WO2007148506A1 - 樹脂組成物及びそれを用いる被加工部材の仮固定方法と表面保護方法 - Google Patents
樹脂組成物及びそれを用いる被加工部材の仮固定方法と表面保護方法 Download PDFInfo
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- WO2007148506A1 WO2007148506A1 PCT/JP2007/060618 JP2007060618W WO2007148506A1 WO 2007148506 A1 WO2007148506 A1 WO 2007148506A1 JP 2007060618 W JP2007060618 W JP 2007060618W WO 2007148506 A1 WO2007148506 A1 WO 2007148506A1
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K45/00—Medicinal preparations containing active ingredients not provided for in groups A61K31/00 - A61K41/00
- A61K45/06—Mixtures of active ingredients without chemical characterisation, e.g. antiphlogistics and cardiaca
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/24—Homopolymers or copolymers of amides or imides
- C08L33/26—Homopolymers or copolymers of acrylamide or methacrylamide
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/045—Hydroxy compounds, e.g. alcohols; Salts thereof, e.g. alcoholates
- A61K31/05—Phenols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/56—Compounds containing cyclopenta[a]hydrophenanthrene ring systems; Derivatives thereof, e.g. steroids
- A61K31/565—Compounds containing cyclopenta[a]hydrophenanthrene ring systems; Derivatives thereof, e.g. steroids not substituted in position 17 beta by a carbon atom, e.g. estrane, estradiol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/56—Compounds containing cyclopenta[a]hydrophenanthrene ring systems; Derivatives thereof, e.g. steroids
- A61K31/565—Compounds containing cyclopenta[a]hydrophenanthrene ring systems; Derivatives thereof, e.g. steroids not substituted in position 17 beta by a carbon atom, e.g. estrane, estradiol
- A61K31/566—Compounds containing cyclopenta[a]hydrophenanthrene ring systems; Derivatives thereof, e.g. steroids not substituted in position 17 beta by a carbon atom, e.g. estrane, estradiol having an oxo group in position 17, e.g. estrone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/56—Compounds containing cyclopenta[a]hydrophenanthrene ring systems; Derivatives thereof, e.g. steroids
- A61K31/57—Compounds containing cyclopenta[a]hydrophenanthrene ring systems; Derivatives thereof, e.g. steroids substituted in position 17 beta by a chain of two carbon atoms, e.g. pregnane or progesterone
- A61K31/573—Compounds containing cyclopenta[a]hydrophenanthrene ring systems; Derivatives thereof, e.g. steroids substituted in position 17 beta by a chain of two carbon atoms, e.g. pregnane or progesterone substituted in position 21, e.g. cortisone, dexamethasone, prednisone or aldosterone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/56—Compounds containing cyclopenta[a]hydrophenanthrene ring systems; Derivatives thereof, e.g. steroids
- A61K31/58—Compounds containing cyclopenta[a]hydrophenanthrene ring systems; Derivatives thereof, e.g. steroids containing heterocyclic rings, e.g. danazol, stanozolol, pancuronium or digitogenin
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/52—Amides or imides
- C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F20/56—Acrylamide; Methacrylamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L39/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions of derivatives of such polymers
- C08L39/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
- C08L39/06—Homopolymers or copolymers of N-vinyl-pyrrolidones
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
Definitions
- the present invention relates to a temporary fixing method and a surface protecting method of a member to be processed when various members are processed, and to a resin composition and an adhesive suitable for the method.
- the surface protective sheet protects the circuit surface of the wafer and the non-processed surface of the optical component, and temporarily fixes the substrate to the substrate via the surface protective sheet.
- the back surface opposite to the circuit surface is ground, so that the back surface is ground.
- the thickness of wafers at the industrial level is generally 150 ⁇ m, but increasingly thinner wafers are required!
- the wafer is made thinner and thinner, the phenomenon that the ground surface (back surface) becomes non-uniform due to the unevenness of the circuit surface, that is, the circuit pattern back surface transfer phenomenon becomes significant.
