BR0210054A - Halogenação oxidativa de hidrocarbonetos de c1 a hidrocarbonetos de c1 halogenados e processos integrados relacionados aos mesmos - Google Patents

Halogenação oxidativa de hidrocarbonetos de c1 a hidrocarbonetos de c1 halogenados e processos integrados relacionados aos mesmos

Info

Publication number
BR0210054A
BR0210054A BR0210054-1A BR0210054A BR0210054A BR 0210054 A BR0210054 A BR 0210054A BR 0210054 A BR0210054 A BR 0210054A BR 0210054 A BR0210054 A BR 0210054A
Authority
BR
Brazil
Prior art keywords
hydrocarbons
oxidative halogenation
hydrocarbon
halide
halogen
Prior art date
Application number
BR0210054-1A
Other languages
English (en)
Inventor
Albert E Schweizer
Mark E Jones
Daniel HICKMAN
Original Assignee
Dow Global Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc filed Critical Dow Global Technologies Inc
Publication of BR0210054A publication Critical patent/BR0210054A/pt

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
    • C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
    • C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
    • C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
    • C07C17/154—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of saturated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/26—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only halogen atoms as hetero-atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
    • C07C17/158—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C21/00—Acyclic unsaturated compounds containing halogen atoms
    • C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
    • C07C21/04—Chloro-alkenes
    • C07C21/06—Vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C07C29/12—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of esters of mineral acids
    • C07C29/124—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of esters of mineral acids of halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

Abstract

"HALOGENAçãO OXIDATIVA DE HIDROCARBONETOS DE C~ 1~ A HIDROCARBONETOS DE C~ 1~ HALOGENADOS E PROCESSOS INTEGRADOS RELACIONADOS AOS MESMOS". Um processo de halogenação oxidativa envolvendo contatar um hidrocarboneto reagente selecionado de metano, um hidrocarboneto de C~ 1~ halogenado, ou uma mistura dos mesmos com uma fonte de halogênio e, preferivelmente uma fonte de oxigênio na presença de um catalisador de haleto de terra rara ou oxi-haleto de terra rara, de modo a formar um hidrocarboneto de C~ 1~ halogenado tendo um número maior de substituintes halogênio quando comparado com o hidrocarboneto reagente. Preferivelmente, o produto é um metano mono-halogenado, mais preferivelmente, cloreto de metila. o processo de halogenação oxidativa para formar haleto de metila pode ser integrado com processos a jusante para produzir produtos químicos de alto consumo valiosos, por exemplo, álcool metílico e/ou éter dimetílico; olefinas leves, incluindo etileno, propileno, e butenos; hidrocarbonetos superiores, incluindo gasolinas; monómero haleto de vinila, e ácido acético. O haleto de hidrogênio, que é um co-produto destes processos a jusante, pode ser reciclado para o processo de halogenação oxidativa.
BR0210054-1A 2001-05-21 2002-04-11 Halogenação oxidativa de hidrocarbonetos de c1 a hidrocarbonetos de c1 halogenados e processos integrados relacionados aos mesmos BR0210054A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/862,058 US6452058B1 (en) 2001-05-21 2001-05-21 Oxidative halogenation of C1 hydrocarbons to halogenated C1 hydrocarbons and integrated processes related thereto
PCT/US2002/011778 WO2002094751A2 (en) 2001-05-21 2002-04-11 Oxidative halogenation of c1 hydrocarbons to halogenated c1 hydrocarbons and integrated processes related thereto

Publications (1)

Publication Number Publication Date
BR0210054A true BR0210054A (pt) 2004-08-17

Family

ID=25337527

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0210054-1A BR0210054A (pt) 2001-05-21 2002-04-11 Halogenação oxidativa de hidrocarbonetos de c1 a hidrocarbonetos de c1 halogenados e processos integrados relacionados aos mesmos

Country Status (17)

