CN111154519A - Gasoline-saving agent - Google Patents

Gasoline-saving agent Download PDF

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Publication number
CN111154519A
CN111154519A CN202010023734.7A CN202010023734A CN111154519A CN 111154519 A CN111154519 A CN 111154519A CN 202010023734 A CN202010023734 A CN 202010023734A CN 111154519 A CN111154519 A CN 111154519A
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China
Prior art keywords
parts
gasoline
saving agent
dicyclohexyl peroxydicarbonate
katoxin
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CN202010023734.7A
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Chinese (zh)
Inventor
马辉
苏闰明
何永斌
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Shanghai Mingma New Energy Technology Co Ltd
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Shanghai Mingma New Energy Technology Co Ltd
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Priority to CN202010023734.7A priority Critical patent/CN111154519A/en
Publication of CN111154519A publication Critical patent/CN111154519A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
    • C10L1/1608Well defined compounds, e.g. hexane, benzene
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/188Carboxylic acids; metal salts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/19Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/30Organic compounds compounds not mentioned before (complexes)
    • C10L1/301Organic compounds compounds not mentioned before (complexes) derived from metals
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/22Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

The invention relates to the technical field of oil saving, in particular to a gasoline saving agent, which is prepared from the following raw materials in parts by weight: 13-18 parts of barium naphthenate, 24-26 parts of vegetable oleic acid, 32-38 parts of dicyclohexyl peroxydicarbonate, 4-6 parts of katoxin and 18-22 parts of cumene. The invention can increase the combustion rate of gasoline by the combustion-supporting catalysis of barium naphthenate, dicyclohexyl peroxydicarbonate and catoxin, can avoid deposits in a combustion chamber, reduces the emission of pollutants and saves the oil consumption.

