ES2253747T3 - Proceso para la fabricar composiciones detergentes. - Google Patents

Proceso para la fabricar composiciones detergentes.

Info

Publication number: ES2253747T3
Authority: ES; Spain
Prior art keywords: surfactant; ionic; parts; particle; premix
Prior art date: 1996-07-04
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

ES96201854T

Other languages

English (en)

Spanish (es)

Inventor

Scott John Donoghue

Marcel Karel Nelis Liplijn

Carole Patricia Denise Wilkinson

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Procter and Gamble Co

Original Assignee

Procter and Gamble Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-07-04

Filing date

1996-07-04

Publication date

2006-06-01

1996-07-04 Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co

2006-06-01 Application granted granted Critical

2006-06-01 Publication of ES2253747T3 publication Critical patent/ES2253747T3/es

2016-07-04 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 21
230000008569 process Effects 0.000 title claims abstract description 18
239000000203 mixture Substances 0.000 title claims description 21
239000003599 detergent Substances 0.000 title claims description 15
238000004519 manufacturing process Methods 0.000 title claims description 8
239000002245 particle Substances 0.000 claims abstract description 71
239000004094 surface-active agent Substances 0.000 claims abstract description 31
239000002736 nonionic surfactant Substances 0.000 claims abstract description 29
239000000654 additive Substances 0.000 claims abstract description 23
239000007921 spray Substances 0.000 claims abstract description 13
238000002156 mixing Methods 0.000 claims abstract description 9
239000003945 anionic surfactant Substances 0.000 claims abstract description 8
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 31
229910000323 aluminium silicate Inorganic materials 0.000 claims description 13
239000000463 material Substances 0.000 claims description 13
125000000129 anionic group Chemical group 0.000 claims description 6
239000011236 particulate material Substances 0.000 claims description 6
MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 claims description 4
239000007844 bleaching agent Substances 0.000 claims description 3
238000009826 distribution Methods 0.000 claims description 3
239000010457 zeolite Substances 0.000 description 27
229910021536 Zeolite Inorganic materials 0.000 description 24
-1 aluminosilicate ion Chemical class 0.000 description 23
239000000047 product Substances 0.000 description 17
125000000217 alkyl group Chemical group 0.000 description 12
235000014113 dietary fatty acids Nutrition 0.000 description 12
239000000194 fatty acid Substances 0.000 description 12
229930195729 fatty acid Natural products 0.000 description 12
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
150000004665 fatty acids Chemical class 0.000 description 9
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 7
239000011575 calcium Substances 0.000 description 7
239000011734 sodium Substances 0.000 description 7
150000001298 alcohols Chemical class 0.000 description 6
238000004090 dissolution Methods 0.000 description 6
229910052708 sodium Inorganic materials 0.000 description 6
239000012530 fluid Substances 0.000 description 5
238000005342 ion exchange Methods 0.000 description 5
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 4
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
239000002253 acid Substances 0.000 description 4
230000000996 additive effect Effects 0.000 description 4
125000004432 carbon atom Chemical group C* 0.000 description 4
239000007859 condensation product Substances 0.000 description 4
239000000843 powder Substances 0.000 description 4
239000003760 tallow Substances 0.000 description 4
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
238000005054 agglomeration Methods 0.000 description 3
230000002776 aggregation Effects 0.000 description 3
239000002738 chelating agent Substances 0.000 description 3
150000002148 esters Chemical class 0.000 description 3
150000004702 methyl esters Chemical class 0.000 description 3
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical group [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 2
102000004190 Enzymes Human genes 0.000 description 2
108090000790 Enzymes Proteins 0.000 description 2
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
230000009435 amidation Effects 0.000 description 2
238000007112 amidation reaction Methods 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
239000002518 antifoaming agent Substances 0.000 description 2
229910052791 calcium Inorganic materials 0.000 description 2
229910001424 calcium ion Inorganic materials 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
238000009833 condensation Methods 0.000 description 2
230000005494 condensation Effects 0.000 description 2
239000000428 dust Substances 0.000 description 2
