DE2821705A1 - Verfahren zur herstellung von organozinnverbindungen - Google Patents

Verfahren zur herstellung von organozinnverbindungen

Info

Publication number: DE2821705A1
Authority: DE; Germany
Prior art keywords: tin; zinc; salt; reaction; organic
Prior art date: 1977-05-18
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Withdrawn

Application number

DE19782821705

Other languages

German (de)

English (en)

Inventor

Roger Geoffrey Hargreaves

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Tenneco Chemicals Inc

Original Assignee

Tenneco Chemicals Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-05-18

Filing date

1978-05-18

Publication date

1978-11-30

1978-05-18 Application filed by Tenneco Chemicals Inc filed Critical Tenneco Chemicals Inc

1978-11-30 Publication of DE2821705A1 publication Critical patent/DE2821705A1/de

Status Withdrawn legal-status Critical Current

Links

150000001875 compounds Chemical class 0.000 title claims description 57
238000004519 manufacturing process Methods 0.000 title description 6
150000004820 halides Chemical class 0.000 claims description 68
238000006243 chemical reaction Methods 0.000 claims description 56
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 51
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 51
239000011701 zinc Substances 0.000 claims description 48
150000003839 salts Chemical class 0.000 claims description 47
229910052725 zinc Inorganic materials 0.000 claims description 47
238000000034 method Methods 0.000 claims description 34
239000000725 suspension Substances 0.000 claims description 30
239000000047 product Substances 0.000 claims description 23
239000007788 liquid Substances 0.000 claims description 22
-1 halide compound Chemical class 0.000 claims description 19
125000004432 carbon atom Chemical group C* 0.000 claims description 18
239000000203 mixture Substances 0.000 claims description 13
VFWCMGCRMGJXDK-UHFFFAOYSA-N 1-chlorobutane Chemical compound CCCCCl VFWCMGCRMGJXDK-UHFFFAOYSA-N 0.000 claims description 12
239000007795 chemical reaction product Substances 0.000 claims description 12
239000002904 solvent Substances 0.000 claims description 11
AFCAKJKUYFLYFK-UHFFFAOYSA-N tetrabutyltin Chemical compound CCCC[Sn](CCCC)(CCCC)CCCC AFCAKJKUYFLYFK-UHFFFAOYSA-N 0.000 claims description 10
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 9
239000007787 solid Substances 0.000 claims description 9
125000000217 alkyl group Chemical group 0.000 claims description 8
CNDHHGUSRIZDSL-UHFFFAOYSA-N 1-chlorooctane Chemical compound CCCCCCCCCl CNDHHGUSRIZDSL-UHFFFAOYSA-N 0.000 claims description 7
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 7
239000007791 liquid phase Substances 0.000 claims description 7
125000000962 organic group Chemical group 0.000 claims description 7
150000004714 phosphonium salts Chemical class 0.000 claims description 7
238000002360 preparation method Methods 0.000 claims description 7
150000003242 quaternary ammonium salts Chemical class 0.000 claims description 7
229910052801 chlorine Inorganic materials 0.000 claims description 6
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
229910052794 bromium Inorganic materials 0.000 claims description 5
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
239000000460 chlorine Substances 0.000 claims description 5
125000001309 chloro group Chemical group Cl* 0.000 claims description 5
XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 claims description 5
229940006461 iodide ion Drugs 0.000 claims description 5
RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium group Chemical group [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 claims description 5
JTGNPNLBCGBCMP-UHFFFAOYSA-N tetraoctylstannane Chemical compound CCCCCCCC[Sn](CCCCCCCC)(CCCCCCCC)CCCCCCCC JTGNPNLBCGBCMP-UHFFFAOYSA-N 0.000 claims description 5
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 4
125000003342 alkenyl group Chemical group 0.000 claims description 4
150000002430 hydrocarbons Chemical class 0.000 claims description 4
229910052740 iodine Chemical group 0.000 claims description 4
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 3
CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 claims description 3
229940006460 bromide ion Drugs 0.000 claims description 3
229930195733 hydrocarbon Natural products 0.000 claims description 3
239000004215 Carbon black (E152) Substances 0.000 claims description 2
125000005843 halogen group Chemical group 0.000 claims description 2
238000000605 extraction Methods 0.000 claims 1
239000007858 starting material Substances 0.000 claims 1
229910052718 tin Inorganic materials 0.000 description 43
JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 12
239000010410 layer Substances 0.000 description 11
238000009835 boiling Methods 0.000 description 10
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 8
239000012071 phase Substances 0.000 description 7
239000011541 reaction mixture Substances 0.000 description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
239000003085 diluting agent Substances 0.000 description 6
150000004010 onium ions Chemical class 0.000 description 6
239000011592 zinc chloride Substances 0.000 description 6
235000005074 zinc chloride Nutrition 0.000 description 6
150000001298 alcohols Chemical class 0.000 description 5
125000004429 atom Chemical group 0.000 description 5
239000000463 material Substances 0.000 description 5
239000000843 powder Substances 0.000 description 5
230000035484 reaction time Effects 0.000 description 5
HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 5
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
GCTFWCDSFPMHHS-UHFFFAOYSA-M Tributyltin chloride Chemical compound CCCC[Sn](Cl)(CCCC)CCCC GCTFWCDSFPMHHS-UHFFFAOYSA-M 0.000 description 3
239000006227 byproduct Substances 0.000 description 3
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
239000007789 gas Substances 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
239000000376 reactant Substances 0.000 description 3
239000003381 stabilizer Substances 0.000 description 3
CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 2
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
150000001340 alkali metals Chemical class 0.000 description 2
