CN102477319A

CN102477319A - Emulsion cleaning gasoline with environmental protection and energy saving

Info

Publication number: CN102477319A
Application number: CN2010105619490A
Authority: CN
Inventors: 张朝斌; 张筌
Original assignee: Individual
Current assignee: Individual
Priority date: 2010-11-21
Filing date: 2010-11-21
Publication date: 2012-05-30

Abstract

The invention relates to an emulsion cleaning gasoline with environmental protection and energy saving, which is prepared by mixing an emulsifier, a dispersant, an antiseptic, a stabilizing agent, a pour-point depressant, a lubricant, a high energy catalyst, a reducing agent, a mixed surfactant, an additive oleic acid and polyhydric alcohol amine, ethanolamine, sodium hydroxide and potassium hydroxide with neutral pH value, water-soluble metal salt sulfate, nitrate and chlorate, water-soluble polymer polymer polyvinyl alcohol and water in proportion under the normal temperature condition. The product is light yellow liquid which is clear and transparent. The emulsion cleaning gasoline has the advantages of easy raw material acquisition, simple technology, good stability, strong power, reliable usage, energy saving, environmental protection, no three wastes discharge, no corrosion on engine and the like. The emulsion cleaning gasoline is characterized in that the color is clear and transparent, and the emulsion cleaning gasoline enables intersolubility with any gasoline.

Description

A kind of can environmental protection, energy-conservation emulsification clean type gasoline

The present invention relates to a kind of can environmental protection, energy-conservation emulsification clean type gasoline.

The emulsification cleaning technique of gasoline for a period of time, and are not known, and it is perfect that its application does not also reach.Particularly as the fuel of motor vehicle.Up to the technical requirements of also failing to reach of the gasoline of today after emulsification technical indicator and performance in every respect, also exist shortcoming in many ways.Like oily water separation, it is insufficient to burn, and cylinder is had corrosion, and the flue gas of discharge also has the black smoke phenomenon, and winter is not antifreeze etc.Thereby influenced the popularization of emulsion gasoline.For save energy, safeguard environmental protection, the emulsification cleaning technique and the quality upgrading of gasoline are imperative.

The present invention a kind of can environmental protection, energy-conservation emulsification clean type gasoline, remedy and improved above-mentioned many-sided deficiency.Especially from conservation, reduce cost and take as the leading factor.Raw material is carried out preferably making a kind of raw material that pleiotropy arranged, and the consumption of two kinds of raw materials is combined into a kind of amount of raw material.As select emulsifying agent for use, and not only have emulsifying property, also have combustion-supporting, anticorrosion and the cleaning dispersiveness.Pour point depressant not only has freeze-proof, has stability and smoke elimination pour point depression property simultaneously.

The present invention a kind of can environmental protection, energy-conservation emulsification clean type gasoline, by emulsifying agent aniorfic surfactant dodecylbenzene sulfonate, non-ionics sorbitol ester and T 46155 dehydration sorbitol ester and can improve the water-soluble metal salt of calorific value.Wherein dodecylbenzene sulfonate is its sodium salt, magnesium salts or amine salt.Dehydration mountain multitude's sugar alcohol is for being the series product (like Span-80, this dish-60, Span-65, this dish-85, Span-83, this dish-40, this dish-20) of trade(brand)name with this dish.Soxylat A 25-7 dehydration sorbitol ester is for being the series product (like tween-80, Tween-60, tween 20) of trade(brand)name with the tween.Water-soluble metal salt can be the vitriol of the water-soluble iron of ability, aluminium, cobalt, potassium, copper.Or the nitrate salt of water-soluble iron, aluminium, cobalt, nickel, calcium, magnesium, sodium, potassium.Or muriate and oxymuriate that can be water-soluble, comprise the oxymuriate of iron, cobalt, calcium, potassium, sodium, nickel, tin, lithium.

Cleaning is disperseed Ji: the low-carbon alcohol of terepthaloyl moietie, USP Kosher, Virahol, Ucar 35.

Sanitas: N, N-two salicyls-1.2 propyl diamine.

Ignition dope: methane, ethane, propane, butane.

Solubilising smoke suppressor: benzene, YLENE and dimethyl benzene and ferrocene.

Stablizer: be polyhydric alcohol amine (Monoethanolamine MEA BASF, diethylolamine, trolamine, tetrem hydramine), polyoxyethylene nonylphenol and thanomin.

Solubilizing agent: oleic acid, comprise animal oleic acid and vegetable oil acid, can add a little sodium hydroxide and Pottasium Hydroxide for regulating pH value.

Pour point depressant: be alkylnaphthalene, prevent to solidify, improve number number of gasoline, increase rate of utilization because of the low gasoline of temperature adds water.

Mixed surfactant: the mixture that is AEO and diglycollic amide; Its intramolecularly contains hydrophilic group and oleophilic group; Can reduce surface tension and incompatible biphase interfacial energy makes oil-water emulsion; Form water in oil fine particle, emulsify well can not produce separation phenomenon.

Reductive agent: secondary octanol, propyl carbinol, isopropylcarbinol, the trimethyl carbinol, primary isoamyl alcohol.

Additive: Triple Pressed Stearic Acid alkylolamide and high molecular weight water soluble polymer Vilaterm alcohol and water.

