JP6038032B2 - セキュリティ要素 - Google Patents
セキュリティ要素 Download PDFInfo
- Publication number
- JP6038032B2 JP6038032B2 JP2013530702A JP2013530702A JP6038032B2 JP 6038032 B2 JP6038032 B2 JP 6038032B2 JP 2013530702 A JP2013530702 A JP 2013530702A JP 2013530702 A JP2013530702 A JP 2013530702A JP 6038032 B2 JP6038032 B2 JP 6038032B2
- Authority
- JP
- Japan
- Prior art keywords
- refractive index
- low
- layer
- waveguide layer
- microstructure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000463 material Substances 0.000 claims description 80
- 238000000034 method Methods 0.000 claims description 23
- -1 polyethylene terephthalate Polymers 0.000 claims description 18
- 238000000151 deposition Methods 0.000 claims description 17
- 239000011159 matrix material Substances 0.000 claims description 17
- 229920000642 polymer Polymers 0.000 claims description 16
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 15
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 15
- 238000004519 manufacturing process Methods 0.000 claims description 13
- 229920003227 poly(N-vinyl carbazole) Polymers 0.000 claims description 12
- 238000004049 embossing Methods 0.000 claims description 11
- 230000008569 process Effects 0.000 claims description 10
- 239000000975 dye Substances 0.000 claims description 9
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 9
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 8
- 230000008021 deposition Effects 0.000 claims description 7
- 239000004417 polycarbonate Substances 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 239000000020 Nitrocellulose Substances 0.000 claims description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 3
- 229920001109 fluorescent polymer Polymers 0.000 claims description 3
- PXZQEOJJUGGUIB-UHFFFAOYSA-N isoindolin-1-one Chemical class C1=CC=C2C(=O)NCC2=C1 PXZQEOJJUGGUIB-UHFFFAOYSA-N 0.000 claims description 3
- 229920001220 nitrocellulos Polymers 0.000 claims description 3
- 229920000515 polycarbonate Polymers 0.000 claims description 3
- 150000004696 coordination complex Chemical class 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 161
- 239000000758 substrate Substances 0.000 description 67
- 239000000203 mixture Substances 0.000 description 15
- 239000000123 paper Substances 0.000 description 13
- 238000000576 coating method Methods 0.000 description 11
- 239000011248 coating agent Substances 0.000 description 10
- 239000004922 lacquer Substances 0.000 description 10
- 230000003287 optical effect Effects 0.000 description 9
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
- 239000012790 adhesive layer Substances 0.000 description 7
- 239000011888 foil Substances 0.000 description 7
- 239000002105 nanoparticle Substances 0.000 description 7
- 230000008859 change Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000010408 film Substances 0.000 description 6
- 239000002086 nanomaterial Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 5
- 239000011247 coating layer Substances 0.000 description 5
- 238000005286 illumination Methods 0.000 description 5
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 5
- 230000005855 radiation Effects 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 238000010894 electron beam technology Methods 0.000 description 4
- 229910052741 iridium Inorganic materials 0.000 description 4
- MILUBEOXRNEUHS-UHFFFAOYSA-N iridium(3+) Chemical compound [Ir+3] MILUBEOXRNEUHS-UHFFFAOYSA-N 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
- 239000004800 polyvinyl chloride Substances 0.000 description 4
- 229920000915 polyvinyl chloride Polymers 0.000 description 4
- 238000010791 quenching Methods 0.000 description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 238000003490 calendering Methods 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 238000001723 curing Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000005284 excitation Effects 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000000976 ink Substances 0.000 description 3
- 239000003446 ligand Substances 0.000 description 3
- 238000004020 luminiscence type Methods 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 125000004430 oxygen atom Chemical group O* 0.000 description 3
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 3
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 3
- HRGDZIGMBDGFTC-UHFFFAOYSA-N platinum(2+) Chemical compound [Pt+2] HRGDZIGMBDGFTC-UHFFFAOYSA-N 0.000 description 3
