KR900700725A - 전도성 벌집형 본체 및 배출가스 촉매장치 지지체로서의 그 작동 및 감시방법 - Google Patents
전도성 벌집형 본체 및 배출가스 촉매장치 지지체로서의 그 작동 및 감시방법Info
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- KR900700725A KR900700725A KR1019890702446A KR890702446A KR900700725A KR 900700725 A KR900700725 A KR 900700725A KR 1019890702446 A KR1019890702446 A KR 1019890702446A KR 890702446 A KR890702446 A KR 890702446A KR 900700725 A KR900700725 A KR 900700725A
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- honeycomb body
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- conductive honeycomb
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- 239000003054 catalyst Substances 0.000 title claims description 8
- 238000000034 method Methods 0.000 title claims 6
- 238000012544 monitoring process Methods 0.000 title claims 4
- 230000003197 catalytic effect Effects 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims 5
- 239000000919 ceramic Substances 0.000 claims 4
- 239000011248 coating agent Substances 0.000 claims 4
- 238000010438 heat treatment Methods 0.000 claims 3
- 239000000853 adhesive Substances 0.000 claims 1
- 230000001070 adhesive effect Effects 0.000 claims 1
- 238000006555 catalytic reaction Methods 0.000 claims 1
- 229910010293 ceramic material Inorganic materials 0.000 claims 1
- 238000002485 combustion reaction Methods 0.000 claims 1
- 238000005260 corrosion Methods 0.000 claims 1
- 230000007797 corrosion Effects 0.000 claims 1
- 230000008878 coupling Effects 0.000 claims 1
- 238000010168 coupling process Methods 0.000 claims 1
- 238000005859 coupling reaction Methods 0.000 claims 1
- 238000010285 flame spraying Methods 0.000 claims 1
- 238000009434 installation Methods 0.000 claims 1
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 230000001105 regulatory effect Effects 0.000 claims 1
- 230000002787 reinforcement Effects 0.000 claims 1
- 238000005096 rolling process Methods 0.000 claims 1
- 238000009827 uniform distribution Methods 0.000 claims 1
- 238000010586 diagram Methods 0.000 description 2
- 238000005485 electric heating Methods 0.000 description 1
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2803—Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
- F01N3/2807—Metal other than sintered metal
- F01N3/281—Metallic honeycomb monoliths made of stacked or rolled sheets, foils or plates
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
- F01N3/2006—Periodically heating or cooling catalytic reactors, e.g. at cold starting or overheating
- F01N3/2013—Periodically heating or cooling catalytic reactors, e.g. at cold starting or overheating using electric or magnetic heating means
- F01N3/2026—Periodically heating or cooling catalytic reactors, e.g. at cold starting or overheating using electric or magnetic heating means directly electrifying the catalyst substrate, i.e. heating the electrically conductive catalyst substrate by joule effect
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N9/00—Electrical control of exhaust gas treating apparatus
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2330/00—Structure of catalyst support or particle filter
- F01N2330/02—Metallic plates or honeycombs, e.g. superposed or rolled-up corrugated or otherwise deformed sheet metal
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2330/00—Structure of catalyst support or particle filter
- F01N2330/30—Honeycomb supports characterised by their structural details
- F01N2330/44—Honeycomb supports characterised by their structural details made of stacks of sheets, plates or foils that are folded in S-form
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/40—Engine management systems
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24149—Honeycomb-like
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Toxicology (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Exhaust Gas After Treatment (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 스타트 촉매장치 및 주촉매장치에 대한 여러위치를 표시한 자동차의 2분기 배기시스템의 일부를 나타낸 개략도,
제2도는 전기로 가열되는 촉장치의 기본 회도,
제3도는 원판별로 가열되는 촉매장치의 기본회로도.
