KR870005980A - 불소화 아크릴단량체 및 그로부터 유도된 중합체의 제조 방법 및 그들을 소수성 및 소유성 처리제로 이용하는 방법 - Google Patents

불소화 아크릴단량체 및 그로부터 유도된 중합체의 제조 방법 및 그들을 소수성 및 소유성 처리제로 이용하는 방법 Download PDF

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KR870005980A
KR870005980A KR860010287A KR860010287A KR870005980A KR 870005980 A KR870005980 A KR 870005980A KR 860010287 A KR860010287 A KR 860010287A KR 860010287 A KR860010287 A KR 860010287A KR 870005980 A KR870005980 A KR 870005980A
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fluorinated
monomer
formula
carbon atoms
hydrogen atom
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KR860010287A
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KR900004647B1 (ko
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조세리나 마리
드쎙 앙드레
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쟝 르블랑제
소시에떼 아토샹
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Priority to KR1019900003611A priority Critical patent/KR920004805B1/ko
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C333/00—Derivatives of thiocarbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C333/02—Monothiocarbamic acids; Derivatives thereof
    • C07C333/08—Monothiocarbamic acids; Derivatives thereof having nitrogen atoms of thiocarbamic groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C271/06—Esters of carbamic acids
    • C07C271/08—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
    • C07C271/10—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C271/18—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of hydrocarbon radicals substituted by doubly-bound oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C271/06—Esters of carbamic acids
    • C07C271/08—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms
    • C07C271/26—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atom of at least one of the carbamate groups bound to a carbon atom of a six-membered aromatic ring
    • C07C271/28—Esters of carbamic acids having oxygen atoms of carbamate groups bound to acyclic carbon atoms with the nitrogen atom of at least one of the carbamate groups bound to a carbon atom of a six-membered aromatic ring to a carbon atom of a non-condensed six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C311/00—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C311/01—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms
    • C07C311/02—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C311/09—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton the carbon skeleton being further substituted by at least two halogen atoms

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Graft Or Block Polymers (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)
  • Polymerisation Methods In General (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)
  • Paints Or Removers (AREA)

Abstract

내용 없음

Description

불소화 아크릴단량체 및 그로부터 유도된 중합체의 제조 방법 및 그들을 소수성 및 소유성 처리제로 이용하는 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 하기 식으로 표시됨을 특징으로 하는 불소화 아크릴 단량체:
    상기 식에서, RF는 직쇄 또는 측쇄를 갖고 2 내지 20 탄소원자를 함유하는 피플루오로알킬라디칼을 나타내고, R은 수소 원자 또는 메틸라디칼을 나타내고, A는 2 내지 9 탄소원자를 갖고 하나 또는 그 이상의 산소원자를 함유할 수 있는 이배위 결합을 나타내고, Q는 산소 또는 유황원자 또는 -NR′-기를 나타내는데, R′은 수소원자 또는 1 내지 4 탄소원자를 함유하는 알킬라디칼을 나타내고, W는 탄소를 통해 Q에 연결된 이배위 결합으로, 하나 또는 그 이상의 산소, 유황 및/또는 질소원자를 함유할 수 있는 것을 나타낸다.
  2. 제2항에 있어서, 퍼플루오로알킬라디칼 RF가 4 내지 16 탄소원자를 함유하는, R이 메틸라디칼이고 A가 -CH2CH2- 가교이고, -Q-W-가 -O-CH2CH2, -S-CH2CH2- 또는 -O-CH2CH2N(R″) SO2CH2CH2-이고, R″이 수소원자 또는 메틸라디칼을 나타냄을 특징으로 하는 단량체.
  3. 제1단계에서, 톨루엔 2,4-디이소시아네이트를 실질적으로 동몰량의 식 (III)의 폴리플루오로화 화합물과 반응시켜
    RF-W-Q-H (III)
    식(IV)의 불소화 우레탄-이소시아네이트를 형성하고
    이를 실질적으로 동몰량의 식 (V)로 표현되는 아크릴에스테르와 반응시키는 것을 특징으로 하는 제1항의 단량체의 제조 방법.
    부호 A,R,RF,Q 및 W는 제1항과 같음.
  4. 제3항에 있어서, 불활성 분위기에서 30 내지 90℃ 범위의 온도로 불활성 유기용매내에서 반응이 수행됨을 특징으로 하는 단량체의 제조 방법.
  5. 제3항 또는 제4항에 있어서, 폴리플루오로화 화합물이 하기식의 화합물 중의 하나에 해당함을 특징으로 하는 단량체의 제조 방법.
    상기 식에서 RF는 4 내지 16 탄소원자를 함유하고 R″은 수소원자 또는 메틸라디칼이다.
  6. 제3항 내지 제5항 중의 하나에 있어서, 에스테르(V)가 2-히드록시에틸메타크릴레이트임을 특징으로 하는 단량체의 제조 방법.
  7. 하기 일반식 (VIII) 단위를 10 내지 100중량% 함유하고, 제1항의 단량체의 단일 중합, 상기 단량체를 불소화된 또는 불소화되지 않은 다른 단량체와 공중합 또는 하기식 (IV)의 불소화우레탄 이소시아네이트를 하기식 (V)의 아크릴 에스테르의 단일 중합체 또는 그 에스테르와 불소화된 또는 불소화되지 않은 단량체의 공중합체에 그라프트하여 제조합을 특징으로 하는 중합체.
    상기 식에서 부호 RF,R,A,Q 및 W는 제1항과 같음.
  8. 제7항에 있어서, 공단량체 또는 공단량체들을 알킬아크릴레이트 또는 메타크릴레이트, 다음 식의 화합물;
    및 그들의 혼합물에서 선택됨을 특징으로 하는 공중합체.
  9. 제7항 또는 제1항의 중합체를 여러가지 재질, 특히 가준을 처리하여 그것으로 하여금 발수성 및 발유성을 갖게 하는 데 이용함을 특징으로 하는 방법.
  10. 제7항 또는 제8항의 중합체로 처리한 물질 및 제품.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860010287A 1985-12-03 1986-12-02 불소화 아크릴 단량체로부터 유도된 중합체의 제조방법 KR900004647B1 (ko)