- the cause of the back surface transfer phenomenon is explained as follows.
- the pressure-sensitive adhesive surface protection sheet currently in use has a limit to the ability to follow the irregularities of the semiconductor wafer circuit. For this reason, a gap (air pocket) is interposed between the adhesive layer and the circuit surface, and the wafer is not directly supported by the adhesive (protective layer) in that region.
- the scribe line moves the wafer vertically between the circuit dies while compressing the air pockets. It is not ground in the region and is thicker than other parts.
- the wafer is more shaved and consequently thinner than other parts.
- a conventional surface protective sheet is generally a sheet having an adhesive layer as a surface protective layer on a polymer film material.
- the adhesive is designed to have a low elastic modulus so as to follow the irregularities on the circuit surface.
- this tendency is too strong, when the sheet is peeled from the wafer, a large stress is applied to the wafer, leading to breakage.
- an energy ray easy-peelable protective sheet that cures the adhesive by irradiating energy rays such as ultraviolet rays before peeling the sheet and reduces the adhesive force between the wafer and the protective sheet. It has been developed. However, if the pressure-sensitive adhesive layer is uncured during grinding, it is too soft and the wafer breaks during grinding.
- Patent Document 1 discloses that an energy ray easily peelable protective sheet as described above is attached to a wafer on which a circuit is formed, and after the adhesive layer is cured with energy rays, the wafer is subjected to backside grinding. A grinding method is disclosed.
- the pressure-sensitive adhesive is not a fluid, so that it cannot sufficiently follow the unevenness of the wafer circuit surface.
- Patent Document 2 discloses a hot-melt type semiconductor surface protective sheet.
- a hot-melt type sheet that melts and exhibits fluidity when heated to 60 to 100 ° C. can follow the unevenness of the circuit surface and exhibit excellent grindability.
- this sheet has the property of melting whenever the temperature exceeds the melting point.
- a semiconductor wafer is generally a film used for fixing a chip after being bonded to a protective sheet, that is, a die attachment film (Die Attachment film).
- DAF Metal film forming process by sputtering
- a metal film forming process by sputtering may be subjected to a heating process. For this reason, there has been a problem that the protective sheet is remelted due to the temperature rise in the above process.
- Patent Document 1 Japanese Patent Laid-Open No. 11 026406
- Patent Document 2 Japanese Patent Laid-Open No. 2000-38556
- An object of the present invention is to improve the dimensional accuracy of a member after cutting, and has high adhesive strength, excellent releasability in water, and an environment in which no adhesive remains on the member after separation.
- the object is to provide a photo-curing adhesive having excellent workability.
- the object of the present invention is to protect a circuit surface of a wafer and a non-processed surface of an optical component, particularly when thinning a semiconductor wafer, an optical component, etc. by a back surface grinding method, and a photocurable adhesive having the above characteristics. It is to provide.
- the present inventor is a material that has sufficient followability to the unevenness of the circuit surface of the wafer and the optical component.
- N, N-jetylacrylamide and Z or N-isopropylacrylamide were used, and this had a specific hydrophilicity.
- the present invention provides a surface protection for a workpiece that is intended to protect the portion of the workpiece that is on the surface of the workpiece without being damaged when processing an optical member or the like.
- the workpiece is bonded to the base material, and after the workpiece is processed, the workpiece is recovered by immersing the bonded portion in water and removing the cured body.
- the present invention also provides a temporary fixing method of a workpiece to be processed, and further provides a resin composition and an adhesive suitable for the application.
- the present invention has the following features.
- Component (A) N, N-Jetylacrylamide and / or N-isopropyl acrylamide
- Component (D) The resin composition according to 1 above, which contains a polymerization inhibitor.
- An adhesive comprising the resin composition according to any one of 1 to 6 above.