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 239000011112 polyethylene naphthalate Substances 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- 230000003595 spectral effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- RNJVAUBBYGWVBF-UHFFFAOYSA-N 1-(2-prop-2-enoyloxypropoxy)propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COCC(C)OC(=O)C=C RNJVAUBBYGWVBF-UHFFFAOYSA-N 0.000 description 2
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 229920001131 Pulp (paper) Polymers 0.000 description 2
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000002390 adhesive tape Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 125000005605 benzo group Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002301 cellulose acetate Polymers 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- TXCDCPKCNAJMEE-UHFFFAOYSA-N dibenzofuran Chemical compound C1=CC=C2C3=CC=CC=C3OC2=C1 TXCDCPKCNAJMEE-UHFFFAOYSA-N 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical group C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005538 encapsulation Methods 0.000 description 2
- 235000012438 extruded product Nutrition 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000007850 fluorescent dye Substances 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 239000010985 leather Substances 0.000 description 2
- QDLAGTHXVHQKRE-UHFFFAOYSA-N lichenxanthone Natural products COC1=CC(O)=C2C(=O)C3=C(C)C=C(OC)C=C3OC2=C1 QDLAGTHXVHQKRE-UHFFFAOYSA-N 0.000 description 2
- 229920005615 natural polymer Polymers 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000012994 photoredox catalyst Substances 0.000 description 2
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical compound C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 description 2
- 238000000053 physical method Methods 0.000 description 2
- 230000010287 polarization Effects 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- XSCHRSMBECNVNS-UHFFFAOYSA-N quinoxaline Chemical compound N1=CC=NC2=CC=CC=C21 XSCHRSMBECNVNS-UHFFFAOYSA-N 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 125000001544 thienyl group Chemical group 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 description 1
- VEJOYRPGKZZTJW-FDGPNNRMSA-N (z)-4-hydroxypent-3-en-2-one;platinum Chemical compound [Pt].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O VEJOYRPGKZZTJW-FDGPNNRMSA-N 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- LHENQXAPVKABON-UHFFFAOYSA-N 1-methoxypropan-1-ol Chemical compound CCC(O)OC LHENQXAPVKABON-UHFFFAOYSA-N 0.000 description 1
- TZMSYXZUNZXBOL-UHFFFAOYSA-N 10H-phenoxazine Chemical compound C1=CC=C2NC3=CC=CC=C3OC2=C1 TZMSYXZUNZXBOL-UHFFFAOYSA-N 0.000 description 1
- YOSZEPWSVKKQOV-UHFFFAOYSA-N 12h-benzo[a]phenoxazine Chemical compound C1=CC=CC2=C3NC4=CC=CC=C4OC3=CC=C21 YOSZEPWSVKKQOV-UHFFFAOYSA-N 0.000 description 1
- VVZRKVYGKNFTRR-UHFFFAOYSA-N 12h-benzo[a]xanthene Chemical compound C1=CC=CC2=C3CC4=CC=CC=C4OC3=CC=C21 VVZRKVYGKNFTRR-UHFFFAOYSA-N 0.000 description 1
- BDDQPKXDNUKVCC-UHFFFAOYSA-N 12h-benzo[b]phenoxazine Chemical compound C1=CC=C2C=C3NC4=CC=CC=C4OC3=CC2=C1 BDDQPKXDNUKVCC-UHFFFAOYSA-N 0.000 description 1
- SWAGSGUXOCHFHN-UHFFFAOYSA-N 12h-benzo[b]xanthene Chemical compound C1=CC=C2C=C3CC4=CC=CC=C4OC3=CC2=C1 SWAGSGUXOCHFHN-UHFFFAOYSA-N 0.000 description 1
- GPYLCFQEKPUWLD-UHFFFAOYSA-N 1h-benzo[cd]indol-2-one Chemical compound C1=CC(C(=O)N2)=C3C2=CC=CC3=C1 GPYLCFQEKPUWLD-UHFFFAOYSA-N 0.000 description 1
- VFMUXPQZKOKPOF-UHFFFAOYSA-N 2,3,7,8,12,13,17,18-octaethyl-21,23-dihydroporphyrin platinum Chemical compound [Pt].CCc1c(CC)c2cc3[nH]c(cc4nc(cc5[nH]c(cc1n2)c(CC)c5CC)c(CC)c4CC)c(CC)c3CC VFMUXPQZKOKPOF-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- BCHZICNRHXRCHY-UHFFFAOYSA-N 2h-oxazine Chemical compound N1OC=CC=C1 BCHZICNRHXRCHY-UHFFFAOYSA-N 0.000 description 1
- AGIJRRREJXSQJR-UHFFFAOYSA-N 2h-thiazine Chemical compound N1SC=CC=C1 AGIJRRREJXSQJR-UHFFFAOYSA-N 0.000 description 1
- WADCPEMKIBAJHH-UHFFFAOYSA-N 3,4-diphenylpyrrole-2,5-dione Chemical compound O=C1NC(=O)C(C=2C=CC=CC=2)=C1C1=CC=CC=C1 WADCPEMKIBAJHH-UHFFFAOYSA-N 0.000 description 1
- GOLORTLGFDVFDW-UHFFFAOYSA-N 3-(1h-benzimidazol-2-yl)-7-(diethylamino)chromen-2-one Chemical compound C1=CC=C2NC(C3=CC4=CC=C(C=C4OC3=O)N(CC)CC)=NC2=C1 GOLORTLGFDVFDW-UHFFFAOYSA-N 0.000 description 1
- HQQTZCPKNZVLFF-UHFFFAOYSA-N 4h-1,2-benzoxazin-3-one Chemical compound C1=CC=C2ONC(=O)CC2=C1 HQQTZCPKNZVLFF-UHFFFAOYSA-N 0.000 description 1
- JKOCGAMDKVAHCI-UHFFFAOYSA-N 6,7-Benzocoumarin Chemical compound C1=CC=C2C=C(OC(=O)C=C3)C3=CC2=C1 JKOCGAMDKVAHCI-UHFFFAOYSA-N 0.000 description 1
- VDISGEKPIVMONQ-UHFFFAOYSA-N 7h-benzo[c]phenoxazine Chemical compound C1=CC2=CC=CC=C2C2=C1NC1=CC=CC=C1O2 VDISGEKPIVMONQ-UHFFFAOYSA-N 0.000 description 1
