CN109505048A - Based on superfine mulberry silk fiber/silk tussah fibre silk scarf fabrics - Google Patents
Based on superfine mulberry silk fiber/silk tussah fibre silk scarf fabrics Download PDFInfo
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- CN109505048A CN109505048A CN201811555502.5A CN201811555502A CN109505048A CN 109505048 A CN109505048 A CN 109505048A CN 201811555502 A CN201811555502 A CN 201811555502A CN 109505048 A CN109505048 A CN 109505048A
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- Prior art keywords
- silk
- mulberry silk
- fiber
- mulberry
- silk fiber
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- 235000008708 Morus alba Nutrition 0.000 title claims abstract description 182
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- 238000009955 starching Methods 0.000 claims abstract description 61
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 41
- VFLDPWHFBUODDF-FCXRPNKRSA-N curcumin Chemical compound C1=C(O)C(OC)=CC(\C=C\C(=O)CC(=O)\C=C\C=2C=C(OC)C(O)=CC=2)=C1 VFLDPWHFBUODDF-FCXRPNKRSA-N 0.000 claims abstract description 34
- 238000002360 preparation method Methods 0.000 claims abstract description 33
- 239000002105 nanoparticle Substances 0.000 claims abstract description 32
- 238000012545 processing Methods 0.000 claims abstract description 31
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000002002 slurry Substances 0.000 claims abstract description 19
- 229920000570 polyether Polymers 0.000 claims abstract description 18
- 239000000853 adhesive Substances 0.000 claims abstract description 17
- 230000001070 adhesive effect Effects 0.000 claims abstract description 17
- 229940109262 curcumin Drugs 0.000 claims abstract description 17
- 235000012754 curcumin Nutrition 0.000 claims abstract description 17
- 239000004148 curcumin Substances 0.000 claims abstract description 17
- VFLDPWHFBUODDF-UHFFFAOYSA-N diferuloylmethane Natural products C1=C(O)C(OC)=CC(C=CC(=O)CC(=O)C=CC=2C=C(OC)C(O)=CC=2)=C1 VFLDPWHFBUODDF-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229920000728 polyester Polymers 0.000 claims abstract description 17
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 14
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- 238000000034 method Methods 0.000 claims description 22
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- 241000255789 Bombyx mori Species 0.000 claims description 15
- 230000008569 process Effects 0.000 claims description 15
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 12
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 12
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 12
- 239000004327 boric acid Substances 0.000 claims description 12
- 239000004202 carbamide Substances 0.000 claims description 12
- 230000002255 enzymatic effect Effects 0.000 claims description 11
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims description 9
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 7
- -1 1- dodecyl Chemical group 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 102000004190 Enzymes Human genes 0.000 claims description 4
- 108090000790 Enzymes Proteins 0.000 claims description 4
- 108091005804 Peptidases Proteins 0.000 claims description 3
- 239000004365 Protease Substances 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 3
- 235000019441 ethanol Nutrition 0.000 claims description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 229910052727 yttrium Inorganic materials 0.000 claims description 3
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 3
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 2
- 230000018044 dehydration Effects 0.000 claims description 2
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- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 238000001354 calcination Methods 0.000 claims 1
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- 238000009941 weaving Methods 0.000 abstract description 12
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- 238000001035 drying Methods 0.000 description 9
- 239000000047 product Substances 0.000 description 8
- 238000004043 dyeing Methods 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
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- 230000035699 permeability Effects 0.000 description 7
- 238000002791 soaking Methods 0.000 description 5
- 235000014676 Phragmites communis Nutrition 0.000 description 3
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- 239000000463 material Substances 0.000 description 3
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- 241000196324 Embryophyta Species 0.000 description 2
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- 210000002268 wool Anatomy 0.000 description 2
- KKAJSJJFBSOMGS-UHFFFAOYSA-N 3,6-diamino-10-methylacridinium chloride Chemical compound [Cl-].C1=C(N)C=C2[N+](C)=C(C=C(N)C=C3)C3=CC2=C1 KKAJSJJFBSOMGS-UHFFFAOYSA-N 0.000 description 1
- 229910052582 BN Inorganic materials 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 201000004624 Dermatitis Diseases 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 206010054949 Metaplasia Diseases 0.000 description 1
- 229920001410 Microfiber Polymers 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- 244000273928 Zingiber officinale Species 0.000 description 1
- 235000006886 Zingiber officinale Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
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- 150000001413 amino acids Chemical class 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000008397 ginger Nutrition 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
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- 238000009940 knitting Methods 0.000 description 1
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Classifications
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D23/00—Scarves; Head-scarves; Neckerchiefs
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/14—Air permeable, i.e. capable of being penetrated by gases
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D13/00—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
- D03D13/008—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft characterised by weave density or surface weight
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
- D06L1/14—De-sizing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/80—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides
- D06M11/82—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides with boron oxides; with boric, meta- or perboric acids or their salts, e.g. with borax
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/2246—Esters of unsaturated carboxylic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/507—Polyesters
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
- D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2211/00—Protein-based fibres, e.g. animal fibres
- D10B2211/01—Natural animal fibres, e.g. keratin fibres
- D10B2211/04—Silk
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/06—Load-responsive characteristics
- D10B2401/063—Load-responsive characteristics high strength
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2501/00—Wearing apparel
- D10B2501/04—Outerwear; Protective garments
- D10B2501/042—Headwear
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
- General Chemical & Material Sciences (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Woven Fabrics (AREA)
Abstract
The invention discloses a kind of based on superfine mulberry silk fiber/silk tussah fibre silk scarf fabrics, preparation method, which is specifically included, impregnates the starching solution being made of water-soluble poly ester polyether slurry, turkey red oil, 1- orthododecyl nitrogen heterocyclo heptane-2-ketone, nanoparticle, adhesive SD28, curcumin and water for ultra-fine Raw Silk, carry out starching processing, then it dries, obtains starching ultrafine mulberry silk；By starching ultrafine mulberry silk by winder and silk twisting, through to mulberry silk fiber and broadwise mulberry silk fiber, refining obtains degumming through to mulberry silk fiber and degumming broadwise mulberry silk fiber for preparation；Then by degumming through being prepared through mixing weaving to silk tussah fibre based on superfine mulberry silk fiber/silk tussah fibre silk scarf fabrics to mulberry silk fiber, degumming broadwise mulberry silk fiber with degumming, the present invention is not easy to break end when having weaving, and elasticity is good and the good advantage of warmth retention property for cloth cover.
