EP1612286A2 - Alliage d'aluminium pour moulage sous pression - Google Patents

Alliage d'aluminium pour moulage sous pression Download PDF

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Publication number
EP1612286A2
EP1612286A2 EP05405361A EP05405361A EP1612286A2 EP 1612286 A2 EP1612286 A2 EP 1612286A2 EP 05405361 A EP05405361 A EP 05405361A EP 05405361 A EP05405361 A EP 05405361A EP 1612286 A2 EP1612286 A2 EP 1612286A2
Authority
EP
European Patent Office
Prior art keywords
aluminum alloy
ppm
alloy according
aluminum
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP05405361A
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German (de)
English (en)
Other versions
EP1612286A3 (fr
EP1612286B1 (fr
Inventor
Hubert Koch
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Aluminium Rheinfelden GmbH
Original Assignee
Aluminium Rheinfelden GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Aluminium Rheinfelden GmbH filed Critical Aluminium Rheinfelden GmbH
Priority to SI200531356T priority Critical patent/SI1612286T1/sl
Priority to PL05405361T priority patent/PL1612286T3/pl
Publication of EP1612286A2 publication Critical patent/EP1612286A2/fr
Publication of EP1612286A3 publication Critical patent/EP1612286A3/fr
Application granted granted Critical
Publication of EP1612286B1 publication Critical patent/EP1612286B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/06Making non-ferrous alloys with the use of special agents for refining or deoxidising
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/02Alloys based on aluminium with silicon as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/02Alloys based on aluminium with silicon as the next major constituent
    • C22C21/04Modified aluminium-silicon alloys

