KR960703413A - 스티렌계중합체 제조촉매 및 그것을 이용한 스티렌계 중합체의 제조방법 - Google Patents
스티렌계중합체 제조촉매 및 그것을 이용한 스티렌계 중합체의 제조방법Info
- Publication number
- KR960703413A KR960703413A KR1019950706047A KR19950706047A KR960703413A KR 960703413 A KR960703413 A KR 960703413A KR 1019950706047 A KR1019950706047 A KR 1019950706047A KR 19950706047 A KR19950706047 A KR 19950706047A KR 960703413 A KR960703413 A KR 960703413A
- Authority
- KR
- South Korea
- Prior art keywords
- styrene
- catalyst
- producing
- polymer
- substituent
- Prior art date
Links
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title claims abstract 43
- 229920000642 polymer Polymers 0.000 title claims abstract 19
- 239000003054 catalyst Substances 0.000 title claims abstract 16
- 238000004519 manufacturing process Methods 0.000 title claims abstract 8
- 125000001424 substituent group Chemical group 0.000 claims abstract 7
- 150000003623 transition metal compounds Chemical class 0.000 claims abstract 7
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 claims abstract 6
- 239000003446 ligand Substances 0.000 claims abstract 5
- 150000001450 anions Chemical class 0.000 claims abstract 3
- 150000001768 cations Chemical class 0.000 claims abstract 3
- 150000008040 ionic compounds Chemical class 0.000 claims abstract 3
- 230000000379 polymerizing effect Effects 0.000 claims abstract 3
- 239000002841 Lewis acid Substances 0.000 claims abstract 2
- 150000001336 alkenes Chemical class 0.000 claims abstract 2
- 150000007517 lewis acids Chemical class 0.000 claims abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract 2
- 150000001875 compounds Chemical class 0.000 claims 2
- 229910052751 metal Inorganic materials 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 125000004122 cyclic group Chemical group 0.000 claims 1
- -1 diolefin compound Chemical class 0.000 claims 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 claims 1
- 229910052735 hafnium Inorganic materials 0.000 claims 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims 1
- 229910052747 lanthanoid Inorganic materials 0.000 claims 1
- 150000002602 lanthanoids Chemical class 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- 229910052758 niobium Inorganic materials 0.000 claims 1
- 239000010955 niobium Substances 0.000 claims 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims 1
- 229910052715 tantalum Inorganic materials 0.000 claims 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 229910052726 zirconium Inorganic materials 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
- C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F12/06—Hydrocarbons
- C08F12/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
- C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/28—Titanium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
Abstract
1. 청구 범위에 기재된 발명이 속한 기술분야
본 발명은 신규의 스티렌계중합체 제조촉매 및 그것을 이용한 스티렌계중합체의 제조방법에 관한 것이다.
2. 본 발명이 해결하려고 하는 기술적 과제
본 발명은 방향족 비닐 연쇄부가 고도의 신디오탁틱 구조를 갖는 스티렌계중합체를 효율적으로 제조하는 신규의 고활성 촉매 및 당해 촉매를 사용한 스티렌계중합체의 제조방법을 제공하는 것이다.
3. 발명의 해결방법의 요지
본 발명은 5원환측에 적어도 하나의 치환기를 갖는 인데닐기를 π배위자로서 갖는 전이금속화합물을 함유하는 스티렌계중합체 제조촉매, 및 (A) 상기 전이금속화합물, (B) 알루미녹산 및/또는 비배위성 음이온과 양이온과의 이온성 화합물 및 원하는 바에 따라 이용되는 (C) 루이스산으로 된 스티렌계중합체 제조촉매, 및 상기 촉매의 존재하에, 스티렌계단량체를 중합시키고, 또는 스티렌계단량체와 올레핀 등을 중합시켜, 스티렌계중합체를 제조하는 방법이다.
4. 발명의 중요한 용도
본 발명의 스티렌계 중합체 제조촉매는 5원환측에 적어도 하나의 치환기를 갖는 인데닐기를 π배위자로서 갖는 전이금속화합물을 합유하는 것이며, 고활성을 갖고, 당해 촉매를 이용하는 것에 의해, 방향족 비닐 연쇄부가 고도의 신디오탁틱구조를 갖는 스티렌계중합체를 효율 좋게 제조하도록 한 것이다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (8)
- 5원환측에 적어도 하나의 치환기를 갖는 인데닐기를 π배위자로서 갖는 전이금속화합물을 함유하여 되는 스티렌계중합체 제조촉매.
- (A) 5원환측에 적어도 하나의 치환기를 갖는 인데닐기를 π배위자로서 갖는 전이금속화합물 및 (B) ①알루미녹산 및 ② 비배위성 음이온과 양이온과 이온성 화합물의 적어도 1종의 화합물로 된 스티렌계중합체 제조촉매.