- the resin composition of the present invention has a high water absorption due to its composition, so that the cured product has high swelling and solubility and good peelability, and the cured product itself is soluble in water. Has high or both properties. Therefore, by using the resin composition of the present invention, the member is bonded and temporarily fixed, and after the temporarily fixed member is processed, the processed member Can be easily removed simply by soaking in water. In addition, since the viscosity of the adhesive before curing can be easily adjusted, the gap can be filled with the resin composition of the present invention according to the shape of the article by arbitrarily adjusting the viscosity.
- the temporary fixing method and the surface protection method of the member of the present invention use a resin composition that reduces the adhesive strength by contact with water. Therefore, the member can be easily fixed only by contacting with water. Compared to conventional adhesives, it has the characteristics that it can be recovered, and it is not necessary to use an organic solvent that is expensive, highly ignitable, or generates a gas harmful to the human body. can get.
- component (A): N, N jetyl acrylamide and Z or N-isopropyl acrylamide can be used.
- One or more selected from the group power consisting of the copolymer power of two or more monomers selected from the group power consisting of N, N-ethylacrylamide, attalyloyl morphophore, and N isopropylacrylamide can be used.
- a homopolymer of N bul-2-pyrrolidone or a copolymer containing at least N bul-2-pyrrolidone is preferable.
- component (C): a polymerization initiator can be used.
- the composition ratio of the component (A) to the component (B) can be arbitrarily determined according to the desired viscosity. That is, when the viscosity is increased, the component (B) is mixed in a large amount, and when the viscosity is decreased, the component (B) is mixed in a small amount. .
- the component (A) is preferably 1 to 50 parts by mass with respect to 100 parts by mass of the total amount of the components (A) and (B).
- the viscosity is adjusted to a high viscosity.
- the polymerization initiator is, for example, a photopolymerization initiator or a redox polymerization initiator. Various known photopolymerization initiators can be used as the photopolymerization initiator.
- heptane 1 monostrength Rubonic acid, 7, 7 dimethyl-2,3 Dioxobicyclo [2. 2. 1] Heptane mono 1-carboxy 2 bromoethyl ester, 7, 7 dimethyl -2, 3 Dioxobicyclo [2. 2. 1] Heptane-1 Carboxy-2 methyl ester, 7, 7 Dimethyl 2, 3 Dioxobicyclo [2. 2. 1] Heptane 1 Camphor quinone derivatives such as rubonic acid chloride; Methyl-1 [4- (methylthio) phenol] 2 Morpholinopropane 1-one, 2-Benzyl-1-2-dimethylamino-1- 1- (4-morpholinophenol) 1-butanone, etc.
- Benzyldiphenylphosphine oxide 2, 4, 6-trimethylbenzoyldiphosphine oxide, Benzyljetoxyphosphine oxide, 2, 4, 6 Trimethylbenzoyldimethoxyphenylphosphine oxide , 2, 4, 6 acyl phosphine oxide derivatives such as trimethyl benzoyl jet phosphine oxide; It is.
- the photopolymerization initiator can be used alone or in combination of two or more. As the photopolymerization initiator, benzyldimethylketal and 2-methyl-1 [4- (methylthio) phenol] 2 morpholinopropane 1one are preferred.
- the red tus polymerization initiator is preferably a redox catalyst containing an organic peroxide and a reducing agent.
- a ketone peroxide such as methyl ethyl ketone peroxide or methylcyclohexanone peroxide and a metal sarcophagus such as cobalt naphthenate or copper naphthenate; or otanoyl peroxide, benzoyl peroxide Di-silver oxide such as oxide, ⁇ , ⁇ ⁇ ⁇ ⁇ Dimethylaline, ⁇ , ⁇ ⁇ ⁇ ⁇ Dimethyl- ⁇ - A combination with a tertiary amine such as toluidine; or a combination of tamennoide oral peroxide, disopropylbenzene hydride oral peroxide and organic thiourea such as thiourea, ethylenethiourea, acetylthiourea, etc.
