CN105297057A - Hydrocarbon oil removal rust removal cleaning agent - Google Patents
Hydrocarbon oil removal rust removal cleaning agent Download PDFInfo
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- CN105297057A CN105297057A CN201510762764.9A CN201510762764A CN105297057A CN 105297057 A CN105297057 A CN 105297057A CN 201510762764 A CN201510762764 A CN 201510762764A CN 105297057 A CN105297057 A CN 105297057A
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- carbon hydrogen
- oil removing
- rust cleaning
- removing agent
- hydrogen detergent
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Abstract
The invention belongs to the technical field of industrial cleaning, particularly relates to a hydrocarbon oil removal rust removal cleaning agent, which uses a carbon hydrocarbon solvent with 166 DEG C-192 DEG C boiling range as a basic solvent, and is added with surfactant combinations, organic solvents, corrosion inhibitors and auxiliary additives. The hydrocarbon oil removal rust removal cleaning agent can safely and rapidly remove oil pollution and rust scales, can be used in normal temperature and below 75 DEG C, can clean up the oil pollution and the rust scales in 2-5 minutes, and does not hurt base surfaces of workpieces.
Description
Technical field
The invention belongs to industry cleaning link technical field, be specifically related to a kind of hydrocarbon detergent for degreasing and rust removal.
Background technology
In the five metals course of processing, the surface of some workpiece is had to be subject to environmental influence and to produce corrosion.As everyone knows, mineral acid is used for the rust cleaning of metallic surface, and its rust cleaning ability is strong and rapid; But mineral acid, while removing rust staining, is easy to injure metallic surface, namely loses more than gain.In the five metals course of processing, various processing oil can be used as ROLLING OIL, drawing oil, punching oil, stretching wet goods, workpiece surface after processing can adhere to this quasi-grease, next uses the clean-out systems such as white spirit, methylene dichloride, trieline, agent for carbon hydrogen detergent, water base degreaser to be cleaned up by the grease of workpiece surface.Hardware workpiece is after the manufacturing procedure such as punching press, drawing completes, and during to workpiece cleaning, often space-number hour or several days, can cause the corrosion of part workpiece thus.The rust cleaning ability that the mineral acid such as sulfuric acid, hydrochloric acid is stronger is well-known, but uses these mineral acids can not remove the greasy dirt of workpiece surface attachment, and in addition also can injure the surface not having corrosion, therefore the degreasing and rust removal of some workpiece is very thorny.
Summary of the invention
In order to solve the problem, the object of the present invention is to provide a kind of hydrocarbon detergent for degreasing and rust removal; It adopts based on organic agent for carbon hydrogen detergent, adds the tensio-active agent and auxiliary agent with rust removing function, achieves and removes grease and rust deposite simultaneously; In addition by the help of inhibiter, the injury of aforementioned substances to workpiece surface has been protected.
The present invention is achieved through the following technical solutions:
A kind of rust cleaning oil removing agent for carbon hydrogen detergent, described rust cleaning oil removing agent for carbon hydrogen detergent is made up of the following raw material counted by weight percentage:
Described surfactant composition is the mixture of aniorfic surfactant and nonionic surface active agent.
Preferably, described hydrocarbon basal liquid to be boiling range the be solvent oil of 120 DEG C ~ 230 DEG C; Preferred boiling range is the solvent oil of 130 DEG C ~ 192 DEG C; More preferably boiling range is the solvent oil of 166 DEG C ~ 188 DEG C.
Preferably, described hydrocarbon basal liquid is the one or more combination thing in petroleum base, Sweet natural gas base, normal paraffin, isoparaffin.CH1140, CH1145, CH1150 or CH1130 of the preferably new ball cleaning in Guangdong Science and Technology Co., Ltd. production further.
Preferably, described normal paraffin, isoparaffin are by coal-based obtained normal paraffin or isoparaffin.Preferably, described surfactant composition is the mixture of aniorfic surfactant and nonionic surface active agent, and the volume ratio of the two is preferably 1:1 ~ 4.
Preferably, described anion surfactant is phosphate ester surfactant, sulphonic acids tensio-active agent.
Preferably, described anion surfactant be 6503, one or more mixtures composition in AEO-3P, AEO-9P, OP-9P or Witco 1298 Soft Acid.
Preferably, described nonionic agent is the one or more combination thing in JFC (abbreviation of fatty alcohol-polyoxyethylene ether) series (JFC, JFC-1, JFC-2, JFC-E), peregal series, serial, the L64 (polyether glycol) of OP.Do not repel other nonionic surface active agent of the same type.
Preferably, described organic except Oil solvent be one or more combination thing in alcohol ether, single acid anhydride ester, alcohol ether-ether, morpholine.Do not repel other nonionic surface active agent of the same type.
Preferably, described inhibiter is for containing nitrogen compound.More particularly 6501, one or more combination thing in benzotriazole, tetrahydroglyoxaline.Do not repel other nonionic surface active agent of the same type.