- RGHINSLFCBMCFS-UHFFFAOYSA-N 7h-benzo[c]xanthene Chemical compound C1=CC2=CC=CC=C2C2=C1CC1=CC=CC=C1O2 RGHINSLFCBMCFS-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910002706 AlOOH Inorganic materials 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- DQEFEBPAPFSJLV-UHFFFAOYSA-N Cellulose propionate Chemical compound CCC(=O)OCC1OC(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C1OC1C(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C(COC(=O)CC)O1 DQEFEBPAPFSJLV-UHFFFAOYSA-N 0.000 description 1
- 229920002284 Cellulose triacetate Polymers 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 239000005041 Mylar™ Substances 0.000 description 1
- 241000208125 Nicotiana Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Natural products C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004697 Polyetherimide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 description 1
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 1
- 235000004789 Rosa xanthina Nutrition 0.000 description 1
- 241000109329 Rosa xanthina Species 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 239000004775 Tyvek Substances 0.000 description 1
- 229920000690 Tyvek Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 1
- IXPCJOPIVIEBBA-UHFFFAOYSA-N [Pt+2].N1C(C=C2N=C(C=C3NC(=C4)C=C3)C=C2)=CC=C1C=C1C=CC4=N1 Chemical class [Pt+2].N1C(C=C2N=C(C=C3NC(=C4)C=C3)C=C2)=CC=C1C=C1C=CC4=N1 IXPCJOPIVIEBBA-UHFFFAOYSA-N 0.000 description 1
- GCPWJFKTWGFEHH-UHFFFAOYSA-N acetoacetamide Chemical compound CC(=O)CC(N)=O GCPWJFKTWGFEHH-UHFFFAOYSA-N 0.000 description 1
- CUJRVFIICFDLGR-UHFFFAOYSA-N acetylacetonate Chemical compound CC(=O)[CH-]C(C)=O CUJRVFIICFDLGR-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- RJGDLRCDCYRQOQ-UHFFFAOYSA-N anthrone Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3CC2=C1 RJGDLRCDCYRQOQ-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- XJHABGPPCLHLLV-UHFFFAOYSA-N benzo[de]isoquinoline-1,3-dione Chemical compound C1=CC(C(=O)NC2=O)=C3C2=CC=CC3=C1 XJHABGPPCLHLLV-UHFFFAOYSA-N 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229920001727 cellulose butyrate Polymers 0.000 description 1
- 229920006218 cellulose propionate Polymers 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000000875 corresponding effect Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 125000006575 electron-withdrawing group Chemical group 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 229920002457 flexible plastic Polymers 0.000 description 1
- 229920005570 flexible polymer Polymers 0.000 description 1
- 238000002073 fluorescence micrograph Methods 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- HUVCZKYUWFGVLS-UHFFFAOYSA-N imidazo[4,5-e]thiazine Chemical compound C1=NSC2=NC=NC2=C1 HUVCZKYUWFGVLS-UHFFFAOYSA-N 0.000 description 1
- 239000006115 industrial coating Substances 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 150000002503 iridium Chemical class 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 238000001748 luminescence spectrum Methods 0.000 description 1
- 239000002082 metal nanoparticle Substances 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052754 neon Inorganic materials 0.000 description 1
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000005026 oriented polypropylene Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 238000005293 physical law Methods 0.000 description 1
- SIOXPEMLGUPBBT-UHFFFAOYSA-M picolinate Chemical compound [O-]C(=O)C1=CC=CC=N1 SIOXPEMLGUPBBT-UHFFFAOYSA-M 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001601 polyetherimide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- FYNROBRQIVCIQF-UHFFFAOYSA-N pyrrolo[3,2-b]pyrrole-5,6-dione Chemical compound C1=CN=C2C(=O)C(=O)N=C21 FYNROBRQIVCIQF-UHFFFAOYSA-N 0.000 description 1
- 238000003847 radiation curing Methods 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 230000010076 replication Effects 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 229920006163 vinyl copolymer Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/14—Security printing
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
- G03H1/00—Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
- G03H1/0005—Adaptation of holography to specific applications
- G03H1/0011—Adaptation of holography to specific applications for security or authentication
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/14—Security printing
- B41M3/144—Security printing using fluorescent, luminescent or iridescent effects
