EP2102133A1 - Niedrig sinterndes, piezoelektrisches material auf blei-zirkonat-titanat-mischkristall-basis, verfahren zu dessen herstellung sowie ein dieses material umfassendes piezoelektrisches bauelement - Google Patents
Niedrig sinterndes, piezoelektrisches material auf blei-zirkonat-titanat-mischkristall-basis, verfahren zu dessen herstellung sowie ein dieses material umfassendes piezoelektrisches bauelementInfo
- Publication number
- EP2102133A1 EP2102133A1 EP07821267A EP07821267A EP2102133A1 EP 2102133 A1 EP2102133 A1 EP 2102133A1 EP 07821267 A EP07821267 A EP 07821267A EP 07821267 A EP07821267 A EP 07821267A EP 2102133 A1 EP2102133 A1 EP 2102133A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- mixed crystal
- lead zirconate
- silver
- sintering
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229910052451 lead zirconate titanate Inorganic materials 0.000 title claims abstract description 78
- 239000000463 material Substances 0.000 title claims abstract description 43
- 238000005245 sintering Methods 0.000 title claims abstract description 43
- HFGPZNIAWCZYJU-UHFFFAOYSA-N lead zirconate titanate Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ti+4].[Zr+4].[Pb+2] HFGPZNIAWCZYJU-UHFFFAOYSA-N 0.000 title claims abstract description 24
- 239000006104 solid solution Substances 0.000 title claims abstract description 14
- 238000000034 method Methods 0.000 title claims description 24
- 238000004519 manufacturing process Methods 0.000 title abstract description 11
- 229910052709 silver Inorganic materials 0.000 claims abstract description 51
- 239000004332 silver Substances 0.000 claims abstract description 49
- 239000010936 titanium Substances 0.000 claims abstract description 33
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000013078 crystal Substances 0.000 claims description 50
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 49
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 48
- 239000000203 mixture Substances 0.000 claims description 27
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 24
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 23
- 229910052744 lithium Inorganic materials 0.000 claims description 23
- 239000011575 calcium Substances 0.000 claims description 19
- 229910052742 iron Inorganic materials 0.000 claims description 19
- 230000008569 process Effects 0.000 claims description 15
- 238000001354 calcination Methods 0.000 claims description 14
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 10
- 229910052791 calcium Inorganic materials 0.000 claims description 10
- 229910052712 strontium Inorganic materials 0.000 claims description 10
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 10
- 229910017052 cobalt Inorganic materials 0.000 claims description 9
- 239000010941 cobalt Substances 0.000 claims description 9
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 9
- 238000000227 grinding Methods 0.000 claims description 9
- 239000011777 magnesium Substances 0.000 claims description 9
- 229910052759 nickel Inorganic materials 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 8
- 230000003647 oxidation Effects 0.000 claims description 8
- 238000007254 oxidation reaction Methods 0.000 claims description 8
- 229910052723 transition metal Inorganic materials 0.000 claims description 8
- 150000003624 transition metals Chemical class 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 7
- 229910052788 barium Inorganic materials 0.000 claims description 6
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 5
- 229910003002 lithium salt Inorganic materials 0.000 claims description 5
- 159000000002 lithium salts Chemical class 0.000 claims description 5
- 229910052749 magnesium Inorganic materials 0.000 claims description 5
- 238000009472 formulation Methods 0.000 claims description 4
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims description 4
- JNGZXGGOCLZBFB-IVCQMTBJSA-N compound E Chemical compound N([C@@H](C)C(=O)N[C@@H]1C(N(C)C2=CC=CC=C2C(C=2C=CC=CC=2)=N1)=O)C(=O)CC1=CC(F)=CC(F)=C1 JNGZXGGOCLZBFB-IVCQMTBJSA-N 0.000 claims description 2
- LVTJOONKWUXEFR-FZRMHRINSA-N protoneodioscin Natural products O(C[C@@H](CC[C@]1(O)[C@H](C)[C@@H]2[C@]3(C)[C@H]([C@H]4[C@@H]([C@]5(C)C(=CC4)C[C@@H](O[C@@H]4[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@@H](O)[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@H](CO)O4)CC5)CC3)C[C@@H]2O1)C)[C@H]1[C@H](O)[C@H](O)[C@H](O)[C@@H](CO)O1 LVTJOONKWUXEFR-FZRMHRINSA-N 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 abstract description 6
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract description 4
- 239000000919 ceramic Substances 0.000 description 18
- 239000010955 niobium Substances 0.000 description 17
- 238000007792 addition Methods 0.000 description 10
- 229910052758 niobium Inorganic materials 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 7
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 7
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 6
- 229910052787 antimony Inorganic materials 0.000 description 6
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 6
- IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 description 6
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 6
- 229910052715 tantalum Inorganic materials 0.000 description 6