Description

Gasoline-saving agent
Technical Field
The invention relates to the technical field of oil saving, in particular to a gasoline saving agent.
Background
The twenty-first century is an environmental protection century, and the reduction of the emission of harmful gases in automobile exhaust is a problem to be solved urgently. Important pollutants in exhaust emissions are hydrocarbons, carbon monoxide and nitrogen oxides. After the hydrocarbon is discharged into the atmosphere, the hydrocarbon and the nitrogen oxide are easy to generate ozone under the sunlight to form chemical smog, the high-altitude ozone can shield ultraviolet rays and is beneficial to a human body, and the low-altitude ozone can damage the respiratory system of the human body and also influence the growth of crops. Carbon monoxide enters human blood to combine with hemoglobin, so that the blood conveying function is reduced, and poisoning and even death are caused in severe cases. Nitric oxide not only affects the respiratory system of the human body, causing the occurrence of tracheitis, pneumonia and pulmonary diseases, but also is a main component for producing acid rain.
The addition of gasoline-saving agents to gasoline is one of the effective solutions to this problem. The gasoline saving agent not only has the effects of lubricating and cleaning an oil way system of the engine, but also has a certain catalytic combustion-supporting effect, and can disperse cleaned particles and take away the particles from the gasoline for combustion, thereby recovering the normal oil supply function of the engine, improving the combustion state of the engine and reducing the emission pollution increased by incomplete combustion. In view of the above, a gasoline saving agent is provided.
Disclosure of Invention
The invention aims to provide a gasoline saving agent for gasoline, which has the advantages of simple preparation method, oil consumption reduction, pollutant emission reduction, gasoline combustion efficiency improvement and the like.
In order to achieve the above purpose, the invention provides the following technical scheme:
a gasoline-saving agent is prepared from the following raw materials in parts by weight: 13-18 parts of barium naphthenate, 24-26 parts of vegetable oleic acid, 32-38 parts of dicyclohexyl peroxydicarbonate, 4-6 parts of katoxin and 18-22 parts of cumene.
Preferably, the feed is prepared from the following raw materials in parts by weight: 15 parts of barium naphthenate, 25 parts of vegetable oleic acid, 35 parts of dicyclohexyl peroxydicarbonate, 5 parts of katoxin and 20 parts of cumene.
Preferably, the katoxin is 2, 2-bis (ethylferrocene) propane.
Preferably, the preparation method comprises the following steps:
s1: adding the cumin and the vegetable oil acid with the corresponding weight parts into a stirrer at normal temperature and normal pressure for dispersing, and mixing and stirring for 15-20 minutes to form a mixed solution A;
s2: adding barium naphthenate, dicyclohexyl peroxydicarbonate and carbethoxy in corresponding weight parts into a normal-temperature normal-pressure stirrer for dispersing, and mixing and stirring for 10-15 minutes to form a mixed solution B;
s3: and adding the mixed solution B into the mixed solution A, and mixing and stirring for 35-40 minutes to obtain the gasoline-saving agent.
Preferably, the blending amount of the gasoline saving agent in gasoline is 0.5-0.7 mL/L.
Further, the barium naphthenate adopted by the invention is prepared by diluting with dimethylbenzene after reacting barium sulfate, caustic soda liquid and non-degreased naphthenic acid, the fineness is less than or equal to 15um, and brown viscous liquid can be used as a stabilizer of paint and printing ink; the barium naphthenate added into gasoline can effectively improve the combustion performance of gasoline, reduce exhaust pollution, reduce the abrasion of an internal combustion engine, save the oil consumption and prolong the service life of equipment.
Furthermore, the vegetable oil acid adopted by the invention is light yellow transparent oily liquid at normal temperature, has the chemical name of cis-9-octadecenoic acid, the melting point of 13.4 ℃ and the specific gravity of 0.8905, is insoluble in water, can be dissolved in organic solvents such as ethanol, gasoline and the like, and is converted into stearic acid when being hydrogenated.
Furthermore, the dicyclo hexyl peroxydicarbonate used in the invention is white solid powder, has a melting point of 44-46 ℃, is easily soluble in aromatic hydrocarbon and chlorohydrocarbon, is soluble in ketone and ester, is slightly soluble in ethanol and aliphatic hydrocarbon, is insoluble in water, and is used as a combustion improver and an initiator.
Furthermore, the captoxin adopted by the invention is 2, 2-bis (ethyl ferrocene) propane, and the molecular formula is C27H32Fe2And is used as a burning rate catalyst.
Furthermore, the isopropyl benzene adopted by the invention is colorless liquid with special aromatic odor, and can be used as an organic synthetic raw material and an additive for improving the octane number of the engine fuel.
The invention has the advantages that the combustion rate of gasoline can be increased by the combustion-supporting catalysis action of barium naphthenate, dicyclohexyl peroxydicarbonate and carbitol, deposits in a combustion chamber can be avoided, the emission of pollutants is reduced, and the oil consumption is saved.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In the following embodiments, unless otherwise specified, the technical means used are conventional means well known to those skilled in the art.
Example 1
In the embodiment, the gasoline-saving agent is prepared from the following raw materials in parts by weight: 13 parts of barium naphthenate, 24 parts of vegetable oleic acid, 32 parts of dicyclohexyl peroxydicarbonate, 4 parts of katoxin and 18 parts of cumene.
Preferably, the katoxin is 2, 2-bis (ethylferrocene) propane.
Preferably, the preparation method comprises the following steps:
s1: adding the cumin and the vegetable oil acid with the corresponding weight parts into a stirrer at normal temperature and normal pressure for dispersing, and mixing and stirring for 15-20 minutes to form a mixed solution A;
s2: adding barium naphthenate, dicyclohexyl peroxydicarbonate and carbethoxy in corresponding weight parts into a normal-temperature normal-pressure stirrer for dispersing, and mixing and stirring for 10-15 minutes to form a mixed solution B;
s3: and adding the mixed solution B into the mixed solution A, and mixing and stirring for 35-40 minutes to obtain the gasoline-saving agent.
Example 2
The preparation method of the gasoline saving agent in this embodiment is the same as that in embodiment 1, and is not repeated herein.
In the embodiment, the gasoline-saving agent is prepared from the following raw materials in parts by weight: 18 parts of barium naphthenate, 26 parts of vegetable oleic acid, 38 parts of dicyclohexyl peroxydicarbonate, 6 parts of katoxin and 22 parts of cumene.
Example 3
The preparation method of the gasoline saving agent in this embodiment is the same as that in embodiment 1, and is not repeated herein.
In the embodiment, the gasoline-saving agent is prepared from the following raw materials in parts by weight: 15 parts of barium naphthenate, 25 parts of vegetable oleic acid, 35 parts of dicyclohexyl peroxydicarbonate, 5 parts of katoxin and 20 parts of cumene.
Example 4
The preparation method of the gasoline saving agent in this embodiment is the same as that in embodiment 1, and is not repeated herein.
In the embodiment, the gasoline-saving agent is prepared from the following raw materials in parts by weight: 16 parts of barium naphthenate, 25 parts of vegetable oleic acid, 37 parts of dicyclohexyl peroxydicarbonate, 6 parts of katoxin and 20 parts of cumene.
Example 5
The preparation method of the gasoline saving agent in this embodiment is the same as that in embodiment 1, and is not repeated herein.
In the embodiment, the gasoline-saving agent is prepared from the following raw materials in parts by weight: 14 parts of barium naphthenate, 25 parts of vegetable oleic acid, 33 parts of dicyclohexyl peroxydicarbonate, 4 parts of katoxin and 20 parts of cumene.
Comparative example 1
In this comparative example, the composition of the gasoline-saving agent and the preparation method thereof are the same as those in example 3, and details are not repeated herein, except that barium naphthenate is not incorporated in this comparative example.
Comparative example 2
In this comparative example, the composition of a gasoline-saving agent and the preparation method thereof are the same as those of example 3, and details are not repeated herein, except that dicyclohexyl peroxydicarbonate is not incorporated in this comparative example.
Comparative example 3
In this comparative example, the composition of a gasoline-saving agent and the preparation method thereof are the same as those in example 3, and are not described herein again, except that katoxin is not incorporated in this comparative example.
Comparative example 4
In this comparative example, the composition of a gasoline-saving agent and the preparation method thereof are the same as those in example 3, and no further description is given herein, except that 12 parts of barium naphthenate, 31 parts of dicyclohexyl peroxydicarbonate, and 3 parts of carbethoxy are incorporated in this comparative example.
Comparative example 5
In this comparative example, the composition of a gasoline-saving agent and the preparation method thereof are the same as those in example 3, and details are not repeated herein, except that 19 parts of barium naphthenate, 39 parts of dicyclohexyl peroxydicarbonate and 7 parts of carbethoxy are incorporated in this comparative example.
Comparative example 6
No gasoline economizer was added in this comparative example.
Test of
The above examples 1 to 5 and comparative examples 1 to 6 were tested for exhaust emission and fuel saving efficiency, and the gasoline used was # 92.
The test basis is as follows: GB18352.3-2005 Minicai pollutant discharge limiting and measuring method.
The gasoline-saving agent prepared by the invention is mixed in No. 92 gasoline according to the mixing amount of 0.7 mL/L.
The results of comparing examples 1 to 5 with comparative examples 1 to 6 according to the present invention are as follows:
Figure BDA0002361709850000051
Figure BDA0002361709850000061
it can be seen from the table that, as the amounts of barium naphthenate, dicyclohexyl peroxydicarbonate and catorin are increased together, the exhaust emission and the fuel saving efficiency tend to increase first and then decrease, wherein the exhaust emission and the fuel saving efficiency of example 3 are the best, the maximum CO emission is reduced by 69%, the maximum HC emission is reduced by 88.5%, and the maximum fuel consumption is reduced by 26.3%.
Therefore, the invention adopts the deposit reducing function of barium naphthenate, the combustion supporting performance of dicyclohexyl peroxydicarbonate and the combustion rate catalyzing performance of catoxin, so that the combustion rate of gasoline can be increased, deposits in a combustion chamber can be avoided, the emission of pollutants is further reduced, and the oil consumption is saved; the additive is mixed in a mixed solution of vegetable oleic acid and cumene, and the mixed solution of barium naphthenate, dicyclohexyl peroxydicarbonate and katoxin can be well dissolved under the actions of the anti-wear performance of the vegetable oleic acid and a solvent of the cumene, so that carbon monoxide is fully converted into carbon dioxide, the combustion heat can be improved and the power can be increased in the combustion of gasoline, and the effects of saving energy and reducing atmospheric pollution are achieved.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, but rather as the intention of all modifications, equivalents, improvements, and equivalents falling within the spirit and scope of the invention.

