CN107227181A - Gasoline additive and preparation method thereof - Google Patents
Gasoline additive and preparation method thereof Download PDFInfo
- Publication number
- CN107227181A CN107227181A CN201710308542.9A CN201710308542A CN107227181A CN 107227181 A CN107227181 A CN 107227181A CN 201710308542 A CN201710308542 A CN 201710308542A CN 107227181 A CN107227181 A CN 107227181A
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- CN
- China
- Prior art keywords
- parts
- oil
- gasoline additive
- ether
- alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003254 gasoline additive Substances 0.000 title claims abstract description 94
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical group CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 claims abstract description 74
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical group CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 claims abstract description 74
- BBMCTIGTTCKYKF-UHFFFAOYSA-N 1-heptanol Chemical group CCCCCCCO BBMCTIGTTCKYKF-UHFFFAOYSA-N 0.000 claims abstract description 48
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 48
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical group CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims abstract description 48
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 46
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical group C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims abstract description 46
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical group CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims abstract description 46
- -1 succimide Chemical compound 0.000 claims abstract description 46
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical group CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 claims abstract description 46
- QNLZIZAQLLYXTC-UHFFFAOYSA-N 1,2-dimethylnaphthalene Chemical group C1=CC=CC2=C(C)C(C)=CC=C21 QNLZIZAQLLYXTC-UHFFFAOYSA-N 0.000 claims abstract description 44
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 37
- 229930195729 fatty acid Natural products 0.000 claims abstract description 37
- 239000000194 fatty acid Substances 0.000 claims abstract description 37
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical group COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims abstract description 35
- 239000002994 raw material Substances 0.000 claims abstract description 26
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Chemical group CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 24
- GWHJZXXIDMPWGX-UHFFFAOYSA-N 1,2,4-trimethylbenzene Chemical group CC1=CC=C(C)C(C)=C1 GWHJZXXIDMPWGX-UHFFFAOYSA-N 0.000 claims abstract description 24
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Chemical group CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 24
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Chemical group CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000005642 Oleic acid Chemical group 0.000 claims abstract description 24
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Chemical group CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 24
- TWXWPPKDQOWNSX-UHFFFAOYSA-N dicyclohexylmethanone Chemical compound C1CCCCC1C(=O)C1CCCCC1 TWXWPPKDQOWNSX-UHFFFAOYSA-N 0.000 claims abstract description 24
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Chemical group CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims abstract description 24
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims abstract description 24
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical group CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 24
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims abstract description 24
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 80
- 238000003756 stirring Methods 0.000 claims description 25
- 238000005119 centrifugation Methods 0.000 claims description 22
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 20
- 235000019486 Sunflower oil Nutrition 0.000 claims description 17
- 239000010495 camellia oil Substances 0.000 claims description 17
- 239000003813 safflower oil Substances 0.000 claims description 17
- 239000008159 sesame oil Substances 0.000 claims description 17
- 235000011803 sesame oil Nutrition 0.000 claims description 17
- 239000002600 sunflower oil Substances 0.000 claims description 17
- 235000019774 Rice Bran oil Nutrition 0.000 claims description 16
- 239000008165 rice bran oil Substances 0.000 claims description 16
- 235000019482 Palm oil Nutrition 0.000 claims description 15
- 239000002540 palm oil Substances 0.000 claims description 15
- 239000000706 filtrate Substances 0.000 claims description 13
- 238000007789 sealing Methods 0.000 claims description 13
- 238000010792 warming Methods 0.000 claims description 13
- 239000003921 oil Substances 0.000 claims description 9
- 235000019198 oils Nutrition 0.000 claims description 9
- QUTGXAIWZAMYEM-UHFFFAOYSA-N 2-cyclopentyloxyethanamine Chemical compound NCCOC1CCCC1 QUTGXAIWZAMYEM-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 150000003949 imides Chemical class 0.000 claims description 4
- FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-naphthoquinone Chemical group C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 claims description 2
- 125000002730 succinyl group Chemical group C(CCC(=O)*)(=O)* 0.000 claims description 2
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 claims 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims 2
- QNLVXLJTOLHAMA-UHFFFAOYSA-N N=NC=NN.N=NC=NN.C(O)(O)=O Chemical compound N=NC=NN.N=NC=NN.C(O)(O)=O QNLVXLJTOLHAMA-UHFFFAOYSA-N 0.000 claims 1
- 235000021314 Palmitic acid Nutrition 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 239000000835 fiber Substances 0.000 claims 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 claims 1
- 239000000446 fuel Substances 0.000 abstract description 11
- 239000000463 material Substances 0.000 abstract description 7
- 230000007613 environmental effect Effects 0.000 abstract description 5
- 230000009467 reduction Effects 0.000 abstract description 5
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 18
- 238000002156 mixing Methods 0.000 description 12
- 238000010438 heat treatment Methods 0.000 description 11
- 229910052799 carbon Inorganic materials 0.000 description 9
- 239000003502 gasoline Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 5
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000000295 fuel oil Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- QBUKAFSEUHGMMX-MTJSOVHGSA-N (5z)-5-[[3-(1-hydroxyethyl)thiophen-2-yl]methylidene]-10-methoxy-2,2,4-trimethyl-1h-chromeno[3,4-f]quinolin-9-ol Chemical group C1=CC=2NC(C)(C)C=C(C)C=2C2=C1C=1C(OC)=C(O)C=CC=1O\C2=C/C=1SC=CC=1C(C)O QBUKAFSEUHGMMX-MTJSOVHGSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- DJOWTWWHMWQATC-KYHIUUMWSA-N Karpoxanthin Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1(O)C(C)(C)CC(O)CC1(C)O)C=CC=C(/C)C=CC2=C(C)CC(O)CC2(C)C DJOWTWWHMWQATC-KYHIUUMWSA-N 0.000 description 1
- 241000209094 Oryza Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000010903 husk Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/18—Use of additives to fuels or fires for particular purposes use of detergents or dispersants for purposes not provided for in groups C10L10/02 - C10L10/16
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/16—Hydrocarbons
- C10L1/1608—Well defined compounds, e.g. hexane, benzene
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
- C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
- C10L1/1826—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms poly-hydroxy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
- C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
- C10L1/1857—Aldehydes; Ketones
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/188—Carboxylic acids; metal salts thereof
- C10L1/1881—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
- C10L1/1905—Esters ester radical containing compounds; ester ethers; carbonic acid esters of di- or polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/232—Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
- C10L2230/22—Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
The present invention relates to gasoline additive and preparation method thereof, the gasoline additive includes the following raw material：Isopropanol, isobutanol, isoamyl alcohol, n-heptanol, n-octyl alcohol, n-dodecanol, tetradecanol, naphthalene, 1,2,4 trimethylbenzenes, dimethylbenzene, dimethylnaphthalene, oleic acid, amyl group dicyclohexyl ketone, succimide, triethylene glycol, sorbierite, fatty acid amine, ether, dimethyl carbonate and dimethyl ether.The present invention gasoline additive, largely reduce oil consumption so that fuel economy be improved significantly, in addition, the present invention gasoline additive to reduction NOxGeneration there is material impact, promote the use of the present invention gasoline additive to environmental protection tool have very important significance.The addition of especially bio-based has to fuel economy further to be improved, while also reducing NOxConcentration, with good commercial promise.