Preferably, described supplementary additive is the one or more combination thing in citric acid, tartrate, gluconic acid.Do not repel other nonionic surface active agent of the same type.
Rust cleaning oil removing agent for carbon hydrogen detergent of the present invention is made up of hydrocarbon basal liquid, surfactant composition, organic Oil solvent, inhibiter and supplementary additive of removing.The present invention can wipe oil and rust deposite safely and fast, this clean-out system can normal temperature and lower than the condition of 75 DEG C under use, within 2 to 5 minutes, can greasy dirt and rust deposite be removed clean, not injure workpiece basal plane.
concrete embodiment
Below in conjunction with embodiment, the present invention is described in further detail, understands the present invention to help those skilled in the art.
Embodiment 1
A kind of rust cleaning oil removing agent for carbon hydrogen detergent, be made up of the following raw material counted by weight percentage: anion surfactant (wherein 6503=1%, AEO-3P=1%, AEO-9P=1%, Witco 1298 Soft Acid=1%) 4%, nonionic agent (JFC=0.5%, OP-9P=0.5%, L64=0.5%) 1.5%, organic except Oil solvent (N-formyl morpholine N-=0.5%, DMP=0.5%, DBP=0.5%, DOP=0.5%, butyl glycol ether=0.5%, glycol methyl ether acetate=0.5%) 3%, inhibiter (6501=0.5%, benzotriazole=0.1%, tetrahydroglyoxaline=0.1%) 0.7%, supplementary additive (citric acid=0.25%, tartrate=0.1%, gluconic acid=0.05%) 0.13%, hydrocarbon basal liquid (CH1140) surplus.
Embodiment 2
A kind of rust cleaning oil removing agent for carbon hydrogen detergent, is made up of the following raw material counted by weight percentage: anion surfactant (wherein 6503=2%, AEO-3P=3%) 5%, nonionic agent (JFC) 5%, organic except Oil solvent (butyl glycol ether) 10%, inhibiter (benzotriazole) 0.1%, supplementary additive (citric acid) 0.5%, hydrocarbon basal liquid (CH1145) surplus.
Embodiment 3
A kind of rust cleaning oil removing agent for carbon hydrogen detergent, be made up of the following raw material counted by weight percentage: anion surfactant (wherein AEO-9P=1%, Witco 1298 Soft Acid=1%) 2%, nonionic agent (OP-9P=0.5%, L64=0.5%) 1%, organic except Oil solvent (morpholine=3%, DMP=2%) 5%, inhibiter (6501=0.1%, benzotriazole=0.1%, tetrahydroglyoxaline=0.3%) 0.5%, supplementary additive (citric acid=1%, tartrate=0.5%, gluconic acid=0.5%) 2%, hydrocarbon basal liquid (CH1140=10%, CH1145=10%, CH1150=25.5%, CH1130=44%) surplus.
Embodiment 4
A kind of rust cleaning oil removing agent for carbon hydrogen detergent, is made up of the following raw material counted by weight percentage: anion surfactant (wherein Witco 1298 Soft Acid) 5%, nonionic agent (L64) 1%, organic except Oil solvent (morpholine=3%, DMP=1%, glycol methyl ether acetate=4%) 8%, inhibiter (tetrahydroglyoxaline) 0.5%, supplementary additive (citric acid=0.3%, tartrate=0.2%, gluconic acid=0.5%) 1%, hydrocarbon basal liquid (CH1140=54.3%, CH1130=30%) surplus.
During preparation, first supplementary additive is added the organic of metering and dissolve except in Oil solvent, the heating of this process helps lend some impetus to dissolving.The tensio-active agent each measured mixes, and the organic Oil solvent that removes being dissolved with supplementary additive is slowly added, and constantly stirs, until mix simultaneously.Add the inhibiter measured again, stir.Guarantee that said process mixes, after sediment-free, add base solvent, and mix; Obtained described rust cleaning oil removing agent for carbon hydrogen detergent.
Above-described embodiment, just preferred embodiment of the present invention, is not used for limiting the scope of the present invention, therefore all equivalences done with the feature described in the claims in the present invention and principle change or modify, and all should be included within the claims in the present invention scope.
Concrete use-testing result is as follows:
Example 1
Workpiece: foreign copper-nickel alloy slightly becomes rusty
Working temperature, normal temperature.Working hour, ultrasonic 2 minutes.Rinsing, drying.Satisfied.
Example 2
Workpiece: skin copper slightly becomes rusty
Working temperature, normal temperature.Working hour, ultrasonic 3 minutes.Rinsing, drying.Satisfied.
Example 3
Workpiece: red copper is slightly become rusty
Working temperature, normal temperature.Working hour, ultrasonic 1 minute.Rinsing, drying.Satisfied.
Example 4
Workpiece: 304 stainless steel oil in water emulsions are residual, dust, fingerprint
Working temperature, 40 DEG C.Working hour, ultrasonic 5 minutes.Rinsing, drying.Satisfied.