Description
Technical field
The invention belongs to field of fabric producing technology, and in particular to a kind of based on superfine mulberry silk fiber/silk tussah fibre
Silk scarf fabrics.
Background technique
Tussah silk has the good characteristics such as smooth comfortable, moisture retention is strong and cool in summer and warm in winter, in addition, tussah silk face fabric is rich in each
Kind is conducive to the natural amino acid of human skin, and the underclothes for often wearing tussah silk face fabric can improve skin quality, be not easy to draw
Play skin allergy, but its quality is well-pressed and not easy dyeing, the sight for people of gradually having faded out.The most of scarf are to be trapped among neck
Long scarve in son, the method for production have woven, manual woollen yarn knitting etc., and material is based on silk and wool, the sense of touch of silk scarf
It is smooth, with soft, frivolous, elasticity is good, washing shrinkage is low, the feature of the feel of smooth softness as silk and pendency sense.
Mulberry silk has the characteristics that elongated, soft, moisture absorption, good luster, traditional silk (four moultinism silks or five dormancy ages
Silk) wrinkle resistance is poor, it is unable to fabric ultrathin type silk and product；The method of existing modified silk fiber is to be bred as three moultinisms
Kind silkworm, such as dawn, SG, 305, production fiber number are about the silk of 2.0 daniers；It is bred as three moultinism kind silkworm of mutagenesis, medication
Common four moultinisms silk mutagenesis at three molt silkworms, is produced silk ultra-fine by product；Or with " ultra-fine element " (the chloro- N- phenyl miaow of 2,4- bis-
Azoles) induction four molt silkworms, three dormancyization, produce silk ultra-fine；Or mulberry leaf surface is uniformly sprayed on anti-JH and is added to silkworm
Food makes common four dormancies silkworm, three dormancyization, produces silk ultra-fine.But since ultrafine mulberry silk fiber number is small, fibre strength is lower,
Therefore, the problem of in simultaneously silk twisting process because of strength, frequent fracture of wire, in addition due to through Xiang Zhangli during looming weaving
With the factor of reed friction, often breaks end, be not used to produce.
Summary of the invention
There are scarfs prepared by a variety of mulberry silks for the prior art, but are all that coarse denier fiber is prepared, and do not see pass
In the report of 13/15D filament, the record of scarf is more prepared without 9/11D superfine mulberry silk fiber raw silk, mainly due to fine denier filament
The fracture of wire in production, this root problem lead to not apply, and can not embody the excellent properties of fine denier filament, and refining fabric is system
The basic of standby scarf is also deciding step, is played a decisive role to scarf performance.The present invention solves fine denier filament production by starching
The problem of easy fracture of wire, then degumming obtain increasing the smooth warmth retention property of scarf with a small amount of tussah silk blend after silk ultra-fine.
To solve the above problems, being enclosed the invention discloses a kind of based on superfine mulberry silk fiber/silk tussah fibre silk
Towel fabric, preparation method includes the following steps:
(1) ultra-fine Raw Silk is impregnated by water-soluble poly ester polyether slurry, turkey red oil, 1- dodecyl azacyclo-
The starching solution that hept- 2- ketone, nanoparticle, adhesive SD28, curcumin and water form carries out starching processing, then dries, obtain
To starching ultrafine mulberry silk；The nanoparticle is prepared by nano yttrium oxide, boric acid, urea；
(2) starching ultrafine mulberry silk is twisted by winder and silk, preparation is through to mulberry silk fiber and broadwise mulberry silk fiber；
Through successively passing through desizing treatment, enzymatic treatment and hot water treatment to mulberry silk fiber and broadwise mulberry silk fiber, then dries, obtain
Degumming is through to mulberry silk fiber and degumming broadwise mulberry silk fiber；
(3) then by degumming through being knitted to mulberry silk fiber, degumming broadwise mulberry silk fiber with degumming through being mixed to silk tussah fibre
Preparation is made based on superfine mulberry silk fiber/silk tussah fibre silk scarf fabrics.