Description
Technical field
The present invention relates to a kind of gasoline additive and preparation method thereof.
Background technology
Petroleum resources are nervous, energy scarcity, how to solve the research topic that energy deficiency has become countries in the world attention.
Automobile is one of main means of transport, effective alternative energy resources fail to be widely popularized it is present, gasoline is still main automobile-used
Fuel, buying car easily, is maintained the car expensive, increasingly elevated oil price, the high maintenance cost of repairs, how to save fuel oil, reduces expense, day
Gradually turn into the emphasis of public concern, while people are directed to engine improvement, also attempt to change by addition gasoline additive
The performance of kind gasoline quality, increase automobile, reduces the cost of use of vehicle.
In order to improve the combustion rate of gasoline, reduce pollution of the vehicle exhaust to environment, the existing many different types of in the market
Gasoline additive chemical products.Although current various gasoline additive species are various, there are many shortcomings, such as additive work(
Can be single, combustion adjuvant is without except carbon effect, and decarbonizer uses also effect with not good again without oil-saving effect；Additive is not obvious, section
Oily effect is not notable, and cleaning effect is not good, lacks lubrication care action, exhaust emissions is not improved.
The content of the invention
It is an object of the present invention to propose a kind of gasoline additive.
A kind of gasoline additive of the present invention, includes the raw material of following parts by weight：30 parts~50 parts of isopropanol, isobutanol
10 parts~30 parts, 15 parts~25 parts of isoamyl alcohol, 1 part~10 parts of n-heptanol, 20 parts~30 parts of n-octyl alcohol, n-dodecanol 3 parts~10
Part, 5 parts~15 parts of tetradecanol, 1 part~10 parts of naphthalene, 5 parts~15 parts of 1,2,4- trimethylbenzenes, 3 parts~15 parts of dimethylbenzene, diformazan
20 parts~40 parts of base naphthalene, 30 parts~50 parts of oleic acid, 20 parts~30 parts of amyl group dicyclohexyl ketone, 10 parts~25 parts of succimide,
1 part~15 parts of triethylene glycol, 10 parts~20 parts of sorbierite, 1 part~15 parts of fatty acid amine, 10 parts~20 parts of ether, dimethyl carbonate
30 parts~40 parts and 10 parts~30 parts of dimethyl ether.
The present invention gasoline additive, largely reduce oil consumption so that fuel economy be improved significantly,
In addition, the gasoline additive of the present invention is to reduction NOxGeneration there is material impact, promote the use of the present invention gasoline additive
Have very important significance to environmental protection tool.Especially the addition of bio-based has to fuel economy further improves and carries
Height, while also reducing NOxConcentration, with good commercial promise.
In addition, according to the above-mentioned gasoline additive of the present invention, can also have technical characteristic additional as follows：
Further, described gasoline additive, includes the raw material of following parts by weight：Palm oil 1 part~10 part, meter
10 parts~20 parts of oil extracted from rice husks, 1 part~10 parts of sunflower oil, 20 parts~30 parts of tea-seed oil, 0.1 part~2 parts of safflower seed oil and sesame oil
0.05 part~3 parts.
As the preferred embodiment of the present invention, described gasoline additive includes the raw material of following parts by weight：Isopropyl
30 parts of alcohol, 30 parts of isobutanol, 15 parts of isoamyl alcohol, 10 parts of n-heptanol, 20 parts of n-octyl alcohol, 10 parts of n-dodecanol, 5 parts of tetradecanol,
10 parts of naphthalene, 5 parts of 1,2,4- trimethylbenzenes, 15 parts of dimethylbenzene, 20 parts of dimethylnaphthalene, 50 parts of oleic acid, 20 parts of amyl group dicyclohexyl ketone,
25 parts of succimide, 1 part of triethylene glycol, 20 parts of sorbierite, 1 part of fatty acid amine, 20 parts of ether, 30 parts of dimethyl carbonate, diformazan
3 parts of 30 parts of ether, 1 part of palm oil, 20 parts of rice bran oil, 1 part of sunflower oil, 30 parts of tea-seed oil, 0.1 part of safflower seed oil and sesame oil.