- organic peroxide such as thi
- the addition ratio of the component (C) to the polymerization initiator is preferably 0.1 to 20 parts by mass with respect to 100 parts by mass of the total amount of the components (A) and (B).
- the addition ratio of the component (C) is more preferably 0.2 to 10 parts by mass. If the ratio of component (C) to be added is 0.1 parts by mass or more, the effect of accelerating curing can be reliably obtained. When the addition ratio of component (C) is 20 parts by mass or less, a sufficient curing rate can be obtained.
- component (C) As a more preferred form, by adding 0.2 parts by mass or more of component (C), the degree of cross-linking of the cured product of the yarn and the product is increased, and the position and the like are not shifted during cutting, and the peelability is improved. This is more preferable.
- the resin composition of the present invention can use a small amount of component (D): a polymerization inhibitor in order to improve its storage stability.
- a polymerization inhibitor include methylno, iduloquinone, hydroquinone, 2,2-methylene monobis (4-methylolene 6-tert-butinolephenol), strength tecol, hydroquinone monomethylenoether, monotertiary butylhydroquinone,
- the use ratio of these polymerization inhibitors is preferably 0.001 to 3 parts by mass with respect to 100 parts by mass of the total amount of component (A) and component (B). Is more preferable.
- the polymerization inhibitor is used in an amount of 0.001 part by mass or more, the storage stability is ensured, and when it is 3 parts by mass or less, good adhesiveness is obtained and it is not uncured.
- a polar organic solvent may be used together.
- the polar organic solvent preferably has a boiling point of 50 ° C or higher and 200 ° C or lower.
- a polar organic solvent having a boiling point within the above range is selected, it is preferable because the cured composition can more reliably exhibit a phenomenon in which the adhesive strength is lowered when it comes into contact with warm water.
- Examples of such a polar organic solvent include alcohols, ketones, esters and the like. Among them, an alcohol is preferably selected as the polar organic solvent.
- Examples of the alcohol include methanol, ethanol, n-propanol, isopropanol, n-butanol, isobutanol, sec-butanol, tert-butanol, n-amyl alcohol, isoamyl alcohol, 2-ethylbutyl alcohol and the like. Can be mentioned.
- Examples of the alcohols include methanol, ethanol, n-propanol, isopropanol, n-butanol, isobutanol, sec-butanol, and tert-butanol having a boiling point of 120 ° C or lower, methanol, ethanol, isopropanol, n-butanol is particularly preferred.
- the addition ratio of the polar organic solvent is preferably 0.5 to: LO parts by mass with respect to 100 parts by mass of the total amount of the components (A) and (B). If the addition ratio is 0.5 parts by mass or more, the peelability can be secured, and if it is 10 parts by mass or less, the cured product of the composition is peeled without fear of lowering the initial adhesiveness.
- a particulate material that does not dissolve in the components (A), (B), and (C) may be used together with the components (A), (B), and (C).
- the particulate material that does not dissolve in the components (A), (B) and (C) may be either organic or inorganic particles.
- organic particles include polyethylene particles, polypropylene particles, crosslinked polymethyl methacrylate particles, and crosslinked polystyrene particles.
- inorganic particles include ceramic particles such as glass, silica, alumina, and titanium.
- the particulate material that does not dissolve in the components (A), (B), and (C) is preferably spherical in terms of improving processing accuracy, that is, controlling the thickness of the adhesive.
- the organic particles include methyl methacrylate monomers, crosslinked polymethyl methacrylate particles obtained as monodisperse particles by a known emulsion polymerization method of a styrene monomer and a crosslinkable monomer, crosslinked polymers.
- Restyrene particles and inorganic particles are preferable because the film thickness of the composition after curing due to the variation in the particle size with less deformation of spherical silica force particles becomes uniform.
- crosslinked polymethyl methacrylate particles and crosslinked polystyrene particles are more preferable.