Definitions

  • the invention relates to an aluminum alloy for die casting of components with high elongation in the cast state.
  • the die casting technology has developed so far today that it is possible to produce components with high quality standards.
  • the quality of a die casting depends not only on the machine setting and the chosen process, but also to a great extent on the chemical composition and the microstructure of the aluminum alloy used. These two latter parameters are known to affect the castability, the feeding behavior (G. Schindelbauer, J. Czikel "mold filling and volume deficit conventional aluminum die-casting alloys", foundry research 42, 1990, p. 88/89), the mechanical properties and - very important in die casting - The life of the casting tools (LA Norström, B. Klarenfjord, M. Svenson's "General Aspect on Wash-out Mechanism in Aluminum Diecasting Dies", 17th International NADCA Diecasting Congress 1993, Cleveland OH).
  • the die-cast parts In order that the required mechanical properties, in particular a high elongation at break, can be achieved, the die-cast parts usually have to be subjected to a heat treatment.
  • This heat treatment is necessary for the molding of the casting phases and thus for achieving a tough breaking behavior.
  • a heat treatment usually means a solution annealing at temperatures just below the solidus temperature with subsequent quenching in water or another medium to temperatures ⁇ 100 ° C.
  • the material thus treated now has a low yield strength and tensile strength.
  • a thermal aging is then carried out. This can also be done by the process, e.g. by thermal application during painting or by stress-relief annealing of an entire group of components.
  • die castings are cast close to the final dimensions, they usually have a complicated geometry with thin wall thicknesses.
  • delays have to be expected, such as reworking, e.g. by directing the castings or, in the worst case, rejects.
  • the solution annealing also causes additional costs and the economics of this production method could be significantly increased if alloys were available which meet the required properties without a heat treatment.
  • An AISi alloy with good as-cast mechanical values is known from EP-A-0 687 742. Also known, for example, from EP-A-0 911 420 alloys of the type AlMg, which have a very high ductility in the cast state, but tend to hot or cold cracks in complicated shape design and are therefore unsuitable. Another disadvantage of ductile die-cast alloys is their slow aging in the cast state, which causes a temporal change in the mechanical properties, including a loss of elongation. can result. This behavior is tolerated in many applications, since the property limits are not exceeded or fallen below, but is not tolerable in some applications and can only be turned off by a targeted heat treatment.
  • the invention has for its object to provide a suitable die-casting aluminum alloy, which is very easy to cast, has a high elongation in the cast state and no longer ages after casting.
  • the alloy should be well weldable and crimpable, can be riveted and have a high corrosion resistance.
  • the object is achieved by an aluminum alloy with 8.0 to 11.5 wt .-% silicon 0.3 to 0.8% by weight of manganese 0.08 to 0.4% by weight of magnesium Max. 0.4% by weight of iron Max. 0.1% by weight of copper Max. 0.1% by weight of zinc Max.
  • the alloy composition according to the invention it is possible to achieve a high elongation in diecast parts in the cast state with good values for the yield strength and the tensile strength, so that the alloy is particularly suitable for the production of safety components in the automotive industry.
  • molybdenum it has been found that by adding molybdenum, the elongation can be increased again without loss of the other mechanical properties.
  • the desired effect is achieved with an addition of 0.05 to 0.5 wt .-% Mo, the preferred content is 0.08 to 0.25 wt .-% Mo.
  • the elongation can be even further improved.
  • the preferred content is 0.10 to 0.18 wt% Zr.
  • the relatively large proportion of eutectic silicon is refined by strontium. Compared to granular die-cast alloys with higher impurities, the alloy according to the invention also has advantages in terms of fatigue strength.
  • the fracture toughness is higher due to the very small present mixed crystals and the refined eutectic.
  • the strontium content is preferably between 50 and 150 ppm and should generally not fall below 50 ppm, since otherwise the casting behavior can be worsened. Instead of strontium, sodium and / or calcium may be added.
  • the preferred silicon content is 8.0 to 10.0 wt% Si.
  • the limitation of the magnesium content to preferably 0.08 to 0.25 wt.% Mg causes the eutectic structure not to be significantly coarsened and the alloy has only a low curing potential, which contributes to a high elongation.
  • the proportion of manganese prevents sticking in the mold and ensures good mold release.
  • the manganese content gives the casting a high structural strength at elevated temperature, so that with demolding with very little to no distortion is expected.
  • the iron content is preferably limited to max. Limited to 0.25 wt .-% Fe.
  • the alloy according to the invention can be riveted in the cast state.
  • the alloy according to the invention is preferably produced as a horizontal continuous casting ingot.
  • a die-cast alloy with low oxide contamination can be melted without expensive melt cleaning: an important prerequisite for achieving high elongation values in the die-cast part.
  • any contamination of the melt, in particular by copper or iron, must be avoided.
  • the cleaning of the inventive time-finished AISi alloy is preferably carried out by means of a purge gas treatment with inert gases by means of an impeller.
  • Grain refining is preferably carried out in the case of the alloy according to the invention.
  • the alloy gallium phosphide and / or indium phosphide in an amount corresponding to 1 to 250 ppm, preferably 1 to 30 ppm of phosphorus can be supplied.
  • the alloy for grain refining may also contain titanium and boron, the addition of titanium and boron via a master alloy with 1 to 2% by weight of Ti and 1 to 2% by weight of B, balance aluminum.
  • the aluminum master alloy contains 1.3 to 1.8% by weight of Ti and 1.3 to 1.8% by weight of B, and has a Ti / B weight ratio of about 0.8 to 1.2.
  • the content of the master alloy in the alloy of the present invention is preferably adjusted to 0.05 to 0.5% by weight.
  • the aluminum alloy according to the invention is particularly suitable for the production of safety components in diecasting.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Molds, Cores, And Manufacturing Methods Thereof (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Mold Materials And Core Materials (AREA)
  • Manufacture Of Alloys Or Alloy Compounds (AREA)
  • Body Structure For Vehicles (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)
  • Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
  • Metal Extraction Processes (AREA)
EP05405361A 2004-06-29 2005-05-26 Alliage d'aluminium pour moulage sous pression Active EP1612286B1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
SI200531356T SI1612286T1 (sl) 2004-06-29 2005-05-26 Aluminijeva legura za tlačno litje
PL05405361T PL1612286T3 (pl) 2004-06-29 2005-05-26 Odlewniczy stop aluminium

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH10912004 2004-06-29

Publications (3)

Publication Number Publication Date
EP1612286A2 true EP1612286A2 (fr) 2006-01-04
EP1612286A3 EP1612286A3 (fr) 2007-05-30
EP1612286B1 EP1612286B1 (fr) 2011-07-13

Family

ID=34974215

Family Applications (1)

Application Number Title Priority Date Filing Date
EP05405361A Active EP1612286B1 (fr) 2004-06-29 2005-05-26 Alliage d'aluminium pour moulage sous pression

Country Status (15)