As the preferred embodiment of the present invention, described gasoline additive includes the raw material of following parts by weight：Isopropyl
50 parts of alcohol, 10 parts of isobutanol, 25 parts of isoamyl alcohol, 1 part of n-heptanol, 30 parts of n-octyl alcohol, 3 parts of n-dodecanol, 15 parts of tetradecanol, naphthalene
1 part, 15 parts of 1,2,4- trimethylbenzenes, 3 parts of dimethylbenzene, 40 parts of dimethylnaphthalene, 30 parts of oleic acid, 30 parts of amyl group dicyclohexyl ketone, fourth
10 parts of imidodicarbonic diamide, 15 parts of triethylene glycol, 10 parts of sorbierite, 15 parts of fatty acid amine, 10 parts of ether, 40 parts of dimethyl carbonate, diformazan
10 parts of ether, 10 parts of palm oil, 10 parts of rice bran oil, 10 parts of sunflower oil, 20 parts of tea-seed oil, 2 parts of safflower seed oil and sesame oil 0.05
Part.
As the preferred embodiment of the present invention, described gasoline additive includes the raw material of following parts by weight：Isopropyl
40 parts of alcohol, 20 parts of isobutanol, 20 parts of isoamyl alcohol, 5 parts of n-heptanol, 25 parts of n-octyl alcohol, 7 parts of n-dodecanol, 10 parts of tetradecanol, naphthalene
5 parts, 10 parts of 1,2,4- trimethylbenzenes, 10 parts of dimethylbenzene, 30 parts of dimethylnaphthalene, 40 parts of oleic acid, 25 parts of amyl group dicyclohexyl ketone, fourth
17 parts of imidodicarbonic diamide, 7 parts of triethylene glycol, 15 parts of sorbierite, 8 parts of fatty acid amine, 15 parts of ether, 35 parts of dimethyl carbonate, dimethyl ether
2 parts of 20 parts, 5 parts of palm oil, 15 parts of rice bran oil, 5 parts of sunflower oil, 25 parts of tea-seed oil, 1 part of safflower seed oil and sesame oil.
As the preferred embodiment of the present invention, described gasoline additive includes the raw material of following parts by weight：Isopropyl
35 parts of alcohol, 5 parts of isobutanol, 17 parts of isoamyl alcohol, 3 parts of n-heptanol, 22 parts of n-octyl alcohol, 5 parts of n-dodecanol, 7 parts of tetradecanol, naphthalene 3
Part, 7 parts of 1,2,4- trimethylbenzenes, 6 parts of dimethylbenzene, 25 parts of dimethylnaphthalene, 35 parts of oleic acid, 22 parts of amyl group dicyclohexyl ketone, fourth two
14 parts of acid imide, 4 parts of triethylene glycol, 13 parts of sorbierite, 4 parts of fatty acid amine, 13 parts of ether, 32 parts of dimethyl carbonate, dimethyl ether 14
1.5 parts of part, 2 parts of palm oil, 13 parts of rice bran oil, 3 parts of sunflower oil, 23 parts of tea-seed oil, 0.5 part of safflower seed oil and sesame oil.
As the preferred embodiment of the present invention, described gasoline additive includes the raw material of following parts by weight：Isopropyl
45 parts of alcohol, 25 parts of isobutanol, 23 parts of isoamyl alcohol, 7 parts of n-heptanol, 27 parts of n-octyl alcohol, 8 parts of n-dodecanol, 13 parts of tetradecanol, naphthalene
8 parts, 13 parts of 1,2,4- trimethylbenzenes, 13 parts of dimethylbenzene, 35 parts of dimethylnaphthalene, 45 parts of oleic acid, 27 parts of amyl group dicyclohexyl ketone, fourth
18 parts of imidodicarbonic diamide, 12 parts of triethylene glycol, 17 parts of sorbierite, 13 parts of fatty acid amine, 17 parts of ether, 37 parts of dimethyl carbonate, diformazan
26 parts of ether, 8 parts of palm oil, 17 parts of rice bran oil, 8 parts of sunflower oil, 28 parts of tea-seed oil, 1.5 parts of safflower seed oil and sesame oil 2.55
Part.
It is another object of the present invention to the preparation method for proposing described gasoline additive.
The preparation method of described gasoline additive, comprises the following steps：S101：First, it is isopropanol, succinyl is sub-
Amine, isoamyl alcohol, ether, n-octyl alcohol and fatty acid amine mixing, sealing stirring 10min~20min, obtain the first solution；S102：Will
40 DEG C~60 DEG C are warming up to after the mixing of surplus stock component, is incubated and stirs 30min~40min, be then cooled to 0 DEG C~10 DEG C
And 1h~3h is incubated, obtain the second solution；S103：Will first solution and second solution mix after be heated to 20 DEG C~
40 DEG C, then centrifuged successively, filter operation, and collect filtrate, obtain gasoline additive.
Further, in the step S102, heating rate is 10 DEG C/min~12 DEG C/min；Rate of temperature fall be 1 DEG C/
Min~3 DEG C/min.
Further, in the step S103, the rotating speed of the centrifugally operated is 1500r/min~3500r/min, from
The time of the heart is 5min~15min.
The additional aspect and advantage of the present invention will be set forth in part in the description, and will partly become from the following description
Obtain substantially, or recognized by the practice of the present invention.
Embodiment
Embodiments of the invention are described below in detail, the embodiment is exemplary, it is intended to for explaining the present invention, and
It is not considered as limiting the invention.
It is an object of the present invention to propose a kind of gasoline additive.
Described gasoline additive, includes the raw material of following parts by weight：30 parts~50 parts of isopropanol, 10 parts of isobutanol~
30 parts, 15 parts~25 parts of isoamyl alcohol, 1 part~10 parts of n-heptanol, 20 parts~30 parts of n-octyl alcohol, 3 parts~10 parts of n-dodecanol, positive ten
5 parts~15 parts of tetrol, 1 part~10 parts of naphthalene, 5 parts~15 parts of 1,2,4- trimethylbenzenes, 3 parts~15 parts of dimethylbenzene, dimethylnaphthalene 20
Part~40 parts, 30 parts~50 parts of oleic acid, 20 parts~30 parts of amyl group dicyclohexyl ketone, 10 parts~25 parts of succimide, triethylene glycol 1
Part~15 parts, 10 parts~20 parts of sorbierite, 1 part~15 parts of fatty acid amine, 10 parts~20 parts of ether, dimethyl carbonate 30 parts~40
10 parts~30 parts of part and dimethyl ether.