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D15/00—Printed matter of special format or style not otherwise provided for
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/20—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
- B42D25/29—Securities; Bank notes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
- B42D25/373—Metallic materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
- B42D25/378—Special inks
- B42D25/387—Special inks absorbing or reflecting ultraviolet light
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
- G03H1/00—Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
- G03H1/02—Details of features involved during the holographic process; Replication of holograms without interference recording
- G03H1/024—Hologram nature or properties
- G03H1/0244—Surface relief holograms
-
- B42D2033/04—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/328—Diffraction gratings; Holograms
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
- G03H2222/00—Light sources or light beam properties
- G03H2222/10—Spectral composition
- G03H2222/15—Ultra Violet [UV]
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
- G03H2240/00—Hologram nature or properties
- G03H2240/50—Parameters or numerical values associated with holography, e.g. peel strength
- G03H2240/54—Refractive index
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Computer Security & Cryptography (AREA)
- Business, Economics & Management (AREA)
- Accounting & Taxation (AREA)
- Finance (AREA)
- Credit Cards Or The Like (AREA)
- Diffracting Gratings Or Hologram Optical Elements (AREA)
Description
本発明は、セキュリティ文書の分野、更に詳細には複写(違法な複写)及び偽造からセキュリティ文書を保護することを目的としたセキュリティ要素の分野である。光、特にUV光で照射した後に回転及び/又は傾斜でのその視覚的外観が変化するセキュリティ機能を有するセキュリティ要素が開示されている。前記セキュリティ要素を含むセキュリティ文書、並びに前記セキュリティ要素の製造方法も開示されている。
多色偏光又は非偏光のためのゼロ次回析フィルタを含み、前記ゼロ次回析フィルタは
低屈折率nlowを有する媒体;及び
高屈折率nhighを有する導波路層;
を含み、
前記媒体及び前記導波路層は、格子線を形成するように配置され、該格子線は、フィルタがそのために設計される光の波長よりも小さい周期長さを有し、前記センサは、低屈折率媒体と導波路層との間の境界面を含み、該境界面はナノ構造を構成し;且つ前記ナノ構造の少なくとも幾つかが蛍光又は燐光材料のいずれか1つによって実現されることを特徴とする、前記センサを記載している。
− 第1の基材を形成する媒体で作られている格子線を提供する工程;
− 複数のナノ構造物を第1の境界面上に堆積させる工程、その際、前記ナノ構造物の少なくとも幾つかが蛍光及び燐光材料のいずれか1つによって実施される;及び
− 少なくとも1つの導波路層を格子線及びナノ構造物上に堆積させる工程、その際、導波路層が媒体よりも高い屈折率を有する
を含む。
低屈折率nlowを有する媒体もしくは基材;
発光材料を含む、高屈折率nhighを有する導波路層;及び
導波路層の表面上の、又は媒体もしくは基材と導波路層との間の境界面での、又は導波路層から500nm、特に200nm、非常に特に50nmよりも小さい距離での回折微細構造
を含み、その際、低屈折率nlowを有する媒体もしくは基材と導波路層との間の屈折率の差が少なくとも0.005、特に少なくとも0.01、非常に特に少なくとも0.1であり;
微細構造の周期(Λ)が100〜1500nm、特に100〜1000nm、非常に特に100〜500nmの範囲であり;
導波路層の質量厚さ(d)が30〜1000nm、特に50〜400nm、非常に特に60〜200nmの範囲であり;且つ
微細構造の深さ(t)が50〜1000nm、特に80〜600nm、非常に特に100〜300nmの範囲である、前記セキュリティ要素によって解決されてきた。
a)低屈折率nlowを有する媒体の層;
b)低屈折率nlowを有する媒体上の回析微細構造;
c)該回析微細構造上に、発光材料を含む、高屈折率nhighを有する導波路層;及び任意に
d)低屈折率nlowを有する媒体の層
を含む。
A)低屈折率nlowを有する媒体の層;
B)該低屈折率nlowを有する媒体上に発光材料を含む、高屈折率nhighを有する導波路層;
C)該高屈折率nhighを有する導波路層上に回析微細構造;及び任意に
D)低屈折率nlowを有する媒体の層
を含む。
が挙げられる。
− 低屈折率nlowを有する媒体を提供する工程、
− エンボシングによって低屈折率nlowを有する媒体中に回折微細構造を形成する工程、
− 該回折微細構造上に発光材料を含む(ポリマー)層(導波路層)を堆積させる工程;及び任意に
− 該導波路層上に低屈折率nlowを有する媒体の層を堆積させる工程;又は
− 低屈折率nlowを有する媒体を提供する工程、
− 該低屈折率nlowを有する媒体上に発光材料を含む(ポリマー)層(導波路層)を堆積させる工程;
− 該導波路層上にエンボシングによって回折微細構造を形成する工程、及び任意に
− 該導波路層上に低屈折率nlowを有する媒体の層を堆積させる工程
を含む。好ましくは全ての堆積工程は、ロールツーロールプロセスの一部である。
A)硬化性組成物(UVプライマー、低屈折率nlowを有する媒体)を基材の少なくとも一部に適用する工程;
B)硬化性組成物の少なくとも一部に回析微細構造を形成する工程;
C)該組成物を硬化する工程;
D)低屈折率nlowを有する媒体上に発光材料(導波路層)を含む(ポリマー)層を堆積させる工程
を含む。
実施例1
深さ140nmで周期270nmの矩形格子は、UV硬化性のOrmocomp(登録商標)材料(Microresist Technology GmbH(独国)から市販されている)中で複製される。
透明な紫外線活性化プライマー[(1−メチル−1,2−エタンジイル)ビス[オキシ(メチル−2,1−エタンジイル)]ジアクリレート(1〜20%)、ポリ(オキシ−1,2−エタンジイル)、α−ヒドロキシ−[(1−オキソ−2−プロペン−1−イル)オキシ]−、2−エチル−2−(ヒドロキシメチル)−1,3−プロパンジオールとのエーテル(3:1)(10〜50%)、オリゴ[2−ヒドロキシ−2−メチル−1−[4−(1−メチルビニル)フェニル]プロパノン](1〜5%)、オキシビス(メチル−2,1−エタンジイル)ジアクリレート(30〜45%)](91質量%)(BASF社製)を、THF中で以下の式
深さ140nmで周期270nmの矩形格子は、透明な紫外線活性化プライマー[(1−メチル−1,2−エタンジイル)ビス[オキシ(メチル−2,1−エタンジイル)]ジアクリレート(1〜20%)、ポリ(オキシ−1,2−エタンジイル)、α−ヒドロキシ−[(1−オキソ−2−プロペン−1−イル)オキシ]−、2−エチル−2−(ヒドロキシメチル)−1,3−プロパンジオールとのエーテル(3:1)(10〜50%)、オリゴ[2−ヒドロキシ−2−メチル−1−[4−(1−メチルビニル)フェニル]プロパノン](1〜5%)、オキシビス(メチル−2,1−エタンジイル)ジアクリレート(30〜45%)](91重量%)中にニッケルシムを用いてグラビア印刷によってUV鋳造される。矩形格子は、2質量%のフタルイミド染料及び酢酸エチル中の1%のニトロセルロース結合剤及びメトキシプロパノールを含有するインクを用いて又は2質量%のフタルイミジン染料及び3%の塩化ビニル及びメチルエチルケトン中の酢酸ビニルコポリマーを含有するインクを用いて6ミクロンの巻線バーコーターによって上塗りされる。
Claims (10)
- a)低屈折率nlowを有する媒体の層;
b)低屈折率nlowを有する媒体上の回折微細構造;及び
c)該回折微細構造上の、発光材料を含む、高屈折率nhighを有する導波路層
を含み、さらに、導波路層c)上に
d)低屈折率n low を有する媒体の層
を含むか又は
A)低屈折率nlowを有する媒体の層;
B)該低屈折率nlowを有する媒体上の、発光材料を含む、高屈折率nhighを有する導波路層;及び
C)該高屈折率nhighを有する導波路層上の回折微細構造
を含み、さらに、回折微細構造C)上に
D)低屈折率n low を有する媒体の層
を含むセキュリティデバイスであって、その際、
低屈折率nlowを有する媒体と導波路層との間の屈折率の差が少なくとも0.005であり;
微細構造の周期(Λ)が100〜1500nmの範囲であり;