150000002170 ethers Chemical class 0.000 description 2
239000008187 granular material Substances 0.000 description 2
230000002209 hydrophobic effect Effects 0.000 description 2
CBOIHMRHGLHBPB-UHFFFAOYSA-N hydroxymethyl Chemical compound O[CH2] CBOIHMRHGLHBPB-UHFFFAOYSA-N 0.000 description 2
229920000058 polyacrylate Polymers 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
238000005507 spraying Methods 0.000 description 2
239000000126 substance Substances 0.000 description 2
150000003467 sulfuric acid derivatives Chemical group 0.000 description 2
238000005406 washing Methods 0.000 description 2
YGUMVDWOQQJBGA-VAWYXSNFSA-N 5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical group C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S(O)(=O)=O)C(S(=O)(=O)O)=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 YGUMVDWOQQJBGA-VAWYXSNFSA-N 0.000 description 1
229910017090 AlO 2 Inorganic materials 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical group OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
MBBZMMPHUWSWHV-BDVNFPICSA-N N-methylglucamine Chemical compound CNC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO MBBZMMPHUWSWHV-BDVNFPICSA-N 0.000 description 1
229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
229910004298 SiO 2 Inorganic materials 0.000 description 1
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
229920002472 Starch Polymers 0.000 description 1
ZUBJEHHGZYTRPH-KTKRTIGZSA-N [(z)-octadec-9-enyl] hydrogen sulfate Chemical compound CCCCCCCC\C=C/CCCCCCCCOS(O)(=O)=O ZUBJEHHGZYTRPH-KTKRTIGZSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
230000009471 action Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
150000004996 alkyl benzenes Chemical class 0.000 description 1
150000008051 alkyl sulfates Chemical class 0.000 description 1
125000002947 alkylene group Chemical group 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical class OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
239000003093 cationic surfactant Substances 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
239000002178 crystalline material Substances 0.000 description 1
238000005520 cutting process Methods 0.000 description 1
230000002950 deficient Effects 0.000 description 1
230000003111 delayed effect Effects 0.000 description 1
238000000280 densification Methods 0.000 description 1
238000001035 drying Methods 0.000 description 1
UZABCLFSICXBCM-UHFFFAOYSA-N ethoxy hydrogen sulfate Chemical class CCOOS(O)(=O)=O UZABCLFSICXBCM-UHFFFAOYSA-N 0.000 description 1
238000004299 exfoliation Methods 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
150000002193 fatty amides Chemical class 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
235000013305 food Nutrition 0.000 description 1
238000001879 gelation Methods 0.000 description 1
150000002314 glycerols Chemical class 0.000 description 1
238000005469 granulation Methods 0.000 description 1
230000003179 granulation Effects 0.000 description 1
125000001165 hydrophobic group Chemical group 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
CQDGTJPVBWZJAZ-UHFFFAOYSA-N monoethyl carbonate Chemical class CCOC(O)=O CQDGTJPVBWZJAZ-UHFFFAOYSA-N 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
230000001151 other effect Effects 0.000 description 1
235000014366 other mixer Nutrition 0.000 description 1
239000005022 packaging material Substances 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
229920000151 polyglycol Polymers 0.000 description 1
239000010695 polyglycol Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
230000009467 reduction Effects 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
229940071089 sarcosinate Drugs 0.000 description 1
229920002545 silicone oil Polymers 0.000 description 1
229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
238000005063 solubilization Methods 0.000 description 1
230000007928 solubilization Effects 0.000 description 1
239000002904 solvent Substances 0.000 description 1
235000019698 starch Nutrition 0.000 description 1
239000008107 starch Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
- C11D11/0088—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads the liquefied ingredients being sprayed or adsorbed onto solid particles

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)

ES96201854T 1996-07-04 1996-07-04 Proceso para la fabricar composiciones detergentes. Expired - Lifetime ES2253747T3 (es)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
EP96201854A EP0816485B1 (en)	1996-07-04	1996-07-04	Process for making detergent compositions

Publications (1)

Publication Number	Publication Date
ES2253747T3 true ES2253747T3 (es)	2006-06-01

Family

ID=8224140

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
ES96201854T Expired - Lifetime ES2253747T3 (es)	1996-07-04	1996-07-04	Proceso para la fabricar composiciones detergentes.