- (A) 5원환측에 적어도 하나의 치환기를 갖는 인데닐기를 π배위자로서 갖는 전이금속화합물 및 (B) ①알루미녹산 및 ② 비배위성 음이온과 양이온과의 이온성 화합물의 적어도 1종의 화합물및 (C)루이스산으로 된 스티렌계중합체 제조촉매.
- 제1항, 제2항 또는 제3항 중의 어느 한 항에 있어서, 전이금속화합물의 금속이 티타늄, 지르코늄, 하프늄, 란타노이드계 금속, 니오븀, 탄탈륨에서 선택된 적어도 1종인 스티렌계중합체 제조촉매.
- 제1항, 제2항 또는 제3항 중의 어느 한 항에 있어서, 5원환측에 적어도 하나의 치환기를 갖는 인데닐기의 치환기가 탄소수 1~20의 알킬기인 스티렌계중합체 제조촉매.
- 제2항 또는 제3항 중의 어느 한 항에 있어서, (B) 알루미녹산이 쇄상 알루미녹산 또는 환상 알루미녹산인 스티렌계중합체 제조촉매.
- 제1항 또는 제6항 중의 어느 한 항에 기재된 촉내의 존재하에, (a) 스티렌계단량체를 중합시키는 것을 특징으로 하는 스티렌계중합체의 제조방법.
- 제1항 또는 제6항 중의 어느 한 항에 기재된 촉매의 존재하에, (a) 스티렌계단량체와 (b) 올레핀, 디올레핀화합물 및 아세틸렌류 중에서 선택된 적어도 1종을 중합시키는 것을 특징으로 하는 스티렌계중합체의 제조방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5164529A JPH0733812A (ja) | 1993-07-02 | 1993-07-02 | スチレン系重合体製造触媒及びそれを用いたスチレン系重合体の製造方法 |
JP93-164529 | 1993-07-02 | ||
PCT/JP1994/001078 WO1995001378A1 (fr) | 1993-07-02 | 1994-07-01 | Catalyseur de production d'un polymere de styrene et procede de production d'un polymere de styrene l'utilisant |
Publications (1)
Publication Number | Publication Date |
---|---|
KR960703413A true KR960703413A (ko) | 1996-08-17 |
Family
ID=15794904
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019950706047A KR960703413A (ko) | 1993-07-02 | 1994-07-01 | 스티렌계중합체 제조촉매 및 그것을 이용한 스티렌계 중합체의 제조방법 |
Country Status (6)
Country | Link |
---|---|
US (1) | US5747614A (ko) |
EP (1) | EP0707013B1 (ko) |
JP (1) | JPH0733812A (ko) |
KR (1) | KR960703413A (ko) |
DE (1) | DE69421813T2 (ko) |
WO (1) | WO1995001378A1 (ko) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3369294B2 (ja) * | 1994-03-11 | 2003-01-20 | 出光興産株式会社 | 遷移金属化合物、それを用いた重合用触媒及び該重合用触媒を用いたスチレン系重合体の製造方法 |
DE4431838A1 (de) * | 1994-09-07 | 1996-03-14 | Basf Ag | Geträgerte Metallocen-Katalysatorsysteme |
DE19522013A1 (de) * | 1995-06-21 | 1997-01-02 | Hoechst Ag | Übergangsmetallverbindung |
CA2192156C (en) * | 1995-12-08 | 2006-07-11 | Nobuhiro Tsujimoto | Catalyst and process for producing conjugated diene polymer |
IT1283282B1 (it) * | 1996-03-21 | 1998-04-16 | Enichem Spa | Procedimento per la preparazione di polimeri vinilaromatici cristallini a struttura predominantemente sindiotattica |
US6225426B1 (en) * | 1996-04-10 | 2001-05-01 | Uniroyal Chemical Company, Inc. | Process for producing polyolefin elastomer employing a metallocene catalyst |
JP2000248015A (ja) | 1999-02-26 | 2000-09-12 | Idemitsu Petrochem Co Ltd | オレフィン−スチレン類共重合用触媒及びオレフィン−スチレン系共重合体の製造方法 |
US6291386B1 (en) * | 1999-05-25 | 2001-09-18 | Equistar Chemicals, Lp | Process for the in-situ preparation of single-site transition metal catalysts and polymerization process |
JP4542657B2 (ja) * | 2000-02-21 | 2010-09-15 | 日本ポリオレフィン株式会社 | 多置換インデン誘導体およびその製造方法 |
JP2002179714A (ja) * | 2000-12-12 | 2002-06-26 | Idemitsu Petrochem Co Ltd | 重合体混合物の製造方法 |
ITMN20070043A1 (it) | 2007-11-30 | 2009-06-01 | Pe Labellers Spa | Macchina etichettatrice per etichette stampate su film continuo. |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
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US5155080A (en) * | 1988-07-15 | 1992-10-13 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
