CN1195834C - 制备洗涤剂组合物的方法 - Google Patents

制备洗涤剂组合物的方法 Download PDF

Info

Publication number: CN1195834C
Authority: CN; China
Prior art keywords: nonionogenic tenside; parts; surfactant; premixture; particle size
Prior art date: 1996-07-04
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CNB971973946A

Other languages

English (en)

Chinese (zh)

Other versions

CN1332790A (zh

Inventor

S·J·多诺胡

M·K·N·里普利恩

C·P·D·维尔金森

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Procter and Gamble Co

Original Assignee

Procter and Gamble Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-07-04

Filing date

1997-06-27

Publication date

2005-04-06

1997-06-27 Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co

2002-01-23 Publication of CN1332790A publication Critical patent/CN1332790A/zh

2005-04-06 Application granted granted Critical

2005-04-06 Publication of CN1195834C publication Critical patent/CN1195834C/zh

2017-06-27 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 19
239000000203 mixture Substances 0.000 title claims description 20
239000003599 detergent Substances 0.000 title claims description 11
239000002245 particle Substances 0.000 claims abstract description 60
239000004094 surface-active agent Substances 0.000 claims abstract description 24
239000000654 additive Substances 0.000 claims abstract description 22
239000003945 anionic surfactant Substances 0.000 claims abstract description 14
238000002156 mixing Methods 0.000 claims abstract description 12
230000000996 additive effect Effects 0.000 claims description 16
239000011236 particulate material Substances 0.000 claims description 9
230000015572 biosynthetic process Effects 0.000 claims description 5
MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 claims description 4
150000001450 anions Chemical class 0.000 claims description 2
230000003287 optical effect Effects 0.000 claims description 2
239000013618 particulate matter Substances 0.000 claims description 2
230000011218 segmentation Effects 0.000 claims description 2
239000002736 nonionic surfactant Substances 0.000 abstract description 4
238000005507 spraying Methods 0.000 abstract description 3
239000010457 zeolite Substances 0.000 description 28
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 27
229910021536 Zeolite Inorganic materials 0.000 description 22
239000000047 product Substances 0.000 description 19
-1 supercarbonate Chemical compound 0.000 description 16
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
235000014113 dietary fatty acids Nutrition 0.000 description 12
239000000194 fatty acid Substances 0.000 description 12
229930195729 fatty acid Natural products 0.000 description 12
239000008187 granular material Substances 0.000 description 10
239000000463 material Substances 0.000 description 10
238000005406 washing Methods 0.000 description 10
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
239000003795 chemical substances by application Substances 0.000 description 9
238000005342 ion exchange Methods 0.000 description 9
150000004665 fatty acids Chemical class 0.000 description 8
238000002360 preparation method Methods 0.000 description 7
239000000843 powder Substances 0.000 description 6
239000011575 calcium Substances 0.000 description 5
239000007921 spray Substances 0.000 description 5
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical group [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 4
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 4
125000000217 alkyl group Chemical group 0.000 description 4
229910000323 aluminium silicate Inorganic materials 0.000 description 4
150000001412 amines Chemical class 0.000 description 4
229910001424 calcium ion Inorganic materials 0.000 description 4
125000004432 carbon atom Chemical group C* 0.000 description 4
239000011734 sodium Substances 0.000 description 4
239000003760 tallow Substances 0.000 description 4
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
150000008051 alkyl sulfates Chemical class 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
238000009833 condensation Methods 0.000 description 3
230000005494 condensation Effects 0.000 description 3
239000007859 condensation product Substances 0.000 description 3
238000004090 dissolution Methods 0.000 description 3
239000003352 sequestering agent Substances 0.000 description 3
229910052708 sodium Inorganic materials 0.000 description 3
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
102000004190 Enzymes Human genes 0.000 description 2
108090000790 Enzymes Proteins 0.000 description 2
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
241000282326 Felis catus Species 0.000 description 2
229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
239000002253 acid Substances 0.000 description 2
239000013543 active substance Substances 0.000 description 2
238000005054 agglomeration Methods 0.000 description 2
230000002776 aggregation Effects 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
238000002425 crystallisation Methods 0.000 description 2