Country Link
US (1) US6452058B1 (pt)
EP (1) EP1395536B1 (pt)
JP (1) JP4226910B2 (pt)
KR (1) KR100876032B1 (pt)
CN (1) CN1283601C (pt)
AR (1) AR033899A1 (pt)
AU (1) AU2002256217B2 (pt)
BR (1) BR0210054A (pt)
CA (1) CA2447761C (pt)
DE (1) DE60222546T2 (pt)
GC (1) GC0000323A (pt)
MX (1) MXPA03010555A (pt)
MY (1) MY129647A (pt)
NO (1) NO20035158L (pt)
RU (1) RU2286329C2 (pt)
TW (1) TW593218B (pt)
WO (1) WO2002094751A2 (pt)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7674941B2 (en) 2004-04-16 2010-03-09 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US7838708B2 (en) 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
US7847139B2 (en) 2003-07-15 2010-12-07 Grt, Inc. Hydrocarbon synthesis
US7880041B2 (en) 2004-04-16 2011-02-01 Marathon Gtf Technology, Ltd. Process for converting gaseous alkanes to liquid hydrocarbons
US7883568B2 (en) 2006-02-03 2011-02-08 Grt, Inc. Separation of light gases from halogens
US7964764B2 (en) 2003-07-15 2011-06-21 Grt, Inc. Hydrocarbon synthesis
US7998438B2 (en) 2007-05-24 2011-08-16 Grt, Inc. Zone reactor incorporating reversible hydrogen halide capture and release
US8008535B2 (en) 2004-04-16 2011-08-30 Marathon Gtf Technology, Ltd. Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US8053616B2 (en) 2006-02-03 2011-11-08 Grt, Inc. Continuous process for converting natural gas to liquid hydrocarbons
US8273929B2 (en) 2008-07-18 2012-09-25 Grt, Inc. Continuous process for converting natural gas to liquid hydrocarbons