229910052784 alkaline earth metal Inorganic materials 0.000 description 2
150000001342 alkaline earth metals Chemical class 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
125000003710 aryl alkyl group Chemical group 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
150000001805 chlorine compounds Chemical class 0.000 description 2
238000001816 cooling Methods 0.000 description 2
SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
239000012259 ether extract Substances 0.000 description 2
238000001704 evaporation Methods 0.000 description 2
230000008020 evaporation Effects 0.000 description 2
230000007717 exclusion Effects 0.000 description 2
239000000706 filtrate Substances 0.000 description 2
238000004508 fractional distillation Methods 0.000 description 2
238000004817 gas chromatography Methods 0.000 description 2
229910052736 halogen Inorganic materials 0.000 description 2
150000002367 halogens Chemical class 0.000 description 2
238000011065 in-situ storage Methods 0.000 description 2
239000000543 intermediate Substances 0.000 description 2
150000002576 ketones Chemical class 0.000 description 2
239000006194 liquid suspension Substances 0.000 description 2
239000011777 magnesium Substances 0.000 description 2
229910052749 magnesium Inorganic materials 0.000 description 2
238000002844 melting Methods 0.000 description 2
230000008018 melting Effects 0.000 description 2
239000007769 metal material Substances 0.000 description 2
239000012074 organic phase Substances 0.000 description 2
239000003208 petroleum Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical compound CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 description 2
IFXQFMQQHDIQJS-UHFFFAOYSA-N 1-chlorobutane;1-chlorooctane Chemical compound CCCCCl.CCCCCCCCCl IFXQFMQQHDIQJS-UHFFFAOYSA-N 0.000 description 1
ZYVYEJXMYBUCMN-UHFFFAOYSA-N 1-methoxy-2-methylpropane Chemical compound COCC(C)C ZYVYEJXMYBUCMN-UHFFFAOYSA-N 0.000 description 1
KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
239000002879 Lewis base Substances 0.000 description 1
NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
229910001128 Sn alloy Inorganic materials 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
229910001297 Zn alloy Inorganic materials 0.000 description 1
230000001476 alcoholic effect Effects 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
239000003513 alkali Substances 0.000 description 1
150000008044 alkali metal hydroxides Chemical class 0.000 description 1
229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
150000001350 alkyl halides Chemical class 0.000 description 1
239000008346 aqueous phase Substances 0.000 description 1
125000002029 aromatic hydrocarbon group Chemical group 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
238000010923 batch production Methods 0.000 description 1
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
VBQDSLGFSUGBBE-UHFFFAOYSA-N benzyl(triethyl)azanium Chemical compound CC[N+](CC)(CC)CC1=CC=CC=C1 VBQDSLGFSUGBBE-UHFFFAOYSA-N 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
LXXQZQRSAHHWJX-UHFFFAOYSA-N chloroform 1,2-dichloroethane Chemical compound C(Cl)(Cl)Cl.ClCCCl.C(CCl)Cl LXXQZQRSAHHWJX-UHFFFAOYSA-N 0.000 description 1
239000002026 chloroform extract Substances 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
125000000753 cycloalkyl group Chemical group 0.000 description 1
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
150000001983 dialkylethers Chemical class 0.000 description 1
AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
238000004821 distillation Methods 0.000 description 1
239000000428 dust Substances 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000000284 extract Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000000417 fungicide Substances 0.000 description 1
239000008187 granular material Substances 0.000 description 1
150000002366 halogen compounds Chemical class 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
239000012442 inert solvent Substances 0.000 description 1
PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical group II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
238000002955 isolation Methods 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
150000007527 lewis bases Chemical class 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
238000002156 mixing Methods 0.000 description 1
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
125000001624 naphthyl group Chemical group 0.000 description 1
239000003921 oil Substances 0.000 description 1
239000012044 organic layer Substances 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
229910000073 phosphorus hydride Inorganic materials 0.000 description 1
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical class CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000000243 solution Substances 0.000 description 1
235000011150 stannous chloride Nutrition 0.000 description 1
238000003756 stirring Methods 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical compound CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 description 1
DPKBAXPHAYBPRL-UHFFFAOYSA-M tetrabutylazanium;iodide Chemical compound [I-].CCCC[N+](CCCC)(CCCC)CCCC DPKBAXPHAYBPRL-UHFFFAOYSA-M 0.000 description 1
RWWNQEOPUOCKGR-UHFFFAOYSA-N tetraethyltin Chemical group CC[Sn](CC)(CC)CC RWWNQEOPUOCKGR-UHFFFAOYSA-N 0.000 description 1
125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 description 1
CHYBTAZWINMGHA-UHFFFAOYSA-N tetraoctylazanium Chemical compound CCCCCCCC[N+](CCCCCCCC)(CCCCCCCC)CCCCCCCC CHYBTAZWINMGHA-UHFFFAOYSA-N 0.000 description 1
OIQCWAIEHVRCCG-UHFFFAOYSA-N tetrapropylstannane Chemical class CCC[Sn](CCC)(CCC)CCC OIQCWAIEHVRCCG-UHFFFAOYSA-N 0.000 description 1
239000011135 tin Substances 0.000 description 1
150000003606 tin compounds Chemical class 0.000 description 1
AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 description 1
125000003944 tolyl group Chemical group 0.000 description 1
XMHKTINRBAKEDS-UHFFFAOYSA-N trioctyltin Chemical class CCCCCCCC[Sn](CCCCCCCC)CCCCCCCC XMHKTINRBAKEDS-UHFFFAOYSA-N 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
238000010626 work up procedure Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
- C07F7/2208—Compounds having tin linked only to carbon, hydrogen and/or halogen