A kind of preparation method based on superfine mulberry silk fiber/silk tussah fibre silk scarf fabrics, including following step
It is rapid:
(1) ultra-fine Raw Silk is impregnated by water-soluble poly ester polyether slurry, turkey red oil, 1- dodecyl azacyclo-
The starching solution that hept- 2- ketone, nanoparticle, adhesive SD28, curcumin and water form carries out starching processing, then dries, obtain
To starching ultrafine mulberry silk；The nanoparticle is prepared by nano yttrium oxide, boric acid, urea；
(2) starching ultrafine mulberry silk is twisted by winder and silk, preparation is through to mulberry silk fiber and broadwise mulberry silk fiber；
Through successively passing through desizing treatment, enzymatic treatment and hot water treatment to mulberry silk fiber and broadwise mulberry silk fiber, then dries, obtain
Degumming is through to mulberry silk fiber and degumming broadwise mulberry silk fiber；
(3) then by degumming through being knitted to mulberry silk fiber, degumming broadwise mulberry silk fiber with degumming through being mixed to silk tussah fibre
Preparation is made based on superfine mulberry silk fiber/silk tussah fibre silk scarf fabrics.
A kind of superfine mulberry silk fiber silk scarf preparation method of starching ultrafine mulberry silk, includes the following steps, will
Ultra-fine Raw Silk impregnates by water-soluble poly ester polyether slurry, turkey red oil, 1- orthododecyl nitrogen heterocyclo heptane-2-ketone, receives
The starching solution that rice corpuscles, adhesive SD28, curcumin and water form carries out starching processing, then dries, obtain ultra-fine silkworm
Silk fiber silk scarf starching ultrafine mulberry silk；The nanoparticle is prepared by nano yttrium oxide, boric acid, urea.
A kind of superfine mulberry silk fiber silk scarf preparation method of raw silk starching solution, includes the following steps, by water
Dissolubility polyester polyethers slurry, turkey red oil, 1- orthododecyl nitrogen heterocyclo heptane-2-ketone, nanoparticle, adhesive SD28, ginger
Flavine and water mixing composition superfine mulberry silk fiber silk scarf raw silk starching solution；The nanoparticle is by nano oxidized
Yttrium, boric acid, urea are prepared.
A kind of preparation method of the superfine mulberry silk fiber for silk scarf fabrics, comprising the following steps:
(1) ultra-fine Raw Silk is impregnated by water-soluble poly ester polyether slurry, turkey red oil, 1- dodecyl azacyclo-
The starching solution that hept- 2- ketone, nanoparticle, adhesive SD28, curcumin and water form carries out starching processing, then dries, obtain
To starching ultrafine mulberry silk；The nanoparticle is prepared by nano yttrium oxide, boric acid, urea；
(2) starching ultrafine mulberry silk is twisted by winder and silk, preparation is through to mulberry silk fiber and broadwise mulberry silk fiber；
Through successively passing through desizing treatment, enzymatic treatment and hot water treatment to mulberry silk fiber and broadwise mulberry silk fiber, then dries, obtain
Degumming is through to mulberry silk fiber and degumming broadwise mulberry silk fiber；
The superfine mulberry silk fiber for silk scarf fabrics includes degumming through to mulberry silk fiber and degumming broadwise silkworm
Silk fiber.
In the present invention, water-soluble poly ester polyether slurry, turkey red oil, 1- orthododecyl nitrogen heterocyclo heptane-2-ketone, bonding
Agent SD28, curcumin are all existing product, wherein water-soluble poly ester polyether slurry, turkey red oil, 1- dodecyl azepine
Cycloheptyl -2- ketone, curcumin are commercial products, for example water-soluble poly ester polyether slurry SH, adhesive SD28 are open product.This hair
It is bright to configure new size composition using these open substances, silk ultra-fine fiber is surface-treated, can be increased ultra-fine
The intensity of silk fiber, make its and silk twisting process and looming weaving during avoid being broken, water-soluble poly ester polyether slurry
Material is as basic processes composition, its dispersibility can be improved in turkey red oil, and the guess of 1- orthododecyl nitrogen heterocyclo heptane-2-ketone can
To increase organic matter in the even flat effect on superfine mulberry silk fiber surface, adhesive improves the bonding force of organic component, curcumin
Size composition especially nanoparticle should be can be further improved in the combination effect of fiber surface.It is organic with existing routine
Object slurry is different, and the present invention is directed to special superfine mulberry silk fiber, has developed nanoparticle, preparation method is, by urea
It being dispersed in water, boric acid and ethyl alcohol is then added, nano yttrium oxide is added after stirring, stirring removed solvent after 2~2.5 hours,
Obtain solids, then by solids under nitrogen, 950~1000 DEG C calcine 5 hours, obtain nanoparticle using crushing.
Nanoparticle is not directly used in starching by any surface treatment, on the one hand since surface treatment does not have effect to silk gum, separately
On the one hand also avoid the coupling agent of surface treatment to the unfavorable of paste compound and to the unfavorable of subsequent desizing, generally without place
The nanoparticle application effect of reason is poor, this is common sense, and the present invention is using turkey red oil and 1- positive dodecyl aza cyclohepta-
2- ketone is added in water-soluble poly ester polyether slurry, it is evident that the dispersibility that nanoparticle can be improved, it is several in conjunction with curcumin
Additive effectively improves nanoparticle in the attachment on superfine mulberry silk fiber surface.Fibre can be improved using nanoparticle in the present invention
The tensile strength of dimension, more important is avoid the residual to silk gum in desizing processes, improve desizing effect.