230000008025 crystallization Effects 0.000 description 2
GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 2
230000000694 effects Effects 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
230000002209 hydrophobic effect Effects 0.000 description 2
CBOIHMRHGLHBPB-UHFFFAOYSA-N hydroxymethyl Chemical compound O[CH2] CBOIHMRHGLHBPB-UHFFFAOYSA-N 0.000 description 2
230000006872 improvement Effects 0.000 description 2
239000002563 ionic surfactant Substances 0.000 description 2
150000002632 lipids Chemical class 0.000 description 2
150000004702 methyl esters Chemical class 0.000 description 2
229920000058 polyacrylate Polymers 0.000 description 2
239000000126 substance Substances 0.000 description 2
229910021653 sulphate ion Inorganic materials 0.000 description 2
230000002087 whitening effect Effects 0.000 description 2
VPTUPAVOBUEXMZ-UHFFFAOYSA-N (1-hydroxy-2-phosphonoethyl)phosphonic acid Chemical compound OP(=O)(O)C(O)CP(O)(O)=O VPTUPAVOBUEXMZ-UHFFFAOYSA-N 0.000 description 1
LDDMACCNBZAMSG-BDVNFPICSA-N (2r,3r,4s,5r)-3,4,5,6-tetrahydroxy-2-(methylamino)hexanal Chemical compound CN[C@@H](C=O)[C@@H](O)[C@H](O)[C@H](O)CO LDDMACCNBZAMSG-BDVNFPICSA-N 0.000 description 1
YGUMVDWOQQJBGA-VAWYXSNFSA-N 5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S(O)(=O)=O)C(S(=O)(=O)O)=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 YGUMVDWOQQJBGA-VAWYXSNFSA-N 0.000 description 1
229910017090 AlO 2 Inorganic materials 0.000 description 1
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical class [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
RKWGIWYCVPQPMF-UHFFFAOYSA-N Chloropropamide Chemical compound CCCNC(=O)NS(=O)(=O)C1=CC=C(Cl)C=C1 RKWGIWYCVPQPMF-UHFFFAOYSA-N 0.000 description 1
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
229910004298 SiO 2 Inorganic materials 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
229920002472 Starch Polymers 0.000 description 1
ZUBJEHHGZYTRPH-KTKRTIGZSA-N [(z)-octadec-9-enyl] hydrogen sulfate Chemical compound CCCCCCCC\C=C/CCCCCCCCOS(O)(=O)=O ZUBJEHHGZYTRPH-KTKRTIGZSA-N 0.000 description 1
230000009471 action Effects 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
125000002947 alkylene group Chemical group 0.000 description 1
235000019270 ammonium chloride Nutrition 0.000 description 1
239000007844 bleaching agent Substances 0.000 description 1
239000013078 crystal Substances 0.000 description 1
230000018044 dehydration Effects 0.000 description 1
238000006297 dehydration reaction Methods 0.000 description 1
GSPKZYJPUDYKPI-UHFFFAOYSA-N diethoxy sulfate Chemical compound CCOOS(=O)(=O)OOCC GSPKZYJPUDYKPI-UHFFFAOYSA-N 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000001035 drying Methods 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
238000007046 ethoxylation reaction Methods 0.000 description 1
235000019387 fatty acid methyl ester Nutrition 0.000 description 1
150000002191 fatty alcohols Chemical class 0.000 description 1
150000002193 fatty amides Chemical class 0.000 description 1
229930182478 glucoside Natural products 0.000 description 1
235000011187 glycerol Nutrition 0.000 description 1
125000005908 glyceryl ester group Chemical group 0.000 description 1
150000002338 glycosides Chemical class 0.000 description 1
230000003179 granulation Effects 0.000 description 1
238000005469 granulation Methods 0.000 description 1
125000001165 hydrophobic group Chemical group 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
229910017053 inorganic salt Inorganic materials 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
238000005259 measurement Methods 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
CQDGTJPVBWZJAZ-UHFFFAOYSA-N monoethyl carbonate Chemical compound CCOC(O)=O CQDGTJPVBWZJAZ-UHFFFAOYSA-N 0.000 description 1
239000003921 oil Substances 0.000 description 1
229920000151 polyglycol Polymers 0.000 description 1
239000010695 polyglycol Substances 0.000 description 1
235000019353 potassium silicate Nutrition 0.000 description 1
230000009467 reduction Effects 0.000 description 1
229940071089 sarcosinate Drugs 0.000 description 1
229920002545 silicone oil Polymers 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
235000017550 sodium carbonate Nutrition 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
ZUFONQSOSYEWCN-UHFFFAOYSA-M sodium;2-(methylamino)acetate Chemical compound [Na+].CNCC([O-])=O ZUFONQSOSYEWCN-UHFFFAOYSA-M 0.000 description 1
239000002904 solvent Substances 0.000 description 1
235000019698 starch Nutrition 0.000 description 1
239000008107 starch Substances 0.000 description 1
230000019635 sulfation Effects 0.000 description 1
238000005670 sulfation reaction Methods 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 description 1
SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 1
238000009736 wetting Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
- C11D11/0088—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads the liquefied ingredients being sprayed or adsorbed onto solid particles