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)

DE19782821705 1977-05-18 1978-05-18 Verfahren zur herstellung von organozinnverbindungen Withdrawn DE2821705A1 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
GB2090277		1977-05-18

Publications (1)

Publication Number	Publication Date
DE2821705A1 true DE2821705A1 (de)	1978-11-30

Family

ID=10153716

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DE19782821705 Withdrawn DE2821705A1 (de)	1977-05-18	1978-05-18	Verfahren zur herstellung von organozinnverbindungen

Country Status (14)

Country	Link
JP (1)	JPS53144533A (xx)
AU (1)	AU3620878A (xx)
BE (1)	BE867169R (xx)
BR (1)	BR7803258A (xx)
DE (1)	DE2821705A1 (xx)
DK (1)	DK217678A (xx)
ES (1)	ES469950A1 (xx)
FR (1)	FR2391220A2 (xx)
IT (1)	IT7868128A0 (xx)
NL (1)	NL7805310A (xx)
NO (1)	NO781716L (xx)
NZ (1)	NZ187219A (xx)
SE (1)	SE7805672L (xx)
ZA (1)	ZA782657B (xx)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE4006043C1 (xx) *	1990-02-26	1991-04-18	Th. Goldschmidt Ag, 4300 Essen, De

1978
- 1978-05-09 ZA ZA00782657A patent/ZA782657B/xx unknown
- 1978-05-10 NZ NZ187219A patent/NZ187219A/xx unknown
- 1978-05-16 NO NO78781716A patent/NO781716L/no unknown
- 1978-05-17 NL NL7805310A patent/NL7805310A/xx not_active Application Discontinuation
- 1978-05-17 FR FR7814653A patent/FR2391220A2/fr active Granted
- 1978-05-17 DK DK217678A patent/DK217678A/da unknown
- 1978-05-17 SE SE7805672A patent/SE7805672L/xx unknown
- 1978-05-17 IT IT7868128A patent/IT7868128A0/it unknown
- 1978-05-17 AU AU36208/78A patent/AU3620878A/en active Pending
- 1978-05-17 BE BE187774A patent/BE867169R/xx active
- 1978-05-17 ES ES469950A patent/ES469950A1/es not_active Expired
- 1978-05-18 JP JP5833678A patent/JPS53144533A/ja active Pending
- 1978-05-18 DE DE19782821705 patent/DE2821705A1/de not_active Withdrawn
- 1978-05-18 BR BR7803258A patent/BR7803258A/pt unknown

