DE1811063C - - Google Patents

Info

Publication number: DE1811063C
Authority: DE; Germany
Prior art keywords: catalyst; weight; oxygen; percent; propylene
Prior art date: 1967-11-28
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

DE19681811063

Other languages

German (de)

English (en)

Other versions

DE1811063B2 (de

DE1811063A1 (de

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1967-11-28

Filing date

1968-11-26

Publication date

1973-08-09

1968-09-20 Priority claimed from JP43067580A external-priority patent/JPS492085B1/ja

1968-11-26 Application filed filed Critical

1969-08-14 Publication of DE1811063A1 publication Critical patent/DE1811063A1/de

1973-01-18 Publication of DE1811063B2 publication Critical patent/DE1811063B2/de

1973-08-09 Application granted granted Critical

1973-08-09 Publication of DE1811063C publication Critical patent/DE1811063C/de

Status Granted legal-status Critical Current

Links

239000003054 catalyst Substances 0.000 claims description 159
238000006243 chemical reaction Methods 0.000 claims description 76
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 62
239000000203 mixture Substances 0.000 claims description 52
MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 35
239000001301 oxygen Substances 0.000 claims description 34
229910052760 oxygen Inorganic materials 0.000 claims description 34
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 33
150000001336 alkenes Chemical class 0.000 claims description 30
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
VQTUBCCKSQIDNK-UHFFFAOYSA-N isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 24
NLHHRLWOUZZQLW-UHFFFAOYSA-N acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 23
239000007789 gas Substances 0.000 claims description 21
230000000694 effects Effects 0.000 claims description 20
238000007254 oxidation reaction Methods 0.000 claims description 19
230000003647 oxidation Effects 0.000 claims description 17
KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 14
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 13
238000005839 oxidative dehydrogenation reaction Methods 0.000 claims description 13
OAICVXFJPJFONN-UHFFFAOYSA-N phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 13
229910052698 phosphorus Inorganic materials 0.000 claims description 13
239000011574 phosphorus Substances 0.000 claims description 13
STNJBCKSHOAVAJ-UHFFFAOYSA-N Methacrolein Chemical compound CC(=C)C=O STNJBCKSHOAVAJ-UHFFFAOYSA-N 0.000 claims description 12
ZOXJGFHDIHLPTG-UHFFFAOYSA-N boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 12
229910052796 boron Chemical group 0.000 claims description 12
QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 11
HGINCPLSRVDWNT-UHFFFAOYSA-N acrylaldehyde Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 claims description 10
238000004519 manufacturing process Methods 0.000 claims description 10
GYCMBHHDWRMZGG-UHFFFAOYSA-N 2-cyanopropene-1 Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 claims description 9
OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
229910052799 carbon Inorganic materials 0.000 claims description 9
229910052750 molybdenum Inorganic materials 0.000 claims description 9
239000011733 molybdenum Substances 0.000 claims description 9
ZOKXTWBITQBERF-UHFFFAOYSA-N molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 8
229910052720 vanadium Inorganic materials 0.000 claims description 8
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 7
229910052721 tungsten Inorganic materials 0.000 claims description 7
239000010937 tungsten Substances 0.000 claims description 7
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium(0) Chemical group [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 7
230000003197 catalytic Effects 0.000 claims description 6
RRHGJUQNOFWUDK-UHFFFAOYSA-N isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 6
MHNNAWXXUZQSNM-UHFFFAOYSA-N 2-methylbut-1-ene Chemical compound CCC(C)=C MHNNAWXXUZQSNM-UHFFFAOYSA-N 0.000 claims description 5
DJGPQOFRRRXVHB-UHFFFAOYSA-N [Sb+]=O.[O-2].[Fe+2] Chemical compound [Sb+]=O.[O-2].[Fe+2] DJGPQOFRRRXVHB-UHFFFAOYSA-N 0.000 claims description 5
229910000410 antimony oxide Inorganic materials 0.000 claims description 5
230000000875 corresponding Effects 0.000 claims description 5
WEVYAHXRMPXWCK-UHFFFAOYSA-N acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 4
150000001299 aldehydes Chemical class 0.000 claims description 4
CURLTUGMZLYLDI-UHFFFAOYSA-N carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 4
239000001569 carbon dioxide Substances 0.000 claims description 4
229910002092 carbon dioxide Inorganic materials 0.000 claims description 4
IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
150000001993 dienes Chemical class 0.000 claims description 3
150000002825 nitriles Chemical class 0.000 claims description 2
229910052757 nitrogen Inorganic materials 0.000 claims description 2
230000004913 activation Effects 0.000 claims 3
229910052751 metal Inorganic materials 0.000 claims 3