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)

CNB971973946A 1996-07-04 1997-06-27 制备洗涤剂组合物的方法 Expired - Fee Related CN1195834C (zh)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
EP96201854.5		1996-07-04
EP96201854A EP0816485B1 (en)	1996-07-04	1996-07-04	Process for making detergent compositions

Publications (2)

Publication Number	Publication Date
CN1332790A CN1332790A (zh)	2002-01-23
CN1195834C true CN1195834C (zh)	2005-04-06

Family

ID=8224140

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CNB971973946A Expired - Fee Related CN1195834C (zh)	1996-07-04	1997-06-27	制备洗涤剂组合物的方法

Country Status (10)

Country	Link
EP (1)	EP0816485B1 (ja)
JP (1)	JPH11514033A (ja)
CN (1)	CN1195834C (ja)
AR (1)	AR008062A1 (ja)
AT (1)	ATE312901T1 (ja)
BR (1)	BR9710199A (ja)
CA (1)	CA2259535C (ja)
DE (1)	DE69635575T2 (ja)
ES (1)	ES2253747T3 (ja)
WO (1)	WO1998001520A2 (ja)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6156718A (en) *	1996-07-04	2000-12-05	The Procter & Gamble Company	Process for making detergent compositions
US6906022B1 (en) *	1998-09-25	2005-06-14	The Procter & Gamble Company	Granular detergent compositions having homogenous particles and process for producing same
AU9585098A (en) *	1998-09-25	2000-04-17	Procter & Gamble Company, The	Granular detergent composition having improved appearance and solubility
CA2343810A1 (en) *	1998-09-25	2000-04-06	Jacqueline Westfield	Granular detergent composition having improved appearance and solubility
US6964945B1 (en)	1998-09-25	2005-11-15	The Procter & Gamble Company	Solid detergent compositions
US6673766B1 (en) *	1998-09-25	2004-01-06	The Procter & Gamble Company	Solid detergent compositions containing mixtures of surfactant/builder particles
JP2003527455A (ja) *	1998-09-25	2003-09-16	ザ、プロクター、エンド、ギャンブル、カンパニー	改善された溶解度特性を有する粒状洗剤組成物
JP2002528600A (ja)	1998-10-26	2002-09-03	ザ、プロクター、エンド、ギャンブル、カンパニー	外観と溶解性の改良された粒状洗剤組成物の製造方法
EP1104804B1 (en) *	1999-06-14	2005-04-20	Kao Corporation	Method for producing single nucleus detergent particles
CN1200999C (zh) *	1999-06-21	2005-05-11	宝洁公司	制造粒状洗涤剂组合物的方法
US6833346B1 (en) *	1999-06-21	2004-12-21	The Procter & Gamble Company	Process for making detergent particulates
US6951837B1 (en)	1999-06-21	2005-10-04	The Procter & Gamble Company	Process for making a granular detergent composition
GB0111863D0 (en) *	2001-05-15	2001-07-04	Unilever Plc	Granular composition
DE102006029007A1 (de) *	2006-06-24	2008-01-03	Cognis Ip Management Gmbh	Feste Tenside in granularer Form