Families Citing this family (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6680415B1 (en) * 1999-11-22 2004-01-20 Dow Global Technologies Inc. Oxyhalogenation process using catalyst having porous rare earth halide support
US7019182B2 (en) * 2001-04-18 2006-03-28 Grt, Inc. Method of hydrocarbon preservation and environmental protection
US6525230B2 (en) * 2001-04-18 2003-02-25 Grt, Inc. Zone reactor
US7230150B2 (en) * 2001-04-18 2007-06-12 Grt, Inc. Zone reactor
CN1649808A (zh) * 2001-05-23 2005-08-03 陶氏环球技术公司 从单碳原料的卤乙烯生产
MXPA03010693A (es) * 2001-05-23 2004-07-01 Dow Global Technologies Inc Halogenacion oxidante y deshidreogenacion opcional de hidrocarburos de c3+.
US20050192468A1 (en) * 2001-06-20 2005-09-01 Sherman Jeffrey H. Hydrocarbon conversion process improvements
US20030069452A1 (en) * 2001-06-20 2003-04-10 Sherman Jeffrey H. Method and apparatus for synthesizing from alcohols and ethers from alkanes, alkenes, and aromatics
US7161050B2 (en) * 2001-06-20 2007-01-09 Grt, Inc. Method and apparatus for synthesizing olefins, alcohols, ethers, and aldehydes
US20030078456A1 (en) * 2001-06-20 2003-04-24 Aysen Yilmaz Integrated process for synthesizing alcohols, ethers, aldehydes, and olefins from alkanes
US20040152929A1 (en) * 2002-05-08 2004-08-05 Clarke William D Process for vinyl chloride manufacture from ethane and ethylene with air feed and alternative hcl processing methods
WO2005069751A2 (en) * 2003-06-21 2005-08-04 Richards Alan K Anhydrous processing of methane into methane-sulfonic acid, methanol, and other compounds
CN100425588C (zh) * 2004-01-17 2008-10-15 湖南大学 从甲烷经非合成气过程制备醋酸、甲醇和二甲醚的新流程
WO2005095310A2 (en) * 2004-03-23 2005-10-13 Shell Internationale Research Maatschappij B.V. The utilization of zirconium and zirconium based alloys for the containment of halogen containing environments used in the production of olefins, alcohols, ethers, ethoxylates glycols, and olefin oxides from alkanes
US8173851B2 (en) * 2004-04-16 2012-05-08 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US8642822B2 (en) 2004-04-16 2014-02-04 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
US20080275284A1 (en) 2004-04-16 2008-11-06 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US7091387B2 (en) * 2004-04-21 2006-08-15 Shell Oil Company Process to convert alkanes into primary alcohols
US7462752B2 (en) * 2004-04-21 2008-12-09 Shell Oil Company Process to convert linear alkanes into alpha olefins
WO2005110953A1 (en) * 2004-04-30 2005-11-24 Shell Internationale Research Maatschappij B.V. Derivatives of alcohols and olefins
US20060229228A1 (en) * 2005-04-11 2006-10-12 Zachary John Anthony Komon Method of making alkoxylates
US20060229475A1 (en) * 2005-04-11 2006-10-12 Weiss Michael J Synthesis of hydroxylated hydrocarbons
ZA200708923B (en) 2005-05-04 2009-02-25 Dow Global Technologies Inc Oxidative halogenation of C1 hydrocarbons to halogenated C1 hydrocarbons
CN100457706C (zh) * 2005-06-22 2009-02-04 微宏科技（湖州）有限公司 从甲烷合成乙酰溴、醋酸、醋酸酯的新流程
US7683230B2 (en) * 2005-10-27 2010-03-23 Stauffer John E Methyl bromide to olefins
CN100582064C (zh) * 2006-03-20 2010-01-20 微宏科技（湖州）有限公司 从甲烷经过非合成气方法合成碳三至碳十三高碳烃的流程
CN101284232B (zh) * 2007-04-13 2013-01-16 微宏动力***（湖州）有限公司 甲烷溴氧化制溴甲烷及其转化制碳氢化合物的催化剂
CN101397231B (zh) * 2007-09-28 2013-04-03 天津市化学试剂研究所 一种直链奇数正构烷烃的制备方法
US7696390B2 (en) * 2008-06-10 2010-04-13 Stauffer John E Methanol synthesis
US8282810B2 (en) 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
EP2399887A1 (en) * 2008-07-18 2011-12-28 GRT, Inc. Continuous process for converting natural gas to liquid hydrocarbons
US7812201B2 (en) 2008-10-01 2010-10-12 Targa Resources, Inc. Process and catalyst for converting alkanes
CN101723795A (zh) * 2008-10-13 2010-06-09 微宏动力***（湖州）有限公司 甲烷制备溴甲烷、高碳烃、甲醇和二甲醚的方法
US8674149B2 (en) * 2008-10-27 2014-03-18 Dow Global Technologies Llc Oxidative mono-halogenation of methane
WO2010132325A1 (en) * 2009-05-12 2010-11-18 Shell Oil Company An integrated process to produce hydrocarbons from natural gas containing carbon dioxide
US8198495B2 (en) 2010-03-02 2012-06-12 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8367884B2 (en) 2010-03-02 2013-02-05 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
RU2446877C2 (ru) * 2010-07-16 2012-04-10 Учреждение Российской Академии наук Институт катализа им. Г.К. Борескова Сибирского отделения Российской Академии наук Каталитическая система для гетерогенных реакций
RU2446881C2 (ru) * 2010-07-16 2012-04-10 Учреждение Российской Академии наук Институт катализа им. Г.К. Борескова Сибирского отделения Российской Академии наук Способ селективного каталитического оксихлорирования метана в метилхлорид
US8815050B2 (en) 2011-03-22 2014-08-26 Marathon Gtf Technology, Ltd. Processes and systems for drying liquid bromine
US20120259145A1 (en) * 2011-04-06 2012-10-11 Stauffer John E Manufacture of methanol
US8440868B2 (en) * 2011-04-06 2013-05-14 John E. Stauffer Manufacture of methanol
US8436220B2 (en) 2011-06-10 2013-05-07 Marathon Gtf Technology, Ltd. Processes and systems for demethanization of brominated hydrocarbons
US8829256B2 (en) 2011-06-30 2014-09-09 Gtc Technology Us, Llc Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons
CN102344339B (zh) * 2011-07-15 2015-03-11 厦门大学 铈基催化剂在甲烷卤氧化制卤代甲烷中的应用
US8802908B2 (en) 2011-10-21 2014-08-12 Marathon Gtf Technology, Ltd. Processes and systems for separate, parallel methane and higher alkanes' bromination
US9193641B2 (en) 2011-12-16 2015-11-24 Gtc Technology Us, Llc Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems
RU2522576C1 (ru) * 2013-04-10 2014-07-20 Ассоциация делового сотрудничества в области передовых комплексных технологий "АСПЕКТ" Способ каталитического пиролиза хлористого метила
CN104209134B (zh) * 2013-06-03 2016-09-28 中国科学院大连化学物理研究所 甲烷溴氧化制备溴甲烷和co的催化剂及其制备方法和应用
CN104211556B (zh) * 2013-06-05 2016-03-30 中国石油化工股份有限公司 一种低碳烯烃的制备方法
WO2015080519A1 (ko) * 2013-11-29 2015-06-04 주식회사 엘지화학 요크-쉘 입자, 촉매 및 이의 제조방법
US10040737B2 (en) 2015-07-14 2018-08-07 John E. Stauffer Methanol production from methane and carbon dioxide
US10293304B2 (en) 2015-07-14 2019-05-21 John E. Stauffer Carbon dioxide recovery using an absorption column in combination with osmotic filters
US10493397B2 (en) 2015-07-14 2019-12-03 John E. Stauffer Carbon dioxide recovery
KR20170003568U (ko) 2016-04-06 2017-10-16 박선희 거푸집 연결 고정부재
US9981896B2 (en) 2016-07-01 2018-05-29 Res Usa, Llc Conversion of methane to dimethyl ether
WO2018004994A1 (en) 2016-07-01 2018-01-04 Res Usa, Llc Fluidized bed membrane reactor
WO2018004993A1 (en) 2016-07-01 2018-01-04 Res Usa, Llc Reduction of greenhouse gas emission
EP3272418A1 (en) * 2016-07-21 2018-01-24 ETH Zurich A catalyst composition for direct synthesis of vinyl chloride from ethylene
CN108144632B (zh) * 2018-01-22 2020-11-03 西安元创化工科技股份有限公司 一种甲烷氧氯化的二氧化钌催化剂及其制备方法
CN108704670B (zh) * 2018-06-07 2021-02-19 中国科学技术大学先进技术研究院 一种Pt1@MIL纳米催化剂及其制备方法和应用