LELOWRISYMNNSU-UHFFFAOYSA-N Hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 claims 2
230000036881 Clu Effects 0.000 claims 1
230000003213 activating Effects 0.000 claims 1
UGFAIRIUMAVXCW-UHFFFAOYSA-N carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 1
229910002091 carbon monoxide Inorganic materials 0.000 claims 1
239000000470 constituent Substances 0.000 claims 1
238000009776 industrial production Methods 0.000 claims 1
238000009114 investigational therapy Methods 0.000 claims 1
230000000052 comparative effect Effects 0.000 description 55
229910004298 SiO 2 Inorganic materials 0.000 description 34
238000001354 calcination Methods 0.000 description 17
PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 15
229910052714 tellurium Inorganic materials 0.000 description 14
238000007792 addition Methods 0.000 description 13
GRYLNZFGIOXLOG-UHFFFAOYSA-N nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 13
239000000047 product Substances 0.000 description 12
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
-1 antimony halides Chemical class 0.000 description 9
IZYSFFFJIOTJEV-UHFFFAOYSA-P diazanium;dioxido(dioxo)tungsten Chemical compound [NH4+].[NH4+].[O-][W]([O-])(=O)=O IZYSFFFJIOTJEV-UHFFFAOYSA-P 0.000 description 9
229910052742 iron Inorganic materials 0.000 description 9
FGIUAXJPYTZDNR-UHFFFAOYSA-N Potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 8
WATWJIUSRGPENY-UHFFFAOYSA-N antimony Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 8
229910052787 antimony Inorganic materials 0.000 description 8
239000000969 carrier Substances 0.000 description 8
NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
239000000843 powder Substances 0.000 description 8
230000015572 biosynthetic process Effects 0.000 description 7
238000005755 formation reaction Methods 0.000 description 7
239000000463 material Substances 0.000 description 7
239000008188 pellet Substances 0.000 description 7
238000003756 stirring Methods 0.000 description 7
XHGGEBRKUWZHEK-UHFFFAOYSA-N telluric acid Chemical compound O[Te](O)(=O)=O XHGGEBRKUWZHEK-UHFFFAOYSA-N 0.000 description 7
LPXPTNMVRIOKMN-UHFFFAOYSA-M Sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 6
LAJZODKXOMJMPK-UHFFFAOYSA-N Tellurium dioxide Chemical compound O=[Te]=O LAJZODKXOMJMPK-UHFFFAOYSA-N 0.000 description 6
IAQRGUVFOMOMEM-ONEGZZNKSA-N trans-but-2-ene Chemical compound C\C=C\C IAQRGUVFOMOMEM-ONEGZZNKSA-N 0.000 description 6
239000002253 acid Substances 0.000 description 5
UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 description 5
239000000376 reactant Substances 0.000 description 5
239000000377 silicon dioxide Substances 0.000 description 5
239000000243 solution Substances 0.000 description 5
KGBXLFKZBHKPEV-UHFFFAOYSA-N Boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 4
229910000147 aluminium phosphate Inorganic materials 0.000 description 4
VHUUQVKOLVNVRT-UHFFFAOYSA-N ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 4
235000011114 ammonium hydroxide Nutrition 0.000 description 4
238000009835 boiling Methods 0.000 description 4
239000004327 boric acid Substances 0.000 description 4
238000004817 gas chromatography Methods 0.000 description 4
UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
238000000034 method Methods 0.000 description 4
239000011259 mixed solution Substances 0.000 description 4
VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 4
239000004323 potassium nitrate Substances 0.000 description 4
235000010333 potassium nitrate Nutrition 0.000 description 4
239000002244 precipitate Substances 0.000 description 4
235000012239 silicon dioxide Nutrition 0.000 description 4
239000007787 solid Substances 0.000 description 4
239000000126 substance Substances 0.000 description 4
230000001629 suppression Effects 0.000 description 4
125000000383 tetramethylene group Chemical class [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 4
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 3
NCNCGGDMXMBVIA-UHFFFAOYSA-L Iron(II) hydroxide Chemical compound [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 description 3
238000006297 dehydration reaction Methods 0.000 description 3
238000005470 impregnation Methods 0.000 description 3
235000014413 iron hydroxide Nutrition 0.000 description 3
230000001590 oxidative Effects 0.000 description 3
235000010288 sodium nitrite Nutrition 0.000 description 3
239000011949 solid catalyst Substances 0.000 description 3
239000007858 starting material Substances 0.000 description 3
QGAVSDVURUSLQK-UHFFFAOYSA-N Ammonium heptamolybdate Chemical compound N.N.N.N.N.N.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo] QGAVSDVURUSLQK-UHFFFAOYSA-N 0.000 description 2
LJCFOYOSGPHIOO-UHFFFAOYSA-N Antimony pentoxide Chemical compound O=[Sb](=O)O[Sb](=O)=O LJCFOYOSGPHIOO-UHFFFAOYSA-N 0.000 description 2
FAPDDOBMIUGHIN-UHFFFAOYSA-K Antimony trichloride Chemical compound Cl[Sb](Cl)Cl FAPDDOBMIUGHIN-UHFFFAOYSA-K 0.000 description 2
ADCOVFLJGNWWNZ-UHFFFAOYSA-N Antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
