CN103937569A - Method for producing water-in-oil catalyst - Google Patents
Method for producing water-in-oil catalyst Download PDFInfo
- Publication number
- CN103937569A CN103937569A CN201410177905.6A CN201410177905A CN103937569A CN 103937569 A CN103937569 A CN 103937569A CN 201410177905 A CN201410177905 A CN 201410177905A CN 103937569 A CN103937569 A CN 103937569A
- Authority
- CN
- China
- Prior art keywords
- beaker
- accounts
- glycerol
- sodium hydroxide
- oleic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 60
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 51
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 16
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 16
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000005642 Oleic acid Substances 0.000 claims abstract description 16
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 16
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 16
- 238000003756 stirring Methods 0.000 claims abstract description 16
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 10
- 238000001816 cooling Methods 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- -1 Soxylat A 25-7 Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 3
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 3
- 238000002485 combustion reaction Methods 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 abstract description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 abstract 3
- 229920000056 polyoxyethylene ether Polymers 0.000 abstract 3
- 238000010438 heat treatment Methods 0.000 abstract 2
- 239000003921 oil Substances 0.000 description 11
- 239000002283 diesel fuel Substances 0.000 description 10
- 238000000889 atomisation Methods 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical class [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000013538 functional additive Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- VKJKEPKFPUWCAS-UHFFFAOYSA-M potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Landscapes
- Catalysts (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
The invention relates to a method for producing a water-in-oil catalyst. The water-in-oil catalyst is formed by mixing oleic acid, glycerol, sodium hydroxide, triethylene diamine and polyoxyethylene ether. The method particularly comprises the following processing steps: firstly pouring the oleic acid into a beaker, wherein the oleic acid accounts for 30% of total percentage; secondly pouring the glycerol into the beaker, and uniformly stirring the glycerol as a first emulsifying agent, wherein the glycerol accounts for 10% of the total percentage; thirdly injecting the sodium hydroxide into the beaker, and uniformly stirring the sodium hydroxide as a second emulsifying agent, wherein the sodium hydroxide accounts for 20% of the total percentage; then injecting the triethylene diamine into the beaker, and uniformly stirring the triethylene diamine as a third emulsifying agent, wherein the triethylene diamine accounts for 10% of the total percentage; and finally placing the beaker on a fire for heating, adding the polyoxyethylene ether to the beaker when heating to 30 DEG C, and stirring till natural cooling to form a catalyst product, wherein the polyoxyethylene ether accounts for 30% of the total percentage. The method disclosed by the invention achieves the effects that complete combustion is realized and combustion efficiency is improved.
Description
Technical field:
Present method invention relates to a kind of working method of fuel catalyst, particularly a kind of water in oil Catalyst Production method.
Background technology:
Along with the demand for energy in the economic fast development whole world increases day by day, oil price is rising all the way also, and the fossil energy reserves of global range reduce just gradually and use the caused environmental pollution of the fossil energy large problem of facing mankind especially.Diesel oil is as the main fuel of heavy duty, often having supply falls short of demand, situation occurs, in the long run, crude oil is Nonrenewable resources, and people's environmental consciousness is more and more stronger, in diesel engine vent gas, the content of particulate matter oxynitrides and hydrocarbon polymer is very high, contaminate environment, form a kind of factor of air haze, grievous injury HUMAN HEALTH.And Medium diesel oil in the market, poor stability, profit are easily separated, are mainly that catalyst performance is poor.
In CN93110029, disclose a kind of diesel-dope, by naphthenic acid rare earth, calcium, barium, manganese, iron and stablizer (SP-400) form; Method for preparing water in oil emulsified diesel oil is disclosed in CN92103798, with oleophylic and two kinds of compound preparations of nonionogenic tenside of water; In CN95111785, disclose formula and the compound method of energy-saving emulsified diesel, by diesel oil, through Potcrate treated water, emulsifying agent and functional additive mix and blend, obtain by Homogenizing pump or colloidal mill and static mixer; In CN1303907, disclose a kind of composition, preparation method of diesel water blending high-energy catalyst and in the application of preparing on diesel oil emulsification, by mixed emulsifier, stablizer, cetane number improver and high-energy catalyst, formed.These additives all do not solve water and oil firing boiling point problem, and the boiling point of water and diesel oil is different, and water boiling point is 100 ℃, and diesel oil boiling point is 200 ℃-350 ℃, so also just do not reach perfect combustion.Long-term storage also there will be demixing phenomenon simultaneously.