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3172915A (en) 1965-03-09 Preparation of oxygenated methane derivatives
US1086381A (en) 1912-10-11 1914-02-10 Du Pont Powder Co Preparation of alcohol from chlorhydrocarbons.
US3657367A (en) 1968-10-31 1972-04-18 Stauffer Chemical Co Oxychlorination of saturated and unsaturated hydrocarbons in the presence of a fluidized catalyst containing lanthanum and didymium
IT958619B (it) 1971-06-30 1973-10-30 Sumitomo Chemical Co Procedimento per preparare idrocarburi clorurati
US3894107A (en) 1973-08-09 1975-07-08 Mobil Oil Corp Conversion of alcohols, mercaptans, sulfides, halides and/or amines
US4523040A (en) 1981-09-01 1985-06-11 Olah George A Methyl halides and methyl alcohol from methane
EP0164798A1 (en) * 1981-09-01 1985-12-18 George Andrew Olah Process for the preparation of methyl monohalides
US4471150A (en) 1981-12-30 1984-09-11 Mobil Oil Corporation Catalysts for light olefin production
FR2529883A1 (fr) 1982-07-06 1984-01-13 Ugine Kuhlmann Procede de fabrication de chlorure de vinyle
US4480145A (en) 1982-09-16 1984-10-30 Mobil Oil Corporation Catalysts for the conversion of methanol to ethylene plus gasoline
US4795843A (en) 1985-08-26 1989-01-03 Uop Inc. Conversion of methane into larger organic hydrocarbons
US4769504A (en) 1987-03-04 1988-09-06 The United States Of America As Represented By The United States Department Of Energy Process for converting light alkanes to higher hydrocarbons
US4990696A (en) 1988-12-29 1991-02-05 Stauffer John E Methyl alcohol process
US5087786A (en) 1990-04-25 1992-02-11 Amoco Corporation Halogen-assisted conversion of lower alkanes
US5001293A (en) 1990-04-25 1991-03-19 Amoco Corporation Halocarbon conversion
US5354916A (en) 1992-03-10 1994-10-11 Exxon Research And Engineering Company Low temperature conversion of alkanes
US5243098A (en) 1992-11-04 1993-09-07 Energia Andina Ltd. Conversion of methane to methanol
US5397560A (en) 1993-04-06 1995-03-14 The Dow Chemical Company Microporous crystalline aluminosilicate designated DCM-2
US5536873A (en) 1994-12-09 1996-07-16 E. I. Du Pont De Nemours And Company Preparation of pentenoic acid
FR2748740B1 (fr) * 1996-05-15 1998-08-21 Rhone Poulenc Chimie Composition a base d'oxyde de cerium et d'oxyde de zirconium a haute surface specifique et a capacite elevee de stockage d'oxygene, procede de preparation et utilisation en catalyse
DE19721301C1 (de) 1997-05-21 1998-10-01 Basf Ag Verfahren zur Hydrolyse von Alkylmonohalogeniden
US5912393A (en) 1997-12-09 1999-06-15 Uop Llc Metallo aluminophosphate molecular sieve with novel crystal morphology and methanol to olefin process using the sieve
PL354730A1 (en) 1999-11-22 2004-02-23 The Dow Chemical Company A process for the conversion of ethylene to vinyl chloride, and novel catalyst compositions useful for such process