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 239000002003 electrode paste Substances 0.000 description 5
- 150000002500 ions Chemical group 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052700 potassium Inorganic materials 0.000 description 5
- 239000011591 potassium Substances 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- -1 Ag + Chemical class 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000002019 doping agent Substances 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 3
- 229910052808 lithium carbonate Inorganic materials 0.000 description 3
- 229910021645 metal ion Inorganic materials 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 229910001923 silver oxide Inorganic materials 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- 229910013553 LiNO Inorganic materials 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 238000010344 co-firing Methods 0.000 description 2
- 238000005056 compaction Methods 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 150000002642 lithium compounds Chemical class 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 239000000370 acceptor Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 150000002611 lead compounds Chemical class 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/48—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
- C04B35/49—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates containing also titanium oxides or titanates
- C04B35/491—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates containing also titanium oxides or titanates based on lead zirconates and lead titanates, e.g. PZT
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N30/00—Piezoelectric or electrostrictive devices
- H10N30/01—Manufacture or treatment
- H10N30/09—Forming piezoelectric or electrostrictive materials
- H10N30/093—Forming inorganic materials
- H10N30/097—Forming inorganic materials by sintering
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- H10N30/8548—Lead-based oxides
- H10N30/8554—Lead-zirconium titanate [PZT] based
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- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
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- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
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- C04B2235/327—Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
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- H10N30/053—Manufacture of multilayered piezoelectric or electrostrictive devices, or parts thereof, e.g. by stacking piezoelectric bodies and electrodes by integrally sintering piezoelectric or electrostrictive bodies and electrodes
Definitions
- the present invention relates to a low-sintering, piezoelectric material PZT mixed crystal based (PZT, lead zirconate titanate, Pb (Zri- m Ti m) O 3), for example for the production of multilayer actuators with silver internal electrodes,
- PZT lead zirconate titanate
- Pb Zri- m Ti m
- Piezoceramics are used as so-called multilayer ceramics (multilayer or multilayer components), inter alia, as sensors or actuators in piezo stacks (piezo stacks) and are used, for example, in injection systems. When used as sensors or actuators can
- Piezoceramics serve either to cause a high mechanical deflection of lower force by a voltage control or to generate a high electrical voltage by a pressure control.
- piezoelectric ceramic layers are provided, for example by screen printing, with a conductive internal electrode composition, in particular internal electrode paste.
- the piezoelectric ceramic layers provided with the conductive internal electrode composition are stacked on each other so that piezoelectric
- Internal electrode composition are used for cofirene sintering temperatures of up to about 1150 0 C. Since PbO however, begins to evaporate off at temperatures of about 700 0 C, the good piezoelectric properties are obtained at the expense of a high PbO loss. This burden on the one hand the environment and on the other hand, the controllability of the manufacturing process and thus the resulting properties.
- Low-sintering PZT compositions are already known, for example ternary systems based on Zr, Nb and Ti, ie PZ-PN-PT. Often, these compositions have a high PbO excess as a sintering aid. These systems have the disadvantage that they interact massively in the application as piezoceramic multilayer actuators with the internal electrodes of, for example, Ag, Ag 1 -JPd x or Cu, for example form alloys, which has a negative effect on the electromechanical properties. In extreme cases, the internal electrodes even dissolve completely and the components lose their functionality.
- sintering aids are also known for lowering the sintering temperature, for example additions of barium in the form of Ba (Cuo , 5We 1S ) O 3 , vanadium in the form of V 2 O 5 or glasses containing boron, bismuth and cadmium (BBC). contain.
- BBC bismuth and cadmium
- the low-sintered, PZT mixed crystal base piezoelectric material according to the invention which can be produced by the method according to claim 7, also has the advantage over prior art that at lower sintering temperatures even better properties than the previously known for the
- multilayer actuators for example in motor vehicle injection systems, can be obtained.