The present invention gasoline additive, largely reduce oil consumption so that fuel economy be improved significantly,
In addition, the gasoline additive of the present invention is to reduction NOxGeneration there is material impact, promote the use of the present invention gasoline additive
Have very important significance to environmental protection tool.Especially the addition of bio-based has to fuel economy further improves and carries
Height, while also reducing NOxConcentration, with good commercial promise.
It is another object of the present invention to the preparation method for proposing described gasoline additive.
The preparation method of described gasoline additive, comprises the following steps：
S101：First, isopropanol, succimide, isoamyl alcohol, ether, n-octyl alcohol and fatty acid amine are mixed, sealing is stirred
10min~20min is mixed, the first solution is obtained.
S102：40 DEG C~60 DEG C are warming up to after surplus stock component is mixed, is incubated and stirs 30min~40min, then
It is cooled to 0 DEG C~10 DEG C and is incubated 1h~3h, obtains the second solution.
S103：20 DEG C~40 DEG C are heated to after first solution and second solution are mixed, is then carried out successively
Centrifugation, filter operation, and filtrate is collected, obtain gasoline additive.
The present invention is described in detail below by specific embodiment.
Embodiment 1
Embodiment 1 proposes a kind of gasoline additive, and described gasoline additive includes the raw material of following parts by weight：It is different
30 parts of propyl alcohol, 30 parts of isobutanol, 15 parts of isoamyl alcohol, 10 parts of n-heptanol, 20 parts of n-octyl alcohol, 10 parts of n-dodecanol, tetradecanol 5
Part, 10 parts of naphthalene, 5 parts of 1,2,4- trimethylbenzenes, 15 parts of dimethylbenzene, 20 parts of dimethylnaphthalene, 50 parts of oleic acid, amyl group dicyclohexyl ketone 20
Part, 25 parts of succimide, 1 part of triethylene glycol, 20 parts of sorbierite, 1 part of fatty acid amine, 20 parts of ether, 30 parts of dimethyl carbonate and
30 parts of dimethyl ether.
The preparation method of the gasoline additive of embodiment 1, comprises the following steps：
(1) first, isopropanol, succimide, isoamyl alcohol, ether, n-octyl alcohol and fatty acid amine are mixed, sealing stirring
10min, obtains the first solution.
(2) 60 DEG C are warming up to after surplus stock component is mixed, is incubated and stirs 30min, be then cooled to 10 DEG C and protect
Warm 1h, obtains the second solution；Wherein, heating rate is 10 DEG C/min, and rate of temperature fall is 3 DEG C/min.
(3) 40 DEG C are heated to after mixing first solution and second solution, is then centrifuged, filtered successively
Operation, and filtrate is collected, obtain gasoline additive；Wherein, the rotating speed of centrifugation is 1500r/min, and the time of centrifugation is
15min。
Embodiment 2
Embodiment 2 proposes a kind of gasoline additive, and described gasoline additive includes the raw material of following parts by weight：It is different
50 parts of propyl alcohol, 10 parts of isobutanol, 25 parts of isoamyl alcohol, 1 part of n-heptanol, 30 parts of n-octyl alcohol, 3 parts of n-dodecanol, 15 parts of tetradecanol,
1 part of naphthalene, 15 parts of 1,2,4- trimethylbenzenes, 3 parts of dimethylbenzene, 40 parts of dimethylnaphthalene, 30 parts of oleic acid, 30 parts of amyl group dicyclohexyl ketone,
10 parts of succimide, 15 parts of triethylene glycol, 10 parts of sorbierite, 15 parts of fatty acid amine, 10 parts of ether, 40 parts of dimethyl carbonate and two
10 parts of methyl ether.
The preparation method of the gasoline additive of embodiment 2, comprises the following steps：
(1) first, isopropanol, succimide, isoamyl alcohol, ether, n-octyl alcohol and fatty acid amine are mixed, sealing stirring
20min, obtains the first solution.
(2) 40 DEG C are warming up to after surplus stock component is mixed, is incubated and stirs 40min, be then cooled to 0 DEG C and be incubated
3h, obtains the second solution；Wherein, heating rate is 10 DEG C/min, and rate of temperature fall is 3 DEG C/min.
(3) 20 DEG C are heated to after mixing first solution and second solution, is then centrifuged, filtered successively
Operation, and filtrate is collected, obtain gasoline additive；Wherein, the rotating speed of centrifugation is 3500r/min, and the time of centrifugation is
5min。
Embodiment 3
Embodiment 3 proposes a kind of gasoline additive, and described gasoline additive includes the raw material of following parts by weight：It is different
40 parts of propyl alcohol, 20 parts of isobutanol, 20 parts of isoamyl alcohol, 5 parts of n-heptanol, 25 parts of n-octyl alcohol, 7 parts of n-dodecanol, 10 parts of tetradecanol,
5 parts of naphthalene, 10 parts of 1,2,4- trimethylbenzenes, 10 parts of dimethylbenzene, 30 parts of dimethylnaphthalene, 40 parts of oleic acid, 25 parts of amyl group dicyclohexyl ketone,
17 parts of succimide, 7 parts of triethylene glycol, 15 parts of sorbierite, 8 parts of fatty acid amine, 15 parts of ether, 35 parts of dimethyl carbonate and diformazan
20 parts of ether.