In the present invention, nano yttrium oxide, boric acid, urea mass ratio be 50: 65: 100；In starching solution, water-soluble poly
The mass fraction of ester polyether slurry is 10%~20%, and the mass fraction of turkey red oil is 0.4%~0.6%, 1- dodecyl
The mass fraction of azacyclo- hept- 2- ketone is 0.2%~0.5%, and the mass fraction of adhesive SD28 is 3%~5%, the matter of nanoparticle
Measuring score is 3~3.3%, and the mass fraction of curcumin is 2~2.2%, remaining is water.Ultra-fine silkworm can be improved in such proportion
The effect of impregnation of silk fiber, so that size composition is uniformly dispersed in fiber surface, in terms of embodiment effect, ultrafine mulberry silk is fine
The tensile strength of dimension is improved, and desizing effect is good.
In the present invention, starching handle when, bath raio be 1:5~1:10, temperature be 30 DEG C~40 DEG C, the time be 25min~
30min；After the completion of starching, ultrafine mulberry silk is dry in hot-air drying device after centrifugal dehydration, obtains the ultra-fine mulberry of starching
Silk.
In the present invention, the specification of ultra-fine Raw Silk is 9/11D, by the ultra-fine silkworm list that fiber number is 1.0~1.2 daniers
Silk filature obtains, and is existing product, and raw silk is by filature by product made of the mutual obvolvent of several Bombyx-mori Baves, and fine denier is raw
Silk weaving at fabric have wrinkle resistance it is strong, rich in the characteristics such as gloss, dyeing effect be good, but the prior art has no with this fineness
Report of the mulberry silk as scarf fabrics, main cause is exactly that mechanical strength described in background is too low, and the present invention passes through starching
Processing solves existing technical problem.
In the present invention, degumming is through referring to that degumming silk tussah fibre as scarf warp fiber, is only located to silk tussah fibre
Based on superfine mulberry silk fiber/silk tussah fibre silk scarf fabrics through to, in weaving, degumming silk tussah fibre and de-
Glue through to mulberry silk fiber collectively as through being weaved to silk fiber；The warming of pure mulberry silk fabric lining can be improved
Property.
In the present invention, winder, simultaneously silk twisting and weaving can carry out network originally as the prior art on slack winder
Cylinder processing carries out simultaneously silk twisting processing on simultaneously silk twisting mill, is weaved on loom；The present invention is preferably through fine to mulberry silk
Dimension is 4/9/11D mulberry silk 14T/2S2Z, and broadwise mulberry silk fiber is 2/9/11D mulberry silk 18T/2S2Z, the degumming toothed oak of use
Silk fiber is the prior art, such as silk tussah fibre disclosed in " 2014102867302 ".It is of the present invention to be based on ultra-fine silkworm
Silk fiber/silk tussah fibre silk scarf fabrics be plain weave, through to density be 48/10cm, latitudinal density be 51/
10cm.The product warmth retention property of this specification is good, wrinkle resistance is excellent, it is preferred that through into 48/10cm of density, degumming tussah silk
The advantages of fiber is 10/10cm, can keep mulberry silk while using tussah silk superperformance elasticity is good, at the same it is also sharp
In subsequent dyeing.
In the present invention, desizing treatment carries out in desizing solution, and enzymatic treatment carries out in enzyme solutions, and hot water treatment is in hot water
It is carried out in solution；In desizing solution, the mass fraction of sodium carbonate is 1.5%~2.0%, remaining is water, and the bath raio of desizing treatment is
1:30, temperature are 80 DEG C~85 DEG C, and the time is 30 min~60min；In enzyme solutions, the mass fraction of alkali protease is 0.2%
~0.5%, the mass fraction of sodium sulphate is 0.1%~0.2%, and the mass fraction of sodium carbonate is 0.5%, remaining is water, enzymatic treatment
Bath raio is 1:30, and temperature is 55 DEG C~65 DEG C, and the time is 60 min~90min；In hydrothermal solution, the mass fraction of acetic acid is
0.2%~0.3%, remaining is water, and the bath raio of hot water treatment is 1:30, and temperature is 90 DEG C, and the time is 30 min.After the completion of processing,
Drying and processing is carried out on blast heater, and degumming is made through to mulberry silk fiber and degumming broadwise mulberry silk fiber, to practice Bai Chao
Thin mulberry silk fiber.The effect of this step is removal silk gum, and then embodies the excellent properties of silk fiber, such as warming, soft,
Crease-resistant, the present invention is using three step process and provides processing solution and Parameter Conditions, can cooperate starching condition, and silk gum processing is dry
Only, optimum performance is provided for silk fabric.
Compared with thick denier (filament number is 2.6~3.0 daniers) silk, fine-denier (1.0~1.2 danier of monofilament) silk
Refractive property it is more preferable, reflecting feel is strong, and pendency sense is strong, can improve the smooth and elastic of squeeze, and dyeing and printing products are bright in luster
Degree is preferable.But since ultrafine mulberry silk fiber number is small, fibre strength is lower.Therefore, because of strength in simultaneously silk twisting process
Problem, frequent fracture of wire, in addition due to often breaking end through the factor to tension and reed friction during looming weaving, it can not
For producing.Therefore, improve the sizing technique of fine-denier silk, improve ultrafine mulberry silk strength and cohesive force, be prepare it is ultra-fine true
The key technology of silk scarf fabrics.