- the addition ratio of the particulate material is 0 with respect to 100 parts by mass of the total amount of the component (A) and the component (B). 1 to 20 parts by mass is preferable, and 0.1 to 10 parts by mass is particularly preferable. If the addition ratio is 0.1 parts by mass or more, the film thickness of the composition after curing is almost constant, and if it is 20 parts by mass or less, there is no possibility that the initial adhesiveness is lowered.
- the resin composition of the present invention includes various elastomers such as commonly used acrylic rubber, urethane rubber, acrylonitrile-butadiene-styrene rubber, and the like within a range not impairing the object of the present invention; inorganic filler, solvent, Additives such as fillers, reinforcing materials, plasticizers, thickeners, dyes, pigments, flame retardants, silane coupling agents and surfactants may be used.
- the present invention is a method in which a member is bonded and temporarily fixed using a resin composition that comes into contact with water to reduce the adhesive strength, and the temporarily fixed member is processed and then processed.
- the member is temporarily fixed by immersing the member in water and the cured product of the resin composition is removed, whereby various members such as an optical member without using an organic solvent. Can be processed with high accuracy.
- the cured product comes into contact with water, absorbs water, swells and dissolves, and the cured product of the composition can be removed, both in terms of environment and workability.
- the phrase “the cured product absorbs water and swells” means a state in which 10 parts by mass or more of water is absorbed and swollen with respect to 100 parts by mass of the cured product before water absorption.
- the use of the adhesive comprising the resin composition of the present invention ensures the effects of the present invention.
- the peelability in water can be achieved in a short time, and the productivity is also favorable.
- the temperature of the hot water it is possible to bond in a short time using hot water of 30 ° C to 90 ° C, preferably 40 ° C to 90 ° C. This is preferable because the cured product of the agent swells and dissolves and the cured adhesive product can be removed.
- the method of contacting the cured product with water is recommended because the method of immersing the entire joined body in water is simple.
- a member made of a material that can transmit ultraviolet rays is preferable when used as an ultraviolet ray curable adhesive, in which the material of the member used for temporary fixing is not particularly limited.
- examples of such materials include crystal members, glass members, and plastic members. Therefore, the temporary fixing method of the present invention can be applied to temporary fixing in the processing of crystal resonators, glass lenses, plastic lenses, and optical disks. It is.
- the adhesive in the temporary fixing method, assuming that a photocurable adhesive is used as the adhesive, for example, an appropriate amount of adhesive is applied to the adhesive surface of one member to be fixed or the supporting substrate. Then, after applying the adhesive by a method of superimposing the other member or a method of laminating a large number of members to be temporarily fixed and infiltrating the adhesive into the gap, the member is then applied. Examples thereof include a method of temporarily fixing members by irradiating visible light or ultraviolet light to cure the photocurable adhesive.
- the temporarily fixed member is cut into a desired shape, subjected to processing such as polishing, polishing, drilling, etc., and then the member is immersed in water, preferably warm water, to cure the adhesive. Objects can be peeled off by force.
- the present invention provides the above-described resin composition, after the surface of the workpiece is coated and cured, the workpiece is immersed in water after processing, A method for protecting a surface of a workpiece, wherein the cured product is removed. That is, by applying the resin composition to the surface and curing it without processing the workpiece, it is possible to prevent the surface from becoming dirty or chipping during processing.
- the cured product swells or dissolves in contact with water, and the cured product of the greave composition can be removed, which is excellent in terms of environment and workability. The effect is obtained.
- a member made of a material that can transmit ultraviolet rays is preferable when used as an ultraviolet curable adhesive in which the material of the member used for protecting the surface is not particularly limited.
- examples of such a material include a crystal member, a glass member, and a plastic member. Therefore, the surface protection method of the present invention is applicable to surface protection in the processing of a crystal resonator, a glass lens, a plastic lens, and an optical disk.