導波路層の質量厚さ(d)が60〜200nmの範囲であり;且つ
微細構造の深さ(t)が50〜1000nmの範囲であり、
低屈折率n low を有する媒体が、エンボス可能なアクリレート層で被覆されたポリメチルメタクリレート、ポリカーボネート、及びポリエチレンテレフタレートから選択され、
高屈折率n high を有する導波路層がマトリックス材料及び発光材料を含み、
マトリックス材料がポリビニルカルバゾール、ポリメチルメタクリレート、UVプライマー、塩化ビニル及び酢酸ビニルコポリマー及びニトロセルロースから選択され、
発光材料が、金属錯体
- 回折微細構造が270±30nmの範囲の微細構造周期(Λ)を有する回折格子であり;導波路層の質量厚さ(d)が140±50nmの範囲であり;且つ微細構造の深さ(t)が140±30nmの範囲である、請求項1に記載のセキュリティデバイス。
- 回折微細構造が、互いに隣接又は近接している少なくとも2つの部分領域からなり、その際、1つの部分領域が1つの溝方向を含み、別の部分領域が別の異なる溝方向を含み及び/又は1つの部分領域が1つの格子周期を含み且つ別の部分領域が別の異なる格子周期を含む、請求項1または2に記載のセキュリティデバイス。
- 両方の部分領域が回折微細構造中にロゴを含み、発光材料の照射時に第1のロゴが明るく見えて、第2のロゴが溝の方向に応じて暗く見え、且つ回転時に第1のロゴが暗く見えて、第2のロゴが明るく見える、請求項3に記載のセキュリティデバイス。
- 部分領域が、記号、ストライプ、幾何学的な形状、デザイン、文字、英数文字、それらの対象又は部分の表現を有する、請求項4に記載のセキュリティデバイス。
- 以下の工程:
− 低屈折率nlowを有する媒体を提供する工程、
− エンボシングによって低屈折率nlowを有する媒体中に回折微細構造を形成する工程、及び
− 該回折微細構造上に、発光材料を含むポリマー層である高屈折率nhighを有する導波路層を堆積させる工程
を含む、請求項1に記載のセキュリティデバイスの製造方法。 - 以下の工程:
− 低屈折率nlowを有する媒体を提供する工程、
− 該低屈折率nlowを有する媒体上に、発光材料を含むポリマー層である高屈折率nhighを有する導波路層を堆積させる工程、及び
− 該導波路層上にエンボシングによって回折微細構造を形成する工程
を含む、請求項1に記載のセキュリティデバイスの製造方法。 - 全ての堆積工程がロールツーロールプロセスの一部である、請求項6又は7に記載の方法。
- 請求項1から5までのいずれか1項に記載のセキュリティデバイスを、紙幣、クレジットカード、パスポート、チケットの製造に及びブランド保護の目的に用いる使用。
- 請求項1から5までのいずれか1項に記載のセキュリティデバイスを含む製品。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US38749010P | 2010-09-29 | 2010-09-29 | |
US61/387,490 | 2010-09-29 | ||
EP10182151.0 | 2010-09-29 | ||
EP10182151 | 2010-09-29 | ||
PCT/EP2011/066768 WO2012041851A1 (en) | 2010-09-29 | 2011-09-27 | Security element |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2013546007A JP2013546007A (ja) | 2013-12-26 |
JP6038032B2 true JP6038032B2 (ja) | 2016-12-07 |
Family
ID=44675603
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2013530702A Expired - Fee Related JP6038032B2 (ja) | 2010-09-29 | 2011-09-27 | セキュリティ要素 |
Country Status (9)
Country | Link |
---|---|
US (1) | US9310766B2 (ja) |
EP (1) | EP2621730B1 (ja) |
JP (1) | JP6038032B2 (ja) |
KR (1) | KR20130124494A (ja) |
CN (1) | CN103124641B (ja) |
AU (1) | AU2011310652B2 (ja) |
CA (1) | CA2811165A1 (ja) |
MX (1) | MX344784B (ja) |
WO (1) | WO2012041851A1 (ja) |
Families Citing this family (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
MX363517B (es) | 2011-06-21 | 2019-03-26 | Basf Se | Rejillas de difracción de impresión en papel y tabla. |
AU2012100573B4 (en) * | 2012-05-10 | 2013-03-28 | Innovia Security Pty Ltd | An optical security device |
RU2645161C2 (ru) | 2012-09-17 | 2018-02-16 | Басф Се | Защитные элементы и способ их получения |
GB201222813D0 (en) * | 2012-12-18 | 2013-01-30 | Rue De Int Ltd | Security device |
US9996843B2 (en) * | 2013-12-13 | 2018-06-12 | Colorado State University Research Foundation | Nano-stamp and matched reader for anti-counterfeiting applications |
CN105917477A (zh) * | 2014-02-28 | 2016-08-31 | 松下知识产权经营株式会社 | 发光器件以及发光装置 |
WO2015128909A1 (ja) | 2014-02-28 | 2015-09-03 | パナソニックIpマネジメント株式会社 | 発光素子および発光装置 |
CN105940510B (zh) * | 2014-02-28 | 2019-01-11 | 松下知识产权经营株式会社 | 发光装置 |
JP2016034015A (ja) * | 2014-02-28 | 2016-03-10 | パナソニックIpマネジメント株式会社 | 発光装置 |
US9518215B2 (en) | 2014-02-28 | 2016-12-13 | Panasonic Intellectual Property Management Co., Ltd. | Light-emitting device and light-emitting apparatus |
US9618697B2 (en) * | 2014-02-28 | 2017-04-11 | Panasonic Intellectual Property Management Co., Ltd. | Light directional angle control for light-emitting device and light-emitting apparatus |
US9515239B2 (en) | 2014-02-28 | 2016-12-06 | Panasonic Intellectual Property Management Co., Ltd. | Light-emitting device and light-emitting apparatus |
CN105940506A (zh) * | 2014-02-28 | 2016-09-14 | 松下知识产权经营株式会社 | 发光器件以及发光装置 |
JP2016034012A (ja) | 2014-02-28 | 2016-03-10 | パナソニックIpマネジメント株式会社 | 発光素子および発光装置 |
JP6672585B2 (ja) * | 2014-12-15 | 2020-03-25 | 凸版印刷株式会社 | 表示体 |
WO2016098329A1 (ja) * | 2014-12-15 | 2016-06-23 | 凸版印刷株式会社 | 表示体及び表示体の製造方法 |
JP6596820B2 (ja) * | 2014-12-15 | 2019-10-30 | 凸版印刷株式会社 | 表示体 |
AT516688A1 (de) * | 2014-12-15 | 2016-07-15 | Hueck Folien Gmbh | Sicherheitselement mit Farbkippeffekt und fluoreszierenden Merkmalen, Verfahren zu dessen Herstellung und dessen Verwendung |
US10031276B2 (en) | 2015-03-13 | 2018-07-24 | Panasonic Intellectual Property Management Co., Ltd. | Display apparatus including photoluminescent layer |
US10182702B2 (en) | 2015-03-13 | 2019-01-22 | Panasonic Intellectual Property Management Co., Ltd. | Light-emitting apparatus including photoluminescent layer |
JP6566313B2 (ja) * | 2015-03-13 | 2019-08-28 | パナソニックIpマネジメント株式会社 | 表示装置および発光装置 |
JP6569856B2 (ja) | 2015-03-13 | 2019-09-04 | パナソニックIpマネジメント株式会社 | 発光装置および内視鏡 |