The preparation method of the gasoline additive of embodiment 3, comprises the following steps：
(1) first, isopropanol, succimide, isoamyl alcohol, ether, n-octyl alcohol and fatty acid amine are mixed, sealing stirring
15min, obtains the first solution.
(2) 50 DEG C are warming up to after surplus stock component is mixed, is incubated and stirs 35min, be then cooled to 5 DEG C and be incubated
2h, obtains the second solution；Wherein, heating rate is 11 DEG C/min, and rate of temperature fall is 2 DEG C/min.
(3) 30 DEG C are heated to after mixing first solution and second solution, is then centrifuged, filtered successively
Operation, and filtrate is collected, obtain gasoline additive；Wherein, the rotating speed of centrifugation is 2200r/min, and the time of centrifugation is
10min。
Embodiment 4
Embodiment 4 proposes a kind of gasoline additive, and described gasoline additive includes the raw material of following parts by weight：It is different
35 parts of propyl alcohol, 5 parts of isobutanol, 17 parts of isoamyl alcohol, 3 parts of n-heptanol, 22 parts of n-octyl alcohol, 5 parts of n-dodecanol, 7 parts of tetradecanol, naphthalene
3 parts, 7 parts of 1,2,4- trimethylbenzenes, 6 parts of dimethylbenzene, 25 parts of dimethylnaphthalene, 35 parts of oleic acid, 22 parts of amyl group dicyclohexyl ketone, fourth two
14 parts of acid imide, 4 parts of triethylene glycol, 13 parts of sorbierite, 4 parts of fatty acid amine, 13 parts of ether, 32 parts of dimethyl carbonate and dimethyl ether 14
Part.
The preparation method of the gasoline additive of embodiment 4, comprises the following steps：
(1) first, isopropanol, succimide, isoamyl alcohol, ether, n-octyl alcohol and fatty acid amine are mixed, sealing stirring
12min, obtains the first solution.
(2) 45 DEG C are warming up to after surplus stock component is mixed, is incubated and stirs 33min, be then cooled to 3 DEG C and be incubated
1.5h, obtains the second solution；Wherein, heating rate is 10 DEG C/min, and rate of temperature fall is 2 DEG C/min.
(3) 25 DEG C are heated to after mixing first solution and second solution, is then centrifuged, filtered successively
Operation, and filtrate is collected, obtain gasoline additive；Wherein, the rotating speed of centrifugation is 1700r/min, and the time of centrifugation is
7min。
Embodiment 5
Embodiment 5 proposes a kind of gasoline additive, and described gasoline additive includes the raw material of following parts by weight：It is different
45 parts of propyl alcohol, 25 parts of isobutanol, 23 parts of isoamyl alcohol, 7 parts of n-heptanol, 27 parts of n-octyl alcohol, 8 parts of n-dodecanol, 13 parts of tetradecanol,
8 parts of naphthalene, 13 parts of 1,2,4- trimethylbenzenes, 13 parts of dimethylbenzene, 35 parts of dimethylnaphthalene, 45 parts of oleic acid, 27 parts of amyl group dicyclohexyl ketone,
18 parts of succimide, 12 parts of triethylene glycol, 17 parts of sorbierite, 13 parts of fatty acid amine, 17 parts of ether, 37 parts of dimethyl carbonate and two
26 parts of methyl ether.
The preparation method of the gasoline additive of embodiment 5, comprises the following steps：
(1) first, isopropanol, succimide, isoamyl alcohol, ether, n-octyl alcohol and fatty acid amine are mixed, sealing stirring
17min, obtains the first solution.
(2) 55 DEG C are warming up to after surplus stock component is mixed, is incubated and stirs 38min, be then cooled to 7 DEG C and be incubated
2.5h, obtains the second solution；Wherein, heating rate is 12 DEG C/min, and rate of temperature fall is 3 DEG C/min.
(3) 34 DEG C are heated to after mixing first solution and second solution, is then centrifuged, filtered successively
Operation, and filtrate is collected, obtain gasoline additive；Wherein, the rotating speed of centrifugation is 3000r/min, and the time of centrifugation is
12min。
Embodiment 6
Embodiment 6 proposes a kind of gasoline additive, and described gasoline additive includes the raw material of following parts by weight：It is different
30 parts of propyl alcohol, 30 parts of isobutanol, 15 parts of isoamyl alcohol, 10 parts of n-heptanol, 20 parts of n-octyl alcohol, 10 parts of n-dodecanol, tetradecanol 5
Part, 10 parts of naphthalene, 5 parts of 1,2,4- trimethylbenzenes, 15 parts of dimethylbenzene, 20 parts of dimethylnaphthalene, 50 parts of oleic acid, amyl group dicyclohexyl ketone 20
Part, 25 parts of succimide, 1 part of triethylene glycol, 20 parts of sorbierite, 1 part of fatty acid amine, 20 parts of ether, 30 parts of dimethyl carbonate, two
30 parts of methyl ether, 1 part of palm oil, 20 parts of rice bran oil, 1 part of sunflower oil, 30 parts of tea-seed oil, 0.1 part of safflower seed oil and sesame oil 3
Part.
The preparation method of the gasoline additive of embodiment 6, comprises the following steps：
(1) first, isopropanol, succimide, isoamyl alcohol, ether, n-octyl alcohol and fatty acid amine are mixed, sealing stirring
10min, obtains the first solution.
(2) 60 DEG C are warming up to after surplus stock component is mixed, is incubated and stirs 30min, be then cooled to 10 DEG C and protect
Warm 1h, obtains the second solution；Wherein, heating rate is 10 DEG C/min, and rate of temperature fall is 3 DEG C/min.