- Component (A) Component: N, N Jetylacrylamide (DEAA, manufactured by Kojin Co., Ltd.) 50 parts by mass
- MDP 2,2-methylene bis (4 methyl 6-tert-butylphenol
- Tensile shear bond strength Measured according to JIS K 6850. Specifically, using heat-resistant Pyrex (registered trademark, the same shall apply hereinafter) glass (25mm X 25mm X 2. Omm) as the adherend, the bonded area was 8mm in diameter, and two heat-resistant materials were used. Roh bonded to I Rex glass, by the fusion Co. curing apparatus using an electrodeless discharge lamp was cured by the integrated quantity of light 2000mi / C m 2 conditions of a wavelength of 365 nm, to prepare a tensile shear bond strength test specimen . The test specimens were measured for tensile shear bond strength using a universal testing machine at a temperature of 23 ° C and humidity of 50% at a tensile speed of lOmmZmin.
- Peel test The same as above except that the resin composition prepared above was applied to the above heat-resistant glass and was bonded to blue sheet glass (150 mm X 150 mm X 1.7 mm) as a support. The composition was cured under conditions to produce a peel test specimen. The obtained specimen was immersed in warm water (80 ° C.), and the time for the heat-resistant Pyrex (registered trademark) glass to peel was measured.
- a resin composition was prepared in the same manner as in Example 1 except that the raw materials shown in Table 1 were used in the composition shown in Table 1.
- the obtained composition the measurement of the tensile shear adhesive strength and the peel test, the surface protective film peel test, and the surface curability test were conducted in the same manner as in Example 1. The results are shown in Table 1.
- BDK Benzyldimethyl ketal (IRGACUR manufactured by Ciba Specialty Chemicals)
- NIPAM N-isopropylacrylamide (NIPAM manufactured by Kojin Co., Ltd.)
- Polybulol pyrrolidone K-30 Polybulol pyrrolidone (Nippon Shokubai K-30)
- Polybulol pyrrolidone K-85 Polybulol pyrrolidone (Nippon Shokubai K-85)
- Polybulol pyrrolidone K-90 Polybulol pyrrolidone (Nippon Shokubai K-90)
- peel test specimens A and B were prepared in the same manner as in Example 1 and peeled by changing the temperature of hot water at 40 ° C, 50 ° C, 60, 70 ° C. A test and a surface protective film peeling test were conducted. The results are shown in Table 2. As a result, it had peelability at any temperature.
- Example 2 Using the resin composition of Example 2, 150 mm ⁇ 150 mm ⁇ 2 mm metathermal pyrex glass and the blue plate glass used in Example 1 were bonded and cured in the same manner as in Example 1 using dummy glass. Use a dicing machine only for the heat-resistant glass fiber part of this adhesion test specimen. And cut into 10 mm squares. The heat-resistant Pyrex glass did not fall off during cutting, indicating good workability. When the adhesion test specimen, in which only the heat-resistant Pyrex glass part was cut, was immersed in warm water at 80 ° C, it peeled off after 60 minutes.
- a hot-melt type adhesive (Nikkasei Energy Adfix A) was heated to 90 ° C. and dissolved to bond the 150 mm ⁇ 150 mm ⁇ 2 mm metathermal pyrex glass and the blue plate glass used in Example 1. Only the heat-resistant Pyrex glass portion of this adhesion test specimen was cut into 10 mm squares using a dicing machine. The heat-resistant Pyrex glass did not fall off during cutting, indicating good workability.
- test piece was immersed in an N-methylbidrirone solution for 1 day, the cut test piece was collected, and 10 pieces of the cut test pieces peeled off in the same manner as in Example 14 were taken out, and the back side of the cut test piece (hot melt type) Each piece of the surface temporarily fixed with an adhesive was observed using an optical microscope, the maximum width of the portion where the glass was missing was measured, and the average value and standard deviation were obtained. The results are shown in Table 3.