The present invention improves strength of raw silk by starching processing, and the scarf fabrics of preparation have the function of wear-resisting, high-strength, increase
The service life of scarf fabrics can effectively remove silk gum by refining treatment, so that scarf fabrics have good warmth retention property
Energy；The mulberry silk that the present invention uses intensity originally relatively low is raw material, and in conjunction with preparation process, not only wool type is rich for manufactured scarf fabrics
It is full, while through to a small amount of existing silk tussah fibre of addition, warming moisture-absorbing is good, and synthesis is seen, scarf is ventilative to light, comfortable magnificent
Expensive, beautiful top grade, and it is crease-resistant, intensity is good, harmless to human skin.
Compared with prior art, the sizing technique that the present invention limits improves the intensity of fiber, hence it is evident that reduces ultra-fine mulberry
Silk fiber the phenomenon that fracture of wire frequent occurrence, improves the cohesive force of superfine mulberry silk fiber in simultaneously silk twisting process, increases
Lubricity；It in concise scouring processes, can remove completely, not influence the service performance of mulberry silk fiber, especially starching and handle
Effect is also improved to the silk performance after degumming, estimation is swollen in soaking process silk gum, and inorganic agent is allowed to have a little infiltration
Thoroughly effect, in conjunction with desizing, the process of enzymatic treatment hot water treatment, obtain based on superfine mulberry silk fiber/silk tussah fibre
Silk scarf fabrics gas permeability and warmth retention property are preferable；And the strong operability of processing method of the present invention, it is suitble to industry metaplasia
It produces, processing cost is low.
Specific embodiment
The invention patent is further described below with reference to embodiment:
Polyester polyethers slurry SH, turkey red oil, 1- orthododecyl nitrogen heterocyclo heptane-2-ketone, curcumin are commercially available, open produce
Product, adhesive are commercial product, such as adhesive SD28, adhesive HD.
Synthesis example
10Kg urea is dispersed in 30 liters of water, 13Kg boric acid and 50L ethyl alcohol is then added, it is nano oxidized that 20Kg is added after stirring
Yttrium stirs 2.5 hours back spins and boils off except solvent, obtains solids, then by solids under nitrogen, 950 DEG C calcine 5 hours,
Nanoparticle is obtained using crushing, aerodynamic particle size is between 500~700 nanometers.
Embodiment one
On cone dyeing machine, by 9/11D superfine mulberry silk fiber cheese, (raw silk is 1.0~1.2 daniers by fiber number
Ultra-fine silkworm monofilament filature obtains, breaking strength 0.9CN/dtex) impregnate it is bis- macro by 50Kg polyester polyethers slurry SH(), 2 Kg it is native
Ear its red oil, 2Kg 1- orthododecyl nitrogen heterocyclo heptane-2-ketone (letter health), 15 Kg adhesive SD28,16Kg nanoparticles,
The starching solution of 10Kg curcumin and 405Kg water mixing composition, bath raio 1:8,30 DEG C of soaking temperature, soaking time 30min.Starching
After the completion, it is dehydrated on centrifugal dehydrator, then, is dried in hot wind drying plant, the silk fiber cheese dried,
For starching ultrafine mulberry silk (breaking strength 2.1CN/dtex).
The silk fiber cheese of above-mentioned drying is subjected to winder processing on slack winder, then in simultaneously silk twisting mill
It is upper to carry out and silk twisting processing, it prepares through to mulberry silk fiber and broadwise mulberry silk fiber；Wherein through being to mulberry silk fiber
4/9/11D mulberry silk 14T/2S2Z, broadwise mulberry silk fiber are 2/9/11D mulberry silk 18T/2S2Z.
It hangs and practices in slot in silk, by above-mentioned through impregnating to mulberry silk fiber and broadwise mulberry silk fiber by 45 Kg sodium carbonate
With the desizing solution of 2955Kg water composition, bath raio 1:30 is warming up to 80 DEG C, and handles 35min at this temperature, and processing is completed
Afterwards, drain；The enzymatic treatment liquid of 6 Kg alkali proteases, 5Kg sodium sulphate, 15Kg sodium carbonate and 2974Kg water composition, bath raio is added
For 1:30,60 DEG C are warming up to, and handles 90min at this temperature, after the completion of processing, drain；7Kg acetic acid and 2993Kg is added
Water, bath raio 1:30 are warming up to 90 DEG C, and handle 30min at this temperature.After the completion of processing, successively with 80 DEG C, 60 DEG C of water
It washes, then washes 3 times with cold water, drying processing is finally carried out on blast heater, obtain degumming through to mulberry silk fiber and degumming latitude
To mulberry silk fiber.
Using existing degumming silk tussah fibre, above-mentioned degumming through to mulberry silk fiber as warp fiber, above-mentioned degumming broadwise
Mulberry silk fiber is as weft fiber, and conventional woven preparation is true based on superfine mulberry silk fiber/silk tussah fibre on loom
Silk scarf fabrics are plain weave, and through being 48/10cm to density, wherein 10/10cm of degumming silk tussah fibre, broadwise are close
Degree is 51/10cm.
