DE69027009T2 - Photographische Silberbromojodidemulsionen, Elemente und Verfahren - Google Patents

Photographische Silberbromojodidemulsionen, Elemente und Verfahren

Info

Publication number: DE69027009T2
Authority: DE; Germany
Prior art keywords: silver; iodide; emulsion; photographic; solution
Prior art date: 1989-12-13
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

DE1990627009

Other languages

German (de)

English (en)

Other versions

DE69027009D1 (de

Inventor

Elizabeth Pui-Iu Chang

Gary Lynn Hiller

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Eastman Kodak Co

Original Assignee

Eastman Kodak Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-12-13

Filing date

1990-12-06

Publication date

1997-01-23

1990-12-06 Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co

1996-06-20 Publication of DE69027009D1 publication Critical patent/DE69027009D1/de

1997-01-23 Application granted granted Critical

1997-01-23 Publication of DE69027009T2 publication Critical patent/DE69027009T2/de

2010-12-07 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000000839 emulsion Substances 0.000 title claims description 121
ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 title claims description 73
238000000034 method Methods 0.000 title claims description 45
230000008569 process Effects 0.000 title claims description 24
238000006243 chemical reaction Methods 0.000 claims description 31
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 29
SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 26
239000000203 mixture Substances 0.000 claims description 17
229910001961 silver nitrate Inorganic materials 0.000 claims description 13
230000015572 biosynthetic process Effects 0.000 claims description 9
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 8
150000003842 bromide salts Chemical class 0.000 claims description 7
XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 claims description 6
150000003378 silver Chemical class 0.000 claims description 6
239000013078 crystal Substances 0.000 claims description 5
238000004519 manufacturing process Methods 0.000 claims description 5
239000011541 reaction mixture Substances 0.000 claims description 5
229910001513 alkali metal bromide Inorganic materials 0.000 claims description 3
230000006911 nucleation Effects 0.000 claims description 3
238000010899 nucleation Methods 0.000 claims description 3
229910001516 alkali metal iodide Inorganic materials 0.000 claims description 2
CBEQRNSPHCCXSH-UHFFFAOYSA-N iodine monobromide Chemical class IBr CBEQRNSPHCCXSH-UHFFFAOYSA-N 0.000 claims description 2
239000012429 reaction media Substances 0.000 claims description 2
230000003698 anagen phase Effects 0.000 claims 1
239000000243 solution Substances 0.000 description 87
-1 silver halide Chemical class 0.000 description 54
229910052709 silver Inorganic materials 0.000 description 40
239000004332 silver Substances 0.000 description 40
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 30
239000012153 distilled water Substances 0.000 description 28
229920000159 gelatin Polymers 0.000 description 26
235000019322 gelatine Nutrition 0.000 description 26
JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 22
NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 21
238000001556 precipitation Methods 0.000 description 21
108010010803 Gelatin Proteins 0.000 description 17
239000008273 gelatin Substances 0.000 description 17
235000011852 gelatine desserts Nutrition 0.000 description 17
238000011160 research Methods 0.000 description 16
238000011161 development Methods 0.000 description 15
239000003795 chemical substances by application Substances 0.000 description 14
239000010410 layer Substances 0.000 description 13
239000000975 dye Substances 0.000 description 12
150000001875 compounds Chemical class 0.000 description 10
239000000463 material Substances 0.000 description 10
239000001828 Gelatine Substances 0.000 description 9
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 8
238000007792 addition Methods 0.000 description 8
229920001577 copolymer Polymers 0.000 description 7
150000004694 iodide salts Chemical class 0.000 description 7
JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 6
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
229910021612 Silver iodide Inorganic materials 0.000 description 6
239000003112 inhibitor Substances 0.000 description 6
239000003607 modifier Substances 0.000 description 6
230000035945 sensitivity Effects 0.000 description 6
230000001235 sensitizing effect Effects 0.000 description 6
229940045105 silver iodide Drugs 0.000 description 6
239000011230 binding agent Substances 0.000 description 5
239000000969 carrier Substances 0.000 description 5
239000002612 dispersion medium Substances 0.000 description 5
238000002360 preparation method Methods 0.000 description 5
230000005070 ripening Effects 0.000 description 5
150000003839 salts Chemical class 0.000 description 5
239000002609 medium Substances 0.000 description 4
229920000642 polymer Polymers 0.000 description 4
ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 4
230000003595 spectral effect Effects 0.000 description 4
238000003756 stirring Methods 0.000 description 4
238000005406 washing Methods 0.000 description 4
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
238000011026 diafiltration Methods 0.000 description 3
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
229910052737 gold Inorganic materials 0.000 description 3
239000010931 gold Substances 0.000 description 3