(3) 40 DEG C are heated to after mixing first solution and second solution, is then centrifuged, filtered successively
Operation, and filtrate is collected, obtain gasoline additive；Wherein, the rotating speed of centrifugation is 1500r/min, and the time of centrifugation is
15min。
Embodiment 7
Embodiment 7 proposes a kind of gasoline additive, and described gasoline additive includes the raw material of following parts by weight：It is different
50 parts of propyl alcohol, 10 parts of isobutanol, 25 parts of isoamyl alcohol, 1 part of n-heptanol, 30 parts of n-octyl alcohol, 3 parts of n-dodecanol, 15 parts of tetradecanol,
1 part of naphthalene, 15 parts of 1,2,4- trimethylbenzenes, 3 parts of dimethylbenzene, 40 parts of dimethylnaphthalene, 30 parts of oleic acid, 30 parts of amyl group dicyclohexyl ketone,
10 parts of succimide, 15 parts of triethylene glycol, 10 parts of sorbierite, 15 parts of fatty acid amine, 10 parts of ether, 40 parts of dimethyl carbonate, two
10 parts of methyl ether, 10 parts of palm oil, 10 parts of rice bran oil, 10 parts of sunflower oil, 20 parts of tea-seed oil, 2 parts of safflower seed oil and sesame oil
0.05 part.
The preparation method of the gasoline additive of embodiment 7, comprises the following steps：
(1) first, isopropanol, succimide, isoamyl alcohol, ether, n-octyl alcohol and fatty acid amine are mixed, sealing stirring
20min, obtains the first solution.
(2) 40 DEG C are warming up to after surplus stock component is mixed, is incubated and stirs 40min, be then cooled to 0 DEG C and be incubated
3h, obtains the second solution；Wherein, heating rate is 10 DEG C/min, and rate of temperature fall is 3 DEG C/min.
(3) 20 DEG C are heated to after mixing first solution and second solution, is then centrifuged, filtered successively
Operation, and filtrate is collected, obtain gasoline additive；Wherein, the rotating speed of centrifugation is 3500r/min, and the time of centrifugation is
5min。
Embodiment 8
Embodiment 8 proposes a kind of gasoline additive, and described gasoline additive includes the raw material of following parts by weight：It is different
40 parts of propyl alcohol, 20 parts of isobutanol, 20 parts of isoamyl alcohol, 5 parts of n-heptanol, 25 parts of n-octyl alcohol, 7 parts of n-dodecanol, 10 parts of tetradecanol,
5 parts of naphthalene, 10 parts of 1,2,4- trimethylbenzenes, 10 parts of dimethylbenzene, 30 parts of dimethylnaphthalene, 40 parts of oleic acid, 25 parts of amyl group dicyclohexyl ketone,
17 parts of succimide, 7 parts of triethylene glycol, 15 parts of sorbierite, 8 parts of fatty acid amine, 15 parts of ether, 35 parts of dimethyl carbonate, diformazan
2 parts of 20 parts of ether, 5 parts of palm oil, 15 parts of rice bran oil, 5 parts of sunflower oil, 25 parts of tea-seed oil, 1 part of safflower seed oil and sesame oil.
The preparation method of the gasoline additive of embodiment 8, comprises the following steps：
(1) first, isopropanol, succimide, isoamyl alcohol, ether, n-octyl alcohol and fatty acid amine are mixed, sealing stirring
15min, obtains the first solution.
(2) 50 DEG C are warming up to after surplus stock component is mixed, is incubated and stirs 35min, be then cooled to 5 DEG C and be incubated
2h, obtains the second solution；Wherein, heating rate is 11 DEG C/min, and rate of temperature fall is 2 DEG C/min.
(3) 30 DEG C are heated to after mixing first solution and second solution, is then centrifuged, filtered successively
Operation, and filtrate is collected, obtain gasoline additive；Wherein, the rotating speed of centrifugation is 2200r/min, and the time of centrifugation is
10min。
Embodiment 9
Embodiment 9 proposes a kind of gasoline additive, and described gasoline additive includes the raw material of following parts by weight：It is different
35 parts of propyl alcohol, 5 parts of isobutanol, 17 parts of isoamyl alcohol, 3 parts of n-heptanol, 22 parts of n-octyl alcohol, 5 parts of n-dodecanol, 7 parts of tetradecanol, naphthalene
3 parts, 7 parts of 1,2,4- trimethylbenzenes, 6 parts of dimethylbenzene, 25 parts of dimethylnaphthalene, 35 parts of oleic acid, 22 parts of amyl group dicyclohexyl ketone, fourth two
14 parts of acid imide, 4 parts of triethylene glycol, 13 parts of sorbierite, 4 parts of fatty acid amine, 13 parts of ether, 32 parts of dimethyl carbonate, dimethyl ether 14
1.5 parts of part, 2 parts of palm oil, 13 parts of rice bran oil, 3 parts of sunflower oil, 23 parts of tea-seed oil, 0.5 part of safflower seed oil and sesame oil.
The preparation method of the gasoline additive of embodiment 9, comprises the following steps：
(1) first, isopropanol, succimide, isoamyl alcohol, ether, n-octyl alcohol and fatty acid amine are mixed, sealing stirring
12min, obtains the first solution.
(2) 45 DEG C are warming up to after surplus stock component is mixed, is incubated and stirs 33min, be then cooled to 3 DEG C and be incubated
1.5h, obtains the second solution；Wherein, heating rate is 10 DEG C/min, and rate of temperature fall is 2 DEG C/min.
