804789

Family Applications (1)

Application Number Title Priority Date Filing Date
FR2002708A Active FR3108264B1 (fr) 2020-03-19 2020-03-19 Installation d’oligomérisation d’éthylène pour produire des alpha-oléfines

Country Status (4)

Country Link
US (1) US20230158471A1 (fr)
CA (1) CA3172136A1 (fr)
FR (1) FR3108264B1 (fr)
WO (1) WO2021185706A1 (fr)

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2552079B1 (fr) 1983-09-20 1986-10-03 Inst Francais Du Petrole Procede ameliore de synthese du butene-1 par dimerisation de l'ethylene
US5792428A (en) * 1994-07-18 1998-08-11 Chemical Research & Licensing Company Apparatus for conducting exothermic reactions
US6004256A (en) * 1995-05-26 1999-12-21 Townsend; Phillip Catalytic distillation oligomerization of vinyl monomers to make polymerizable vinyl monomer oligomers uses thereof and methods for same
US6274783B1 (en) * 2000-03-20 2001-08-14 Catalytic Distillation Technologies Catalytic distillation process for the production of C8 alkanes
CA2510190C (fr) 2002-12-20 2011-10-11 Sasol Technology (Pty) Limited Tetramerisation d'olefines
CA2583007C (fr) 2007-03-29 2015-03-31 Nova Chemicals Corporation Aminophosphine
FR2984311B1 (fr) 2011-12-20 2015-01-30 IFP Energies Nouvelles Procede de production d'octenes mettant en oeuvre la dimerisation de l'ethylene en butenes et la dimerisation des butenes en octenes
FR2992962B1 (fr) 2012-07-04 2015-06-26 Axens Procede de separation de l'hexene-1 a partir d'un melange de produits issus d'une zone de trimerisation de l'ethylene
FR3019064B1 (fr) 2014-03-25 2020-02-28 IFP Energies Nouvelles Nouvelle composition catalytique et procede pour l'oligomerisation de l'ethylene en hexene-1
FR3023183A1 (fr) 2014-07-04 2016-01-08 IFP Energies Nouvelles Composition catalytique et procede de dimerisation selective de l'ethylene en butene-1
FR3042989A1 (fr) 2015-10-30 2017-05-05 Ifp Energies Now Nouvelle composition catalytique a base de nickel en presence d'un activateur specifique et son utilisation dans un procede d'oligomerisation des olefines
FR3045414B1 (fr) 2015-12-18 2019-12-27 IFP Energies Nouvelles Nouvelle composition catalytique a base de nickel et de ligand de type phosphine et d'une base de lewis et son utilisation dans un procede d'oligomerisation des olefines
FR3061034B1 (fr) 2016-12-22 2019-05-31 IFP Energies Nouvelles Procede d'oligomerisation d'olefines mettant en œuvre un dispositif de nettoyage
CN112969676A (zh) * 2018-10-31 2021-06-15 鲁姆斯科技有限责任公司 异丁烯经由催化蒸馏的选择性二聚合和醚化
BR112022001560A2 (pt) * 2019-07-30 2022-05-03 Dow Global Technologies Llc Método para reduzir a incrustação em um reator de aprimoramento
TWI801918B (zh) * 2020-06-29 2023-05-11 美商魯瑪斯科技有限責任公司 用於丁烯之經控制寡聚化的方法
CN116648444A (zh) * 2020-10-28 2023-08-25 鲁姆斯科技有限责任公司 通过催化蒸馏对c5烯烃进行二聚化和三聚化

Also Published As

Publication number Publication date
CA3172136A1 (fr) 2021-09-23
WO2021185706A1 (fr) 2021-09-23
FR3108264A1 (fr) 2021-09-24
US20230158471A1 (en) 2023-05-25

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