Country Link
US (1) US7108042B2 (fr)
EP (1) EP1612286B1 (fr)
JP (1) JP2006016693A (fr)
KR (2) KR101295458B1 (fr)
CN (1) CN1737176A (fr)
AT (1) ATE516379T1 (fr)
BR (1) BRPI0502521B8 (fr)
CA (1) CA2510545C (fr)
DK (1) DK1612286T3 (fr)
ES (1) ES2368923T3 (fr)
MX (1) MXPA05006962A (fr)
NO (1) NO339588B1 (fr)
PL (1) PL1612286T3 (fr)
PT (1) PT1612286E (fr)
SI (1) SI1612286T1 (fr)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008006908A1 (fr) * 2006-07-14 2008-01-17 Bdw Technologies Gmbh alliage en aluminium et son utilisation pour un composant coulé notamment d'un vÉhicule AUTOMOBILE
DE102010055011A1 (de) * 2010-12-17 2012-06-21 Trimet Aluminium Ag Gut gießbare, duktile AlSi-Legierung und Verfahren zur Herstellung eines Gussteils unter Verwendung der AlSi-Gusslegierung
AT511397A1 (de) * 2011-05-03 2012-11-15 Sag Motion Ag Verfahren zur raffination und gefügemodifikation von aimgsi-legierungen
DE102015007929A1 (de) 2015-06-20 2016-12-22 Daimler Ag Aluminium-Gusslegierung, Verfahren zum Herstellen eines Bauteils aus einer Aluminium-Gusslegierung und Verwendung einer Aluminium-Gusslegierung
EP3176275A1 (fr) * 2015-12-03 2017-06-07 Audi Ag Alliage de coulée sous pression de silicium/aluminium. procédé de fabrication d'un composant coulé sous pression en alliage et composants de carrosserie comprenant un tel composant coulé sous pression
EP3342889A1 (fr) 2016-12-28 2018-07-04 Befesa Aluminio, S.L. Alliage de fonderie d'aluminium
EP3342888A1 (fr) 2016-12-28 2018-07-04 Befesa Aluminio, S.L. Alliage de fonderie d'aluminium
EP3342890A1 (fr) 2016-12-28 2018-07-04 Befesa Aluminio, S.L. Alliage de fonderie d'aluminium
EP3235917B1 (fr) 2016-04-19 2018-08-15 Rheinfelden Alloys GmbH & Co. KG Alliage d'aluminium pour moulage sous pression
EP3334850A4 (fr) * 2015-08-13 2019-03-13 Alcoa USA Corp. Alliages de moulage d'aluminium 3xx améliorés, et leurs procédés de fabrication
CN112708793A (zh) * 2020-12-17 2021-04-27 烟台路通精密科技股份有限公司 一种铸造铝硅合金配料熔炼方法
US11781202B1 (en) 2022-09-14 2023-10-10 Suzhou Huijin Smart Materials Technology Co., Ltd. Aluminum alloy for new energy vehicle integral die-cast part, preparation method therefor and application thereof