JP2016171228A (ja) * | 2015-03-13 | 2016-09-23 | パナソニックIpマネジメント株式会社 | 発光素子、発光装置および検知装置 |
JP2017003697A (ja) | 2015-06-08 | 2017-01-05 | パナソニックIpマネジメント株式会社 | 発光素子および発光装置 |
JP2017005054A (ja) | 2015-06-08 | 2017-01-05 | パナソニックIpマネジメント株式会社 | 発光装置 |
US10359155B2 (en) | 2015-08-20 | 2019-07-23 | Panasonic Intellectual Property Management Co., Ltd. | Light-emitting apparatus |
JP6748905B2 (ja) * | 2015-08-20 | 2020-09-02 | パナソニックIpマネジメント株式会社 | 発光装置 |
JP2017040818A (ja) | 2015-08-20 | 2017-02-23 | パナソニックIpマネジメント株式会社 | 発光素子 |
JP6719094B2 (ja) | 2016-03-30 | 2020-07-08 | パナソニックIpマネジメント株式会社 | 発光素子 |
EP3639634A4 (en) * | 2017-06-15 | 2021-07-14 | Jabil Inc. | SYSTEM, DEVICE AND METHOD FOR USING SURFACE MOUNTING TECHNOLOGY ON METAL SUBSTRATES |
DE102019113005A1 (de) * | 2019-05-16 | 2020-11-19 | Bundesdruckerei Gmbh | Lumineszierendes Sicherheitselement |
Family Cites Families (77)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US458475A (en) | 1891-08-25 | Rail-fastener and chair for the same | ||
US5164227A (en) | 1987-06-19 | 1992-11-17 | Van Leer Metallized Products (Usa) Limited | Method for embossing a coated sheet with a diffraction or holographic pattern |
US4913858A (en) | 1987-10-26 | 1990-04-03 | Dennison Manufacturing Company | Method of embossing a coated sheet with a diffraction or holographic pattern |
DE3932505C2 (de) | 1989-09-28 | 2001-03-15 | Gao Ges Automation Org | Datenträger mit einem optisch variablen Element |
JPH07209848A (ja) * | 1994-01-20 | 1995-08-11 | Kimoto & Co Ltd | 遮光性マスキングフィルム |
JPH08262963A (ja) * | 1995-03-22 | 1996-10-11 | Toppan Printing Co Ltd | 画像表示体及びその製造に用いる熱転写シート |
JPH10129107A (ja) | 1996-11-01 | 1998-05-19 | Toppan Printing Co Ltd | 画像表示体 |
JP3845941B2 (ja) * | 1997-03-25 | 2006-11-15 | 三菱化学株式会社 | イミダゾール金属錯体及びそれを用いた有機電界発光素子 |
DE19731968A1 (de) * | 1997-07-24 | 1999-01-28 | Giesecke & Devrient Gmbh | Sicherheitsdokument |
US6451455B1 (en) | 1998-04-01 | 2002-09-17 | The Trustees Of Princeton University | Metal complexes bearing both electron transporting and hole transporting moieties |
US6413656B1 (en) | 1998-09-14 | 2002-07-02 | The University Of Southern California | Reduced symmetry porphyrin molecules for producing enhanced luminosity from phosphorescent organic light emitting devices |
JP3684294B2 (ja) * | 1997-10-23 | 2005-08-17 | パイオニア株式会社 | 回転体 |
JP3326390B2 (ja) * | 1998-07-07 | 2002-09-24 | 日本電信電話株式会社 | 再生専用多重ホログラムカード |
US6451415B1 (en) | 1998-08-19 | 2002-09-17 | The Trustees Of Princeton University | Organic photosensitive optoelectronic device with an exciton blocking layer |
US6830828B2 (en) | 1998-09-14 | 2004-12-14 | The Trustees Of Princeton University | Organometallic complexes as phosphorescent emitters in organic LEDs |
US6097147A (en) | 1998-09-14 | 2000-08-01 | The Trustees Of Princeton University | Structure for high efficiency electroluminescent device |
EP3076759A1 (en) | 1999-03-23 | 2016-10-05 | The University Of Southern California | Cyclometallated metal complexes as phosphorescent dopants in organic leds |
EP2306495B1 (en) | 1999-05-13 | 2017-04-19 | The Trustees of Princeton University | Very high efficiency organic light emitting devices based on electrophosphorescence |
US6310360B1 (en) | 1999-07-21 | 2001-10-30 | The Trustees Of Princeton University | Intersystem crossing agents for efficient utilization of excitons in organic light emitting devices |
US6458475B1 (en) | 1999-11-24 | 2002-10-01 | The Trustee Of Princeton University | Organic light emitting diode having a blue phosphorescent molecule as an emitter |
CN1224297C (zh) | 1999-12-01 | 2005-10-19 | 普林斯顿大学理事会 | 作为有机发光器件的磷光掺杂剂的l2mx形式的络合物 |
JP2001255808A (ja) | 2000-03-09 | 2001-09-21 | Hitachi Maxell Ltd | ホログラム |
JP2001265198A (ja) | 2000-03-17 | 2001-09-28 | Hitachi Maxell Ltd | ホログラム |
US6645645B1 (en) | 2000-05-30 | 2003-11-11 | The Trustees Of Princeton University | Phosphorescent organic light emitting devices |
US20020121638A1 (en) | 2000-06-30 | 2002-09-05 | Vladimir Grushin | Electroluminescent iridium compounds with fluorinated phenylpyridines, phenylpyrimidines, and phenylquinolines and devices made with such compounds |
EP1325671B1 (en) | 2000-08-11 | 2012-10-24 | The Trustees Of Princeton University | Organometallic compounds and emission-shifting organic electrophosphorescence |
JP2002072835A (ja) | 2000-08-31 | 2002-03-12 | Dainippon Printing Co Ltd | 不可視情報を伴なった光回折構造を有する情報記録体、ならびにその情報記録体製造用ラベル、および情報記録体製造用転写シート |
JP4086498B2 (ja) | 2000-11-29 | 2008-05-14 | キヤノン株式会社 | 金属配位化合物、発光素子及び表示装置 |
JP4343528B2 (ja) | 2000-11-30 | 2009-10-14 | キヤノン株式会社 | 発光素子及び表示装置 |