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KR1019900003611A KR920004805B1 (ko) 1985-12-03 1990-03-17 불소화 아크릴 단량체로부터 유도된 중합체의 제조방법

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR17882 1985-12-03
FR8517882A FR2590895B1 (fr) 1985-12-03 1985-12-03 Monomeres acryliques fluores, polymeres en derivant et leur application comme agents hydrophobes et oleophobes
FR17882/85 1985-12-03

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KR1019900003611A Division KR920004805B1 (ko) 1985-12-03 1990-03-17 불소화 아크릴 단량체로부터 유도된 중합체의 제조방법

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KR900004647B1 KR900004647B1 (ko) 1990-07-02

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US (1) US4920190A (ko)
EP (1) EP0225826B1 (ko)
JP (2) JPS62132850A (ko)
KR (1) KR900004647B1 (ko)
CN (1) CN1010309B (ko)
AT (1) ATE53990T1 (ko)
AU (1) AU596131B2 (ko)
CA (1) CA1260492A (ko)
DE (1) DE3672129D1 (ko)
DK (1) DK578886A (ko)
ES (1) ES2004866A6 (ko)
FI (1) FI90063C (ko)
FR (1) FR2590895B1 (ko)
GR (1) GR862835B (ko)
NO (1) NO167396C (ko)
ZA (1) ZA869088B (ko)

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CA1260492A (fr) 1989-09-26
NO167396B (no) 1991-07-22
FI90063C (fi) 1993-12-27
JPH0328207A (ja) 1991-02-06
FR2590895A1 (fr) 1987-06-05
CN86108160A (zh) 1987-06-17
JPH034542B2 (ko) 1991-01-23
NO167396C (no) 1991-10-30
ATE53990T1 (de) 1990-07-15
KR900004647B1 (ko) 1990-07-02
EP0225826B1 (fr) 1990-06-20
EP0225826A2 (fr) 1987-06-16
US4920190A (en) 1990-04-24
DE3672129D1 (de) 1990-07-26
FI864949A (fi) 1987-06-04
NO864430D0 (no) 1986-11-06
CN1010309B (zh) 1990-11-07
JPS62132850A (ja) 1987-06-16
AU596131B2 (en) 1990-04-26
FR2590895B1 (fr) 1988-01-15
NO864430L (no) 1987-06-04
EP0225826A3 (en) 1988-06-01
ES2004866A6 (es) 1989-02-16
FI864949A0 (fi) 1986-12-03
FI90063B (fi) 1993-09-15
DK578886D0 (da) 1986-12-02
DK578886A (da) 1987-06-04
GR862835B (en) 1987-03-30
ZA869088B (en) 1987-08-26
AU6590086A (en) 1987-06-11

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