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE4006043C1 (xx) *	1990-02-26	1991-04-18	Th. Goldschmidt Ag, 4300 Essen, De

Also Published As

Publication number	Publication date
NL7805310A (nl)	1978-11-21
JPS53144533A (en)	1978-12-15
BE867169R (fr)	1978-11-17
NO781716L (no)	1978-11-21
NZ187219A (en)	1980-12-19
FR2391220B2 (xx)	1980-07-04
SE7805672L (sv)	1978-11-19
IT7868128A0 (it)	1978-05-17
ES469950A1 (es)	1979-09-16
FR2391220A2 (fr)	1978-12-15
DK217678A (da)	1978-11-19
AU3620878A (en)	1979-11-22
ZA782657B (en)	1979-05-30
BR7803258A (pt)	1979-01-02

Legal Events

Date	Code	Title
1978-11-30	OAR	Request for search filed
1979-01-18	OB	Request for examination as to novelty
1979-10-31	OC	Search report available
1982-09-09	8139	Disposal/non-payment of the annual fee

Publication	Publication Date	Title
DE2540210C3 (de)	1983-12-01	Verfahren zur Herstellung von Organozinntrihalogeniden
DE2607178C3 (de)	1983-03-03	Verfahren zur Herstellung von Organozinndihalogeniden oder Gemischen aus Organozinndihalogeniden und Organozinntrihalogeniden
DE69310363T2 (de)	1997-08-21	Verfahren zur herstellung von trialkylverbindungen von metallen der gruppe 3a
CH618179A5 (xx)	1980-07-15
CH622759A5 (xx)	1981-04-30
DE2821705A1 (de)	1978-11-30	Verfahren zur herstellung von organozinnverbindungen
DE2646455C2 (xx)	1987-10-15
DE2226774C3 (de)	1981-12-10	Verfahren zur Herstellung von Distannanen der Formel R↓3↓Sn-Sn R↓3↓
DE1217951B (de)	1966-06-02	Verfahren zur Herstellung von Alkylzinnhalogenidgemischen mit hohem Anteil an Dialkylzinndihalogeniden
DE2749083C2 (de)	1987-03-26	Verfahren zur Herstellung von Organozinnverbindungen
DE2701146A1 (de)	1977-07-28	Verfahren zur herstellung von organozinnverbindungen
DE1283839B (de)	1968-11-28	Verfahren zur Herstellung von aliphatischen Organozinnhalogeniden
DE2545065C3 (de)	1979-04-19	Verfahren zur Herstellung von Monomethylzinntrihalogeniden
DE1945645A1 (de)	1970-03-26	Verfahren zur Herstellung von Diorganochlorphosphinen
DE2840272A1 (de)	1979-04-05	Verfahren zur herstellung von o-benzyltoluol und alkylderivaten desselben
DE2200697A1 (de)	1972-07-20	Verfahren zur Herstellung von Methylzinnverbindungen
DE2506917C3 (de)	1982-02-25	Verfahren zur Herstellung eines Alkylzinnchlorids
DE2218211C2 (de)	1982-09-16	Verfahren zur Herstellung von asymmetrischen Triorganozinnhalogeniden
DE102016217012A1 (de)	2017-03-16	Verfahren zur Vorbereitung von hochreinem Monooctylzinn-Trichlorid
AT257655B (de)	1967-10-25	Verfahren zur Herstellung von Alk(en)yl-zinnhalogenidgemischen
DE2837451A1 (de)	1979-03-15	Verfahren zur herstellung von dimethylzinndichlorid
DE3535033C2 (xx)	1988-09-29
AT215427B (de)	1961-06-12	Verfahren zur Herstellung von Dibenzylzinndihalogeniden bzw. im Benzolkern substituierten Dibenzylzinndihalogeniden
DE19624906B4 (de)	2004-04-29	Verfahren zur Herstellung von Organozinntrihalogeniden und Diorganozinndihalogeniden
DE1955463C3 (de)	1979-07-12	Verfahren zur Herstellung von Tricyclohexylzinnchlorid

DE2821705A1 - Verfahren zur herstellung von organozinnverbindungen - Google Patents

Info

Links

Classifications

Landscapes

Applications Claiming Priority (1)

Publications (1)

Family

ID=10153716

Family Applications (1)

Country Status (14)

Cited By (1)

Cited By (1)

Also Published As

Similar Documents

Legal Events