KR100533556B1 (ko) | 2000-11-30 | 2005-12-06 | 캐논 가부시끼가이샤 | 발광 소자 및 표시 장치 |
JP4154145B2 (ja) | 2000-12-01 | 2008-09-24 | キヤノン株式会社 | 金属配位化合物、発光素子及び表示装置 |
US6573651B2 (en) | 2000-12-18 | 2003-06-03 | The Trustees Of Princeton University | Highly efficient OLEDs using doped ambipolar conductive molecular organic thin films |
KR100898304B1 (ko) | 2001-03-02 | 2009-05-19 | 더 트러스티즈 오브 프린스턴 유니버시티 | 이중 도우프층, 인광 유기 발광 디바이스 |
JP4307000B2 (ja) | 2001-03-08 | 2009-08-05 | キヤノン株式会社 | 金属配位化合物、電界発光素子及び表示装置 |
JP4438042B2 (ja) | 2001-03-08 | 2010-03-24 | キヤノン株式会社 | 金属配位化合物、電界発光素子及び表示装置 |
JP4307001B2 (ja) | 2001-03-14 | 2009-08-05 | キヤノン株式会社 | 金属配位化合物、電界発光素子及び表示装置 |
KR100916231B1 (ko) | 2001-03-14 | 2009-09-08 | 더 트러스티즈 오브 프린스턴 유니버시티 | 청색 인광계 유기발광다이오드용 재료 및 장치 |
JP2002286941A (ja) * | 2001-03-28 | 2002-10-03 | Harison Toshiba Lighting Corp | 導光体及び面状発光装置 |
CN1302565C (zh) | 2001-05-16 | 2007-02-28 | 普林斯顿大学理事会 | 高效多色电致磷光oled |
JP3650082B2 (ja) | 2001-06-04 | 2005-05-18 | 三洋電機株式会社 | 有機エレクトロルミネッセンス素子、発光材料および有機化合物 |
US7067202B2 (en) | 2001-06-15 | 2006-06-27 | Sanyo Electric Co., Ltd. | Luminescent organometallic compound and light emitting device |
WO2002104080A1 (fr) | 2001-06-15 | 2002-12-27 | Canon Kabushiki Kaisha | Dispositif a electroluminescence organique |
JP4310077B2 (ja) | 2001-06-19 | 2009-08-05 | キヤノン株式会社 | 金属配位化合物及び有機発光素子 |
EP2256838B1 (en) | 2001-08-29 | 2018-12-12 | The Trustees of Princeton University | Organic light emitting devices having charge carrier blocking layers comprising metalcomplexes |
JP3960765B2 (ja) | 2001-09-03 | 2007-08-15 | 三洋電機株式会社 | 発光素子用発光材料 |
JP2003073387A (ja) | 2001-09-04 | 2003-03-12 | Canon Inc | 金属配位化合物及び有機発光素子 |
DE10150293B4 (de) | 2001-10-12 | 2005-05-12 | Ovd Kinegram Ag | Sicherheitselement |
US6835469B2 (en) | 2001-10-17 | 2004-12-28 | The University Of Southern California | Phosphorescent compounds and devices comprising the same |
US6869695B2 (en) | 2001-12-28 | 2005-03-22 | The Trustees Of Princeton University | White light emitting OLEDs from combined monomer and aggregate emission |
JP2003248414A (ja) * | 2002-02-22 | 2003-09-05 | Ntt Advanced Technology Corp | 導波路ホログラム型偽造防止シール |
US7491472B2 (en) * | 2002-07-26 | 2009-02-17 | Dai Nippon Printing Co., Ltd. | Volume hologram transfer foil |
JP2004223975A (ja) * | 2003-01-27 | 2004-08-12 | Toppan Printing Co Ltd | 偽造防止媒体、情報表示媒体、偽造防止転写箔、偽造防止シール、及び、それらの製造方法 |
DE10338550A1 (de) | 2003-08-19 | 2005-03-31 | Basf Ag | Übergangsmetallkomplexe mit Carbenliganden als Emitter für organische Licht-emittierende Dioden (OLEDs) |
GB0326576D0 (en) | 2003-11-14 | 2003-12-17 | Printetch Ltd | Printing composition |
WO2005113704A2 (en) | 2004-05-18 | 2005-12-01 | The University Of Southern California | Luminescent compounds with carbene ligands |
JP5000496B2 (ja) | 2004-06-28 | 2012-08-15 | チバ ホールディング インコーポレーテッド | トリアゾールとベンゾトリアゾールのエレクトロルミネセンス金属錯体 |
GB0417422D0 (en) | 2004-08-05 | 2004-09-08 | Suisse Electronique Microtech | Security device |
DE102005011612A1 (de) | 2004-08-13 | 2006-02-23 | Giesecke & Devrient Gmbh | Datenträger mit einer optisch variablen Struktur |
DE102004049118A1 (de) * | 2004-10-07 | 2006-04-13 | Giesecke & Devrient Gmbh | Sicherheitselement und Verfahren zu seiner Herstellung |
DE102004057072A1 (de) | 2004-11-25 | 2006-06-01 | Basf Ag | Verwendung von Übergangsmetall-Carbenkomplexen in organischen Licht-emittierenden Dioden (OLEDs) |
DE102005017169B4 (de) * | 2005-04-13 | 2023-06-22 | Ovd Kinegram Ag | Transferfolie |
DE102005039320A1 (de) * | 2005-08-19 | 2007-02-22 | Giesecke & Devrient Gmbh | Kartenförmiger Datenträger |
JP2007072188A (ja) | 2005-09-07 | 2007-03-22 | Dainippon Printing Co Ltd | ホログラム、ホログラムラベル及びホログラム転写箔 |
US8383828B2 (en) | 2006-04-04 | 2013-02-26 | Basf Aktiengesellschaft | Transition metal complexes comprising one noncarbene ligand and one or two carbene ligands and their use in OLEDs |
CN101460515B (zh) | 2006-04-05 | 2013-05-15 | 巴斯夫欧洲公司 | 杂配过渡金属-碳烯配合物以及它们在有机发光二极管(oled)中的用途 |
DE602007000707D1 (de) | 2006-05-31 | 2009-04-30 | Suisse Electronique Microtech | Nanostrukturierter Diffraktionsfilter nullter Ordnung |
WO2008000727A1 (de) | 2006-06-26 | 2008-01-03 | Basf Se | Verwendung von übergangsmetallcarbenkomplexen, die keine cyclometallierung über nicht-carbene enthalten, in oleds |
US20100090455A1 (en) | 2006-11-21 | 2010-04-15 | Ciba Corporation | Apparatus and method for manufacturing a security product |
EP2112994B1 (en) | 2007-02-23 | 2011-01-26 | Basf Se | Electroluminescent metal complexes with benzotriazoles |
