KR940011491A - 올레핀 중합용 촉매와 그를 사용하는 올래핀 중합방법 - Google Patents

올레핀 중합용 촉매와 그를 사용하는 올래핀 중합방법 Download PDF

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KR940011491A
KR940011491A KR1019930024662A KR930024662A KR940011491A KR 940011491 A KR940011491 A KR 940011491A KR 1019930024662 A KR1019930024662 A KR 1019930024662A KR 930024662 A KR930024662 A KR 930024662A KR 940011491 A KR940011491 A KR 940011491A
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olefin polymerization
compound
catalyst
acid
ligand
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KR1019930024662A
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KR0128041B1 (ko
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다까시 다시로
다까시 우에다
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고다 시게노리
미쓰이세끼유 가가꾸고오교오 가부시끼가이샤
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Priority claimed from JP32451092A external-priority patent/JP3387946B2/ja
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/645—Component covered by group C08F4/64 with a metal or compound covered by group C08F4/44, not provided for in a single group of groups C08F4/642 - C08F4/643
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

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  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

(A) 시클로펜타디에닐 골격을 갖는 리간드를 함유하는 주기율표 ⅣB족의 천이 금속화합물, (B) 유기알루미늄화합물, (C1) 브론스테드산, (C2) (C-1) 마그네슘화합물, (C-2) 전자공여체와 접속시켜 얻은 물질 및 (C3) (C-1) 마그네슘화합물, (C-2) 전자공여체(C-3) 유기금속화합물을 서로 접촉시켜 얻은 물질중 어느 하나로 구성되는 올레핀 중합용 촉매를 개시하고 또한 상술한 올레핀 중합용 촉매의 존재하에서 올레핀을 중합하기 위한 방법을 개시한다. 상술한 바와같은 그러한 올레핀 중합용 촉매 및 중합방법은 올레핀 중합활성도와 경제적 효율이 우수하다.

Description

올레핀 중합용 촉매와 그를 사용하는 올레핀 중합방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명에 의한 올레핀 중합용 촉매 제조방법의 설명도,
제2도는 본 발명에 의한 올레핀 중합용 촉매의 또다른 제조방법의 설명도.

Claims (16)

  1. 하기 성분으로 구성된 것이 특징인 올레핀 중합용 촉매 (A) 시클로펜타디에닐 골격을 갖는 리간드를 함유하는 주기율표 ⅣB족의 천이 금속화합물, (B) 유기알루미늄화합물, (C1) 브론스테드산.
  2. 제1항에 있어서, 상기 브론스테드산(C1)이 고체산인 것이 특징인 올레핀 중합용 촉매.
  3. 제2항에 있어서, 상기 고체산이 이온 교환물질인 것이 특징인 올레핀 중합용 촉매.
  4. 제2항에 있어서, 상기 고체산은 헤테로 폴리액시드인 것이 특징인 올레핀 중합용 촉매.
  5. 제1항에 있어서, 브론스테드산(C1)이 유기산인 것이 특징인 올레핀 중합용 촉매.
  6. 제5항에 있어서, 유기산이 설폰산인 것이 특징인 올레핀 중합용 촉매.
  7. 하기 성분으로 구성된 곳이 특징인 올레핀 중합용 촉매 (A) 시클로펜타디에닐 골격을 갖는 리간드를 함유하는 주기율표 ⅣB족의 천이 금속화합물, (B) 유기알루미늄화합물, (C2) (C-1) 마그네슘화합물과 (C-2) 전자공여체를 접촉시켜 얻은 물질.
  8. 하기 성분으로 구성된 것이 특징인 올레핀 중합용 촉매 (A) 시클로펜타디에닐 골격을 갖는 리간드를 함유하는 주기율표 ⅣB족의 천이 금속화합물, (B) 유기알루미늄 화합물, (C3) (C1-) 마그네슘화합물, (C-2) 전자공여체, (C-3) 유기금속화합물을 서로 접촉시켜 얻은 물질.
  9. 하기 성분으로 구성된 올레핀 중합용 촉매의 존재하에서 올레핀을 중합시키는 것이 특징인 올레핀 중합방법. (A) 시클로펜타디에닐 골격을 갖는 리간드를 함유하는 주기율표 ⅣB족의 천이 금속화합물, (B) 유기알루미늄 화합물, (C1) 브론스테드산.
  10. 제9항에 있어서, 상기 브론스테드산(C1)이 고체산인 것이 특징인 올레핀 중합방법.
  11. 제10항에 있어서, 상기 고체산이 이온 교환물질인 것이 특징인 올레핀 중합방법.
  12. 제10항에 있어서, 상기 고체산이 헤테로 폴리산인 것이 특징인 올레핀 중합 방법.
  13. 제9항에 있어서, 브론스테드산(C1)이 유기산인 것이 특징인 올레핀 중합용 방법.
  14. 제13항에 있어서, 유기산이 설폰산인 것이 특징인 올레핀 중합방법.
  15. 하기 성분으로 구성된 올레핀 중합용 촉매의 존재하에서 올레핀을 중합하는 것이 특징인 올레핀 중합방법. (A) 시클로펜타디에닐 골격을 갖는 리간드를 함유하는 주기율표 ⅣB족의 천이 금속화합물, (B) 유기알루미늄 화합물, (C1) 마그네슘화합물와 (C-2) 전자공여체를 접촉시켜 얻은 물질.
  16. 하기 성분으로 구성되는 올레핀 중합용 촉매의 존재하에서 올레핀을 중합하는 것이 특징인 올레핀 중합방법. (A) 시클로펜타디에닐 골격을 갖는 리간드를 함유하는 주기율표 ⅣB족의 천이 금속화합물, (B) 유기 알루미늄 화합물, (C3) (C2) (C-1) (C1-C1) 마그네슘화합물, (C-2) 전자공여체, (C-3) 유기금속화합물을 서로 접촉시켜 얻은 물질.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930024662A 1992-11-18 1993-11-18 올레핀 중합용 촉매와 그를 사용하는 올레핀 중합방법 KR0128041B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP92-309087 1992-11-18
JP4309087A JPH06157651A (ja) 1992-11-18 1992-11-18 オレフィン重合用触媒およびこれを用いるオレフィンの重合方法
JP92-324510 1992-12-03
JP32451092A JP3387946B2 (ja) 1992-12-03 1992-12-03 オレフィン重合用触媒およびオレフィンの重合方法

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KR940011491A true KR940011491A (ko) 1994-06-21
KR0128041B1 KR0128041B1 (ko) 1998-04-04

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EP (1) EP0598609B1 (ko)
KR (1) KR0128041B1 (ko)
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DE (1) DE69310101T2 (ko)

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US6022934A (en) 2000-02-08
US5703181A (en) 1997-12-30
KR0128041B1 (ko) 1998-04-04
DE69310101T2 (de) 1997-09-25
DE69310101D1 (de) 1997-05-28
EP0598609A3 (ko) 1994-08-03
EP0598609B1 (en) 1997-04-23
CA2103301C (en) 2000-05-23
CA2103301A1 (en) 1994-05-19
EP0598609A2 (en) 1994-05-25

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