- Li 2 CO 3 based on the weight of a modified PZT mixed crystal, and 0.6 mol% of metallic silver or ionic Ag + (for example in the form of Ag 2 O), wherein 0.6 mol% corresponds to about 0.21 wt .-% metallic silver or ionic Ag + , based on the weight of a modified PZT mixed crystal, the
- Sintering temperature of a modified, piezoelectric material based on PZT mixed crystal which is preferably substoichiometrically based on a stoichiometrically pure PZT mixed crystal of Pb-Zr / Ti content, by about 200 0 C to 940 0 C can be lowered.
- the addition of metallic or ionic silver results in detectable grain growth, which, in addition to the addition of lithium, leads to excellent electromechanical properties in the modified, low-sintering, PZT mixed crystal-based piezoelectric material.
- the low sintering temperature allows co-sintering (cofirene) of ceramic and inexpensive pure silver internal electrodes.
- the present invention therefore relates to a low sintering, piezoelectric, in particular ceramic, lead zirconate-titanate mixed crystal base material (PZT mixed crystal base), for example for cofinning with Ag / Pd internal electrodes, which have a silver content of significantly over 70
- the lead zirconate-titanate mixed crystal has a lead, zikonium and / or titanium content, based on a stoichiometric pure PZT mixed crystal is substoichiometric, and the PZT solid solution silver in an amount of>
- 0.025 mol% to ⁇ 0.6 mol% in particular from> 0.2 mol% to ⁇ 0.4 mol% or from> 0.005 wt .-% to ⁇ 0.21 wt .-%, in particular of > 0.07 wt .-% to ⁇ 0.14 wt .-%, based on the total weight of the remaining components of the PZT mixed crystal comprises.
- the term "substoichiometric" in the sense of the invention means that the lead, zirconium and / or titanium content, in particular the lead and zikonium and / or titanium content, in the composition due to A- and B-space Doping of a PZT mixed crystal present as ABO 3 perovskite, lower than the lead, zirconium and / or titanium content, in particular the lead and
- the "other components of the PZT mixed crystal" mean those components of the PZT mixed crystal which are not
- Silver, lithium, iron, cobalt and nickel are.
- the minimum content of silver according to the invention is, for example, at least 0.005% by weight, in particular at least 0.07% by weight.
- the PZT mixed crystal further comprises lithium in an amount of, for example, from> 0.01 wt .-% to ⁇
- 0.1 wt .-% in particular in an amount of> 0.02 wt .-% to ⁇ 0.06 wt .-%, based on the total weight of the remaining components of the PZT mixed crystal.
- Mixed crystal further iron and / or cobalt and / or nickel, preferably iron, in particular the oxidation state two and / or three, ie Fe 2+ and / or Fe 3+ , for example in an amount of> 0.01 wt .-% to ⁇ 0.2 wt .-%, in particular of> 0.04 wt .-% to ⁇ 0.1 wt .-%, based on the total weight of the remaining components of the PZT mixed crystal.
- Iron has beneficial effects in that it creates oxygen vacancies which increase diffusion during sintering and thus promote grain growth. In the empirical formula, it is calculated on the B-sites of the perovskite structure because it has a small ionic radius corresponding to Zr, Ti.
- the PZT mixed crystal furthermore comprises strontium and / or calcium and / or magnesium and / or barium, in particular strontium and / or calcium.
- the PZT mixed crystal according to the invention may contain strontium
- Calcium include.
- the ratio of strontium to calcium may vary from 0: 1 to 1: 0, for example from 0.45: 0.55 to 0.55: 0.45.
- Strontium and calcium are preferably present in approximately equal parts, ie 0.5: 0.5.
- the PZT mixed crystal comprises niobium and / or tantalum and / or antimony, preferably niobium, for example in an amount of, for example,> 0.6 mol% to ⁇ 0.9 mol%, in particular in an amount of > 0.7 mol% to ⁇ 0.8 mol%.
- Niobium 5+ , tantalum 5+, and / or antimony 5+ are incorporated into the B-sites of the structure, thereby replacing Zr 4 VTi 4+ and creating Pb vacancies due to their higher valence.
- the released Pb 2+ serves as an additional flux of compaction and the vacancies generated increase diffusion. Therefore, the addition of niobium, tantalum and / or antimony improves the compaction at low sintering temperature.
- the mixed crystal comprises sodium and / or potassium, preferably potassium, for example in an amount of> 0.1 mol% to ⁇ 0.4 mol%, in particular of> 0.2 mol% to ⁇ 0 , 3 mol%.
