FR3039544B1 - Procede de metathese des olefines utilisant un catalyseur contenant du silicium et du molybdene incorpores au moyen d'au moins deux precurseurs - Google Patents
Procede de metathese des olefines utilisant un catalyseur contenant du silicium et du molybdene incorpores au moyen d'au moins deux precurseurs Download PDFInfo
- Publication number
- FR3039544B1 FR3039544B1 FR1557368A FR1557368A FR3039544B1 FR 3039544 B1 FR3039544 B1 FR 3039544B1 FR 1557368 A FR1557368 A FR 1557368A FR 1557368 A FR1557368 A FR 1557368A FR 3039544 B1 FR3039544 B1 FR 3039544B1
- Authority
- FR
- France
- Prior art keywords
- metathesis
- olefins
- precursors
- incorporated
- molybdene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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- 239000002243 precursor Substances 0.000 title abstract 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 title abstract 3
- 229910052710 silicon Inorganic materials 0.000 title abstract 3
- 239000010703 silicon Substances 0.000 title abstract 3
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 title abstract 2
- 238000005649 metathesis reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 2
- 239000011159 matrix material Substances 0.000 abstract 2
- 229910052750 molybdenum Inorganic materials 0.000 abstract 2
- 239000011733 molybdenum Substances 0.000 abstract 2
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/30—Tungsten
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/881—Molybdenum and iron
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- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
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- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
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- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/885—Molybdenum and copper
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- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
- B01J27/19—Molybdenum
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- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J37/0201—Impregnation
- B01J37/0213—Preparation of the impregnating solution
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
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- B01J37/082—Decomposition and pyrolysis
- B01J37/086—Decomposition of an organometallic compound, a metal complex or a metal salt of a carboxylic acid
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
- C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
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- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
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- B01J35/615—100-500 m2/g
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- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/633—Pore volume less than 0.5 ml/g
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- C07C2521/08—Silica
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/28—Molybdenum
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Nanotechnology (AREA)
Abstract
L'invention concerne un procédé de métathèse des oléfines mis en œuvre avec un catalyseur comprenant une matrice mésoporeuse et au moins les éléments molybdène et silicium, lesdits éléments étant incorporés à ladite matrice au moyen d'au moins deux précurseurs dont au moins un précurseur contient du molybdène et au moins un précurseur contient du silicium.
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1557368A FR3039544B1 (fr) | 2015-07-31 | 2015-07-31 | Procede de metathese des olefines utilisant un catalyseur contenant du silicium et du molybdene incorpores au moyen d'au moins deux precurseurs |
CN201680044735.1A CN108136378B (zh) | 2015-07-31 | 2016-07-26 | 使用含有借助至少两种前体并入的硅和钼的催化剂的烯烃复分解方法 |
PCT/EP2016/067830 WO2017021233A1 (fr) | 2015-07-31 | 2016-07-26 | Procede de metathese des olefines utilisant un catalyseur contenant du silicium et du molybdene incorpores au moyen d'au moins deux precurseurs |