230000006872 improvement Effects 0.000 description 3
239000012528 membrane Substances 0.000 description 3
230000005855 radiation Effects 0.000 description 3
GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 3
239000000126 substance Substances 0.000 description 3
229910052717 sulfur Inorganic materials 0.000 description 3
239000011593 sulfur Substances 0.000 description 3
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 2
206010070834 Sensitisation Diseases 0.000 description 2
239000002253 acid Substances 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 2
229920002678 cellulose Polymers 0.000 description 2
239000011248 coating agent Substances 0.000 description 2
238000000576 coating method Methods 0.000 description 2
239000000084 colloidal system Substances 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
230000007547 defect Effects 0.000 description 2
239000006185 dispersion Substances 0.000 description 2
230000002209 hydrophobic effect Effects 0.000 description 2
239000011229 interlayer Substances 0.000 description 2
229910052741 iridium Inorganic materials 0.000 description 2
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 2
238000002156 mixing Methods 0.000 description 2
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
229920000768 polyamine Polymers 0.000 description 2
239000004848 polyfunctional curative Substances 0.000 description 2
235000018102 proteins Nutrition 0.000 description 2
108090000623 proteins and genes Proteins 0.000 description 2
102000004169 proteins and genes Human genes 0.000 description 2
229910052711 selenium Inorganic materials 0.000 description 2
239000011669 selenium Substances 0.000 description 2
230000008313 sensitization Effects 0.000 description 2
238000001228 spectrum Methods 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
238000003860 storage Methods 0.000 description 2
229910052714 tellurium Inorganic materials 0.000 description 2
PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 2
150000003568 thioethers Chemical class 0.000 description 2
229920002554 vinyl polymer Polymers 0.000 description 2
TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 description 1
GVEYRUKUJCHJSR-UHFFFAOYSA-N (4-azaniumyl-3-methylphenyl)-ethyl-(2-hydroxyethyl)azanium;sulfate Chemical compound OS(O)(=O)=O.OCCN(CC)C1=CC=C(N)C(C)=C1 GVEYRUKUJCHJSR-UHFFFAOYSA-N 0.000 description 1
ILKZXYARHQNMEF-UHFFFAOYSA-N (4-azaniumyl-3-methylphenyl)-ethyl-(2-methoxyethyl)azanium;4-methylbenzenesulfonate Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1.CC1=CC=C(S(O)(=O)=O)C=C1.COCCN(CC)C1=CC=C(N)C(C)=C1 ILKZXYARHQNMEF-UHFFFAOYSA-N 0.000 description 1
YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical class C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 1
KAMCBFNNGGVPPW-UHFFFAOYSA-N 1-(ethenylsulfonylmethoxymethylsulfonyl)ethene Chemical compound C=CS(=O)(=O)COCS(=O)(=O)C=C KAMCBFNNGGVPPW-UHFFFAOYSA-N 0.000 description 1
OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 1
BAXOFTOLAUCFNW-UHFFFAOYSA-N 1H-indazole Chemical class C1=CC=C2C=NNC2=C1 BAXOFTOLAUCFNW-UHFFFAOYSA-N 0.000 description 1
JAAIPIWKKXCNOC-UHFFFAOYSA-N 1h-tetrazol-1-ium-5-thiolate Chemical class SC1=NN=NN1 JAAIPIWKKXCNOC-UHFFFAOYSA-N 0.000 description 1
IUMRWGYGZHKZKF-UHFFFAOYSA-N 2-aminoprop-2-enamide Chemical compound NC(=C)C(N)=O IUMRWGYGZHKZKF-UHFFFAOYSA-N 0.000 description 1
FLFWJIBUZQARMD-UHFFFAOYSA-N 2-mercapto-1,3-benzoxazole Chemical class C1=CC=C2OC(S)=NC2=C1 FLFWJIBUZQARMD-UHFFFAOYSA-N 0.000 description 1
RYYXDZDBXNUPOG-UHFFFAOYSA-N 4,5,6,7-tetrahydro-1,3-benzothiazole-2,6-diamine;dihydrochloride Chemical compound Cl.Cl.C1C(N)CCC2=C1SC(N)=N2 RYYXDZDBXNUPOG-UHFFFAOYSA-N 0.000 description 1
244000215068 Acacia senegal Species 0.000 description 1
229920001817 Agar Polymers 0.000 description 1
102000009027 Albumins Human genes 0.000 description 1
108010088751 Albumins Proteins 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
229920002284 Cellulose triacetate Polymers 0.000 description 1
102000008186 Collagen Human genes 0.000 description 1
108010035532 Collagen Proteins 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
229920002307 Dextran Polymers 0.000 description 1
239000004606 Fillers/Extenders Substances 0.000 description 1
241000206672 Gelidium Species 0.000 description 1
229920000084 Gum arabic Polymers 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
244000151018 Maranta arundinacea Species 0.000 description 1
235000010804 Maranta arundinacea Nutrition 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
239000004952 Polyamide Substances 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
229910021607 Silver chloride Inorganic materials 0.000 description 1
229920002125 Sokalan® Polymers 0.000 description 1
235000012419 Thalia geniculata Nutrition 0.000 description 1
229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
229920002494 Zein Polymers 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 1
MPLZNPZPPXERDA-UHFFFAOYSA-N [4-(diethylamino)-2-methylphenyl]azanium;chloride Chemical compound [Cl-].CC[NH+](CC)C1=CC=C(N)C(C)=C1 MPLZNPZPPXERDA-UHFFFAOYSA-N 0.000 description 1
SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 1
HOLVRJRSWZOAJU-UHFFFAOYSA-N [Ag].ICl Chemical compound [Ag].ICl HOLVRJRSWZOAJU-UHFFFAOYSA-N 0.000 description 1
239000000205 acacia gum Substances 0.000 description 1
235000010489 acacia gum Nutrition 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000002411 adverse Effects 0.000 description 1
235000010419 agar Nutrition 0.000 description 1