Claims (18)
- 유체가 흐를 수 있는 다수의 채널을 형성하는 적어도 부분적으로 구조화된 고온 내부식성 시트(51,52; 61,62; 71,72; 81,82; 91,92; 101,102; 121,122; 151,152; 161,162; 171,172;)의 감겨지거나 집적된 층으로 이루어진, 바람직하게는 평형시트와 파형시트의 층으로 이루어진, 특히 배출가스 촉매장치용 지지체로서의 전도성 벌집형본체(50; 60; 80; 100; 110; 120; 140; 150; 160;)에 있어서, 시트(51,52; 61,62; 71,72; 81,82; 91,92; 101,102; 121,122; 151,152; 161,162; 171,172;)를 통한 최소한 하나의 전류통로에 0.03 내지 2Ω, 바람직하게는 0, 1 내지 1Ω, 특히 약 0.6Ω의 저항이 얻어지도록 갭(118) 및/ 또는 전기절연된 중간층(58; 68; 88; 98; 108; 128; 148; 178) 또는 코팅에 의해 그 횡단면 및/ 또는 그 축방향폭에 대해 전기적으로 세분되는 것을 특징으로 하는 전도성 벌집형 본체.
- 제1항에 있어서, 벌집형본체(60; 80; 100)는 그 횡단면 및/ 또는 그 축방향 폭에 대해 부분적으로 서로 전기절연된 부분영역으로 세분되며, 상기 부분영역은 정해진 전기커넥팅브리지(73;65;66;116)에 의해 전체가 또는 그룹별로 전기적으로 직렬로 접속되어 있는 것을 특징으로 하는 전도성 벌집형 본체.
- 제1항 또는 2항에 있어서, 각각의 전류통로는 최소한4개의 전류가 흐를 수 있는 평행하게 인접한 시트층, 바람직하게는 8내지 12개의 시트층으로 구성되는 것을 특징으로 하는 전도성 벌집형 본체.
- 제3항에 있어서, 최소한 4개의 전류가 흐를 수 있는 평행하게 인접한 시트층은 우곡형(57)으로 하나의 본체(50)로 층을 이루고 중간층(58)은 우곡형루프의 맞은편 절연작용을 하는 것을 특징으로 하는 전도성 벌집형본체.
- 제4항에 있어서, 전향부(73)의 부분에는 최소한 4개의 층이 평평하게 접해 놓이며, 이 부분의 전기저항을 강하시키는 부가의 보강재(74)가 설치될 수 있는 것을 특징으로 하는 전도성 벌집형부재.
- 제1항, 2항 또는 3항에 있어서, 벌집형 본체(60)는 거의 U형으로 휘어진 층(61,62)으로 구성되고, 상기층은 중간층(68)또는 코팅에 의해 그룹별로 서로 전기절연되어 있으며 지지벽(65,66,69)에 고정되어 있고, 지지벽(65,66,69)은 서로에 대해 절연된 전도성 부분(65,66)을 가지며 상기 부분은 층의 2개 또는 다수그룹을 직렬 접속시키는 것을 특징으로 하는 전도성 벌집형 본체.
- 제1항, 2항 또는 3항에 있어서, 벌집형 본체(100;120)는 엇갈리게 짜맞춰진 시트(101,102;121,122)의 집적체로 구성되고, 집적체는 적어도 그 상부면 및 하부면에 전기적으로 절연된 층(108;128) 또는 코팅을 가지며 접착체외 각 측면에 있는 시트의 적어도 단부는 서로 전기적으로 도통하도록 접속되고 상기 단부에는 전원(20,30)의 양극에 접속하기 위한 접속부(103,104; 123,124)가 설치되는 것을 특징으로 하는 전도성 벌집형본체.
- 제7항에 있어서, 벌집형본체(100)는 원형횡단면을 가지며 집적체의 높이는 횡단면의 직경의 3배보다 작거나 같은 것을 특징으로 하는 전도성 벌집형본체.
- 제1항 내지 8항중의 어느 항에 있어서, 다수의 벌집형본체(100)는 원판형태로 차례로 배열되고 전기적으로 직렬 또는 병렬로 접속되는 것을 특징으로 하는 전도성 벌집형 본체.
- 제1항 내지 9항중 어느 한 항에 있어서, 전기절연된 중간층(58; 68; 88; 108; 128; 148; 178)또는 코팅은 입자형의 세라믹물질로 이루어지며, 상기 물질은 인접면상에 도포되는 바람직하게는 용사(flame spraying)되는 것을 특징으로 하는 전도성 벌집형 본체.
- 제1항 내지 9항중 어느 한 항에 있어서, 전기절연된 중간층(58; 68; 88; 108; 128; 148; 178)은 세라믹부분 또는 세라믹 섬유매트로 이루어지는 것을 특징으로 하는 전도성 벌집형 본체.