Starching ultrafine mulberry silk also increases the cohesive force between monofilament other than in monofilament surface raising filament strength,
The two combines and effectively increases strength of raw silk, solves the problems, such as existing ultra-fine raw silk in simultaneously silk twisting process because strength is through normal off
Silk, since through the factor to tension and reed friction, often broken end, is not used to the problem of producing during looming weaving,
Entire production process is smooth, no fracture, and fracture of wire occurs if directly being twisted with 9/11D superfine mulberry silk fiber cheese and silk
Situation, weaving process are even more broken end problem occur.Mulberry silk raw silk elongation at break is 15.23%, 16.62% before and after starching, is broken
Splitting elongation can be used as the indirect indexes for measuring silk fiber flexibility, and the raw silk deformability for illustrating that the present invention is handled is more preferable,
Than there is better flexibility before handling.
Be made the unit area weight based on superfine mulberry silk fiber/silk tussah fibre silk scarf fabrics be 25.1 grams/
Square metre, thickness 0.98mm；Soft, wrinkling resistance is good, using turnaround time after folding as the auxiliary of characterization wrinkling resistance
Index, the scarf fabrics prepared after starching improve 40% compared with scarf fabrics prepared by non-starching；Using fabric air-permeability amount instrument to scarf
The gas permeability of fabric is tested, 3 average out to 367mm/S, carries out heat preservation rate survey to scarf fabrics using flat insulation instrument
Examination, 3 average out to 22.3% illustrate that fabric of the invention has preferable gas permeability and warming effect, if being added without tussah silk
Fiber, wrinkling resistance improve 43% compared with scarf fabrics prepared by non-starching, and gas permeability 379mm/S, heat preservation rate 22.0% illustrates few
Warmth retention property, while basic maintenance fabric elasticity can be improved in the addition of amount silk tussah fibre, and Study on dyeing is subsequent gradually to be carried out；Not
The scarf fabrics warmth retention property and gas permeability of starching preparation are poor, respectively 19.8%, 322mm/S.Partial size is directlyed adopt 400
Boron nitride nanometer particle replaces above-mentioned nanoparticle, obtained starching ultrafine mulberry silk breaking strength between~500 nanometers
1.7CN/dtex, elongation at break 16.03, guess is since nanoparticle prepared by the present invention is irregular, when silk gum is swollen
Time may be easier in conjunction with fiber.
Comparative example one
On the basis of example 1, it is added without nanoparticle, the starching ultrafine mulberry silk breaking strength 1.7CN/dtex of preparation,
Elongation at break is 15.99%.The silk fiber cheese of above-mentioned drying is subjected to winder processing on slack winder, then
And silk twisting mill on carry out and silk twisting processing, prepare through to mulberry silk fiber and broadwise mulberry silk fiber；Wherein through to
Mulberry silk fiber is 4/9/11D mulberry silk 14T/2S2Z, and broadwise mulberry silk fiber is 2/9/11D mulberry silk 18T/2S2Z.Using
The method degumming and refining of embodiment one obtains degumming through to mulberry silk fiber and degumming broadwise mulberry silk fiber, further according to embodiment
One on loom conventional woven preparation be plain weave based on superfine mulberry silk fiber/silk tussah fibre silk scarf fabrics,
Through being 48/10cm to density, wherein 10/10cm of degumming silk tussah fibre, latitudinal density are 51/10cm；Entire production
There is fracture of wire in process, and than directly using 9/11D superfine mulberry silk fiber cheese, simultaneously silk twisting generation fracture of wire situation is few.
The fabric hand feel of preparation is soft, using turnaround time after folding as the auxiliary characteristics of characterization wrinkling resistance, after starching
The scarf fabrics of preparation improve 27% compared with scarf fabrics prepared by non-starching；The scarf fabrics warmth retention property of preparation and gas permeability compared with
Difference, respectively 21.5%, 337 mm/S.
Comparative example two
On the basis of example 1, it is added without curcumin, the starching ultrafine mulberry silk breaking strength 1.5CN/dtex of preparation breaks
Splitting elongation is 16.23%.The silk fiber cheese of above-mentioned drying is subjected to winder processing on slack winder, is then existed
And carried out on silk twisting mill and silk twisting processing, it prepares through to mulberry silk fiber and broadwise mulberry silk fiber；Wherein through Xiang Sang
Silk fiber is 4/9/11D mulberry silk 14T/2S2Z, and broadwise mulberry silk fiber is 2/9/11D mulberry silk 18T/2S2Z.Using reality
The method degumming and refining for applying example one obtains degumming through to mulberry silk fiber and degumming broadwise mulberry silk fiber, further according to embodiment one
Conventional woven preparation is plain weave, warp based on superfine mulberry silk fiber/silk tussah fibre silk scarf fabrics on loom
It is 48/10cm to density, wherein 10/10cm of degumming silk tussah fibre, latitudinal density are 51/10cm；Entirely produced
There is fracture of wire in journey, and than directly using 9/11D superfine mulberry silk fiber cheese, simultaneously silk twisting generation fracture of wire situation is few.Due to that cannot connect
Continuous production, it is unfavorable to industrializing, other performance tests need not be carried out.