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4136051A (en) *	1974-02-25	1979-01-23	Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa)	Pourable washing compositions containing a luminosilicates and non-ionics and method for their preparation
JPS6189300A (ja) *	1984-10-09	1986-05-07	ライオン株式会社	非イオン界面活性剤を含む粒状洗剤組成物の製造方法
TW240243B (ja) *	1992-03-12	1995-02-11	Kao Corp
DE4209435A1 (de) *	1992-03-24	1993-09-30	Henkel Kgaa	Granulares, nichtionische Tenside enthaltendes, phosphatfreies Additiv für Wasch- und Reinigungsmittel
TR27586A (tr) *	1992-09-01	1995-06-13	Procter & Gamble	Yüksek yogunlukla zerre deterjanin yapilmasi icin islem ve islem ile yapilan bilesimler.

1996
- 1996-07-04 AT AT96201854T patent/ATE312901T1/de not_active IP Right Cessation
- 1996-07-04 DE DE69635575T patent/DE69635575T2/de not_active Expired - Fee Related
- 1996-07-04 EP EP96201854A patent/EP0816485B1/en not_active Expired - Lifetime
- 1996-07-04 ES ES96201854T patent/ES2253747T3/es not_active Expired - Lifetime
1997
- 1997-06-27 BR BR9710199-0A patent/BR9710199A/pt not_active IP Right Cessation
- 1997-06-27 JP JP10505241A patent/JPH11514033A/ja active Pending
- 1997-06-27 CN CNB971973946A patent/CN1195834C/zh not_active Expired - Fee Related
- 1997-06-27 CA CA002259535A patent/CA2259535C/en not_active Expired - Fee Related
- 1997-06-27 WO PCT/US1997/011281 patent/WO1998001520A2/en active Application Filing
- 1997-07-03 AR ARP970102992A patent/AR008062A1/es unknown

Also Published As

Publication number	Publication date
WO1998001520A2 (en)	1998-01-15
BR9710199A (pt)	1999-11-23
CA2259535C (en)	2002-10-01
ES2253747T3 (es)	2006-06-01
DE69635575T2 (de)	2006-09-14
AR008062A1 (es)	1999-12-09
CN1332790A (zh)	2002-01-23
DE69635575D1 (de)	2006-01-19
ATE312901T1 (de)	2005-12-15
EP0816485A1 (en)	1998-01-07
JPH11514033A (ja)	1999-11-30
EP0816485B1 (en)	2005-12-14
CA2259535A1 (en)	1998-01-15

Legal Events

Date	Code	Title	Description
2002-01-23	C06	Publication
2002-01-23	C10	Entry into substantive examination
2002-01-23	PB01	Publication
2002-01-23	SE01	Entry into force of request for substantive examination
2005-04-06	C14	Grant of patent or utility model
2005-04-06	GR01	Patent grant
2012-08-29	C17	Cessation of patent right
2012-08-29	CF01	Termination of patent right due to non-payment of annual fee	Granted publication date: 20050406 Termination date: 20110627

Publication	Publication Date	Title
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