(3) 25 DEG C are heated to after mixing first solution and second solution, is then centrifuged, filtered successively
Operation, and filtrate is collected, obtain gasoline additive；Wherein, the rotating speed of centrifugation is 1700r/min, and the time of centrifugation is
7min。
Embodiment 10
Embodiment 10 proposes a kind of gasoline additive, and described gasoline additive includes the raw material of following parts by weight：
45 parts of isopropanol, 25 parts of isobutanol, 23 parts of isoamyl alcohol, 7 parts of n-heptanol, 27 parts of n-octyl alcohol, 8 parts of n-dodecanol, tetradecanol 13
Part, 8 parts of naphthalene, 13 parts of 1,2,4- trimethylbenzenes, 13 parts of dimethylbenzene, 35 parts of dimethylnaphthalene, 45 parts of oleic acid, amyl group dicyclohexyl ketone 27
Part, 18 parts of succimide, 12 parts of triethylene glycol, 17 parts of sorbierite, 13 parts of fatty acid amine, 17 parts of ether, 37 parts of dimethyl carbonate,
26 parts of dimethyl ether, 8 parts of palm oil, 17 parts of rice bran oil, 8 parts of sunflower oil, 28 parts of tea-seed oil, 1.5 parts of safflower seed oil and sesame oil
2.55 part.
The preparation method of the gasoline additive of embodiment 10, comprises the following steps：
(1) first, isopropanol, succimide, isoamyl alcohol, ether, n-octyl alcohol and fatty acid amine are mixed, sealing stirring
17min, obtains the first solution.
(2) 55 DEG C are warming up to after surplus stock component is mixed, is incubated and stirs 38min, be then cooled to 7 DEG C and be incubated
2.5h, obtains the second solution；Wherein, heating rate is 12 DEG C/min, and rate of temperature fall is 3 DEG C/min.
(3) 34 DEG C are heated to after mixing first solution and second solution, is then centrifuged, filtered successively
Operation, and filtrate is collected, obtain gasoline additive；Wherein, the rotating speed of centrifugation is 3000r/min, and the time of centrifugation is
12min。
Gasoline additive prepared by embodiment 1-10 is closed very much with 93# regular gasolines and 97# regular gasolines respectively, and gasoline adds
Plus the parts by weight of agent are 0.4%.Tested using TWIN-Tec model engines, rotating speed is 2000r/min, power is
20kw.Fuel economy test is carried out to embodiment 1-10 respectively, and NO is detected by nondixpersive infrared methodxDischarge it is dense
Degree.It the results are shown in Table 1.
Table 1：Fuel consumption and emission comparative test result
Comparison sheet 1 can be seen that after the gasoline additive using the present invention, either 93# gasoline or 97# gasoline, its
Oil consumption is within 240g/kwh, especially embodiment 6-10 gasoline additive, is added on embodiment 1-5 basis
The additive of bio-based so that its oil consumption is reduced within 200g/kwh, illustrates that the gasoline additive of the present invention causes fuel oil
Economy be improved significantly.In addition, NOxConcentration of emission within 2600ppm, embodiment 6-10 NOxConcentration of emission
It is reduced within 2200ppm, it is seen then that gasoline additive of the invention is to reduction NOxGeneration there is material impact, popularization makes
Have very important significance with the gasoline additive of the present invention to environmental protection tool.
To sum up, gasoline additive of the invention, largely reduces oil consumption so that fuel economy is obtained substantially
Improve, in addition, the gasoline additive of the present invention is to reduction NOxGeneration there is material impact, promote the use of the present invention gasoline
Additive has very important significance to environmental protection tool.The addition of especially bio-based has to fuel economy further to be improved
And raising, while also reducing NOxConcentration, with good commercial promise.
In the description of this specification, reference term " one embodiment ", " some embodiments ", " example ", " specifically show
The description of example " or " some examples " etc. means to combine specific features, structure, material or the spy that the embodiment or example are described
Point is contained at least one embodiment of the present invention or example.In this manual, to the schematic representation of above-mentioned term not
Identical embodiment or example must be directed to.Moreover, specific features, structure, material or the feature of description can be with office
Combined in an appropriate manner in one or more embodiments or example.In addition, in the case of not conflicting, the skill of this area
Art personnel can be tied the not be the same as Example or the feature of example and non-be the same as Example or example described in this specification
Close and combine.
Although embodiments of the invention have been shown and described above, it is to be understood that above-described embodiment is example
Property, it is impossible to limitation of the present invention is interpreted as, one of ordinary skill in the art within the scope of the invention can be to above-mentioned
Embodiment is changed, changed, replacing and modification.
Claims (10)
1. a kind of gasoline additive, it is characterised in that include the raw material of following parts by weight：30 parts~50 parts of isopropanol, isobutyl
10 parts~30 parts of alcohol, 15 parts~25 parts of isoamyl alcohol, 1 part~10 parts of n-heptanol, 20 parts~30 parts of n-octyl alcohol, 3 parts of n-dodecanol~
10 parts, 5 parts~15 parts of tetradecanol, 1 part~10 parts of naphthalene, 5 parts~15 parts of 1,2,4- trimethylbenzenes, 3 parts~15 parts of dimethylbenzene, two
20 parts~40 parts of methyl naphthalene, 30 parts~50 parts of oleic acid, 20 parts~30 parts of amyl group dicyclohexyl ketone, succimide 10 parts~25
Part, 1 part~15 parts of triethylene glycol, 10 parts~20 parts of sorbierite, 1 part~15 parts of fatty acid amine, 10 parts~20 parts of ether, carbonic acid diformazan
10 parts~30 parts of 30 parts~40 parts of fat and dimethyl ether.
2. gasoline additive according to claim 1, it is characterised in that also include the raw material of following parts by weight：Palm
1 part~10 parts of oil, 10 parts~20 parts of rice bran oil, 1 part~10 parts of sunflower oil, 20 parts~30 parts of tea-seed oil, 0.1 part of safflower seed oil
~2 parts and 0.05 part~3 parts of sesame oil.