Country Status (10)

Country	Link
EP (1)	EP0816485B1 (ja)
JP (1)	JPH11514033A (ja)
CN (1)	CN1195834C (ja)
AR (1)	AR008062A1 (ja)
AT (1)	ATE312901T1 (ja)
BR (1)	BR9710199A (ja)
CA (1)	CA2259535C (ja)
DE (1)	DE69635575T2 (ja)
ES (1)	ES2253747T3 (ja)
WO (1)	WO1998001520A2 (ja)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6156718A (en) *	1996-07-04	2000-12-05	The Procter & Gamble Company	Process for making detergent compositions
US6906022B1 (en) *	1998-09-25	2005-06-14	The Procter & Gamble Company	Granular detergent compositions having homogenous particles and process for producing same
AU9585098A (en) *	1998-09-25	2000-04-17	Procter & Gamble Company, The	Granular detergent composition having improved appearance and solubility
CA2343810A1 (en) *	1998-09-25	2000-04-06	Jacqueline Westfield	Granular detergent composition having improved appearance and solubility
US6964945B1 (en)	1998-09-25	2005-11-15	The Procter & Gamble Company	Solid detergent compositions
US6673766B1 (en) *	1998-09-25	2004-01-06	The Procter & Gamble Company	Solid detergent compositions containing mixtures of surfactant/builder particles
JP2003527455A (ja) *	1998-09-25	2003-09-16	ザ、プロクター、エンド、ギャンブル、カンパニー	改善された溶解度特性を有する粒状洗剤組成物
JP2002528600A (ja)	1998-10-26	2002-09-03	ザ、プロクター、エンド、ギャンブル、カンパニー	外観と溶解性の改良された粒状洗剤組成物の製造方法
EP1104804B1 (en) *	1999-06-14	2005-04-20	Kao Corporation	Method for producing single nucleus detergent particles
CN1200999C (zh) *	1999-06-21	2005-05-11	宝洁公司	制造粒状洗涤剂组合物的方法
US6833346B1 (en) *	1999-06-21	2004-12-21	The Procter & Gamble Company	Process for making detergent particulates
US6951837B1 (en)	1999-06-21	2005-10-04	The Procter & Gamble Company	Process for making a granular detergent composition
GB0111863D0 (en) *	2001-05-15	2001-07-04	Unilever Plc	Granular composition
DE102006029007A1 (de) *	2006-06-24	2008-01-03	Cognis Ip Management Gmbh	Feste Tenside in granularer Form

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4136051A (en) *	1974-02-25	1979-01-23	Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa)	Pourable washing compositions containing a luminosilicates and non-ionics and method for their preparation
JPS6189300A (ja) *	1984-10-09	1986-05-07	ライオン株式会社	非イオン界面活性剤を含む粒状洗剤組成物の製造方法
TW240243B (ja) *	1992-03-12	1995-02-11	Kao Corp
DE4209435A1 (de) *	1992-03-24	1993-09-30	Henkel Kgaa	Granulares, nichtionische Tenside enthaltendes, phosphatfreies Additiv für Wasch- und Reinigungsmittel
TR27586A (tr) *	1992-09-01	1995-06-13	Procter & Gamble	Yüksek yogunlukla zerre deterjanin yapilmasi icin islem ve islem ile yapilan bilesimler.