239000003513 alkali Substances 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
229910052784 alkaline earth metal Inorganic materials 0.000 description 1
239000012670 alkaline solution Substances 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
239000002216 antistatic agent Substances 0.000 description 1
125000003354 benzotriazolyl group Chemical class N1N=NC2=C1C=CC=C2* 0.000 description 1
229910052797 bismuth Inorganic materials 0.000 description 1
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
238000004061 bleaching Methods 0.000 description 1
229910000085 borane Inorganic materials 0.000 description 1
229940006460 bromide ion Drugs 0.000 description 1
229910052793 cadmium Inorganic materials 0.000 description 1
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000005018 casein Substances 0.000 description 1
BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
235000021240 caseins Nutrition 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
238000005119 centrifugation Methods 0.000 description 1
229910052798 chalcogen Inorganic materials 0.000 description 1
150000001787 chalcogens Chemical class 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
238000005345 coagulation Methods 0.000 description 1
230000015271 coagulation Effects 0.000 description 1
239000011247 coating layer Substances 0.000 description 1
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229910052802 copper Inorganic materials 0.000 description 1
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239000011258 core-shell material Substances 0.000 description 1
238000010908 decantation Methods 0.000 description 1
230000003111 delayed effect Effects 0.000 description 1
238000009826 distribution Methods 0.000 description 1
UIYCHXAGWOYNNA-UHFFFAOYSA-N divinyl sulphide Natural products C=CSC=C UIYCHXAGWOYNNA-UHFFFAOYSA-N 0.000 description 1
239000002019 doping agent Substances 0.000 description 1
238000001035 drying Methods 0.000 description 1
238000000635 electron micrograph Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
150000004676 glycans Chemical class 0.000 description 1
230000005484 gravity Effects 0.000 description 1
125000000623 heterocyclic group Chemical group 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
229920000126 latex Polymers 0.000 description 1
238000002386 leaching Methods 0.000 description 1
239000007788 liquid Substances 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
159000000003 magnesium salts Chemical class 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
239000006224 matting agent Substances 0.000 description 1
238000000691 measurement method Methods 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
229920003145 methacrylic acid copolymer Polymers 0.000 description 1
238000012544 monitoring process Methods 0.000 description 1
QRBFSNYYMHZRGU-UHFFFAOYSA-N n-[2-(4-amino-n-ethyl-3-methylanilino)ethyl]methanesulfonamide;sulfuric acid;hydrate Chemical compound O.OS(O)(=O)=O.CS(=O)(=O)NCCN(CC)C1=CC=C(N)C(C)=C1 QRBFSNYYMHZRGU-UHFFFAOYSA-N 0.000 description 1
FECCTLUIZPFIRN-UHFFFAOYSA-N n-[2-[2-amino-5-(diethylamino)phenyl]ethyl]methanesulfonamide;hydrochloride Chemical compound Cl.CCN(CC)C1=CC=C(N)C(CCNS(C)(=O)=O)=C1 FECCTLUIZPFIRN-UHFFFAOYSA-N 0.000 description 1
229910000510 noble metal Inorganic materials 0.000 description 1
229910052762 osmium Inorganic materials 0.000 description 1
SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
150000004989 p-phenylenediamines Chemical class 0.000 description 1
229910052763 palladium Inorganic materials 0.000 description 1
239000001814 pectin Substances 0.000 description 1
229920001277 pectin Polymers 0.000 description 1
235000010987 pectin Nutrition 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
229920002401 polyacrylamide Polymers 0.000 description 1
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229920002451 polyvinyl alcohol Polymers 0.000 description 1
239000011591 potassium Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
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229910052702 rhenium Inorganic materials 0.000 description 1
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
229910052703 rhodium Inorganic materials 0.000 description 1
239000010948 rhodium Substances 0.000 description 1
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
239000012266 salt solution Substances 0.000 description 1
238000000926 separation method Methods 0.000 description 1
HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
239000002356 single layer Substances 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
VGTPCRGMBIAPIM-UHFFFAOYSA-M sodium thiocyanate Chemical compound [Na+].[S-]C#N VGTPCRGMBIAPIM-UHFFFAOYSA-M 0.000 description 1
239000002904 solvent Substances 0.000 description 1
235000011150 stannous chloride Nutrition 0.000 description 1
239000001119 stannous chloride Substances 0.000 description 1
125000003011 styrenyl group Chemical class [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
125000005504 styryl group Chemical group 0.000 description 1
230000000153 supplemental effect Effects 0.000 description 1
239000000725 suspension Substances 0.000 description 1
229910052716 thallium Inorganic materials 0.000 description 1
BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
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239000010937 tungsten Substances 0.000 description 1
238000001429 visible spectrum Methods 0.000 description 1
239000005019 zein Substances 0.000 description 1
229940093612 zein Drugs 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Classifications

- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/035—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein characterised by the crystal form or composition, e.g. mixed grain
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/015—Apparatus or processes for the preparation of emulsions
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/3022—Materials with specific emulsion characteristics, e.g. thickness of the layers, silver content, shape of AgX grains

Landscapes

Chemical & Material Sciences (AREA)
Physics & Mathematics (AREA)
General Physics & Mathematics (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Crystallography & Structural Chemistry (AREA)
Silver Salt Photography Or Processing Solution Therefor (AREA)

DE1990627009 1989-12-13 1990-12-06 Photographische Silberbromojodidemulsionen, Elemente und Verfahren Expired - Fee Related DE69027009T2 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US45014489A	1989-12-13	1989-12-13

Publications (2)

Publication Number	Publication Date
DE69027009D1 DE69027009D1 (de)	1996-06-20
DE69027009T2 true DE69027009T2 (de)	1997-01-23

Family

ID=23786945

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DE1990627009 Expired - Fee Related DE69027009T2 (de)	1989-12-13	1990-12-06	Photographische Silberbromojodidemulsionen, Elemente und Verfahren

Country Status (4)

Country	Link
EP (1)	EP0432834B1 (ja)
JP (1)	JP2909220B2 (ja)
CA (1)	CA2029579A1 (ja)
DE (1)	DE69027009T2 (ja)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH0619077A (ja) *	1992-04-16	1994-01-28	Eastman Kodak Co	多層カラー写真要素
US6159672A (en) *	1992-04-16	2000-12-12	Eastman Kodak Company	Photographic material having a blue sensitive coupler starved unit
DE69534783T2 (de) *	1994-12-22	2006-10-12	Eastman Kodak Co.	Kubische Silberiodochloridemulsionen, Verfahren zu ihrer Herstellung sowie fotografische Kopierelemente
DE19516351A1 (de) *	1995-05-04	1996-11-07	Du Pont Deutschland	Photographische Silber bromidiodidemulsion und Verfahren zu deren Herstellung
EP1055967B1 (en) *	1999-05-25	2004-09-29	FERRANIA S.p.A.	Silver halide color photographic light-sensitive elements having improved image quality

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
BE636801A (ja) *	1962-09-01
DE3404854A1 (de) *	1984-02-11	1985-08-14	Agfa-Gevaert Ag, 5090 Leverkusen	Fotografisches aufzeichnungsmaterial
EP0340168A3 (de) *	1988-04-27	1990-09-19	Ilford Ag	Photographische Innenbildemulsionen