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DE102008029864B4 (de) * 2008-06-24 2011-02-24 Bdw Technologies Gmbh Gussbauteil und Verfahren zu dessen Herstellung
CN101760676B (zh) * 2008-11-12 2013-04-03 郑东海 一种铸造铝合金车轮毂
CN101935772B (zh) * 2010-09-26 2012-05-30 郑州大学 一种制备铝钛碳稀土细化剂的方法
KR101273533B1 (ko) * 2010-10-19 2013-06-17 한국생산기술연구원 피로특성이 개선된 알루미늄 합금 및 그 제조 방법
KR101380935B1 (ko) * 2011-03-25 2014-04-07 주식회사 스틸앤리소시즈 다이캐스팅용 알루미늄 합금 및 이를 이용한 자동차용 알루미늄 서브프레임
US9038704B2 (en) 2011-04-04 2015-05-26 Emerson Climate Technologies, Inc. Aluminum alloy compositions and methods for die-casting thereof
CN102296212B (zh) * 2011-09-13 2013-01-23 成都银河动力有限公司 P-Fe合金型变质剂及其运用在铝硅合金熔炼中的工艺方法
DE102013002632B4 (de) * 2012-02-16 2015-05-07 Audi Ag Aluminium-Silizium-Druckgusslegierung und Verfahren zur Herstellung eines Druckgussbauteils
EP2653579B1 (fr) * 2012-04-17 2014-10-15 Georg Fischer Druckguss GmbH & Co. KG Alliage d'aluminium
US9771635B2 (en) * 2012-07-10 2017-09-26 GM Global Technology Operations LLC Cast aluminum alloy for structural components
EP2735621B1 (fr) * 2012-11-21 2015-08-12 Georg Fischer Druckguss GmbH & Co. KG Alliage à coulée sous pression en aluminium
CN103898376A (zh) * 2012-12-31 2014-07-02 上海万泰汽车零部件有限公司 用于汽车发动机的压铸铝合金
CN103911528A (zh) * 2013-01-06 2014-07-09 德尔福技术有限公司 用于压铸工艺的高耐腐蚀性铝合金
CN104561776B (zh) * 2013-10-23 2018-01-16 明安国际企业股份有限公司 高尔夫球杆头的不锈钢组成合金
KR101641170B1 (ko) * 2014-09-02 2016-07-20 삼성전자주식회사 다이캐스팅용 알루미늄 합금 및 그 제조 방법
CN104233014B (zh) * 2014-09-30 2016-08-24 南通迪瓦特节能风机有限公司 一种轴流压缩机动叶片合金材料及其制备方法
CN104498784A (zh) * 2014-12-25 2015-04-08 马鸿斌 一种新型铝钛合金及其制备工艺
CN106255770A (zh) * 2015-04-15 2016-12-21 株式会社大纪铝工业所 压铸用铝合金以及使用该铝合金的铝合金压铸件
CN105369082B (zh) * 2015-12-11 2017-11-03 天津爱田汽车部件有限公司 一种压铸铝合金
DE102016004216A1 (de) * 2016-04-07 2016-09-29 Daimler Ag Aluminiumlegierung, insbesondere für ein Gießverfahren, sowie Verfahren zum Herstellen eines Bauteils aus einer solchen Aluminiumlegierung
EP3235916B1 (fr) 2016-04-19 2018-08-15 Rheinfelden Alloys GmbH & Co. KG Alliage de moulage
CN106119624A (zh) * 2016-08-25 2016-11-16 马鸿斌 一种高导热铝合金及其制备方法
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KR102344357B1 (ko) * 2017-05-17 2021-12-27 엘에스전선 주식회사 케이블 도체용 알루미늄 합금
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US20220341005A1 (en) * 2019-10-01 2022-10-27 Ahresty Corporation Aluminum alloy diecast, diecast unit and method for producing same
CN110629079A (zh) * 2019-10-25 2019-12-31 江苏铭利达科技有限公司 用于新能源汽车的铝合金材料
CN110714148A (zh) * 2019-11-21 2020-01-21 珠海市润星泰电器有限公司 一种高性能半固态压铸铝合金及其制备方法
CN113584359A (zh) * 2020-04-30 2021-11-02 华劲新材料研究院(广州)有限公司 一种用再生铝生产的高导热压铸铝合金材料及其制备方法
JP7282054B2 (ja) * 2020-05-19 2023-05-26 堺アルミ株式会社 低熱膨張アルミニウム合金圧延材およびその製造方法
CN115821127A (zh) * 2022-08-10 2023-03-21 帅翼驰新材料集团有限公司 烘烤后性能可提升的高压铸造铝合金
CN115287485A (zh) * 2022-08-10 2022-11-04 帅翼驰新材料集团有限公司 烘烤后性能可提升的高压铸造铝合金的制作方法
CN115386771B (zh) * 2022-10-27 2023-01-06 广州致远新材料科技有限公司 铝合金材料及道闸传动结构件的压铸方法