DE102007024298B3 (de) * | 2007-05-23 | 2008-10-16 | Zahedi Fariborz Martin Loessl | Folienelement zur Echtheitserkennung, Sicherheitspapier, Sicherheitsdokument, Wertdokument, Münze, Jeton, Gebrauchsgegenstand, Gestaltungselement sowie Verfahren zur Herstellung eines Folienelements zur Echtheitserkennung und Verfahren zur Herstellung eines Sicherheitspapiers, eines Sicherheitsdokuments und eines Wertdokuments wie einer Banknote |
JP5292769B2 (ja) * | 2007-11-06 | 2013-09-18 | 大日本印刷株式会社 | 有機エレクトロルミネッセンス素子 |
WO2009077350A1 (en) | 2007-12-14 | 2009-06-25 | Basf Se | Inorganic phosphor, obtainable by wet milling |
DE102008013167A1 (de) * | 2008-03-07 | 2009-09-10 | Giesecke & Devrient Gmbh | Sicherheitselement und Verfahren zu seiner Herstellung |
EP2130884A1 (de) | 2008-06-02 | 2009-12-09 | Hueck Folien Ges.m.b.H. | Sicherheitsetikett oder -klebeband |
US20120029121A1 (en) | 2008-12-19 | 2012-02-02 | Basf Se | Thin aluminium flakes |
JP5627684B2 (ja) | 2009-08-21 | 2014-11-19 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 超顕微鏡的及び光学的可変像を有するデバイスのための装置及び方法 |
RU2562031C2 (ru) | 2009-11-27 | 2015-09-10 | Басф Се | Композиции для покрытий защитных элементов и голограмм |
-
2011
- 2011-09-27 US US13/823,348 patent/US9310766B2/en not_active Expired - Fee Related
- 2011-09-27 CN CN201180046969.7A patent/CN103124641B/zh not_active Expired - Fee Related
- 2011-09-27 WO PCT/EP2011/066768 patent/WO2012041851A1/en active Application Filing
- 2011-09-27 KR KR1020137010520A patent/KR20130124494A/ko not_active Application Discontinuation
- 2011-09-27 AU AU2011310652A patent/AU2011310652B2/en not_active Ceased
- 2011-09-27 JP JP2013530702A patent/JP6038032B2/ja not_active Expired - Fee Related
- 2011-09-27 CA CA2811165A patent/CA2811165A1/en not_active Abandoned
- 2011-09-27 MX MX2013003583A patent/MX344784B/es active IP Right Grant
- 2011-09-27 EP EP11760796.0A patent/EP2621730B1/en active Active
Also Published As
Publication number | Publication date |
---|---|
US20130208327A1 (en) | 2013-08-15 |
CN103124641B (zh) | 2015-12-09 |
CA2811165A1 (en) | 2012-04-05 |
EP2621730B1 (en) | 2019-09-18 |
EP2621730A1 (en) | 2013-08-07 |
KR20130124494A (ko) | 2013-11-14 |
MX2013003583A (es) | 2013-05-31 |
MX344784B (es) | 2017-01-06 |
WO2012041851A1 (en) | 2012-04-05 |
CN103124641A (zh) | 2013-05-29 |
US9310766B2 (en) | 2016-04-12 |
JP2013546007A (ja) | 2013-12-26 |
AU2011310652A1 (en) | 2013-04-18 |
AU2011310652B2 (en) | 2014-10-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6038032B2 (ja) | セキュリティ要素 | |
RU2591770C2 (ru) | Защитный элемент с ахроматическими характеристиками | |
US20180304667A1 (en) | Method for Producing a Multilayer Element, and Multilayer Element | |
JP5811484B2 (ja) | 多層エレメントの製造方法及び多層エレメント | |
CN102259519B (zh) | 变色烫印薄膜及其制备方法 | |
US10875350B2 (en) | Anti-counterfeiting structure | |
JP2003520986A (ja) | 光学変調セキュリティーデバイス | |
JP4498825B2 (ja) | ホログラム転写シート及び印画物 | |
EP2359196B1 (en) | Security device, method and article | |
JP4254367B2 (ja) | 転写シート及びその製造方法 | |
US9962987B2 (en) | Optical security component | |
JP2019510120A (ja) | 安全保障目的のための4−ボラ−3a,4a−ジアザ−s−インダセン類の使用 | |
JP2007106005A (ja) | ラミネートフィルムとその使用方法 | |
RU2459710C2 (ru) | Защитное устройство, содержащее связующий материал с изменяющимися оптическими свойствами | |
KR101245939B1 (ko) | 위조 및 변조 방지용 홀로그램 증착 필름 | |
WO2010151177A1 (ru) | Оптический защитный элемент, способ его изготовления и способ верификации аутентичности объекта с указанным защитным элементом | |
JP6686347B2 (ja) | ホログラム積層体、情報記録媒体およびホログラム積層体の製造方法 | |
RU2341381C1 (ru) | Способ изготовления голографической защитной продукции с дополнительной защитной меткой (варианты) и дополнительная защитная метка (варианты) | |
KR102494353B1 (ko) | 시인성이 개선된 보안요소 식별 기능을 갖는 카드 | |
EP3674756B1 (en) | Display body, anti-counterfeiting thread paper, and anti-counterfeiting medium | |
WO2024012962A1 (en) | Uv-curable coatings having high refractive index |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20140925 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20150731 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20150831 |
|
A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20151111 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20160425 |
|
A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20160816 |
|
A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20160823 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20161003 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20161101 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6038032 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
LAPS | Cancellation because of no payment of annual fees |