1990
- 1990-11-08 CA CA 2029579 patent/CA2029579A1/en not_active Abandoned
- 1990-12-06 DE DE1990627009 patent/DE69027009T2/de not_active Expired - Fee Related
- 1990-12-06 EP EP19900203208 patent/EP0432834B1/en not_active Expired - Lifetime
- 1990-12-13 JP JP2401967A patent/JP2909220B2/ja not_active Expired - Fee Related

Also Published As

Publication number	Publication date
EP0432834B1 (en)	1996-05-15
JP2909220B2 (ja)	1999-06-23
EP0432834A1 (en)	1991-06-19
DE69027009D1 (de)	1996-06-20
CA2029579A1 (en)	1991-06-14
JPH03278048A (ja)	1991-12-09

Legal Events

Date	Code	Title	Description
1997-06-12	8364	No opposition during term of opposition
2001-02-08	8339	Ceased/non-payment of the annual fee

Publication	Publication Date	Title
DE3241634C3 (de)	1998-08-13	Photographische Silberbromidiodidemulsion und Verfahren zu ihrer Herstellung
DE69322677T2 (de)	1999-07-22	Photographisches Silberhalogenidmaterial mit tafelförmigen Körnern mit spezifizierten Dimensionen
DE68925051T2 (de)	1996-08-29	Hochkontrastreiche photographische Elemente und Emulsionen sowie Verfahren zu ihrer Anwendung
DE69126096T2 (de)	1997-12-11	Photographisches Silberhalogenidmaterial und Verfahren
DE3328755C2 (de)	1994-08-11	Lichtempfindliches photographisches Silberhalogenid-Aufzeichnungsmaterial
DE69325410T2 (de)	1999-10-28	Photographisches Silberhalogenidmaterial mit tafelförmigen Silberhalogenid-Körnern und verteilten Absorber-Farbstoffen
DE69320519T2 (de)	1999-01-14	Photographisches Silberhalogenidmaterial mit tafelförmigen Körnern von spezifizierten Dimensionen für verschiedene Farbaufzeichnungen
DE68921802T2 (de)	1995-11-16	Farbphotographisches Material.
DE69024405T2 (de)	1996-08-14	Silberhalogenidemulsionen mit verbesserten Niederintensitätsreziprozitätscharakteristiken und Verfahren zu ihrer Herstellung
DE69322678T2 (de)	1999-06-17	Photographisches Silberhalogenidmaterial mit tafelförmigen Körnern und lokalisierten Absorber-Farbstoffen
DE69027009T2 (de)	1997-01-23	Photographische Silberbromojodidemulsionen, Elemente und Verfahren
DE69122717T2 (de)	1997-05-07	Fotografische filme enthaltend silberhalogenidkörner mit geringen zwillingsebenenabständen
DE69528093T2 (de)	2003-05-08	Farbphotographisches Silberhalogenidelement mit verbessertem Kontrast bei hohen Dichten und Farbbrillanz in den niedrigen Dichten
DE3853596T2 (de)	1995-08-31	Photographische Silberhalogenidmaterialien.
DE68913593T2 (de)	1994-10-06	Hochkontrastreiches photographisches Aufzeichnungsmaterial und Emulsion und Verfahren zu ihrer Entwicklung.
US5166045A (en)	1992-11-24	Doping of silver halide emulsions with group VIB compounds to form improved photoactive grains
DE68911228T2 (de)	1994-06-30	Photographische Silberbromidiodidemulsionen, Elemente und Verfahren.
DE69223223T2 (de)	1998-04-02	Photographische Silberhalogenidemulsion und farbphotographisches lichtempfindliches Silberhalogenidmaterial
US5334495A (en)	1994-08-02	Silver halide grains having small twin-plane separations
DE3688224T2 (de)	1993-07-29	Lichtempfindliches farbphotographisches silberhalogenidmaterial.
DE69023310T2 (de)	1996-06-20	Photographisches Aufzeichnungsmaterial mit verbesserten Lagerungseigenschaften.
DE69422322T2 (de)	2000-07-27	Photographisches Produkt, das eine Mischung von Emulsionen verschiedener Empfindlichkeiten enthält
DE69123188T2 (de)	1997-05-07	Photographisches silberhalogenidmaterial und verfahren zur erzeugung von umkehrbildern
DE69003680T2 (de)	1994-05-05	Dotierung von Silberhalogenidemulsionen mit einem Kaliumselencyanat-Salz zur Bildung verbesserter fotoaktiver Körner.
DE69605222T2 (de)	2000-06-21	Farbumkehrelemente enthaltend eine einen Bleichbeschleuniger freisetzende Verbindung