239000000654 additive Substances 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
239000011609 ammonium molybdate Substances 0.000 description 2
229940010552 ammonium molybdate Drugs 0.000 description 2
235000018660 ammonium molybdate Nutrition 0.000 description 2
SPGWBYVENFBECR-UHFFFAOYSA-N antimony;chloro hypochlorite Chemical compound [Sb].ClOCl SPGWBYVENFBECR-UHFFFAOYSA-N 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
239000011230 binding agent Substances 0.000 description 2
238000006555 catalytic reaction Methods 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
238000000354 decomposition reaction Methods 0.000 description 2
239000003085 diluting agent Substances 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
229910000460 iron oxide Inorganic materials 0.000 description 2
159000000014 iron salts Chemical class 0.000 description 2
VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 description 2
JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 2
239000003208 petroleum Substances 0.000 description 2
239000012495 reaction gas Substances 0.000 description 2
230000003014 reinforcing Effects 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
239000011780 sodium chloride Substances 0.000 description 2
PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
KUGFODPTKMDJNG-UHFFFAOYSA-I Antimony pentachloride Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[SbH3+3] KUGFODPTKMDJNG-UHFFFAOYSA-I 0.000 description 1
VEPSWGHMGZQCIN-UHFFFAOYSA-H Ferric oxalate Chemical compound [Fe+3].[Fe+3].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O VEPSWGHMGZQCIN-UHFFFAOYSA-H 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
NMCUIPGRVMDVDB-UHFFFAOYSA-L Iron(II) chloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 1
VLAPMBHFAWRUQP-UHFFFAOYSA-L Molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 description 1
241000158147 Sator Species 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
GNTDGMZSJNCJKK-UHFFFAOYSA-N Vanadium(V) oxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 1
229940037003 alum Drugs 0.000 description 1
150000001462 antimony Chemical class 0.000 description 1
229910000411 antimony tetroxide Inorganic materials 0.000 description 1
150000001639 boron compounds Chemical class 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
239000001273 butane Substances 0.000 description 1
IAQRGUVFOMOMEM-ARJAWSKDSA-N cis-but-2-ene Chemical compound C\C=C/C IAQRGUVFOMOMEM-ARJAWSKDSA-N 0.000 description 1
229910052593 corundum Inorganic materials 0.000 description 1
239000010431 corundum Substances 0.000 description 1
238000006356 dehydrogenation reaction Methods 0.000 description 1
OTMSDBZUPAUEDD-UHFFFAOYSA-N ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
239000008246 gaseous mixture Substances 0.000 description 1
230000005484 gravity Effects 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
229910000041 hydrogen chloride Inorganic materials 0.000 description 1
239000012535 impurity Substances 0.000 description 1
229910052909 inorganic silicate Inorganic materials 0.000 description 1
CDVDBGXLSOHXOF-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[Fe+2].[Fe+3] CDVDBGXLSOHXOF-UHFFFAOYSA-N 0.000 description 1
PVFSDGKDKFSOTB-UHFFFAOYSA-K iron(3+);triacetate Chemical compound [Fe+3].CC([O-])=O.CC([O-])=O.CC([O-])=O PVFSDGKDKFSOTB-UHFFFAOYSA-K 0.000 description 1
SZQUEWJRBJDHSM-UHFFFAOYSA-N iron(3+);trinitrate;nonahydrate Chemical compound O.O.O.O.O.O.O.O.O.[Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O SZQUEWJRBJDHSM-UHFFFAOYSA-N 0.000 description 1
239000007788 liquid Substances 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
150000007522 mineralic acids Chemical class 0.000 description 1
238000002156 mixing Methods 0.000 description 1
MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 1
239000005078 molybdenum compound Substances 0.000 description 1
150000002752 molybdenum compounds Chemical class 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
230000036284 oxygen consumption Effects 0.000 description 1
OFBQJSOFQDEBGM-UHFFFAOYSA-N pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000004886 process control Methods 0.000 description 1
ATUOYWHBWRKTHZ-UHFFFAOYSA-N propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 1
239000001294 propane Substances 0.000 description 1
238000004153 renaturation Methods 0.000 description 1
230000001932 seasonal Effects 0.000 description 1
238000007086 side reaction Methods 0.000 description 1
239000002002 slurry Substances 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000009331 sowing Methods 0.000 description 1
239000010959 steel Substances 0.000 description 1
239000006188 syrup Substances 0.000 description 1
235000020357 syrup Nutrition 0.000 description 1
238000004227 thermal cracking Methods 0.000 description 1
150000003682 vanadium compounds Chemical class 0.000 description 1
GRUMUEUJTSXQOI-UHFFFAOYSA-N vanadium dioxide Chemical compound O=[V]=O GRUMUEUJTSXQOI-UHFFFAOYSA-N 0.000 description 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