- 제11항에 있어서, 금속재킷튜브(90;141)로 부터 시트를 절연시키기 위해 상기 재킷튜브에 납땜된 세라믹 플레이트(98;148)가 사용되는 것을 특징으로 하는 전도성 벌집형 본체.
- 제1항 내지 12항중 어느 한 항에 있어서, 형태끼워맞춤 결합부(173)에 의해 서로 전기적으로 절연된 시트층(171, 172)의 축방향 밀림이 서로 방지되며, 전기절연을 위해 세라믹 중간층(178)이 형태 끼워맞춤결합 부내로 삽입되어 있는 것을 특징으로 하는 전도성 벌집형 본체.
- 제1항 내지 13항중 어느 한 항에 있어서, 전류가 축방향 으로 흐를 수 있는 벌집형본체(140; 150; 160)의 경우 하나 또는 양전면에 최소한(각각)하나의 전기전도력이 좋은 연결대(145; 156; 166)가 설치되며, 상기 연결대는 벌집형 본체(140; 150; 160)의 횡단면위의 전류밀도의 균일한 분배를 개선시키는 것을 특징으로 하는 전도성 벌집형 본체.
- 제14항에 있어서, 연결대(146)중 최소한 하나가 탄성의(144), 전기적으로 잘 도통되는, 내고온성의, 전기절연부(145)에 의해 밖으로 안내되는 인입선(143)에 접속되어 있고, 상기 인입선(143)는 고전류, 예를 들면 50 내지 400 암페어에 적합하면서도 예컨대 연결대(146) 및 절연부(145)사이의 상대운동에 의한 열을 수용할 수 있는 것을 특징으로 하는 전도성 벌집형 본체.
- 내연기관의 배기스템내의 촉매활성코팅을 가진, 적어도 부분적으로 그 재킷 및 지지부에 대해 절연된 전도성 촉매장치용 지지체를 작동시키고 감시하는 방법에 있어서, 촉매장치용 지지체의(온도에 비례하는) 전기저항이 전체적으로 또는 부분영역에서 측정되어 촉매장치 배기시스템의 감시 및/ 또는 조절에 적용되는 것을특징으로 하는 제1항에 따른 촉매장치용 지지체의 작동 또는 감시방법.
- 제16항에 있어서, 촉매장치용 지지체의 전기저항이 예정된 한계치 이하이거나 미달되면 한계치에 도달될때까지 상기 지지체에 가열전력이 공급되며, 상기 예정된 한계치는 바람직하게는 촉매반응이 자체 적으로 유지되는 온도보다 약간위의 촉매장치용 지지체의 저항에 상응하는 것을 특징으로 하는 방법.
- 제16항 또는 17항에 있어서, 촉매장치용 지지체에 공급되는 가열전력 또는 상기 가열전력에 비례하는 값을 적어도 단시간동안 측정함으로써 촉매장치용 지지체의 저항을 일정한 시간간격으로 측정하는 것을 특징으로 하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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DEP3813928.6 | 1988-04-25 | ||
DE3813928 | 1988-04-25 | ||
PCT/EP1989/000439 WO1989010471A1 (fr) | 1988-04-25 | 1989-04-21 | Corps alveolaire electroconducteur, procede pour son controle et sa mise en oeuvre comme support de catalyseur d'echappement |
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Publication Number | Publication Date |
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KR900700725A true KR900700725A (ko) | 1990-08-16 |
KR0143909B1 KR0143909B1 (ko) | 1998-08-17 |
Family
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Application Number | Title | Priority Date | Filing Date |
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KR1019890702445A KR950013644B1 (ko) | 1988-04-25 | 1989-02-13 | 배출가스촉매장치의 반응을 촉진시키기 위한 방법 및 장치 그리고 상기 방법을 실시하기 위한 전기로 가열되는 지지체 |
KR1019890702446A KR0143909B1 (ko) | 1988-04-25 | 1989-04-21 | 전도성 벌집형 본체 조립체 및 배출가스 촉매장치용 지지체 |
Family Applications Before (1)
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KR1019890702445A KR950013644B1 (ko) | 1988-04-25 | 1989-02-13 | 배출가스촉매장치의 반응을 촉진시키기 위한 방법 및 장치 그리고 상기 방법을 실시하기 위한 전기로 가열되는 지지체 |
Country Status (9)
Country | Link |
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US (3) | US5146743A (ko) |
EP (2) | EP0412086B1 (ko) |
JP (4) | JP2654429B2 (ko) |
KR (2) | KR950013644B1 (ko) |
BR (2) | BR8907397A (ko) |
DE (3) | DE8816514U1 (ko) |
ES (1) | ES2011197A6 (ko) |
RU (2) | RU2054123C1 (ko) |
WO (2) | WO1989010470A1 (ko) |