KR950012724B1 (ko) * | 1989-03-20 | 1995-10-20 | 이데미쓰 고산 가부시끼가이샤 | 스티렌계 혼성중합체 및 그 제조방법 |
AU628194B2 (en) * | 1989-07-28 | 1992-09-10 | Idemitsu Kosan Co. Ltd | Process for producing styrene polymers |
EP0427697B1 (en) * | 1989-10-10 | 1996-05-08 | Fina Technology, Inc. | Metallocene catalysts with Lewis acids and aluminum alkyls |
EP0426638B2 (en) * | 1989-10-30 | 2005-03-02 | Fina Technology, Inc. | Addition of aluminium alkyl for improved metallocene catalyst |
US5387568A (en) * | 1989-10-30 | 1995-02-07 | Fina Technology, Inc. | Preparation of metallocene catalysts for polymerization of olefins |
DE69018376T3 (de) * | 1989-10-30 | 2002-05-16 | Fina Technology, Inc. | Herstellung von Metallocenkatalysatoren für Olefinpolymerisation. |
JP2883695B2 (ja) * | 1990-08-06 | 1999-04-19 | 三井化学株式会社 | 新規遷移金属化合物 |
JP2840462B2 (ja) * | 1990-12-28 | 1998-12-24 | 出光興産株式会社 | スチレン系重合体の製造方法及びその触媒 |
JP2888648B2 (ja) * | 1990-12-28 | 1999-05-10 | 出光興産株式会社 | スチレン系重合体の製造方法及びその触媒 |
JP2939354B2 (ja) * | 1991-03-26 | 1999-08-25 | 出光興産株式会社 | スチレン系重合体の製造方法及びその触媒 |
EP0505997B1 (en) * | 1991-03-29 | 1997-05-28 | Idemitsu Kosan Company Limited | Process for producing styrenic polymer and copolymer |
JP2951438B2 (ja) * | 1991-06-12 | 1999-09-20 | 出光興産株式会社 | スチレン系重合体の製造方法及びその触媒 |
JPH04366109A (ja) * | 1991-06-12 | 1992-12-18 | Idemitsu Kosan Co Ltd | スチレン系重合体の製造方法及びその触媒 |
JP2988071B2 (ja) * | 1991-10-14 | 1999-12-06 | 東ソー株式会社 | 芳香族ビニル化合物重合用触媒および芳香族ビニル化合物重合体の製造方法 |
DE69224463T2 (de) * | 1991-11-28 | 1998-07-09 | Showa Denko Kk | Neues Metallocen und Verfahren zur Herstellung von Polyolefinen unter Verwendung desselben |
JP3194438B2 (ja) * | 1992-01-08 | 2001-07-30 | 出光興産株式会社 | スチレン系重合体の製造方法及びその触媒 |
US5434115A (en) * | 1992-05-22 | 1995-07-18 | Tosoh Corporation | Process for producing olefin polymer |
JP3216662B2 (ja) * | 1992-10-08 | 2001-10-09 | 出光興産株式会社 | スチレン系重合体の製造方法 |
DE4344688A1 (de) * | 1993-12-27 | 1995-06-29 | Hoechst Ag | Metallocenverbindung |
US5594080A (en) * | 1994-03-24 | 1997-01-14 | Leland Stanford, Jr. University | Thermoplastic elastomeric olefin polymers, method of production and catalysts therefor |
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1993
- 1993-07-02 JP JP5164529A patent/JPH0733812A/ja active Pending
-
1994
- 1994-07-01 KR KR1019950706047A patent/KR960703413A/ko not_active Application Discontinuation
- 1994-07-01 DE DE69421813T patent/DE69421813T2/de not_active Expired - Fee Related
- 1994-07-01 EP EP94919841A patent/EP0707013B1/en not_active Expired - Lifetime
- 1994-07-01 US US08/569,121 patent/US5747614A/en not_active Expired - Fee Related
- 1994-07-01 WO PCT/JP1994/001078 patent/WO1995001378A1/ja active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
JPH0733812A (ja) | 1995-02-03 |
US5747614A (en) | 1998-05-05 |
DE69421813T2 (de) | 2000-05-18 |
EP0707013B1 (en) | 1999-11-24 |
DE69421813D1 (de) | 1999-12-30 |
EP0707013A1 (en) | 1996-04-17 |
WO1995001378A1 (fr) | 1995-01-12 |
EP0707013A4 (en) | 1996-06-12 |
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