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Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008006908A1 (fr) * 2006-07-14 2008-01-17 Bdw Technologies Gmbh alliage en aluminium et son utilisation pour un composant coulé notamment d'un vÉhicule AUTOMOBILE
DE102006032699A1 (de) * 2006-07-14 2008-01-17 Bdw Technologies Gmbh & Co. Kg Aluminiumlegierung und deren Verwendung für ein Gussbauteil insbesondere eines Kraftwagens
DE102006032699B4 (de) * 2006-07-14 2010-09-09 Bdw Technologies Gmbh & Co. Kg Aluminiumlegierung und deren Verwendung für ein Gussbauteil insbesondere eines Kraftwagens
DE102010055011A1 (de) * 2010-12-17 2012-06-21 Trimet Aluminium Ag Gut gießbare, duktile AlSi-Legierung und Verfahren zur Herstellung eines Gussteils unter Verwendung der AlSi-Gusslegierung
AT511397A1 (de) * 2011-05-03 2012-11-15 Sag Motion Ag Verfahren zur raffination und gefügemodifikation von aimgsi-legierungen
AT511397B1 (de) * 2011-05-03 2013-02-15 Sag Motion Ag Verfahren zur raffination und gefügemodifikation von aimgsi-legierungen
DE102015007929A1 (de) 2015-06-20 2016-12-22 Daimler Ag Aluminium-Gusslegierung, Verfahren zum Herstellen eines Bauteils aus einer Aluminium-Gusslegierung und Verwendung einer Aluminium-Gusslegierung
EP3334850A4 (fr) * 2015-08-13 2019-03-13 Alcoa USA Corp. Alliages de moulage d'aluminium 3xx améliorés, et leurs procédés de fabrication
EP3176275B1 (fr) 2015-12-03 2018-10-10 Audi Ag Alliage de coulée sous pression de silicium/aluminium. procédé de fabrication d'un composant coulé sous pression en alliage et composants de carrosserie comprenant un tel composant coulé sous pression
EP3176275A1 (fr) * 2015-12-03 2017-06-07 Audi Ag Alliage de coulée sous pression de silicium/aluminium. procédé de fabrication d'un composant coulé sous pression en alliage et composants de carrosserie comprenant un tel composant coulé sous pression
EP3176275B2 (fr) 2015-12-03 2023-12-13 Audi Ag Alliage de coulée sous pression de silicium/aluminium. procédé de fabrication d'un composant coulé sous pression en alliage et composants de carrosserie comprenant un tel composant coulé sous pression
EP3235917B1 (fr) 2016-04-19 2018-08-15 Rheinfelden Alloys GmbH & Co. KG Alliage d'aluminium pour moulage sous pression
KR20180132140A (ko) * 2016-04-19 2018-12-11 라인펠덴 알로이스 게엠베하 운트 콤파니 코만디드게젤샤프트 다이 캐스팅 합금
EP3342888A1 (fr) 2016-12-28 2018-07-04 Befesa Aluminio, S.L. Alliage de fonderie d'aluminium
EP3342890A1 (fr) 2016-12-28 2018-07-04 Befesa Aluminio, S.L. Alliage de fonderie d'aluminium
EP3342889A1 (fr) 2016-12-28 2018-07-04 Befesa Aluminio, S.L. Alliage de fonderie d'aluminium
CN112708793A (zh) * 2020-12-17 2021-04-27 烟台路通精密科技股份有限公司 一种铸造铝硅合金配料熔炼方法
US11781202B1 (en) 2022-09-14 2023-10-10 Suzhou Huijin Smart Materials Technology Co., Ltd. Aluminum alloy for new energy vehicle integral die-cast part, preparation method therefor and application thereof
EP4339315A1 (fr) * 2022-09-14 2024-03-20 Suzhou Huijin Smart Materials Technology Co., Ltd. Alliage d'aluminium pour pièce coulée sous pression intégrée de véhicule à énergie nouvelle, son procédé de préparation et son application

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NO20053158L (no) 2005-12-30
EP1612286A3 (fr) 2007-05-30
JP2006016693A (ja) 2006-01-19
CN1737176A (zh) 2006-02-22
CA2510545C (fr) 2014-09-30
ATE516379T1 (de) 2011-07-15
US20060011321A1 (en) 2006-01-19
PT1612286E (pt) 2011-09-19
ES2368923T3 (es) 2011-11-23
BRPI0502521A (pt) 2007-02-13
PL1612286T3 (pl) 2011-12-30
US7108042B2 (en) 2006-09-19
KR101295458B1 (ko) 2013-08-09
EP1612286B1 (fr) 2011-07-13
NO20053158D0 (no) 2005-06-28
KR101490581B1 (ko) 2015-02-05
MXPA05006962A (es) 2006-01-24
NO339588B1 (no) 2017-01-09
BRPI0502521B8 (pt) 2016-09-13
KR20060046361A (ko) 2006-05-17
CA2510545A1 (fr) 2005-12-29
BRPI0502521B1 (pt) 2015-08-11
DK1612286T3 (da) 2011-10-24
SI1612286T1 (sl) 2011-10-28
KR20130023330A (ko) 2013-03-07

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