From above-mentioned, the present invention can remove greasy dirt and rust deposite on workpiece safely and fast, this clean-out system can normal temperature and lower than the condition of 75 DEG C under use, within 2 to 5 minutes, greasy dirt and rust deposite can be removed clean, not injure workpiece basal plane; Substantially increase working efficiency.
Claims (10)
1. eliminate rust an oil removing agent for carbon hydrogen detergent, it is characterized in that: described rust cleaning oil removing agent for carbon hydrogen detergent is made up of the following raw material counted by weight percentage:
Described surfactant composition is the mixture of aniorfic surfactant and nonionic surface active agent.
2. according to the rust cleaning oil removing agent for carbon hydrogen detergent described in claim 1, it is characterized in that: described hydrocarbon basal liquid to be boiling range the be solvent oil of 120 DEG C ~ 230 DEG C.
3. according to the rust cleaning oil removing agent for carbon hydrogen detergent described in claim 2, it is characterized in that: described hydrocarbon basal liquid is the one or more combination thing in petroleum base, Sweet natural gas base, normal paraffin, isoparaffin.
4. according to the rust cleaning oil removing agent for carbon hydrogen detergent described in claim 3, it is characterized in that: described normal paraffin, isoparaffin are by coal-based obtained normal paraffin or isoparaffin.
5. according to the rust cleaning oil removing agent for carbon hydrogen detergent described in claim 1, it is characterized in that: the volume ratio of described aniorfic surfactant and nonionic surface active agent is 1:1 ~ 4.
6. according to the rust cleaning oil removing agent for carbon hydrogen detergent described in claim 5, it is characterized in that: described anion surfactant is phosphate ester surfactant or sulphonic acids tensio-active agent.
7. according to the rust cleaning oil removing agent for carbon hydrogen detergent described in claim 5, it is characterized in that: described nonionic agent is the one or more combination thing in JFC series, peregal serial, OP-9P, L64.
8., according to the rust cleaning oil removing agent for carbon hydrogen detergent described in claim 1, it is characterized in that: described organic except Oil solvent be one or more combination thing in alcohol ether, single acid anhydride ester, alcohol ether-ether, morpholine.
9. according to the rust cleaning oil removing agent for carbon hydrogen detergent described in claim 1, it is characterized in that: described inhibiter is for containing nitrogen compound.
10. according to the rust cleaning oil removing agent for carbon hydrogen detergent described in claim 1, it is characterized in that: described supplementary additive is the one or more combination thing in citric acid, tartrate, gluconic acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510762764.9A CN105297057A (en) | 2015-11-09 | 2015-11-09 | Hydrocarbon oil removal rust removal cleaning agent |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510762764.9A CN105297057A (en) | 2015-11-09 | 2015-11-09 | Hydrocarbon oil removal rust removal cleaning agent |
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| CN105297057A true CN105297057A (en) | 2016-02-03 |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106521539A (en) * | 2016-12-05 | 2017-03-22 | 郑州丽福爱生物技术有限公司 | Steel surface detergent |
| CN108856116A (en) * | 2018-07-13 | 2018-11-23 | 深圳市鑫承诺环保产业股份有限公司 | A kind of anhydrous cleaning method of precision cutting tool |
| CN109594093A (en) * | 2018-12-31 | 2019-04-09 | 广东新球清洗科技股份有限公司 | Metal base paraffin removal Halogen agent for carbon hydrogen detergent |
| WO2019080475A1 (en) * | 2017-10-23 | 2019-05-02 | 北新集团建材股份有限公司 | Exterior wall coating, and preparation method and wetting agent therefor |
| CN110344070A (en) * | 2019-07-31 | 2019-10-18 | 河池市机务材料有限公司 | A kind of formula and preparation method thereof of spongy chromium plating oil removing |
| WO2022267916A1 (en) * | 2021-06-23 | 2022-12-29 | 北京北方华创微电子装备有限公司 | Surfactant, preparation method therefor, and method for cleaning ceramic part |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106521539A (en) * | 2016-12-05 | 2017-03-22 | 郑州丽福爱生物技术有限公司 | Steel surface detergent |
| WO2019080475A1 (en) * | 2017-10-23 | 2019-05-02 | 北新集团建材股份有限公司 | Exterior wall coating, and preparation method and wetting agent therefor |
| CN108856116A (en) * | 2018-07-13 | 2018-11-23 | 深圳市鑫承诺环保产业股份有限公司 | A kind of anhydrous cleaning method of precision cutting tool |
| CN109594093A (en) * | 2018-12-31 | 2019-04-09 | 广东新球清洗科技股份有限公司 | Metal base paraffin removal Halogen agent for carbon hydrogen detergent |
| CN110344070A (en) * | 2019-07-31 | 2019-10-18 | 河池市机务材料有限公司 | A kind of formula and preparation method thereof of spongy chromium plating oil removing |
| WO2022267916A1 (en) * | 2021-06-23 | 2022-12-29 | 北京北方华创微电子装备有限公司 | Surfactant, preparation method therefor, and method for cleaning ceramic part |
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Application publication date: 20160203 |