- composition according to the invention is a modified PZT (A 2+ B 4+ O 2 " 3 ) composition which is obtained by codoping (donors and
- the codoping with the doping elements silver, lithium, potassium, sodium, strontium, calcium, magnesium, barium, iron, cobalt, nickel, niobium, tantalum and antimony according to the invention takes place both on the A 2+ and on the B 4+ sites Perowskitgitters of a PZT material (lead zirconate titanate, Pb (Ti Zri- m m) O 3) instead.
- the total defect concentration remains low, which in turn increases the stability of the structure and thus the piezoelectric activity and thermal stability of the material.
- the inventive calculation of the doping elements and their amounts is based on the theory of ionic radius and valence-dependent ion substitution.
- Pb 2+ located on the A sites of an ABO 3 perovskite PZT material can be replaced by the electroneutral, isovalent elements Sr 2+ , Ca 2+ , Mg 2+, and Ba 2+ .
- the Pb 2+ can be placed on the A-
- Places can also be replaced by monovalent ions such as Ag + , Li + , K + , Na + , which, however, due to the Pb 2+ low-valent ions oxygen vacancies V 0 arise.
- Zr 4+ and Ti 4+ ions can be formed on the B sites by two, three, four, or five, six, or seven valent metal ions such as Fe 2+ / 3+ , Co 2+ / 3+ , Ni 2 + / 3 + , W 4+ , Mn 4 + / 7 + , Nb 5+ , Ta 5+ and Sb 5+ .
- the low-valency metal ions of the oxidation states two and three, oxygen vacancies V 0 are also formed .
- lead compounds V P t In the case of higher-valent metal ions of the oxidation state five, six and seven, on the other hand, lead compounds V P t.
- the PZT mixed crystal according to the invention follows the general formulation I
- Bi 2+ and B 2 2+ are the same or different and represent Ca 2+ and / or Sr 2+ and / or Mg 2+ and / or Ba 2+ , in particular Ca 2+ and / or Sr 2+ A + is Li + and / or Na + and / or K + , in particular Na + and / or K + , M 5+ is Nb 5+ and / or Ta 5+ and / or Sb 5+ , in particular for Nb 5+ , stands,
- C is a silver salt, for example silver oxide, or metallic silver,
- D represents a lithium salt, for example lithium carbonate and / or lithium nitrate
- E for a salt of a transition metal of the oxidation state two or three in particular for a salt comprising Fe 2+ and / or Fe 3+ and / or Co 2+ and / or
- Co 3+ and / or Ni 2+ and / or Ni 3+ preferably Fe 2+ and / or Fe 3+ , for example iron (III) oxide and / or iron (II) oxide, and
- 0.005 ⁇ x ⁇ 0.07 for example 0.01 ⁇ x ⁇ 0.04, in particular 0.02 ⁇ x ⁇ 0.03, 0.1 ⁇ a ⁇ 0.4, for example 0.2 ⁇ a ⁇ 0.3 .
- c is the silver content of compound C in weight percent, based on the weight of Pbi -xzx (iz) -x a - ((x (ia)) / 2) Bi + Z Z 2 + x (iz) (Zr y ( i - x (i - a )) Ti (iy) (i - x (i - a ))) (A + xa M + ⁇ (ia)) O 3 - (( xa ) / 2), and in one Range 0.005 wt .-% ⁇ c ⁇ 0.21 wt .-%, in particular 0.07 wt .-% ⁇ c ⁇ 0.14 wt .-%, d, the lithium content of the compound D in weight percent, based on the weight of PBI xz - x (iz) - xa - ((x (i-a)) / 2) + XZ Bi B 2 + x (iz)
- the last term of the index of Pb (x (l-a) / 2) "corresponds to the lead positions formed by the doping and the last term of the index of O , (x a) / 2" corresponds to the oxygen vacancies.
- the Pb 2+ and Zr 4+ / Ti 4+ content of the PZT mixed crystal of general formula I is substoichiometric.
- Pb 2+ , Zr 4+ and Ti 4+ -substituting ions Ag + , Li + , K + , Sr 2+ , Ca 2+ , Fe 3+ and Nb 5+ are preferred in the present invention.