DE19681811063 1967-11-28 1968-11-26 Verwendung eines aktivierten katalysators auf der basis von eisenoxid-antimonoxid bei der oxydation bzw. oxydativen dehydrierung von olefinen Granted DE1811063B2 (de)

Applications Claiming Priority (8)

Application Number	Priority Date	Filing Date
JP7589067		1967-11-28
JP7589067		1967-11-28
JP6758068		1968-09-20
JP6757868		1968-09-20
JP6757968		1968-09-20
JP6757868		1968-09-20
JP6757968		1968-09-20
JP43067580A JPS492085B1 (es)	1968-09-20	1968-09-20

Publications (3)

Publication Number	Publication Date
DE1811063A1 DE1811063A1 (de)	1969-08-14
DE1811063B2 DE1811063B2 (de)	1973-01-18
DE1811063C true DE1811063C (es)	1973-08-09

Family

ID=27464874

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DE19681811063 Granted DE1811063B2 (de)	1967-11-28	1968-11-26	Verwendung eines aktivierten katalysators auf der basis von eisenoxid-antimonoxid bei der oxydation bzw. oxydativen dehydrierung von olefinen

Country Status (7)

Country	Link
US (1)	US3668147A (es)
BE (1)	BE730696A (es)
DE (1)	DE1811063B2 (es)
FR (1)	FR1593484A (es)
GB (1)	GB1208690A (es)
IT (1)	IT859097A (es)
NL (1)	NL140163B (es)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
BE627213A (es) *	1962-01-18
US3716496A (en) *	1969-09-06	1973-02-13	Nitto Chemical Industry Co Ltd	Catalyst composition for the oxidation and the oxidative dehydrogenation of olefins
AU465139B2 (en) *	1971-09-02	1975-09-18	SNAMPROGETTI Sp. A	Improved catalysts forthe oxidation of olefines
US4151117A (en) *	1971-09-07	1979-04-24	Rohm And Haas Company	Novel oxidation catalyst and production of unsaturated aldehydes, acids and nitriles therewith
US3875078A (en) *	1972-02-15	1975-04-01	Celanese Corp	Catalyst for oxidation of olefins
DE2212964C3 (de) *	1972-03-17	1980-01-31	Basf Ag, 6700 Ludwigshafen	Vanadinpentoxid, Titandioxid und gegebenenfalls Zirkondioxid, Phosphor sowie weitere Metalloxide enthaltender Trägerkatalysator
DE2235993C2 (de) *	1972-07-21	1984-09-06	Nitto Chemical Industry Co., Ltd., Tokio / Tokyo	Verfahren zur gleichzeitigen Herstellung von Methacrylnitril und Butadien
GB1417787A (en) *	1972-11-13	1975-12-17	Mitsubishi Rayon Co	Catalyst composition for oxidation of butenes
FR2208399A5 (es) *	1972-11-27	1974-06-21	Ugine Kuhlmann
US4093558A (en) *	1972-12-08	1978-06-06	The Standard Oil Company	Molybdate catalysts
US3886096A (en) *	1973-01-02	1975-05-27	Monsanto Co	Oxidation and ammoxidation catalyst
US4083804A (en) *	1974-02-09	1978-04-11	Nitto Chemical Industry Co., Ltd.	Catalyst for use in and process for preparing acrylonitrile
JPS5318014B2 (es) *	1974-02-09	1978-06-13