Order of the present invention is to overcome the defect of prior art, and provide a kind of and can make the abundant atomization of diesel oil, perfect combustion, burning after-burner is carbon distribution not, and exhaust is the environmental protection and energy saving product innovation of over-emitting black exhaust not.Use after this high-energy catalyst, in diesel oil, can add the water of 20-30%, through catalysis emulsification, form the microemulsion of stable performance, its various performance parameters not only can be up to state standards as viscosity, cetane value and flash-point etc., and result of use is better than pure diesel oil.
Summary of the invention:
For above technological deficiency, for achieving the above object, provide a kind of water in oil Catalyst Production method, by oleic acid, glycerol, sodium hydroxide, triethylene diamine, Soxylat A 25-7, mix and form.
The technical solution adopted for the present invention to solve the technical problems is: the present invention makes little oil droplet carry out twice atomization, water-in-oil reaches perfect combustion, and its percentage composition is oleic acid 30%, glycerol 10%, sodium hydroxide 20%, triethylene 2 10%, Soxylat A 25-7 30%.
Concrete procedure of processing is as follows:
A, first in beaker, pour oleic acid into, it is 30% that oleic acid accounts for whole ratio;
B, then in beaker, pour glycerol into, it is 10% that glycerol accounts for whole ratio, and glycerol is carried out to uniform stirring as the first emulsifying agent;
C, the 3rd is again toward beaker hydrogen injecting sodium oxide, and it is 20% that sodium hydroxide accounts for whole ratio, and sodium hydroxide carries out uniform stirring as the second emulsifying agent;
D and then inject triethylene two in beaker, it is 10% that triethylene two accounts for whole ratio, triethylene two carries out uniform stirring as the 3rd emulsifying agent;
E, finally beaker is placed on fire and is heated, while being warmed to 30 ℃, add Soxylat A 25-7 again in beaker, it is 30% that Soxylat A 25-7 accounts for whole ratio, and stirs, until naturally cooling forms catalyst prod.
Beneficial effect of the present invention: make each little oil droplet carry out twice atomization, mix better evenly, reach perfect combustion, improve the effect of efficiency of combustion, reduce sulphur discharged nitrous oxides.
Accompanying drawing explanation:
Fig. 1 is theory structure schematic diagram of the present invention;
In figure, 1, oleic acid, 2, glycerol, 3, sodium hydroxide, 4, triethylene diamine, 5, Soxylat A 25-7.
Embodiment:
Working method of the present invention, by oleic acid 1, glycerol 2, sodium hydroxide 3, triethylene diamine 4, Soxylat A 25-7 5, mix and form, the present invention makes little oil droplet carry out twice atomization, water-in-oil reaches perfect combustion, and its percentage composition is oleic acid 30%, glycerol 10%, sodium hydroxide 20%, triethylene 2 10%, Soxylat A 25-7 30%.
Concrete procedure of processing is first in beaker, to pour oleic acid 1 into, and it is 30% that oleic acid 1 accounts for whole ratio; Then in beaker, pour glycerol 2 into, it is 10% that glycerol 2 accounts for whole ratio, and glycerol 2 is carried out to uniform stirring as the first emulsifying agent; The 3rd again toward beaker hydrogen injecting sodium oxide 3, and it is 20% that sodium hydroxide 3 accounts for whole ratio, and sodium hydroxide 3 carries out uniform stirring as the second emulsifying agent; And then inject triethylene 4 two in beaker, and it is 10% that triethylene 24 accounts for whole ratio, triethylene 24 carries out uniform stirring as the 3rd emulsifying agent; Finally beaker is placed on fire and is heated, while being warmed to 20 ℃, add Soxylat A 25-7 5 again in beaker, it is 30% that Soxylat A 25-7 5 accounts for whole ratio, and stirs, until naturally cooling forms catalyst prod.
Claims (4)
1. a water in oil Catalyst Production method, by oleic acid, glycerol, sodium hydroxide, triethylene diamine, Soxylat A 25-7, mix and form, its percentage composition is oleic acid 30%, glycerol 10%, sodium hydroxide 20%, triethylene 2 10%, Soxylat A 25-7 30%, it is characterized in that: concrete procedure of processing is first in beaker, to pour oleic acid into, and it is 30% that oleic acid accounts for whole ratio; Then in beaker, pour glycerol into, it is 10% that glycerol accounts for whole ratio; The 3rd again toward beaker hydrogen injecting sodium oxide, and it is 20% that sodium hydroxide accounts for whole ratio; And then injecting triethylene two in beaker, it is 10% that triethylene two accounts for whole ratio; Finally beaker is placed on fire and is heated, while being warmed to 30 ℃, add Soxylat A 25-7 again in beaker, it is 30% that Soxylat A 25-7 accounts for whole ratio, and stirs, until naturally cooling forms catalyst prod.