Comparative example three
On cone dyeing machine, by 9/11D superfine mulberry silk fiber cheese, (raw silk is 1.0~1.2 daniers by fiber number
Ultra-fine silkworm monofilament filature obtains, breaking strength 0.9CN/dtex) impregnate it is bis- macro by 50Kg polyester polyethers slurry SH(), 2 Kg it is native
Ear its red oil, 2Kg 1- orthododecyl nitrogen heterocyclo heptane-2-ketone (letter health), 15 Kg adhesive SD28,16Kg nanoparticles,
The starching solution of 10Kg curcumin and 405Kg water mixing composition, bath raio 1:8,30 DEG C of soaking temperature, soaking time 30min.Starching
After the completion, it is dehydrated on centrifugal dehydrator, then, is dried in hot wind drying plant, the silk fiber cheese dried,
For starching ultrafine mulberry silk.The silk fiber cheese of above-mentioned drying is subjected to winder processing on slack winder, is then existed
And carried out on silk twisting mill and silk twisting processing, it prepares through to mulberry silk fiber and broadwise mulberry silk fiber；Wherein through Xiang Sang
Silk fiber is 4/9/11D mulberry silk 14T/2S2Z, and broadwise mulberry silk fiber is 2/9/11D mulberry silk 18T/2S2Z.
It will be obtained through preparing mulberry silk fiber chiffon fabric to mulberry silk fiber and broadwise mulberry silk fiber weaving on loom
The mulberry silk fiber chiffon fabric arrived is plain weave, and through being 48/10cm to density, latitudinal density is 51/10cm.True
Silk, which is hung, to be practiced in slot, by above-mentioned through impregnating to mulberry silk fiber and broadwise mulberry silk fiber by 45 Kg sodium carbonate and 2955Kg water group
At desizing solution, bath raio 1:30 is warming up to 80 DEG C, and handles 35min at this temperature, after the completion of processing, drain；It is added
7Kg acetic acid and 2993Kg water, bath raio 1:30 are warming up to 90 DEG C, and handle 30min at this temperature.After the completion of processing, successively
3 times are washed with 80 DEG C, 60 DEG C of washings, then with cold water, drying processing is finally carried out on blast heater, obtain degumming through to mulberry silk
Fiber and degumming broadwise mulberry silk fiber.
According to embodiment one, conventional woven preparation is enclosed based on superfine mulberry silk fiber/silk tussah fibre silk on loom
Towel fabric is plain weave, and through being 48/10cm to density, wherein 10/10cm of degumming silk tussah fibre, latitudinal density are
51/10cm, unit area weight is 26.2 grams/m, thickness 0.99mm；Feel is slightly soft；Using fabric air-permeability amount instrument pair
The gas permeability of scarf fabrics is tested, and 3 average out to 328mm/S keep the temperature scarf fabrics using flat insulation instrument
Rate test, 3 average out to 22.2%.
Scarf is as one of winter warming ornament, and the performances such as warming, comfortable of fabric material are increasingly by people
Attention.The fine-denier of fiber is the pursuit of the mankind, and the textile fabric used earliest is natural fiber-cotton, fiber crops, hair, silk,
Middle mulberry silk surely belongs to best one of the fiber of wears performance, no matter dress comfort or appearance in terms of have
Unique advantage.Unfortunately, ultrafine mulberry silk poor mechanical property is not used to the preparation of scarf fabrics, is easy fracture of wire, the present invention
It sets about from the simultaneously fracture of wire of silk twisting and weaving process is solved, by the combination of size composition and technique, realizes that raw silk is disconnected
The raising of resistance to spalling is added a small amount of tussah silk blend without fracture of wire phenomenon in production process, while improving the crease-resistant of finished fabric
Ability, breathable heat insulating ability, maintain elasticity.
Claims (10)
1. a kind of based on superfine mulberry silk fiber/silk tussah fibre silk scarf fabrics, which is characterized in that described based on ultra-fine
The preparation methods of mulberry silk fiber/silk tussah fibre silk scarf fabrics the following steps are included:
(1) ultra-fine Raw Silk is impregnated by water-soluble poly ester polyether slurry, turkey red oil, 1- dodecyl azacyclo-
The starching solution that hept- 2- ketone, nanoparticle, adhesive SD28, curcumin and water form carries out starching processing, then dries, obtain
To starching ultrafine mulberry silk；The nanoparticle is prepared by nano yttrium oxide, boric acid, urea；
(2) starching ultrafine mulberry silk is twisted by winder and silk, preparation is through to mulberry silk fiber and broadwise mulberry silk fiber；
Through successively passing through desizing treatment, enzymatic treatment and hot water treatment to mulberry silk fiber and broadwise mulberry silk fiber, then dries, obtain
Degumming is through to mulberry silk fiber and degumming broadwise mulberry silk fiber；
(3) then by degumming through being knitted to mulberry silk fiber, degumming broadwise mulberry silk fiber with degumming through being mixed to silk tussah fibre
Preparation is made based on superfine mulberry silk fiber/silk tussah fibre silk scarf fabrics.
2. according to claim 1 based on superfine mulberry silk fiber/silk tussah fibre silk scarf fabrics, feature exists
In the preparation method of nanoparticle is to be dispersed in water urea, and boric acid and ethyl alcohol is then added, nano oxygen is added after stirring
Change yttrium, stirring removes solvent after 2~2.5 hours, obtains solids, then by solids under nitrogen, 950~1000 DEG C of calcinings
5 hours, nanoparticle was obtained using crushing.
3. according to claim 2 based on superfine mulberry silk fiber/silk tussah fibre silk scarf fabrics, feature exists
In the mass ratio of, nano yttrium oxide, boric acid, urea be 50: 65: 100.