3. gasoline additive according to claim 2, it is characterised in that include the raw material of following parts by weight：Isopropanol
30 parts, 30 parts of isobutanol, 15 parts of isoamyl alcohol, 10 parts of n-heptanol, 20 parts of n-octyl alcohol, 10 parts of n-dodecanol, 5 parts of tetradecanol, naphthalene
10 parts, 5 parts of 1,2,4- trimethylbenzenes, 15 parts of dimethylbenzene, 20 parts of dimethylnaphthalene, 50 parts of oleic acid, 20 parts of amyl group dicyclohexyl ketone, fourth
25 parts of imidodicarbonic diamide, 1 part of triethylene glycol, 20 parts of sorbierite, 1 part of fatty acid amine, 20 parts of ether, 30 parts of dimethyl carbonate, dimethyl ether
3 parts of 30 parts, 1 part of palm oil, 20 parts of rice bran oil, 1 part of sunflower oil, 30 parts of tea-seed oil, 0.1 part of safflower seed oil and sesame oil.
4. gasoline additive according to claim 2, it is characterised in that include the raw material of following parts by weight：Isopropanol
50 parts, 10 parts of isobutanol, 25 parts of isoamyl alcohol, 1 part of n-heptanol, 30 parts of n-octyl alcohol, 3 parts of n-dodecanol, 15 parts of tetradecanol, naphthalene 1
Part, 15 parts of 1,2,4- trimethylbenzenes, 3 parts of dimethylbenzene, 40 parts of dimethylnaphthalene, 30 parts of oleic acid, 30 parts of amyl group dicyclohexyl ketone, fourth two
10 parts of acid imide, 15 parts of triethylene glycol, 10 parts of sorbierite, 15 parts of fatty acid amine, 10 parts of ether, 40 parts of dimethyl carbonate, dimethyl ether
0.05 part of 10 parts, 10 parts of palm oil, 10 parts of rice bran oil, 10 parts of sunflower oil, 20 parts of tea-seed oil, 2 parts of safflower seed oil and sesame oil.
5. gasoline additive according to claim 2, it is characterised in that include the raw material of following parts by weight：Isopropanol
40 parts, 20 parts of isobutanol, 20 parts of isoamyl alcohol, 5 parts of n-heptanol, 25 parts of n-octyl alcohol, 7 parts of n-dodecanol, 10 parts of tetradecanol, naphthalene 5
Part, 10 parts of 1,2,4- trimethylbenzenes, 10 parts of dimethylbenzene, 30 parts of dimethylnaphthalene, 40 parts of oleic acid, 25 parts of amyl group dicyclohexyl ketone, fourth
17 parts of imidodicarbonic diamide, 7 parts of triethylene glycol, 15 parts of sorbierite, 8 parts of fatty acid amine, 15 parts of ether, 35 parts of dimethyl carbonate, dimethyl ether
2 parts of 20 parts, 5 parts of palm oil, 15 parts of rice bran oil, 5 parts of sunflower oil, 25 parts of tea-seed oil, 1 part of safflower seed oil and sesame oil.
6. gasoline additive according to claim 2, it is characterised in that include the raw material of following parts by weight：Isopropanol
35 parts, 5 parts of isobutanol, 17 parts of isoamyl alcohol, 3 parts of n-heptanol, 22 parts of n-octyl alcohol, 5 parts of n-dodecanol, 7 parts of tetradecanol, 3 parts of naphthalene,
7 parts of 1,2,4- trimethylbenzenes, 6 parts of dimethylbenzene, 25 parts of dimethylnaphthalene, 35 parts of oleic acid, 22 parts of amyl group dicyclohexyl ketone, succinyl are sub-
14 parts of amine, 4 parts of triethylene glycol, 13 parts of sorbierite, 4 parts of fatty acid amine, 13 parts of ether, 32 parts of dimethyl carbonate, 14 parts of dimethyl ether, palm fibre
1.5 parts of 2 parts of palmitic acid oil, 13 parts of rice bran oil, 3 parts of sunflower oil, 23 parts of tea-seed oil, 0.5 part of safflower seed oil and sesame oil.
7. gasoline additive according to claim 2, it is characterised in that include the raw material of following parts by weight：Isopropanol
45 parts, 25 parts of isobutanol, 23 parts of isoamyl alcohol, 7 parts of n-heptanol, 27 parts of n-octyl alcohol, 8 parts of n-dodecanol, 13 parts of tetradecanol, naphthalene 8
Part, 13 parts of 1,2,4- trimethylbenzenes, 13 parts of dimethylbenzene, 35 parts of dimethylnaphthalene, 45 parts of oleic acid, 27 parts of amyl group dicyclohexyl ketone, fourth
18 parts of imidodicarbonic diamide, 12 parts of triethylene glycol, 17 parts of sorbierite, 13 parts of fatty acid amine, 17 parts of ether, 37 parts of dimethyl carbonate, diformazan
26 parts of ether, 8 parts of palm oil, 17 parts of rice bran oil, 8 parts of sunflower oil, 28 parts of tea-seed oil, 1.5 parts of safflower seed oil and sesame oil 2.55
Part.
8. the preparation method of the gasoline additive described in claim any one of 1-7, it is characterised in that comprise the following steps：
S101：First, isopropanol, succimide, isoamyl alcohol, ether, n-octyl alcohol and fatty acid amine are mixed, sealing stirring
10min~20min, obtains the first solution；
S102：40 DEG C~60 DEG C are warming up to after surplus stock component is mixed, is incubated and stirs 30min~40min, then cool
To 0 DEG C~10 DEG C and 1h~3h is incubated, obtains the second solution；
S103：20 DEG C~40 DEG C are heated to after first solution and second solution are mixed, then centrifuged successively,
Filter operation, and filtrate is collected, obtain gasoline additive.
9. the preparation method of gasoline additive according to claim 8, it is characterised in that in the step S102, rises
Warm speed is 10 DEG C/min~12 DEG C/min；Rate of temperature fall is 1 DEG C/min~3 DEG C/min.
10. the preparation method of gasoline additive according to claim 8, it is characterised in that in the step S103, institute
The rotating speed for stating centrifugally operated is 1500r/min~3500r/min, and the time of centrifugation is 5min~15min.
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