2. water in oil Catalyst Production method according to claim 1, described carries out uniform stirring using glycerol as the first emulsifying agent.
3. water in oil Catalyst Production method according to claim 1, described sodium hydroxide carries out uniform stirring as the second emulsifying agent.
4. water in oil Catalyst Production method according to claim 1, described triethylene two carries out uniform stirring as the 3rd emulsifying agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410177905.6A CN103937569B (en) | 2014-04-24 | 2014-04-24 | The production method of Water-In-Oil catalyst |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410177905.6A CN103937569B (en) | 2014-04-24 | 2014-04-24 | The production method of Water-In-Oil catalyst |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103937569A true CN103937569A (en) | 2014-07-23 |
| CN103937569B CN103937569B (en) | 2017-05-31 |
Family
ID=51185450
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410177905.6A Expired - Fee Related CN103937569B (en) | 2014-04-24 | 2014-04-24 | The production method of Water-In-Oil catalyst |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103937569B (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102295976A (en) * | 2011-07-13 | 2011-12-28 | 李胜 | Lubricant for heavy-load machining of metals and preparation method thereof |
| CN102477319A (en) * | 2010-11-21 | 2012-05-30 | 张朝斌 | Emulsion cleaning gasoline with environmental protection and energy saving |
-
2014
- 2014-04-24 CN CN201410177905.6A patent/CN103937569B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102477319A (en) * | 2010-11-21 | 2012-05-30 | 张朝斌 | Emulsion cleaning gasoline with environmental protection and energy saving |
| CN102295976A (en) * | 2011-07-13 | 2011-12-28 | 李胜 | Lubricant for heavy-load machining of metals and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103937569B (en) | 2017-05-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104479770B (en) | Novel ethers clean diesel is mixed imitation frosted glass, is contained this clean diesel of mixing imitation frosted glass and preparation method | |
| CN106497616A (en) | Environment protection biological fuel | |
| CN102041116A (en) | Energy-saving and environment-friendly diesel fuel additive | |
| CN102485854A (en) | Formula for emulsified diesel oil | |
| CN103254952B (en) | A kind of preparation of water base micro-emulsion diesel | |
| CN103980964B (en) | A kind of preparation method of tourmaline fuel activating agent | |
| CN104593105B (en) | A kind of high-clean gasoline additive and preparation method thereof | |
| CN103937569A (en) | Method for producing water-in-oil catalyst | |
| CN106566584B (en) | A kind of compound additive for methanol gasoline and the preparation method and application thereof | |
| CN101775318A (en) | Micro-emulsion clean fuel and preparation method thereof | |
| CN101434875A (en) | Ethanol-diesel mixed fuel formula | |
| CN101328424B (en) | Formula of biomass emulsified diesel oil | |
| CN103571547A (en) | Method for preparing ethanol-diesel oil mixed fuel | |
| CN102719284A (en) | Renewable swill-cooked dirty fuel oil | |
| CN106190352A (en) | A kind of lignocellulose base γ valerolactone diesel oil mediation fuel and preparation method thereof | |
| CN102229821A (en) | Micro-emulsified methanol diesel and preparation method thereof | |
| CN102643685B (en) | High-energy organic fuel capable of being mixed with diesel oil at will | |
| CN105441147A (en) | Gasoline additive and preparation method thereof | |
| CN103805299B (en) | Methyl alcohol emulsified diesel oil and preparation method thereof | |
| CN106398741B (en) | A kind of environment-friendly fuel and its preparation method and application | |
| CN104845686B (en) | Formula of diesel oil micro-emulsified complexing agent and preparation method of emulsified diesel oil | |
| CN116445191B (en) | Preparation method of renewable alternative fuel | |
| CN103937570B (en) | The processing method of new mixed diesel | |
| CN102899110A (en) | Energy-saving and environment-friendly watered diesel oil | |
| CN102002404A (en) | High-cleaning composite gasoline and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20140723 Assignee: TIANJIN GUOCHAI NEW ENERGY TECHNOLOGY Co.,Ltd. Assignor: Zhu Wenlei Contract record no.: 2018120000008 Denomination of invention: Method for producing water-in-oil catalyst Granted publication date: 20170531 License type: Exclusive License Record date: 20180725 |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20170531 |