- a 150 mm X 150 mm X 2 mm metathermal pyrethrus glass was bonded using a UV curable PET adhesive tape. Only the heat-resistant Pyrex glass part of this adhesion test specimen was cut into 10 mm square using a dicing machine. The adhesive strength was reduced by irradiating the adhesive tape portion of the test piece with ultraviolet light, and the cut test piece was recovered. Ten pieces of the cut specimens from which the cut specimens were peeled off in the same manner as in Example 14 were taken out, and each piece on the back side of the cut specimen (the surface temporarily fixed with adhesive tape) was observed using an optical microscope. Then, the maximum width of the portion lacking the glass was measured, and the average value and the standard deviation were obtained. The results are shown in Table 3.
- the resin composition of the present invention exhibits high adhesive strength, is less likely to be displaced during processing of the member, and has an effect that a member excellent in dimensional accuracy can be easily obtained. Furthermore, the resin composition of the present invention is characterized in that the adhesive strength is reduced by contact with water, and the bonding force between members or between the member and the jig is reduced, so that the member can be easily recovered. .
- the resin composition of the present invention is industrially useful as an adhesive for temporarily fixing and a surface protecting material for optical lenses, prisms, arrays, silicon wafers, semiconductor mounting components and the like.
- the temporary fixing method of the member of the present invention uses the characteristic resin composition, and therefore is very useful in industry because it is not necessary to use an organic solvent required in the prior art.
- the entire contents of the description, claims and abstract of Japanese Patent Application No. 2006-168635 filed on June 19, 2006 are incorporated herein as the disclosure of the specification of the present invention. Is.
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Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/297,316 US8048258B2 (en) | 2006-06-19 | 2007-05-24 | Resin composition, and temporary fixing method and surface protecting method for members to be processed, by means thereof |
EP07744052A EP2030995B1 (en) | 2006-06-19 | 2007-05-24 | Resin composition, and temporary fixation method and surface protection method for member to be processed each using the resin composition |
DE602007007330T DE602007007330D1 (de) | 2006-06-19 | 2007-05-24 | Harzzusammensetzung und verfahren zur temporären fixierung und oberflächenschutzverfahren für ein teil, das mit der harzzusammensetzung verarbeitet wird |
JP2008522354A JP5254014B2 (ja) | 2006-06-19 | 2007-05-24 | 樹脂組成物及びそれを用いる被加工部材の仮固定方法と表面保護方法 |
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WO2009139356A1 (ja) * | 2008-05-12 | 2009-11-19 | 電気化学工業株式会社 | 硬化性樹脂組成物、それを用いた表面保護方法及び仮固定方法 |