4. according to claim 1 based on superfine mulberry silk fiber/silk tussah fibre silk scarf fabrics, feature exists
In in starching solution, the mass fraction of water-soluble poly ester polyether slurry is 10%~20%, and the mass fraction of turkey red oil is
The mass fraction of 0.4%~0.6%, 1- orthododecyl nitrogen heterocyclo heptane-2-ketone is 0.2%~0.5%, the quality point of adhesive SD28
Number is 3%~5%, and the mass fraction of nanoparticle is 3~3.3%, and the mass fraction of curcumin is 2~2.2%, remaining is water.
5. according to claim 1 based on superfine mulberry silk fiber/silk tussah fibre silk scarf fabrics, feature exists
In when starching is handled, bath raio is 1:5~1:10, and temperature is 30 DEG C~40 DEG C, and the time is 25min~30min；After the completion of starching,
Ultrafine mulberry silk is dry in hot-air drying device after centrifugal dehydration, obtains starching ultrafine mulberry silk.
6. according to claim 1 based on superfine mulberry silk fiber/silk tussah fibre silk scarf fabrics, feature exists
In the specification of ultra-fine Raw Silk is 9/11D, is obtained by the ultra-fine silkworm monofilament filature that fiber number is 1.0~1.2 daniers；Through
It is 4/9/11D mulberry silk 14T/2S2Z to mulberry silk fiber, broadwise mulberry silk fiber is 2/9/11D mulberry silk 18T/2S2Z；Institute
Stating based on superfine mulberry silk fiber/silk tussah fibre silk scarf fabrics is plain weave；Through being 48/10cm to density,
Wherein degumming silk tussah fibre is 10/10cm；Latitudinal density is 51/10cm.
7. according to claim 1 based on superfine mulberry silk fiber/silk tussah fibre silk scarf fabrics, feature exists
In, desizing treatment carries out in desizing solution, and in desizing solution, the mass fraction of sodium carbonate is 1.5%~2.0%, remaining is water,
The bath raio of desizing treatment is 1:30, and temperature is 80 DEG C~85 DEG C, and the time is 30 min~60min.
8. according to claim 1 based on superfine mulberry silk fiber/silk tussah fibre silk scarf fabrics, feature exists
In enzymatic treatment carries out in enzyme solutions, and in enzyme solutions, the mass fraction of alkali protease is 0.2%~0.5%, the matter of sodium sulphate
Measuring score is 0.1%~0.2%, and the mass fraction of sodium carbonate is 0.5%, remaining is water, and the bath raio of enzymatic treatment is 1:30, and temperature is
55 DEG C~65 DEG C, the time is 60 min~90min.
9. according to claim 1 based on superfine mulberry silk fiber/silk tussah fibre silk scarf fabrics, feature exists
In hot water treatment carries out in hydrothermal solution, and in hydrothermal solution, the mass fraction of acetic acid is 0.2%~0.3%, remaining is water, heat
The bath raio of water process is 1:30, and temperature is 90 DEG C, and the time is 30 min.
10. a kind of preparation method based on superfine mulberry silk fiber/silk tussah fibre silk scarf fabrics, which is characterized in that
The following steps are included:
(1) ultra-fine Raw Silk is impregnated by water-soluble poly ester polyether slurry, turkey red oil, 1- dodecyl azacyclo-
The starching solution that hept- 2- ketone, nanoparticle, adhesive SD28, curcumin and water form carries out starching processing, then dries, obtain
To starching ultrafine mulberry silk；The nanoparticle is prepared by nano yttrium oxide, boric acid, urea；
(2) starching ultrafine mulberry silk is twisted by winder and silk, preparation is through to mulberry silk fiber and broadwise mulberry silk fiber；
Through successively passing through desizing treatment, enzymatic treatment and hot water treatment to mulberry silk fiber and broadwise mulberry silk fiber, then dries, obtain
Degumming is through to mulberry silk fiber and degumming broadwise mulberry silk fiber；
(3) then by degumming through being knitted to mulberry silk fiber, degumming broadwise mulberry silk fiber with degumming through being mixed to silk tussah fibre
Preparation is made based on superfine mulberry silk fiber/silk tussah fibre silk scarf fabrics.
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| CN202010105416.5A CN111321499B (en) | 2018-12-18 | 2018-12-18 | Preparation method of silk scarf fabric based on superfine mulberry silk fibers/tussah silk fibers |
| CN201811555502.5A CN109505048B (en) | 2018-12-18 | 2018-12-18 | Silk scarf fabric based on superfine mulberry silk fibers/tussah silk fibers |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| EP4116474A1 (en) * | 2021-07-06 | 2023-01-11 | MANTERO Seta S.p.a. | Ultra-light silk fabric and method for its production |
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| Publication number | Publication date |
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| CN111321499B (en) | 2021-05-07 |
| CN109505048B (en) | 2020-04-03 |
| CN111321499A (en) | 2020-06-23 |
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Denomination of invention: Silk scarf fabric based on ultrafine mulberry silk fiber/tussah silk fiber Effective date of registration: 20230804 Granted publication date: 20200403 Pledgee: Shanghai Rural Commercial Bank Co.,Ltd. Huangpu sub branch Pledgor: SHANGHAI ZHAOWU BRAND MANAGEMENT CO.,LTD. Registration number: Y2023310000432 |