1996
- 1996-07-04 AT AT96201854T patent/ATE312901T1/de not_active IP Right Cessation
- 1996-07-04 DE DE69635575T patent/DE69635575T2/de not_active Expired - Fee Related
- 1996-07-04 EP EP96201854A patent/EP0816485B1/en not_active Expired - Lifetime
- 1996-07-04 ES ES96201854T patent/ES2253747T3/es not_active Expired - Lifetime
1997
- 1997-06-27 BR BR9710199-0A patent/BR9710199A/pt not_active IP Right Cessation
- 1997-06-27 JP JP10505241A patent/JPH11514033A/ja active Pending
- 1997-06-27 CN CNB971973946A patent/CN1195834C/zh not_active Expired - Fee Related
- 1997-06-27 CA CA002259535A patent/CA2259535C/en not_active Expired - Fee Related
- 1997-06-27 WO PCT/US1997/011281 patent/WO1998001520A2/en active Application Filing
- 1997-07-03 AR ARP970102992A patent/AR008062A1/es unknown

Also Published As

Publication number	Publication date
WO1998001520A2 (en)	1998-01-15
BR9710199A (pt)	1999-11-23
CA2259535C (en)	2002-10-01
DE69635575T2 (de)	2006-09-14
AR008062A1 (es)	1999-12-09
CN1332790A (zh)	2002-01-23
CN1195834C (zh)	2005-04-06
DE69635575D1 (de)	2006-01-19
ATE312901T1 (de)	2005-12-15
EP0816485A1 (en)	1998-01-07
JPH11514033A (ja)	1999-11-30
EP0816485B1 (en)	2005-12-14
CA2259535A1 (en)	1998-01-15

Publication	Publication Date	Title
ES2253747T3 (es)	2006-06-01	Proceso para la fabricar composiciones detergentes.
CA1325944C (en)	1994-01-11	Detergent granules from cold dough using fine dispersion granulation
ES2346671T3 (es)	2010-10-19	Composicion detergente para lavado de ropa, solida, muy soluble en el agua que forma una disolucion de lavado transparente al disolverla en agua.
ES2208709T3 (es)	2004-06-16	Agentes de lavado y de limpieza con iminodisuccinatos.
AU651732B2 (en)	1994-07-28	Detergent powder comprising particulate citric acid and a process for its production
US5945395A (en)	1999-08-31	Method for producing nonionic detergent granules
CA2412252C (en)	2013-01-08	Post-added .alpha.-sulfofatty acid ester compositions and methods of making and using the same
JP2007522336A (ja)	2007-08-09	アニオン性洗浄性界面活性剤、スルファミン酸及び／又はその水溶性塩類を含む洗濯洗剤組成物
JPH05331497A (ja)	1993-12-14	タブレット型洗剤組成物
JPH06102794B2 (ja)	1994-12-14	洗剤組成物
ES2202343T3 (es)	2004-04-01	Procedimiento para preparar detergentes en granulos.
ES2420761T3 (es)	2013-08-26	Procedimiento de producción de partículas de detergente de núcleo único
JP5795993B2 (ja)	2015-10-14	粒状洗剤の製造方法
JP2007522335A (ja)	2007-08-09	アニオン性洗浄性界面活性剤、スルファミン酸及びその水溶性塩類を含む洗濯洗剤組成物
US6156718A (en)	2000-12-05	Process for making detergent compositions
US5998356A (en)	1999-12-07	Process for making granular detergents
JP2013249384A (ja)	2013-12-12	粒状洗剤及びその製造方法
JPH06506720A (ja)	1994-07-28	洗剤組成物で有用な界面活性剤粒状物を調整するための高活性ペーストの凝集法
JPH1121585A (ja)	1999-01-26	洗浄剤組成物
JP3161710B2 (ja)	2001-04-25	界面活性剤組成物
JPH1112593A (ja)	1999-01-19	洗浄剤組成物
CN104884600B (zh)	2018-06-15	衣料用粉末洗涤剂组合物
JP4889870B2 (ja)	2012-03-07	衣料用粉末洗剤組成物
CN103108948A (zh)	2013-05-15	洗涤剂颗粒群的制造方法
JP2018065973A (ja)	2018-04-26	粒状洗剤