After under normal temperature condition, putting into the container proportional mixing, stir, churning time 2-10min regulates pH value to 7-7.8, can make as clear as crystal emulsification clean type gasoline, and is the same with commercial gasoline with transparency with present gasoline colourity.Through the synthetic emulsification clean type gasoline of the present invention, have emulsifying property and stablize, fuel value is high, and it is more complete to burn; Transparency and colourity are good, and dynamic performance is strong, and technology is simple, and is easy to use; Be easy to promote, oil-saving effect is remarkable, and oilness is good, is difficult for forming carbon deposit; Equipment is not had wearing and tearing, and smoke intensity and obnoxious flavour content descend significantly, and oil circuit and atomizing nozzle are had self-cleaning function, and sulphur content is low in the no black smoke discharging tail gas; Flue dust and hydrocarbon polymer reduce, and can deposit more than 1 year, and bleed, nondiscoloration, no colloid do not produce compliance with environmental protection requirements.

The present invention a kind of can environmental protection, energy-conservation emulsification clean type gasoline, its preferred plan is following: emulsifying agent comprises the AS dodecylbenzene sulfonate, nonionogenic tenside dehydration sorbitol ester is for being the series product of trade(brand)name with this dish.T 46155 dehydration sorbitol ester is for being the series product of trade(brand)name with the tween, detergent dispersant, ignition dope, stablizer, smoke suppressor, reductive agent, pour point depressant, lubricant, high-energy catalyst, mixed surfactant.Water-soluble metal salt comprises vitriol, nitrate salt and chlorate, also has high molecular weight water soluble polymer Vilaterm alcohol and water.

The present invention a kind of can environmental protection, energy-conservation emulsification clean type gasoline, the raw material technology that is easy to get is simple, good stability, cold starting is fast, dynamic performance is strong, exhaust emissions does not have black smoke, is adapted to suitability for industrialized production.

The emulsification clean type gasoline of manufacturing of the present invention is as clear as crystal light yellow liquid, and various physical indexs are similar with natural gasoline with chemical index, is widely used in all gasoline-fueled engineering machinery, vehicle etc.; Use its engine power performance of emulsification clean type gasoline not have change, mover is had no side effect, rate of economizing gasoline reaches 20%-30%; Smoke intensity reduces 40%, and the exhaust emissions obnoxious flavour reduces 60%, and oil is not separated more than 1 year stationary phase; And can dissolve each other general with natural gasoline; Can obviously reduce carbon deposit, prolong mover work-ing life, the power of mover remains unchanged; Thereby possess internal raising gasoline various aspects of performance, externally have the effect that reduces discharging environmental protection.

Claims

1. an ability environmental protection, energy-conservation emulsification clean type gasoline is characterized in that by emulsifying agent aniorfic surfactant dodecylbenzene sulfonate non-ionics sorbitol ester and T 46155 dehydration sorbitol ester and the water-soluble metal salt that can improve calorific value; Wherein dodecylbenzene sulfonate is its sodium salt, magnesium salts or amine salt, and dehydration mountain multitude's sugar alcohol is for being the series product (like Span-80, this dish-60, Span-65, this dish-85, Span-83, this dish-40, this dish-20) of trade(brand)name with this dish, and Soxylat A 25-7 dehydration sorbitol ester is for being the series product (like tween-80, Tween-60, tween 20) of trade(brand)name with the tween; Water-soluble metal salt can be iron, aluminium, cobalt, potassium that can be water-soluble, the vitriol of copper, or the nitrate salt of water-soluble iron, aluminium, cobalt, nickel, calcium, magnesium, sodium, potassium, or muriate and oxymuriate that can be water-soluble; The oxymuriate that comprises iron, cobalt, calcium, potassium, sodium, nickel, tin, lithium, cleaning is disperseed Ji: the low-carbon alcohol of terepthaloyl moietie, USP Kosher, Virahol, Ucar 35, sanitas: N; N-two salicyls-1.2 propyl diamine, ignition dope: methane, ethane, propane, butane, solubilising smoke suppressor: benzene, YLENE and dimethyl benzene and ferrocene; Stablizer: be polyhydric alcohol amine (Monoethanolamine MEA BASF, diethylolamine, trolamine, tetrem hydramine), polyoxyethylene nonylphenol and thanomin, solubilizing agent: oleic acid; Comprise animal oleic acid and vegetable oil acid; Can add a little sodium hydroxide and Pottasium Hydroxide, pour point depressant for regulating pH value: be alkylnaphthalene, prevent to solidify because of the low gasoline of temperature adds water; Improve number number of gasoline; Increase rate of utilization, mixed surfactant: be the mixture of AEO and diglycollic amide, its intramolecularly contains hydrophilic group and oleophilic group; Can reduce surface tension and incompatible biphase interfacial energy makes oil-water emulsion; Form water in oil fine particle, emulsify well can not produce separation phenomenon; Reductive agent: secondary octanol, propyl carbinol, isopropylcarbinol, the trimethyl carbinol, primary isoamyl alcohol; Additive: Triple Pressed Stearic Acid alkylolamide and high molecular weight water soluble polymer Z 150PH and soft water, add in proportion in the reaction kettle at normal temperatures and pressures, mix; Stirring forms, and finished product is as clear as crystal to be light yellow liquid.