- the PZT mixed crystal according to the invention therefore follows the general formulation II
- Ci represents a silver salt, for example silver oxide, or metallic silver
- Di is a lithium salt, for example lithium carbonate and / or lithium nitrate
- Egg for a salt of a transition metal of the oxidation state two or three in particular for a salt comprising Fe 2+ and / or Fe 3+ and / or Co 2+ and / or Co 3+ and / or Ni 2+ and / or Ni 3+ , preferably Fe 2+ and / or Fe 3+ , for example iron (III) oxide and / or iron (II) oxide, and
- 0.005 ⁇ x ⁇ 0.07 for example 0.01 ⁇ x ⁇ 0.04, in particular 0.02 ⁇ x ⁇ 0.03, 0.1 ⁇ a ⁇ 0.4, in particular 0.2 ⁇ a ⁇ 0.3 , 0.4 ⁇ y ⁇ 0.7, in particular 0.5 ⁇ y ⁇ 0.6,
- Ci is the silver content of the compound Ci in percent by weight, based on the weight
- a further subject matter of the present invention is a process for producing a low-sintering, piezoelectric, in particular ceramic, material based on lead zirconate titanate mixed crystal (PZT).
- PZT lead zirconate titanate mixed crystal
- silver is added in ionic form or added in pure, metallic form to a high-energy fine grinding of the remaining components.
- a redox partner such as palladium
- the addition of pure, metallic silver in the high-energy fine grinding of the calcine leads to an oxidation of the metallic silver. Therefore, the desired effect of grain growth during sintering and thus the desired electromechanical property improvement according to the invention is achieved by the addition of silver in ionic, preferably powdery, form to the calcine or by the addition of pure, metallic silver in the high-energy fine grinding of the calcine.
- the mean grain size of the high-energy fine grinding of the calcinate lies in a range of> 0.1 ⁇ m to ⁇ 1.5 ⁇ m, in particular in a range of> 0.8 ⁇ m to ⁇ 1.2 ⁇ m.
- lithium in particular a lithium salt, in an amount of> 0.01 wt .-% to ⁇ 0.1 wt .-%, in particular of> 0.02 wt .-% to ⁇ 0.05 wt .-%, based on the total weight of the other components; or in an amount of> 0.01 wt .-% to ⁇ 0.1 wt .-%, in particular of>
- lithium is added in powdered form.
- lithium is added to the calcine after calcination.
- iron in particular an Fe 2+ and / or Fe 3+ salt
- iron is present in an amount of> 0.01% by weight to ⁇ 0.2% by weight, in particular from> 0.04 wt .-% to ⁇ 0.1 wt .-%, based on the total weight of the other components; or in an amount of> 0.01% by weight to ⁇ 0.2% by weight, in particular of> 0.04% by weight to ⁇ 0.1% by weight, based on the total weight of the calcine, added.
- iron in powdery form is added.
- iron is added to the calcine after calcination.
- silver in the form of metallic silver and / or silver oxide, and / or lithium in the form of lithium carbonate and / or lithium nitrate and / or iron in the form of iron oxide is added as part of the process according to the invention.
- silver and / or lithium and / or iron are added after calcination and before or during high-energy fine grinding.
- lithium in particular Li 2 CO 3
- the lithium compounds used for example LiCO 3 and / or LiNO 3
- the lithium compounds used function both as doping agent and as flux. This leads to a lowering of the sintering temperature by about 200 0 C to 940 0 C and allows the
- PZT base materials all materials known to the person skilled in the art for the production of PZT mixed crystals can be used as PZT base materials.
- PZT base materials it is possible to use compositions containing the simple oxides, carbonates and niobates of the elements niobium, tantalum, antimony, iron, cobalt, nickel, silver, potassium, sodium, lithium, strontium, calcium, magnesium and / or Barium, such as Nb 3 O 5 , Fe 2 O 3 , Ag 2 O, KNbO 3 , Li 2 CO 3 , SrCO 3 and / or
- CaCO 3 are doped.
- compositions such that the doping elements are theoretically assigned to or occupy the A and B sites in the perovskite structure. This results in a clearly substoichiometric composition of the PZT- with respect to the lead, zirconium or titanium content.
- composition to more environmentally friendly conditions, since the evaporation of toxic PbO is reduced. Furthermore, the cost of composition is reduced if the calculation of the A-sites (Pb) and B-sites (Zr 4 VTi 4+ ) is done by a complete substitution of the dopants.
- composition according to the invention can be prepared both by the Columbite method (calcination of a Zr x Ti x O 2 mixture of the oxides ZrO 2 and TiO 2 and subsequent addition of this precursor with the additives and PbO.) Finally, the powder mixture is transformed into a homogeneous PZT.