Claims (5)

1. The gasoline-saving agent is characterized by being prepared from the following raw materials in parts by weight: 13-18 parts of barium naphthenate, 24-26 parts of vegetable oleic acid, 32-38 parts of dicyclohexyl peroxydicarbonate, 4-6 parts of katoxin and 18-22 parts of cumene.
2. The gasoline saving agent for gasoline according to claim 1, which is prepared from the following raw materials in parts by weight: 15 parts of barium naphthenate, 25 parts of vegetable oleic acid, 35 parts of dicyclohexyl peroxydicarbonate, 5 parts of katoxin and 20 parts of cumene.
3. The gasoline saving agent of claim 1, wherein the katoxin is 2, 2-bis (ethyl ferrocene) propane.
4. The gasoline saving agent for gasoline according to claim 1, wherein the preparation method comprises the following steps:
s1: adding the cumin and the vegetable oil acid with the corresponding weight parts into a stirrer at normal temperature and normal pressure for dispersing, and mixing and stirring for 15-20 minutes to form a mixed solution A;
s2: adding barium naphthenate, dicyclohexyl peroxydicarbonate and carbethoxy in corresponding weight parts into a normal-temperature normal-pressure stirrer for dispersing, and mixing and stirring for 10-15 minutes to form a mixed solution B;
s3: and adding the mixed solution B into the mixed solution A, and mixing and stirring for 35-40 minutes to obtain the gasoline-saving agent.
5. The gasoline saving agent of claim 1, wherein the amount of the gasoline saving agent added in gasoline is 0.5-0.7 mL/L.
CN202010023734.7A 2020-01-09 2020-01-09 Gasoline-saving agent Pending CN111154519A (en)

Priority Applications (1)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102477319A (en) * 2010-11-21 2012-05-30 张朝斌 Emulsion cleaning gasoline with environmental protection and energy saving
CN104262410A (en) * 2014-09-30 2015-01-07 浙江工业大学 Method for synthesizing alkylated ferrocene derivatives
CN108441271A (en) * 2018-04-04 2018-08-24 汪青 Gasoline cleaning agent and preparation method thereof
CN110643398A (en) * 2019-09-29 2020-01-03 上海金山廊林实业有限公司 Gasoline cleaning synergistic oil-saving agent

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102477319A (en) * 2010-11-21 2012-05-30 张朝斌 Emulsion cleaning gasoline with environmental protection and energy saving
CN104262410A (en) * 2014-09-30 2015-01-07 浙江工业大学 Method for synthesizing alkylated ferrocene derivatives
CN108441271A (en) * 2018-04-04 2018-08-24 汪青 Gasoline cleaning agent and preparation method thereof
CN110643398A (en) * 2019-09-29 2020-01-03 上海金山廊林实业有限公司 Gasoline cleaning synergistic oil-saving agent

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