US4000088A (en) *	1974-06-03	1976-12-28	Nippon Kayaku Co., Ltd.	Oxidation catalyst for the manufacture of methacrylic acid
JPS5242552B2 (es) *	1974-08-01	1977-10-25
JPS52125124A (en) *	1976-04-10	1977-10-20	Nitto Chem Ind Co Ltd	Manufacture of acrylonitrile
JPS5462193A (en) *	1977-10-26	1979-05-18	Nitto Chem Ind Co Ltd	Regenerating method for iron antimony type oxide catalyst
JPS5924662B2 (ja) *	1977-11-12	1984-06-11	日東化学工業株式会社	アンチモン含有酸化物触媒の再生法
JPS56126448A (en) *	1980-03-12	1981-10-03	Nitto Chem Ind Co Ltd	Production of antimony-containing oxide catalyst
EP0076678B1 (en) *	1981-10-07	1987-01-07	Nitto Chemical Industry Co., Ltd.	Process for ammoxidation of organic compounds
US4590011A (en) *	1983-11-23	1986-05-20	Monsanto Company	Ammoxidation process
US4746641A (en) *	1984-08-22	1988-05-24	Standard Oil Company	Ammoxidation of paraffins and catalysts therefor
US4788173A (en) *	1985-12-20	1988-11-29	The Standard Oil Company	Catalytic mixtures for ammoxidation of paraffins
US4783545A (en) *	1985-12-20	1988-11-08	The Standard Oil Company	Method for ammoxidation of paraffins and catalyst system therefor
US4837233A (en) *	1986-07-21	1989-06-06	The Standard Oil Company	Catalyst system for ammoxidation of paraffins
US5079379A (en) *	1988-12-29	1992-01-07	Monsanto Company	Fluid bed process
GB9316955D0 (en)	1993-08-14	1993-09-29	Johnson Matthey Plc	Improvements in catalysts
US5877377A (en) *	1993-08-14	1999-03-02	Johnson Matthey Public Limited Company	Metal oxide catalyst and use thereof in chemical reactions
JP2006508499A (ja) *	2002-07-23	2006-03-09	コーニンクレッカ　フィリップス　エレクトロニクス　エヌ　ヴィ	ランプ
JP5011176B2 (ja) *	2008-03-14	2012-08-29	ダイヤニトリックス株式会社	アクリロニトリル合成用触媒およびアクリロニトリルの製造方法
US8293960B2 (en)	2009-08-17	2012-10-23	Lummus Technology Inc.	Process for the production of butadiene
WO2016145023A1 (en) *	2015-03-10	2016-09-15	Ph Matter, Llc	Chromium-free water-gas shift catalyst and process for making the same
JP7204787B2 (ja)	2018-06-28	2023-01-16	アセンド・パフォーマンス・マテリアルズ・オペレーションズ・リミテッド・ライアビリティ・カンパニー	流動床反応器においてシリカ粒子を使用する方法およびシステム

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
IT605134A (es) *	1959-02-24
IT701822A (es) *	1961-11-30
BE633452A (es) *	1962-06-11
US3200141A (en) *	1963-05-27	1965-08-10	Standard Oil Co	Process for the manufacture of acrylonitrile
CA774587A (en) *	1965-08-30	1967-12-26	The B. F. Goodrich Company	Process for preparing unsaturated nitriles
US3338952A (en) *	1965-11-15	1967-08-29	Standard Oil Co	Process for the catalytic ammoxidation of olefins to nitriles
US3445521A (en) *	1966-11-17	1969-05-20	Standard Oil Co	Promoted antimony-iron oxidation catalyst