WO2010010900A1 (ja) * | 2008-07-22 | 2010-01-28 | 電気化学工業株式会社 | 部材の仮固定・剥離方法及びそれに好適な仮固定用接着剤 |
JP2010183014A (ja) * | 2009-02-09 | 2010-08-19 | Disco Abrasive Syst Ltd | ウエーハの加工方法 |
WO2012086552A1 (ja) * | 2010-12-22 | 2012-06-28 | ダイセル・サイテック株式会社 | 吸水性樹脂組成物およびこれを用いた積層体 |
JP2012521098A (ja) * | 2009-03-17 | 2012-09-10 | スス マイクロテク リソグラフィー,ゲーエムベーハー | 無機基板用のマイクロ電子仮支持体の高速製作 |
JP2013041973A (ja) * | 2011-08-15 | 2013-02-28 | Disco Abrasive Syst Ltd | 板状物の研削方法 |
JPWO2012077807A1 (ja) * | 2010-12-10 | 2014-05-22 | 日立化成株式会社 | 光学用粘着材樹脂組成物、それを用いた光学用粘着材シート及び画像表示装置 |
KR20160141664A (ko) * | 2015-06-01 | 2016-12-09 | 닛토덴코 가부시키가이샤 | 반도체 이면용 필름 및 그의 용도 |
WO2019004431A1 (ja) * | 2017-06-29 | 2019-01-03 | 株式会社Adeka | 接着剤組成物 |
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US20080289750A1 (en) | 2006-01-13 | 2008-11-27 | Denki Kagaku Kogyo Kabushiki Kaisha | Curable Resin Composition, Surface Protection Method, Temporary Fixation Method, and Separation Method |
JP2011155112A (ja) * | 2010-01-27 | 2011-08-11 | Disco Abrasive Syst Ltd | ウェーハの加工方法 |
WO2011102341A1 (ja) * | 2010-02-16 | 2011-08-25 | 電気化学工業株式会社 | 半導体ブロック接着装置、半導体ブロック接着方法及び半導体ウエハの製造方法 |
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WO2009139356A1 (ja) * | 2008-05-12 | 2009-11-19 | 電気化学工業株式会社 | 硬化性樹脂組成物、それを用いた表面保護方法及び仮固定方法 |
WO2010010900A1 (ja) * | 2008-07-22 | 2010-01-28 | 電気化学工業株式会社 | 部材の仮固定・剥離方法及びそれに好適な仮固定用接着剤 |
JP5675355B2 (ja) * | 2008-07-22 | 2015-02-25 | 電気化学工業株式会社 | 部材の仮固定・剥離方法及びそれに好適な仮固定用接着剤 |
JP2010183014A (ja) * | 2009-02-09 | 2010-08-19 | Disco Abrasive Syst Ltd | ウエーハの加工方法 |
JP2012521098A (ja) * | 2009-03-17 | 2012-09-10 | スス マイクロテク リソグラフィー,ゲーエムベーハー | 無機基板用のマイクロ電子仮支持体の高速製作 |
JPWO2012077807A1 (ja) * | 2010-12-10 | 2014-05-22 | 日立化成株式会社 | 光学用粘着材樹脂組成物、それを用いた光学用粘着材シート及び画像表示装置 |
JP5842825B2 (ja) * | 2010-12-10 | 2016-01-13 | 日立化成株式会社 | 光学用粘着材樹脂組成物、それを用いた光学用粘着材シート及び画像表示装置 |
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JP2013041973A (ja) * | 2011-08-15 | 2013-02-28 | Disco Abrasive Syst Ltd | 板状物の研削方法 |
KR20160141664A (ko) * | 2015-06-01 | 2016-12-09 | 닛토덴코 가부시키가이샤 | 반도체 이면용 필름 및 그의 용도 |
JP2016225496A (ja) * | 2015-06-01 | 2016-12-28 | 日東電工株式会社 | 半導体裏面用フィルム及びその用途 |
KR102479621B1 (ko) * | 2015-06-01 | 2022-12-20 | 닛토덴코 가부시키가이샤 | 반도체 이면용 필름 및 그의 용도 |
WO2019004431A1 (ja) * | 2017-06-29 | 2019-01-03 | 株式会社Adeka | 接着剤組成物 |
JPWO2019004431A1 (ja) * | 2017-06-29 | 2020-04-30 | 株式会社Adeka | 接着剤組成物 |
Also Published As
Publication number | Publication date |
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TW200808841A (en) | 2008-02-16 |
KR101023368B1 (ko) | 2011-03-18 |
KR20090017497A (ko) | 2009-02-18 |
TWI409281B (zh) | 2013-09-21 |
JPWO2007148506A1 (ja) | 2009-11-19 |
US20090196987A1 (en) | 2009-08-06 |
US8048258B2 (en) | 2011-11-01 |
EP2030995A1 (en) | 2009-03-04 |
EP2030995A4 (en) | 2009-07-01 |
EP2030995B1 (en) | 2010-06-23 |
CN101472962A (zh) | 2009-07-01 |
JP5254014B2 (ja) | 2013-08-07 |
DE602007007330D1 (de) | 2010-08-05 |
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