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8415512B2 (en) 2001-06-20 2013-04-09 Grt, Inc. Hydrocarbon conversion process improvements
US7838708B2 (en) 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
US7847139B2 (en) 2003-07-15 2010-12-07 Grt, Inc. Hydrocarbon synthesis
US7964764B2 (en) 2003-07-15 2011-06-21 Grt, Inc. Hydrocarbon synthesis
US7880041B2 (en) 2004-04-16 2011-02-01 Marathon Gtf Technology, Ltd. Process for converting gaseous alkanes to liquid hydrocarbons
US7674941B2 (en) 2004-04-16 2010-03-09 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US8008535B2 (en) 2004-04-16 2011-08-30 Marathon Gtf Technology, Ltd. Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US7883568B2 (en) 2006-02-03 2011-02-08 Grt, Inc. Separation of light gases from halogens
US8053616B2 (en) 2006-02-03 2011-11-08 Grt, Inc. Continuous process for converting natural gas to liquid hydrocarbons
US8921625B2 (en) 2007-02-05 2014-12-30 Reaction35, LLC Continuous process for converting natural gas to liquid hydrocarbons
US7998438B2 (en) 2007-05-24 2011-08-16 Grt, Inc. Zone reactor incorporating reversible hydrogen halide capture and release
US8415517B2 (en) 2008-07-18 2013-04-09 Grt, Inc. Continuous process for converting natural gas to liquid hydrocarbons
US8273929B2 (en) 2008-07-18 2012-09-25 Grt, Inc. Continuous process for converting natural gas to liquid hydrocarbons

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US6452058B1 (en) 2002-09-17
RU2286329C2 (ru) 2006-10-27
WO2002094751A2 (en) 2002-11-28
DE60222546T2 (de) 2008-06-19
WO2002094751A3 (en) 2003-04-10
JP4226910B2 (ja) 2009-02-18
KR100876032B1 (ko) 2008-12-26
AU2002256217B2 (en) 2007-06-28
CN1283601C (zh) 2006-11-08
CA2447761A1 (en) 2002-11-28
AR033899A1 (es) 2004-01-07
GC0000323A (en) 2006-11-01
NO20035158L (no) 2004-01-20
NO20035158D0 (no) 2003-11-20
EP1395536A2 (en) 2004-03-10
KR20040002990A (ko) 2004-01-07
EP1395536B1 (en) 2007-09-19
CN1525950A (zh) 2004-09-01
JP2004529189A (ja) 2004-09-24
MXPA03010555A (es) 2004-07-01
TW593218B (en) 2004-06-21
RU2003136763A (ru) 2005-05-10
CA2447761C (en) 2010-08-10
DE60222546D1 (de) 2007-10-31
MY129647A (en) 2007-04-30

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