0
- IT IT859097D patent/IT859097A/it unknown
1968
- 1968-11-19 US US777104A patent/US3668147A/en not_active Expired - Lifetime
- 1968-11-21 GB GB55392/68A patent/GB1208690A/en not_active Expired
- 1968-11-26 DE DE19681811063 patent/DE1811063B2/de active Granted
- 1968-11-27 FR FR1593484D patent/FR1593484A/fr not_active Expired
1969
- 1969-03-28 BE BE730696D patent/BE730696A/xx not_active IP Right Cessation
- 1969-03-28 NL NL696904857A patent/NL140163B/xx not_active IP Right Cessation

Publication	Publication Date	Title
DE1811063C (es)	1973-08-09
DE1811063B2 (de)	1973-01-18	Verwendung eines aktivierten katalysators auf der basis von eisenoxid-antimonoxid bei der oxydation bzw. oxydativen dehydrierung von olefinen
DE69012450T2 (de)	1995-03-02	Verfahren zur Herstellung von Eisen-Phosphor und Antimon enthaltenden Metalloxid-Oxidationskatalysatoren.
DE69011495T3 (de)	1998-07-16	Katalysator und Verfahren zur Herstellung von Acrylonitril und Methacrylonitril.
DE1958290A1 (de)	1970-07-16	Oxydehydrierungskatalysator und seine Verwendung zur Umwandlung von Isoamylenen,Methylbutanolen und Gemischen hiervon in Isopren
DE2505249A1 (de)	1975-08-21	Verfahren zur herstellung von acrylnitril
DE2043995C3 (es)	1978-10-26
DE1255105B (de)	1967-11-30	Verfahren zur Herstellung von Acrylsaeurenitril und Methacrylsaeurenitril aus Propylen oder Isobutylen, Ammoniak und Sauerstoff
DE69105890T2 (de)	1995-05-18	Eisen-Antimon enthaltender Katalysator sowie Verfahren zur Herstellung desselben.
DE2155109C3 (de)	1978-03-16	Verfahren zur gleichzeitigen Herstellung von 13-Butadien und Methacrolein
DE2203709A1 (es)	1972-08-17
EP0088328A2 (de)	1983-09-14	Oxidationskatalysator, inbesondere für die Herstellung von Methacrylsäure durch Gasphasenoxidation von Methacrolein
DE2147480C2 (de)	1984-09-06	Verfahren zur Herstellung von Acrylnitril und Methacrylnitril
DE68907642T2 (de)	1993-11-04	Verfahren zur herstellung von cyanwasserstoff durch katalytische ammoxidierung in der gasphase von methanol.
DE1811062A1 (de)	1969-07-10	Verfahren zur Herstellung von Acrylnitril
DE2004874C3 (de)	1978-11-02	Oxydationskatalysator mit Oxyden der Elemente Mo, V, W und Mn
DE1268609B (de)	1968-05-22	Verfahren zur Herstellung von (Meth) Acrolein und (Meth) Acrylsaeure durch katalytische Oxydation von Propylen bzw. Isobutylen
DE1767268C3 (de)	1974-04-25	Verfahren zur Herstellung von Acrylnitril aus Propylen
DE69818718T2 (de)	2004-09-23	Herstellung von Vanadiumantimonatkatalysatoren unter Verwendung von Sn02, nH20
DE69306099T2 (de)	1997-03-13	Verfahren zur Herstellung von Monoalkenylbenzolen
DE2124639A1 (es)	1971-12-02
DE69012279T2 (de)	1995-02-02	Verfahren zur Herstellung ungesättigter Verbindungen.
DE2235993C2 (de)	1984-09-06	Verfahren zur gleichzeitigen Herstellung von Methacrylnitril und Butadien
DE2125640B2 (de)	1978-04-27	Verfahren zur Herstellung von Acryl bzw. Methacrylnitril aus Propylen bzw. Isabutylen
DE2062025A1 (de)	1971-07-22	Verfahren zur Herstellung von Acrolein oder Methacrolein