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-
1988
- 1988-04-25 DE DE8816514U patent/DE8816514U1/de not_active Expired
-
1989
- 1989-02-13 WO PCT/EP1989/000129 patent/WO1989010470A1/de active IP Right Grant
- 1989-02-13 EP EP89902757A patent/EP0412086B1/de not_active Expired - Lifetime
- 1989-02-13 BR BR898907397A patent/BR8907397A/pt not_active IP Right Cessation
- 1989-02-13 DE DE58909751T patent/DE58909751D1/de not_active Expired - Lifetime
- 1989-02-13 KR KR1019890702445A patent/KR950013644B1/ko not_active IP Right Cessation
- 1989-02-13 RU SU894831452A patent/RU2054123C1/ru active
- 1989-02-13 JP JP1502547A patent/JP2654429B2/ja not_active Expired - Lifetime
- 1989-04-21 EP EP89905407A patent/EP0412103B2/de not_active Expired - Lifetime
- 1989-04-21 BR BR898907398A patent/BR8907398A/pt not_active IP Right Cessation
- 1989-04-21 RU SU894831449A patent/RU2067191C1/ru active
- 1989-04-21 KR KR1019890702446A patent/KR0143909B1/ko not_active IP Right Cessation
- 1989-04-21 JP JP1505104A patent/JP2825895B2/ja not_active Expired - Lifetime
- 1989-04-21 WO PCT/EP1989/000439 patent/WO1989010471A1/de active IP Right Grant
- 1989-04-21 DE DE8989905407T patent/DE58900537D1/de not_active Expired - Lifetime
- 1989-04-25 ES ES8901438A patent/ES2011197A6/es not_active Expired
-
1990
- 1990-10-25 US US07/604,060 patent/US5146743A/en not_active Expired - Lifetime
- 1990-10-25 US US07/604,199 patent/US5322672A/en not_active Expired - Lifetime
-
1993
- 1993-04-27 US US08/054,348 patent/US5480621A/en not_active Expired - Lifetime
-
1996
- 1996-05-29 JP JP8157478A patent/JP2787826B2/ja not_active Expired - Lifetime
- 1996-05-29 JP JP8157479A patent/JP2787827B2/ja not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
US5146743A (en) | 1992-09-15 |
US5322672A (en) | 1994-06-21 |
WO1989010471A1 (fr) | 1989-11-02 |
KR0143909B1 (ko) | 1998-08-17 |
WO1989010470A1 (fr) | 1989-11-02 |
BR8907398A (pt) | 1991-04-23 |
JPH03504405A (ja) | 1991-09-26 |
JP2825895B2 (ja) | 1998-11-18 |
RU2054123C1 (ru) | 1996-02-10 |
DE8816514U1 (de) | 1989-10-26 |
JPH03500911A (ja) | 1991-02-28 |
EP0412103A1 (de) | 1991-02-13 |
DE58909751D1 (de) | 1997-01-02 |
EP0412103B2 (de) | 1995-04-26 |
EP0412103B1 (de) | 1991-12-04 |
DE58900537D1 (de) | 1992-01-16 |
JPH09150062A (ja) | 1997-06-10 |
US5480621A (en) | 1996-01-02 |
KR900700724A (ko) | 1990-08-16 |
JPH09150063A (ja) | 1997-06-10 |
JP2654429B2 (ja) | 1997-09-17 |
EP0412086B1 (de) | 1996-11-20 |
KR950013644B1 (ko) | 1995-11-13 |
JP2787826B2 (ja) | 1998-08-20 |
EP0412086A1 (de) | 1991-02-13 |
BR8907397A (pt) | 1991-04-23 |
RU2067191C1 (ru) | 1996-09-27 |
ES2011197A6 (es) | 1989-12-16 |
JP2787827B2 (ja) | 1998-08-20 |
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