- Materials for an electroceramic multilayer component in particular a piezoelectric actuator, a thermistor or a capacitor, with a plurality of superimposed insulating layers of the piezoelectric, in particular ceramic, material and partially interposed therebetween inner electrode layers, which consist of pure Ag, first one of the materials described above processed in a known manner to a pourable slurry and then formed by means of film casting into a green sheet, dried and provided in the usual manner on the surface in some areas with a layer of a conductive inner electrode paste.
- This inner electrode paste is preferably a pure Ag paste or an Ag / Pd paste with a silver content of well over 70 percent by mass.
- the green sheets which have, for example, a thickness of> 30 .mu.m to ⁇ 150 .mu.m, have been printed with the conductive inner electrode paste, they are punched, stacked and laminated, the layer number of insulating layers with the piezoelectric, in particular ceramic, material usually between 10 and ⁇ 500 layers.
- the layer number of insulating layers with the piezoelectric, in particular ceramic, material usually between 10 and ⁇ 500 layers.
- the insulating layers are formed from the, in particular ceramic, green sheets, and the inner electrode layers of the electroceramic multilayer component from the electrode paste layers, which thereafter is present as a dense ceramic-electrode composite and can be used, for example, after attaching an external contact of the internal electrodes as a piezoactuator.
- a further subject matter of the present invention is a low-sintering, piezoelectric, in particular ceramic, material based on lead zirconate titanate mixed crystal, which was produced by the process according to the invention.
- a further subject matter of the present invention is a piezoelectric component, characterized in that the component comprises a material according to the invention or a low-sintering, piezoelectric, in particular ceramic, material based on lead zirconate titanate mixed crystal base preferred embodiment further comprises at least one electrode layer of pure metallic silver.
- Another object of the present invention is the use of the invention or inventively produced, low-sintering, piezoelectric, especially ceramic, lead zirconate titanate solid solution base material for the production of piezomultilayer actuators, especially in motor vehicle injection systems.
- Table 1 Influence of the doping elements silver, lithium, iron, calcium and strontium on the coercive field strength and elongation of the material according to the invention
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DE102006057691A DE102006057691A1 (de) | 2006-12-07 | 2006-12-07 | Niedrig sinterndes, piezoelektrisches Material auf Blei-Zirkonat-Titanat-Mischkristall-Basis, Verfahren zu dessen Herstellung sowie ein dieses Material umfassendes piezoelektrisches Bauelement |
PCT/EP2007/060900 WO2008068096A1 (de) | 2006-12-07 | 2007-10-12 | Niedrig sinterndes, piezoelektrisches material auf blei-zirkonat-titanat-mischkristall-basis, verfahren zu dessen herstellung sowie ein dieses material umfassendes piezoelektrisches bauelement |
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DE102010019712B9 (de) * | 2010-05-07 | 2018-06-21 | Epcos Ag | Keramischer Werkstoff, Bauelement enthaltend den keramischen Werkstoff, Verwendung des Bauelements und Verfahren zur Herstellung des keramischen Werkstoffs |
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JP4535721B2 (ja) * | 2003-11-26 | 2010-09-01 | 京セラ株式会社 | 圧電磁器および積層型圧電素子並びに噴射装置 |
DE102004031307A1 (de) | 2004-06-29 | 2006-01-19 | Robert Bosch Gmbh | Verfahren zur Herstellung von PZT-basierten Hochleistungs-Piezokeramiken |
JP2007230839A (ja) * | 2006-03-02 | 2007-09-13 | Tdk Corp | 圧電磁器組成物、積層型圧電素子及びその製造方法 |
JP2007204346A (ja) * | 2006-02-06 | 2007-08-16 | Iai:Kk | 圧電磁器組成物と圧電共振子 |
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2006
- 2006-12-07 DE DE102006057691A patent/DE102006057691A1/de not_active Ceased
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2007
- 2007-10-12 JP JP2009539677A patent/JP2010511586A/ja active Pending
- 2007-10-12 EP EP07821267A patent/EP2102133A1/de not_active Withdrawn
- 2007-10-12 WO PCT/EP2007/060900 patent/WO2008068096A1/de active Application Filing
Non-Patent Citations (1)
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Also Published As
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DE102006057691A1 (de) | 2008-06-12 |
WO2008068096A1 (de) | 2008-06-12 |
JP2010511586A (ja) | 2010-04-15 |
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