US15/749,298 US10758892B2 (en) | 2015-07-31 | 2016-07-26 | Olefin metathesis method using a catalyst containing silicon and molybdenum incorporated by means of at least two precursors |
TW105124186A TW201714860A (zh) | 2015-07-31 | 2016-07-29 | 使用包含藉由至少二種前驅物併入之矽及鉬之催化劑進行烯烴歧化之方法 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1557368A FR3039544B1 (fr) | 2015-07-31 | 2015-07-31 | Procede de metathese des olefines utilisant un catalyseur contenant du silicium et du molybdene incorpores au moyen d'au moins deux precurseurs |
FR1557368 | 2015-07-31 |
Publications (2)
Publication Number | Publication Date |
---|---|
FR3039544A1 FR3039544A1 (fr) | 2017-02-03 |
FR3039544B1 true FR3039544B1 (fr) | 2020-02-28 |
Family
ID=54145941
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR1557368A Active FR3039544B1 (fr) | 2015-07-31 | 2015-07-31 | Procede de metathese des olefines utilisant un catalyseur contenant du silicium et du molybdene incorpores au moyen d'au moins deux precurseurs |
Country Status (5)
Country | Link |
---|---|
US (1) | US10758892B2 (fr) |
CN (1) | CN108136378B (fr) |
FR (1) | FR3039544B1 (fr) |
TW (1) | TW201714860A (fr) |
WO (1) | WO2017021233A1 (fr) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR3039544B1 (fr) | 2015-07-31 | 2020-02-28 | IFP Energies Nouvelles | Procede de metathese des olefines utilisant un catalyseur contenant du silicium et du molybdene incorpores au moyen d'au moins deux precurseurs |
CN113019449B (zh) * | 2020-06-24 | 2022-10-14 | 上海应用技术大学 | 一种芳香氧化偶氮化合物的催化制备方法 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2437532A (en) * | 1942-12-24 | 1948-03-09 | Union Oil Co | Process for the catalytic reforming of hydrocarbons |
US2722504A (en) * | 1950-12-04 | 1955-11-01 | Union Oil Co | Silicone coated catalyst and use thereof |
FR2787040B1 (fr) * | 1998-12-10 | 2001-01-19 | Inst Francais Du Petrole | Hydrotraitement de charges hydrocarbonees dans un reacteur en lit bouillonnant |
FR2826880B1 (fr) * | 2001-07-04 | 2004-06-18 | Inst Francais Du Petrole | Composition amelioree de catalyseur pour la metathese des olefines |
DE102004009805A1 (de) * | 2004-02-28 | 2005-09-15 | Basf Ag | Trägerkatalysator definierter Porenverteilung im Bereich der Mesoporen |
AR078212A1 (es) * | 2008-09-04 | 2011-10-26 | Basf Catalysts Llc | Catalizador para isomerizacion y metatesis de olefinas |
CN102335631B (zh) * | 2010-07-16 | 2015-05-13 | 中国石油天然气股份有限公司 | 一种低碳烯烃歧化用介孔催化剂及其应用 |
CN102614867B (zh) * | 2011-01-30 | 2015-04-29 | 中国石油化工股份有限公司 | 一种烯烃歧化用催化剂及其制备方法 |
FR2977890B1 (fr) * | 2011-07-15 | 2013-07-19 | IFP Energies Nouvelles | Procede de metathese des olefines utilisant un catalyseur a base d'un materiau spherique comprenant des particules metalliques oxydes piegees dans une matrice mesostructuree |
FR3007029B1 (fr) * | 2013-06-17 | 2015-07-24 | IFP Energies Nouvelles | Procede de metathese des olefines utilisant un catalyseur a base d'un materiau spherique a porosite hierarchisee comprenant des particules metalliques oxydes piegees dans une matrice comprenant de l'oxyde de silicium |
FR3039544B1 (fr) | 2015-07-31 | 2020-02-28 | IFP Energies Nouvelles | Procede de metathese des olefines utilisant un catalyseur contenant du silicium et du molybdene incorpores au moyen d'au moins deux precurseurs |
-
2015
- 2015-07-31 FR FR1557368A patent/FR3039544B1/fr active Active
-
2016
- 2016-07-26 WO PCT/EP2016/067830 patent/WO2017021233A1/fr active Application Filing
- 2016-07-26 US US15/749,298 patent/US10758892B2/en active Active
- 2016-07-26 CN CN201680044735.1A patent/CN108136378B/zh active Active
- 2016-07-29 TW TW105124186A patent/TW201714860A/zh unknown
Also Published As
Publication number | Publication date |
---|---|
WO2017021233A1 (fr) | 2017-02-09 |
CN108136378B (zh) | 2022-05-24 |
FR3039544A1 (fr) | 2017-02-03 |
CN108136378A (zh) | 2018-06-08 |
TW201714860A (zh) | 2017-05-01 |
US10758892B2 (en) | 2020-09-01 |
US20180221854A1 (en) | 2018-08-09 |
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